Hydrated sulphuric acid in dense molecular clouds

We consider sulphur depletion in dense molecular clouds, and suggest hydrated sulphuric acid, H₂SO₄ ·  n H₂O, as a component of interstellar dust in icy mantles. We discuss the formation of hydrated sulphuric acid in collapsing clouds and its instability in heated regions in terms of the existing hot core models and observations. We also show that some features of the infrared spectrum of hydrated sulphuric acid have correspondence in the observed spectra of young stellar objects.     

Chemically driven desorption of CO from icy grains in dark clouds

The chemical desorption of an adsorbed CO molecule in the vicinity of H₂-forming sites on cosmic dust grains in cold dense clouds is investigated theoretically, mainly using a model based on a classical molecular dynamics computational simulation. As a model surface for icy mantles of dust grains, an amorphous water ice slab is generated at 10 K, and the first and the second H atoms are thrown on to the model surface to reproduce the recombination process of the two H atoms, H+H→H₂. Then, the time and space dependence of the local temperature increase of icy mantles caused by the release of H₂ formation energy in the vicinity of H₂-forming sites is examined. It is found that icy mantles are heated locally up to about 30 K in the surface region at R 4 Å and about 20 K at 4 R 6 Å, where R is the distance from the H₂-forming site. The critical temperature of CO desorption is estimated to be about 20–30 K under conditions in typical dense clouds, which might be seen to be comparable to the above result. However, the lifetime of local heating of icy mantles is found to be too short, compared with the time-scale of CO desorption (10¹³ s) and that for H₂ forming in the vicinity of an adsorbed CO molecule (more than 2×10¹³ s). Thus, it is found that the efficiency of chemical desorption of CO on a large dust grain is negligible. On the other hand, chemical desorption can occur on a small dust grain with size less than 20 Å.     

Desorption from interstellar ices

The desorption of molecular species from ice mantles back into the gas phase in molecular clouds results from a variety of very poorly understood processes. We have investigated three mechanisms: desorption resulting from H₂ formation on grains, direct cosmic ray heating and cosmic ray-induced photodesorption. Whilst qualitative differences exist between these processes (essentially deriving from the assumptions concerning the species selectivity of the desorption and the assumed threshold adsorption energies, E _t), all the three processes are found to be potentially very significant in dark cloud conditions. It is therefore important that all three mechanisms should be considered in studies of molecular clouds in which freeze-out and desorption are believed to be important.
Employing a chemical model of a typical static molecular core and using likely estimates for the quantum yields of the three processes, we find that desorption by H₂ formation probably dominates over the other two mechanisms. However, the physics of the desorption processes and the nature of the dust grains and ice mantles are very poorly constrained. We therefore conclude that the best approach is to set empirical constraints on the desorption, based on observed molecular depletions – rather than try to establish the desorption efficiencies from purely theoretical considerations. Applying this method to one such object (L16 89B) yields upper limits to the desorption efficiencies that are consistent with our understanding of these mechanisms.     

Desorption processes and the deuterium fractionation in molecular clouds

Several processes have been suggested as ways of returning accreted grain mantles to the gas, thus preventing the total removal of molecules from the gas phase in dark quiescent clouds. We attempt to distinguish between them by considering not only the calculated gas-phase abundances, but also the ratio of the abundances of deuterated species to non-deuterated species. We find that the D/H ratio in molecules is relatively model-independent, but that desorption due to the formation of H₂ on grains gives the best overall agreement with the observations.     

Measurements of the 44-μm band of H2O ice deposited on amorphous carbon and amorphous silicate substrates

We present 20–110 µm absorbance spectra of H₂O ice, deposited on amorphous carbon and silicate substrates, obtained over the 10–140 K temperature range. The measurements have been carried out in a manner that simulates the deposition, warming and cooling of H₂O ice mantles on interstellar and circumstellar grains. For H₂O ice films deposited on these substrates we find (i) similar 44-µm-band peak wavelength temperature dependences, (ii) no bandshape differences in the respective spectra, and (iii) a structural phase transition occurring between 120 and 130 K. In comparison with published data obtained using a polyethylene substrate, the 52-µm feature (the longitudinal optical mode) observed in our spectra is less prominent. This suggests the presence of material-dependent substrate effects that can alter the appearance of the H₂O far-infrared spectrum. The crystallization temperature of H₂O ice films deposited on our amorphous silicate substrate is significantly different from that reported by Moore et al. (1994) , who found crystallization temperatures down to < 20 K for ice also deposited on an amorphous silicate substrate. This is attributed to differences in the surface structures of the respective substrates. This may indicate that, at least in the context of laboratory measurements, substrate material composition is not as significant as substrate surface structure.     

Probing the surfaces of interstellar dust grains: the adsorption of CO at bare grain surfaces

A solid-state feature was detected at around 2175 cm⁻¹ towards 30 embedded young stellar objects in spectra obtained using the Infrared Spectrometer and Array Camera at the European Southern Observatory Very Large Telescope. We present results from laboratory studies of CO adsorbed at the surface of zeolite wafers, where absorption bands were detected at 2177 and 2168 cm⁻¹ (corresponding to CO chemisorbed at the zeolite surface) and 2130 cm⁻¹ (corresponding to CO physisorbed at the zeolite surface), providing an excellent match to the observational data. We propose that the main carrier of the 2175-band is CO chemisorbed at bare surfaces of dust grains in the interstellar medium. This result provides the first direct evidence that gas–surface interactions do not have to result in the formation of ice mantles on interstellar dust. The strength of the 2175-band is estimated to be  ∼4 × 10⁻¹⁹ cm  molecule⁻¹. The abundance of CO adsorbed at bare grain surfaces ranges from 0.06 to 0.16 relative to H₂O ice, which is, at most, half of the abundance (relative to H₂O ice) of CO residing in H₂O-dominated ice environments. These findings imply that interstellar grains have a large (catalytically active) surface area, providing a refuge for interstellar species. Consequently, the potential exists for heterogeneous chemistry to occur involving CO molecules in unique surface chemistry pathways not currently considered in gas grain models of the interstellar medium.     

Photometric distances to nine dark globules

Distances to nine dark globules are determined by a method using optical ( VRI ) and near-infrared (near-IR) ( JHK ) photometry of stars projected towards the field containing the globules. In this method, we compute intrinsic colour indices of stars projected towards the direction of the globule by dereddening the observed colour indices using various trial values of extinction   A _V   and a standard extinction law. These computed intrinsic colour indices for each star are then compared with the intrinsic colour indices of normal main-sequence stars and a spectral type is assigned to the star for which the computed colour indices best match with the standard intrinsic colour indices. Distances ( d ) to the stars are determined using the   A _V   and absolute magnitude  ( M_V )  corresponding to the spectral types thus obtained. A distance versus extinction plot is made and the distance at which   A _V   undergoes a sharp rise is taken to be the distance to the globule. All the clouds studied in this work are in the distance range 160–400 pc. The estimated distances to dark globules LDN 544, LDN 549, LDN 567, LDN 543, LDN 1113, LDN 1031, LDN 1225, LDN 1252 and LDN 1257 are  180 ± 35, 200 ± 40, 180 ± 35, 160 ± 30, 350 ± 70, 200 ± 40, 400 ± 80, 250 ± 50  and 250 ± 50 pc, respectively. Using the distances determined, we have estimated the masses of the globules and the far-IR luminosity of the IRAS sources associated with them. The mass of the clouds studied are in the range  10–200 M_⊙  .     

Thermal desorption of water ice in the interstellar medium

Water (H₂O) ice is an important solid constituent of many astrophysical environments. To comprehend the role of such ices in the chemistry and evolution of dense molecular clouds and comets, it is necessary to understand the freeze-out, potential surface reactivity and desorption mechanisms of such molecular systems. Consequently, there is a real need from within the astronomical modelling community for accurate empirical molecular data pertaining to these processes. Here we give the first results of a laboratory programme to provide such data. Measurements of the thermal desorption of H₂O ice, under interstellar conditions, are presented. For ice deposited under conditions that realistically mimic those in a dense molecular cloud, the thermal desorption of thin films (≪50 molecular layers) is found to occur with zeroth-order kinetics characterized by a surface binding energy, E _des, of 5773 ± 60 K, and a pre-exponential factor, A , of 10^30 ± 2 molecules cm⁻² s⁻¹. These results imply that, in the dense interstellar medium, thermal desorption of H₂O ice will occur at significantly higher temperatures than has previously been assumed.     

Interstellar Na i D lines towards the Southern Coalsack

The interstellar Na  i D absorption-line profiles observed for 15 stars with lines of sight towards the Southern Coalsack are analysed. The method of profile fitting was used in an attempt to determine column densities, linewidths and velocities for the individual interstellar clouds contributing to the observed absorption lines. In common, the observed spectra show a prominent component which is probably associated with the nearest absorbing material composing the Coalsack. The obtained spatial velocity distribution shows great similarity with earlier results from CO emission. In addition, the Na  i D data reveal evidence for the existence of two or three other structures with radial velocities of about −22, −33 and −40 km s⁻¹. Such components may be the counterparts of interstellar structures observed in diffuse H α and CO emission. The assumption that at least one of these components originated in the Carina arm imposes ∼0.9–1.0 kpc as the maximum distance to the near side of that arm.     

Interstellar CO towards X Persei (HD 24534) – II. Two-component model

The observations made by the Goddard High Resolution Spectrograph (GHRS) aboard the Hubble Space Telescope ( HST ) of molecular CO in absorbing gas towards X Persei are reported. The two-component statistical equilibrium model incorporating radiative excitation of CO by line emission at the same velocity that originates in nearby molecular clouds has been used to reproduce high-resolution GHRS spectra. Earlier analysis indicates that the cloud has a complex structure and at least a two-component model should be used to obtain accurate results. The spectra obtained from the International Ultraviolet Explorer ( IUE ) were used to complement GHRS data and constrain the space of possible solutions. The new oscillator strengths recommended by Eidelsberg et al. for A–X bands have been used. The results show that one of the components may be attributed to the Perseus OB2 molecular cloud, and the other component to an extension of the Taurus dark cloud. The total CO column density N (CO)=(1.0±0.2)×10¹⁶ cm⁻² has been determined. According to the results about 85 per cent of the observed CO belongs to an extension of the Taurus dark cloud. The CO radiation that originates in nearby molecular clouds may be the dominant excitation mechanism of the observed CO. The early results of ¹³CO line analysis indicate a ¹³CO/¹²CO ratio of about 40.     

Chemical evolution ahead of Herbig–Haro objects

Compact regions of enhanced HCO⁺ and NH₃ emission have been detected close to a number of Herbig–Haro objects. An interpretation of these detections is the following: a transient clump within the molecular cloud has been irradiated by the shock that generates the Herbig–Haro object. The irradiation releases icy mantles from the grains within the transient clump and initiates a photochemistry. On the basis of this picture, we have developed an extensive chemical model which predicts that a wide range of species, other than NH₃ and HCO⁺, should also be detectable. These include CH₃OH, H₂S, C₃H₄, H₂CO, SO, SO₂, H₂CS and NS. The chemical effects should last ∼  10⁴ yr  .     

Molecular hydrogen formation on porous dust grains

Recent laboratory experiments on interstellar dust analogues have shown that H₂ formation on dust-grain surfaces is efficient in a range of grain temperatures below 20 K. These results indicate that surface processes may account for the observed H₂ abundance in cold diffuse and dense clouds. However, high abundances of H₂ have also been observed in warmer clouds, including photon-dominated regions (PDRs), where grain temperatures may reach 50 K, making the surface processes extremely inefficient. It was suggested that this apparent discrepancy can be resolved by chemisorption sites. However, recent experiments indicate that chemisorption processes may not be efficient at PDR temperatures. Here we consider the effect of grain porosity on H₂ formation, and analyse it using a rate-equation model. It is found that porosity extends the efficiency of the recombination process to higher temperatures. This is because H atoms that desorb from the internal surfaces of the pores may re-adsorb many times and thus stay longer on the surface. However, this porosity-driven extension may enable efficient H₂ formation in PDRs only if porosity also contributes to significant cooling of the grains, compared to non-porous grains.     

A high sampling-density polarization study of the Southern Coalsack

We present a densely sampled map of visual polarimetry of stars in the direction of the Southern Coalsack dark cloud. Our sample consists of new polarimetric observations of 225 stars drawn from the spectrophotometric survey of Seidensticker, and an additional 173 stars, covering the surrounding areas of the cloud, taken from the literature. Because all the target stars have at least spectroscopic parallaxes, we can reliably investigate the spatial origins of the polarization, in three dimensions. We decompose the polarization into three components, due to (i) the wall of the local hot bubble, (ii) the Coalsack cloud and (iii) material in the Carina spiral arm. The polarization due to the Coalsack varies, both in alignment efficiency  ( p / A_V )  and in the dispersion in polarization angle, across the cloud. Using a simplified radiative transfer treatment we show that the measured polarization in background gas is significantly affected by foreground polarization, and specifically that the analysis of the Coalsack polarization must take the effects of the local hot bubble wall into consideration. Correcting for this effect as well as for the internal line-of-sight averaging in the Coalsack, we find, based on a Chandrasekhar–Fermi analysis, a plane-of-the-sky magnetic field for the Coalsack cloud of  〈 B _⊥〉= 93 ± 23 μG  . A systematic error, best described by a multiplicative factor between 0.5 and 1.5, additionally arises from radiative transfer effect uncertainties. We propose that this high value for the magnetic field in the cloud envelope is due to the fact that the Coalsack cloud is embedded in the hot interior of the Upper Centaurus–Lupus superbubble.     

On the detection of interstellar homonuclear diatomic molecules

The pure rotational spectrum of homonuclear diatomic molecules in the interstellar medium is strongly forbidden, and no such spectrum has been detected. In regions of high excitation, vibrational emission may occur, as is widely detected in the case of H₂ in interstellar shocks and photon-dominated regions. However, it is of considerable interest to know the abundance of homonuclear diatomics in quiescent regions. We propose that vibrational emission from homonuclear diatomic molecules in cold clouds may be detectable, where the excitation is mainly through collisions with non-thermal electrons arising from the cosmic-ray ionization of H₂. As an example, we estimate the intensity of emission from N₂ in cold, dark interstellar clouds. We show that such emission is at the limit of detectability with current technology. Other excitation mechanisms may also contribute and enhance this emission.     

On water ice formation in interstellar clouds

A model is proposed for the formation of water ice mantles on grains in interstellar clouds. This occurs by direct accretion of monomers from the gas, be they formed by gas or surface reactions. The formation of the first monolayer requires a minimum extinction of interstellar radiation, sufficient to lower the grain temperature to the point where thermal evaporation of monomers is just offset by monomer accretion from the gas. This threshold is mainly determined by the adsorption energy of water molecules on the grain material; for hydrocarbon material, chemical simulation places this energy between 0.5 and 2 kcal mol⁻¹, which sets the (true) visible extinction threshold at a few magnitudes. However, realistic distributions of matter in a cloud will usually add to this an unrelated amount of cloud core extinction, which can explain the large dispersion of observed (apparent) thresholds. Once the threshold is crossed, all available water molecules in the gas are quickly adsorbed, because the grain cools down and the adsorption energy on ice is higher than on bare grain. The relative thickness of the mantle, and, hence, the slope of  τ₃( A _v)  depend only on the available water vapour, which is a small fraction of the oxygen abundance. Chemical simulation was also used to determine the adsorption sites and energies of O and OH on hydrocarbons and study the dynamics of formation of water molecules by surface reactions with gaseous H atoms, as well as their chances to stick in situ.     

Crystalline water ice in OH32.8–0.3

The 2.2–200 μm spectrum of OH32.8–0.3 has been modelled. Mie theory and radiative transfer models of the 3-μm band of H₂O ice are consistent with a strongly crystalline structural phase. This is also confirmed by the presence of a 44/62-μm band complex analogous to that of laboratory crystalline H₂O ice analogues. The highly ordered phase may be the result of direct crystallization upon deposition as has been theorized by Kouchi et al. At the large total optical depths typical of the radiative transfer models for this object (τ_9.7∼ 40), we find no significant difference between the Mie theory and radiative transfer models of the 3-μm band. On the other hand, large differences are found for the 9.7-μm silicate band. In contrast to Mie theory extinction profiles, those computed via radiative transfer modelling indicate that the 12-μm H₂O ice band (the so-called librational band) is substantially attenuated. This, in addition to the inherent broadness and weakness of the 12-μm ice band, may explain why this band has not been clearly identified in observational spectra of oxygen–rich evolved objects.     

The far-infrared signature of dust in high-latitude regions

We present ISOPHOT observations of eight interstellar regions in the 60–200 μm wavelength range. The regions belong to mostly quiescent high-latitude clouds and have optical extinction peaks from   A_V ∼1–6 mag  . From the 150- and 200-μm emission, we derived colour temperatures for the classical big grain component which show a clear trend of decreasing temperature with increasing 200-μm emission. The 200-μm emission per unit   A_V   , however, does not drop at lower temperatures. This fact can be interpreted in terms of an increased far-infrared (FIR) emissivity of the big grains. We developed a two-component model including warm dust with the temperature of the diffuse interstellar medium (ISM) of   T = 17.5 K  , and cold dust with   T = 13.5 K  and FIR emissivity increased by a factor of >4. A mixture of the two components can reproduce the observed colour variations and the ratios   I ₂₀₀/ A_V   and  τ₂₀₀/ A_V   . The relative abundance of small grains with respect to the big grains shows significant variations from region to region at low column densities. However, in lines of sight of higher column density, our data indicate the disappearance of small grains, perhaps a signature of adsorption/coagulation of dust. The larger size and porous structure could also explain the increased FIR emissivity. Our results from eight independent regions suggest that these grains might be ubiquitous in the galactic ISM.     

Shocked gas around Cepheus A: evidence for multiple outflows from H2S and SO2 observations

The Cepheus A star-forming region has been investigated through a multiline H₂S and SO₂ survey at millimetre wavelengths. Large-scale maps and high-resolution line profiles reveal the occurrence of several outflows. Cep A East is associated with multiple mass-loss processes: in particular, we detect a 0.6-pc jet-like structure which shows for the first time that the Cep A East young stellar objects are driving a collimated outflow moving towards the south.
The observed outflows show different clumps associated with definitely different H₂S/SO₂ integrated emission ratios, indicating that the gas chemistry in Cepheus A has been altered by the passage of shocks. H₂S appears to be more abundant than SO₂ in high-velocity clumps, in agreement with chemical models. However, we also find quite small H₂S linewidths, suggestive of regions where the evaporated H₂S molecules had enough time to slow down but not to freeze out on to dust grains. Finally, comparison between the line profiles indicates that the excitation conditions increase with the velocity, as expected for a propagation of collimated bow shocks.     

Accurate positions of H2O masers in the Large Magellanic Cloud

Positions with subarcsecond accuracy have been measured for seven 22-GHz H₂O masers associated with H  ii regions in the Large Magellanic Cloud (LMC); two of the masers are new detections. Initial position measurements were obtained with the 70-m antenna of the Canberra NASA Deep Space Network during a period of more than two years in which the antenna was used to monitor the maser emission. The positions were further improved using 22-GHz observations involving three antennas of the Australia Telescope Compact Array.
The positions have been compared with those of 1.6-GHz continuum emission and other LMC masers (of OH and CH₃OH). The H₂O maser positions range from within 1 arcsec (270 mpc) of the centre of a compact H  ii component to beyond the boundary of significant continuum emission. Three of the four masers located near continuum peaks are close to OH masers. In two cases the positional agreement is better than 0.2 arcsec (53 mpc); in the third case the agreement is worse (0.9 arcsec) but the positions of the individual H₂O features appear to be spread over more than 1 arcsec. The velocities of the OH masers are within the spread of the H₂O velocities. The three H₂O masers offset from continuum centres are located  3–7 arcsec  from optical or infrared phenomena probably associated with very early stages of star formation; no other molecular masers are known in these directions.     

Dust coagulation in star formation with different metallicities

Dust grains coagulate into larger aggregates in dense gas. This changes their size distribution and possibly affects the thermal evolution of star-forming clouds. We here investigate dust coagulation in collapsing pre-stellar cores with different metallicities by considering the thermal motions of grains. We show that coagulation does occur even at low metallicity  ∼10⁻⁶ Z_⊙  . However, we also find (i) that the H₂ formation rate on dust grains is reduced only after the majority of H₂ is formed and (ii) that the dust opacity is modified only after the core becomes optically thick. Therefore, we conclude that the effects of dust coagulation can safely be neglected in discussing the temperature evolution of the pre-stellar cores for any metallicity as long as the grain motions are thermal.