Aquifer contamination by chlorinated-VOCs: the case of an urban metropolis megasite overlying the Coastal Plain aquifer in Israel

The Tel Aviv metropolitan region (200 km²), located on the sandy and phreatic Mediterranean Coastal Plain aquifer in Israel, is an example of a contaminated megasite that is additionally complicated by being part of a densely populated urban environment. Despite being a major source of fresh potable water, no dedicated aquifer monitoring systems exist. The vast majority of tested water supply wells (82% of 90 wells) were found to be contaminated with one or more chlorinated volatile organic compounds (Cl-VOCs) such as trichloroethene and tetrachloroethene, originating from multiple sources, including former industrial sites. Temporal variations in Cl-VOC concentrations in water supply wells were large and unpredictable. Such aquifer contamination requires immediate action in terms of aquifer management and municipal water distribution. To cope with temporal and spatial variations in contaminant concentrations in water supply wells in an area where monitoring wells are absent, aquifer impact areas were defined based on the concentration of the Cl-VOC contaminant in pumping wells that was greatest in relation to its drinking water standard over a 3-year period. Such a map can be used to define water supply treatment and municipal well monitoring requirements, until an adequate monitoring system is established.     

城市屋顶雨水回灌裂隙岩溶含水层的国内外案例介绍——兼对济南市屋顶雨水回灌裂隙岩溶含水层问题的思考

通过监测和分析济南市市区降水、屋面雨水水质和水量过程,屋顶雨水属微污染类水,经前期雨水弃流和预处理达到一定质量标准,通过管井回灌到裂隙岩溶含水层,可用于饮用水供水和保护地下水环境。已做的示踪试验表明,北方岩溶含水介质多属多重裂隙岩溶通道,因此在人工开采条件下,回灌应关注快、慢速流带来的不同水质变化问题,包括屋面雨水与裂隙岩溶介质的水岩作用。澳大利亚的案例说明,裂隙岩溶含水层对不同污染物有着不同的衰变效果。100多年来Mount Gambier市城区雨洪水经非承压石灰岩含水层径流一直排放到作为城市供水的蓝湖,到目前它对蓝湖水质没有表现出任何可量度的损害。但对于济南市的屋顶雨水回灌裂隙岩溶含水层,仍有许多问题需要研究。      

Arsenic-rich groundwater in an urban area experiencing drought and increasing population density,Perth, Australia

Groundwater in the Gwelup groundwater management area in Perth, Western Australia has been enriched in As due to the exposure of pyritic sediments caused by reduced rainfall, increased groundwater abstraction for irrigation and water supply, and prolonged dewatering carried out during urban construction activities. Groundwater near the watertable in a 25–60 m thick unconfined sandy aquifer has become acidic and has affected shallow wells used for garden irrigation. Arsenic concentrations up to 7000 μg/L were measured in shallow groundwater, triggering concerns about possible health effects if residents were to use water from household wells as a drinking water source. Deep production wells used for public water supply are not affected by acidity, but trends of progressively increasing concentrations of Fe, SO₄ and Ca over a 30-a period indicate that pyrite oxidation products extend to the base of the unconfined aquifer. Falling Eh values are triggering the release of As from the reduction of Fe(III) oxyhydroxide minerals near the base of the unconfined aquifer, increasing the risk that groundwater used as a drinking water source will also become contaminated with high concentrations of As.     

Groundwater pollution due to sugar-mill effluent, at Sonai, Maharashtra, India

 Analyses of 126 samples collected from 18 dug wells in the shallow basaltic aquifer over a period of 7 months have revealed spatial as well as temporal changes in the chemical properties of groundwater. While the temporal changes have been attributed to dilution and concentration phenomena governed by climatic factors, the spatial variations in the geochemical characteristics of groundwater appeared to be related to pollution due to effluents from the Mula Sugar Factory. The cause of groundwater pollution is the effluent carried by a stream flowing through the area. Fluctuations in the groundwater table, influent water quality character of the stream, less capacity to accommodate large volume of effluent and occurrence of zero base flow (under natural conditions) in the stream are the factors favoring infiltration of constituents of waste water into the underlying weathered basaltic aquifer. Pollutants have entered into the shallow aquifer by downward percolation through the zone of aeration to form a recharge mound at the water table and, further, lateral movement below the water table. The plume of polluted groundwater has a lateral extent of a few meters in the upstream area and more than 400 m on either side of the stream in the downstream part. The zone of polluted groundwater has an areal extent of more than 3.5 km². Groundwater is the only source available for drinking and agricultural purposes. It is recommended that the base of the lagoons and the stream used for release of plant effluent should be waterproofed for the protection of groundwater in the Sonai area. Received: 30 April 1997 · Accepted: 23 September 1997     

Application of Numerical Modeling for Groundwater Flow System Analysis in the Akaki Catchment,Central Ethiopia

A three dimensional steady-state finite difference groundwater flow model is used to quantify the groundwater fluxes and analyze the subsurface hydrodynamics in the Akaki catchment by giving particular emphasis to the well field that supplies water to the city of Addis Ababa. The area is characterized by Tertiary volcanics covered with thick residual and alluvial soils. The model is calibrated using head observations from 131 wells. The simulation is made in a two layer unconfined aquifer with spatially variable recharge and hydraulic conductivities under well-defined boundary conditions. The calibrated model is used to forecast groundwater flow pattern, the interaction of groundwater and surface water, and the effect of pumping on the well field under different scenarios. The result indicates that the groundwater flows regionally to the south converging to the major well field. Reservoirs and rivers play an important role in recharging the aquifer. Simulations made under different pumping rate indicate that an increase in pumping rate results in substantial regional groundwater level decline, which will lead to the drying of springs and shallow hand dug wells. Also, it has implications of reversal of flow from contaminated rivers into productive aquifers close to main river courses. The scenario analysis shows that the groundwater potential is not enough to sustain the ever-growing water demand of the city of Addis Ababa. The sensitivity and scenario analysis provided important information on the data gaps and the specific sites to be selected for monitoring, and may be of great help for transient model development. This study has laid the foundation for developing detailed predictive groundwater model, which can be readily used for groundwater management practices.     

Effects of the planned ephesus recreational canal on freshwater–seawater interface in the Selçuk sub-basin, İzmir-Turkey

An artificial water canal opening is planned between the Agean Sea and the historical Ephesus site for the sake of tourism in the Selçuk sub-basin. In order to predict the effects of the planned canal on freshwater–seawater interface and related contamination in the aquifer, 3-D numerical density dependent flow and solute transport simulations were carried out. The simulations included the pre-pumping and pumping periods without a canal and the prediction period in the presence of the canal. Chloride concentration comparisons of the results obtained from the pre-pumping period and the pumping period indicate that the freshwater-seawater interface in the aquifer has progressed inland due to artificial discharge in the sub-basin. Drawdown during the pumping period is about 15 cm. The planned canal opening could further lower the groundwater levels in the area and would change the groundwater flow directions in the first 4 years. Then the levels and flow directions will nearly recover. However, the canal opening could cause further seawater intrusion into the aquifer to the extent that groundwater would be unfit to use for irrigation after the seventh year of the canal opening in the irrigation cooperative II wells area and would be unfit to use for drinking purposes after the tenth year in the municipality wells area located at the south of the cooperative II wells. On the other hand, the cooperative I wells would not be effected by the opening of the canal.     

Influence of flooding on groundwater flow in central Cambodia

Cambodia is affected by flooding from the Mekong, Tonle Sap and Bassac rivers every year, which harms human populations and damages property, as well as alters the water quality in aquifer systems. The objective of this paper is to highlight the effects of river flooding on groundwater flow using numerical simulation. A two-dimensional groundwater flow model coupled with a groundwater recharge model was applied to the research area in central Cambodia. River level variation was included in model processes, and flood areas and periods were assigned. The results showed that during flooding periods, floodwater from the three rivers played an important role in recharging groundwater. During the dry season, Tonle Sap River received groundwater supply from the northwest, and levels in the Bassac and Mekong River dropped to lower than the groundwater level. This study improves understanding of the surface water and groundwater flow system in the study area.     

济南市玉符河多水源回灌岩溶水水质风险评价

济南以泉城而闻名,保泉和供水安全问题是其面临的巨大挑战,利用多水源进行岩溶水回灌是解决问题的有效措施之一,但是补给水源水质相对岩溶水而言较差,回灌到地下可能存在一定健康和环境风险,需要对回灌系统的水质进行风险评价。本文对比地下水质量标准和地下水水质背景值,重点选择地表源水超标和劣于背景值的风险源监测指标,借鉴澳大利亚含水层补给管理指南,对玉符河多水源回灌岩溶含水层工程运行期的水质风险进行评价。2015年对黄河水、卧虎山水库两种水源多次回灌期间的源水、孔隙水和岩溶水的22项指标进行水质监测和指标分析,风险残余评价结果表明黄河水回灌补源期间,平均浊度的标准指数源水是1.4,孔隙水1.7,岩溶水0.93,硫酸盐平均含量的标准指数源水是0.93,孔隙水0.9,岩溶水0.73,氯离子虽没有超过地下水III类标准,但是在源水中含量是地下水含量的2倍多;卧虎山水库水回灌补源期间,平均浊度的标准指数源水是2.4,孔隙水1.1,岩溶水0.43,硫酸盐平均含量的标准指数在源水0.75,孔隙水0.84,岩溶水0.66,氨氮的平均含量的标准指数源水1.14,孔隙水1.47,岩溶水1.35。因此,浊度、硫酸盐和溶质在裂隙岩溶含水层迁移较快为两种水源玉符河回灌补源工程的共同高风险项和关键控制点。此外,黄河水补源还需注意盐度,卧虎山水库水补源还需控制营养物的污染风险。基于以上评价,还提出了限制回灌量占区域岩溶水资源量比例等建议。      

Quality assessment of groundwater at south Al Madinah Al Munawarah area, Saudi Arabia

Groundwater is the main source of irrigation within south Al Madinah Al Munawarah region. It is also an important source of drinking water in many areas including Madinah city. The wells installed in the aquifer of the study area (south Madinah city) are not currently regulated by the local authorities although they are a key component of water supply. The aquifers in the study area range from unconfined to semi-confined and confined. The main aim of this study is to assess the groundwater in the region for drinking and agricultural uses. For this purpose, hydrochemical analyses of major, minor and trace constituents and nutrients were performed on 29 groundwater samples from the aquifer located about 20 km south of Madinah. The recharge rate of the aquifer of the study area was estimated to be 6.58 % of the annual precipitation using the chloride mass-balance method. Chloride was positively correlated with major ions, which suggests that agricultural activities have some effect on groundwater chemistry through leaching of readily soluble salts from the soil zone. Groundwater of the study area is characterized by dominance of Na over Ca. Chloride was found to be the most dominant anion and replaced by HCO₃, thus reflecting geochemical evolution in the study area. The groundwater of the study area is not safe for drinking but can be safely used for salt-tolerant crops.     

Hydrochemical and statistical studies of the groundwater salinization in Mediterranean arid zones: case of the Jerba coastal aquifer in southeast Tunisia

Coastal aquifers are considered as major sources for freshwater supply worldwide, especially in arid zones. The weak rainfall as well as the intensive extraction of groundwater from coastal aquifers reduce freshwater budget and create local water aquifer depression, causing both seawater intrusion and a threat to groundwater. This phenomenon was observed in the Jerba Island which is located in southeast Tunisia. Jerba??s unconfined aquifer shows high values of groundwater salinity reaching, locally, 17?g/l and a strong contrast between some zones of the aquifer. High pumping rates and weak recharge disturb the natural equilibrium between fresh and saline water causing water salinization in most areas of the island. This study aims at establishing the salinity map of the aquifer and identifying the origin of groundwater salinization. The salinity map shows that zones characterized by low groundwater salinity are located in the center of the study area. High groundwater salinities are observed near the coast and in some parts having low topographic and piezometric levels. Groundwater geochemical characterization, and Br/Cl and Na/Cl ratios suggest that the origin of abnormal salinity is seawater intrusion. Considering groundwater salinity values and Br concentrations, a seawater intrusion map is established. It shows that many areas of the unconfined aquifer are contaminated by mixed groundwater and seawater. The statistical analysis demonstrates that high mineralization of the groundwater is due to gypsum and carbonate dissolution coupled with the mixed groundwater and seawater in many areas.     

The hydrochemical characteristics and evolution of groundwater and surface water in the western part of the River Nile, El Minia district, Upper Egypt

A combination of major and trace elements have been used to characterize surface- and groundwater in El Minia district, Egypt. Surface water versus groundwater chemistry data enabled geographical zonation and chemical types to be differentiated. The main target of this research is to investigate the groundwater quality and hydrochemical evaluation. The situation is further complicated by contamination with lithogenic and anthropogenic (agricultural and sewage wastewaters) sources and low plan exploitation techniques. The investigated Pleistocene aquifer is composed of sand and gravel of different sizes, with some clay intercalation. The semi-confined condition was around the River Nile shifted to unconfine outside the floodplain. The groundwater flow generally from south to north and locally diverts towards the western part from the River Nile. Fifty-six, 11, five, and two water samples were collected from the Pleistocene aquifer, River Nile, Ibrahimia canal, and Al Moheet drain, respectively. The collected water samples were analyzed for major and trace elements. The toxic metal concentrations of Al Moheet drain are higher than those in the River Nile and the Ibrahimia canal. Cr, Hg, As, and Cd concentrations in the River Nile and Ibrahimia canal are fluctuated above and below the WHO drinking standards. Se concentration in River Nile and Ibrahimia canal is below WHO drinking and irrigation guidelines. Total dissolved solid content in groundwater is generally low, but it is increased due to the western part of the study area. The geographic position of the River Nile, Ibrahimia canal, and Al Moheet drain impact on the groundwater quality. The PHREEQC confirm the high mixing proportions from the River Nile into the groundwater and decline away from it. In addition to the thicknesses of the Pleistocene, aquifer and aquitard layer enhance the River Nile and agricultural wastewaters intrusion into the aquifer system. The toxic metal concentrations (Pb, Cd, Cr, PO₄, Se, Mn, As, Hg, Ni, Al, Fe, and SIO₂) in groundwater were increased mainly in the northwestern and southeastern part (far from the River Nile). It is attributed to anthropogenic, high vulnerability rate (unconfined), and partially to lithogenic. In most localities, the groundwater are unsuitable for drinking and irrigation purposes with respect to Se concentration, while they are unsuitable for dinking according Mn, As, and Hg contents. There are some Cd and Pb anomalies concentrations, which cause severe restriction if used in irrigation. The results suggested that significant changes are urgently needed in water use strategy to achieve sustainable development.     

A preliminary assessment of hydrogeological features and selected anthropogenic impacts on an alluvial fan aquifer system in Greece

An investigation was carried out to delineate the hydrogeologic framework and to understand groundwater quality of the Kompsatos River fan aquifer system, northeastern Greece, as well as to assess environmental impact induced by human activities. As groundwater is the only major source of water in this area, it is important to know the effect of geological formations, and anthropogenic activities on groundwater chemistry and environment. A thorough hydrogeological study was performed during the period 2004–2007. The differential river gauging method was used for estimating the volume of water leaking from (or discharging into) the river. Groundwater samples were collected from 89 monitoring wells, during the summer period of 2007, and analyzed for major ions and trace elements. A potential reservoir of groundwater is formed within the Kompsatos River fan. The aquifer system/Kompsatos River interaction is the outstanding feature of this area. Ca–Mg–HCO₃–SO₄ is the dominant water type as a result of dissolving carbonate salts. B, Ba, Mn, Li, Sr, and Zn are the most abundant trace elements in groundwater. Both the major-ion chemistry and trace element enrichment of the groundwater are controlled by mineral dissolution and water–rock interaction. Nitrate contamination of groundwater is related to agricultural practices. An improperly constructed drainage system led locally to salinization of groundwater. Channelization has caused considerable disruption to the river ecosystem. The eventual construction of a dam on the river will adversely affect the environment and the aquifer system. The lack of managerial policy for water is putting environmental resources and water supply in jeopardy.     

Distribution of total petroleum hydrocarbons in Dezful aquifer,Southwest of Iran

Determination of total petroleum hydrocarbon distribution (TPH) in groundwater of Dezful aquifer was the main purpose of this study. The study area, which is located between latitudes 32°00′ and 32°35′?N and longitudes 48°10′ and 49°35′?E, covers about 1,920 km² in the north of Khuzestan Province, Iran. Hydrocarbon pollutants in the area were being released into the aquifer, from a variety of sources. An oil pipe crash accident, which occurred on 19 Feb. 2009 in the vicinity of the northern part of the study area, released about 6,000 barrels of crude oil to the Karkhe River. Other possible sources of TPH in the region are asphalt factories, gas stations, and the Sabzab oil pump station. Since the main source of drinking water in the Dezful area is groundwater reservoirs, this study would be very crucial, especially when there is considerable agricultural activity in the area as well. In order to determine the presence of TPH and heavy metals in the groundwater, samples were taken from wells with different usage within two periods, i.e., in Nov. 2008 and May 2009. The second sampling operation was carried out to determine the effect of the accident in the water resources. In situ groundwater parameter measurements including pH, dissolved oxygen, temperature, and electrical conductivity were also carried out in the field. Based on the results, there are four zones in the study area which were contaminated with TPH from different origins: (1) southeast of Dezful City, which was contaminated by Shokati gas station; (2) southeast of Shush City, which was contaminated by an asphalt factory; (3) southwest of Dezful City, which was contaminated by Sabzab oil pump station; and (4) the shores of Karkhe River which were contaminated due to the pipeline crash accident. This could be a serious threat to the environment and human health because TPH concentration was higher than the EPA standard in the study area. Heavy metals were not distributed in a uniform pattern in the aquifer. The concentrations were lower than the contamination level based on the EPA drinking standard, and there was no meaningful relation between concentrations of TPH and the heavy metals. It was recommended that a monitoring network should be designed to monitor oil contaminants in the ground and surface water monthly because of importance of the water resources and presence of potential oil contaminant sources.     

Nitrate contamination in a shallow urban aquifer in East Ukraine: evidence from hydrochemical,stable isotopes of nitrate and land use analysis

A combined hydrochemical and stable isotope approach was used to investigate the origin of nitrate in the shallow unconfined groundwater of Kharkiv city, Eastern Ukraine. The contamination was investigated in the context of land use within the catchment area. The observed enrichment of sulfate, chloride and nitrate suggests significant groundwater contamination in the shallow urban aquifer, which is widely used as drinking water source for the urban population. Characteristic nitrate/chloride ratios as well as stable isotope ratios (N and O) of nitrate in the most contaminated springs confirmed that septic waste from leaky sewer systems was the main source of nitrate contamination in the groundwater. Nitrate contamination is linked to the type of land use and sewage treatment regime in the catchment area. It is also modulated by the regional hydrogeology, which determines the susceptibility of a given aquifer toward groundwater pollution. A more quantitative assessment of nitrate sources based on the nitrate isotope analysis alone is rather difficult. However, our study confirms that the combination of hydrochemical tracers, robust land-use analysis and nitrate stable isotope measurements represents a valuable approach to identify the origin of the nitrate contamination.     

Water-management failure under complex hydrogeological conditions in the Kolubara District, Serbia

The design of the Rovni Lake reservoir in the Kolubara District, western Serbia, is the basis for the regional water-supply system there. The design was promoted as an example of integrative and sustainable water management, with regard to the planned provision for long-term municipal water supply in the Kolubara region, as well as for the regulation of the downstream river flow. Hydrogeological analyses, however, have indicated three key issues that contest this sustainable water-management model: (1) the capability of the available groundwater sources to fully meet the drinking water demands in the region, (2) a pronounced risk of water loss from the reservoir, and (3) a pronounced risk of karst aquifer contamination. The Rovni project ignores the hydrogeological properties of a karst aquifer and thereby needlessly threatens the groundwater resource. Hence, modifications to the project are recommended in order to mitigate or eliminate the most significant construction and ecological risk factors and to improve sustainable exploitation and integrative water-resource management.     

Groundwater contamination assessment in Al-Quwy’yia area of central Saudi Arabia using transient electromagnetic and 2D electrical resistivity tomography

Groundwater contamination is one of the most significant problems in arid countries. Al-Quwiy’yia region is an example of an area where the groundwater is contaminated as a result of infiltration of waste water in low-lying areas adjacent to inhabited zones. Such contamination poses significant environmental threats for the surrounding environment and groundwater. Surface observations and spatial distribution of contamination observed in the shallow aquifer indicate that the main contamination sources were from sewage as well as from waste water dumping. However, the main source of water supply for the whole area is groundwater abstracted from the relatively shallow aquifer. Therefore, the transient electromagnetic method (TEM) and 2D electrical resistivity tomography (2D ERT) have been applied close to the waste water dump site to characterize the response of pollution plumes. Both of these geoelectrical techniques are sensitive to electrical conductivity as well as to other physical properties, which are greatly influenced by the polluted groundwater. Therefore, it is possible to profile the contamination plumes, both vertically and horizontally, in the vicinity of the measured stations. The ERT profiles gave detailed information about the lateral distribution of the contaminated groundwater, whereas the TEM demonstrated the vertical extensions.     

The processes affecting oxytetracycline contamination of groundwater in a phreatic aquifer underlying industrial fish ponds in Israel

Oxytetracycline (OTC) is an antibiotic that is regularly added to fish ponds used in industrial- scale fish-farming along the Mediterranean coast of Israel. It is not found in unpolluted water. The ponds are constructed upon porous sands that are also the host rock of the local aquifer. These ponds leak. Monitoring for OTC was carried out in a fish pond and three surrounding water wells that exploit the local aquifer. The local groundwater is composed of the native groundwater and the leakage additions. Two wells, P-204 P-205 are used to insure that the water levels in the ponds are maintained. A frequently pumping well, M-2, is located closest to the main source of OTC input at pond B. It is used to supply drinking water and OTC was found in it. This contaminant is related to leakage from the nearby fish pond. OTC is generally assumed to be immobile and effectively removed by soil and sediments. In this case, continuous leakage of the pond has created preferential saturated flow paths that bring the contaminants directly to groundwater, bypassing the immobilizing sorption processes that usually take place in the unsaturated zone. In the absence of such conduits OTC is effectively excluded from reaching other producing wells.     

美国Sand Hills地区地下水数值模拟及水量平衡分析

利用地下水数值模型MODFLOW和非饱和带水平衡模型对处于半干旱半湿润沙丘地区(Sand Hills)地下水位进行了模拟,并分析了含水层补排水量,河流与地下水补排关系,以及区域水平衡过程。揭示了独特沙丘地形和土壤特性对地下水补排量的影响。模拟结果表明,入渗率大、非饱和带厚的沙丘有利于降水入渗补给,减少了地下水蒸散发损失。加上下覆含水层具有良好的地下水储水空间,是该地区储存丰富的地下水量,以维持河流稳定流量,供给众多湖泊和湿地的原因。该研究对我国地下水资源评价和生态环境脆弱地区水资源保护具有指导意义。     

The influence of Zihe Stream on the groundwater resources of the Dawu well field and on the discharge at the Heiwang iron mine, Zibo City area, Shandong Province, China

 The Dawu well field, one of the largest in China, supplies most of the water for the Zibo City urban area in Shandong Province. The field yields 522,400–535,400 m³/d from an aquifer in fractured karstic Middle Ordovician carbonate rocks. Much of the recharge to the aquifer is leakage of surface water from Zihe Stream, the major drainage in the area. Installation of the Taihe Reservoir in 1972 severely reduced the downstream flow in Zihe Stream, resulting in a marked reduction in the water table in the Dawu field. Since 1994, following the installation of a recharge station on Zihe Stream upstream from the well field that injects water from the Taihe Reservoir into the stream, the groundwater resources of the field have recovered. An average of 61.2×10³ m³/d of groundwater, mostly from the Ordovician aquifer, is pumped from the Heiwang iron mine, an open pit in the bed of Zihe Stream below the Taihe Reservoir. A stepwise regression equation, used to evaluate the role of discharge from the reservoir into the stream, confirms that reservoir water is one of the major sources of groundwater in the mine. Received, May 1998 / Revised, May 1999 / Accepted, June 1999     

华北平原东部水资源可持续利用

华北平原东部水资源短缺，深层地下水严重超采，生态环境恶化。为水资源的可持续利用．要发展井灌井排渠灌沟排，以开发利用当地浅层地下水包括微成水和成水为基础．以引调可利用的地表水补源。以调控地下水埋深在临界动态为棱心，以土壤及潜水的地层空间作为调节大气降水、土壤水、地下水、地表水的地下水库．最大限度圯犯时空分布不均的天然降雨转化为可持续利用的水资源。