东准贝勒库都克岩体锆石Hf-O同位素研究

对新疆东准噶尔贝勒库都克岩体具代表性岩石进行Hf-O同位素测定,结果显示贝勒库都克岩体碱长花岗岩和二长花岗岩锆石具较一致的高正εHf(t)值。两个样品εHf(t)值分别为εHf(t)=12.6±0.3(正长花岗岩)和εHf(t)=12.7±0.3(二长花岗岩),其中二长花岗岩δ18O=9.19。结合微量元素地球化学特征,认为贝勒库都克岩体花岗岩不是直接起源于亏损地幔,源岩可能是该区早期发育的玄武质洋壳与少量陆源沉积物的混合物。     

福建龙岩永福岩体锆石U-Pb年龄、地球化学特征及Lu-Hf同位素组成

永福岩体位于永梅晚古生代拗陷带中部。利用LA-ICP-MS锆石U-Pb定年法测得永福岩体中YF-1样品的年龄为133±1 Ma(MSWD=0.50)、YF-2样品的年龄为143±1 Ma(MSWD=0.59),说明其形成于早白垩世,与燕山期岩浆活动有关。该岩体富硅、碱,里特曼指数σ=0.96~2.43,铝饱和指数(A/CNK)=0.98~1.66,属高钾钙碱性系列,准铝质到过铝质范围。稀土元素总量较高,LREE相对富集,HREE相对亏损;具中-弱Eu负异常,弱Ce负异常到无异常,轻重稀土的分馏较微弱;微量元素表现为亏损元素Ba、Sr、K、P和Ti,富集Th、U、Zr、Hf等元素。样品YF-2~YF-7具有S型花岗岩特征,为永福岩体主体,源岩可能来自古-中元古代下地壳沉积岩;而样品YF-1具有Ⅰ型花岗岩特征,源岩可能来自古-中元古代下地壳火成岩。锆石的εHf(t)值除一颗来自残留基底为正值外,其他锆石全部为负值(-4.30~-11.82),Hf同为素二阶段模式年龄tDM2为1.45~1.92 Ga,表明永福岩体可能形成于古老地壳物质的重融。岩体形成于燕山期地壳的伸展背景下,在岩石圈伸展作用下幔源岩浆底侵促使古-中元古代下地壳沉积岩先发生部分熔融,形成永福岩体早期的S型花岗岩,岩浆作用后期,古-中元古代下地壳火成岩部分熔融,形成永福岩体晚期的I型花岗岩。     

Geochronology,petrogenesis and tectonic implications of the Zhongchuan granitic pluton in the Western Qinling metallogenic belt,China

The Zhongchuan district is an important component of the metallogenic belt in the Western Qinling. The Zhongchuan granite pluton occurring in the centre of the Zhongchuan metallogenic area has been poorly constrained, though the Triassic granite in Western Qinling has been well documented. In‐situ zircon U–Pb ages, Hf isotopic compositions and whole‐rock geochemical data are presented for host granite and mafic microgranular enclaves (MMES) from the Zhongchuan pluton, in order to constrain its sources, petrogenesis and tectonic setting of the pluton. The distribution of major, trace and rare earth elements apparently reflect exchange between the MMES and the host granitic rocks mainly due to interactions between coeval felsic host magma and mafic magma. The zircon U–Pb age of host granite (231.6 ± 1.5 to 235.8 ± 2.3 Ma) has overlapping uncertainty with that of the MMES (236.6 ± 1.3 Ma), establishing that the mafic and felsic magmas were coeval. The Hf isotopic composition of the MMES (ε_Hf(t) = −13.4 to 4.0) is distinct from the host granite (ε_Hf(t) = −15.7 to 0.0), indicating that both enriched subcontinental lithosphere mantle (SCLM) and crustal sources contributed to their origin. The zircons have two‐stage Hf model ages of 1064 to 1798 Ma for the host granite and 858 to 1747 Ma for the MMES. This suggests that the granitic pluton was likely derived from partial melting of a Late Mesoproterozoic crust, with subsequent interaction with the SCLM‐derived mafic magmas in tectonic affinity to the South China Block. Copyright © 2012 John Wiley & Sons, Ltd.     

In situ analyses of micas in the Yashan granite,South China: Constraints on magmatic and hydrothermal evolutions of W and Ta–Nb bearing granites

Most rare-metal granites in South China host major W deposits with few or without Ta–Nb mineralization. However, the Yashan granitic pluton, located in the Yichun area of western Jiangxi province, South China, hosts a major Nb–Ta deposit with minor W mineralization. It is thus important for understanding the diversity of W and Nb–Ta mineralization associated with rare-metal granites. The Yashan pluton consists of multi-stage intrusive units, including the protolithionite (-muscovite) granite, Li-mica granite and topaz–lepidolite granite from the early to late stages. Bulk-rock REE contents and La/Yb ratios decrease from protolithionite granite to Li-mica granite to topaz–lepidolite granite, suggesting the dominant plagioclase fractionation. This variation, together with increasing Li, Rb, Cs and Ta but decreasing Nb/Ta and Zr/Hf ratios, is consistent with the magmatic evolution. In the Yashan pluton, micas are protolithionite, muscovite, Li-mica and lepidolite, and zircons show wide concentration ranges of ZrO₂, HfO₂, UO₂, ThO₂, Y₂O₃ and P₂O₅. Compositional variations of minerals, such as increasing F, Rb and Li in mica and increasing Hf, U and P in zircon are also in concert with the magmatic evolution from protolithionite granite to Li-mica granite to topaz–lepidolite granite. The most evolved topaz–lepidolite granite has the highest bulk-rock Li, Rb, Cs, F and P contents, consistent with the highest contents of these elements and the lowest Nb/Ta ratio in mica and the lowest Zr/Hf ratio in zircon. Ta–Nb enrichment was closely related to the enrichment of volatile elements (i.e. Li, F and P) in the melt during magmatic evolution, which raised the proportion of non-bridging oxygens (NBOs) in the melt. The rims of zoned micas in the Li-mica and topaz–lepidolite granites contain lower Rb, Cs, Nb and Ta and much lower F and W than the cores and/or mantles, indicating an exotic aqueous fluid during hydrothermal evolution. Some columbite-group minerals may have formed from exotic aqueous fluids which were originally depleted in F, Rb, Cs, Nb, Ta and W, but such fluids were not responsible for Ta–Nb enrichment in the Yashan granite. The interaction of hydrothermal fluids with previously existing micas may have played an important role in leaching, concentrating and transporting W, Fe and Ti. Ta–Nb enrichment was associated with highly evolved magmas, but W mineralization is closely related to hydrothermal fluid. Thus these magmatic and hydrothermal processes explain the diversity of W and Ta–Nb mineralizations in the rare-metal granites.     

西藏南木林普洛岗岩体锆石定年和Hf同位素特征及其地质意义

对冈底斯中段南木林县普洛岗乡花岗岩岩体进行了原位锆石LA-ICP-MS U-Pb定年和Hf同位素分析。2个花岗岩样品加权平均年龄分别为(44.3±1.1)和(44.5±1.1) Ma,代表该岩体的岩浆结晶年龄为始新世。岩石地球化学资料显示,花岗岩SiO₂质量分数为60.53％~65.28%,K₂O+Na₂O质量分数为6.53％~7.98%,Al₂O₃质量分数为15.52％~16.13%,铝饱和指数为0.86~0.91,属于准铝质高钾钙碱性系列花岗岩类。花岗岩轻稀土元素相对较富集,具有明显的Eu负异常,微量元素中亏损Nb、Ta、Ti和富集Rb、Th、U、Pb。锆石Hf同位素初始比值ε_Hf(t)值为8.8~11.1,¹⁷⁶Hf/¹⁷⁷Hf 为0.282 994~0.283 060,Hf同位素地壳模式年龄为422~557 Ma,反映了其岩浆来源于新生地壳物质的部分熔融。普洛岗乡花岗岩的形成与新特提斯洋向北俯冲、俯冲板片折返断离有关。     

大兴安岭南段维拉斯托高分异花岗岩体的成因与演化及其对Sn-(Li-Rb-Nb-Ta)多金属成矿作用的制约

近年来,大兴安岭南段维拉斯托矿区深部Sn-Li找矿取得重大突破,但人们目前对与成矿作用密切相关的深部花岗岩体成因与演化及其对稀有金属矿化存在怎样的制约尚不清楚.为此,针对该岩体开展了年代学、地球化学和Sr-Nd-Hf同位素组成研究,获得的锆石LA-ICP-MS U-Pb年龄为130.7±0.5 Ma（MSWD=0.53）,属早白垩世岩浆活动产物.化学组成上表现为高硅、富碱（高钠）,贫钙、镁、铁和极低P₂O₅（< 0.01%）含量特征,铝饱和指数（A/CNK）集中于1.02~1.08,全岩Rb/Sr、Nb/Ta比值高,Zr/Hf比值低（< 4）.岩体富Cs、Rb、Th、U、Nb、Ta以及Li、F等元素,亏损Ba、Sr、Ti和稀土元素,轻重稀土比值小,并具显著的四分组效应和Eu负异常（δEu=0.02~0.15）,锆石饱和温度（691~727℃）和Zr+Nb+Ce+Y含量均低于A型花岗岩,以上综合特征反映其应属准铝-弱过铝质高分异I型花岗岩类.岩体具正的ε_Nd（t）（+1.10~+3.75）值和相对均一的ε_Hf（t）（+4.2~+8.7）以及年轻的二阶段模式年龄（T_（Nd）DMC=607~829 Ma;T_（Hf）DMC=627~914 Ma）,说明成矿岩体的岩浆源区可能来自于含大量幔源组分新生下地壳的部分熔融.Sn-（稀有）成矿受岩浆后期的高度分异演化和晚期流体-熔体相互作用共同影响,并与外围的脉状矿体共同构成岩浆-热液成矿系统.      

辽东岫岩晚侏罗世荒地岩体的地球化学、年代学与Hf同位素及构造意义

辽东半岛中生代晚侏罗世岩浆活动较少,研究程度较低.通过对辽宁岫岩县荒地花岗岩岩体进行锆石U-Pb测年、岩石地球化学和锆石Lu-Hf同位素分析来进一步了解辽东半岛晚侏罗世的构造动力学背景,荒地花岗岩的岩浆锆石U-Pb加权平均年龄为161.1±3.6 Ma（MSWD=1.4）,表明荒地岩体的形成时代为晚侏罗世,为燕山期岩浆活动的产物.该岩体含白云母等富铝矿物,地球化学数据也显示,该岩体为过铝质高钾钙碱性系列,富集K、Rb、Cs、Ba等大离子亲石元素,亏损Nb、Ti、P等高场强元素,具轻稀土元素富集,重稀土元素亏损的特征,Eu为中等负异常（δEu=0.33~0.80）.该花岗岩A/CNK平均值为1.10,CIPW标准矿物中出现刚玉分子（>1%）.由此认为该岩体为经历了高程度的结晶分异作用的S型花岗岩.荒地花岗岩CaO/Na₂O比值小于0.3,ε_Hf（t）小于0（-36.968~-23.298）,表明该岩石由地壳的泥质岩熔融形成.两阶段Hf模式年龄T_DMC=2 680~3 568 Ma,表明该岩体源岩的组成物质从地幔储库中脱离的时间为新太古代至古太古代,同时与辽东半岛侏罗纪其他花岗岩进行了比较.综上所述,该岩体形成于古太平洋板块向欧亚大陆俯冲后俯冲角度变大、向更深处俯冲的背景之下.      

西藏拉萨地块阿翁错北二长花岗岩成因：锆石U-Pb年代学、岩石地球化学及Hf同位素制约

西藏拉萨地块阿翁错—盐湖岩浆弧的成因是解决班公湖—怒江特提斯洋俯冲极性和时限的关键。本文选取阿翁错北岩体中的二长花岗岩进行岩相学、锆石U-Pb年代学、岩石地球化学与Hf同位素研究。结果表明：阿翁错北二长花岗岩的锆石²⁰⁶Pb/²³⁸U加权平均年龄为(107.0±0.5) Ma,MSWD＝2.6,属早白垩世晚期。样品表现为高硅、富钾的高钾钙碱性岩石系列,A/CNK值介于1.006～1.019之间,属弱过铝质;微量元素富集大离子亲石元素Rb、K、U、Th及轻稀土元素（LREE）,亏损Nb、Ta、P、Ti等高场强元素,具中等至弱的负Eu异常（δEu=0.55~0.78）,属弱过铝质未分异的I型花岗岩。二长花岗岩样品锆石初始Hf同位素ε_Hf(t)值除1颗锆石达11.1外,其他17颗锆石介于3.7~6.3之间,平均值5.0,Hf同位素二阶段模式年龄变化于928~765 Ma之间。基于同位素以及岩石地球化学数据,阿翁错北岩体很可能是新生地壳熔融产生的长英质岩浆与镁铁质岩浆发生不均一混合作用形成,并有少量幔源物质的参与。结合拉萨地块中北部岩浆岩Hf同位素研究分析,阿翁错—盐湖岩浆弧形成于班公湖—怒江特提斯洋后退式俯冲的构造体制下,阿翁错北岩体的形成时代（107~104 Ma）代表了由断离板片俯冲末期向碰撞环境转化的时限。     

Wolframoixiolite and niobian ferberite from zinnwaldite granitic rocks of the Chukchi Peninsula

The finding of wolframoixiolite with inclusions of niobian ferberite is described from zinnwaldite granite and ongonite of the Severny pluton of the Chukchi Peninsula. The optical, morphological, and chemical properties of minerals are characterized and compared with their analogues from other regions. The petrologic and mineragenic index implications of the minerals are discussed with allowance for our contemporary mineralogical knowledge on W-bearing Ta-Nb minerals.     

粤北大宝山北部九曲岭花岗岩锆石U-Pb年龄和Hf同位素特征

采用LA-MC-ICP-MS锆石U-Pb年龄和Hf同位素测定技术,对大宝山北部九曲岭花岗岩进行测定。结果显示来自九曲岭岩体的三个花岗岩样品的U-Pb谐和年龄分别为169.0±1.9 Ma,171.3±1.4 Ma,450.2±2.9 Ma,表明九曲岭花岗岩体为一复式岩体,主体为燕山期花岗岩,但局部有加里东期花岗岩。锆石Lu-Hf同位素组成测定显示:燕山期岩体的锆石具有低的负εHf(t)值(分别为–12.19~–8.51和–19.47~–8.63),二阶段模式年龄(tDM2)为1.45~1.63 Ga,与华南燕山期花岗岩特征一致,表明其主要是下地壳重熔的产物;加里东期岩体的锆石具有高的εHf(t)值(8.89~12.06),tDM2为0.62~0.78 Ga,表明其源区有新生地壳物质的贡献,暗示早古生代加里东期大宝山区域处于伸展环境。     

Geochemistry and petrogenesis of Permian granitoids in the northwestern margin of the North China Craton: insights from the Dongshengmiao pluton,Inner Mongolia

Permian granitoid emplacement represents one of the most important tectonothermal events in the northern margin of the North China Craton (NCC). In this study, we collected geochronological and geochemical data of the regional Permian granitoid in the northwestern margin of the NCC, and investigated the Dongshengmiao pluton, using it as an example to constrain the regional granitoid petrogenesis and its geodynamic settings. The Dongshengmiao pluton contains porphyritic granite and quartz diorite. LA-ICP-MS zircon U-Pb dating results have constrained the granitoid emplacement to be ca. 287?275 Ma. The Dongshengmiao granitoids have a SiO₂ range of 58.4?76.5%, moderate to high alkali content (Na₂O + K₂O = 5.16–7.94%), and are rich in large-ion lithophile elements (LILEs; e.g. Rb, Ba) and depleted in high-field strength elements (HFSEs; e.g. Nb, Ta, Ti). The zircons in quartz diorite have ε_Hf(t) values of ?15.6 to ?11.1 with two-stage Hf model ages (T_DM2) of 1997–2281 Ma, suggesting that the magma was derived from partial melting of old continental materials. In contrast, porphyritic granite shows variable Hf isotopic composition with ε_Hf(t) values of ?13.7 to ?2.6 and T_DM2 of 1471–2167 Ma, indicating a heterogeneous magma source. Besides the Dongshengmiao pluton, all the Permian granitoids in the northwestern margin of the NCC exhibit similar geochemical characteristics, including enrichment in LILEs, depletion in Nb and Ta, and enriched Hf isotopic signatures. The comprehensive geochemical data indicate that these Permian granitoids are derived from magma mixing between dominant partial melting of ancient felsic crustal materials and minor juvenile basaltic magma. Tectonically, the Dongshengmiao and other granitoids in the northwestern margin of the NCC may have been formed in a post-collisional extensional setting.     

鄂东南地区存在古元古代—太古宙基底——来自铜鼓山岩体锆石U-Pb-Hf同位素的证据

对鄂东南地区位于毛铺—两剑桥断裂带上的铜鼓山岩体进行了野外地质及镜下显微研究及岩石化学分析, 重点分析了其中锆石U-Pb年龄和Hf同位素组成。结果表明铜鼓山岩体为石英闪长玢岩, 岩体形成于(147±2.6) Ma, 属晚侏罗世—早白垩世, 与鄂东南地区其它岩体年龄具有一致性。铜鼓山岩体中存在的大量继承锆石。分析的4个继承锆石形成于古元古代晚期1798~1888 Ma。继承锆石具有高的Th/U比值和极其相似的Lu-Hf同位素组成, 表明它们捕获于同一火成岩。这表明鄂东南地区存在古元古代基底。这些古元古代继承锆石低的εHf(t)值和冥太古代的Hf同位素两阶段模式年代暗示古元古代克拉通化是在太古宙基底上发展的。鄂东南地区和扬子陆块其它众多地区一样存在古元古代—太古宙基底。扬子陆块古元古代—太古宙基底极可能从四川盆地、鄂西崆岭和郧西地区东延至鄂东南地区。     

Isotopic variations in S-type granites: an inheritance from a heterogeneous source?

Inherited zircons from S-type granites provide exceptionally good insight into the isotopic heterogeneity of their sources. Zircons from four samples (one granite, two granodiorites, one granodioritic enclave) of Pan-African S-type granite of the Cape Granite Suite (c. 540 Ma) have been the subject of a laser LA-ICP-MS zircon U/Pb study to determine emplacement ages and inheritance. Zircons from three of these samples (2 granodiorites and 1 granodioritic enclave) were also analysed for Hf isotopes by LA-MC-ICP-MS. Ages of inherited cores range from 1,200 to 570 Ma and show Hafnium isotope values (ε_Hf,t ) for the crystallisation age (t) of the different cores that range from −14.1 to +9.1. Magmatic zircons and magmatic overgrowth with concordant spot ages between ca. 525 and ca. 555 Ma show a similar range of ε_Hf,t , between −8.6 and +1.5, whilst ε_Hf values calculated at 540 Ma (ε_Hf,540) for inherited cores range from −15.2 to +1.7. Thus, our results show that the time evolved ε_Hf arrays of the inherited cores overlap closely with the ε_Hf range displayed by the magmatic rims at the time of crystallisation of the pluton. These similarities imply a genetic relationship between magmatic and inherited zircons. Within the inherited cores, four main peak ages can be identified. This, coupled with their large Hf isotopic range, emphasises that the source of the granite is highly heterogeneous. The combination of the U/Pb zircon ages ranges and Hf isotope data implies that: (1) The source of S-type granite consists of crustal material recording several regional events between 1,200 and 600 Ma. This material records the recycling of a much older crust derived from depleted mantle between 1.14 and 2.02 Ga. (2) The homogenisation of Hf isotopic variation in the magma acquired through dissolution of the entrained zircon, via mechanical mixing and/or diffusion between within the granite was particularly inefficient. (3) This evidence argues for the assembly of the pluton through many relatively small magma batches that undergo rapid cooling from their intrusion temperature (ca. 850°C) to background magma chamber temperature that is low enough to ensure that much of the magmatic zircon crystallised rapidly (>80% by 700°C). (4) There is no evidence for the addition of mantle-derived material in the genesis of S-type Cape Granite Suite, where the most mafic granodiorites are strongly peraluminous, relatively low in CaO and K₂O rich. Interpreted more widely, these findings imply that S-type granites inherit their isotopic characteristic from the source. Source heterogeneity transfers to the granite magma via the genesis of discrete magma batches. The information documented from the S-type CGS zircons has been recorded because the individual batches of magma crystallised the bulk of their magmatic zircon prior to mechanical or diffusional magma homogenisation. This is favoured by zirconium saturation in the magma shortly after emplacement, by partial dissolution of the entrained zircon fraction, as well as by the intrusion of volumetrically subordinate magma batches into a relatively cool pluton. Consequently, evidence recorded within inherited cores will most likely be best preserved in S-type granite plutons intruded at shallow depths. Other studies that have documented similar ε_Hf arrays in magmatic zircons have interpreted these to reflect mixing between crustal- and mantle-derived magmas. This study indicates that such arrays may be wholly source inherited, reflecting mixing of a range of crustal materials of different ages and original isotopic signatures.     

秦岭南召岩体中花岗岩脉的锆石U-Pb定年:对燕山期构造环境的约束

通常认为,花岗岩体中的花岗岩脉与岩体是同一次岩浆活动的产物,是深部演化的岩浆沿着岩体的裂缝侵入后冷凝形成的。南召岩体位于北秦岭东部,近年来在岩体中发现一条宽约5 m的花岗岩脉。岩脉呈紫红色,斑状结构,斑晶为石英。LA-MC-ICP-MS锆石U-Pb定年得出该岩脉的形成时间为(119.6±0.7)Ma,与岩体的年龄(452.3±6.2)Ma相差很大。锆石Hf同位素测试结果表明,岩脉的源岩可能主要是新生地壳,结合地球化学研究分析得出该岩脉呈现I型花岗岩的特性。该岩脉的年龄、Hf同位素和地球化学特征同邻近的伏牛山岩体相近,推测岩脉的源岩可能和伏牛山岩体的源岩相同。根据研究结果及区域地质构造分析,认为燕山期由于太平洋板块的俯冲作用和陆內拉张作用,导致扬子板块及华北板块沿秦岭造山带形成一系列断裂。岩浆沿着断裂上侵,大部分形成了伏牛山岩体,小部分沿着周围的裂隙侵入形成岩脉,并在侵位的过程中与寄主岩发生物质交换。     

吉林南部新太古代末地壳深熔作用——来自变质石英闪长岩及淡色花岗岩的证据

深熔作用是大陆地壳分异、元素迁移富集和混合岩化作用的主要机制和关键地质过程.吉南地区出露的太古宙基底普遍经历了角闪岩相-麻粒岩相变质及深熔作用,长英质淡色体及淡色花岗岩广泛分布.吉南和龙花岗-绿岩地体出露的太古宙变质石英闪长岩及相关的长英质浅色体和含斜方辉石(角闪石)淡色伟晶花岗岩的野外地质特征、相互关系及岩相学特征指...     

江西婺源东坑口酸性岩体年代学及成因研究

文章选取赣东北地区东坑口酸性岩体作为研究对象,对酸性岩体的岩相学、年代学及锆石原位Hf同位素、岩石地球化学进行研究。通过LA-ICP-MS锆石U-Pb定年得出东坑口酸性岩体中花岗斑岩的年龄为（134.25±0.99）Ma,花岗闪长斑岩加权平均年龄为（132.6±1.3）Ma,可以判断其形成时代属燕山晚期。东坑口酸性岩体主量元素地球化学特征基本一致,均为高钾钙碱性花岗岩,SiO₂含量较高,铝饱和指数A/CNK值均小于1.1,属于典型的I型花岗岩;微量元素地球化学表现为富集大离子亲石元素Rb、Th、U,明显亏损高场强元素Ti、P,轻微亏损Ba、Sr的特征;酸性岩体稀土元素特征具有一致性,Eu亏损不明显。结合Hf同位素表明酸性岩体的岩浆由下地壳变质砂岩部分熔融组合形成,且东坑口岩体具有典型的埃达克岩特征,为低Mg^#埃达克岩系。该酸性岩体是在陆陆碰撞过程中,碰撞挤压致使下地壳加厚以后,向伸展减薄转换的体制中形成的。产出环境为陆内造山环境,太平洋板块向华南大陆俯冲引起的弧后多阶段岩石圈伸展作用。     

Characteristic Features and U—Pb Isotopic Ages of Zircons in a Middle Proterozoic Granite Pluton from Baohan Area,Hainan Province,China

The crystal form,chemical composition and U-Pb isotopic composition of various zircon fractions is a Middle Proterozoic granite pluton from the Baoban area suggest that the zircons are typically magmatogenic in nature,and different from those of sedimentary and epigenetic orgins.The various zircon fractions yielded and age of about 1440.87Ma,which may represent the ge of zircon crystallization.The so-called aoban-group migmatite is,as a matter of fact,a Middle Proterozoic granite pluton.     

胶东地区东部晚侏罗世花岗岩锆石U-Pb定年、Hf同位素特征及其对金成矿构造背景的限定SCIEI北大核心CSCD

胶东地区是目前我国最重要的金矿产地,已累积探明黄金储量接近5000t。金矿在胶东地区分布非常不均,主要集中在胶北地体,而胶东东部地区金矿产出较少。晚侏罗世的玲珑花岗岩是胶北金矿区最重要的赋矿围岩之一。虽然胶东东部同样有晚侏罗世花岗岩发育,但赋存金矿较少,因此前人对东部这些花岗岩体的研究相对较少。本文选取胶东东部的文登岩体和垛崮山岩体进行了锆石U-Pb定年和Hf同位素分析,同时收集整理了胶北地体的玲珑岩体数据,通过开展胶东东部及西北部同一时期岩体的差异性研究,为该区金成矿作用的研究提供重要线索。分析结果显示,文登岩体和垛崮山岩体的形成时代为晚侏罗世(~160Ma),与玲珑岩体时代一致。三个岩体均含有较多的三叠纪(~230Ma)和新元古代(~780Ma)的继承锆石,表明晚侏罗世花岗岩的岩浆源区主要为经历了超高压变质作用的扬子板块。不同的是,玲珑岩体中有更多的华北板块物源的年龄记录(~1400Ma、~1700Ma、~2500Ma),垛崮山岩体中这些年龄的继承锆石少于玲珑岩体,而文登岩体更少。文登岩体、垛崮山岩体的新生岩浆锆石ε;(t)值范围分别为-30.7~-20.3和-27.5~-17.9,玲珑岩体的新生岩浆锆石ε;(t)值的变化范围更广,在-29.3~-9.3之间,而且呈现出从文登岩体到垛崮山岩体到玲珑岩体,ε;(160Ma)值逐渐增高的现象。其原因可能是扬子板块与华北板块碰撞后,幔源岩浆底侵并诱发加厚的地壳发生部分熔融,形成花岗岩。在此过程中胶北地体深部受到幔源物质的影响,从而对金及成矿相关元素产生一定的预富集作用,而同时期胶东东部地区未受到明显的地幔物质影响,可能是该区金矿产出较少的原因之一。     

Metamorphic growth and recrystallization of zircon: Distinction by simultaneous in-situ analyses of trace elements,U–Th–Pb and Lu–Hf isotopes in zircons from eclogite-facies rocks in the Sulu orogen

Simultaneous in-situ analyses of trace elements, U–Th–Pb and Lu–Hf isotopes were carried out on distinct domains of zircons in ultrahigh-pressure (UHP) eclogite-facies metamorphic rocks from the main hole of the Chinese Continental Scientific Drilling (CCSD) in the Sulu orogen. For the first time, trace elements are directly linked to Lu–Hf isotopes in metamorphic zircons with reference to their U–Pb dates. This enables methodological integration to distinguish four types of metamorphic zircon: solid-state, replacement and dissolution recrystallizations of protolith zircons, and new growth from the aqueous fluid. Metamorphically grown zircons are characterized by concordant U–Pb ages for the metamorphism, flat HREE patterns typical of the garnet effect, low contents of REE (especially HREE), Y, Nb + Ta and Th + U, high contents of Hf, low (Lu/Gd)_N, Lu/Hf and Th/U (< 0.1) ratios, and elevated ¹⁷⁶Hf/¹⁷⁷Hf ratios relative to solid-state recrystallized zircons. This suggests the effects of both garnet and fluid on the growth of metamorphic zircons. In contrast, metamorphic recrystallization has reset the U–Th–Pb isotope system of protolith zircons to different extents, depending on the extents of fluid action during metamorphism. Solid-state recrystallized zircons exhibit the lowest degrees of resetting and thus almost inherit all geochemical features from the protolith zircons, which are characterized by discordant U–Pb ages close to or below the protolith age, steep MREE–HREE patterns typical of magmatic origin, high contents of trace elements and their ratios, and low ¹⁷⁶Hf/¹⁷⁷Hf ratios. On the other hand, dissolution recrystallized zircons show the highest degrees of reworking and thus have concordant or nearly concordant U–Pb ages for the metamorphism, steep MREE–HREE patterns, lowered contents of trace elements such as REE, Th, U, Y, Nb, Ta and Ti relative to the protolith zircons, and almost unchanged Hf isotope ratios. Replacement recrystallized zircons display intermediate degrees of reworking and thus have their many features of elements and isotopes in between. While the metamorphic growth in the presence of both garnet and fluid is characterized by both depletion of HREE with flat pattern and the low contents of trace elements, the metamorphic recrystallization in the presence of aqueous fluid is indicated by gradual decreases of MREE to HREE without the flat HREE pattern. Therefore, the simultaneous in-situ analyses of metamorphic zircons have the advantage over single-term analyses in making distinction between the new growth and the different types of recrystallization.     

Permian–Carboniferous arc magmatism in southern Mexico: U–Pb dating,trace element and Hf isotopic evidence on zircons of earliest subduction beneath the western margin of Gondwana

Undeformed felsic to mafic igneous rocks, dated by U–Pb zircon geochronology between 311 and 255 Ma, intrude different units of the Oaxacan and Acatlán metamorphic complexes in southwestern Mexico. Rare earth element concentrations on zircons from most of these magmatic rocks have a typical igneous character, with fractionated heavy rare earths and negative Eu anomalies. Only inherited Precambrian zircons are depleted in heavy rare earth elements, which suggest contemporaneous crystallization in equilibrium with metamorphic garnet during granulite facies metamorphism. Hf isotopic signatures are, however, different among these magmatic units. For example, zircons from two of these magmatic units (Cuanana pluton and Honduras batholith) have positive εHf values (+3.8–+8.5) and depleted mantle model ages (using a mean crustal value of ¹⁷⁶Lu/¹⁷⁷Hf = 0.015) (T _DMC) ranging between 756 and 1,057 Ma, whereas zircons from the rest of the magmatic units (Etla granite, Zaniza batholith, Carbonera stock and Sosola rhyolite) have negative εHf values (?1 to ?14) and model ages between 1,330 and 2,160 Ma. This suggests either recycling of different crustal sources or, more likely, different extents of crustal contamination of arc-related mafic magmas in which the Oaxacan Complex acted as the main contaminant. These plutons thus represent the magmatic expression of the initial stages of eastward subduction of the Pacific plate beneath the western margin of Gondwana, and confirm the existence of a Late Carboniferous–Permian magmatic arc that extended from southern North America to Central America.