PbSrNd isotopic data of Indian Ocean ridges: new evidence of large-scale mapping of mantle heterogeneities

A PbSrNd isotope study of South West and East Indian Ridges confirms that the Indian Ocean belongs to a specific regional isotopic domain, as previously suggested by the results from islands of this ocean. The isotopic domain defined by the Indian MORB is indeed different from that of the North Atlantic and East Pacific Oceans. This demonstrates that the convective circulation of the upper mantle does not allow a rapid homogenization from one region to the other.The isotopic data of the Indian ridges can be interpreted by a contamination model, in which the depleted upper mantle (identical to that under the North Atlantic) is contaminated by two different types of contaminant, one corresponding to the source of the “central Indian Ocean” islands (Amsterdam, St. Paul, Marion, Prince Edward, Réunion, Rodriguez, Mauritius), and the other to a source similar to that of Walvis or Ninety East aseismic ridges. These two contaminants would have contributed to the ridge volcanism in different proportions over time.     

Charge distribution on the atmospheric aerosol over the North Atlantic and the Indian Ocean

The distribution of electric charge on the marine aerosol was determined near the sea surface of the Indian Ocean and the North Atlantic during the final stage of the Snellius II-expedition. Mean values for small ion concentrationsn ⁺=455 cm^–3 andn ^–=340 cm^–3 were found over the Atlantic, whilen ⁺=310 andn ^–=250 cm^–3 were the mean values over the Indian Ocean. The ration ⁺/n^– increased from 1.2 to 2.0 with decreasing wind velocity. At wind velocities below 5 m/s 75% of the net space charge near the ocean surface was found to be carried by small ions.     

Late Cretaceous magnetic anomalies in the North Atlantic

An identification of anomalies 31–34 is presented for the North Atlantic. North of the Azores-Gibraltar Ridge this implies a revision of the identification of the magnetic anomalies older than anomaly 26. DSDP site 10 in the western North Atlantic appears to be located on the old end of anomaly 33. The relative spacings of anomalies 29–34 in the North and South Atlantic, North and South Pacific and Indian Oceans are compared and the estimated relative widths of the magnetic polarity intervals in the Late Cretaceous are revised.     

Long-Term Stability of Sea Surface Topography from Topex/Poseidon Altimetry

The stability of the mean ocean level was investigated using the T/P altimeter data of 1993-1997 in 39 blocks of about 30° by 30°: 20 blocks forming the Pacific Ocean, 10 the Atlantic, and 9 blocks in the Indian Ocean. The 1993-1997 yearly means were found to be nearly constant, the computed linear terms came out as: (0.9±1.3) mm/year for the Pacific, (0.3±1.1) mm/year for the Atlantic, (–0.7 ± 1.4) mm/year for the Indian Ocean. No SST model was used in the solution.     

Evolution of Atlantic-Pacific δC gradients over the last 2.5 m.y.

The evolution of interocean carbon isotopic gradients over the last 2.5 m.y. is examined using high-resolution δ¹³C records from deep sea cores in the Atlantic and Pacific Oceans. Over much of the Northern Hemisphere ice ages, relative reductions in North Atlantic Deep Water production occur during ice maxima. From 2.5 to 1.5 Ma, glacial reductions in NADW are less than those observed in the late Pleistocene. Glacial suppression of NADW intensified after 1.5 Ma, earlier than the transition to larger ice sheets around 0.7 Ma. At a number of times during the Pleistocene, δ¹³C values at DSDP Site 607 in the North Atlantic were indistinguishable from eastern equatorial Pacific δ¹³C values from approximately the same depth (ODP Site 677), indicating significant incursions of low δ¹³C water into the deep North Atlantic. Atlantic/Pacific δ¹³C values converge during glaciations between 1.13-1.05 m.y., 0.83-0.70 m.y., and 0.46-0.43 m.y. This represents a pseudo-periodicity of approximately 300 kyr which cannot easily be ascribed to global ice volume or orbital forcing. This partial decoupling, at low frequencies, of the δ¹⁸O and δ¹³C signals at Site 607 indicates that variations in North Atlantic deep water circulation cannot be viewed simply as a linear response to ice sheet forcing.     

Differences between Mean Sea Levels for the Pacific,Atlantic and Indian Oceans From Topex/Poseidon Altimetry

Geopotential values W of the mean equipotential surfaces representing the mean ocean topography were computed on the basis of four years (1993 - 1996) TOPEX/POSEIDON altimeter data: W = 62 636 854.10m ² s ^–2 for the Pacific (P), W = 62 636 858.20m ² s ^–2 for the Atlantic (A), W = 62 636 856.28m ²s^–2 for the Indian (I) Oceans. The corresponding mean separations between the ocean levels were obtained as follows: A – P = – 42 cm, I– P = – 22 cm, I – A = 20 cm, the rms errors came out at about 0.3 cm. No sea surface topography model was used in the solution.     

High-precision U–U–Th disequilibrium dating of the recent past: a review

Although it was demonstrated 20 years ago that mass spectrometric U–Th methods are capable of high-precision dating of young corals, the use of this approach to decipher recent environmental, climatic and archaeological records is still restricted and its potential has not yet been widely recognised. U–Th methods are typically used to determine the ages of carbonate materials such as speleothem and coral. Dating young carbonates of this sort is challenging. Their extremely low ²³⁰Th content necessitates stricter instrumental and laboratory conditions than those required for dating older samples. Moreover, analyses must be corrected for the presence of non-radiogenic ²³⁰Th, which is proportionally far more significant than in older samples. Nevertheless, 2σ precisions of around ±1–10 years are readily achievable for pristine coral samples dating from the last 500 years. Although the range of analytical precisions for speleothems may vary more widely depending on U concentrations and levels of non-radiogenic ²³⁰Th correction, published studies reveal 2σ precisions of around ±10–80 years for typical speleothems. This paper demonstrates how the U–Th method may be applied to establish the causes of recent coral mortality, to determine the recurrence interval of extreme wave events, to investigate earthquake frequency and neotectonic uplift, to reconstruct recent climatic history, and to understand settlement patterns and sociopolitical changes in Polynesia prior to European contact.     

Regional energetics over the North Pacific,South China Sea and the Indonesian seas during winter

The energy equation was applied to four limited regions to investigate the basic mechanisms through which area-averaged eddy kinetic energy is maintained during the northern winter. The regions selected for this study are as follows: extratropical North Pacific (24.2°N–44.6°N, 130°E–150°W), tropical eastern North Pacific (0°–19.6°N, 170°W–110°W), South China Sea and. Bay of Bengal (0°–19.6°N, 80°E–140°E), and Timor Sea and eastern Indian Ocean (0°–19.6°S, 80°E–140°E). The zonally averaged upper flows over the first region were found to be barotropically stable. In contrast, they were barotropically unstable over the second region; namely, eddy motions over the tropical eastern North Pacific are maintained by receiving energy from zonal flows via barotropic interaction. The third and fourth regions are characterized by the importance of the conversion process between eddy available potential and eddy kinetic energy.Contribution No. 77-5, Department of Meteorology, University of Hawaii, USA.     

Vertical concentration profiles of lead in the Central Pacific at 15°N and 20°S

Concentrations of lead were measured in a surface transect and at two vertical profile stations (15°N and 20°S) in the Central Pacific. These measurements complement similar measurements made earlier in the North Pacific at 33°N and in the Northwest Atlantic at 34°N [1,2], as well as recent measurements of eolian lead input fluxes near each of these locations [3]. The new transect of surface water concentrations of lead corroborates previous measurements, which decrease from 13 ng/kg at 30°N to 4 ng/kg at 17°S in the Central Pacific [4]. This transect gradient is shown to overlie a similar geographic gradient of subsurface maximum concentrations of lead in the three Pacific vertical profile stations, decreasing from 14 ng/kg at 33°N to 11 ng/kg at 14°N to 2.5 ng/kg at 20°S. Lead concentrations at each of those locations exhibit maxima at 400 m, decreasing concentrations to 2500 m and approximately concentrations of 0.8–1.1 ng/kg below that depth. The subsurface maximum at the northwest Atlantic profile station (36 ng/kg at 34°N) is also congruent with surface water lead concentrations which decrease from 806 ng/kg to 32 ng/kg in an offshore transect from Rhode Island to 34°N, 66°W [5], and the shape of the Atlantic profile is congruent with those in the Pacific. There is a positive correlation between the magnitudes of eolian lead input fluxes and the magnitudes of the upper water maxima in lead concentration profiles at corresponding locations as follows: South Pacific easterlies 3 ng/cm² yr vs. 2.5 ng/kg; North Pacific easterlies 6 ng/cm² yr vs. 11 ng/kg; North Pacific westerlies 50 ng/cm² yr vs. 14 ng/kg; and North Atlantic westerlies 170 ng/cm² yr vs. 36 ng/kg.This relationship enables one to view the anthropogenic perturbations of the marine lead cycle on a global scale, since the industrial origin of eolian and seawater lead has been established by correlations between geographic patterns of industrial lead emissions to the atmosphere and isotopic ratios of industrial leads [3] and by geographic patterns of Pb/silicate-dust ratios and lead isotopic ratios in ocean surface waters [3–5]. These new data coupled with earlier biogeochemical data indicate that surface water concentrations of lead in the North Pacific and North Atlantic are now conservatively estimated to be 8 to 20-fold greater and those in the South Pacific are 2-fold greater than natural concentrations because of industrial emissions of lead to the atmosphere.     

Global upper ocean heat content and climate variability

Observational data from the Global Temperature and Salinity Profile Program were used to calculate the upper ocean heat content (OHC) anomaly. The thickness of the upper layer is taken as 300 m for the Pacific/Atlantic Ocean and 150 m for the Indian Ocean since the Indian Ocean has shallower thermoclines. First, the optimal spectral decomposition scheme was used to build up monthly synoptic temperature and salinity dataset for January 1990 to December 2009 on 1° × 1° grids and the same 33 vertical levels as the World Ocean Atlas. Then, the monthly varying upper layer OHC field (H) was obtained. Second, a composite analysis was conducted to obtain the total-time mean OHC field ([`([`(H)])] \bar{\bar{H}} ) and the monthly mean OHC variability ( [(\textH)\tilde] \widetilde{\text{H}} ), which is found an order of magnitude smaller than [^(\textH)] \widehat{\text{H}} . Third, an empirical orthogonal function (EOF) method is conducted on the residue data ( [^(\textH)] \widehat{\text{H}} ), deviating from [(\textH)\tilde] \widetilde{\text{H}}  +  [(\textH)\tilde] \widetilde{\text{H}} , in order to obtain interannual variations of the OHC fields for the three oceans. In the Pacific Ocean, the first two EOF modes account for 51.46% and 13.71% of the variance, representing canonical El Nino/La Nina (EOF-1) and pseudo-El Nino/La Nina (i.e., El Nino Modoki; EOF-2) events. In the Indian Ocean, the first two EOF modes account for 24.27% and 20.94% of the variance, representing basin-scale cooling/warming (EOF-1) and Indian Ocean Dipole (EOF-2) events. In the Atlantic Ocean, the first EOF mode accounts for 49.26% of the variance, representing a basin-scale cooling/warming (EOF-1) event. The second EOF mode accounts for 8.83% of the variance. Different from the Pacific and Indian Oceans, there is no zonal dipole mode in the tropical Atlantic Ocean. Fourth, evident lag correlation coefficients are found between the first principal component of the Pacific Ocean and the Southern Oscillation Index with a maximum correlation coefficient (0.68) at 1-month lead of the EOF-1 and between the second principal component of the Indian Ocean and the Dipole Mode Index with maximum values (around 0.53) at 1–2-month advance of the EOF-2. It implies that OHC anomaly contains climate variability signals.     

210Po and210Pb distributions in the central and eastern Indian Ocean

Disequilibrium between²¹⁰Po and²¹⁰Pb and between²¹⁰Pb and²²⁶Ra has been mapped in the eastern and central Indian Ocean based on stations from Legs 3 and 4 of the GEOSECS Indian Ocean expedition.²¹⁰Po/²¹⁰Pb activity ratios are less than 1.0 in the surface mixed layer and indicate a residence time for Po of 0.6 years.²¹⁰Po and²¹⁰Pb are generally in radioactive equilibrium elsewhere in the water column except at depths of 100–500 m, where Po may be returned to solution after removal from the surface water, and in samples taken near the bottom at a few stations.²¹⁰Pb excesses relative to²²⁶Ra are observed in the surface water but these excesses are not as pronounced as in the North Pacific and North Atlantic. The difference is attributable to a lower flux of²¹⁰Pb from the atmosphere to the Indian Ocean. Below the main thermocline,²¹⁰Pb activities increase with depth to a broad maximum before decreasing to lower values near the bottom. Departures from this pattern are especially evident at stations taken in the Bay of Bengal (where²¹⁰Pb/²²⁶Ra activity ratios as low as 0.16 are observed) and near the Mid-Indian Ridge. The data suggest that removal of²¹⁰Pb at oceanic boundaries, coupled with eddy diffusion along isopycnals, can explain gradients in²¹⁰Pb near the boundary. Application of a simple model including isopycnal diffusion, chemical removal, production and radioactive decay produces fits the observed²¹⁰Pb/²²⁶Ra gradients for eddy diffusion coeffients of ～ 10⁷ cm²/s. High productivity in surface waters of the Bay of Bengal makes this region a sink for reactive nuclides in the northern Indian Ocean.     

Paleobathymetry of the crest of spreading ridges related to the age of ocean basins

Measurements of the crest of the spreading ridge in the young ocean basins of the Afar region and Gulf of Aden and in the mature Indian, Atlantic, and Pacific Oceans show that the depth of the ridge crest is correlated (r = 0.99) with the logarithm of the age of the ocean basin. Ridge crests in a very young basin (Afar) are at sea level, at about 1.5 km in young basins (Gulf of Aden), and at about 2.6 km in mature basins (Indian, Atlantic, Pacific). A new curve that relates crestal depth and age of the ocean basin is coupled with the existing depth/age curve for oceanic crust in a comprehensive scheme which can be used for relating depth and age of oceanic crust.     

Variable influence of the atmospheric flux on the trace metal chemistry of oceanic suspended matter

The particulate concentrations of 17 trace metals, Al, Sc, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, Se, Ag, Sb, Au, Hg, Pb and Th have been measured in the marine atmosphere (58 samples) and in the deep waters (35 samples) of the Tropical North Atlantic. For oceanic suspended matter, our results are similar to those in samples from the Atlantic and the Pacific Oceans collected during the GEOSECS Program. Based on these results, we have made a flux balance for the mixed layer between input via the atmosphere and removal through small and large particles. These data show that the primary flux of suspended aluminosilicates in the Tropical North Atlantic is attributable to the atmospheric input. Elements Sc, Th, Fe, V, Mn, Co and Cr show high correlation with Al in the marine atmosphere. Of these elements, Fe, Mn, V, Co and Cr are influenced by additional processes such as biological, in the marine environment. For elements Ni, Cu, Zn, Se, Ag, Sb, Au, Hg and Pb, we observe high enrichments (relative to average crustal material) in the marine atmosphere which may be due, at least partially, to the influence of anthropogenic sources. These metals also show similar enrichments in deep ocean suspended matter. Model calculations indicate that the atmospheric flux may not control the deep ocean particulate chemistry of Ni, Cu, Zn, Ag, Sb, Au and Hg. Hence it is likely that, for these elements, the enrichment in the ocean is due to processes within the marine regime, for example their involvement in the biological cycle of the ocean. For Se and Pb, the atmospheric source looks to be the dominant contribution to their particulate concentration in seawater. In the deep North Atlantic, particulate Pb appears to be mostly of anthropogenic origin, which is not the case for Se.     

Energy Decay of the 2004 Sumatra Tsunami in the World Ocean

The catastrophic Indian Ocean tsunami generated off the coast of Sumatra on 26 December 2004 was recorded by a large number of tide gauges throughout the World Ocean. This study uses gauge records from 173 sites to examine the characteristics and energy decay of the tsunami waves from this event in the Indian, Atlantic and Pacific oceans. Findings reveal that the decay (e-folding) time of the tsunami wave energy within a given oceanic basin is not uniform, as previously reported, but depends on the absorption characteristics of the shelf adjacent to the coastal observation site and the time for the waves to reach the site from the source region. In general, the decay times for island and open-ocean bottom stations are found to be shorter than for coastal mainland stations. Decay times for the 2004 Sumatra tsunami ranged from about 13 h for islands in the Indian Ocean to 40–45 h for mainland stations in the North Pacific.     

Bismuth in the Atlantic and North Pacific: a natural analogue to plutonium and lead?

Bismuth has been analysed on samples from a vertical section from California to VERTEX IV, north of Hawaii, from a profile in the western Sargasso Sea and from an extensive suite of surface stations in the North and South Atlantic. Taken together with data from samples of Bermuda rain and from the Mississippi, Amazon and the Orinoco and its tributaries, a general outline of the processes controlling the Bi distribution in the ocean can be worked out. The dominant source in the open ocean is aeolian with the fluvial inputs being very small. Most of the aeolian input is probably derived from volcanoes; an anthropogenic flux may be important in the northwest Atlantic. Bismuth is scavenged in the mixed layer and regenerated at shallow depth to give a distribution in the northwest Pacific similar to that of^239,240Pu and anthropogenic Pb. Below 2 km the values are extremely low, in the range 20–50 fM, lower than the coexisting levels for²³²Th. The residence time of the element in the water column is sufficiently short that there are large concentration decreases between the Deep Waters of the Atlantic and Pacific. In the latter ocean, the element appears to reflect essentially one-dimensional processes.     

Tephrochronology of the Kamchatka–Kurile and Aleutian arcs: evidence for volcanic episodicity

Volcanic ash layers in North Pacific deep-sea sediment provide a record of episodic explosive volcanism in the Kamchatka–Kurile and Aleutian arcs over the past five million years. We counted 450 ash layers, determined layer thickness and cumulative ash thickness to quantify the flux of ash with time. We use this record to investigate the eruptive history of these arcs, test the reliability of the marine ash record, and inquire into the regional episodicity of North Pacific explosive volcanic history. Episodes of explosive volcanism occurred at approximately 0.2–0.5, 0.7–0.9, 1.5–1.7, and 2.5–2.65 Ma in the Kamchatka arc and 0.15–0.4, 1.7–1.8, 2.55–2.65, and at 3.0–3.1 Ma in the eastern Aleutian arc. These generally coeval eruptive episodes suggest that the pulses in explosive volcanism in the North Pacific enumerated here and recognized by others are regionally episodic over a wide portion of the Pacific rim and not just a response to local volcanogenic processes.     

全球海洋碳循环模式MOM4_L40对碳和营养物自然分布的模拟

本文介绍了国家气候中心发展的一个全球海洋碳循环环流模式,并分析评估了该模式的基本性能.该模式是在美国地球物理流体动力学实验室(GFDL,Geophysical Fluid Dynamics Laboratory)的全球海洋环流模式MOM4(Modular Ocean Model Version 4)基础上发展的一个垂直方向40层、包含生物地球化学过程的全球三维海洋碳循环环流模式,简称为MOM4_L40(Modular Ocean Model Version 4 With 40Levels).该模式在气候场强迫下长期积分1000年,结果分析表明,与观测相比,模式较好地模拟了海洋温度、盐度、总二氧化碳、总碱、总磷酸盐的表面和垂直分布特征.模拟的海洋总二氧化碳分布与观测基本相符,表层为低值区,其下为高值区,高值区域位于10°S—60°N之间,但2000m以上模拟值较观测偏小,2000m以下模拟值较观测偏大.总体来说,MOM4_L40模式是一个可信赖的海洋碳循环过程模拟研究工具.     

UUThTh systematics and the precise measurement of time over the past 500,000 years

We have developed techniques to measure the²³⁰Th abundance in corals by isotope dilution mass spectrometry. This, coupled with our previous development of mass spectrometric techniques for²³⁴U and²³²Th measurement, has allowed us to reduce significantly the analytical errors in²³⁸U²³⁴U²³⁰Th dating and greatly reduce the sample size. We show that 6 × 10⁸ atoms of²³⁰Th can be measured to ±30‰ (2σ) and 2 × 10¹⁰ atoms of²³⁰Th to ±2‰. The time over which useful age data on corals can be obtained ranges from a few years to 500 ky. The uncertainty in age, based on analytical errors, is ±5 y (2σ) for a 180 year old coral (3 g), ±44 y at 8294 years and ±1.1 ky at 123.1 ky (250 mg of coral). We also report²³²Th concentrations in corals (0.083–1.57 pmol/g) that are more than two orders of magnitude lower than previous values. Ages with high analytical precision were determined for several corals that grew during high sea level stands 120 ky ago. These ages lie specifically within or slightly postdate the Milankovitch insolation high at 128 ky and support the idea that the dominant cause of Pleistocene climate change is Milankovitch forcing.     

Heavy metal contents in growth bands of Porites corals: record of anthropogenic and human developments from the Jordanian Gulf of Aqaba

In order to assess pollutants and impact of environmental changes in the coastal region of the Jordanian Gulf of Aqaba, concentrations of six metals were traced through variations in 5 years growth bands sections of recent Porties coral skeleton. X-radiography showed annual growth band patterns extending back to the year 1925. Baseline metal concentrations in Porites corals were established using 35 years-long metal record from late Holocene coral (deposited in pristine environment) and coral from reef that is least exposed to pollution in the marine reserve in the Gulf of Aqaba. The skeleton samples of the collected corals were acid digested and analyzed for their Cd, Cu, Fe, Mn, Pb and Zn content using Flame Atomic Absorption Spectrophotometer (FAAS). All metal profiles (except Fe and Zn) recorded the same metal signature from recent coral (1925–2005) in which low steady baseline levels were displayed in growth bands older than 1965, similar to those obtained from fossil and unpolluted corals. Most metals showed dramatic increase (ranging from 17% to 300%) in growth band sections younger than 1965 suggesting an extensive contamination of the coastal area since the mid sixties. This date represents the beginning of a period that witnessed increasing coastal activities, constructions and urbanization. This has produced a significant reduction in coral skeletal extension rates. Results from this study strongly suggest that Porites corals have a high tendency to accumulate heavy metals in their skeletons and therefore can serve as proxy tools to monitor and record environmental pollution (bioindicators) in the Gulf of Aqaba.     

Seabirds indicate changes in the composition of plastic litter in the Atlantic and south-western Indian Oceans

I compare plastic ingested by five species of seabirds sampled in the 1980s and again in 1999-2006. The numbers of ingested plastic particles have not changed significantly, but the proportion of virgin pellets has decreased 44-79% in all five species: great shearwater Puffinus gravis, white-chinned petrel Procellaria aequinoctialis, broad-billed prion Pachyptila vittata, white-faced storm petrel Pelagodroma marina and white-bellied storm petrel Fregetta grallaria. The populations sampled range widely in the South Atlantic and western Indian Oceans. The most marked reduction occurred in great shearwaters, where the average number of pellets per bird decreased from 10.5 to 1.6. This species migrates between the South and North Atlantic each year. Similar decreases in virgin pellets have been recorded in short-tailed shearwaters Puffinus tenuirostris in the Pacific Ocean and northern fulmars Fulmarus glacialis in the North Sea. More data are needed on the relationship between plastic loads in seabirds and the density of plastic at sea in their foraging areas, but the consistent decrease in pellets in birds suggests there has been a global change in the composition of small plastic debris at sea over the last two decades.