新疆三塘湖盆地石炭系含油气系统初步评价

新疆三塘湖盆地晚古生代发育哈尔加乌组和卡拉岗组陆相火山喷发岩系,二者在岩石组合上均以中酸性火山岩及其碎屑岩为主,局部夹基性火山岩。通过岩性剖面和化石组合对比认为哈尔加乌组和卡拉岗组为同一时代地层,没有上下关系,时代为晚石炭世—早二叠世。对哈尔加乌组火山岩进行锆石SHRIMP U-Pb定年获取年龄值为319.6±9.8 Ma,表明这套火山岩含有石炭纪的部分,限定这套火山岩系的喷发时限为石炭纪中期至早二叠世。哈尔加乌组和卡拉岗组火山岩发育多期的火山喷发—沉积旋回,形成巨厚层的火山岩和火山碎屑岩的互层,具备良好的油气储集条件,其下伏老爷庙组暗色泥岩夹层有机碳(TOC)含量较高(0.71%～1.62%),属于一般烃源岩—好烃源岩,这套烃源岩与哈尔加乌组—卡拉岗组火山岩构成生储盖组合,上覆上二叠统芨芨槽子群泥岩为盖层,构成盆地与火山岩相关的石炭系含油气系统,具有重大的石油地质意义。     

西准噶尔萨吾尔地区二叠纪火山活动规律

西准噶尔萨吾尔地区位于新疆阿勒泰的吉木乃县及塔城地区和丰县。区内泥盆纪—二叠纪均有火山活动,其中二叠纪火山作用尤为强烈。二叠纪火山岩地层包括哈尔加乌组和卡拉岗组,哈尔加乌组为一套陆相中基性-中性火山岩及火山碎屑岩,卡拉岗组为一套陆相中基性-中酸性火山岩及火山碎屑岩。哈尔加乌—卡拉岗旋回火山岩主要岩性包括橄榄玄武岩、玄武岩、粗玄岩、安山岩、粗安岩、流纹岩、火山碎屑岩等。根据火山岩地层综合剖面以及火山岩的岩石学、岩相学特征,萨吾尔地区二叠纪火山活动由早至晚可分为5个阶段:中性喷发阶段、间歇性基性喷发阶段、酸性爆发及喷溢阶段、小规模中性间歇性爆发及喷溢阶段、基性喷发阶段;火山岩为陆相火山岩,具有双峰式特征,形成于伸展的构造背景下。     

新疆三塘湖盆地石炭系含油气系统初步评价

新疆三塘湖盆地晚古生代发育哈尔加乌组和卡拉岗组陆相火山喷发岩系,二者在岩石组合上均以中酸性火山岩及其碎屑岩为主,局部夹基性火山岩。通过岩性剖面和化石组合对比认为哈尔加乌组和卡拉岗组为同一时代地层,没有上下关系,时代为晚石炭世—早二叠世。对哈尔加乌组火山岩进行锆石SHRIMP U Pb定年获取年龄值为3196±98 Ma,表明这套火山岩含有石炭纪的部分,限定这套火山岩系的喷发时限为石炭纪中期至早二叠世。哈尔加乌组和卡拉岗组火山岩发育多期的火山喷发—沉积旋回,形成巨厚层的火山岩和火山碎屑岩的互层,具备良好的油气储集条件,其下伏老爷庙组暗色泥岩夹层有机碳（TOC）含量较高（071％162％）,属于一般烃源岩—好烃源岩,这套烃源岩与哈尔加乌组—卡拉岗组火山岩构成生储盖组合,上覆上二叠统芨芨槽子群泥岩为盖层,构成盆地与火山岩相关的石炭系含油气系统,具有重大的石油地质意义。     

东天山觉罗塔格一带晚古生代岩浆岩地球化学特征及构造意义

通过对东天山觉罗塔格一带晚古生代岩浆岩地质特征、岩石化学特征等系统研究,认为该晚古生代岩浆岩主要由早石炭世至中二叠世的火山岩和侵入岩组成,其形成与康古尔洋向北俯冲有关。早石炭世岩浆岩为康古尔洋初始俯冲而成的钙碱性岛弧火山岩及具有低压、低温特征的高钾钙碱性I型花岗岩;晚石炭世岩浆岩为后碰撞弧火山岩;早二叠世岩浆岩为具有后碰撞弧和板内双重特征的火山岩及高温、高压特征的I型花岗岩;中二叠世发育具有低压、高温特征的高钾钙碱性A型花岗岩。综合前人资料及本文研究成果,初步认为觉罗塔格一带晚古生代经历了俯冲碰撞—碰撞造山—造山后陆内伸展的构造演化过程。     

西准噶尔托里地区卡拉岗组火山岩地球化学特征及其构造意义

对西准噶尔托里地区卡拉岗组火山岩进行了系统的岩相学、锆石U-Pb年代学及岩石地球化学研究。卡拉岗组火山岩从底部到顶部依次发育6个岩性段,其中中下部第4岩性段英安岩的LA-ICP-MS锆石U-Pb年龄为(298±3)Ma,为晚石炭世-早二叠世产物。火山岩整体上为准铝质-过铝质高钾钙碱性岩石,富集大离子亲石元素和轻稀土元素,相对亏损高场强元素和重稀土元素。火山岩及周围同时代A型花岗岩的年龄、主微量元素、Sr-Nd及锆石Hf同位素综合对比表明,卡拉岗组火山岩主要源于新生地壳的部分熔融。火山岩相关构造判别图解及区域构造-岩浆演化综合研究显示,卡拉岗组火山岩与区域上A型花岗岩均形成于后碰撞伸展环境。卡拉岗组火山岩的形成表明,西准噶尔晚古生代增生造山作用应早于晚石炭世。     

兴蒙造山带中段北部晚古生代两期岩浆活动及其构造意义

兴蒙造山带位于中亚造山带东段,长期以来是地质学家研究的焦点区域。内蒙古巴彦乌拉地区位于兴蒙造山带中段北部苏尼特左旗以北,广泛出露晚古生代宝力格组火山—沉积地层和酸性侵入岩体。本文对阿尔善宝拉格附近的宝力格组中性火山岩和侵入其中的花岗斑岩岩墙,及巴彦乌拉苏木南部花岗闪长岩进行了锆石LA-ICP-MS U-Pb定年,定年结果显示,宝力格组火山岩年龄为310.5±0.78 Ma,与巴彦乌拉苏木北部地区火山岩年龄(307.1±6.3Ma,308.9±1.8Ma)一致,证明本区宝力格组地层形成于晚石炭世;花岗闪长岩和花岗斑岩岩墙年龄分别为312.5±0.75 Ma和286.6±0.75 Ma,形成时代分别为晚石炭世和早二叠世;通过区域对比分析认为,兴蒙造山带北部晚古生代存在晚石炭世和早二叠世两期重要的岩浆活动,统计获得峰值年龄分别为318Ma和281Ma。岩石地球化学特征显示,本区晚石炭世宝力格组火山岩具有由低钾拉斑向钙碱性、碱性系列过渡的特征,并以钙碱性和碱性系列为主;早二叠世花岗斑岩为A型花岗岩,具有与邻区锡林浩特及巴彦乌拉—东乌珠穆沁旗带内A型花岗岩类似的地球化学特征;在花岗岩构造判别图中,花岗斑岩落入后造山区域,晚石炭世到早二叠世期间岩浆的形成环境向后造山环境逐渐演化,同时在SiO2和Na2O对K2O相关图解中,K2O含量具有增高变化的趋势,暗示构造环境有向更加稳定的板内环境演变的特征。因此,结合前人地质资料,兴蒙造山带北部晚古生代大量火山岩浆活动可能与二连—贺根山蛇绿混杂带形成有关,晚石炭世时期研究区处于后造山阶段,随着早二叠世大量A型花岗岩、碱性岩浆和双峰式火山岩的形成,该区进入造山后期更广泛的伸展环境。     

新疆巴里坤县老爷庙、额仁山一带晚古生代火山岩

老爷庙-额仁山一带发育3套性质不同的火山岩，通过对其岩石组合、岩相、古火山机构特征的详细观察及岩石学、岩石化学、地球化学的研究，晚泥盆世老爷庙组火山岩为玄武岩-安山岩组合，发育盾状和层状火山，属海相环境，为板块消减带岛弧型高铝玄武岩；晚石炭世-早二叠世哈尔加乌组火山岩为陆相火山岩，岩石组合为安山岩．英安岩-流纹岩，以爆发相为主，常形成破火山及锥状火山机构，为陆-陆碰撞造山期火山岩；早二叠世中晚期卡拉岗组火山岩为一套以酸性为主的陆相火山岩，喷溢相发育，常形成穹状古火山机构，岩石组合为英安岩-流纹岩，为造山期弛张期火山岩，3套火山岩为板块不同阶段的火山岩，从老爷庙组火山岩→哈尔加乌组火山岩→拉岗组火山岩，岩石向酸性演化，地壳成熟度愈来愈高，南混合壳转化为陆壳．     

新疆西天山伊犁地块晚古生代火山岩地质特征及构造意义

对新疆西天山伊犁盆地晚古生代火山岩时空分布和地质特征、岩石化学等进行系统总结,认为该盆地晚古生代火山岩主要由晚泥盆世至早二叠世的火山岩组成,其形成与南北天山洋盆演化有关.晚泥盆—早石炭世大哈拉军山组火山岩为天山南北洋盆大洋板块俯冲而成的钙碱性火山岩,晚石炭世伊什基里克组火山岩为挤压环境向拉张环境过渡的钙碱性火山岩和碱性火山岩,早二叠世乌郎组火山岩为后造山具裂谷特征的双峰式火山岩组合.     

小兴安岭西北部石炭纪地层火山岩的锆石LA-ICP-MSU-Pb年代学及其地质意义

小兴安岭西北部晚古生代火山-沉积地层时代的厘定对讨论区域构造演化具有重要意义。本文对该区晚古生代火山岩和粉砂岩进行了锆石LA-ICP-MSU-Pb年代学研究。结果表明,原晚石炭世-早二叠世宝力高庙组、早二叠世大石寨组和晚二叠世五道岭组火山岩均形成于石炭纪,锆石U-Pb年龄集中于353～352Ma和307～306Ma。早石炭世洪湖吐河组上部粉砂岩的碎屑锆石具有两组206Pb/238U谐和年龄,其加权平均年龄分别为385.2±6Ma和353.0±3.6Ma,前者与区域中晚泥盆世钙碱性火山岩的时代相近,后者与早石炭世火山岩的年龄一致,表明沉积物源主要来自中晚泥盆世-早石炭世火山岩,沉积上限为杜内期。新的年代学资料及地层学资料表明,区域早石炭世火山活动(353～352Ma)伴有洪湖吐河组海相沉积,晚石炭世火山活动(307～306Ma)则伴有宝力高庙组陆相沉积。综合区域上普遍缺失巴什基尔阶,认为大兴安岭北部-小兴安岭西北部地区早石炭世晚期发生的海-陆转变与额尔古纳-兴安地块和松嫩地块的碰撞拼合密切相关,早石炭世火山岩可能形成于碰撞前的俯冲环境,晚石炭世火山岩形成于碰撞后的伸展背景。     

新疆博格达山晚古生代地层的形成时代、物源及其演化:碎屑锆石U-Pb年代学证据

新疆博格达山主体由石炭系海相火山一沉积岩系组成,以发育两期双峰式火山岩,但不发育花岗岩为特征,对其晚古生代地层时代的划分和演化争议较大。本文重点对博格达山北部两个晚古生代砂岩进行了碎屑锆石U-Pb年代学分析,重新标定博格达山地区晚古生代地层的形成时代;利用物源区的演化,约束晚古生代构造演化。测年结果显示博格达上亚群砂岩的碎屑锆石表面年龄值分布范围较宽,主峰年龄为343~284 Ma(80%),次峰年龄为386~375 Ma(3%)、503~441Ma(7%)和871~735 Ma(10%);芦草沟组砂岩的碎屑锆石表面年龄值非常集中,主峰年龄为358~279 Ma(97%),次峰年龄为257~251 Ma(约3%)。博格达山中部原石炭纪博格达群上亚群与西部和南部下芨芨槽群相当,应属于早二叠世,中部一东部的石炭一二叠纪界线应在博格达下亚群一上亚群或居里得能组一沙雷塞尔克组之间的不整合面之中。博格达北部地区晚二叠世以南侧天山物源区供给为主,反映出晚古生代期间博格达山地区至少存在晚石炭世末和中二叠世两期构造隆升。结合区域火山岩与火山碎屑岩的研究,认为博格达山地区晚古生代主要经历4个演化阶段:早石炭世弧后盆地裂解阶段、晚石炭世碰撞拼贴阶段、早二叠世碰撞后伸展阶段、中-晚二叠世再次隆升到稳定阶段。     

Wavelength-dispersive X-ray fluorescence spectrometric determination of Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites

Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours.     

高压微波消解法测定醋酸纤维过滤器采集的微尘粒子中的砷镉钴铬铜铁锰镍铅钒锌

最新的流行病学研究表明,空气中较高浓度的悬浮细颗粒可能对人类的健康有不利的影响。根据该项研究显示,由于心脏病、慢性呼吸问题和肺功能指标恶化而导致死亡率的升高与细尘粒子有关。这些研究结果已经促使欧盟于1999年4月出台了限制空气中二氧化硫、二氧化氮、氧化氮、铅和颗粒物含量的法案(1999/30/EC),对各项指标包括对可吸入PM10颗粒的浓度提出了新的限制性指标。PM10颗粒是指可以通过预分级器分离采集的气体动力学直径小于10μm的细颗粒。目前研究的兴趣重点逐步偏向PM2.5这些更细微颗粒物,PM2.5这种颗粒物对健康有明显的不利影响。在欧盟指令2008/50/EC中,对PM10和PM2.5都提     

硅酸盐类样品中硅、铁、铝、钛、锰、钙、镁、钾、钠和磷的x射线荧光光谱测定

本文拟定了一种以熔融法制备样片,用X射线荧光光谱测定硅酸盐类样品中Si、Fe、Al、Tj、Mn、Ca、Mg、K、Na、P等元素的分析方法。在对不同靶材X光管和分光晶体实验对比的基础上,选择了最佳的测量条件。该法具有快速、准确,测量范围广,检测限低,价格便宜等优点。经过近百个各种类型标样或管理样品的分析对比表明,本法不仅适用于硅酸盐类岩石样品的分析,还适用于铁矿、铝土矿、碳酸盐类岩矿样品以及水泥、耐火材料等样品的分析。     

Isotopic systematics of He,Ar, S,Cu, Ni,Re, Os,Pb, U,Sm, Nd,Rb, Sr,Lu, and Hf in the rocks and ores of the Norilsk deposits

This paper reports the first results of a study of 11 isotope systems (³He/⁴He, ⁴⁰Ar/³⁶Ar, ³⁴S/³²S, ⁶⁵Cu/⁶³Cu, ⁶²Ni/⁶⁰Ni, ⁸⁷Sr/⁸⁶Sr, ¹⁴³Nd/¹⁴⁴Nd, ^206–208Pb/²⁰⁴Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others.     

Viscous, cohesive, non-Newtonian, depositing, radial slurry flow

Mining induced subsidence can significantly affect mining costs where major surface facilities and natural environment need to be protected. Overburden grout injection is a technology used to control coal mine subsidence by injecting the mine waste material extracted from the coal back into the inter-burden rock during longwall mining. The flowing slurry is here categorised as a nonlinear viscous cohesive (Bingham plastic) fluid. During longwall mining the grout slurry is pumped into the separated beds of the rock mass through a central vertical borehole, which is drilled deep into the inter-burden rock strata above the coal seam. However, a blockage can occur in the injection system when the slurry velocity falls below a certain critical threshold velocity, indicating a material phase change from cohesive-viscous to cohesive-frictional. In situ field injection tests through boreholes have been simulated at a smaller scale at the CSIRO laboratory in Brisbane by pumping the slurry through a radial disk (gap = 4 mm) from its centre. Laboratory experiments indicate a general, nonlinear, cohesive, viscous, frictional model for shear behaviour of the slurry, in which the material shear parameters are functions of the disk radial distance. Complete dimensional and dimensionless analytical solutions have been developed based on an approach related to Bingham–Herschel–Bulkley fluid mechanics. The derived formulae include relations for minimum pump pressure, local pressure and pressure gradient, wall shear stress, volume rate, velocity and velocity gradient. The theoretical results match the experimental measurements. The experiments covered slurries with maximum particle sizes of 0.5 to 2 mm with about 50% being larger than 100 µm. The viscosities at the various solids concentrations were measured with a standard torsion viscometer. This study differs from the previous research in several distinct aspects, namely, consideration of the variable shear parameters rather than fixed values, inclusion of total nonlinear behaviour, and implementation of a friction function to mimic behaviour of the deposited and consolidating stiff slurry, which can cause a significant pressure rise as a result of the increased shear resistance.     

硅酸盐中铁、锰、钛、钙、钾、磷、硅、铝、镁、钠、锶、铷、钡的X-射线荧光光谱定量测定

本文介绍样品经四硼酸锂熔融制成玻璃小饼。采用Lachance模式和理论a系数来校正元素间的效应,由3080E型X-射线荧光谱仪和DF-350B数据处理系统完成硅酸盐中十三个项目的测定。     

Bellechester,Minnesota, USA,lagoon collapses

Bellechester, Minnesota, is a small community of approximately 155 residents located on the county line between Goodhue and Wabasha counties in southeast Minnesota's karst region. Bellechester is served by a 21-year-old wastewater treatment facility (WWTF) consisting of three waste-stabilization ponds. On 28 April 1992 six sinkholes were discovered to have drained cell 2 of the WWTF resulting in the loss of approximately 8.7×10⁶ 1 of partially treated effluent and about 600 m³ of soil into previously undetected subsurface voids of unknown dimensions. In the week following the collapse, approximately 200 water wells located within a 5-km radius of the WWTF were sampled in an after-the-fact, emergency sampling program. Twelve samples with elevated fecal coliform levels, 18 samples with nitrate-nitrogen greater than the 10 mg/1 standard, and no samples with elevated chlorides were found. However, the elevated levels could not be unambiguously attributed to the WWTF collapse. This is the third WWTF to fail by sinkhole collapse in southeast Minnesota since 1974. All three collapsed lagoons have been located in similar geomorphic and stratigraphic settings. However, at least two lagoons have collapsed in the adjacent area in northeast Iowa, and these lagoons are located at different stratigraphic positions. Twenty-two WWTFs constructed in southeast Minnesota's karst region in the last 25 years have been identified as subject to potential sinkhole collapse. An unknown but significant number of manure storage lagoons, flood control structures, etc., have also been constructed in the karst region and are at risk. Public agencies are beginning to develop plans to deal with the risk associated with existing and future waste lagoons in this environment. The critical hydrogeologic parameters that can be used to prioritize the risk of collapse at existing facilities include: (1) the lithology of the first bedrock beneath each lagoon, (2) the thickness of surficial materials between the lagoon and the bedrock surface, (3) the presence and construction of liners (seepage rate), and (4) the proximity to existing sinkholes.     

Mercury,arsenic, antimony,and selenium contents of sediment from the Kuskokwim River,Bethel, Alaska,USA

The Kuskokwim River at Bethel, Alaska, drains a major mercury-antimony metallogenic province in its upper reaches and tributaries. Bethel (population 4000) is situated on the Kuskokwim floodplain and also draws its water supply from wells located in river-deposited sediment. A boring through overbank and floodplain sediment has provided material to establish a baseline datum for sediment-hosted heavy metals. Mercury (total), arsenic, antimony, and selenium contents were determined; aluminum was also determined and used as normalizing factor. The contents of the heavy metals were relatively constant with depth and do not reflect any potential enrichment from upstream contaminant sources.     

滇东南花岗岩与锡、银、铜、铅、锌多金属矿床的成因关系

滇东南锡、银、铅、锌多金属矿床主要分布在个旧、白牛厂、都龙3个矿区,而滇东南较大的3个花岗岩体又分别出露在3个矿区或附近.花岗岩体均形成于燕山晚期,岩石化学、矿物成分相似,富含锡、银、铅、锌、钨、铜等成矿元素.矿床主金属元素组合与岩体之间的距离由远而近出现由锡、钨、(铍、铌、钽)→锡、钨、(铁)、铜、铟→锡、铅、锌、银、铟、(锑)有规律的变化.花岗岩浆是成矿物质来源和成矿热源.岩浆侵入初期使上覆地层隆起产生背斜(凹陷部位成向斜);同时使地层产生一系列裂隙、压性断层或层间断裂;岩浆侵入晚期,这些断层再次活动,表现为张性,岩浆产生的含矿热液沿由其活动所造成的断裂迁移、充填、交代、沉淀而形成矿床.     

岩石密度和超高压岩石折返速率

在常温常压条件下对中国大陆科学钻CCSD主孔100-3000米岩心样品进行了密度测量,建立了密度连续剖面,并界定了不同超高压岩石的密度值。通过对比高温高压物性实验资料,岩石密度随着退变程度增强而降低,榴辉岩密度变化序列为3.52g/cm3→3.49g/cm3→3.07g/cm3→2.93g/cm3。超高压长英质岩石密度变化序列为3.00g/cm→2.80g/cm3→2.65g/cm3。上述实验资料是讨论不同折返阶段岩石所受浮力的基础,为研究折返速率大小提供了基本参数。本文通过折返板块运动平衡时,上浮力与粘滞力平衡这一关系式,定量研究了大陆俯冲板块的折返速率,认为密度差产生上浮力从而引起折返,温度对板块折返速率的影响最为显著;密度差大小、折返角度、折返板块大小对折返速率也有直接的影响。定量模拟分析表明,在温度高于850℃时,板块的折返速率可以超过100mm/a;当温度降至700℃时,折返速率则低于1.5mm/a。作者认为在折返早期,温度较高,板块快速折返至60-70km榴辉岩相深度;随着传导散热,温度降低,板块以较慢的速率折返至中下地壳。折返速率的估算表明,浮力是板块折返第一阶段(从>100km深部折返至<40km的中下地壳)的主要驱动力。