热带太平洋第二类El Nio事件及其对中国气候的影响

基于热带太平洋次表层海温资料,分析了热带太平洋第二类El Nio事件海温异常的分布特征及其形成机制,讨论了与经典El Nio事件、El Nio Modoki、WP(西太平洋暖池)及CT(冷舌)El Nio事件之间的关系,揭示了第二类El Nio事件对中国降水的影响,得到以下结论。(1)第二类El Nio事件表征为热带太平洋次表层海温异常第三模态,占总方差贡献的4.7%。在海洋表面层,第二类El Nio事件暖期赤道东太平洋为沿赤道西伸的冷舌,热带中西太平洋为环绕冷舌的马蹄型大范围暖区。该型具11a和30~40a年代际振荡及3~4a年际变率,峰值多出现在春季。第二类El Nio事件是热带太平洋异常海面风应力场和赤道两侧的风应力旋度共同作用的结果,在赤道东印度洋-中西太平洋与赤道东太平洋-南美洲上空出现以反号垂直运动为特征的异常Walker环流。(2)El Nio Modoki与第二类El Nio事件有密切关系,它实质上是第二类El Nio事件次表层海温与近海面大气相互作用的结果,捕捉了第二类El Nio事件的主要信息。(3)第二类El Nio事件对中国春季及夏初降水有一定影响。在事件暖期,东海地区存在一个显著的异常反气旋性环流,其南侧的中国南方地区盛行异常东北气流,水汽来源减少,导致该地区少雨,其西侧的异常偏南气流北上直达华北地区,异常多水汽向北输送,并与北方的偏北流场相遇,导致该地区降水偏多。在第二类El Nio事件冷期相反。本文结果还指出,WP与CT El Nio事件是由经典El Nio事件第一模态与El Nio Modoki事件组合而成,它们不是独立的El Nio类型。此外,还讨论了夏半年El Nio事件对大气环流影响的物理过程。     

Impact of quasi-decadal variability in the tropical Pacific on ENSO modulations

The impact of quasi-decadal (QD: 8 to 18 years) variability in the tropical Pacific on ENSO events is investigated. It is found that there is a significant difference in the behavior of ENSO events between the phases of positive and negative anomalies of the QD Niño-3.4 index. During the period of negative QD-scale Niño-3.4 index, ENSO events, especially La Niña events, occur more frequently, and larger amplitudes of thermal anomalies related to El Niño events appear over the central to eastern equatorial Pacific. Furthermore, propagations of upper ocean heat content anomaly and a phase relationship between upper ocean heat content and Niño-3 index in the equatorial Pacific, which have been pointed out by previous studies, are clearly detected during the period of negative QD Niño-3.4 index.     

Anomalous eastward displacement of the tropical western Pacific warm pool and warming of the tropical eastern Pacific

INTRODUCTIONSincetheTOGA-COARElOP(October1992--March1993),usingthelOPdatamanyscientistshaveanalyzedthedifferenttimescaleair-seainteractionduringoccurringanddevelopingperiodof1992/1993EINifio,andespeciallyemphasizedtheintraseasonalvariation(Wuetal.,1993;Liu,1993;WuandSheng,1993).ThishasgottenanewunderstandingoftheEINino*ThisworkissupportedbytheNationalKeyProjectStudiesonShort-rangeClimatePredictionSysteminChinaundercontractNo.96--908-04-02--2.1.FirstinstituteofOceanography,S…     

ENSO indices from sea surface salinity observed by Aquarius and Argo

Analysis of the first 26 months of data from the Aquarius satellite confirms the existence of a sharp sea surface salinity (SSS) front along the equator in the western equatorial Pacific. Following several earlier studies, we use the longitudinal location of the 34.8-psu isohaline as an index, termed Niño-S34.8, to measure the zonal displacement of the SSS front and consequently the eastern edge of the western Pacific warm pool. The on-going collection of the Array for Real-time Geostrophic Oceanography (ARGO) program data shows high correlations between Niño-S34.8 and the existing indices of El Niño, suggesting its potential important role in ENSO evolution. Further analysis of the ARGO data reveals that SSS variability in the southeastern tropical Pacific is crucial to identify the type of El Niño. A new SSS index, termed the southeastern Pacific SSS index (SEPSI), is defined based on the SSS variability in the region (0°–10°S, 150°–90°W). The SEPSI is highly correlated with the El Niño Modoki index, as well as the Trans-Niño index, introduced by previous studies. It has large positive anomalies during central Pacific El Niño or El Niño Modoki events, as a result of enhanced zonal sea surface temperature gradients between the central and eastern tropical Pacific, and can be used to characterize the type of El Niño. The processes that possibly control these SSS indices are also discussed.     

Influence of Asian monsoon and ENSO events on particle fluxes in the western subtropical Pacific

A time-series sediment trap was deployed from October 2007 to May 2011 in the western subtropical Pacific with the aim of understanding the seasonal and inter-annual variability on particle flux in response to El Niño-Southern Oscillation (ENSO) events. Total mass fluxes varied from 3.04 mg m⁻² day⁻¹ to 31.1 mg m⁻² day⁻¹, with high fluxes during February–April and low fluxes during other months. This seasonal variation was also characterized by a distinct change in the CaCO₃ flux between the two periods. The marked increase in particle flux during February–April may be attributed to enhanced biological productivity in surface waters caused by strong wind-driven mixing in response to the western North Pacific monsoon system. The 2009/10 strong El Niño was accompanied by a significant reduction in particle flux, whereas the La Niña had no recognizable effect on particle flux in the subtropical Pacific. In particular, in the mature phase of the 2009/10 strong El Niño, the fluxes of organic carbon and biogenic silica decreased by 70–80% compared with those during the normal period, implying that the El Niño acted to suppress biological productivity in surface waters. The suppression of biological productivity during the 2009/10 strong El Niño is attributed to the decrease in precipitation due to the shift in the western Pacific warm pool. This finding is opposite that of other studies of the western equatorial Pacific, where El Niño events were observed to result in an increase in biological productivity and particle flux. The difference in particle flux between the western equatorial and subtropical Pacific is attributed to the regional differences in oceanic and atmospheric circulation systems generated by the strong El Niño.     

Analysis of the influence that climatic variability has on the formation of the total-ozone-content field at extratropical latitudes of the Northern Hemisphere

Having applied the method of discriminant analysis to the TOMS data of satellite sounding of the total ozone content (TOC) in the March months of 1979–2008, the authors could make a new estimate of the TOC field variability in the Northern Hemisphere and interlongitudinal regularities of its changes under the action of climatic variability. The effects of temperature variations in the polar stratosphere, El Niño, and quasi-biennial oscillation (QBO) have proven comparable and reach 80 DU in some regions. The influence of the Arctic Oscillation (AO) reaches 40 DU. The regions of TOC variations and their location and dimensions change depending on the phases of QBO, AO, and El Niño-Southern Oscillation (ENSO). Three regions of increased TOC—over Europe, Eastern Siberia, and the Pacific Ocean—are formed in years with a warm stratosphere. A compensating TOC decrease takes place in the tropics and over Greenland. In the years of El Niño and the easterly QBO phase, the TOC increases over Europe and drops over the central Pacific, as well as to the south from 45° N. The AO controls the ozone growth over most of Eurasia at temperate latitudes and its weak drop over the Atlantic. It was impossible to obtain such quantitative estimates with the use of methods based on an independent analysis of the TOC series at individual points of the coordinate grid. Testing with the Monte Carlo method confirmed that the results obtained are significant with a probability of 95–99.9%.     

两类El Niño不同衰减型的演变特征及其与我国夏季降水的联系

利用中国气象局743站日降水、NCEP-/NCAR大气环流、英国气象局Hadley中心全球月平均海表温度（SST）等资料,探讨了两类El Niño不同衰减型的演变特征及其对衰减阶段夏季（6-8月）我国降水异常分布的可能影响。根据海表温度异常（SSTA）沿赤道（5°S~5°N）的演变特征,EP-El Niño存在两种衰减型:自东向西（E-W）衰减（大于0.5℃的海温正距平首先在南美沿岸消失,并向西扩展）和自西向东（W-E）衰减（大于0.5℃的海温正距平首先在赤道中太平洋消失,并向东扩展）;CP-El Niño存在3种衰减方式:对称（S）衰减（赤道中太平洋暖海温的发展和衰减关于某一峰值对称）、延迟（P）衰减（衰减阶段紧接着呈现EP-El Niño分布）、突然（A）衰减（衰减阶段紧接着发生EP-La Niña事件）。对于EP-El Niño,在华北、华南、长江和黄河（简称两河）之间及两河的上游地区,E-W与W-E衰减阶段夏季降水呈现完全相反的异常分布特征。E-W衰减阶段夏季两河之间及上游地区偏旱的可能性显著增大,华北地区降水异常偏多,长江以南略偏多;而W-E衰减阶段夏季,两河之间及上游地区降水偏多,降水异常大值中心主要位于沿江地区,华南大部和华北地区降水明显偏少。对于CP-El Niño的3种衰减方式:夏季降水异常大值带在S衰减方式下主要位于黄河和淮河之间;在P方式衰减时,出现在长江流域;而在A型衰减时,主要位于黄河下游地区。S和A衰减方式下,东北大部尤其东北北部降水偏少,而处于P衰减时,东北大部降水明显偏多;在西南地区,S衰减时夏季降水总体偏多,A衰减时情况相反;在西北北部地区,A衰减时偏旱,而S和P衰减时降水总体偏多。不同的衰减方式均对应不同的降水异常空间分布,区分衰减型使得两类El Niño次年我国夏季降水异常显著区的分布范围和信号强度均较未区分衰减型时有较好的改善,为我国汛期降水短期气候预测工作提供了重要依据。     

Decadal modes of sea surface salinity and the water cycle in the tropical Pacific Ocean: The anomalous late 1990s

Limitations in sea surface salinity (SSS) observations and timescale separation methods have led to an incomplete picture of the mechanisms of SSS decadal variability in the tropical Pacific Ocean, where the El Niño Southern Oscillation (ENSO) dominates. Little is known regarding the roles of the North Pacific Gyre Oscillation (NPGO) and the Pacific Decadal Oscillation (PDO) in the large-scale SSS variability over the tropical basin. A self-organizing map (SOM) clustering analysis is performed on the intrinsic mode function (IMF) maps, which are decomposed from SSS and other hydrological fields by ensemble empirical mode decomposition (EEMD), to extract their asymmetric features on decadal timescales over the tropical Pacific. For SSS, an anomalous pattern appeared during 1997 to 2004, a period referred to as the anomalous late 1990s, when strong freshening prevailed in large areas over the southwestern basin and moderate salinization occurred in the western equatorial Pacific. During this period, the precipitation and surface currents were simultaneously subjected to anomalous fluctuations: the precipitation dipole and zonal current divergence along the equator coincided with the SSS increase in the far western equatorial Pacific, while the weak zonal current convergence in the southwestern basin and large-scale southward meridional currents tended to induce SSS decreases there. The dominant decadal modes of SSS and sea surface temperature (SST) in the tropical Pacific both resemble the NPGO but occur predominantly during the negative and positive NPGO phases, respectively. The similarities between the NPGO and Central Pacific ENSO (CP-ENSO) in their power spectra and associated spatial patterns in the tropics imply their dynamical links; the correspondence between the NPGO-like patterns during negative (positive) phases and the CP La Niña (CP El Niño) patterns for SSS is also discussed.     

Heat budget of the western Pacific warm pool and the contribution of eddy heat transport diagnosed from HYCOM assimilation

Using the high-resolution Hybrid Coordinate Ocean Model and the Navy Coupled Ocean Data Assimilation Global 1/12° Analysis (GLBa0.08), and the Objectively Analyzed Air–Sea Fluxes and the International Satellite Climatology Cloud Project products, we investigated the seasonal and interannual evolutions of heat budget, including the pseudo-heat content change, the net air–sea heat flux and the eddy heat transport (EHT), based on the time-dependent heat budget analysis in the western Pacific warm pool (WPWP). The results show that the pseudo-heat content change has significant semi-annual variation, which peaks in April–May and September. There is strong positive feedback between EHT and the net air–sea heat flux. EHT is important in balancing the sea surface heat flux into the WPWP. The seasonal EHT variability is dominated by its meridional component. On the interannual time scale, the zonal and vertical components of EHT show comparable amplitudes with the meridional one. The observed net air–sea heat flux in the WPWP is highly correlated with EHT and the pseudo-heat content change on the interannual time scale. The net air–sea heat flux leads the pseudo-heat content change by about half a month and leads EHT by about one month. The variations of the air–sea heat flux and EHT are connected to the El Niño Southern Oscillation events: during the development of El Niño (La Niña) events, the warm pool expanded eastward (retreated westward), the net air–sea surface flux into the WPWP increased (decreased) and EHT enhanced (weakened) significantly.     

On the warm/cold regime shift in the South China Sea: Observation and modeling study

Remote sensing data sets and a high-resolution three-dimensional regional ocean model were utilized to investigate the shifting of warm/cold regime and the associated sea level variation in the South China Sea (SCS) during 2000–2003. Both the altimetry data and the model results showed an increase in the sea level (warm phase) followed by an abrupt decrease (cold phase) in the SCS during 2000–2003. Heat budget calculations performed with the model revealed excess heat advection from the western Pacific warm pool into the SCS during the warm phase than the cold phase. The warm phase, which occurred during La Niña episodes, resulted from the intrusion of abnormally warmer western Pacific water that increased the heat content and thus sea level in the SCS. The cold phase, which occurred during El Niño episodes, was triggered by a reduction in the net atmospheric heat flux followed by cold water advection into the SCS. Decrease in the rate of precipitation minus evaporation (P?E) also accounted for the falling of sea level during cold phase. The present study integrated the available remote sensing data and advanced numerical model to identify the time-dependent three-dimensional dynamic and thermodynamic forcing that are important in governing the warm/cold regime shift in the SCS.     

Coastal upwelling along the north coast of Papua New Guinea and SST cooling over the pacific warm pool: A case study for the 2002/03 El Niño event

We investigate an overlooked mechanism—coastal upwelling—for sea surface temperature (SST) cooling in the western side of the mean location of the Pacific warm pool (WSWP: 5°S–5°N, 140°E–150°E) prior to El Niño onset. We analyze various observed data such as the TRIangle Trans-Ocean buoy Network (TRITON) moored buoy data, Conductivity-Temperature-Depth (CTD) data, satellite data and a hindcast experiment output by a high-resolution ocean general circulation model (OGCM). We focus on the precondition of the 2002/03 El Niño event, for which many datasets are available. Relatively cool water upwelled along the north coast of Papua New Guinea (PNG) during December 2001, prior to the onset of the 2002/03 El Niño event, and then spread out over a wider area to the northeast. Simultaneously, strong west-northerly surface winds occur along the north coast. Heat budget analysis of TRITON buoy data in the WSWP reveals that negative zonal heat advection due to eastward current is the main factor for cooling the mixed layer in the WSWP in contrast to the warming effect of the surface heat flux during the period. This cooling requires a source of colder water to the west. Similar analysis of OGCM outputs also suggests that the upwelled relatively cool water along the PNG north coast, and its northeastward extension to the equatorial region, contributes to cooling of the surface water over the WSWP mainly via negative zonal heat advection. Similar mechanisms are confirmed also for the 1982/83 and 1997/98 El Niño events by analyses of OGCM outputs and historical SST data. The low SST in the WSWP generated a positive zonal SST gradient together with high SST east of the WSWP. It may contribute to enhancement of the westerly surface wind in this region, leading to the onset of the 2002/03 El Niño event.     

Climatic variability in the vicinity of Wallis,Futuna, and Samoa islands (13°–15° S, 180°–170° W)

Mean conditions, seasonal, and ENSO-related (El Niño Southern Oscillation) variability in the vicinity of Wallis, Futuna, and Samoa islands (13°–15° S, 180°–170° W) over the 1973–1995 period are analysed for wind pseudo-stress, satellite-derived and in situ precipitation, sea surface temperature (SST) and salinity (SSS), sea level, and 0–450 m temperature and geostrophic current. The mean local conditions reflect the presence of the large scale features such as the western Pacific warm pool, the South Pacific Convergence Zone (SPCZ), and the South Pacific anticyclonic gyre. The seasonal changes are closely related to the meridional migrations of the SPCZ, which passes twice a year over the region of study. During the warm phase of ENSO (El Niño), we generally observe saltier-than-average SSS (of the order of 0.4), consistent with a rainfall deficit (0.4 m yr⁻¹), a hint of colder-than-average surface temperature is also identified in subsurface (0.3°C), a weak tendency for westward geostrophic current anomalies (2 cm s⁻¹ at the surface), a sea level decrease (5–10 cm), together with easterly (5 m²s⁻²) and well marked southerly (10 m²s⁻²) wind pseudo-stress anomalies. Anomalies of similar magnitude, but of opposite sign, are detected during the cold phase of ENSO (La Niña). While these ENSO-related changes apply prior to the 1990s, they were not observed during the 1991–1994 period, which appears atypical.     

The different relationship of Pacific interior subtropical cells and two types of ENSO

The Pacific interior subtropical?tropical cells (STCs) and their relation to the two types of El Niño-Southern Oscillation (ENSO) are investigated by using GODAS reanalysis ocean data for the period of 1980–2017. The results show that the interior STC transport into the equatorial region across 9°S and 9°N has a close relationship with the eastern Pacific (EP) ENSO, while it is much weaker with the central Pacific (CP) ENSO. It is suggested that the effect of interior STCs on the tropical Pacific climate is reflected in its relation with the western Pacific thermocline depth or SSHA. During the EP El Niño, the anomalous interior STCs at 9°S and 9°N converge to the equatorial region from the lag months of ? 25 to ? 8, leading to an accumulation of heat content in the equatorial Pacific; from the lag months of ? 8 to 10, they diverge poleward, inducing a discharge of equatorial heat content. The peak poleward interior STC anomaly first appears at 9°N at a zero-lag time, while that at 9°S is observed 4–5 months later. But there is also no appearance of a time lag between the interior STCs at 9°N and 9°S in recharging the period during the EP La Niña mature phase. However, during CP El Niño, only the conspicuous anomalous interior STC divergence appears during the mature and decay phases for the lag months of ? 2 to 10, with being symmetric at 9°N and 9°S.     

Trends of sea surface temperature and sea surface temperature fronts in the South China Sea during 2003–2017

The trends of the sea surface temperature(SST) and SST fronts in the South China Sea(SCS) are analyzed during2003–2017 using high-resolution satellite data. The linear trend of the basin averaged SST is 0.31°C per decade,with the strongest warming identified in southeastern Vietnam. Although the rate of warming is comparable in summer and winter for the entire basin, the corresponding spatial patterns of the linear trend are substantially different between them. The SST trend to the west of the Luzon Strait is characterized by rapid warming in summer, exceeding approximately 0.6°C per decade, but the trend is insignificant in winter. The strongest warming trend occurs in the southeast of Vietnam in winter, with much less pronounced warming in summer. A positive trend of SST fronts is identified for the coast of China and is associated with increasing wind stress. The increasing trend of SST fronts is also found in the east of Vietnam. Large-scale circulation, such as El Ni?o, can influence the trends of the SST and SST fronts. A significant correlation is found between the SST anomaly and Ni?o3.4 index, and the ENSO signal leads by eight months. The basin averaged SST linear trends increase after the El Ni?o event(2009–2010), which is, at least, due to the rapid warming rate causing by the enhanced northeasterly wind. Peaks of positive anomalous SST and negatively anomalous SST fronts are found to co-occur with the strong El Ni?o events.     

Spatial classification of La Niña events

Thirty La Niña events have been selected from monthly mean sea surface temperature (SST) data of the Hadley Centre Global Sea Ice and Sea Surface Temperature (HadISST) and Centennial Observation-Based Estimates (COBE SST2) datasets from 1870 to 2013 based on a criterion of –0.5°С for a cold anomaly in the Niño 3.4 region (5° N–5° S, 170°–120° W) and its minimum duration of 5 months. The selected events are classified by hierarchical clustering analysis according to two characteristics: geographic coordinates and SST anomalies during the mature phase of La Niña. The objective classification method identifies two types of La Niña differing by the evolution of negative SST anomalies in the equatorial Pacific and by the Southern Oscillation Index.     

Oceanic Rossby waves induced by the meridional shift of the ITCZ in association with ENSO events

This study investigated the eastern Pacific Intertropical Convergence Zone (ITCZ) as an atmospheric forcing to the ocean by using various observed and reanalysis data sets over 29 years. Climatologically, a zonal band of positive wind stress curl (WSC) with a 10° meridional width was exhibited along the ITCZ. A southward shift of the positive WSC band during the El Niño phase induced a negative (positive) WSC anomaly along the northern (southern) portion of the ITCZ, and vice versa during the La Niña phase. This meridional dipole accounted for more than 25 % of interannual variances of the WSC anomalies (WSCAs), based on analysis of the period 1993–2008. The negative (positive) WSCA in the northern portion of the ITCZ during the El Niño (La Niña) phase was collocated with a positive (negative) sea surface height anomaly (SSHA) that propagated westward as a Rossby wave all the way to the western North Pacific. This finding indicates that this off-equatorial Rossby wave is induced by the WSCA around the ITCZ. Our analysis of a 1.5-layer reduced gravity model revealed that the Rossby waves are mostly explained by wind stress forcing, rather than by reflection of an equatorial Kelvin wave on the eastern coastal boundary. The off-equatorial Rossby wave had the same SSHA polarity as the equatorial Kelvin wave, and generation of a phase-preserving Rossby wave without the Kelvin wave reflection was explained by meridional movement of the ITCZ. Thus, the ITCZ acts as an atmospheric bridge that connects the equatorial and off-equatorial oceanic waves.     

Analysis of the cause and effect relationships between El Niño in the Pacific and its analog in the equatorial Atlantic

The relations between the processes occurring in the equatorial latitudes of the Pacific and Atlantic oceans were studied on the basis of the Granger causality analysis and a simulation of phase dynamics using the indices of the El Niño-Southern Oscillation (ENSO) and the equatorial Atlantic mode (EAM). Data on the monthly means of the sea-surface temperature over the period 1870–2006 for the Niño 3 (5° S-5° N, 150° W-90° W) and Niño 3.4 (5° S-5° N, 170° W-120° W) regions in the Pacific and the Atlantic 3 region (20° W-0, 3° S-3° N) in the Atlantic Ocean were used as the ENSO and EAM indices. The statistically significant influence of the EAM on the ENSO is noted. The lag time of this influence is estimated at two months. No significant reverse effect is revealed. An increase in the EAM’s influence on the ENSO was observed in the second half of the 20th century.     

热带太平洋海平面低频变化

本文选取ECMWF ORAS4再分析数据对1959-2015年热带太平洋海平面的低频变化进行了分析。热带太平洋海平面年际变化第一模态反映了ENSO爆发阶段的海平面变化,热带东、西太平洋变化反相,其时间序列与Niño3.4指数高度相关。海平面第二模态则体现了El Niño爆发前后热带太平洋暖水的输运过程。El Niño爆发前热带西太平洋暖水聚集的位置,以及爆发后暖水向赤道外输运的位置在两类El Niño事件中均有所不同。此外,ENSO的周期在近半个世纪发生了显著的年代际变化,这一变化与热带太平洋的年代际变化有关。热带太平洋的年代际变化对海平面趋势变化也有着显著的影响。卫星高度计观测到的近20年海平面的快速上升（下降）正是由20世纪90年代后热带太平洋频繁的位相转换引起的。     

ENSO-induced interannual variability in the southeastern South China Sea

In this study, El Niño Southern Oscillation (ENSO)-induced interannual variability in the South China Sea (SCS) is documented using outputs from an eddy-resolving data-assimilating model. It is suggested that during an El Niño (La Niña) event, off-equatorial upwelling (downwelling) Rossby waves induced by Pacific equatorial wind anomalies impinge on the Philippine Islands and excite upwelling (downwelling) coastal Kelvin waves that propagate northward along the west coast of the Philippines after entering the SCS through the Mindoro Strait. The coastal Kelvin waves may then induce negative (positive) sea level anomalies in the southeastern SCS and larger (smaller) volume transport through the Mindoro and Luzon Straits during an El Niño (La Niña) event.     

El Niño/Southern Oscillation (ENSO) Related Variations in Particulate Export Fluxes in the Western and Central Equatorial Pacific

Time-series data from sediment trap moorings intermittently deployed during 1991–1999 show that the fluxes of biogenic material (carbonate, opal and organic matter, including amino acids) and other related parameters are temporally and spatially distinct across the Western Pacific Warm Pool (WPWP). These variations resulted from the El Niño and La Niña conditions, which alternately prevailed over the equatorial Pacific Ocean during the mooring deployments. The westernmost WPWP (a hemipelagic region) recorded relatively high average total mass and amino acid fluxes during the El Niño event. This was in sharp contrast to the eastern part of the WPWP (oligotrophic and weak upwelling regions) which recorded higher flux values during the La Niña event. Settling particulate organic matter was rich in labile components (amino acids) during La Niña throughout the study area. Relative molar ratios of aspartic acid to β-alanine together with relative molar content of non-protein amino acids β-alanine and γ-aminobutyric acid) suggested that organic matter degradation was more intense during La Niña relative to that during El Niño in the WPWP. This study clearly shows that during an El Niño event the well documented decrease in export flux in the easternmost equatorial Pacific is accompanied by a significant increase in export flux in the westernmost equatorial Pacific Ocean.