西藏驱龙斑岩铜矿S、Pb同位素组成:对含矿斑岩与成矿物质来源的指示

驱龙铜矿是西藏陆陆碰撞造山带冈底斯斑岩铜矿带内代表性矿床之一。本文对其含矿斑岩和矿石矿物进行了S、Pb同位素组成分析。驱龙矿床含矿斑岩与矿石矿物的硫同位素组成比较一致,含矿斑岩δ34S为-2.1‰~-1.1‰,黄铜矿δ34S为-6.3‰~-1.0‰,均值-2.76‰;硬石膏δ34S为 12.5‰~ 14.4‰,平均 13.4‰。成矿热液中的硫同位素基本达到了平衡,显示出岩浆硫组成特点。含矿斑岩的206Pb/204Pb范围为18.5104~18.6083,207Pb/204Pb变化于15.5946~15.7329之间,208Pb/204Pb为38.6821~39.1531之间;矿石矿物黄铜矿的206Pb/204Pb、207Pb/204Pb、208Pb/204Pb分别为18.4426~18.5909、15.5762~15.6145、38.5569~38.8568。含矿斑岩与矿石矿物的铅同位素组成比较一致,它们的变化幅度较小,应具有相同的起源与演化历史。无论是岩石铅还是矿石铅,在铅构造模式图上均位于造山带铅演化曲线上。驱龙矿床硫、铅同位素数据暗示,成矿物质主要来自深源岩浆,含矿斑岩起源于西藏造山带加厚的下地壳熔融,具有幔源成分的混染。     

西藏轮郎铅锌矿床S、Pb同位素组成及对成矿物质来源的示踪

轮郎矽卡岩型铅锌矿床位于冈底斯斑岩铜矿带北侧的铅锌银成矿带。本文基于该矿床成矿地质条件,对矽卡岩型矿石中主要的金属矿物闪锌矿、方铅矿、磁黄铁矿和黄铁矿的S、Pb同位素特征进行研究,进一步探讨了矿床成矿物质来源,并与区域矿产特征进行对比。结果显示,矿石矿物的δ34S为-2.3‰~4.1‰,平均值为1.46‰,其频率直方图具有塔式分布特征,具幔源硫特征。矿石矿物的~(206)Pb/~(204)Pb为18.179~18.692,平均值为18.543;~(207)Pb/~(204)Pb为15.588~15.802,平均值为15.687;~(208)Pb/~(204)Pb为38.532~39.305,平均值为38.900;μ值在9.44~9.83之间,具有上地壳与地幔混合的造山带铅特征。轮郎矿床S、Pb同位素特征与冈底斯成矿带北亚带矽卡岩型矿床类似。成矿物质主要来源于念青唐古拉结晶基底片麻岩,部分来自造山带幔源物质。     

滇西北雪鸡坪斑岩铜矿S,Pb同位素组成及对成矿物质来源的示踪

雪鸡坪斑岩铜矿位于西南三江构造火成岩带义敦岛弧带,其成矿斑岩为印支期石英闪长玢岩和石英二长斑岩。研究对该矿区安山岩、矿化斑岩和矿石矿物系统进行S,Pb同位素分析结果表明:金属硫化物的δ34S值为-3.1‰～ 0.7‰,平均值为-1.1‰,与矿化斑岩的硫同位素组成(-1.4‰和-1.5‰)一致,均落入幔源硫范围,表明硫主要来自岩浆;δ34S黄铁矿(-1.8‰～ 0.7‰,平均-0.5‰)>δ34S黄铜矿(-2.2‰～0.0‰,平均-1.2‰)>δ34S方铅矿(-3.1‰～-1.3‰,平均-2.4‰),硫同位素分馏基本达到平衡。矿石矿物(208Pb/204Pb=37.917～38.230,平均值38.075;207Pb/204Pb=15.528～15.614,平均值15.571;206Pb/204Pb=17.929～18.082,平均值17.981)与矿化斑岩(208Pb/204Pb=37.832、37.883,207Pb/204Pb=15.529、15.538,206Pb/204Pb=17.906、17.910)以及安山岩(208Pb/204Pb=37.816～37.884,207Pb/204Pb=15.549～15.562,206Pb/204Pb=17.845～17.919)的初始铅组成基本一致,变化范围较小,表明三者具有相同的来源;在铅构造模式图上,所有样品铅同位素均位于造山带演化线上或附近,在铅同位素源区判别图中,均落入造山带和下地壳区域,这表明Pb主要来源于壳幔混合。雪鸡坪铜矿S,Pb同位素组成共同指示成矿物质主要来自于深部岩浆,这种岩浆可能主要起源于俯冲洋壳板片的部分熔融并受到少量地壳物质的混染。     

湖南黄沙坪铅锌多金属矿床铅、硫同位素地球化学特征

黄沙坪铅锌多金属矿床是湘南的代表性矿床之一, 矿床受SN向宝岭倒转背斜和观音打座倒转背斜的控制,赋存围岩以花岗斑岩与石英斑岩为主,矿石以铅锌硫化物矿石为主,对该矿床S同位素研究表明,δ34S值为-2.2‰～17.2‰。矿石Pb同位素组成206Pb/204Pb为17.893～18.772; 207Pb/204Pb为15.580～16.045;208Pb/204Pb为38.490～41.560。研究表明,该矿床的硫源可能是岩浆来源与海水(地层)硫混合作用形成;矿床中异常铅矿化的铅是岩源来源。     

内蒙古鸡冠山斑岩型钼矿床S、Pb同位素组成:对成矿物质来源的指示

内蒙古鸡冠山钼矿床位于中亚-蒙古巨型造山带东段,是西拉沐沦钼金属成矿带中典型的大型斑岩型钼矿床。矿床产于燕山晚期火山侵入杂岩中,矿体与岩体关系密切,矿化类型以细脉浸染状斑岩型矿化为主。在野外地质观察的基础上,本文对矿石矿物黄铁矿、辉钼矿进行了S同位素组成分析,对矿床围岩全岩及黄铁矿单矿物进行了Pb同位素组成分析。结果表明,钼矿石δ~(34)S变化范围为4. 617‰～7. 072‰,平均值为5. 653‰,离散度小,硫化物δ~(34)S值全为正值,表明矿石中S源是均一的。辉钼矿δ~(34)S变化范围为4. 617‰～5. 351‰,平均值为4. 875‰。硫同位素比值5. 653‰具花岗质岩浆硫特征,推测其硫可能主要来源于下地壳岩浆源,并有一定量的地幔物质混入。全岩的~(206)Pb/~(204)Pb、~(207)Pb/~(204)Pb和~(208)Pb/~(204)Pb分别为17. 876～19. 618、15. 519～15. 609和38. 111～40. 408,表明鸡冠山钼矿床围岩的全岩铅同位素组成均变化较大。矿石矿物黄铁矿的~(206)Pb/~(204)Pb、~(207)Pb/~(204)Pb和~(208)Pb/~(20 4)Pb分别为17. 781～17. 830、15. 523～15. 526和38. 084～38. 102,表明矿石矿物铅同位素组成变化较小。围岩全岩和矿石硫化物的铅同位素投影点均落在造山带演化线的下方,表明铅很可能源于地幔或者下地壳。     

湘南宝山铅锌矿床硫、铅、碳、氧同位素特征及成矿物质来源

宝山铅锌矿床是湘南地区代表性矿床之一。宝山铅锌矿床的成矿作用与156~158 Ma的宝山花岗闪长斑岩密切相关。花岗闪长斑岩主要由古老地壳部分熔融而成。为确定成矿物质来源,文章系统研究了宝山铅锌矿床的硫、铅、碳、氧同位素组成特征。矿床中硫化物黄铁矿、闪锌矿、方铅矿的δ34S值呈狭窄的塔式分布,变化在-2.17‰~6.46‰之间,平均值为3.13‰。δ34S值总体表现为δ34S黄铁矿δ34S闪锌矿δ34S方铅矿,表明硫同位素分馏基本达到了平衡。矿石、花岗闪长斑岩和赋矿地层硫同位素对比研究表明,矿石中的硫主要由岩浆分异演化而来,岩浆中的硫主要来自古老地壳。矿石206Pb/204Pb、207Pb/204Pb和208Pb/204Pb比值分别为18.188~18.844、15.661~15.843和38.562~39.912,赋矿地层206Pb/204Pb、207Pb/204Pb和208Pb/204Pb比值分别为18.268~19.166、15.620~5.721和38.364~39.952。矿石铅同位素组成比地层中的更富放射性成因铅,矿石中部分铅来自宝山花岗闪长质岩浆,在成矿流体运移过程中有部分地层铅参与了成矿,岩浆中的铅主要来自古老地壳。热液方解石的碳、氧同位素组成介于岩浆和赋矿碳酸盐岩的碳、氧同位素之间,主要是由于岩浆流体和碳酸盐岩不同比例的水岩反应所致,测水组有机碳的加入造成了部分热液方解石δ13CPDB值偏低。     

江西德兴朱砂红斑岩铜矿床H-O-S-Pb同位素特征及意义

江西德兴斑岩铜矿田位于扬子地块东南缘,毗邻赣东北深断裂;该矿田由富家坞、铜厂及朱砂红矿床组成,属世界超大型斑岩铜矿。本文在系统的野外观察及室内岩相学观察的基础上,通过H、O、S、Pb同位素地球化学研究手段,探讨该矿床的成矿流体及成矿物质来源。H、O同位素研究结果显示,矿石石英脉中石英的δ~(18)O值范围为8.4‰~11.2‰,与之平衡的δ~(18)O_(H_2O)值范围分别为0.44‰~3.14‰,含矿石英脉中石英的δD值范围为-73.2‰~56.9‰,成矿流体以岩浆分异热液及天水热液为主。矿石中硫化物δ~(34)S组成变化范围较窄,为-4.3‰~-0.9‰,多数集中在0值左右且在S同位素直方图上呈塔式分布特点,表明具有岩浆硫(0±3‰)的特征。矿石硫化物中Pb同位素组成比较稳定,~(206)Pb/~(204)Pb、~(207)Pb/~(204)Pb和~(208)Pb/~(204)Pb比值分别为18.079~18.643、15.545~15.578和38.058~38.595。朱砂红矿床硫化物中Pb同位素组成与德兴含矿斑岩大致相同,明显区别于源自双桥山群地层的矿石中Pb同位素组成,表明成矿物质主要来源于含矿斑岩,并非双桥山群浅变质地层。朱砂红矿床的流体来源为岩浆分异热液及天水热液的混合,成矿物质主要来自斑岩,矿床发育与斑岩体密切相关。德兴矿区三个矿床对比研究表明,朱砂红斑岩型矿床H、O同位素特征与铜厂斑岩铜矿床大体一致,成矿流体来源基本相似;三个矿床中S同位素表现为从东南的富家坞矿床向西北的朱砂红矿床由高到低的变化趋势,但变化范围基本保持一致,朱砂红矿床可能比铜厂矿床及富家坞矿床受更多围岩物质混染;三个矿床Pb同位素总体显示出壳幔混合铅的特征。三个矿床为同一成矿系统,矿床的差异可能源自岩浆与围岩混染程度的不同。     

秦岭凤太矿集区喷流沉积型铅锌矿床S、Pb同位素地球化学特征

凤太矿集区位于秦岭泥盆系铅锌等多金属成矿带的中段,铅锌矿床主要产于中泥盆统古道岭组和上泥盆统星红铺组之间的硅质岩中。对区内三个典型铅锌矿床中S、Pb同位素组成研究表明,铅硐山、八方山、银母寺3个铅锌矿床金属硫化物的δ34S值变化范围较小,均不超过10‰。区内硫化物的δ34S值总体变化于4.3‰~13.2‰,指示S主要来自海水硫酸盐的还原作用。3个矿床矿石矿物的Pb同位素中206 Pb/204 Pb变化于17.775~18.180,207Pb/204Pb变化于15.457~15.805,208Pb/204Pb变化于37.977~38.670。各个矿床之间Pb同位素组成均有较大的重叠,暗示3个铅锌矿床具有相似的铅源。通过Pb同位素构造模式图解以及Δβ-Δγ分类图解分析表明,矿石铅来源于早古生代中期到末期扬子板块向华北板块之下俯冲以及晚古生代扬子板块、秦岭微板块向华北板块俯冲的历程中。     

湘西地区铅锌矿成矿物质来源——来自S、Pb同位素的证据

湘西地区铅锌矿床位于湘西-鄂西成矿带西南段,具有良好的成矿地质背景和控矿条件,有望成为中国最大的铅锌矿基地。S和Pb同位素组成分析结果表明,湘西地区矿床的δ~(34)S值变化范围为6.30‰~34.66‰,平均值为19.64‰,明显富重硫,具有双塔式分布特征,矿石硫主要来源于容矿地层中的海相硫酸盐类和海水。8个矿床矿石矿物的~(206)Pb/~(204)Pb值范围为17.689~18.295,~(207)Pb/~(204)Pb值变化于15.535~18.848之间,~(208)Pb/~(204)Pb值介于37.294~38.630之间。区内铅锌矿床Pb同位素成分具有造山带和上地壳Pb同位素特征,成矿物质来源于造山带和上地壳的混合作用,铅成因类型为上地壳和地幔因岩浆作用而混合的俯冲铅。提出了湘西地区铅锌矿成矿作用的两阶段演化模式,认为区内铅锌成矿作用经历了成矿流体形成和成矿流体迁移富集2个演化阶段。     

豫西南赤土店铅锌矿床地质、流体包裹体和S、Pb同位素地球化学特征

豫西南栾川地区近年铅锌矿勘查取得显著进展,显示出良好的资源前景。赤土店铅锌矿床是新发现的铅锌矿之一,从控矿要素和矿体产状看,有两种矿化类型,即北西西向断裂构造控制的脉状铅锌矿,和石宝沟岩体外围矽卡岩带中的铅锌矿,并以前者为主。在空间上围绕斑岩体往外,构成近斑岩体发育矽卡岩型钼矿化,远斑岩体接触带的围岩矽卡岩中发育矽卡岩型多金属矿床,在斑岩体外围的断裂带中发育脉型铅锌银矿床的空间分布或分带规律。流体包裹体研究显示,成矿阶段温度较高(290～340℃),流体含大量CO2,并发生过流体不混溶分离。S同位素组成(0.20‰～8.30‰,平均3.93‰)显示,硫有深部岩浆(区内斑岩硫集中在2‰～4‰)和地层(分别集中在-13‰～-8‰和6‰～11‰两个区间)两种来源。被矿相学研究证实共生的方铅矿-闪锌矿矿物对计算出平衡温度为388.29℃,亦显示高温特征。Pb同位素组成(206Pb/204Pb=17.005～l7.953,207Pb/204Pb=15.414～15.587,208Pb/204Pb=37.948～39.03)反映,脉状铅锌矿成矿物质可能主要来自斑岩,部分来自地层。综合分析认为,赤土店矿床为与燕山期斑岩有关的铅锌矿,其脉状矿体为岩浆热液充填-交代成因类型。     

Fluid Inclusions and Hydrogen,Oxygen, and Lead Isotopes of the Antuoling Molybdenum Deposit,Northern Taihang Mountains,China

The Antuoling Mo deposit is a major porphyry‐type deposit in the polymetallic metallogenic belt of the northern Taihang Mountains, China. The processes of mineralization in this deposit can be divided into three stages: an early quartz–pyrite stage, a middle quartz–polymetallic sulfide stage, and a late quartz–carbonate stage. Four types of primary fluid inclusions are found in the deposit: two‐phase aqueous inclusions, daughter‐mineral‐bearing multiphase inclusions, CO₂–H₂O inclusions, and pure CO₂ inclusions. From the early to the late ore‐forming stages, the homogenization temperatures of the fluid inclusions are 300 to >500°C, 270–425°C, and 195–330°C, respectively, with salinities of up to 50.2 wt%, 5.3–47.3 wt%, and 2.2–10.4 wt% NaCl equivalent, revealing that the ore‐forming fluids changed from high temperature and high salinity to lower temperature and lower salinity. Moreover, based on the laser Raman spectra, the compositions of the fluid inclusions evolved from the NaCl–CO₂–H₂O to the NaCl–H₂O system. The δ¹⁸O_H2O and δD values of quartz in the deposit range from +3.9‰ to +7.0‰ and ?117.5‰ to ?134.2‰, respectively, reflecting the δD of local meteoric water after oxygen isotopic exchange with host rocks. The Pb isotope values of the sulfides (²⁰⁸Pb/²⁰⁴Pb, 36.320–37.428; ²⁰⁷Pb/²⁰⁴Pb, 15.210–15.495; ²⁰⁶Pb/²⁰⁴Pb, 16.366–17.822) indicate that the ore‐forming materials originated from a mixed upper mantle–lower crust source.     

广西大厂锡多金属矿床硅质岩和层状矿体氧硅同位素研究

作者对大厂地区泥盆纪地层中的不同成历的硅质岩进行了系统的硅氧同位素研究。其中一种是与矿化无关的浅海放射虫硅质岩，其硅质来自海水的溶解硅，表现出低的负δ30Si值和变化较大的δ18O值；另一种岩石可能属海底喷气成因，表现出你的负δ30Si值和均一的δ18O值，与硫化物成矿作用有密切关系。     

Shoreline tufa and tufaglomerate from Pleistocene Lake Bonneville,Utah, USA: stable isotopic and mineralogical records of lake conditions,processes, and climate

Shoreline carbonate deposits of Pleistocene Lake Bonneville record the conditions and processes within the lake, including the evaporative balance as well as vertical and lateral chemical and isotopic gradients. Tufas (swash‐zone) and tufaglomerates (cemented, subaqueous colluvium or beachrock) on multiple, well‐developed shorelines near the Silver Island Range, Utah, also present an opportunity to examine physicochemical lake processes through time. Three shorelines are represented by carbonate deposits, including the 23–20 ka Stansbury stage, 15–14.5 ka Bonneville stage, and 14.5–14 ka Provo stage. Mean δ¹⁸O_VSMOW values of all three shorelines are statistically indistinguishable ( ～ 27 ± 1‰), when a few Bonneville samples of unusual composition are neglected. However, differences in primary carbonate mineralogy indicate that the correspondence is an artefact of the different fractionation factors between calcite or aragonite and water. Second, in order to sustain a much smaller, shallower lake during the colder Stansbury stage, the climate must have also been relatively dry. Third, δ¹⁸O values in tufa are higher than tufaglomerate by ～ 0.5‰, consistent with greater evaporative enrichment of lake water in the swash zone. Fourth, mean δ¹³C values for the Provo, Stansbury and Bonneville shorelines (4.4, 5.0 and 5.2‰, respectively) show that carbon species were dominated by atmospheric exchange, with the variations produced by differences in the oxidation of organic matter. Comparisons of shoreline carbonates with deep‐lake marls of the same approximate age indicate that shoreline carbonate was much higher in δ¹³C and δ¹⁸O values (both ～ 2.5‰) during Bonneville time, whereas isotopic differences were minor (both ～ 1‰) in Stansbury time. In particular, the Bonneville stage may have sustained large vertical or lateral isotopic gradients due to evaporative enrichment effects on δ¹⁸O values. In contrast, the lake during the much shallower Stansbury stage may have been well mixed. Differences in the primary mineralogy (Stansbury and Bonneville, aragonite > calcite; Provo, calcite > aragonite) reflect profound differences in lake chemistry in terms of open versus closed‐basin lakes. The establishment of a continuous outlet during Provo time probably reduced the Mg²⁺/Ca²⁺ ratio of lake water. Curiously, regardless of primary mineralogy, tufaglomerate cements are enriched in Na⁺ and Cl^? and depleted in Mg²⁺ relative to capping tufa of the same age. This probably reflects vital or kinetic effects in the swash zone (tufa). We suspect that ‘abiotic’ effects may have been important in the dark pore space of developing tufaglomerate, where the absence of light suppressed photosynthesis. Copyright © 2005 John Wiley & Sons, Ltd.     

湘南宝山矿床REE、Pb-S同位素地球化学及黄铁矿Rb-Sr同位素定年

湘南宝山矿区的花岗闪长岩体、地层(灰岩)、方解石及黄铁矿具有相似的稀土元素地球化学特征,即轻稀土富集和Eu负异常。其中,黄铁矿表现为最低的稀土总量、明显的Eu负异常和较明显的Ce负异常,这反映了流体的稀土元素地球化学特征。认为成矿流体既有来自花岗闪长岩体的岩浆水参与,又有大气降水的作用。本次工作的矿床硫化物单矿物Pb同位素组成变化范围较小,在铅同位素构造演化图上均位于地壳演化线附近,反映的主要是地壳的信息。矿床硫化物S同位素组成与岩体及围岩地层基本一致,属于同源。通过对六个黄铁矿样品的Rb-Sr同位素分析,获得宝山矿床的Rb-Sr等时线年龄为174±7Ma,MSWD=0.55,黄铁矿的(87Sr/86Sr)i为0.70912±0.00016,高于花岗闪长岩体的锶同位素初始比值。黄铁矿Rb-Sr等时线年龄与花岗闪长岩体的单颗粒锆石U-Pb年龄十分一致,表明矿床的形成与岩体有密切的联系,花岗闪长岩体提供了矿床形成所需要的能量和部分流体,而地层也提供了部分成矿物质。     

Geochemical Characteristics of Gold Polymetallic Deposits as Exemplified by the Laozuoshan Deposit,Heilong jiang,China

From the studies of ore deposit geologic settings,sulfur isotopes,lead isotopes,carbon isotopes and oxygen isotopes,fluid inclusions and petrochemistry in this paper,the authors have drawn a conclusion that the ore-forming hydrothermal solutions are the high-temperature magmatic hydrothermal solutions for the gold ore deposit,and at the same time,the involvemety of crustal materials can not be ruled out .It is the first time that the authors have proposed that the Laozuoshan gold-ploymetallic ore deposit in Heilongjiang Province was formed in the calc-alkaline series environment at the margin of an active continent.     

江苏栖霞山铅锌多金属矿床深部碳-氧-锶同位素地球化学特征及其指示意义

以栖霞山铅锌多金属矿床深部找矿钻孔岩心为对象,开展碳-氧-锶同位素地球化学研究。结果表明,栖霞山矿床矿石样品δ13CV-PDB同位素值为-5.1‰～1.9‰,且由浅部至深部,矿石样品的δ13C、δ18O值处于增大的趋势,指示成矿流体中的碳起源于碳酸盐岩、源自地幔和岩浆的深源碳。对锶同位素的研究显示,栖霞山矿石~(87)Sr/~(86)Sr值为0.704816～0.71405,部分大于矿体围岩黄龙组灰岩的~(87)Sr/~(86)Sr值(0.708329～0.709685),部分小于矿体围岩黄龙组灰岩的~(87)Sr/~(86)Sr值,并与不同来源的Sr同位素对比,揭示栖霞山矿石中Sr兼具基底地层Sr和幔源Sr的混合来源特征,且在围岩蚀变过程中~(87)Sr/~(86)Sr的变化应主要由成矿流体引起。结合本区成矿地质特征认为,栖霞山矿床成矿流体可能来自花岗岩的期后热液,在热动力作用下,流经元古宇基底地层,形成具有混合物质来源的成矿流体,成矿作用过程主要为成矿流体与围岩碳酸盐岩发生水-岩反应所致。     

Carbon and nitrogen isotope records in sediments of Lake Taihu, China, and their paleoenvironmental significance

Lake sediments can provide important historical information on records of paleoenvironments and paleoclimates and their changes.This study deals with the sedimentary history of the westem Taihu Lake based on seven geochemical indices measured in an 89-cm long sediment core. The core, corresponding to a time period from 6870 a B.P. to the present, was analyzed for δ^13Corg, δ^15N, TOC, TN, TP, C/N ratio and radiocarbon dates. Comparison of these multiple geochemical tracers helps to improve interpretations of the paleoenvironmental changes. All of the geochemical proxies used in the study change regularly, and show four major time scales that suggest different environments. During 6870-6532 a B.P., the values of all parameters slightly varied. δ^13Corg values increased in a wave pattern from -25.9‰ to -20.7‰. Similarly, δ^15N values increased from 1.6‰ to 4.5‰. TOC, TN and TP concentrations remained around 0.8%, 0.1%-3.2% and 0.5%, respectively. C/N ratios varied from 20.6 to 6.6. At 6370 a B.P., the sediment record profile showed dramatic variations in all parameters. δ^13Corg and δ^15N values dropped to -26.9‰ and 1.3‰, respectively.     

胶东夏甸金矿成矿流体及成矿物质来源:H-O、He-Ar、Sr-Nd-Pb同位素证据

夏甸金矿是胶东金矿集区中一处大型焦家式矿床。文章在详尽的岩相学和矿相学研究基础上,对该矿床进一步开展 了H-O同位素并首次开展了He-Ar和Sr-Nd-Pb同位素示踪研究,为该矿床成矿流体及成矿物质来源提供了新的制约。石 英中流体包裹体的H-O同位素（δDV-SMOW=-102.3‰~-93.9‰,δ18OH2O=-0.2‰~1.6‰） 揭示出成矿流体主要为富集地幔流体, 并有少许大气降水加入;黄铁矿中He-Ar同位素[3He/4/He=0.58×10− 6~1.90×10− 6 （0.42~1.36 Ra）,40Ar/36Ar=724.7~1358.4]同样 表明成矿流体以富集地幔流体为主导;矿石及蚀变岩的Nd-Pb同位素既不同于围岩花岗岩,也不同于基底变质岩,与胶东 地区中生代软流圈地幔起源的玄武岩也相差甚远,而与胶东地区中生代富集岩石圈地幔起源的煌斑岩相一致,但它们的初 始87Sr/86Sr比值明显高于煌斑岩,甚至高于围岩花岗岩。Sr-Nd-Pb同位素特征表明成矿流体及成矿物质来源于富集岩石圈地 幔,并在其上升过程中与基底变质岩发生了相互作用。     

紫阳黄柏树湾和竹山文峪河毒重石矿床锶同位素及碳氧同位素研究

紫阳黄柏树湾毒重石矿床和竹山文峪河毒重石-重晶石矿床呈层状或似层状产于下寒武统下部或其相当层位的硅质岩中,矿体受岩性和岩相控制作用明显.对矿床中毒重石、钡解石和方解石的锶同位素及碳氧同位素的研究结果表明,形成这些矿物的碳主要来自沉积物中的生物有机质在早期成岩阶段经降解、缩合及脱羧基作用所形成的烃类物质或生物气;而锶主要为沉积物孔隙水中海水锶与沉积物中火山碎屑物质蚀变过程中所释放的锶的混合.毒重石形成于早期成岩阶段沉积物的孔隙水介质中,形成毒重石的成矿流体主要为早期成岩阶段沉积物中由海水、有机质组分和火山物质组分相互叠加和混合而组成的孔隙水有机成矿流体.毒重石矿石中广泛发育的生物碎屑及粒屑结构说明生物作用通过生物成因重晶石 (bio- barite)的形式将海水中的 Ba2 浓集并沉降于海底,形成钡矿床的初始富集体.因而,海水中生物作用和沉积物的早期成岩作用是形成本区毒重石矿床的主要机制.     

Sulfur, Carbon and Lead Isotope Studies of the Dajing Polymetallic Deposit in Linxi County, Inner Mongolia, China – Implication for Metallogenic Elements from Hypomagmatic Source

Abstract: The Dajing Cu‐polymetallic ore deposit in Linxi county, Inner Mongolia Autonomous Region, China, is economically a valuable Cu–Sn–Ag–Zn–Pb deposit in the southern section of the Da Hinggan metallogenic province. For the analyzed 23 samples of sulfide minerals, including chalcopyrite, pyrite, sphalerite and galena, the δ³⁴S values range from –1.8 to +3.8 % with an average of +0.65 %. The narrow distributions of the δ³⁴S values with +1 % peak value, including the published data, and the δ¹³C values around –5 % indicate that the sulfur and carbon of the hydrothermal fluids are derived from a hypomagmatic source, and exclude the possibility that the hosted strata, i.e., the Upper Permian Linxi Formation, provided certain amounts of sulfur and carbon. The ²⁰⁶Pb/²⁰⁴Pb, ²⁰⁷Pb/²⁰⁴Pb and ²⁰⁸Pb/²⁰⁴Pb ratios of sulfide ores range respectively within 18.257‐18.368, 15.476‐15.609, and 37.916‐38.355 with the model ages of 122–209 Ma. The black shale, however, contains higher radiogenic lead with the ²⁰⁶Pb/²⁰⁴Pb ratios of 18.473‐20.156, differing from the ores. However, the ²⁰⁶Pb/²⁰⁴Pb, ²⁰⁷Pb/²⁰⁴Pb and ²⁰⁸Pb/²⁰⁴Pb ratios of the ore, basaltic porphyrite and feldspar leads are similar, and lie on the same lines in the diagrams of ²⁰⁸Pb/²⁰⁴Pb vs. ²⁰⁶Pb/²⁰⁴Pb and ²⁰⁷Pb/²⁰⁴Pb vs. ²⁰⁶Pb/²⁰⁴Pb. The fact that these mixing lines are composed of the two end members, the mantle and orogenic belt, strongly supports that all the metallogenic elements were carried by the hypomagma mixing the matters of the mantle and orogenic belt prior to the Mesozoic. Therefore, the Dajing ore deposit is a typical mag–matic–hydrothermal vein type ore deposit associated with subvolcanic rocks.