$
\begin{gathered}
3H_2 WO_4^0 \leftrightarrow H_3 W_3 O_{12}^{3 - } + 3H^ + \log K_p = - 7.5 \pm 0.1, \hfill \\
3H_2 WO_4^0 \leftrightarrow W_3 O_9^{3 - } + 1.5H_2 O + 3H^ + + 0.75O_2 \log K_p = - 25.7 \pm 0.2, \hfill \\
5H_2 WO_4^0 \leftrightarrow \left[ {W^V W_4^{VI} O_{16} } \right]^{3 - } + 3H^ + + 3.5H_2 O + 0.25O_2 \log K_p = - 4.6 \pm 0.1 \hfill \\
\end{gathered}
$
\begin{gathered}
3H_2 WO_4^0 \leftrightarrow H_3 W_3 O_{12}^{3 - } + 3H^ + \log K_p = - 7.5 \pm 0.1, \hfill \\
3H_2 WO_4^0 \leftrightarrow W_3 O_9^{3 - } + 1.5H_2 O + 3H^ + + 0.75O_2 \log K_p = - 25.7 \pm 0.2, \hfill \\
5H_2 WO_4^0 \leftrightarrow \left[ {W^V W_4^{VI} O_{16} } \right]^{3 - } + 3H^ + + 3.5H_2 O + 0.25O_2 \log K_p = - 4.6 \pm 0.1 \hfill \\
\end{gathered}
相似文献
9.
Solubility curves of water-hydrogen fluid were studied using a high-pressure gas apparatus at a pressure of 200 MPa under
variable fluid composition in haplogranite (Ab
39
Or
32
Qtz
29, 950°C), Na-disilicate (Na2Si2O5, 950°C), and albite melts (1200°C). The mole fraction of hydrogen in experiments was controlled directly by Ar-H2 mixtures using a specially designed cell with a Shaw membrane. $
X_{H_2 }^{Ar - H_2 }
$
X_{H_2 }^{Ar - H_2 }
ranged from 0 to 1. In some experiments with haplogranite and Na-disilicate melts under oxidizing conditions, in order to
increase the accuracy of experimental parameters, the fugacities of oxygen and hydrogen were controlled using the double-capsule
technique and the solid-phase buffer mixtures Ni-NiO (NNO) and Co-CoO (CCO). The addition of H2 to the H2O-saturated systems ($
X_{H_2 }^{H_2 O - H_2 }
$
X_{H_2 }^{H_2 O - H_2 }
≥ 0.012) results in the appearance of a distinct maximum on the solubility curves at $
X_{H_2 }^{H_2 O - H_2 }
$
X_{H_2 }^{H_2 O - H_2 }
= 0.05–0.07 (H2 mole fractions were calculated for real H2O-H2 mixtures of real gases), and the maximum content of H2O-H2 fluid increases relative to the H2O-saturated melts by 1.51 wt % for haplogranite melt at $
X_{H_2 }
$
X_{H_2 }
= 0.063, 2.68 wt % for albite melt at $
X_{H_2 }
$
X_{H_2 }
= 0.066, and 3.54 wt % for Na-disilicate melt at $
X_{H_2 }
$
X_{H_2 }
= 0.067. A further increase in H2 content in the gas mixture decreases the solubility of H2O-H2 fluid in the melts, and under pure H2 pressure, the contents of fluid components are 0.08 wt % in haplogranite melt and 0.06 wt % in albite melt. The 1H NMR study of aluminosilicate and Na-silicate glasses obtained under the pressure of H2O and H2O-H2 fluids suggests different mechanisms of the dissolution of H2O and H2O-H2 fluids in magmatic melts. In addition to the spectra of dissolved water fluid, the spectra of quenched glasses synthesized
under H2O-H2 fluid pressure exhibited a narrow line of molecular hydrogen with a width at half height of 1.8–2.0 kHz at $
X_{H_2 }
$
X_{H_2 }
≥ 0.653 for albite and $
X_{H_2 }
$
X_{H_2 }
≥ 0.063 for Na-disilicate and two lines at $
X_{H_2 }
$
X_{H_2 }
≥ 0.063 for the haplogranite composition. 相似文献
10.
Sources of radiation in the early Universe: The equation of radiative transfer and optical distances
We have derived the radiative-transfer equation for a point source with a specified intensity and spectrum, originating in the early Universe between the epochs of annihilation and recombination, at redshifts zs = 108?104. The direct radiation of the source is separated from the diffuse radiation it produces. Optical distances from the source for Thomson scattering and bremsstrahlung absorption at the maximum of the thermal background radiation are calculated as a function of the redshift z. The distances grow sharply with decreasing z, approaching asymptotic values, the absorption distance increasing more slowly and reaching their limiting values at lower z. For the adopted z values, the optical parameters of the Universe can be described in a flat model with dusty material and radiation, and radiative transfer can be treated in a grey approximation. 相似文献
11.
We perform a statistical analysis of the properties of 170 rich clusters of galaxies. We confirm the existence of correlations
between the X-ray luminosity and temperature of the cluster intergalactic medium (IGM) and between the velocity dispersion
of the galaxies and the X-ray luminosity of the IGM. In addition, we have found a new anti-correlation between the optical
luminosity in Hα and the X-ray luminosity of the cluster IGM: log $
\left( {\frac{{L_{H\alpha } }}
{{L_ \odot }}} \right) = a - b\log \left( {\frac{{L_x }}
{{L_ \odot }}} \right)
$
\left( {\frac{{L_{H\alpha } }}
{{L_ \odot }}} \right) = a - b\log \left( {\frac{{L_x }}
{{L_ \odot }}} \right)
. Clusters form sequences with different values of a but similar values of b. 相似文献
12.
I. F. Malov 《Astronomy Reports》2004,48(4):337-341
It is shown that a model with accretion in a “quasi-propeller” mode can explain the observed spindown of pulsars with periods P<0.1 s. The mean accretion rate for 39 selected objects is \(\dot M = 5.6 \times 10^{ - 11} M_ \odot /year\). If \(\dot M\) is constant during the pulsar’s lifetime, the neutron star will stop rotating after 107 years. The mean magnetic field at the neutron-star surface calculated in this model, \(\bar H_0 = 6.8 \times 10^8 G\), is consistent to an order of magnitude with the values of H0 for millisecond pulsars from known catalogs. However, the actual value of H0 for particular objects can differ from the catalog values by appreciable factors, and these quantities must be recalculated using more adequate models. The accretion disk around the neutron star should not impede the escape of the pulsar’s radiation, since this radiation is generated near the light cylinder in pulsars with P<0.1 s. Pulsars such as PSR 0531+21 and PSR 0833-45 have probably spun down due to the effect of magnetic-dipole radiation. If the difference in the braking indices for these objects from n=3 is due to the effect of accretion, the accretion rate must be of the order of 1018 g/s. 相似文献
13.
We have modeled the Hα, Hβ, and Hγ (Balmer series), P14 (Paschen series), and Brγ (Brackett series) hydrogen lines formed in the inner regions of the accretion disk around the Herbig Ae star UX Ori. Our calculations are based on spectra obtained with the Nordic Optical Telescope (NOT) and the IRTF. We computed a grid of non-LTE models for a radiating area in the accretion disk and determined the basic parameters of the lines using the method of Sobolev. Analyzing the theoretical and observed line profiles, equivalent widths, and luminosities, we have estimated the accretion rate and electron-temperature distribution in the inner parts of the accretion disk. The accretion rate of UX Ori is about $\dot M_a = (3 - 10) \times 10^{ - 9} M_ \odot /yr$ , and the temperature distribution is consistent with the power law T(r)=T(r *)(r/r *)?1/n , where the electron temperature near the stellar surface T(r *) is 15000–20000 K and the power-law index n≈2–3 is about two to three. The resulting value for $\dot M_a $ eliminates problems connected with the application of magnetospheric accretion models to Herbig Ae/Be stars. Another important conclusion is that, at the estimated accretion rate, the energy release is substantially (about two orders of magnitude) lower than the stellar luminosity. Therefore, the optical radiation of UX Ori accretion disks cannot appreciably contribute to the observed variability of these stars, which must be determined mainly by variability in the circumstellar extinction. 相似文献
14.
V. L. Afanas’ev S. N. Dodonov A. V. Moiseev O. V. Verkhodanov A. I. Kopylov Yu. N. Pariiskii N. S. Soboleva A. V. Temirova O. P. Zhelenkova W. M. Goss 《Astronomy Reports》2003,47(5):377-385
The results of spectroscopic observations of the host galaxies of objects in the RC catalog (the “Big Trio” program) obtained using the new SCORPIO spectrograph of the Special Astrophysical Observatory are presented. The spectroscopic redshifts of the objects are compared with their photometric color redshifts, and the errors in the latter are estimated. Based on BV RI observations obtained on the 6-m telescope of the SAO, the errors for the population of powerful radio galaxies are close to those found previously for radio quiet galaxies (about 10–20%). The detection of Ly α in the B filter in RC 1626+0448 is confirmed. This object is the second spectrally studied FR II radio source from the RC catalog to have a redshift z>2.5. Star formation in its host galaxy began at a redshift z>3.3. This first use of the new SCORPIO spectrograph demonstrates its promise for studies of very distant steep-spectrum radio galaxies brighter than 23m–24m in V. 相似文献
15.
A new version of the STRUCTON (2009) computer model is proposed for the simulation of the molecular mass distributions (MMD)
characterizing the diversity of anions in silicate melts depending on their polymerization and temperature. In contrast to
earlier versions, the new version of the model accounts for disproportionation reactions of Q
n
species and makes use of their proportions in the statistical simulations of the origin of real Si-O complexes. The new potentialities
of the STRUCTON program package are illustrated by its application to studying the structural-chemical characteristics of
melts in the Na2O-SiO2 system along its liquidus line, including the points of eutectics and phase transitions at 0.333 ≤ $
N_{SiO_2 }
$
N_{SiO_2 }
< 0.500. This problem is solved with the use of a temperature-composition dependence of polymerization constants K
p
Na in the Toop-Samis approximation. The variations in K
p
Na were proved to be as large as three orders of magnitude due to both the temperature effect at a constant composition and
the composition effect at a constant temperature. The results of the MMD simulations on the liquidus show that the concentration
of the SiO44− ion strongly decreases, and the proportion of chain species increases compared to those at a stochastic distribution. The
concentration of the Si2O76− anion reaches its maximum (∼42%) at 40 mol % in the liquid, i.e., the composition of Na6Si2O7. At $
N_{SiO_2 }
$
N_{SiO_2 }
> 0.40, this ion dominates over the SiO44− monomer. More silicic melts with $
N_{SiO_2 }
$
N_{SiO_2 }
≥ 0.45, are dominated by (Si
n
O3n
)3n− ring species, and the concentrations of these species are related as (Si3O9)6− > (Si4O12)8− > (Si5O15)10−. The maximum concentration of these flat rings also occurs near the composition of stoichiometric metasilicate with Si/O
= 0.333. The comparison of the dependence of the average size of anions i
av and the average number of their species on depolymerization indicates that a change in the proportion of Q
n
species in melt at decreasing temperature results in structural restyling and an increase in the average size of Si-O complexes.
The average number of anion species thereby decreases compared to that in a stochastic MMD. The results presented in this
publication direct the progress in the thermodynamic theory of silicate melts to a new avenue that makes use of the capabilities
and advantages of the ion-polymer model, the theory of associated solutions, spectroscopic data, and the experimental study
of variations in oxide activities depending on composition and temperature. 相似文献
16.
N. V. Chukanov R. K. Rastsvetaeva I. V. Pekov A. E. Zadov R. Allori N. V. Zubkova G. Giester D. Yu. Puscharovsky K. V. Van 《Geology of Ore Deposits》2009,51(7):588-594
Biachellaite, a new mineral species of the cancrinite group, has been found in a volcanic ejecta in the Biachella Valley,
Sacrofano Caldera, Latium region, Italy, as colorless isometric hexagonal bipyramidal-pinacoidal crystals up to 1 cm in size
overgrowing the walls of cavities in a rock sample composed of sanidine, diopside, andradite, leucite and hauyne. The mineral
is brittle, with perfect cleavage parallel to {10$
\bar 1
$
\bar 1
0} and imperfect cleavage or parting (?) parallel to {0001}. The Mohs hardness is 5. Dmeas = 2.51(1) g/cm3 (by equilibration with heavy liquids). The densities calculated from single-crystal X-ray data and from X-ray powder data
are 2.515 g/cm3 and 2.520 g/cm3, respectively. The IR spectrum demonstrates the presence of SO42−, H2O, and absence of CO32−. Biachellaite is uniaxial, positive, ω = 1.512(1), ɛ = 1.514(1). The weight loss on ignition (vacuum, 800°C, 1 h) is 1.6(1)%.
The chemical composition determined by electron microprobe is as follows, wt %: 10.06 Na2O, 5.85 K2O, 12.13 CaO, 26.17 Al2O3, 31.46 SiO2, 12.71 SO3, 0.45 Cl, 1.6 H2O (by TG data), −0.10 −O=Cl2, total is 100.33. The empirical formula (Z = 15) is (Na3.76Ca2.50K1.44)Σ7.70(Si6.06Al5.94O24)(SO4)1.84Cl0.15(OH)0.43 · 0.81H2O. The simplified formula is as follows: (Na,Ca,K)8(Si6Al6O24)(SO4)2(OH)0.5 · H2O. Biachellaite is trigonal, space group P3, a =12.913(1), c = 79.605(5) ?; V = 11495(1) ?3. The crystal structure of biachellaite is characterized by the 30-layer stacking sequence (ABCABCACACBACBACBCACBACBACBABC)∞. The tetrahedral framework contains three types of channels composed of cages of four varieties: cancrinite, sodalite, bystrite
(losod) and liottite. The strongest lines of the X-ray powder diffraction pattern [d, ? (I, %) (hkl)] are as follows: 11.07 (19) (100, 101), 6.45 (18) (110, 111), 3.720 (100) (2.1.10, 300, 301, 2.0.16, 302), 3.576 (18) (1.0.21,
2.0.17, 306), 3.300 (47) (1.0.23, 2.1.15), 3.220 (16) (2.1.16, 222). The type material of biachellaite has been deposited
at the Fersman Mineralogical Museum of the Russian Academy of Sciences, Moscow, Russia, registration number 3642/1. 相似文献
17.
Yu. N. Pariiskii N. S. Soboleva A. V. Temirova N. N. Bursov O. P. Zhelenkova 《Astronomy Reports》2012,56(5):336-344
Published data from long-term observations of a strip of sky at declination ?? ?? 5° carried out at 7.6 cm on the RATAN-600 radio telescope are used to estimate some statistical properties of radio sources. Limits on the sensitivity of the survey due to noise imposed by background sources, which dominates the radiometer sensitivity, are refined. The vast majority of noise due to background sources is associated with known radio sources (for example, from the NVSS with a detection threshold of 2.3 mJy) with normal steep spectra (?? = 0.7?C0.8, S ?? ?? ??? ), which have also been detected in new deep surveys at decimeter wavelengths. When all such objects are removed from the observational data, this leaves another noise component that is observed to be roughly identical in independent groups of observations. We suggest this represents a new population of radio sources that are not present in known catalogs at the 0.6 mJy level at 7.6 cm. The studied redshift dependence of the number of steep-spectrum objects shows that the sensitivity of our survey is sufficient to detect powerful FRII radio sources at any redshift, right to the epoch of formation of the first galaxies. The inferred new population is most likely associated with low-luminosity objects at redshifts z < 1. In spite of the appearance of new means of carrying out direct studies of distant galaxies, searches for objects with very high redshifts among steep and ultra-steep spectrum radio sources remains an effective method for studying the early Universe. 相似文献
18.
Radio Sources in the Central Section of the RZF Catalog. Search for Objects with Ultra-Steep Spectra
Results of reducing and selecting data from the Ratan Zenith Field (RZF) are presented. A deep survey in the region 0h ≤ R.A. ≤ 24h, 40.5° ≤ DEC ≤ 42.5° carried out on the RATAN-600 radio telescope was used. Within +2′ of the center of the survey region, 448 objects were detected, 69 of them with ultra-steep spectra (USS). The SDSS digital optical survey (DR12), NVSS radio maps, and the FIRST catalogs have been used to cross-identify 208 radio sources from the RZF catalog, obtained as part of the “Genetic Code of the Universe” project. The characteristics of these objects are studied, and the distribution of the SDSS galaxies in a two-color diagram is obtained. Photometric redshifts and radio luminosities at 3940 and 1400 MHz are determined for 27 objects with spectral indices α < −1.1 (S ∝ να) for which magnitudes in various filters are presented in the SDSS. In the sample of USS objects, 12 galaxies have redshifts z < 0.5, are detected at wavelength λ = 7.6 cm, and have relatively high radio luminosities (type FR II or intermediate type FR I–FR II). Only one radio galaxy proved to be a rare nearby galaxy with relatively low radio luminosity L1400 MHz = 1.51 × 1024 W/Hz (type FR I). Two objects are candidate GHz-Peaked Spectrum objects. 相似文献19.
The massif of Fedorov Tundra was formed as part of the Paleoproterozoic (2.5 Ga) Fedorov-Pana platinum-bearing layered complex
as a result of consecutive emplacement of two intrusive phases. The emplacement of the first phase resulted in the formation
of a large layered intrusive body composed of amphibole gabbro, gabbronorite, norite, pyroxenite, olivine pyroxenite, and
harzburgite. The second phase gave birth to a gabbronorite intrusion smaller in volume and enriched in sulfides and PGM. Magmatic
breccia has been observed in the contact zone between two phases. The rocks of the massif are referred to the series of normal
alkalinity and to the quartz- and olivine-normative groups differing in saturation with silica. Using isoplethic and isobaric
joins of the q-fo-fa-di-hd-ab-an-aq phase diagram, the stages of rock formation are considered. The thermodynamic conditions of rock crystallization were determined
as T = 1000−800°C and $
P_{H_2 O}
$
P_{H_2 O}
= 1000−2500 bar for the first intrusive phase and T = 1000–900°C and $
P_{H_2 O}
$
P_{H_2 O}
= 800−1000 bar for the second intrusive phase. 相似文献
20.
O. V. Verkhodanov A. I. Kopylov Yu. N. Pariiskii N. S. Soboleva A. V. Temirova O. P. Zhelenkova 《Astronomy Reports》2002,46(7):531-542
BV RI data are presented for the majority of steep-spectrum objects in the RC catalog with m R <23.5m. Previously developed programs are applied to these data to estimate the redshifts and ages of the stellar systems of the host galaxies. Applying this program to the color data (BV RI JHK) for distant radio galaxies with spectroscopic redshifts indicates that this approach provides accurate estimates of the redshifts of such radio galaxies, close to those obtained using field galaxies (~20%). The age estimates are much less trustworthy, but a lower limit to the ages of objects that are not very distant (z<1.5) can be determined with certainty. We have identi fied several galaxies whose formal ages exceed the age of the Universe at the corresponding z in simple Cold Dark Matter models for the Universe. The possibility of using such objects to elucidate the role of “dark energy” is discussed. This paradox disappears in models with cosmological constants (Λ terms) equal to 0.6–0.8. 相似文献
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