The 16°40′ S triple junction in the North Fiji Basin (SW Pacific)

During the last three years, the North Fiji Basin (SW Pacific) has been intensively studied on three oceanographic cruises carried out by French, American and Japanese ships. One of the main goals of these cruises was to study by means of precise SeaBeam, SEAMARC II, seismic and magnetic surveys, the active spreading system and its associated hydrothermal processes. The North Fiji basin, bounded by the major Pacific and Indo-Australian plates, shows a complex polyphased tectonic evolution. One of the last phases of this evolution is the functioning since 3 Ma of a NS spreading center in the axial part of the basin. The tectonic instability of the area resulted in a permanent rearrangement of the ridge axis. Among others, the 16°40′ S triple junction is one of the major manifestations of such an instability. Sinistral strike-slip motion 1 Ma ago, along the North Fiji Fracture Zone induced the change in direction of two segments of the axis from NS to N15 and N160. The first segment is characterized by a typical spreading ridge similar to various parts of the EPR, while the second shows an atypical ‘en echelon’ fan-shape opening. The N15 and N160 ridges converging with the North Fiji Fracture Zone constitute the 16°40′ S Ridge-Ridge-Fracture Zone triple junction. The detailed morphologic and kinematic study of this junction allows us to understand one of the mechanisms of the deformation in the North Fiji basin.     

Geologic setting of the Snake Pit hydrothermal site: An active vent field on the Mid-Atlantic Ridge

TheSnake Pit Hydrothermal Site lies on the axis of the Mid-Atlantic Ridge at 23°22′ N latitude, about 30 km south of the Kane Transform Intersection. Active ‘black smoker’ vents and a surrounding field of hydrothermal sediment occur at the crest of a laterally extensive neovolcanic ridge. It is one of the first active hydrothermal vent fields to be found on a slow-spreading ridge axis and despite significant differences in its geologic setting from those of the East Pacific Rise, has many similarities to its fast-spreading counterparts. Although preliminary reports have documented many interesting aspects of these vents and their surroundings, new data collected from the manned submersible ALVIN and the deep-towed ANGUS camera system define the regional tectonic setting as well as the local geologic environment of this fascinating area. The Snake Pit vents are located on a local peak of a volcanic constructional ridge at a depth of 3450 m, 700–800 m deeper than vents known from the East Pacific Rise, Galapagos, or Juan de Fuca spreading centers. The vent field is at least 600 m long and up to 200 m wide and is covered by a thick blanket of greenish to yellow-orange hydrothermal sediment. Both active and extinct vents are perched along the crests of steep-sided sulfide mounds that reach heights of over 40 m. High-temperature (350° C) fluids are vented from black smoker chimneys and low-temperature (226° C) fluids seep from sulphide domes and subordinate anhydrite constructions. Water temperatures, flow rates, fluid chemistries, and mineralization are strikingly similar to vents of faster spreading ridge crests; however, a somewhat distinct fauna inhabit the area.     

Hydrothermal Vent Geology and Biology at Earth’s Fastest Spreading Rates

Earth’s fastest present seafloor spreading occurs along the East Pacific Rise near 31°–32° S. Two of the major hydrothermal plume areas discovered during a 1998 multidisciplinary geophysical/hydrothermal investigation of these mid-ocean ridge axes were explored during a 1999 Alvin expedition. Both occur in recently eruptive areas where shallow collapse structures mark the neovolcanic axis. The 31° S vent area occurs in a broad linear zone of collapses and fractures coalescing into an axial summit trough. The 32° S vent area has been volcanically repaved by a more recent eruption, with non-linear collapses that have not yet coalesced. Both sites occur in highly inflated areas, near local inflation peaks, which is the best segment-scale predictor of hydrothermal activity at these superfast spreading rates (150 mm/yr).     

GLORIA imagery of sea floor structures in the northern North Fiji Basin

GLORIA side-scan imagery from the northern North Fiji Basin reveals modern and relict sea-floor fabric. The South Pandora Ridge is marked by steep escarpments and small rift basins, but no recent volcanism. The northern and eastern limbs of the 16°58S, 173°55E triple junction are marked by rift grabens flanked by steep escarpments, but little recent volcanism is apparent there. At present, there is no well-organized spreading system in the northern North Fiji Basin; extension and shearing are occurring within narrowly confined areas. It is uncertain how these areas relate to one another and fit into the regional tectonic framework.     

The morphology and tectonics of the Mark area from Sea Beam and Sea MARC I observations (Mid-Atlantic Ridge 23° N)

High-resolution Sea Beam bathymetry and Sea MARC I side scan sonar data have been obtained in the MARK area, a 100-km-long portion of the Mid-Atlantic Ridge rift valley south of the Kane Fracture Zone. These data reveal a surprisingly complex rift valley structure that is composed of two distinct spreading cells which overlap to create a small, zero-offset transform or discordant zone. The northern spreading cell consists of a magmatically robust, active ridge segment 40–50 km in length that extends from the eastern Kane ridge-transform intersection south to about 23°12′ N. The rift valley in this area is dominated by a large constructional volcanic ridge that creates 200–500 m of relief and is associated with high-temperature hydrothermal activity. The southern spreading cell is characterized by a NNE-trending band of small (50–200 m high), conical volcanos that are built upon relatively old, fissured and sediment-covered lavas, and which in some cases are themselves fissured and faulted. This cell appears to be in a predominantly extensional phase with only small, isolated eruptions. These two spreading cells overlap in an anomalous zone between 23°05′ N and 23°17′ N that lacks a well-developed rift valley or neovolcanic zone, and may represent a slow-spreading ridge analogue to the overlapping spreading centers found at the East Pacific Rise. Despite the complexity of the MARK area, volcanic and tectonic activity appears to be confined to the 10–17 km wide rift valley floor. Block faulting along near-vertical, small-offset normal faults, accompanied by minor amounts of back-tilting (generally less than 5°), begins within a few km of the ridge axis and is largely completed by the time the crust is transported up into the rift valley walls. Features that appear to be constructional volcanic ridges formed in the median valley are preserved largely intact in the rift mountains. Mass-wasting and gullying of scarp faces, and sedimentation which buries low-relief seafloor features, are the major geological processes occurring outside of the rift valley. The morphological and structural heterogeneity within the MARK rift valley and in the flanking rift mountains documented in this study are largely the product of two spreading cells that evolve independently to the interplay between extensional tectonism and episodic variations in magma production rates.     

Accumulation rates of hydrothermal metalliferous sediments in the Lau Basin,S. W. Pacific

Five cores were recovered on a traverse in the Lau Basin at 18°30′S crossing a supposed active spreading center. The sediments were subjected to selective chemical leaching for Mn, Fe, Cu, Zn, and As. Accumulation rates were determined using¹⁴C. These rates increase from west to east, reflecting the influence of volcaniclastic inputs from the Tonga- Kermadec Ridge. All elements display highest non-detrital accumulation rates closest to the supposed spreading center, suggesting a hydrothermal input to the sediments there. Variable hydrothermal inputs also influence the other cores.     

Spatial structures of hydrothermal vents and vent-associated megafauna in the back-arc basin system of the Okinawa Trough,western Pacific

Spatial patterns and morphology of hydrothermal vents and the occurrence of vent-associated megafauna were investigated in the back-arc basin system of the Okinawa Trough, western Pacific. Amongst hydrothermal vent fields located on the rising slopes to the NE and S of the basin, the Iheya North area has been subjected to a series of intensive diving surveys. Hydrothermal vents demonstrated concentrated patterns of distribution on different spatial scales. In Iheya North, the majority of vents occurred in lines parallel to the NE to W/SW alignment of the spreading axis, within a radius of ca. 200 m around the most active sulphide structure with the highest recorded fluid temperature of over 300°C. The morphology of hydrothermal vents varied greatly from an incipient flat rock with crevices to a 20- to 30-m-tall, multi-flanged structure with concomitant variation in the distribution and abundance of vent-associated megafauna, particularly a galatheid Shinkaia crosnieri and Bathymodiolus mussels. Comparison of active and inactive vents revealed that the spatial extent of Shinkaia ‘aggregation’ (a group of individuals with short nearest-neighbour distances) effectively defined a habitat unit of this species, and active hydrothermal chimneys contained more of these units, leading to greater spatial occupancy by Shinkaia. Given the temporally unstable nature of vent structures as recognised by repeated surveys, vent assemblages are thought to be closely dictated by the spatio-temporal dynamics of vents in the Okinawa Trough back-arc system.     

An Angus/Argo study of the neovolcanic zone along the East Pacific rise from the Clipperton fracture zone to 12°N

Still photographs and video images collected along the Neovolcanic Zone of the East Pacific Rise from 10°15′N to 11°53′N show that recent volcanic sheet flows, possibly less than 100 years old, are superimposed on an older sediment-laden pillow terrane. This recent activity is restricted to a narrow zone that crosses two topographic highs at 10°55′N and 11°26′N and diminishes along-axis away from these highs. The association of recent sheet flows with older flows and collapse structures on the overlapping spreading centers at 11°45′N supports the evolutionary model for the occurrence and evolution of overlapping spreading centers by MacDonald and others (1986, 1988).     

Spreading rates,rift propagation,and fracture zone offset histories during the past 5 my on the Mid-Atlantic Ridge; 25°–27°30′ S and 31°–34°30′ S

The southern Mid-Atlantic Ridge (MAR) is spreading at rates (34–38 mm yr⁻¹) that fall within a transitional range between those which characterize slow and intermediate spreading center morphology. To further our understanding of crustal accretion at these transitional spreading rates, we have carried out analysis of magnetic anomaly data from two detailed SeaBeam surveys of the MAR between 25°–27°30′S and 31°–34°30′S. Within these areas, the MAR is subdivided into 9 ridge segments bounded by large- and short-offset discontinuities of the ridge axis. From two-dimensional Fourier inversions of the magnetic anomaly data we establish the history of spreading within each ridge segment for the past 5 my and the evolution of the bounding ridge-axis discontinuities. We see evidence for the initiation and diminishment of small-offset discontinuities, and for the transition of rigid large-offset transform faults to less stable short-offset features. Individual ridge segments display independent spreading histories in terms of both the sense and amount of asymmetric spreading within each which have given rise to changes through time in the lengths of bounding ridge-axis discontinuities. Over the past 3–5 my, the short-offset discontinuities within the area have lengthened/shortened by approximately the same amount (∼ 10 km). During this same time period, larger-offset transform faults have remained comparatively constant in length. A shift in plate motion at anomaly 3 time may have given rise to change in the length of short-offset second-order discontinuities. However, the pattern of lengthening/shortening short-offset discontinuities we see is not simply related to the geometry of the plate boundary in these regions which precludes a simply relationship between plate motion changes and response at the plate boundary. We document a case of rapid (minimum 60 mm yr⁻¹) small-scale rift propagation, occurring between 2.5 and 1.8 my, associated with transition of the Moore transform fault to an oblique-trending ridge-axis discontinuity. Propagation across the Moore discontinuity and similar propagation within the 31°–34°30’S area may be associated with the reduced age contrast in lithosphere across second-order discontinuities. Total opening rates within our northern survey area decreased from anomaly 4′ to 2 time and rates within both areas have increased since the Jaramillo. Total opening rates measured for anomaly intervals differ along the plate boundary significantly, more than expected with changing distance to the pole of rotation. These differences imply a degree of short-term non-rigid plate behaviour which may be associated with ridge segments acting as independent spreading cells. Magnetic polarity transition widths from our inversion studies may be used to infer a zone of crustal accretion which is 3–6 km wide, within the inner floor of the rift valley. A systematic increase of transition width with age would be expected if deeper crustal sources dominate the magnetic signal in older crust but this is not observed. We present results from three-dimensional analysis of magnetic anomaly data which show magnetization highs located at the intersection of the MAR with both large- and short-offset discontinuities. Within the central anomaly the highs exceed 15 A m⁻¹ compared with a background of approximately 8–10 A m⁻¹ and they persist for at least 2.5 my. The highs may be caused by eruption of fractionated strongly magnetized basalts at ridge-axis discontinuities with both large and small offsets.     

Helium Isotopes in Pacific Waters from Adjacent Region of Honshu, Japan

We have measured helium isotopic ratios of thirty-seven Pacific water samples from various depths collected in adjacent regions of Honshu, Japan. The ³He/⁴He ratios vary significantly from 0.989 R _atm to 1.208 R _atm where R _atm is the atmospheric ratio of 1.39 × 10⁻⁶. The mid-depth (750–1500 m) profile of ³He/⁴He ratios at ST-1 located Northwestern Pacific Ocean east of Japan (Off Joban; 37°00′ N, 142°40′ E) is significantly different from that at ST-2 of the Northern Philippine Sea south of Japan (Nankai Trough; 33°07′ N, 139°59′ E), suggesting that these waters were separated by a topographic barrier, the Izu-Ogasawara Ridge. Taking ³He/⁴He data of the Geosecs expeditions in the western North Pacific, an extensive plume of 15% excess ³He relative to the air may be traced at ST-1 over 12,000 kilometers to the northwest of the East Pacific Rise where the mantle helium may originate. The 20% excess found at ST-2 may be attributable to the additional source of the subduction-type mantle helium in the Okinawa Trough. A 15% excess of ³He has also been discovered at a depth of about 1000∼1500 m at ST-3 adjacent to Miyakejima Island (33°57′ N, 139°22′ E) and ST-4 of Sagami Bay (35°00′ N, 139°22′ E). It is confirmed that mid-depth all over the western North Pacific water is affected by the mantle helium with a high ³He/⁴He ratio. This revised version was published online in July 2006 with corrections to the Cover Date.     

Influence of ridges on hydrographic parameters in the Southwest Indian Ocean

The objective of the paper is to use the data collected along two meridional sections (45° E and 57°30′ E) during the austral summer (January–March) 2004 to understand the influence of seabed topography across the Madagascar and Southwest Indian Ridges on hydrographic parameters. The study was supplemented by World Ocean Circulation Experiment (WOCE) Conductivity-Temperature-Depth data collected during February–March 1996 along 30° E, as well as Levitus climatology. A southward shift of 2° latitude (between 45° E and 57°30′ E) was recorded for the two predominant frontal structures, i.e., the Agulhas Return Front and Southern Subtropical Front, which is attributed to the influence of seabed topography on hydrographic parameters. No significant spatial variation of these fronts was noted between the 30° E and 45° E meridional sections. Between latitudes 31° S and 42° S, the temperature and salinity structures show deepening over the ridges. The Antarctic Circumpolar Current core was detected between 40°15′ S and 43° S.     

Second-order ridge axis discontinuities in the south Atlantic: Morphology,structure, and evolution

Continuous along-axis Sea Beam coverage of the slow-intermediate spreading (34–38 mm yr⁻¹ full rate) southern Mid-Atlantic Ridge (25°–27°30′S and 31°–38° S) shows that the ridge axis is segmented by both rigid and non-rigid discontinuities. Following the model of Macdonald et al. (1988b), a hierarchy of four orders is proposed for ridge axis discontinuities based on a continuum of relative age and distance offset across the discontinuites. This paper discusses the characteristics associated with five second-order discontinuities found in the areas surveyed. First-order discontinuities represent rigid offsets, transform faults, whereas non-rigid discontinuities fall into the second, third and fourth orders. Like transform fault boundaries, second-order discontinuities have distinctive morphologic signatures both on and off-axis-discordant zones — and therefore are better defined than third- or fourth-order discontinuities. Second-order discontinuities are offsets that range in distance from less than 10 km to approximately 30 km and vary in age offset from 0.5 to approximately 2.0 m.y. The variable morphotectonic geometries associated with these discontinuities indicate that horizontal shear strains are accommodated by both extensional and strike-slip tectonism and that the geometries are unstable in time. Three characteristic geometries are recognized: (1)en echelon jog in the plate boundary where ridge axis tips overlap slightly, (2)en echelon jog in the plate boundary where ridge axes are separated by an extensional basin whose long axis is oriented parallel to the strike of the adjoining ridge axes, and (3) oblique offset characterized by a large extensional basin that is oriented approximately 45° to the strike of the ridge axes. In the case of the third type, evidence for short strands of strike-slip tectonism that link an obliquely oriented extensional basin flanking ridge tips is often apparent. Analysis of the detailed bathymetric and magnetic data collected over the second-order discontinuities and their off axis terrain out to 5–7 m.y. documents that second-order discontinuities can follow several evolutionary paths: they can evolve from transform fault boundaries through prolonged asymmetric spreading, they may migrate along strike leaving a V-shaped wake, and they may remain in approximately the same position but oscillate slightly back and forth. In addition, a small change in the pole of relative motion occurring 4–5 Ma is thought to have resulted in the initiation of at least one second-order discontinuity in the survey area. A geologic model is proposed which involves the interplay of lithospheric thickness, asymmetric spreading, temporal and spatial variability of along-axis magmatic input and changes in the poles of relative motion to explain the origin, morphology and evolution of second-order ridge axis discontinuities.     

The Mid-atlantic Ridge (31°S–34°30′S): Temporal and spatial variations of accretionary processes

The ridge located between 31° S and 34°30′S is spreading at a rate of 35 mm yr⁻¹, a transitional velocity between the very slow (≤20 mm yr⁻¹) opening rates of the North Atlantic and Southwest Indian Oceans, and the intermediate rates (60 mm yr⁻¹) of the northern limb of the East Pacific Rise, and the Galapagos and Juan de Fuca Ridges. A synthesis of multi-narrow beam, magnetics and gravity data document that in this area the ridge represents a dynamically evolving system. Here the ridge is partitioned into an ensemble of six distinct segments of variable lengths (12 to 100 km) by two transform faults (first-order discontinuities) and three small offset (< 30 km) discontinuities (second-order discontinuities) that behave non-rigidly creating complex and heterogeneous morphotectonic patterns that are not parallel to flow lines. The offset magnitudes of both the first and second-order discontinuities change in response to differential asymmetric spreading. In addition, along the fossil trace of second-order discontinuities, the lengths of abyssal hills located to either side of a discordant zone are observed to lengthen and shorten creating a saw-toothed pattern. Although the spreading rate remains the same along the length of the ridge studied, the morphology of the spreading segments varies from a deep median valley with characteristics analogous to the rift segments of the North Atlantic to a gently rifted axial bulge that is indistinguishable from the shape and relief of the intermediate rate spreading centers of the East Pacific Rise (i.e., 21°N). Like other carefully surveyed ridge segments at slow and fast rates of accretion, the along-axis profiles of each ridge segment are distinctly convex upwards, and exhibit along-strike changes in relief of 500m to 1500 between the shallowest portion of the segment (approximate center) and the segment ends. Such spatial variations create marked along-axis changes in the morphology and relief of each segment. A relatively low mantle Bouguer anomaly is known to be associated with the ridge segment characterized by a gently rifted axial bulge and is interpreted to indicate the presence of focused mantle upwelling (Kuo and Forsyth, 1988). Moreover, the terrain at the ends of each segment are known to be highly magnetized compared to the centers of each segment (Carbotte et al, 1990). Taken together, these data clearly establish that these profound spatial variations in ridge segment properties between adjoining segments, and along and across each segment, indicate that the upper mantle processes responsible for the formation of this contrasting architecture are not solely related to passive upwelling of the asthenosphere beneath the ridge axis. Rather, there must be differences in the thermal and mechanical structure of the crust and upper mantle between and along the ridge segments to explain these spatial variations in axial topography, crustal structure and magnetization. These results are consistent with the results of investigations from other parts of the ridge and suggest that the emplacement of magma is highly focused along segments and positioned beneath the depth minimum of a given segment. The profound differences between segments indicate that the processes governing the behavior of upwelling mantle are decoupled and the variations in the patterns of axis flanking morphology and rate of accretion indicate that processes controlling upwelling and melt production vary markedly in time as well. At this spreading rate and in this area, the accretionary processes are clearly three-dimensional. In addition, the morphology of a ridge segment is not governed so much by opening rate as by the thermal structure of the mantle which underlies the segment.     

Machias Seamount,Western Samoa: Sediment remobilization,tectonic dismemberment and subduction of a guyot

Machias Seamount, located at 14°57′S, 172°14′W about 140 km south of Savaii, Western Samoa, rises to less than 700 m depth. This guyot is situated on the NE (seaward) flank of the Tonga Trench where depths reach 7,700 m. A SeaMARC II bathymetric and side-scan sonar survey shows that faults aligned parallel to the local strike of the Tonga Trench dissect the trench-facing half of the guyot. Faulting is largely confined to the interval within 35 km of the trench axis. Faults are absent and sediment flows are radially distributed on the NE-facing flank of the guyot. Sediment flow is pervasive on the trench-facing (SW) slope, but the pattern is not radial because the neo-tectonic fabric controls resedimentation.     

Newly discovered hydrothermal fields along the ultraslow-spreading Southwest Indian Ridge around 63°E

The ultraslow-spreading Southwest Indian Ridge(SWIR) to the east of the Melville fracture zone is characterized by very low melt supply and intensive tectonic activity. Due to its weak thermal budget and extremely slow spreading rate, the easternmost SWIR was considered to be devoid of hydrothermal activity until the discovery of the inactive Mt. Jourdanne hydrothermal field(27°51′S, 63°56′E) in 1998. During the COMRA DY115-20 cruise in2009, two additional hydrothermal fields(i.e., the Tiancheng(27°51′S, 63°55′E) and Tianzuo(27°57′S, 63°32′E)fields) were discovered. Further detailed investigations of these two hydrothermal sites were conducted by Chinese manned submersible Jiaolong in 2014–2015. The Tiancheng filed can be characterized as a lowtemperature(up to 13.2°C) diffuse flow hydrothermal field, and is hosted by fractured basalts with hydrothermal fauna widespread on the seafloor. The Tianzuo hydrothermal field is an inactive sulfide field, which is hosted by ultramafic rocks and controlled by detachment fault. The discovery of the three hydrothermal fields around Segment #11 which receives more melt than the regional average, provided evidence for local enhanced magmatism providing heat source to drive hydrothermal circulation. We further imply that hydrothermal activity and sulfide deposits may be rather promising along the easternmost SWIR.     

Kinematic elements of Antarctic Intermediate Water in the western South Atlantic

The northward flowing Antarctic Intermediate Water (AAIW) is a major contributor to the large-scale meridional circulation of water masses in the Atlantic. Together with bottom and thermocline water, AAIW replaces North Atlantic Deep Water that penetrates into the South Atlantic from the North. On the northbound propagation of AAIW from its formation area in the south-western region of the Argentine Basin, the AAIW progresses through a complex spreading pattern at the base of the main thermocline. This paper presents trajectories of 75 subsurface floats, seeded at AAIW depth. The floats were acoustically tracked, covering a period from December 1992 to October 1996. Discussions of selected trajectories focus on mesoscale kinematic elements that contribute to the spreading of AAIW. In the equatorial region, intermittent westward and eastward currents were observed, suggesting a seasonal cycle of the AAIW flow direction. At tropical latitudes, just offshore the intermediate western boundary current, the southward advection of an anticyclonic eddy was observed between 5^°S and 11°S. Farther offshore, the flow lacks an advective pattern and is governed by eddy diffusion. The westward subtropical gyre return current at about 28°S shows considerable stability, with the mean kinetic energy to eddy kinetic energy ratio being around one. Farther south, the eastward deeper South Atlantic Current is dominated by large-scale meanders with particle velocities in excess of 60 cm s^-1. At the Brazil–Falkland Current Confluence Zone, a cyclonic eddy near 40°S 50°W seems to act as injector of freshly mixed AAIW into the subtropical gyre. In general, much of the mixing of the various blends of AAIW is due to the activity of mesoscale eddies, which frequently reoccupy similar positions.     

Geophysical investigations over a segment of the Central Indian Ridge, Indian Ocean

 Swath bathymetric, gravity, and magnetic studies were carried out over a 55 km long segment of the Central Indian Ridge. The ridge is characterized by 12 to 15 km wide rift valley bounded by steep walls and prominent volcanic constructional ridges on either side of the central rift valley. A transform fault at 7°45′S displaces the ridge axis. A mantle Bouguer anomaly low of −14 mGals and shallowing of rift valley over the middle of the ridge segment indicate along axis crustal thickness variations. A poorly developed neovolcanic zone on the inner rift valley floor indicate dominance of tectonic extension. The off-axis volcanic ridgs suggest enhanced magmatic activity during the recent past. Received: 24 May 1996 / Rivision received: 13 January 1997     

Dissolved and labile particulate Zr,Hf, Nb,Ta, Mo and W in the western North Pacific Ocean

Dissolved and labile particulate Zr, Hf, Nb, Ta, Mo and W were determined at stations K1 (51°N, 165°E), K2 (47°N, 160°E), KNOT (44°N, 155°E) and 35N (35°N, 160°E) in the western North Pacific Ocean. A portion of seawater for dissolved species (D) was passed through a 0.2 μm Nuclepore filter and acidified to pH 2.2 with HCl and HF. A portion of seawater for acid-dissolvable species (AD) was acidified without filtration. Labile particulate (LP) species is defined as AD minus D, which represents a chemically labile fraction of particulate species. D-Zr, Hf and Ta increase with depth, Nb shows a slight depletion in surface water, whereas Mo and W have a conservative vertical profile. The concentration range of D-Zr, Hf, Nb, Ta and W is 31–275, 0.14–0.95, 4.0–7.2, 0.08–0.29 and 40–51 pmol kg⁻¹, respectively, whereas that of Mo is 97–105 nmol kg⁻¹. LP-species of Zr, Hf and Ta account for 10–14% of AD in average and increase up to 25% below 4000 m, whereas those for Mo and W are negligible. In contrast, LP-Nb shows maxima (up to 27%) in surface water. We also found that D-Zr/Hf, Nb/Ta and Mo/W mole ratios generally increase in the order continental crust < river water < coastal sea < open ocean.     

Intense hydrothermal activity at the axis of the east pacific rise near 13°N: Sumbersible witnesses the growth of sulfide chimney

A submersible study of a fast spreading (12 cm yr^-1) Mid-Ocean ridge segment (East Pacific Rise near 12°50′ N) led to the discovery of intense hydrothermal activity. Twenty four sites with active vents and sixty inactive hydrothermal deposits were found within a narrow graben averaging about 300 m in width along a 20 km long segment of the ridge crest. The graben is floored with fresh basaltic sheet flows including collapsed pits or lava lake structures. From both deep towed camera stations and manned submersible observations, it is estimated that the average spacing between the ridge axis hydrothermal deposits averaging in size 10–50 m in diameter lies between 100 to 200 m. The hydrothermal deposits found in the central graben are believed to have formed rapidly (on the order of a few decades). Detailed investigations of one active site have enabled us to witness the growth of an active chimney which increased its height by 40 cm in 5 days i.e. 8 cm per day. Extensive hydrothermal deposits were discovered on an off-axis seamount located 6 km East of the ridge axis. The hydrothermal deposits found on both the ridge axis and on the seamount are similar in composition and consist essentially of zinc, copper and iron mineral phases. Chemical studies conducted on the venting fluids (320°C) showed that the concentration of the dissolved major metal ions (Fe, Mn, and Zn) is about 0.10–0.13 gl^-1. If we accept an average flow rate of 10ls^-1 based on visual observations the mass of metallic products spewing out from an active chimney must be about 100 kg per day.