赣南西华山钨矿床的流体混合作用:基于H、O同位素模拟分析

赣南西华山钨矿床是我国典型的大型石英脉型黑钨矿矿床.H、O同位素的研究表明,该矿床δD值-43‰～-66‰,石英δ18O值2.3‰～13.2‰,对应的成矿流体δ18O值-8.7‰～7.6‰,表明成矿流体为岩浆水与大气降水的混合流体.不同机制下矿物O同位素模拟计算表明,冷却、沸腾和混合作用所形成矿物的O同位素组成明显不同...     

新疆萨喀尔得铜矿C-H-O-S同位素特征简

新疆萨喀尔得铜矿属中低温热液型,该矿石英和方解石样品中δ13CPDB值为-17.3‰~-0.7‰,δ18OSMOW为16.2‰~22.4‰,δ18OH2O水值为6.9‰~12.5‰,δD变化于-73.8‰~-52.4‰之间。研究表明,成矿流体主要来源于深部发生循环加热的建造水,并混合变质水和岩浆水;成矿早期流体中的C主要来源于地层水或大气降水,晚期有深部岩浆水的加入。δ34S值变化范围为0.2‰~6.1‰,表明流体中的S主要来自岩浆或上地幔。     

哀牢山南段长安金矿床成矿流体特征及成因类型探讨

长安金矿床是三江造山带哀牢山成矿带南段大型矿床之一,就位于甘河断裂的脆性破碎带内.其成矿流体具有中低温、中低盐度的特点,气相成分以H2O、CO2为主,主成矿期流体中CO2含量可达21.162mo1％～32.832mo1％;液相成分以Cl-、K+、Na+为主.成矿流体的δ13CCo2值为-3.427‰～8.749‰,显示海相碳酸盐源特征并与岩浆活动有关;δD值为-111‰～ -78.383‰,δ18O值介于10.527‰～13.565‰,δ34S值集中分布在+1‰～+3‰之间,综合表明长安金矿流体具有岩浆热液的性质,同时,源自海相碳酸盐地层的变质水也参与了成矿作用.在哀牢山南段的金平地区,受新生代大规模富碱性岩浆沿断裂上侵的影响,含金的岩浆气液在运动过程中混合浅部流体并活化、萃取矿区地层及有关地质体中的金元素,使其转入溶液形成含金的成矿流体;当成矿流体运移到浅部有利构造或岩性部位时,物理化学条件的变化,促使Au等成矿物质快速沉淀、富集形成微细浸染状矿化.综合研究认为,长安金矿床兼具造山型和卡林型金矿床的典型地质地球化学特征,可被厘定为类卡林型金矿床,为卡林型与造山型之间的过渡类型.     

新疆小热泉子铜矿床成因

新疆小热泉子铜矿床位于古板块缝合带上,在石炭纪为火山喷流沉积环境.矿体具明显的沉积和后期热液改造特征,硫同位素δ(34S)值为-0.11‰～11.10‰,平均为5.73‰,接近大气降水的δ(34S)值.δ(DH2O)为-78.1‰～-77.0‰,明显低于变质水区域值,而接近于岩浆水区域值(-80‰～-40‰),在δ(18O)-δ(D)相关图上,数据点落在近岩浆水区域,表明成矿流体可能为次火山热液与地下水的混合流体.小热泉子铜矿床中黄铁矿的w(Se)高(0.009 5%～0.37%),w(S)/w(Se)值为143～2 137,反映成矿与岩浆热液作用关系密切.矿石中石英的流体包裹体均一温度反映出两阶段热液成矿的特征.矿床硫化物K-Ar同位素年龄显示,矿床的模式年龄有2个年龄段:斑点状闪锌矿与结核状闪锌矿的模式年龄分别为387.2,444.9 Ma,二者组成的等时线年龄为339.1 Ma,与地层年龄早石炭世较接近,可作为火山喷流沉积成矿阶段的起始时间;浸染状黄铜矿的模式年龄为230.2 Ma,可作为热液期中后期的成矿年龄.综合分析矿床成矿特征和地球化学数据认为,该矿床为火山喷流沉积-热液叠加改造型矿床.     

新疆萨喀尔得铜矿C-H-O-S同位素特征

新疆萨喀尔得铜矿属中低温热液型,该矿石英和方解石样品中^δ13CPDB值为-17．3‰— -0．7％,δ^18OSMOW为16．2‰-22．4‰ δ18OH2O 水值为6.9‰-12.5‰水值为6．9‰-12．5‰,8D变化于-73．8‰—-52．4‰之间。研究表明,成矿流体主要来源于深部发生循环加热的建造水,并混合变质水和岩浆水;成矿早期流体中的C主要来源于地层水或大气降水,晚期有深部岩浆水的加入。^δ^34S值变化范围为0．2‰-6．1％o,表明流体中的S主要来自岩浆或上地幔。     

新疆阿合奇县布隆金矿床成矿流体及成矿作用

新疆阿合奇县布隆石英重晶石脉型金矿床是一个少见的金矿新类型 ,其中流体包裹体类型主要有NaCl H2 O型、CO2 H2 O±CH4型和CO2 H2 O NaCl型。均一温度变化范围大 ,从 1 5 9～ 390℃ ,金主成矿阶段温度集中于 2 0 0～ 340℃ ,流体盐度为 2 .4 2 %～ 1 9.2 9%NaCleq ,但各阶段含石盐子晶多相包裹体的盐度高达 2 9.0 2 %～ 4 6 .2 %NaCleq。成矿流体密度为 0 .731～ 1 .1 32g/cm3 。成矿流体气相成分中以H2 O和CO2 为主 ,含少量N2 ,CH4,C2 H6,H2 S等 ;液相成分以Na+ 、Cl-为主 ,其次是Ca2 + ,K+ ,Mg2 + ,SO2 -4。布隆金矿床石英中流体包裹体的δ1 3 CPDB值为 - 4 .6‰～ - 1 .4‰ ,δ1 8OSMOW 为 1 7.2‰～2 1 .1‰ ,δ1 8O水 值为 6 .7‰～ 1 4 .7‰ ,δD变化于 - 70‰～ - 5 5‰ ,表明成矿流体主要来源于建造水 ,并混合少量岩浆水和大气降水 ,流体中的碳主要来源于海相碳酸盐岩。物理化学条件和流体组成的改变以及流体的不混溶作用在成矿过程中起了重要作用     

青藏高原东南缘哀牢山大坪金矿成矿流体演化

大坪金矿是青藏高原东南缘哀牢山构造带中的大型石英脉型金矿床,由北矿区和南矿区组成.北矿区和南矿区的成矿流体包裹体均一温度及其氢、氧、硫同位素、气液相成份的测试结果表明其成矿温度为:187～329℃(平均为281℃)和168～338℃(平均为264℃)、氢同位素组成(δDV-SMOW)为:-70‰～-81‰和-71‰～-86‰、氧同位素组成(δ18OH2o)为:2.9‰～9.8‰和3.5‰～5.1‰、硫同位素值(δ34S)为:0.7‰～15.5‰和10.6‰～15.8‰.在氢-氧同位素图解上,所有样品均落在岩浆水和地下水趋势线之间.其中,北矿区样品更靠近岩浆水区域,部分样品落在岩浆水区域内,南矿区相时靠近地下水区域.流体包裹体成份分析表明,气相成份主要为H2O和CO2,其次为N2,并含有少量CH4、C2H2、C2H4、C2H6和CO;离子成份主要为K+、Na+、Ca2+、Cl-和SO42-,及少量NO3-、Mg2+、F-和Br-.含金石英脉ESR定年数据揭示了北矿区成矿时代为27.2～29.1Ma,南矿区为17.3～22.1Ma.总体来看,北矿区成矿时代要早于南矿区;北矿区成矿流体是以岩浆流体为主,并有少量地下水混入,而南矿区成矿流体中地下水的参与程度要大于北矿区;成矿流体具有从北矿区向南矿区、从早到晚以及从深部向浅部,岩浆流体组分相对减少,地下水组分逐渐增加的演化趋势.     

甘肃岷县马坞金矿同位素特征与成因探讨

马坞金矿位于岷县东部,属岷-礼成矿带的中段,为一中型金矿。赋矿地层及成矿地质背景与中川地区的其他金矿床具有相似性。主成矿期石英的氢氧同位素测试结果表明：δD为-78‰～-98‰,δ^18OSMOW（矿物？）为18.0‰～20.2‰,δ18O水为0.45‰～8.54‰,显示成矿流体为岩浆水、变质水和大气降水的混合水,其中以岩浆水和变质水为主;主成矿期黄铁矿同位素的测定结果显示：δ34S为＋7.1‰～＋7.9‰,平均＋7.65‰。可见其变化范围较小,均一性强,具有地层硫特征。结合区内已有同位素资料及区域成岩成矿背景,推断马坞金矿的成矿作用与区内中川岩体关系密切,其中成矿流体主要来源于岩浆与地层,混入少量大气降水;成矿物源主要来自地层,另有深部物源参与成矿。     

内蒙古林西边家大院银多金属矿床同位素地球化学特征及成矿物质来源探讨

边家大院银多金属矿床位于大兴安岭成矿带南段,是一个典型的热液脉型银多金属矿床。基于稳定同位素C、H、O、S和放射性Pb同位素的测试和分析,对边家大院银多金属矿床成矿流体及物质来源进行示踪。同位素测试结果表明:成矿流体中水的δD_(水-SMOW)值为-138.5‰~-111.7‰,δ~(18)O_(水-SMOW)值为-8.85‰~9.38‰,表明成矿流体为岩浆水与大气降水的混合物。热液方解石δ~(13)C_(PDB)值为-7.7‰~-2.67‰,δ~(18)O_(SMOW)为-0.41‰~6.03‰,表明热液矿物方解石是2个阶段成矿作用的产物,成矿早阶段流体与岩浆水特征相似,碳主要来源于岩浆,成矿晚阶段流体具有大气降水的特征。边家大院银多金属矿床矿石硫化物δ~(34)S值为0.76‰~4.4‰,显示银铅锌矿体的形成与岩浆作用密切相关,硫主要来自岩浆源。矿石样品~(208)Pb/~(204)Pb值介于38.1~38.634,~(207)Pb/~(204)Pb值介于15.518~15.681,~(206)Pb/~(204)Pb值介于18.155~18.284,表明成矿与岩浆作用关系密切,成矿流体中铅主要来自深源岩浆。成矿作用的发生是在一种总硫浓度比较低的平衡体系中进行的。边家大院银多金属矿床的成因类型属于火山-次火山热液脉状银多金属矿床。     

湖南白马山-龙山金矿带包裹体-同位素地球化学及成矿流体特征

文章测试了白马山-龙山金矿带中龙山、古台山、高家坳一带金矿床的石英包裹体水的δ(18)D‰、δ(18)O‰值,龙山、古台山一带金矿床石英δ(18)D值具有相似变化范围,变化范围为-59‰～-66‰,极差不大(7‰),分析结果认为本区成矿流体与区域液体主要为大气降水.而高家坳一带金矿中石英δD值变化较大为-57.7‰～-87.7‰,极差达30‰,矿液为封存于地层中的原生水与大气降水混合而成.龙山一带金矿床硫化物的δ(34)S值变化不大,大部分样品集中在-2.O‰～ 2.O‰之间,硫主要来源于深部岩浆,少量来自于地层.产于中泥盆统半山组中的高家坳一带金矿硫化物δ(34)S值变化范围大,集中在6.21‰～22.25‰的,反映其硫主要来自沉积岩层的硫化物.这些同位素特征表明,白马山-龙山金矿带经历了多期成矿作用,早期为成矿流体与大气降水混合成矿;晚期为地下热水为主,有变质水及岩浆水混合的混合型成矿溶液.     

The terrestrial fauna of the Late Triassic Pant-y-ffynnon Quarry fissures,South Wales,UK and a new species of Clevosaurus (Lepidosauria: Rhynchocephalia)

Pant-y-ffynnon Quarry in South Wales yielded a rich cache of fossils in the early 1950s, including articulated specimens of new species (the small sauropodomorph dinosaur Pantydraco caducus and the crocodylomorph Terrestrisuchus gracilis), but no substantial study of the wider fauna of the Pant-y-ffynnon fissure systems has been published. Here, our overview of existing specimens, a few described but mostly undescribed, as well as freshly processed material, provides a comprehensive picture of the Pant-y-ffynnon palaeo-island of the Late Triassic. This was an island with a relatively impoverished fauna dominated by small clevosaurs (rhynchocephalians), including a new species, Clevosaurus cambrica, described here from a partially articulated specimen and isolated bones. The new species has a dental morphology that is intermediate between the Late Triassic Clevosaurus hudsoni, from Cromhall Quarry to the east, and the younger C. convallis from Pant Quarry to the west, suggesting adaptive radiation of clevosaurs in the palaeo-archipelago. The larger reptiles on the palaeo-island do not exceed 1.5?m in length, including a small carnivorous crocodylomorph, Terrestrisuchus, and a possible example of insular dwarfism in the basal dinosaur Pantydraco.     

Définition d'une limite multicritère ; stratigraphie du passage Campanien–Maastrichtien du site géologique de Tercis (Landes,SW France)Definition of a multi-criteria boundary; stratigraphy of the Campanian–Maastrichtian interval of the geological site at Tercis (Landes,SW France)

Lithostratigraphy, physicochemical stratigraphy, biostratigraphy, and geochronology of the 77–70 Ma old series bracketing the Campanian–Maastrichtian boundary have been investigated by 70 experts. For the first time, direct relationships between macro- and microfossils have been established, as well as direct and indirect relationships between chemo-physical and biostratigraphical tools. A combination of criteria for selecting the boundary level, duration estimates, uncertainties on durations and on the location of biohorizons have been considered; new chronostratigraphic units are proposed. The geological site at Tercis is accepted by the Commission on Stratigraphy as the international reference for the stratigraphy of the studied interval. To cite this article: G.S. Odin, C. R. Geoscience 334 (2002) 409–414.     

The effect of water on accessory phase solubility in subaluminous and peralkaline granitic melts

The solubilities of columbite, tantalite, wolframite, rutile, zircon and hafnon were determined as a function of the water contents in peralkaline and subaluminous granite melts. All experiments were conducted at 1035 °C and 2 kbar and the water contents of the melts ranged from nominally dry to approximately 6 wt.% H₂O. Accessory phase solubilities are not affected by the water content of the peralkaline melt. By contrast, solubilities are affected by the water content of the subaluminous melt, where the solubilities of all the accessory phases examined increase with the water content of the melt, up to 2 wt.% H₂O. At higher water contents, solubilities are nearly constant. It can be concluded that water is not an important control of accessory phase solubility, although the water content will affect diffusivities of components in the melt, thus whether or not accessory phases will be present as restite material. The solubility behaviour in the subaluminous and peralkaline melts supports previous spectroscopic studies, which have observed differences in the coordination of high field strength elements in dry vs. wet subaluminous granitic glasses, but not for peralkaline granitic glasses. Lastly, the fact that wolframite solubility increases with increasing water content in the subaluminous melt suggests that tungsten dissolved as a hexavalent species.     

Late Wuchiapingian (Late Dzhulfian,early Late Permian) limestone olistolites within the Tertiary flysch of Glypia Unit (Mount Parnon,central–eastern Peloponnesus,Greece)

Some olistolites reworked in a Tertiary flysch of Mount Parnon (Peloponnesus, Greece) exhibit a Late Permian assemblage, dominated by Paradunbarula (Shindella) shindensis, Hemigordiopsis cf. luquensis and Colaniella aff. minima. This association corresponds to the Late Wuchiapingian (=Late Dzhulfian), a substage whose algae and foraminifera are generally little known. Contemporaneous limestones crop out in the middle part of the Episkopi Formation in Hydra, but they are rather commonly reworked in Mesozoic and Cainozoic sequences. The palaeobiogeographical affinities shared by the foraminiferal markers of Greece, southeastern Pamir, and southern China, are very strong (up to the specific level), and are congruent with the Pangea B reconstructions. To cite this article: E. Skourtsos et al., C. R. Geoscience 334 (2002) 925–931.     

PALEONTOLOGY

正20141596 Liu Yunhuan(School of Earth Sciences and Resources,Chang’an University,Xi’an 710054,China);Shao Tiequan Early Cambrian Quadrapyrgites Fossils of Xixiang Boita in Southern Shaanxi Province(Journal of Earth Sciences and Environment,ISSN1672-6561,CN61-1423/P,35(3),2013,p.39-43,3 illus.,20 refs.)     

GEOCHEMICAL EXPLORATION

正20141719 Chen Zhijun(State Key Laboratory of Geological Processes and Mineral Resources,China University of Geosciences,Wuhan 430074,China);Chen Jianguo Automated Batch Mapping Solution for Serial Maps:A Case Study of Exploration Geochemistry Maps(Journal of Geology,ISSN1674-3636,CN32-1796/P,37(3),2013,p.456-464,2 illus.,2 tables,10 refs.)     

MICROPALAEONTOLOGY

正20140962 Chen Fenning(Xi’an Institute of Geology and Mineral Resources,Xi’an710054,China);Chen Ruiming Late Miocene-Early Pleistocene Ostracoda Fauna of Gyirong Basin,Southern Tibet(Acta Geologica Sinica,ISSN0001-5717,CN11-1951/P,87(6),2013,p.872-886,6illus.,56refs.)     

PETROLOGY

正1.IGNEOUS PETROLOGY20142008Cai Jinhui(Wuhan Center,China Geological Survey,Wuhan 430205,China);Liu Wei Zircon U-Pb Geochronology and Mineralization Significance of Granodiorites from Fuzichong Pb-Zn Deposit,Guangxi,South China(Geology and Mineral Resources of South China,ISSN1007-3701,CN42-1417/P,29(4),2013,p.271-281,7illus.,     

ENVIRONMENTAL GEOLOGY

正20141205Cheng Weiming(State Key Laboratory of Resources and Environmental Information System,Institute of Geographic Sciences and Natural Resources Research,CAS,Beijing 100101,China);Xia Yao Regional Hazard Assessment of Disaster Environment for Debris Flows:Taking Jundu Mountain,Beijing as an     

PROSPECTING EXPLORATION

正20141266Fan Chaoyan(Guangdong Provincial Key Laboratory of Mineral Resources and Geological Processes,Guangzhou 510275,China);Wang Zhenghai On Error Analysis and Correction Method of Measured Strata Section with Wire Projection Method(Journal of