川西义敦岛弧稻城花岗岩体和海子山花岗岩体锆石U-Pb年代学、Hf同位素特征及地质意义

义敦岛弧形成于晚三叠世大规模俯冲造山作用过程中,位于松潘-甘孜褶皱带和羌塘地体之间。稻城岩体和海子山岩体分别为义敦岛弧上出露的晚三叠世和白垩纪花岗质岩体。结合野外考察,本文对上述岩体进行岩相学、锆石U-Pb年代学和Hf同位素的研究,结果表明,1稻城岩体和海子山岩体主要矿物为斜长石、钾长石、石英和黑云母,副矿物为锆石、榍石、磁铁矿和磷灰石等;钠质斜长石颗粒,以及钾长石和石英不连续出现,表明二者均属于低熔线花岗岩,是含水条件下,在与造山事件有关的环境中形成。2稻城岩体的侵位年龄为217.4Ma,属晚三叠世花岗岩侵入体,εHf(t)为-7.1~-0.1,二阶段模式年龄(tDM2)为1.26~1.7Ga,表明在中元古代与扬子克拉通经历了共同的地壳演化历史;海子山岩体的形成时代为98.3 Ma,为白垩纪时期产物,εHf(t)变化于-12.1~+2.5,二阶段模式年龄(tDM2)变化于1.0~1.93Ga。3结合前人研究成果,本文认为稻城岩体源岩可能是与扬子克拉通有关的中元古代的下地壳物质,在甘孜-理塘洋俯冲闭合后的同碰撞造山阶段,因地幔岩浆底侵作用而发生了部分熔融,同时伴有少量的亏损地幔成分加入,之后上升侵位于中—上地壳,并且侵位后经历了快速的冷却过程。海子山岩体是与俯冲有关的造山后伸展环境下形成的A2型花岗岩,源岩主要为中元古代地壳物质,同样有少量地幔物质加入,在白垩纪时侵位于地壳较浅部位,之后亦同样经历了快速的冷却过程。     

甘孜-理塘蛇绿混杂岩带晚三叠世构造演化——来自理塘地区勇杰岩体地球化学、年代学的制约

甘孜-理塘蛇绿混杂岩带是西南三江构造带的重要组成部分,经历了古特提斯构造体系的演化,形成完整的沟-弧-盆体系。义敦岛弧属甘孜-理塘弧盆系范畴,位于甘孜-理塘缝合带西侧。对义敦岛弧勇杰岩体开展详细的岩石学、地球化学、年代学研究,为甘孜-理塘洋盆晚三叠世构造演化研究提供新的证据。义敦勇杰岩体黑云母二长花岗岩和花岗质细晶岩的锆石UPb年龄分别为214.2±1.4Ma和206.2±1.8Ma,整体属高钾钙碱性弱过铝质花岗岩;稀土元素配分曲线具轻稀土元素相对富集、重稀土元素相对平坦的特征,负Eu异常明显;微量元素表现为大离子亲石元素Rb、Ba、Th、U、K相对富集,高场强元素Nb、Ta、P、Ti亏损的特征,显示勇杰岩体黑云母二长花岗岩明显具俯冲型花岗岩的特征,而花岗质细晶岩具有碰撞型花岗岩的特征。总体反映晚三叠世甘孜-理塘洋盆从俯冲至碰撞的地球动力学背景,应属理塘蛇绿混杂岩带碰撞造山过程的产物。     

川西稻城岩体岩浆混合作用：矿物学特征的证据

义敦岛弧形成于晚三叠世大规模俯冲造山作用过程中,位于松潘甘孜地体和羌塘地体之间。稻城边部岩体是义敦岛弧带内规模巨大的复式花岗质岩体,由花岗岩、花岗闪长岩和钾长花岗岩组成。大量暗色镁铁质微粒包体发育于花岗闪长岩和钾长花岗岩中,且其与寄主岩石的接触界线明显。暗色镁铁质微粒包体具有细粒结构,发育石英眼构造、针状磷灰石和具环带结构的斜长石斑晶。文中以稻城岩体寄主岩石和暗色微粒包体中斜长石、黑云母和角闪石为研究对象,开展岩相学和电子探针原位化学成分分析,厘定了矿物形成的物理化学条件,探讨了岩浆混合作用过程及其形成的构造环境。研究表明：花岗闪长岩和暗色微粒包体中的斜长石主要为中长石,其核部呈浑圆状;前者核部的An值(21~50)显著高于幔部(21~34);后者则发育典型的突变环带,An值(29~44)呈波状变化且相对集中。暗色微粒包体与寄主花岗闪长岩中斜长石的An值部分重叠表明二者形成过程中存在含量的岩浆混合作用。斜长石环带中的An值随Al2O3、FeO、MgO和CaO含量的升高而升高,但随SiO2、Na2O和K2O含量的升高而降低。寄主岩石和暗色微粒包体中角闪石富镁铁,阳离子特征为：CaB=1.56~1.75,Ti=0.08~0.13,属于钙质角闪石,具壳源特征,其结晶温度分别为697~725 ℃和680~705 ℃。花岗闪长岩中黑云母的Mg/(Mg+Fe2+)为0.37~0.45,显示出富Fe贫Ca、Mg,属于典型的岩浆成因黑云母。黑云母TiO2含量变化范围为3.54%~4.62%,Al2O3含量变化范围为13.89%~15.15%;黑云母的氧化系数为0.08~0.11,Mg#为0.39~0.46,MF值为0.36~0.44,单位分子中阳离子数AlⅥ为0.03~0.11,以单位分子中Ti和Al阳离子数计算的黑云母结晶温度为584~624 ℃,表明其结晶温度较高,具壳幔混源特征。稻城岩体是以壳源为主的壳幔混源成因的I型花岗岩,暗色微粒包体是由镁铁质岩浆与长英质岩浆不同程度的混合作用形成的。     

义敦岛弧措交玛岩体岩浆混合成因:镁铁质微粒包体的证据

义敦岛弧北部的措交玛岩基岩体主要由黑云母二长花岗岩和边部的花岗闪长岩组成。在黑云母二长花岗岩中存在有少量镁铁质微粒包体,其成分为闪长质,与寄主岩石接触关系从渐变到截然。在包体周围的寄主岩石中存在黑云母、角闪石自身的包含结构,角闪石包含黑云母,斜长石发育明显的溶蚀结构,核部斜长石被溶蚀成筛状,边部环带状斜长石溶蚀不明显,是基性岩浆注入到酸性岩浆中导致岩浆混合的结果。黑云母二长花岗岩具有更高的轻重稀土分异系数,闪长质包体轻重稀土分异系数较低,黑云母二长花岗岩和暗色闪长质微粒包体具有明显相似性的微量元素特征。寄主岩黑云母二长花岗岩锆石U-Pb年龄为236±1.9Ma,闪长质包体为235±3.9Ma,二者形成年代在误差范围内基本一致,可能为甘孜-理塘洋向西俯冲过程中,俯冲洋壳部分熔融形成的玄武质岩浆上涌底侵于壳-幔边界导致地壳的部分熔融形成酸性的黑云母二长花岗岩岩基。     

湘东北早白垩世桃花山—小墨山花岗岩体岩石地球化学特征及成因

出露于湖南东北部华容县附近的桃花山—小墨山岩体侵位于中元古代冷家溪群。通过锆石LA-ICP-MS U-Pb法测得两岩体侵位时代分别为129 ± 1 Ma和117 ± 1 Ma。桃花山主体岩性为（片麻状）二云母二长花岗岩,SiO2 = 71.75%~73.81%,K2O/Na2O = 0.84~1.11,属弱过铝质高钾钙碱性系列;岩石明显富集大离子亲石元素,亏损高场强元素;Eu为中等负异常,ΣREE较高,Rb/Sr = 0.9~2.7,（La/Yb）N = 26.92~86.02;高ISr（0.714~0.723）,低εNd（-9.76~-10.6）, 高t2DM （1.72~1.79 Ga）。小墨山黑云母二长花岗岩SiO2 = 69.64%~72.73%,K2O/Na2O = 0.62~0.7,准铝质至弱过铝质,Rb/Sr = 0.26~0.88,（La/Yb）N =11.97~12.67;低ISr（ 0.707~0.709）,高εNd（-6.38~-6.73）,低t2DM （1.43~1.46 Ga）。综合分析表明,桃花山二云母二长花岗岩为壳源含白云母过铝花岗岩类（GPG）,源岩为华南古元古代基底;小墨山黑云母二长花岗岩类似含堇青石及富黑云母过铝花岗岩类（CPG）,源岩为低成熟度的变杂砂岩。桃花山、小墨山岩体形成于华南早白垩世伸展背景下的局部挤压增厚环境。江南断裂晚燕山期的逆冲推覆构造造成了华容地区的小范围地壳增厚,并为桃花山源岩的“湿”深熔作用提供了流体聚集通道;小墨山花岗岩的形成则与幔源岩浆的底侵有关,热的幔源岩浆不仅为地壳的部分熔融提供了热量,而且与熔融的壳源岩浆发生了混合作用。     

滇西北休瓦促钨钼矿区复式岩体地质及其成矿特征——来自年代学、氧逸度和地球化学的约束

休瓦促钨钼矿床位于义敦岛弧南段的香格里拉北部,目前已达中-大型。该区发育由两期岩体(晚三叠世的黑云母花岗岩和晚白垩世的斑状二长花岗岩)叠加而成的复式岩体,而该矿区钨钼矿形成于82~86Ma。然而,两期岩体间关系,以及晚三叠世岩体对矿床的形成有怎样的贡献,目前未有报道。笔者通过对两期岩体形成时间及其地球化学特征的研究,从成岩年代学、岩浆氧逸度等方面探究上述问题,并揭示两期岩体的成矿特征,为找矿实践提供一定的参考依据。研究表明,黑云母花岗岩结晶年龄为211.7±2.6Ma,SiO_2偏高(69.48%~73.73%),属高钾的钾玄质系列,偏铝质,富集轻稀土元素和大离子亲石元素而亏损重稀土元素以及高场强元素Nb、Sr、Ti等,有微弱的负Eu异常,岩浆氧逸度相对较高(fO_2=-19.4~-9.1,平均-13.7);斑状二长花岗岩结晶年龄为76.8±3.8Ma,且有一颗锆石核部的年龄值为219±2.6Ma,该岩体与前者有相似的地球化学特征,SiO_2高(67.35%~75.65%),属偏铝质的钾玄质系列,ΣREE较高,高于黑云母花岗岩,铕负异常明显大于前者,岩浆氧逸度相对较低(fO_2=-30.4~-18.2,平均-23.4)。据此,结合休瓦促矿区断层发育情况,提出矿区内两期岩体以近南北向F_4为界呈断层接触关系,北西向走滑断层(F_1-F_3)为控矿构造。本文认为,晚期斑状二长花岗岩对早期黑云母花岗岩具有一定的继承性关系,黑云母花岗岩来源于晚三叠世甘孜-理塘洋向西俯冲环境下地壳的部分熔融,岩浆富水、氧逸度高,利于形成Cu-Au矿床,且在找矿实践中得到部分验证;斑状二长花岗岩来源于加厚下地壳的部分熔融,岩浆贫水、氧逸度低于黑云母花岗岩,与W-Mo矿床相关。即,晚白垩世岩浆热液沿矿区断裂-裂隙系统运移,继承和发展早期岩浆活动,形成脉状细晶岩和W-Mo矿床。     

四川红原地区三叠纪花岗岩的地球化学特征及地质意义

红原地区三叠纪花岗岩位于松潘-甘孜造山带的北部,侵位于三叠纪西康群砂板岩系中,岩石类型主要为中细粒花岗闪长岩和二长花岗岩。岩石地球化学分析结果表明该区岩体属于准铝质-过铝质富钾钙碱性系列,大部分为I型花岗岩(羊拱海和达盖寨岩体部分表现为A型),稀土元素总量变化较大,轻稀土元素相对富集,稀土元素球粒陨石标准化配分型式为右倾型,Eu异常不明显。轻重稀土元素分馏明显,轻稀土元素分镏大于重稀土元素。岩石地球化学特征指示该区花岗岩体可能为同源的地壳物质的部分熔融作用所形成,源岩可能为变杂砂岩和变中性火山岩,热源可能来自于地幔岩浆的底侵作用。     

青海冷湖盐场北山黑云母二长花岗岩年代学、地球化学及其地质意义

柴北缘西端青海冷湖盐场北山地区发育黑云母二长花岗岩,岩体高硅(Si O2=73.92%~75.98%)、富钾(K2O=3.71%~4.78%)、贫镁钙,铝饱和指数A/CNK介于1.03~1.11,属强过铝质花岗岩。稀土元素球粒陨石标准化曲线呈右倾型,Eu异常不明显;岩体含有富铝矿物石榴子石,刚玉标准分子约为1%,Th、Y含量低,且与Rb呈负相关性,源岩为沉积岩,具S型花岗岩特征,是幔源岩浆底侵作用引发地壳物质部分熔融的产物。LA-ICP-MS锆石U-Pb测年结果表明岩体形成于254±4 Ma。结合区域地质背景及岩石地球化学特征认为盐场北山黑云母二长花岗岩形成与俯冲作用有关,类似于岛弧环境产物,从而揭示柴北缘晚二叠世具有活动大陆边缘性质。     

大兴安岭南段晚中生代侵入岩时空分布及主脊与东坡岩体特征对比

通过岩相学、地球化学、锆石U-Pb年代学对位于大兴安岭主脊上的马勒根坝岩体、朝阳沟岩体和大兴安岭东坡区域的野猪沟岩体、布敦化岩体的4个不同花岗岩岩体的岩石类型、主量和微量元素特征、年代学及构造背景进行对比分析,讨论了研究区在晚侏罗世—早白垩世的岩浆活动及地质背景。LA-ICP-MS锆石U-Pb年龄显示:主脊朝阳沟岩体和东坡布敦化岩体年龄分别为(154±1) Ma和(154.1±1.6) Ma,属于晚侏罗世岩体,主脊马勒根坝岩体和东坡野猪沟岩体年龄分别为(144.62±0.74) Ma和(140.2±2.7) Ma,属于早白垩世岩体。岩相学和地球化学特征显示:主脊岩体为高钾钙碱性-准铝质-过铝质花岗岩岩体,东坡岩体为钙碱性-高钾钙碱性-准铝质-弱过铝质TTG型岩体;主脊比东坡岩体更加亏损Ba、Nb、Sr、P、Ti、Eu元素,为高分异I型花岗岩,东坡岩体为正常的I型花岗岩。结合区域地质资料分析,认为在晚侏罗世—早白垩世伊泽奈崎板块NNW向俯冲和蒙古—鄂霍次克洋闭合共同作用于大兴安岭南段地区,在大兴安岭主脊形成断裂带,导致幔源岩浆上涌底侵下地壳而形成沿断裂带分布的花岗岩体;主脊处于碰撞向伸展环境过渡的时期,东坡区域此时应处于俯冲时期。     

内蒙古中部巴音勿拉山岩体的地质特征及构造意义

巴音勿拉山岩体位于华北克拉通北部,白乃庙岛弧岩带南部,锆石LA-ICP-MS U-Pb定年结果及锆石特征表明其侵位时代为(410.9±1.2)Ma。岩体岩石组合为一套正长岩杂岩,富钾富碱,铝质量分数较高,属偏铝质岩石。地球化学特征表明岩浆源区为岩石圈地幔,岩浆演化过程中下地壳的同化作用显著。其形成与白乃庙岛弧岩带与华北克拉通碰撞后的伸展作用有关。     

Police, politics, and the right to the city

Space and spatiality have recently been at the core of debates concerning the political possibilities of the city. The arguments advanced in this paper might be seen as an attempt to contribute to these debates through a reflection on the spatiality of (in) justice, politics, and the right to the city. The case of French urban policy, with its focus on distressed urban areas, and the `suburban problem' in France are used as examples to make arguments more concrete.     

Rb-Sr, K-Ar, H-and O-Isotope systematics of the Middle Riphean shales from the Debengda Formation, the Olenek Uplift, North Sibera

Clay subfractions (SFs) of <0.1, 0.1–0.2, 0.2–0.3, 0.3–0.6, 0.6–2 and 2–5 μm separated from Middle Riphean shales of the Debengda Formation are studied using the TEM, XRD, K-Ar and Rb-Sr isotopic methods. The oxygen and hydrogen isotope compositions in the SFs are studied as well. The low-temperature illite-smectite is dominant mineral in all the SFs except for the coarsest ones. The XRD, chemical and isotopic data imply that two generations of authigenic illite-smectite different in age are mixed in the SFs. The illite crystallinity index decreases in parallel with size diminishing of clay particles. As compared to coarser SFs, illite of fine-grained subfractions is enriched in Al relative to Fe and Mg, contains more K, and reveals higher K/Rb and Rb/Sr ratios. The Rb-Sr age calculated by means of the leachochron (“inner isochron”) method declines gradually from 1254-1272 Ma in the coarsest SFs to 1038-1044 Ma in finest ones, while the K-Ar age decreases simultaneously from 1225–1240 to 1080 Ma. The established positive correlation of δ¹⁸O and δD values with dimensions of clay particles in the SFs seems to be also consistent with the mixing systematics. The isotopic systematics along with data on mineral composition and morphology lead to the conclusion that mixedlayer illite-smectite was formed in the Debengda shales during two periods 1211–1272 and 1038–1080 Ma ago. The first period is likely close to the deposition time of sediments and corresponds to events of burial catagenesis, whereas the second one is correlative with the regional uplift and changes in hydrological regime during the pre-Khaipakh break in sedimentation.     

Isotopic systematics of He,Ar, S,Cu, Ni,Re, Os,Pb, U,Sm, Nd,Rb, Sr,Lu, and Hf in the rocks and ores of the Norilsk deposits

This paper reports the first results of a study of 11 isotope systems (³He/⁴He, ⁴⁰Ar/³⁶Ar, ³⁴S/³²S, ⁶⁵Cu/⁶³Cu, ⁶²Ni/⁶⁰Ni, ⁸⁷Sr/⁸⁶Sr, ¹⁴³Nd/¹⁴⁴Nd, ^206–208Pb/²⁰⁴Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others.     

Influences of the unsaturated,saturated, and riparian zones on the transport of nitrate near the Merced River,California, USA

Transport and transformation of nitrate was evaluated along a 1-km groundwater transect from an almond orchard to the Merced River, California, USA, within an irrigated agricultural setting. As indicated by measurements of pore-water nitrate and modeling using the root zone water quality model, about 63% of the applied nitrogen was transported through a 6.5-m unsaturated zone. Transport times from recharge locations to the edge of a riparian zone ranged from approximately 6 months to greater than 100 years. This allowed for partial denitrification in horizons having mildly reducing conditions, and essentially no denitrification in horizons with oxidizing conditions. Transport times across a 50–100-m-wide riparian zone of less than a year to over 6 years and more strongly reducing conditions resulted in greater rates of denitrification. Isotopic measurements and concentrations of excess N₂ in water were indicative of denitrification with the highest rates below the Merced River. Discharge of water and nitrate into the river was dependent on gradients driven by irrigation or river stage. The results suggest that the assimilative capacity for nitrate of the groundwater system, and particularly the riverbed, is limiting the nitrate load to the Merced River in the study area.     

扬子北缘马元铅锌矿床闪锌矿微量元素及S-Pb-He-Ar-C同位素地球化学研究

马元铅锌矿床是近年扬子陆块北缘铅锌找矿的新突破。矿体呈层状、似层状产于碑坝隆起翼部震旦系灯影组角砾状白云岩层间构造带中,围岩蚀变很弱。矿石中硫化物以闪锌矿、方铅矿为主,中粗粒晶质结构,充填于白云岩角砾间。闪锌矿富集Cd、Ge、Ag,贫In、Tl、Se,Ga/In为6~132,Ge/In多1000,成矿温度以中-低温为主。金属硫化物ε~(34)S值相对集中,为12.9‰~19.4‰,平均为17.4‰,来自于海相硫酸盐的还原。铅同位素组成稳定,~(206)Pb/~(204)Pb为17.858~17.918:~(207)Pb/~(204)Pb为15.603~15.694;~(208)Pb/~(204)Pb为37.756~38.046,具有造山带和上地壳铅的特征,震旦系可能提供了金属成矿物质。闪锌矿中流体包裹体的~3He/~4He为0.03Ra~1.05Ra,~(40)Ar/~(36)Ar为326.1~765.1,~(38)Ar/~(36)Ar为0.183~0.204,表明成矿流体主要为地壳流体和饱和大气水(大气降水或海水)的混合。闪锌矿内流体包裹体挥发分δ~(13)C_(CH_4)值为-36.01‰~-28.80‰,δ~(13)C_(C_2H_6)值为-27.72‰~-22.44‰,δ~(13)C_(CO_2)值为-23.24‰~-9.68‰,表明有机流体参与了成矿作用。石英、方解石的H-O同位素结果表明具有海水和有机水混合的特征。可见,成矿流体具有两种流体混合的特征,一为蒸发海水与围岩反应所形成的盆地卤水,二为有机流体。推测矿区可能存在一个古油气藏,由于TSR生成一高硫气藏,为区内还原性有机流体的主要来源。当富含Pb、Zn等成矿物质的成矿流体运移至富含CH_4和H_2S的还原性流体的矿区角砾岩带时,两种流体混合,Pb、Zn等遇到H_2S发生反应而沉淀成矿,并伴生热液白云石等,形成了马元铅锌矿床。综上所述,我们认为马元矿床属MVT型铅锌矿床。     

贵州岑巩羊桥罗家塘杷榔动物群的发现及其后生动物早期演化的意义

岑巩县羊桥乡罗家塘杷榔组仅出露中-上部地层,岩性单一,均为青灰、灰绿色粉砂质泥、页岩.在其上部层位发现了俞氏贵州始海百合(Guizhoueocrinus yui Zhao,Parsley et Peng,2007),计有棘皮动物始海百合、腕足动物、软体动物-软舌螺、节肢动物-三叶虫等8属9种,包括了2个未定名的新种和1...     

Breakthroughs in the biodiversity, biogeography, biostratigraphy, and basin analysis of the Beaufort group

Over the past decade researchers working on the rocks of the Beaufort Group in the main Karoo Basin of South Africa have vastly increased our understanding of this important Permo-Triassic sequence. Many new fossil forms have been discovered, allowing for breakthroughs into the biodiversity, biogeography and biostratigraphy of the group. Taxonomic and phylogenetic advances are many and varied, and cover most of the vertebrate taxa, but with emphasis placed on the temnospondyl amphibians, archosauriforms and non-mammalian synapsids, in particular the anomodontia. Biostratigraphic breakthroughs have centered on the Middle Permian Eodicynodon and Tapinocephalus assemblage zones, the Late Permian Dicynodon Assemblage Zone, and the Triassic Lystrosaurus and Cynognathus assemblage zones. Correlation of these biozones with better dated sequences in Europe, Russia and China has allowed for many chronostratigraphic refinements, which are in turn vital for sequence stratigraphical analysis of the basin fill. Based on fossil data, both the lower (Ecca–Beaufort) and upper (Beaufort–Molteno) contacts of the group have been proved to be highly diachronous. The refined chronostratigraphic framework has also allowed for a better analysis of the basin evolution through time, particularly in terms of the correlation of external stimuli that affect basin sedimentation patterns.     

Delivery of Trace Metals (Al,Fe, Mn,V, Co,Ni, Cu,Cd, Ag,Pb) from the Trinity River Watershed Towards the Ocean

The Trinity River (Texas, USA) contains in its watershed 23 different reservoir lakes, the largest one being Lake Livingston situated in the lower Trinity River watershed and two potentially polluting metroplexes, Dallas and Houston. In order to determine fluxes of nutrients and trace metals to Galveston Bay, a survey that included 24 discreet samples collected over a year and at various stages of discharge was carried out during 2000–2001. Geochemical (i.e., sorption by Fe oxyhydroxides), biological (i.e., seasonal uptake by sinking algae in Lake Livingston), and hydrological (i.e., dilution effects by increasing flow rates) controls were found to be mainly responsible for variations in dissolved trace metal concentrations rather than pollution sources. The Trinity River loads of suspended sediments and pollutant trace metals entering Galveston Bay at Anahuac were <20% of those reaching Lake Livingston, and only a few percent of the total upstream trace metal load is entering the Gulf of Mexico. Thus, during the transit through the 23 man-made lakes and an estuary, >96% of the pollutant trace metal load is lost to sediments.     

深港西部通道填海区地下水铜、钒、铊、镉、钨迁移的实验研究

填海工程使滨海地区的地下水物理化学条件改变,导致该区域地下水中重金属浓度升高。本文以深港西部通道填海区为例,采用实验室模拟填海条件的办法,初步探讨了影响填海区地下水重金属迁移的关键因素。模拟实验结果表明,填海区地下水中钨元素含量升高与地下水淡化、淤泥氧化过程以及填料风化有关;铜元素含量升高则与淤泥氧化过程以及填料风化有关;钒元素含量升高与地下水淡化和淤泥氧化过程有关,而其他元素含量升高则主要与填料风化释放有关。