The Littorina transgression in the southwestern Baltic Sea: new insights based on proxy methods and radiocarbon dating of sediment cores

Rößler, D., Moros, M. & Lemke, W. 2010: The Littorina transgression in the southwestern Baltic Sea: new insights based on proxy methods and radiocarbon dating of sediment cores. Boreas, 10.1111/j.1502‐3885.2010.00180.x. ISSN 0300‐9483. The Littorina transgression is one of the most pronounced environmental events in the Holocene history of the Baltic Sea. It changed the hydrographic system from the freshwater Ancylus Lake into the brackish‐marine Littorina Sea. Here, 18 cores from two western Baltic basins, Mecklenburg Bay and the Arkona Basin, were analysed. We show that, besides biological indicators, sedimentary organic carbon, C/N ratio, bulk δ¹³C isotope values and carbonate content display clearly the transition from Ancylus Lake to the Littorina Sea. The first appearances of benthic foraminifers, marine molluscs and ostracods represent the onset of brackish‐marine conditions in the bottom waters. Central Arkona Basin sediments display more abrupt shifts in geochemical parameters and microfossil records at the transition from Ancylus Lake to the Littorina Sea than those from Mecklenburg Bay. Mixing of reworked Ancylus material with Littorina Sea stage material was stronger in Mecklenburg Bay, resulting in less pronounced proxy parameter changes and older bulk material dates. Radiocarbon dating of both calcareous material (benthic foraminifers, mollusc shells) and bulk fractions at the transgression horizon shows large age discrepancies. Based on calcareous fossil dates it appears that marine waters began to enter Mecklenburg Bay c. 8000 cal. a BP. In the Arkona Basin the first marine signals are recorded approximately 800 years later, c. 7200 cal. a BP. This indicates a transgression pathway via the Great Belt into Mecklenburg Bay and then into the Arkona Basin.     

New insights into Holocene atmospheric circulation dynamics in central Scandinavia inferred from oxygen‐isotope records of lake‐sediment cellulose

St. Amour, N. A., Hammarlund, D., Edwards, T. W. D. & Wolfe, B. B. 2010: New insights into Holocene atmospheric circulation dynamics in central Scandinavia inferred from oxygen‐isotope records of lake‐sediment cellulose. Boreas, Vol. 39, pp. 770–782. 10.1111/j.1502‐3885.2010.00169.x. ISSN 0300‐9843 Cellulose‐inferred lakewater oxygen‐isotope records have been obtained from two hydrologically open basins (Lake Spåime and Lake Svartkälstjärn), located on a west–east transect across central Sweden, to investigate changes in atmospheric circulation patterns during the Holocene. The Lake Spåime δ¹⁸O record is sensitive to changes in the seasonal distribution of precipitation in the Scandes Mountains of west‐central Sweden, and thus generally portrays variations in δ¹⁸O of precipitation (δ¹⁸O_P) that are governed predominantly by the influence of air masses originating from the North Atlantic. In contrast, the Lake Svartkälstjärn δ¹⁸O record appears to reflect the varying influence of air masses delivering moisture from the North Atlantic and the Baltic Sea. A comparison of inferred changes in δ¹⁸O_P over the Holocene between the two sites reveals systematic patterns of variability over widely different time scales. These include: (1) a previously recognized long‐term regional decline in δ¹⁸O_P, possibly in response to the declining vigour of Northern Hemisphere atmospheric circulation related to decreasing summer solar insolation; (2) newly identified inverse centennial‐ to millennial‐scale δ¹⁸O_P fluctuations at the two sites that may be linked to changes in modes of atmospheric circulation analogous to those described at interannual to multidecadal time scales by the North Atlantic Oscillation (NAO) index; and (3) a prolonged interval of apparent climatic stability in the mid‐Holocene (c. 6300–4200 cal. yr BP) characterized by persistently negative NAO‐like circulation.     

A chronology of environmental changes in the Lake Vättern basin from deglaciation to its final isolation

During and after deglaciation, Lake Vättern developed from a proglacial lake situated at the westernmost rim of the Baltic Ice Lake (BIL), into a brackish water body connecting the North Sea and the Baltic Sea, and finally into an isolated freshwater lake. Here we present geochemical and mineralogical data from a 70‐m composite sediment core recovered in southern Lake Vättern. Together with a radiocarbon age model of this core, we are able to delineate the character and timing of the different lake stages. In addition to a common mineralogical background signature seen throughout the sediment core, the proglacial sediments bear a calcite imprint representing ice‐sheet transported material from the limestone bedrock that borders the lake basin in the northeast. The proglacial fresh to brackish water transition is dated to 11 480±290 cal. a BP and is in close agreement with other regional chronologies. The brackish period lasted c. 300 years and was followed by a c. 1600 year freshwater period before the Vättern basin became isolated from the Initial Littorina Sea. Decreasing detrital input, increasing δ¹³C values and the appearance of diatoms in the upper 15 m of the sediment succession are interpreted as an overall increase in biological productivity. This mode of sedimentation continues until the present and is interpreted to mark the final isolation of the lake at 9530±50 cal. a BP. Consequently, the isolation of Lake Vättern was not an outcome of the Ancylus Lake regression, but rather because of ongoing continental uplift in the early Littorina period.     

Early diagenetic processes during Mn-carbonate formation: evidence from the isotopic composition of authigenic Ca-rhodochrosites of the Baltic Sea

The formation of authigenic Ca-rich rhodochrosite (ACR) in sapropelic sediments of the Gotland Basin, Baltic Sea, is governed by deepwater renewal processes whereby saline water from the North Atlantic flushes the brackish anoxic Baltic Deeps. The carbon and oxygen isotopic compositions of these Mn-carbonates suggest that ACR formation takes place just below the sediment surface and that dissolved compounds from the deepwater column, such as water and bicarbonate molecules, were incorporated in ACR during authigenesis. Porewaters near the sediment surface display δ¹⁸O values of −5.4‰ (VSMOW) and are generally depleted in ¹⁸O, compared to the oxygen isotopic composition of water in equilibrium with Mn-carbonate solid solutions (ACR δ¹⁸O values are −4.6‰). This suggests that early burial diagenetic processes significantly modify the initial isotopic composition of water during Mn-carbonate formation. The reduction of sulfate having δ¹⁸O values of +8.4‰ accounts for a permanent enrichment of porewater ¹⁸O and observed δ¹⁸O values at depth equal to −4.6‰. However, this process does not explain the observed disequilibrium in the oxygen isotopic composition between water and ACR close to the sediment surface where Mn-carbonate formation takes place. Based on isotopic mass balance calculations, we suggest that MnO₂ with δ¹⁸O values of +8.9‰ released oxygen enriched in ¹⁸O into the anoxic porewaters close below the sediment surface. This process should occur after oxygenation events during deepwater renewal when MnO₂ accumulates at the surface of anoxic sediments. Manganese carbonates formed in these waters display δ¹⁸O values of ∼1.0‰ heavier than values expected solely from the initial deepwater composition. This quantitatively explains the discrepancy between paleosalinities calculated from ACR δ¹⁸O based on Mn-carbonate/water isotopic equilibrium fractionation and direct observations for the same period. Our results emphasize the important role of microbial MnO₂ reduction during rhodochrosite authigenesis and suggest that Mn(II) activity, rather than alkalinity, is the limiting component for sedimentary Mn-carbonate formation.     

Ostracods (Crustacea) and their palaeoenvironmental implication for the Solimões Formation (Late Miocene; Western Amazonia/Brazil)

Western Amazonia's landscape and biota were shaped by an enormous wetland during the Miocene epoch. Among the most discussed topics of this ecosystem range the question on the transitory influx of marine waters. Inter alia the occurrence of typically brackish water associated ostracods is repeatedly consulted to infer elevated salinities or even marine ingressions. The taxonomical investigation of ostracod faunas derived from the upper part of the Solimões Formation (Eirunepé; W-Brazil) documents a moderately diverse assemblage (19 species). A wealth of freshwater ostracods (mainly Cytheridella, Penthesilenula) was found co-occurring with taxa (chiefly Cyprideis) usually related to marginal marine settings today. The observed faunal compositions as well as constantly very light δ¹⁸O- and δ¹³C-values obtained by measuring both, the freshwater and brackish water ostracod group, refer to entirely freshwater conditions. These results corroborate with previous sedimentological and palaeontological observations, which proposed a fluvial depositional system for this part of western Amazonia during the Late Miocene. We demonstrate that some endemic, “brackish” water ostracods (i.e., Cyprideis) have been effectively adapted to freshwater conditions. Thus, their occurrence is no univocal evidence for the influence of brackish or marine waters in western Amazonia during the Miocene.     

Neoglacial transition of atmospheric circulation patterns over Fennoscandia recorded in Holocene Lake Torneträsk sediments

Atmospheric circulation over the North Atlantic has undergone significant fluctuations during the Holocene. To better constrain these changes and their impacts on the Fennoscandian subarctic, we investigated molecular and inorganic proxies as well as plant wax D/H isotopes (δD_C28) in a Holocene sedimentary record from Lake Torneträsk (Sweden). These data indicate a thermal maximum c. 8100 to 6300 cal. a BP with reduced soil organic matter input, followed by a long‐term cooling trend with increasing soil erosion. δD data suggest a stable atmospheric circulation with predominance of westerly flow and North Atlantic moisture sourcing during the Early and Middle Holocene. A substantial depletion in δD followed by increased flood frequency starting at c. 5300 cal. a BP and intensifying c. 1500 cal. a BP suggests a reorganization of the atmospheric circulation from zonal towards meridional flow with predominantly Arctic Ocean and Baltic Sea moisture sourcing.     

Middle and late Cenomanian oceanic anoxic events in shallow and deeper shelf environments of western Morocco

The response of shallow‐water sequences to oceanic anoxic event 2 and mid‐Cenomanian events 1a and 1b was investigated along the west African margin of Morocco north of Agadir (Azazoul) and correlated with the deep‐water sequence of the Tarfaya Basin (Mohammed Beach) based on biostratigraphy, mineralogy, phosphorus and stable isotopes. In the deeper Mohammed Beach section results show double peaks in δ¹³C_org for mid‐Cenomanian events 1a and 1b (Rotalipora reicheli biozone, lower CC10a biozone), the characteristic oceanic anoxic event 2 δ¹³C excursion (Rotalipora cushmani extinction, top of CC10a biozone) and laminated (anoxic) black shale. In the shallow environment north of Agadir, a fluctuating sea‐level associated with dysoxic, brackish and mesotrophic conditions prevailed during the middle to late Cenomanian, as indicated by oyster biostromes, nannofossils, planktonic and benthonic foraminiferal assemblages. Anoxic conditions characteristic of oceanic anoxic event 2 (for example, laminated black shales) did not reach into shallow‐water environments until the maximum transgression of the early Turonian. Climate conditions decoupled along the western margin of Morocco between mid‐Cenomanian event 1b and the Cenomanian–Turonian boundary, as also observed in eastern Tethys. North of Agadir alternating humid and dry seasonal conditions prevailed, whereas in the Tarfaya Basin the climate was dry and seasonal. This climatic decoupling can be attributed to variations in the Intertropical Convergence Zone and in the intensity of the north‐east trade winds in tropical areas.     

MIS 3 marine and lacustrine sediments at Kriegers Flak,southwestern Baltic Sea

Anjar, J., Larsen, N. K., Björck, S., Adrielsson, L. & Filipsson, H. L. 2010: MIS 3 marine and lacustrine sediments at Kriegers Flak, southwestern Baltic Sea. Boreas, 10.1111/j.1502‐3885.2010.00139.x. ISSN 0300‐9483. Sediment cores from the Kriegers Flak area in the southwestern Baltic Sea show a distinct lithological succession, starting with a lower diamict that is overlain by a c. 10 m thick clay unit that contains peat, gyttja and other organic remains. On top follows an upper diamict that is inter‐layered with sorted sediments and overlain by an upward‐coarsening sequence with molluscs. In this paper we focus on the clay unit, which has been subdivided into three subunits: (A) lower clay with benthic foraminifera and with diamict beds in the lower part; (B) thin beds of gyttja and peat, which have been radiocarbon‐dated to 31–35 ¹⁴C kyr BP (c. 36–41 cal. kyr BP); and (C) upper clay unit. Based on the preliminary results we suggest the following depositional model: fine‐grained sediments interbedded with diamict in the lower part (subunit A) were deposited in a brackish basin during a retreat of the Scandinavian Ice Sheet, probably during the Middle Weichselian. Around 40 kyr BP the area turned into a wetland with small ponds (subunit B). A transgression, possibly caused by the damming of the Baltic Basin during the Kattegat advance at 29 kyr BP, led to the deposition of massive clay (subunit C). The data presented here provide new information about the paleoenvironmental changes occurring in the Baltic Basin following the Middle Weichselian glaciation.     

Early Last Interglacial palaeoenvironments in the western Baltic Sea: benthic foraminiferal stable isotopes and diatom‐based sea‐surface salinity

Knudsen, K. L., Jiang, H., Kristensen, P., Gibbard, P. L. & Haila, H. 2011: Early Last Interglacial palaeoenvironments in the western Baltic Sea: benthic foraminiferal stable isotopes and diatom‐based sea‐surface salinity. Boreas, 10.1111/j.1502‐3885.2011.00206.x. ISSN 0300‐9483. Stable isotopes from benthic foraminifera, combined with diatom assemblage analysis and diatom‐based sea‐surface salinity reconstructions, are used for the interpretation of changes in bottom‐ and surface‐water conditions through the early Eemian at Ristinge Klint in the western Baltic Sea. Correlation of the sediments with the Eemian Stage is based on a previously published pollen analysis that indicates that they represent pollen zones E2–E5 and span ～3400 years. An initial brackish‐water phase, initiated c. 300 years after the beginning of the interglacial, is characterized by a rapid increase in sea‐surface and sea‐bottom salinity, followed by a major increase at c. 650 years, which is related to the opening of the Danish Straits to the western Baltic. The diatoms allow estimation of the maximum sea‐surface salinity in the time interval of c. 650–1250 years. After that, slightly reduced salinity is estimated for the interval of c. 1250–2600 years (with minimum values at c. 1600–2200 years). This may be related to a period of high precipitation/humidity and thus increased freshwater run‐off from land. Together with a continuous increase in the water depth, this may have contributed to the gradual development of a stratified water column after c. 1600 years. The stratification was, however, particularly pronounced between c. 2600 and 3400 years, a period with particularly high sea‐surface temperature, as well as bottom‐water salinity, and thus a maximum influence of Atlantic water masses. The freshwater run‐off from land may have been reduced as a result of particularly high summer temperatures during the climatic optimum.     

Late Holocene Baltic Sea outflow changes reconstructed using C37:4 content from marine cores

The Baltic Sea is an intra‐continental brackish water body. Low saline surface water, the so‐called Baltic outflow current, exits the Baltic Sea through the Kattegat into the Skagerrak. Ingressions of saline oxygen‐rich bottom water enter the Baltic Sea basins via the narrow and shallow Kattegat and are of great importance for the ecological and ventilation state of the Baltic Sea. Over recent decades, progress has been made in studying Holocene changes in saline water inflow. However, reconstructions of past variations in Baltic Sea outflow changes are sparse and hampered because of the lack of suitable proxies. Here, we used the relative proportion of tetra‐unsaturated C₃₇ ketones (C_37:4 %) in long‐chain alkenones produced by coccolithophorids as a proxy for outflowing Baltic Sea water in the Skagerrak. To evaluate the applicability of the proxy, we compared the biomarker results with grain‐size records from the Kattegat and Mecklenburg Bay in addition to previously published salinity reconstructions from the Kattegat over the last 5000 years. All Skagerrak records showed an increase in C_37:4 % that is accompanied by enhanced bottom water currents in the Kattegat and western Baltic Sea over the past 3500 cal. a BP, indicating an increase in Baltic Sea outflow. This probably reflects higher precipitation in the Baltic Sea catchment area owing to a re‐organization of North Atlantic atmospheric circulation with an increased influence of wintertime Westerlies over the Baltic catchment from the mid‐ to the late Holocene.     

A regional 8200 cal. yr BP cooling event in northwest Europe,induced by final stages of the Laurentide ice-sheet deglaciation?

The most notable change in δ¹⁸O in Greenland ice cores during the Holocene occurs at 8200 cal. yr BP. Here we present a new high-resolution marine record from the northern North Sea, along with tree-ring data from Germany, which contain evidence of a pronounced temperature drop (>2°C) contemporaneous with that of the Greenland ice-core records. The synchronous timing of the cooling event in the Greenland ice-cores, marine record and tree-ring data from northwest Europe reflects a regional influence on the North Atlantic ocean–atmospheric system, suggesting a prominent role of the North Atlantic thermohaline circulation. The operation of the North Atlantic ocean circulation is sensitive to variation in the freshwater budget, implying that any change in freshwater flux is capable of altering the North Atlantic circulation system. We hypothesise minor but long-term freshwater fluxes in the final stages of the deglaciation of the Laurentide ice-sheet as a forcing mechanism. © 1998 John Wiley & Sons, Ltd.     

Synopsis of strontium isotope variations in groundwater at Äspö, southern Sweden

Strontium isotope ratios are used to identify end-member ground-water compositions at Äspö in southeastern Sweden where the Hard Rock Laboratory (HRL) has been constructed to evaluate the suitability of crystalline rock for the geologic disposal of nuclear waste. The Hard Rock Laboratory is a decline (tunnel) constructed in 1.8 Ga-old granitic rock that forms islands in an archipelago along the Swedish coast. Ground-water samples were obtained for isotopic analyses from boreholes drilled from the surface and from side boreholes drilled within the HRL. Infiltration at Äspö occurs primarily through fractures zones in the granitic bedrock beneath thin soils throughout the area. Because of extremely low Sr concentrations, rain and snow are not important contributors to the Sr isotope budget of the ground-water system. At shallow levels, water percolating downward along fractures and fracture zones acquires a δ⁸⁷Sr between +9.5 and +10.0‰ and maintains this value downward while Sr concentrations increase by two orders of magnitude. Ground-water samples from both boreholes and from in the HRL show the effects of mixing with saline waters containing as much as 59 mg/L Sr and δ⁸⁷Sr values as large as +13.9‰. Baltic Sea water is a potential component of the groundwater system with δ⁸⁷Sr values only slightly larger than modern marine values (+0.3‰) but with much lower concentrations (1.5 mg/L) than ocean water (8 mg/L). However, because of large Sr concentration differences between the saline groundwater (59 mg/L) and Baltic Sea water (1.5 mg/L), δ⁸⁷Sr values are not particularly sensitive indicators of sea-water intrusion even though their δ⁸⁷Sr values differ substantially.     

Changes in the inflow of saline water into the Bornholm Basin (SW Baltic Sea) during the past 7100 years – evidence from benthic foraminifera record

The Baltic Sea (~393 000 km²) is the largest brackish sea in the world and its hydrographic and environmental conditions are strongly dependent on the frequency of saline water inflows from the North Sea. To improve our understanding of the natural variability of the Baltic Sea ecosystem detailed reconstructions of past saline water inflow changes based on palaeoecological archives are needed. Here we present a high‐resolution study of benthic foraminiferal assemblages accompanied by sediment geochemistry (loss on ignition, total organic carbon) and other microfossil data (ostracods and cladocerans) from a well‐dated 8‐m‐long gravity core taken in the Bornholm Basin. The foraminiferal diversity in the core is low and dominated by species of Elphidium. The benthic foraminiferal faunas in the central Baltic require oxic bottom water conditions and salinities >11–12 PSU. Consequently, shell abundance peaks in the record reflect frequent saline water inflow phases. The first appearance of foraminiferal tests and ostracods in the investigated sediment core is dated to c. 6.9 cal. ka BP and attributed to the first inflows of saline and oxygenated bottom waters into the Bornholm Basin during the Littorina Sea transgression. The transgression terminated the Ancylus Lake phase, reflected in the studied record by abundant cladocerans. High absolute foraminiferal abundances are found within two time intervals: (i) c. 5.5–4.0 cal. ka BP (Holocene Thermal Maximum) and (ii) c. 1.3–0.75 cal. ka BP (Medieval Climate Anomaly). Our data also show three intervals of absent or low saline water inflows: (i) c. 6.5–6.0 cal. ka BP, (ii) c. 3.0–2.3 cal. ka BP and (iii) c. 0.5–0.1 cal. ka BP (Little Ice Age). Our study demonstrates a strong effect of saline and well‐oxygenated water inflows from the Atlantic Ocean on the Baltic Sea ecosystem over millennial time scales, which is linked to the major climate transitions over the last 7 ka.     

Circulation of water masses in the Baltic Proper revealed through iodine isotopes

Tracer technology has been used to understand water circulation in marine systems where the tracer dose is commonly injected into the marine waters through controlled experiments, accidental releases or waste discharges. Anthropogenic discharges of ¹²⁹I have been used to trace water circulation in the Arctic and North Atlantic Ocean. Here, ¹²⁹I, together with ¹²⁷I, is utilized as a tracer of water pathways and circulation in the Baltic Sea through collection of seawater depth profiles. The results indicate the presence of ¹²⁹I signatures which are distinct for each water mass and provide evidence for: (1) inflow water masses through the Drogden Sill that may reach as far as the SW of the Arkona Sea, (2) a portion of North Atlantic water in the bottom of Arkona basin, (3) cyclonic upwelling which breaks through the halocline in a pattern similar to the Baltic haline conveyor belt and (4) more influx of fresher water from the Gulf of Finland and Bothnian Sea in August relative to April. These findings provide advances in labeling and understanding water pathways in the Baltic Sea.     

Recrystallization of dolomite: evidence from the Monterey Formation (Miocene), California

Dolomites from the upper calcareous-siliceous member of the Miocene Monterey Formation exposed west of Santa Barbara, California, were analysed for geochemical, isotopic and crystallographic variation. The data clearly document the progressive recrystallization of dolomite during burial diagenesis in marine pore fluids. Recrystallization is recognized by the following compositional and crystallographic variations. Dolomites have decreasing δ¹⁸O and δ¹³C compositions, decreasing Sr contents and increasing Mg contents with increasing burial depths and temperatures from east to west in the study area. δ¹⁸O values vary from 5·3‰ in the east to − 5·5‰ PDB in the west and are interpreted to reflect the greater extent and higher temperature of dolomite recrystallization in the west. δ¹³C values correlate with δ¹⁸O and decrease from 13·6‰ in the east to − 8·7‰ PDB in the west. Sr concentrations correlate positively with δ¹⁸O values and decrease from a mean of 750 ppm in the east to a mean of 250 ppm in the west. Mol% MgCO₃ values inversely correlate with δ¹⁸O values and increase from a minimum of 41·0 in the east to a maximum of 51·4 in the west. Rietveld refinements of powder X-ray diffraction data indicate that the more recrystallized dolomites have more contracted unit cells and increased cation ordering. The fraction of the Ca sites in the dolomites that are occupied by Ca atoms increases slightly with the approach to stoichiometry. The fraction of the Mg sites occupied by Mg atoms strongly correlates with mol% MgCO₃. Even in early diagenetic, non-stoichiometric dolomites, there is little substitution of Mg in Ca sites. During recrystallization, the amount of Mg substituting for Ca in Ca sites decreases even further. Most of the disorder in the least recrystallized, non-stoichiometric dolomites is related to substitution of excess Ca on Mg sites.     

Iron isotope variations in Holocene sediments of the Gotland Deep, Baltic Sea

Holocene sediments from the Gotland Deep basin in the Baltic Sea were investigated for their Fe isotopic composition in order to assess the impact of changes in redox conditions and a transition from freshwater to brackish water on the isotope signature of iron. The sediments display variations in δ⁵⁶Fe (differences in the ⁵⁶Fe/⁵⁴Fe ratio relative to the IRMM-14 standard) from −0.27 ± 0.09‰ to +0.21 ± 0.08‰. Samples deposited in a mainly limnic environment with oxygenated bottom water have a mean δ⁵⁶Fe of +0.08 ± 0.13‰, which is identical to the mean Fe isotopic composition of igneous rocks and oxic marine sediments. In contrast, sediments that formed in brackish water under periodically euxinic conditions display significantly lighter Fe isotope signatures with a mean δ⁵⁶Fe of −0.14 ± 0.19‰. Negative correlations of the δ⁵⁶Fe values with the Fe/Al ratio and S content of the samples suggest that the isotopically light Fe in the periodically euxinic samples is associated with reactive Fe enrichments and sulfides. This is supported by analyses of pyrite separates from this unit that have a mean Fe isotopic composition of −1.06 ± 0.20‰ for δ⁵⁶Fe. The supply of additional Fe with a light Fe isotopic signature can be explained with the shelf to basin Fe shuttle model. According to the Fe shuttle model, oxides and benthic ferrous Fe that is derived from dissimilatory iron reduction from shelves is transported and accumulated in euxinic basins. The data furthermore suggest that the euxinic water has a negative dissolved δ⁵⁶Fe value of about −1.4‰ to −0.9‰. If negative Fe isotopic signatures are characteristic for euxinic sediment formation, widespread euxinia in the past might have shifted the Fe isotopic composition of dissolved Fe in the ocean towards more positive δ⁵⁶Fe values.     

Variability of Stable Isotope Fingerprints of the Serpulid Ficopomatus enigmaticus Within a Permanently Stratified Estuary: Implications for (Palaeo)environmental Interpretations

This paper examines how the mixing of freshwater and seawater, and related mixing of freshwater and marine particulate organic matter (POM) in the permanently stratified estuary of the River Krka, Croatia, are reflected in the stable isotope fingerprints of soft tissues and tubes of the serpulid Ficopomatus enigmaticus. The carbon stable isotope composition (δ¹³C values) of the river-borne POM is retained over long distances, causing a depletion in ¹³C of POM in brackish waters. A trophic depletion in ¹³C was recorded in serpulid soft tissues. The serpulid carbonate tubes were depleted in ¹³C even at locations with salinity close to that of the sea and were subject to large isotope fractionation between dissolved inorganic C (DIC) and carbonate caused by vital effects, making carbonate depleted in ¹³C by several per mil compared with DIC. These effects, though large in the freshwater zone, fade towards the sea. The carbonate δ¹⁸O values of tubes reflect the δ¹⁸O values of the water. The temperature-related differences in δ¹⁸O values of tubes from different sites are masked by source-related differences in the δ¹⁸O values of water arising from mixing of freshwater and seawater in the estuary. Therefore, in serpulide tubes, the terrestrial component can easily be overestimated because of vital effects during biomineralisation and trophic depletion in ¹³C in freshwater and brackish environments.     

Darss Sill as a biological border in the fossil record of the Baltic Sea: evidence from diatoms

Biostratigraphical and palaeoecological analyses of cores along a transect from Femer Belt to the Arkona Basin reveal that North Sea waters began to enter the western Baltic Sea between 8600 and 8400 calibrated years BP. Studies of diatoms indicate that Mecklenburg Bay was characterised by slightly brackish-water conditions between 8400 and 8000 cal. years BP. At around 8000 cal. years BP increasing salinity is indicated by a strong dominance of the diatoms Paralia sulcata and Dimeregramma minor. Some centuries later another diatom assemblage appeared and became dominant in Mecklenburg Bay. This assemblage includes Hyalinella lateripunctata and Pravifusus hyalinus species typical of shallow water areas along the Atlantic coast today. At this time the first marine molluscs made their appearance. The oldest shell of a marine mollusc found in our material is dated to 7600 cal. years BP. The associated assemblage that includes adult specimens of the gastropod Aporrhais pespelicani indicates higher salinities than today.During the Littorina Sea stage a marine diatom flora with P. sulcata, Catenula adhaerens and D. minor crossed the Darss Sill and became widely distributed in the Arkona Basin, Pomeranian Bay and the Baltic Sea proper. In contrast, taxa indicative of the Hyalinella lateripunctata/P. hyalinus assemblage are only found west of the Darss Sill in Femer Belt and Mecklenburg Bay. Apparently, the Darss Sill threshold has been acting as an important salinity border from around 7800 cal. years BP until today.     

Nd isotope signature of Holocene Baltic Mn/Fe precipitates as monitor of climate change during the Little Ice Age

Neodymium (Nd) isotope profiles were analyzed on two Baltic Mn/Fe precipitates (99/2 and TL1) from shallow water (20 m) of the Mecklenburg Bay. The age range of these Mn/Fe precipitates determined by ²²⁶Ra_ex/Ba dating reaches from recent growth back to ∼4300 and 1000 yr BP, respectively. Over this time range, the Nd isotope composition varies from ε_Nd (0) = −13.1 to −17.5 in the selected Baltic precipitates indicating substantial changes in the Nd isotope composition of the Baltic Sea. The lowest ε_Nd values were recorded during the time interval of the Little Ice Age (LIA, AD ∼1350 to 1850). These minimum values indicate either an increase of the input of less radiogenic Nd from Scandinavian Archean-Proterozoic sources (ε_Nd about −22) to the Baltic Sea or a decrease of the input of more radiogenic Nd from continental European sources (ε_Nd about −12) and/or North Sea water (ε_Nd about −10). Variations of both, erosive continental input and North Sea inflow may indicate a direct response of the Nd isotope signal in the Baltic Sea to climate changes during the LIA and be related to cyclic shifts in the atmospheric circulation triggered by the North Atlantic Oscillation (NAO). Another aspect that possibly influenced the input of trace elements and Nd isotopes into the Baltic Sea is the population development in the circum Baltic area during the LIA. The lowest ε_Nd values also correspond to the medieval demographic crises that led to a significant decrease of agricultural activity and farmland. The reduction of soil erosion and enhanced regrowth of natural vegetation may have changed the amount and proportions of dissolved and suspended particulate matter transported into the Baltic Sea by rivers which in turn may have resulted in a change of the Nd isotope composition of Baltic Sea water.     

Salinity and Temperature Regimes in Eastern Alaskan Beaufort Sea Lagoons in Relation to Source Water Contributions

Shallow estuarine lagoons characterize >70 % of the eastern Alaskan Beaufort Sea coastline and, like temperate and tropical lagoons, support diverse and productive biological communities. These lagoons experience large variations in temperature (?2 to 14 °C) and salinity (0 to >45) throughout the year. Unlike lower latitude coastal systems, transitions between seasons are physically extreme and event-driven. On Arctic coastlines, a brief summer open-water period is followed by a 9-month ice-covered period that concludes with a late-spring sea ice breakup and intense freshwater run-off. From 2011 to 2014, we examined interannual variations in water column physical structure (temperature, salinity, and δ¹⁸O) in five lagoons that differ with respect to their degree of exchange with adjacent marine waters and magnitude of freshwater inputs. Temperature, salinity, and source water composition (calculated using a salinity and δ¹⁸O mixing model) were variable in space and time. During sea ice breakup in June, water column δ¹⁸O and salinity measurements showed that low salinity waters originated from meteoric inputs (50–80 %; which include river inputs and direct precipitation) and sea ice melt (18–51 %). Following breakup, polar marine waters became prevalent within a mixed water column over the summer open-water period within all five lagoons (26–63 %). At the peak of ice-cover extent and thickness in April, marine water sources dominated (75–87 %) and hypersaline conditions developed in some lagoons. Seasonal runoff dynamics and differences in lagoon geomorphology (i.e., connectivity to the Beaufort Sea) are considered key potential drivers of observed salinity and source water variations.