胶磷矿晶体结构研究

详细叙述了磷灰石的晶体结构,并采用多种方法对磷灰石结构中配位多面体各元素间的化学键力进行计算,分析了磷灰石的表面特性。针对贵州典型磷矿区具有代表性的胶磷矿试样,其主要由微晶磷灰石组成,采用x射线衍射分析了胶磷矿试样的物相组成、结晶度、晶胞参数以及磷灰石晶粒大小。在扫描电子显微镜下,2种胶磷矿多呈集合体形态,两种胶磷矿中磷酸盐矿物主要为氟磷灰石。     

贵州织金含稀土磷矿床稀土元素赋存状态研究

利用等离子质谱仪ICP-MS、扫描电镜配合能谱分析、电子探针分析方法,研究了贵州织金含磷岩系剖面稀土含量变化。结果表明,剖面上稀土含量与磷灰石含量变化呈正相关关系,说明稀土主要赋存于磷灰石矿物中;利用扫描电镜、电子探针分析方法对生物碎屑、白云石和胶磷矿进行单矿物微量元素分析研究表明,胶磷矿中稀土含量最高,生物碎屑和白云石稀土含量较低,说明织金含稀土磷矿床稀土元素赋存状态是以类质同象的形式存在于胶磷矿中;利用稀土元素化学物相分析研究同样表明只有少量的稀土元素被磷块岩中粘土矿物所吸附,大量的稀土元素以类质同相形式存在于胶磷矿中。     

云南镇雄县银厂湾磷矿地质特征及成因分析

云南省镇雄县银厂湾磷矿为隐伏矿,矿体呈层状赋存于下寒武统梅树村组( 1ms),现已控制三个矿体,矿体产状与岩层产状一致,均较为平缓。矿体矿石矿物为胶磷矿、微晶碳磷灰石和氟磷灰石。通过研究,该矿床形成于海湾潮下低能带的古地理环境,主要由富磷生物碎屑沉积聚集而成,属沉积的碳酸盐-硅质层状磷块岩矿床。     

卡哈洛磷矿矿石特征及其成因分析

卡哈洛磷矿磷矿石以磷质碎屑（砂屑、鲕粒、砾屑、团块、生物碎屑）结构为主,次为胶状泥晶结构;原生磷块岩矿石主要有纹层-条带状和块状两种构造类型,矿石中磷酸盐矿物为泥晶磷灰石（胶磷矿）。矿床形成于水体较浅、水动力条件强、以波浪作用为主的潮下浅滩环境。     

震旦纪陡山沱组的泥晶磷块岩

泥晶磷块岩(micritic phosphorite)是磷块岩的主要类型之一。我国的磷块岩矿床也多有这种矿石。过去往往把组成泥晶磷块岩的磷酸盐矿物叫做胶磷矿(collophane)。扫描电镜、X-射线衍射等观察结果表明,胶磷矿实际上也是结晶质磷灰石,只是由于颗粒极其微小而已。由这种泥晶磷灰石组成的泥晶磷块岩也同样不像过去描述的那样单调,而是具有比较复杂的结构、构造。     

寻甸先锋下寒武统磷块岩的地质特征及成矿机理

先锋磷块岩产地,地处寻甸县西部,为南北向展布的滇东磷矿带中段。由于所处古构造、古地形及古地理的差异,含磷岩系的特征、厚度、组构等均受沉积岩相制约。磷块岩位于含磷岩系下部,由胶磷矿磷基、内碎屑、鲕粒、骨屑、白云石及少量陆源砂构成,具化学沉积作用,机械沉积作用特征。一、含磷岩系划分     

磷灰石伟晶岩的发现—在辽东半岛地区寻找变质磷矿床的一个线索

前震旦紀变质岩在辽东半岛地区分布极其广泛,几乎占基岩出露面积百分之五十。因此找寻变质磷矿床一直是有关部门密切注意的对象。到1964年为止,在辽东半岛前震旦紀变质岩系中虽已发现有磷矿化现象,但多为胶磷矿,尚未发现典型的变质磷矿床。根据邻区所发现的变质磷矿床资料,大部份矿床附近的伟晶岩中富含磷灰石,磷灰石与白云石密切共生而组成磷灰岩或磷灰石白云质大理岩。这些     

贵州织金磷块岩型稀土矿与热液作用:流体包裹体证据

对织金磷-稀土矿果化矿段中摩天冲、戈仲伍矿段中磷肥厂磷块岩进行岩相学研究,对磷块岩中石英、白云石矿物流体包裹体进行冷热台显微测温研究,结果表明,磷肥厂硅质磷块岩中胶磷矿主要以碎屑磷灰石形式存在,粒径50～200?m,以硅质胶结和白云石胶结为主;石英、白云石捕获流体包裹体均一温度分布于87.5～127.8℃,盐度变化于12.31%～20.61%,计算的流体压力为5.54～8.02 MPa;而摩天冲白云质磷块岩中胶磷矿主要以是碎屑磷灰石形式存在,粒径变化于50～300?m范围,以白云石胶结为主;白云石捕获的流体包裹体均一温度变化于99.8～184.3℃范围,盐度变化于12.31～20.61 wt%,计算的流体压力变化于13.7～22.6 MPa。碎屑磷灰石胶结物以及流体均一温度和盐度上存在显著的差异,指示果化矿段中摩天冲白云质磷块岩所揭示的热液体系很可能是热卤水与正常海水混合所致,而晚期不含NaCl的硅质热液对早期形成的白云质磷块岩的交代对戈仲伍矿段中磷肥厂硅质磷块岩有着重要的影响。     

云南省永善县务基磷矿床地质特征及成因分析

云南省永善县务基磷矿赋存于下寒武统梅树村组中谊村段地层中,矿石矿物以胶磷灰石为主,具砂屑、砾屑及鲕粒结构,薄-中层状、块状及条纹条带状构造,矿石自然类型为砾屑状磷块岩、条纹状白云质磷块岩、条带状白云质磷块岩、硅质磷块岩。通过分析矿区所处古构造、古地理特征和矿石结构特征,认为务基矿区磷矿为浅海相沉积磷块岩矿床。     

高镁磷尾矿的矿石结构与矿物组成

利用电子探针背散射电子成像分析和微区成分分析功能,对贵州瓮福高镁磷尾矿的矿石结构和矿物组成进行了研究,以探索尾矿与其原矿之间的差异,为综合开发利用磷尾矿提供必要的依据。结果表明该高磷尾矿的矿石结构可分为单矿物结构和多矿物碎屑结构两类。前者矿物组成包括白云石单矿物、磷灰石单矿物、褐铁矿单矿物、石英单矿物;后者包括白云石-磷灰石多矿物、磷灰石-白云石-石英多矿物,属高镁低品位磷矿。矿物组成类型按其含量从高到低依次为白云石质尾矿、白云石磷灰石质尾矿、磷灰石白云石石英质尾矿、石英质尾矿、磷灰石质尾矿、褐铁矿质尾矿,白云石质尾矿是尾矿中最丰富的矿物,白云石颗粒是含量最高的碎屑类型。     

会泽黄草岭磷矿地质特征及成矿浅析

会泽县黄草岭磷矿含矿层位为下寒武统渔户村组中谊村段（∈1yz）,胶磷矿由砂屑、砾屑、鲕粒组成,孔隙一基底胶结,多伴铁泥质胶结,颗粒形态次圆、不规则状,细、粗颗粒含量不均;沉积环境处于古陆边缘浅海地域,矿物质来源主要取决于古陆风化淋滤作用.     

江西大背坞地区浅变质岩中同生碎屑的发现及其地质意义

同生碎屑是沉积岩中一种反映动荡沉积环境的典型构造现象。笔者在大背坞地区首次发现了同生碎屑，这对确定双桥山群属于浊流相沉积提供了又一重要证据。根据同生碎屑的变形特征，笔者认为本区双桥山群地层主要经历两期变形，即以压扁为主的区域褶皱变形和以剪切为主的韧性剪切变形。     

滇池地区沉积磷块岩中胶磷矿矿物学特征及其研究意义

本文从物理性质、化学成分及其成因结构等方面,对云南滇池地区胶磷矿进行了矿物学特征研究。提出该区胶磷矿主要以三种形式赋存在磷块岩中。对不同矿石类型中胶磷矿做扫描电镜研究,得知胶磷矿主要由超微晶低碳氟磷灰石集合体、磷酸盐显微莓群以及纤维放射状磷灰石等构成。经化学分析、红外、晶胞参数测定,不同胶磷矿有一定差异,特别是碳和磷,经矿物学对比发现,反映随变质作用的加深,胶磷矿有向晶质氟磷灰石演化的趋势,脱碳作用表现明显。本区胶磷矿稀土元素含量不高,钇族较富,铈族较贫。球粒陨石标准化后为铈亏损型模式。     

Concentrically zonal textures in a sample of the Kaidun meteorite

The paper reports the results of the textural and mineralogical studying of clast Kaidun #d6A. The principal minerals of the clast are phyllosilicates, carbonates, and sulfides, but the clast contains no anhydrous silicates. The clast is characterized by extremely high concentration of inclusions, which broadly vary in size, composition, and texture, from completely remelted to practically unchanged when brought to the parent body. The latter group includes two inclusions having a concentrically zonal texture, which have never before been found in meteorites. One of the inclusions consists of serpentine replaced by talc in the margins. The inclusion was formed in relation to silification under the effect of silicon-bearing aqueous fluid at a temperature of more than 300°C. The other inclusion consists of alternating Ca carbonate and phyllosilicate zones. The texture and composition of the inclusion suggest that its genesis was related to the metasomatic alteration of carbonates under the effect of silicon- and alumina-bearing aqueous fluids at temperatures of about 400–500°C. These processes are typical of large differentiated planets, and there are no reasons to expect them in the parent bodies of carbonaceous chondrites, such as Kaidun. Our results obtained on clast #d6A are in good agreement with the hypothesis that the parent body of the Kaidun meteorite was Phobos [1]. Correspondingly, inclusions #d6Aa and #d6Ab likely originated from Mars, as previously examined alkali-rich clasts did. The clast described in this publication seems to originate from the surface regolith of Phobos, which was compacted in the process of the aqueous alteration of the material and subsequently buried at a greater depth.     

Regional variation in the composition of Neoglacial end moraines, Jotunheimen, Norway: an altitudinal gradient in clast roundness and its possible palaeoclimatic significance

Matthews, John A. 1987 06 01: Regional variation in the composition of Neoglacial end moraines. Jotunheimen, Norway: an altitudinal gradient in clast roundness and its possible palaeoclimatic significance Boreas , Vol. 16, pp. 173–188. Oslo. ISSN 0300–9483.
Quantitative indices of clast roundness from Neoglacial end moraines in front of 81 Jotunheimen glaciers were compared and analysed. Statistical techniques, including non-metric multidimensional scaling, multiple regression and partial correlation, were used to relate clast roundness to selected environmental variables. Three independent variables – site altitude, glacier length (interchangeable with height of headwall relative to glacier length) and aspect – cumulatively accounted for about 58% of the variability in clast roundness. A climatic factor complex (represented by altitude and aspect) was found more important than morphological factors (such as glacier size and headwall size) in accounting for clast roundness variations between glaciers. The scale of the independent effects of altitude, morphology, aspect and geology was found in the approximate proportions 4:1.5:1:1. Several theoretical mechanisms are proposed which could explain a causal relationship between climate and clast roundness by influencing the relative importance of supraglacial and subglacial debris supply. The palaeoclimatic implications of the results are discussed with particular reference to the prediction of mean annual temperatures from clast roundness; one unit increase in clast roundness corresponding to an increase in mean annual temperature of about 1.4°C within the study area.     

贵州织金新华含稀土磷矿床扫描电镜研究

用扫描电子显微镜和Ｘ射线能谱仪等方法研究织金新华含稀土磷矿床矿物组成,结构特征及微量元素含量变化特征。通过ＥＤＡＸ能谱仪进行矿物成分分析,得出Ｙ２Ｏ３质量分烽与胶磷矿物密切相关的结论。对伴生矿物作了相关研究,初步探讨了稀土元素赋存状态及富集规律。     

江西××胶磷矿选矿试验研究

针对江西× ×难选胶磷矿,采用单一正浮选工艺进行试验.试验对各主要影响因素逐一研究分析,获得了最佳药剂制度,并在此基础上有针对性的进行了三组闭路试验,均获得了较满意的选别指标,满足了选矿厂的不同需求.研究结果为该胶磷矿的开发利用提供了技术支持.     

Carbon-rich chondritic clast PV1 from the Plainview H-chondrite regolith breccia: Formation from H3 chondrite material by possible cometary impact

Chondritic clast PV1 from the Plainview H-chondrite regolith breccia is a subrounded, 5-mm-diameter unequilibrated chondritic fragment that contains 13 wt% C occurring mainly within irregularly shaped 30-400-μm-size opaque patches. The clast formed from H3 chondrite material as indicated by the mean apparent chondrule diameter (310 μm vs. ∼300 μm in H3 chondrites), the mean Mg-normalized refractory lithophile abundance ratio (1.00 ± 0.09×H), the previously determined O-isotopic composition (Δ¹⁷O = 0.66‰ vs. 0.68 ± 0.04‰ in H3 chondrites and 0.73 ± 0.09‰ in H4-6 chondrites), the heterogeneous olivine compositions in grain cores (with a minimum range of Fa1-19), and the presence of glass in some chondrules. Although the clast lacks the fine-grained, ferroan silicate matrix material present in type 3 ordinary chondrites, PV1 contains objects that appear to be recrystallized clumps of matrix material. Similarly, the apparent dearth of radial pyroxene and cryptocrystalline chondrules in PV1 is accounted for by the presence of some recrystallized fragments of these chondrule textural types. All of the chondrules in PV1 are interfused indicating that temperatures must have briefly reached ∼1100°C (the approximate solidus temperature of H-chondrite silicate). The most likely source of this heating was by an impact. Some metal was lost during impact heating as indicated by the moderately low abundance of metallic Fe-Ni in PV1 (∼14 wt%) compared to that in mean H chondrites (∼18 wt%). The carbon enrichment of the clast may have resulted from a second impact event, one involving a cometary projectile, possibly a Jupiter-family comet. As the clast cooled, it experienced hydrothermal alteration at low water/rock ratios as evidenced by the thick rims of ferroan olivine around low-FeO olivine cores. The C-rich chondritic clast was later incorporated into the H-chondrite parent-body regolith and extensively fractured and faulted.     

Glacigenic clast fabrics: genetic fingerprint or wishful thinking?

The interpretation of glacigenic diamictons is a subjective process, for which quantitative support is frequently sought from parameters such as clast shape and fabric. It has been widely suggested that different glacigenic diamicton facies possess distinct clast‐fabric signatures. This paper examines this concept using a data set of 111 clast fabrics, and a synthesis of published results. Eigenvalues are calculated and compared for a variety sedimentary facies. It is concluded that clast fabric alone is not able to discriminate between different glacigenic facies, and it is argued that clast fabric offers little quantitative support in the interpretation of glacigenic sediments. It is suggested, therefore, that although clast fabric may continue to have a role as an indicator of relative strain at specific sites, its use in the discrimination of glacigenic facies is limited. Consequently, we should be much more selective in undertaking such analyses in the future. Copyright © 1999 John Wiley & Sons, Ltd.