北京房山岩体的磁组构特征及其 对岩体侵位的约束

岩浆岩的磁组构与岩浆流动、侵位时应力和冷凝后遭受后期构造改造作用有关.本文分析了北京房山岩体东山口-凤凰亭剖面岩石磁化率各向异性(AMS)变化.热磁曲线和磁滞回线分析显示,岩石的主要载磁矿物为多畴磁铁矿颗粒.AMS磁化率椭球体呈压扁状,磁面理发育且产状陡倾,磁化率各向异性度P值平均值高达1.189.自边缘相(东山口)到中心相(凤凰亭),岩石磁化率椭球的扁率E值和形状因子T值逐渐减小,说明磁组构主要反映岩浆流动和岩体侵位时近NNE-SSW方向的挤压作用,在侵位冷凝后并没有遭受到明显的构造改造.     

Environmental magnetism of nanophase iron minerals: Testing the biomineralization pathway

Nanoparticles of iron oxides and iron oxyhydroxides are sensitive proxies of environmental change near the earth's surface. Our research programme aims to provide information about the environmental control variables (temperature, rainfall, pH, as well as microbial type and concentration) for the process of Fe(III) to Fe(II) reduction and solid phase precipitation. Such solid phases of environmental change proxies (e.g., magnetite and maghemite) are being produced in the laboratory for calibration of field data. Low temperature magnetometry and Mössbauer spectra are shown to be extremely useful for characterization and granulometry of such nanophases. In addition, it appears that magnetism may also be a sensitive probe for physical–chemical properties of the outermost ‘skins’ of such nanoparticles, confirming Louis Néel's predictions for the magnetic behavior of such outermost layers.     

Magnetic characterization and Mössbauer spectroscopy of magnetic concentrates from Greek lake sediments

Bulk magnetic properties of three Greek lake sediments indicated that the main magnetic constituent was predominantly pseudo-single-domain magnetite. This was confirmed by successfully extracting and directly identifying the magnetite. The majority of the magnetite in the magnetic concentrates is present as grains of about 2–3 μm in size, the overall size ranging from < 1to～ 10 μm with occasional grains up to ～ 20 μm. The grains are roughly equidimensional and angular in form indicating that they are of primarily detrital origin, although an authigenic origin for the very fine grains must be a possibility. Mössbauer spectra of the magnetic concentrates suggest that either the magnetite is slightly non-stoichiometric to a similar degree in the three lakes, or contains impurity ions. Haematite was also found in the concentrates but its abundance is only ～10–15% that of magnetite and its is not detectable in any of the magnetic properties of the sediments.     

Magnetic structure of polluted soil profiles from Eastern Ukraine

Our study concerned magnetic properties of soil profiles taken from polluted regions of Eastern Ukraine around the industrial centres Krivyj Rig, Mariupol and Komsomolsk. Soils represent chernozem and podzoluvisol. The low-field magnetic susceptibility shows enhancement in the topsoil caused by contamination by coarse-grain magnetite connected with industrial pollution. Magnetic mineralogy was determined by means of thermal demagnetisation of SIRM, monitoring of susceptibility changes during warming from ?196°C to room temperature and heating to 700°C, and Mössbauer analysis. Granulometry of magnetic particles was investigated by determination of hysteresis parameters, susceptibility, M _s , SIRM and ARM ratios and frequency dependence of susceptibility. The chemical parameters, namely pH, organic carbon and iron content in different pedogenic and lithogenic minerals, measured for particular horizons determined pedogenic characteristic of soil profiles. Our study showed that differences in magnetic parameters of non-polluted and polluted soil profiles are not limited to the topsoil, but reach deep layers of the parent material. Industrial pollution promotes formation of the so-called “pedogenic” SP and SD particles in these layers.     

Magnetic particles in atmospheric particulate matter collected at sites with different level of air pollution

Magnetic measurements of deposited atmospehric dust can serve as an additional parameter in assessing environmental pollution. This method is based on the assumption that atmospherically deposited particles contain significant portion of ferrimagnetic iron oxides of anthropogenic origin, which can be easily detected. Aim of this paper is to identify clearly magnetic fraction of daily samples of particulate matter less than 10 μm (PM10), routinely used for air quality assessment and monitoring. We used combination of thermomagnetic analyses and other physical and chemical methods, including scanning electron microscopy (SEM) and Mössbauer spectroscopy. Our results show that daily samples of PM10, collected at sites with different degree of atmospheric pollution, contain magnetite of spherical shape, which is presumably of industrial origin. Thus, magnetic methods can be applied directly to the same substances, which are used routinely in air quality assessment and monitoring.     

Magnetic properties of high-Ti basaltic rocks from the Krušné hory/Erzgebirge MTS. (Bohemia/Saxony), and their relation to mineral chemistry

This study provides new thermomagnetic and petrographic data on specific basaltic rock association from the broader vicinity of the Lou?ná-Oberwiesenthal volcanic centre, western Bohemia/Saxony. Two types of volcanic rocks were recognized there: (i) high-Ti types (3.5–5.2 wt% TiO₂) represented by (mela)nephelinite s.s., and sporadically present (ii) medium-Ti types (2.5–3.5 wt% TiO₂) of olivine nephelinite, nepheline basanite and phonotephrite compositions. In order to examine the rock-magnetic behaviour, they were studied for their variations in the Curie temperature (T_C) and field-dependent susceptibility, spinel group minerals, chemistry and petrology. Magnetic susceptibility of ulvöspinel-rich titanomagnetite, as a dominant magnetic carrier, depends on the amplitude of measured magnetic field, whereas pure magnetite is field-independent. Field dependence parameter ^kHD of the studied basaltic rocks ranges from 0.8 to 18.7%, TiO₂ contents in titanomagnetite range from 12.7 to 20.1 wt.%. TiO₂ content in titanomagnetite does not correlate with whole-rock TiO₂ content (2.8 to 5.6 wt.%). The content of substituted titanium in the sublattice of magnetite is also sensitively reflected in the Curie temperature, ranging from 200 to 580°C. The spinel group minerals are designated as titanomagnetite with the dominance of ulvöspinel, magnetite and magnesioferrite components, or titanomagnetite with the magnetite, ulvöspinel and magnesioferrite components. Only two samples are characterized by a significant presence of Cr-spinel and magnesiochromite components forming cores of titanomagnetites. The titanomagnetite-bearing rocks in the studied area, likewise the low- to medium-Ti basaltic rocks from the ?eské st?edoho?í Mts., provide similar thermomagnetic curves.     

Fe3+ in shocked olivine crystals of the ALHA 77005 meteorite

ALHA 77005, a shocked achondrite of the shergottite group, is unique in containing cumulus olivine crystals which display a brownish color in thin section. Mössbauer, EPR, and optical spectroscopic studies show the presence of Fe³⁺ in the olivine. Approximately 4.5 wt.% of the total iron in the olivine (24 wt.% as FeO) is in the trivalent state. The Fe³⁺ ions preferentially occupy M2 lattice positions. Charge transfer between Fe³⁺ and Fe²⁺ as well as between Fe³⁺ and oxygen ligands causes a broad absorption band in the optical spectrum at high energies which is the reason for the olivine color. It is concluded that the color of the ALHA 77005 olivine is preterrestrial and may be the result of shock-induced oxidation of the olivine crystals on the meteorite parent body.     

Magnetic properties of synthetic six-line ferrihydrite nanoparticles

Three synthetic samples of six-line ferrihydrite (Fh5.4, Fh4.1, and Fh3.0), with average particle sizes of 5.4, 4.1, and 3.0 nm (respectively), have been studied by low-temperature magnetic techniques, Mössbauer spectroscopy, transmission electron microscopy, and X-ray absorption spectroscopy. Magnetic data indicate that these nanoparticles are not only antiferromagnetic, but that they also possess a ferromagnetic-like moment due to the presence of uncompensated spins. Both magnetic and Mössbauer data indicate that nanoparticles of six-line ferrihydrite are superparamagnetic at room temperature, with a low-temperature transition between blocked and unblocked magnetic states dependent on average particle size. In particular, low-field magnetic susceptibility data display a peak in amplitude at 45 K (Fh3.0), 55 K (Fh4.1), and 80 K (Fh5.4). Low-temperature induced magnetization data, acquired in magnetic fields up to 5 T, also display clearly a superparamagnetic behavior. These data were tentatively modeled as the sum of two contributions: a linear term due to the antiferromagnetic susceptibility and a nonlinear term due to the uncompensated spins. Model estimates of the magnetization carried by the uncompensated spins (M_nc) show a decrease in M_nc with increasing temperature. Extrapolation of M_nc values down to zero provided an estimate of the Néel temperature for six-line ferrihydrite on the order of 500 K.     

Frequency-dependent susceptibility and other magnetic properties of Celtic and Mediaeval graphitic pottery from Bohemia: an introductory study

Frequency-dependent magnetic susceptibility, its anisotropy (AMS), its temperature variation, natural remanent magnetization and time-dependent isothermal remanent magnetization as well as M?ssbauer spectroscopy of a small collection of Celtic and Mediaeval graphitic pottery from Southern Bohemia were investigated. The mineral composition of the pottery is dominated by fragments of quartz, accompanied mainly by various silicates from granitoids and paragneisses, or by calcite, within the plastic component being probably illite but also graphite. No ferrimagnetic minerals were found in optical microscope, among Fe-oxides only limonite was observed, even though the bulk susceptibility of the pottery varies in the orders of 10^?4 to 10^?2 [SI]. This may indicate presence of ferromagnetic particles in the ultrafine (superparamagnetic, SP) state, which is confirmed by frequency-dependent susceptibility ranging from 3% to almost 16%. The low temperature susceptibility vs. temperature curves are only moderately sloped, showing the Verwey transition only in one case. The high temperature curves mostly show presence of two magnetic phases, maghemite and magnetite. Cooling curves show distinctly lower susceptibilities than the heating curves indicating instability of the assemblage of ferrimagnetic minerals, particularly in temperatures slightly under 700 °C. M?ssbauer spectroscopy confirmed the results of the frequency-dependent susceptibility, showing the increase of ferrimagnetic sextets in the spectra measured at 4.2K, likely indicating maghemite as the distinct ferrimagnetic phase. The frequency-dependent AMS indicates preferred orientation of SP1,16 particles, coaxiality between SP_1,16 grain AMS and whole specimen AMS indicate that all grains, ultrafine and coarser ones, were oriented by the same process, i.e. copying the pottery structure created during wheel-turning.     

Tetrahedral occupancy of ferric iron in (Mg,Fe)O: Implications for point defects in the Earth's lower mantle

We investigated the concentration and site occupation of ferric iron (Fe³⁺) in (Mg,Fe)O to understand the influence of point defects on transport properties such as atomic diffusion, electrical conductivity and viscosity. We conducted Mössbauer spectroscopy of (Mg_0.8Fe_0.2)O single crystals synthesized at temperatures from 1673 to 2273 K and pressures from 5 to 15 GPa with Re–ReO₂ and Mo–MoO₂ oxygen fugacity buffers. The isomer shift of the Mössbauer spectra suggests that Fe³⁺ occupies mostly the tetrahedral site at reduced conditions and both the octahedral and tetrahedral sites at oxidized conditions. We formulate a thermodynamic model of point defect dissolution in (Mg,Fe)O which suggests that unassociated tetrahedral Fe³⁺ is more stable than unassociated octahedral Fe³⁺ at high-pressure and low oxygen fugacity due to the effect of configurational entropy. The pressure dependence of Fe³⁺ concentration indicates a change in the dominant site occupancy of Fe³⁺: (1) Fe³⁺ in the tetrahedral site, (2) Fe³⁺ in the octahedral site, and (3) defect clusters of Fe³⁺ and cation vacancy, in the order of increasing oxygen fugacity and decreasing pressure. This is in reasonable agreement with previously reported experiments on Fe³⁺ concentration, Mg–Fe interdiffusivity and electrical conductivity. We consider it plausible that (Mg,Fe)O accommodates Fe³⁺ in the tetrahedral site down to the lower mantle. Based on our results and available experimental data, we discuss the solubility competition between Fe³⁺ and protons (H⁺), and its implications for transport properties in the lower mantle.     

Magnetic susceptibility of cambisol profiles in the vicinity of the Vír dam,Czech Republic

Magnetic susceptibility of 72 cambisol profiles from the vicinity of the Vír dam, NW Moravia was measured. The enhanced susceptibility of topsoil, particularly of the horizon O, was assessed from the aspect of vegetation setting and magnetic mineralogy. Magnetic susceptibility variations with field and temperature as well as frequency dependent susceptibility were applied to indicate magnetic carriers. It was found that the enhanced magnetic susceptibility is caused very likely by the presence of maghemite and magnetite of various grain sizes. Magnetic minerals are pedogenic in origin in all three horizons, while in the O and A horizons they are mostly anthropogenic in origin. Magnetic susceptibility was correlated with contents of trace elements Mo, Cu, Pb, Zn, Ag, As, Cd, Sb, Bi, Hg, Se, furthermore with TOT/C, TOT/S, and ¹³⁷C. The close association of susceptibility with Pb, Sb and Hg, or also with Mo, As, Se and their similar depth variations suggest a slight anthropogenic input in soils from a long-distant source. The same is valid for ¹³⁷C, its strong correlation with magnetic susceptibility has been found.     

Magnetic properties of olivine basalt: Application to Mars

The natural remanent magnetisation (NRM) of basalt lava containing (oxidised) magnetic phases is usually assumed to be proportional to the weight percent of magnetic phases. It is shown here that olivine basalt has a different behaviour. The NRM intensity increases at an increasing rate with the amount of magnetic phases. This is attributed to the oxidation of olivine during cooling of the basalt that leads to the exsolution of magnetite in a single domain state. In this way, olivine basalt is found to become an order of magnitude more magnetic than basalt that does not contain olivine. A simple explanation for the magnetic anomalies on Mars is offered, based upon these findings and Mössbauer spectroscopy data from Gusev crater on Mars.     

Variation of the phase composition of C2 chondrites on heating

The kinetics of metamorphism of the Staroe Boriskino C2 chondrite heated at 450°C in an inert atmosphere of helium flow was investigated. After being heated at 450°C during 160 minutes one specimen was moreover heated for 10 minutes at 500°C. The phase distribution was determined by means of Mössbauer spectroscopy, X-ray diffraction analysis, and electron probe microanalysis.The material changes rapidly (1–2 minutes). As a result of dehydration, the iron of the phyllosilicate is oxidized, the charge compensation being realized through the removal of iron and magnesium cations with the formation of magnetite and forsterite. Upon 10 minutes additional heating at 500°C iron appears in the olivine structure, the degree of iron oxidation declines, and magnetite disappears. Possible trends of change of C2 chondrite material are:

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Catalytic decarboxylations of fatty acids in immature oil source rocks

More attention has been paid to the formation conditions of petroleum and gas[1,2]. It is gen-erally accepted that various types of organic materials have served as the most important source of petroleum and gas in sediments. The formation of hydrocarbons…     

Paleomagnetism in deep-sea core A179-15

Core A179-15 from the southern North Atlantic exhibits one of the best paleoclimatic records for the last 25,000 years. This is because it is a high-sedimentation rate core and because it has been analysed at 1 cm intervals by Ericson and Wollin. The core has been used by Mörner for global climatic correlations. The magnetic measurements show a fairly drastic declination excursion at 12,350 B.P., i.e. exactly at the same age as the end of the Gothenburg Magnetic “Flip”. Therefore, the declination excursion in core A179-15 probably represents the end of the Gothenburg Magnetic “Flip” and Excursion. The excursion and a lithologic boundary verify the chronology earlier applied by Mörner.     

Characteristics of magnetic carriers responsible for Late Paleozoic remagnetization in carbonate strata of the mid-continent, U.S.A.

Magnetic analysis of carbonate strata of the mid-continent region of the United States indicates that the Late Paleozoic remagnetization already recognized in the Appalachians also affects almost the entire mid-continent. Magnetic intensity is regionally variable, with more intense magnetizations occurring on intracratonic arches. Magnetization is carried predominately by magnetite, which often occurs in tiny hollow spheroids composed of well formed octahedral microcrysts. Spheroid chemistry and morphology suggests that the magnetite is authigenic, composed of iron extracted from pre-existing pyrite or clay. The timing of the remagnetization, the character of the magnetite, and the regional variation in magnetic intensity support the idea that the remagnetization is a diagenetic consequence of tectonically-driven brine migration.     

Magnetic survey of topsoils in Windsor–Essex County, Canada

Windsor–Essex County is a major cross-border truck and transportation route, with significant localized industrialization as well as rural and farming areas. Magnetic property measurements (in-field and laboratory susceptibility, frequency-dependent susceptibility, hysteresis properties, thermomagnetic and thermosusceptibility curves, anhysteretic and isothermal magnetizations) were made in order to determine the potential for using such variables to distinguish between natural and anthropogenic pollutants. In-field magnetic susceptibility measured on 324 soil sampling sites on a 0.5–2 km grid spacing through Windsor–Essex County ranged from 3.7 × 10^− 6 to 305.2 × 10^− 6 SI (average 36.2 ± 35.8 × 10^− 6 SI), and showed that high magnetic susceptibility values were obtained on soil sampling sites in and around the cities/towns of Windsor, Harrow, Olinda and Oakland and near the beaches of Point Pelee National Park (PPNP) and Deerbrook, whereas lower susceptibility values were observed in near the towns of Lakeshore and Essex. On this grid spacing, Highway 401 (the major truck route) did not show anomalous susceptibility values; however, closer (1–3 m) sampling on other roads did show anomalously high values, suggesting that the coarser grid spacing may have missed anomalies. Laboratory measurements indicated that the dominant magnetic mineral in the Windsor–Essex County soils is magnetite; however, the grain size is variable. Pseudo-single domain (PSD)–multidomain (MD) magnetite is generally found on beaches and in PPNP, whereas single domain (SD)–PSD magnetite has been found near the City of Windsor and other towns. While certain correlations exist between some anthropogenic activities and the measured magnetic susceptibility and magnetic property values, no overall correlation can be made. A variety of geologic and anthropogenic factors must be considered when interpreting the origin of the magnetic signal in a particular area.     

Magnetic particles in indoor dust as marker of pollution emitted by different outside sources

The potential relation between outdoor pollutants and the quality of indoor air was evaluated. A case study was carried out in the small town of Zyrardow situated south-west of Warsaw, Poland. The indoor dust from 20 apartments from several parts of the town that are anticipated to be exposed to various levels of pollution was investigated: a mildly polluted area (suburban), a heating plant area, a post-industrial area and the city center. For evaluation of indoor dust several magnetic parameters (mass-specific magnetic susceptibility χ, its temperature dependence, anhysteretic remanent magnetization, hysteresis loop parameters) were applied. Analysis of magnetic properties was supplemented by analysis of chemical elements: Cd, Cu, Co, Cr, Fe, Mn, Ni, Pb and Zn. Depending on the location of apartments, large variations in concentration, mineralogy and grain-size of magnetic particles were detected. The thermomagnetic analysis revealed magnetite as a primary magnetic phase. In indoor dust, the Curie temperature of ~760°C and soft hysteresis loops with relatively low coercivity values of ~1.5-5 mT are an attribute of metallic iron. The dust collected from apartments located near the local heating plant area, in contaminated post-industrial and suburban areas contains mainly magnetite and only a small amount of metallic iron. Mass-specific magnetic susceptibility is in the range from 40 to 200 × 10^-8 m³kg^-1 and linearly correlates with concentration of individual heavy metals: Ni, Cr, Co and Zn. Magnetic fraction of dust from the city center mainly consists of magnetite and variable amounts of metallic iron. Magnetic susceptibility shows linear correlations with concentration of Fe and concentration of individual heavy metals (Zn, Ni and Co) considered as traffic-related. The study demonstrates that metallic iron present in indoor dust is a potential marker of trafficrelated sources and it makes it possible to use magnetic methods as a tool for evaluation of traffic-related impact on indoor air levels.     

南海北部陆区岩石磁化率的矿物学研究

基于2517套现场测量资料,245块岩石样品的体积磁化率测量和详细的岩矿鉴定及硅酸盐全分析结果,结合单矿物磁化率特征及各岩石之间的对比研究,发现岩石磁化率主要受组成岩石的矿物磁化率控制.即岩石磁化率(κr)与组成岩石各个矿物磁化率(κ1)及其体积含量(C2)成正比.例如侵入岩磁化率,κr=-5.68×102Cq+2.8...     

Magnetic survey of topsoils in Windsor–Essex County,Canada

Windsor–Essex County is a major cross-border truck and transportation route, with significant localized industrialization as well as rural and farming areas. Magnetic property measurements (in-field and laboratory susceptibility, frequency-dependent susceptibility, hysteresis properties, thermomagnetic and thermosusceptibility curves, anhysteretic and isothermal magnetizations) were made in order to determine the potential for using such variables to distinguish between natural and anthropogenic pollutants. In-field magnetic susceptibility measured on 324 soil sampling sites on a 0.5–2 km grid spacing through Windsor–Essex County ranged from 3.7 × 10^− 6 to 305.2 × 10^− 6 SI (average 36.2 ± 35.8 × 10^− 6 SI), and showed that high magnetic susceptibility values were obtained on soil sampling sites in and around the cities/towns of Windsor, Harrow, Olinda and Oakland and near the beaches of Point Pelee National Park (PPNP) and Deerbrook, whereas lower susceptibility values were observed in near the towns of Lakeshore and Essex. On this grid spacing, Highway 401 (the major truck route) did not show anomalous susceptibility values; however, closer (1–3 m) sampling on other roads did show anomalously high values, suggesting that the coarser grid spacing may have missed anomalies. Laboratory measurements indicated that the dominant magnetic mineral in the Windsor–Essex County soils is magnetite; however, the grain size is variable. Pseudo-single domain (PSD)–multidomain (MD) magnetite is generally found on beaches and in PPNP, whereas single domain (SD)–PSD magnetite has been found near the City of Windsor and other towns. While certain correlations exist between some anthropogenic activities and the measured magnetic susceptibility and magnetic property values, no overall correlation can be made. A variety of geologic and anthropogenic factors must be considered when interpreting the origin of the magnetic signal in a particular area.