The Role of Organic Matter in the Formation of Siderite from Xuanlong Area,Hebei Province

Based on the analysis of siderite distribution,occurrence,chemical compositionk,structureal characteristics,carbon-oxygen isotopic characteristics and relationship between siderite and hematite,this paper presents a systematic study of siderite in the region studied.suggesting that the siderite in the Xuanlong area genetically resulted from organically reduced primary hematite during the diagenesis.The ferric and ferrous relations directly depend on organic contents.In the presence of organic matter ferrous iron can be converted to ferric iron through or ganic reduction.The above conclusion has also been proved by organic geochemistry.data.     

我国铁矿床的一种新类型——弓长岭式含石墨的富磁铁矿矿床及其成因

Graphite has been identified for the first time from rich magnetite ores in Gongehangling,Northeast China.It is suggested that the deposit is originated from siderite of sedimentary origin through regional metamorphism.In view of the unique charaeteristics of its geologieal setting and mineral assemblage this deposit should be elassified as a new type in China     

An Effective Method for Free Vibration of Plate on Elastic Half Space

The vibration analysis of a plate on an elastic foundation is an important problem in engineering. It is the interaction of a plate with the three-dimensional half space and the plate is usually loaded from both the upper and lower surfaces. The contact pressure from the soil can not be predefined. According to Lambs solution for a single oscillating force acting on a point on the surface of an elastic half space, and the relevant approximation formulae, a relation between the local pressure and the deflection of the plate has been proposed. Based on this analysis, the reaction of the soil can be represented as the deformation of the plate. Therefore, the plate can be separated from the soil and only needs to be divided by a number of elements in the analysis. The following procedure is the same as the standard finite element method. This is a semi-analytical and semi-numerical method. It has been applied to the dynamic analysis of circular or rectangular plates on the elastic half space, at low or high frequency vibration, and on rigid, soft or flexible foundations. The results show that this method is versatile and highly accurate.     

包含一个未知熵的单变度线斜率符号的判断及相平衡实验反应的选择

The concept of “Slope Entropy Limit” is proposed in this paper. With the aid of computer, a Slope Entropy Limit Table can be readily established, which will be helpful to estimating the slope signs of univariant lines involved in a multisystem with a phase of unknown entropy. Under fortunate circumstances the unknown entropy is expected to be restricted within acceptable limits based on slope sign data on some critical univariant lines. Otherwise, these critical univariant reactions are considered most optimum to be tested experimentally. A critical entropy limit can be obtained only if the slope sign of such a line is confimed. The entropy limit thus obtained is subjected to a much less extent to uncertainties in PT measurements in comparison with entropy values derived from PT brackets.     

Jurassic-Cretaceous Boundary Strata of the Somanakamura Group in NE Japan and their Correlation with Coeval Terrestrial Deposits in China

Defining the Jurassic-Cretaceous boundary is a controversy in stratigraphic study of the world. It has been widely accepted that this boundary can be defined at the bottom of Berriasian in Tethys, with the appearance of the ammonite Berriasella jacobi dating to ca. 145 Ma. However, it is difficult for the widespread terrestrial deposits in China to correlate with the international standard of marine facies. The Somanakamura Group in Japan is represented by a succession of marine-continental transitional strata. It provides a bridge of marine and nonmarine stratigraphic correlation. The ammonite and radiolarian fossils preserved in this group suggest an age from Bajocian to early Valanginian. The J-K boundary was defined in or atop the Tomizawa Formation of the group according to the ammonite data. The present authors study the fossil spores and pollen newly found from the Tomizawa and Koyamada formations. Three assemblages have been recognized. They are Assemblage 1 (Cyathidites-Classopollis) from the upper part of the Tomizawa Formation, Assemblage 2 (Cyathidites-Jiaohepollis) from the lower part of the Koyamada Formation, and Assemblage 3 (Cyathidites-Spheripollenites-Ephedripites) from the middle to upper part of the Koyamada Formation. With the reference of ammonite evidence, the J-K boundary can be defined between Assemblage 1 and Assemblage 2. This palynological J-K boundary can be correlated with that of terrestrial sequence in China. However, local biostratigraphy imply that the continental J-K boundary in China is of 135 or 137 Ma age. It has a considerable discrepancy from the marine standard. Biogeographically, the distribution pattern of spores and pollen in southern China is in accordance with that in the Somanakamura Group, which parallels the Tuchengzi Formation in northeastern China. By the palynological correlation between the Somanakamura Group and the strata in southern China, and then with the sequence in northeastern China, it is suggested that the continental J-K boundary is located in the Tuchengzi Formation.     

Geochemistry of sedimentary rocks and its relation to crustal evolution and mineralization in Southwest Yangtze Massif, China

Through a systematic study on trace elements and REE geochemistry of mudstone deposited in the basin and lower slope environments during Upper Proterozoic to Triassic in the Southwest Yangtze Mssif,three geochemical abnormal horizons of which the geochemical characteristics are quite different from those of other horizons have been established for the first time.They are the Lower Cambrian,the Upper Devonian and the Upper Permian,As compared with the crustal evolution in this area.these three geochemical abnormal horizons are corresponding to the pulling-apart periods of geotectonic cycles.which illustrates that uncommon depositional sources puring into the basin from the earth‘s interior may be one of the most important causes to originate the geochemical anomalies in these lhrizons.Thus it can be realized that the geochemistry of post-Archean sedimentary rocks has a great deal to do with the crustal evolution and it can be used as a tracer to analyze the crustal evolution.The elements in this area are mainly concentrated in these geochemical abnormal horizons,and the degree of enrichment and deficiency of trace elements in other horizons is very limited.A series of research on mineralization indicates that the main strata-bound ore deposits discovered in the Southwest Yangtze Massif occur in the Cambrian,Devonian and Permian-Trassic strata.The results of isotope tracer resarch have also proved that most of the metallogenic elements in these ore deposits came from the host strata.which illustrates that the geochemical abnormal horizons may have made great contributions to these ore-forming processes.Thus it can be concluded that it is only the particular horizons corresponding to the particular periode of earth‘s evolution that can they be the significant source beds because only in these uncommon horizons there can be highly enriched metallogeinc elements.which may be one of the most important reasons for explaining the time-bound nature of mineralization.     

Characterizing Fracture Spatial Patterns by Using Semivariograms

Semivariogram is applied to fracture data obtained from detailed scanline surveys of nine field sites in western New York, USA in order to investigate the spatial patterns of natural fractures. The length of the scanline is up to 36 m. How both fracture spacing and fracture length vary with distance is determined through semivariogram calculations. In this study, the authors developed a FORTRAN program to resample the fracture data from the scanline survey. By calculating experimental semivariogram, the authors found five different types of spatial patterns that can be described by linear, spherical, reversed spherical, polynomial I (for a<0) and polynomial II (for a>0) models, of which the last three are newly proposed in this study. The well-structured semivariograms of fracture spacing and length indicate that both the location of the fractures and the length distribution within their structure domains are not random. The results of this study also suggest that semivariograms can provide useful infor     

包裹体研究与石碌铁矿成因的探讨

Shilu iron deposit is one of the highly economically important rich iron deposits in China. Based upon the research results on its ore composition and fluid inclusions, it can be reasonably explained that the genesis of this iron deposit is such that marine voleanic sediments there suffered later regional metmnorphism and hydrothermal reformation. The temperature of regional metamorphism ranges from 465 to 536℃,while that of hydrothermal reformation from 344 to 396℃. The latter seems to be related to the migmatization of Zhan Xian stock near Shilu iron deposit, Due to the hydrothermal reformation, the ore-forming materials were mobilized and transfered from the marine sedimentary rocks, subsequently redepositing and concentrating as a rich iron deposit in the present site.     

Quantitative assessment and significance of gas washing of oil in Block 9 of the Tahe Oilfield, Tarim Basin, NW China

Some Ordovician and Triassic oils in Block 9 are characterized by light oils,which have distinctly differentiated from heavy oils in other blocks in the Tahe Oilfield,Tarim Basin.Based on the whole oil gas chroma- tograms,this paper estimates the effect of oil migration and fractionation and the amount of depletion(Q)in terms of the n-alkanes depletion model.The results showed that the amount of depletion in the Ordovician reservoir is highest in the east of this block,e.g.the depletion is 97% in Well T904.The amount of Q gets lower to the west,e.g.the depletion is 53.4%in Well T115 and there is no sign of depletion in Well S69.It is suggested that the direction of gas washing is from the east to the west.The compositions and isotopic characteristics of associated gas in Ordovician oils indicated that the gas might be derived from Cambrian source rocks of the Caohu Depression which lies to the east of Block 9.In contrast,no obvious depletion of n-alkanes in Triassic oils was found,suggesting that the migration pathway of natural gas has been limited to the Ordovician karst fracture system formed in the Early Hercynian Orogeny.Different depletions of the Ordovician and Triassic oils can reveal fault activities in this region.     

First Discovery of Dicerorhinus sumatrensis from Yanjinggou Provides Insights into the Pleistocene Rhinocerotidae of South China

The Rhinocerotidae is one of the most common and important families in the Pleistocene mammalian fauna of South China. Since the last century, most of the Pleistocene rhinocerotid fossils were prematurely assigned to Rhinoceros sinensis, which has resulted in confusion of taxonomy for decades, especially in South China. The Yanjinggou area in Chongqing Municipality of China, where the neotype of R. sinensis came from, has yielded abundant rhinocerotid fossils and is a key area to solve this problem. A recently discovered juvenile skull from a karstic fissure in this area can be referred to Dicerorhinus sumatrensis (Fischer, 1814), which is the first confirmed non-Rhinoceros rhinocerotid from the area. This new finding indicates that non-Rhinoceros fossils might have been mixed in AMNH collection from Yanjinggou and thus the diagnosis of Rhinoceros sinensis needs reformation. On the other hand, Stephanorhinus ?kirchbergensis is also detected in Granger’s collection based on our reobservation. The coexistence of Rhinoceros, Dicerorhinus and Stephanorhinus shows the higher diversity of Pleistocene rhinocerotids in South China.     

混合型石棉矿床的基本地质特征

As is evidenced from the occurrence, mineral composition, asbestos minerals, the type of veins and fibrous characters it is recognized that the origin of the asbestos deposit studied in this paper in Shaanxi is different from either the serpentine type resulted from ultrabasic rocks or that originated from dolomitic limestones or dolomite.It can be considered as a gradation between the two types mentioned above.     

Permeability Heterogeneity in a Fractured Sandstone–Mudstone Rock Mass in Xiaolangdi Dam Site, Central China

Abstract: Heterogeneity of permeability in fractured media is a hot research topic in hydrogeology. Numerous approaches have been proposed to characterize heterogeneity in the last several decades. However, little attention has been paid to correlate permeability heterogeneity with geological information. In the present study, several causes of permeability heterogeneity, that is, lithology, tectonism, and depth, are identified. The unit absorption values (denoted as ω), which are results obtained from the packer test, are employed to represent permeability. The variability of permeability in sandstone–mudstone is so significant that the value of unit absorptions span 3–4 orders of magnitude at any depth with several test sections. By declustering, it has been found that under a similar tectonic history, the means of permeability differ greatly at different formations as a result of different mudrock contents. It has also been found that in the same formation, permeability can be significantly increased as a result of faulting. The well-known phenomenon, the decrease in permeability with depth, is found to be caused by the fractures in the rock mass, and the relationship between permeability and depth can be established in the form of logω–logd. After subtracting the trend of ω with absolute depth, the mean of the residual value at each relative depth can be well correlated with the distribution of mudstone. The methods proposed in this paper can be utilized to research in similar study areas.     

Effects of urbanization on groundwater level in aquifers of Binh Duong Province,Vietnam

The purpose of this paper was to assess the impact of urbanization on the groundwater level(GWL)in aquifers of Binh Duong(BD)Province.The research method is to analyze the trend of GWL,the recharge capacity of surface over time and the relationship between them.The data of the GWL used in the study are the average values in the dry and rainy seasons of 35 observation wells from 2011 to 2018,which are in Pleistocene and Pliocene aquifers.The ability to recharge groundwater from the surface in this study was represented by the curve number(CN),a parameter used in hydrology for calculating direct runoff or infiltration from rainfall.The land use data to identify the CN was analyzed from the Landsat images.The results show that besides over-exploitation,the change of surface characteristic due to the urbanization development process is also the cause of the GWL decline.The analysis of seasonal GWL data shows that the increase in impervious surface area is the cause of GWL decline in the Pleistocene aquifer,which is more evident in the rainy season than in the dry season.The statistical results also show that in the rainy season and in shallow aquifers,a higher CN change can be found with the wells that had a remarkable GWL decline compared to the remaining wells.     

Deep-penetrating geochemistry of the Tuwu copper deposit, northwestern China

Desert terrains in northern China are covered by widespread regolith sediments which mask geochemical signals from ore bodies and are major obstacles to mineral exploration. There is a critical need to study the vertical distribution of elements in this regolith and to establish optimum sampling and analytical methods. The aim of this study is to understand the dispersion and variation of elements throughout the cover in a vertical profile. The results demonstrate that the main elements show a distribution pattern of enrichment in clay layers in the vertical profile, i.e., most elements tend to be enriched in the most upper part of the profile above the orebodies except for some elements like Cu, Ca and Ag. Meanwhile, both fine (-160 mesh) and coarse (+20 mesh) fraction samples from clay-rich horizons are favorable samples and selective leaching of the elements absorbed on clays or oxide coatings is effective for localizing buried deposits. The distribution of active Cu and Mo is quite different because chalcopyrite is weathered into Cu sulfate and CuCO3, and is precipitated in alkaline environments in a layer below close to the surface. Mo is soluble in the alkaline environment so it can penetrate the caliche layer and be enriched on the surface of soil enriched with weakly cemented clay.     

岩石化学系列和元素演化周期性

Continental crust rocks can be grouped into three petrochemical, systems, i.e.,oxygen-poor, transitional, and oxygen-rich system, which are intimately related to the intensity of crustal movement. Stable areas in the crust are characterized by rocks of oxygen-poor system, while rocks of oxygen-rich system are typical of active regions.Rocks of the transitional system form all gradations between the two systems Parallel to the orogenic cycle in crustal movement an evolutionary cycle from low to high oxygen content can always be recognized with respect to rocks in each system. On the other hand, with regard to rocks of the same type in the same petrochemical system, apart from the influence of crustal movement intensity, a tendency of increasing oxygen content with decreasing orogenic age is noticeable. As a region changes from active into gradational geologically, oxygen content is found decreasing for rocks of the same type,or vice versa. In this context, new implications may be attached to studies on petrochemical system : (1) A“family tree” can be established for rocks, thus sheding light on their evolutionary hlstoryand geneses (2)To provide information on the intensity of crustal movement, i.e., the tectonic nature for the studied area at the time of magma generation, and (3) To aid in determining petrogenetie age of magmatic rocks and in making geological divisions.     

Compaction Rate of an Early Permian Volcanic Tuff from Wuda Coalfield, Inner Mongolia

Compaction rates of sediments or volcaniclastic material are needed to reconstruct original thickness of a bed,which in turn is required to reconstruct subsidence rates,sea-level rise,or in the case of volcaniclastic,the location or direction of the eruption site.The knowledge of compaction rates can also aid in the reconstruction of deformed fossils.The known shape of deformed fossils can allow the determination of the compaction they experienced.Here we report the compaction rate in an early Permian volcanic tuff from Wuda,Inner Mongolia,determined from the deformation of standing tree fern stems of known anatomy.The compaction rate has been found to be 0.56 in this case,indicating that 44% of original thickness remains.     

Bioavailability of crops to environmental hormone Pb in soils and its remediation

Lead （Pb）, as an environmental hormone, acts as an estrogen in animal and human bodies, and its environmental pollution can result in many procreant anomalies, such as maladjustment of incretion, weakening of procreation function and descending of genital immunity. Experiments on pot-growth of paddies and corns in this study indicated that these crops did not show any macro-toxic symptoms in the observed contents of Pb added （0-4000 mg/kg） in soils. However, lead in soils can be easily absorbed by crops and accumulated in the different parts of plants. Statistical analysis showed that Pb contents in the crops are strongly positively correlated to the Pb contents in soils. In the crops, the Pb contents of roots are highest, tens to thousands of times those of straws and seeds. It is suggested that the root is a barrier of Pb absorbed by straws and seeds. Based on this fact, Pb pollution in soils can be gradually reduced by planting crops and subsequently removing the roots from the soil. This biotechnology may be used in environmental remediation, which embraces the quality of sustainable agricultural economy and a healthy environment.     

Methylmercury and total mercury distribution in the sediments of Baihua Reservoir, Guizhou Province, China

Mercury is an important pollutant in lakes. Methylmercury （MeHg）, the most toxic mercury species, which can be formed from inorganic mercury in lakes, can be bioaccumulated into high concentration in food chain and result in a potential threat to human beings. Sediments play an important role for the Hg biogeochemistry in the aquatic systems： Mercury methylation has been shown to be fastest in the surfacial sediments, where the microbial activity is highest. The formation of MeHg in lakes suggests that sediments and/or near-shore wetlands can be the sources of MeHg in aquatic environments. The Baihua Reservoir, located in the suburb of Guiyang, was impounded in 1966. From the 1970s to the 1990s, Guizhou Organic Chemical Plant which used inorganic mercury as catalyst to produce acetic acid, was responsible for the discharge of waste water with high mercury content.     

Stratigraphic Division and Correlation of the Nihewan Beds by Multivariate Statistical Analysis

Described in paper is the principle of optimal partitioning method for stratigraphic division and correlation.The Nihewan Beds are taken for example to show how to apply this approach in stratigraphic division and correlation.The semiquantitative spectral analysis data on aggregate trace elements in 324 samples taken from the nine sections in the Nihewan Basin are treated with multivariate statistical method for stratigraphic division and correlation.First ,the data from all the sections are respectively calculated by the optimal partitioning method to establish the stratigraphic boundaries.The optimal partitioning method has proved itself to be applicable to stratigraphic division and correlation. In our practice the Nihewan Beds are divided into five zones (I-V).Zone I includes subzones Ia and Ib,Zones Ia,Ib,II and III are considered to be corresponding to the Pliocene(N2),the early Early Pleistocene,the late Early Pleistocene,and the Middle Pleistocene,respectively .Zones IV and V are probably Late Pleistocene in age.This indicated that sediments deposited con-temporaneous in the sections of the same basin are similar in geochemical characteristics,although dif-ferent in geographical location.However,the sediments also show some variations ,with a transitional relationship from one section to another .For example ,in Zone II,the sediments of the Xiaodukou section show not only the characteristics of the Nangou-Hongya and Hutouliang sections,but also those of the Xiashagou,Shixiaxi,Shixiadong and Wulitai sections.It can be seen from the above that the zones can be characteristically correlated with one another.In addition the feasibility of the optimal partitioning method is also described in the present paper.     

The main geochemical biological and reworking metallogenic models of the Lanmuchang independent Tl deposit

Thallium(Tl)is dispersed element and it seldom occurs in the form of independent minerals.So the element is hard to form any independent deposit.The world annual production of Tl is about 13 ton.most of which is recovered as by-product from non-ferrous metal metallurgical products.Reported in this paper is the only large-sized independent tl deposit in the world,of which the tl ores can be mined,ore-dressed and smelted independently.Bio-enrichment and hydrothermal reworking are the two important metallogenic mechanisms of this Tl deposit.This paper will give a discussion to the Lanmuchang Tl deposit in the following respects including its geolgical characteristics,element association of Tl,Hg,As and Au and W,sulfur isotopic composition.involvement of hallogens in metallogenesis and the metallogenic models.