海洋中二甲基亚砜的来源、分布及迁移转化

二甲基亚砜(DMSO)是海水中的主要溶解态甲基硫化物,DMSO在二甲基硫(DMS)的生物地球化学循环中起着重要的作用。它能通过DMS的光化学氧化和细菌氧化生成,可作为DMS的1个汇,也可以通过生物直接合成或其它途径产生。DMSO同时又可以被酶、细菌、植物等还原为DMS,因此,DMSO又可充当DMS的1个源。DMSO除了能被还原为DMS外,还可能会被细菌氧化为SO42-,在氯过氧化物酶作用下被H2O2氧化为DMSO2等。海洋中DMSO的测定通常采用还原剂NaBH4将其还原为DMS后,再利用气相色谱进行测定。海水中DMSO的分布不均匀,高浓度区是那些温度较高,光照充足、浮游植物较多、生物活性较高的表层水或近岸水。     

Semi-empirical equations for the partial molar volumes of some ions in water and in seawater

Partial molar volumes of the major salts of seawater found in diluted seawater and in pure water are experimentally determined at temperatures of 5°C, 15°C and 25°C. The range of salinity investigated, which is not purely oceanographic, is the link between pure water and seawater in the World Ocean.The partial molar volumes were determined by using the procedure of Poisson and Chanu (1976). An empirical relation is given, linking the partial molar volumes of the salts or major ions of seawater in pure water with those measured in seawater, within the salinity range 0–40 g kg⁻¹ and the temperature range 0–25°C.     

惠州市大亚湾淡澳河入海口的海水入侵和土壤盐渍化

海水入侵和土壤盐渍化是重要的海洋灾害类型。文章选取3个土壤采样点和3个地下水采样点,以地下水氯离子浓度和矿化度以及土壤氯离子含量、硫酸根离子含量和全盐量为监测项目,首次对惠州市大亚湾淡澳河入海口沿岸区域的海水入侵和土壤盐渍化状况进行研究。研究表明:研究区2个采样点未受海水入侵,1个采样点海水入侵程度为轻度;1个采样点为氯化物-硫酸盐型和中盐渍化土,2个采样点为氯化物型和盐土;海水入侵程度以及土壤盐渍化类型和程度与离岸距离均无相关性,但受与河口距离的影响。今后将进一步加强监测和研究,为沿海环境风险管控和海岸带整治修复提供科学依据。     

海岸带海水入侵的研究进展

海岸带海水入侵问题一直是国际社会共同关注的焦点。海水入侵的影响因素很多,其中人为因素占较大比重。海水入侵的方式因地而异,孔隙水含水层海水入侵较为严重。在研究中突变界面模型和过渡带模型各有其实用性。其中过渡带模型更具有适用价值,是今后主要的研究方向。本文概述了海岸带海水入侵问题现状,系统地总结了海岸带海水入侵模型近40多年来的研究成果,分析了研究中存在的困难,为进一步的研究打下基础。     

广西涠洲岛珊瑚礁海域水质环境变化研究与评价

文章根据2013—2016年广西涠洲岛珊瑚礁海域水质实际调查情况,应用单因子污染指数评价法、富营养化指数法和有机污染指数法,对近年来涠洲岛珊瑚礁海域水质环境变化进行综合分析和评价。2013—2016年,广西涠洲岛珊瑚礁海域水质大部分符合国家第一类海水水质标准,满足珊瑚礁的正常生长要求,但悬浮物含量持续偏高,对珊瑚礁造成一定影响。涠洲岛海域水体虽未出现显著的污染,根据历史数据分析,人为排污已在一定程度上影响珊瑚礁的生长,持续的监测有助于及时发现水质环境质量的变化。     

洞头县重点养殖海域水质监测及分析

洞头列岛海域是浙江省重要的海洋水产养殖基地,近两年来频繁发生赤潮,为了保护洞头县规模化水产养殖产业的优良生态环境,2003年9月至2004年7月对洞头县重点养殖海域水质的时空变化趋势和质量状况进行了研究和分析.结果表明,洞头列岛海域海水综合质量总体上处于轻污染水平,富营养化明显,DIN和IP是水质富营养化的主要因素,而油类是需要重点控制的污染物.     

Short-term changes of marine bacterioplankton in antarctic coastal environment

Observations of the short-term changes of seawater bacterioplankton were carried out during the summer of 1988 in Antarctic coastal surface waters. The studies were designed to compare the variations of bacterioplankton in freemoving and enclosed seawater. Even when a diurnal cycle is present the data collected from the enclosed seawater experiments remain much more constant than the corresponding data in free-moving seawater. The wide range of parameters used in the two experiments reveals common properties which illustrate the major role of displacements of water masses at a fixed sampling station in the temporal changes observed in free-moving Antarctic coastal seawater.     

Long lifetimes of β-glucosidase,leucine aminopeptidase,and phosphatase in Arctic seawater

The active lifetime of extracellular enzymes is a critical determinant of the effectiveness of enzyme production as a means for heterotrophic marine microbes to obtain organic substrates. Here, we report lifetimes of three classes of extracellular enzyme in Arctic seawater. We also investigated the relative importance of photochemical processes and particle-associated processes in inactivating extracellular enzymes. Enzyme inactivation in filtered seawater was slow, with apparent half-lives of enzyme activities on the order of hundreds of hours. The presence of particles (including cells) did not significantly change inactivation rates, suggesting that the long half-lives observed in filtered seawater were realistic for enzymes in unfiltered seawater. Phosphatase and leucine aminopeptidase were susceptible to photoinactivation, but only under high intensity UV-B and UV-C illumination; there was no evidence for increased inactivation rates under natural illumination at our study site in Ny Ålesund, Svalbard. Comparison of inactivation rates of commercially-obtained enzymes from non-marine sources with the extracellular enzymes naturally present in Arctic seawater suggests that the natural enzymes contain structural features that confer longer lifetimes, consistent with observations reported by others from a range of field sites that cell-free enzymes can contribute a substantial fraction of total hydrolytic activity in the water column.     

Todorokite formation in seawater by microbial mediation

Microbial manganese oxidation in seawater was carried out in enrichment cultures which were obtained from the seawater supply system at the Marine Science Museum, Tokai University (Shimizu-shi, Japan). The manganese oxide formed was well-crystallized todorokite. The major element composition was within the range of marine manganese concretions and the O/Mn molar ratio was 1.8. The conditions for formation of manganese oxide minerals in marine environments are discussed on the basis of these results.     

White-light promoted degradation of leucopterin and related pteridines dissolved in seawater, with evidence for involvement of complexation from major divalent cations of seawater

The photochemical instability of several related pteridines in seawater was investigated by aseptic incubation of solutions at 20–22°C under illumination from cool-white light of intensity 6 kerg cm⁻² sec⁻¹, and the chemical changes were spectrophotometrically monitored. All the pteridines showed markedly accelerated degradation from this illumination relative to their behaviour in total darkness.Pterin and lumazine were degraded very slowly with zero-order reaction kinetics, while the other pteridines photolysed rapidly (according to first-order kinetics) with decomposition rates increasing in the order dioxylumazine (2,4,6,7-tetrahydroxypteridine) < leucopterin < isoxanthopterin < xanthopterin < oxylumazine (2,4,6-trihydroxypteridine). Excepting leucopterin and dioxylumazine, the photolysis rates were attributable to the pH of seawater and not its salt content; this was also the case with oxylumazine which required the salt content of seawater for decomposition in darkness. Leucopterin and dioxylumazine (both 6,7-dihydroxylated pteridines) gave evidence of complexation with the major divalent cations (Ca²⁺, Mg²⁺) of seawater, by virtue of which their photolytic degradation rates were enhanced to magnitudes obtained in pH-10 buffer without seawater. It is proposed that such complexation produces structural forms of these pteridines analogous to their normal ionic forms at pH 10–12.The photolysis of the 6-hydroxylated pteridines (xanthopterin, oxylumazine) proceeded via intermediate formation of their corresponding 7-hydroxylated derivatives (leucopterin, dioxylumazine).     

Monitoring trace metals in seawater using a diffusive gradient in thin film probe in Ulsan Bay,East Sea,Korea: Comparison with transplanted mussels

To evaluate the applicability of a diffusive gradient in thin film (DGT) probe for monitoring dissolved metals in coastal seawater, DGT-labile metal concentrations were compared with total dissolved metal concentrations using spiked and natural seawater samples in the laboratory and transplanted mussels (Mytilus galloprovincialis). This was achieved through the simultaneous deployment of DGT probes and transplanted mussels in Ulsan Bay during winter and summer. DGT-labile metal concentrations were 45% (Cu) ~ 90% (Zn) of total dissolved concentrations, and the order of non-labile concentrations was Cu > Pb > Co ~ Ni > Cd ~ Zn in both metal-contaminated and non-contaminated seawater samples, which was similar to the order of stability of metal complexes in the Irving–Williams series. The overall variability of the DGT probe results within and between tanks was less than 10% (relative standard deviation: RSD) for all the metals tested during a 48-h deployment. The accumulation of metals, as determined by DGT probes, represented the spatial gradients better than the transplanted mussels did for all of the metals tested, and the extent of metal accumulation in mussels differed depending on the metal. The comparison of results for the DGT probe and the transplanted mussels in two seasons (winter and summer) suggested that metal accumulation in mussels was controlled by the physiological factors of mussels and partly by their diet (particulate metal loadings). The DGT probe could be used as a monitoring tool for dissolved metals in coastal seawater because its results explained only labile species. When using the DGT probe, slightly more than half of the total dissolved concentration in seawater samples for all the metals investigated displayed timeintegrated properties and distinct spatial gradients from pristine to metal-contaminated seawater.     

南沙群岛珊湖礁潟湖垂直沉降颗粒物中主要元素的生物地球化学过程研究

本文首次报道用沉积物捕捉器（ＳＴ）研究南沙群岛珊瑚礁湖沉降颗粒物中主要元素垂直通量、垂直转移形态、再循环过程及垂直通量与表层海水温度的关系。结果显示,作为生物化学沉积标志的Ｃａ、Ｍｇ具有最高的垂直通量,达１．４和０．１ｇ／（ｍ２·ｄ）以上,作为生物富集标志的Ｂｒ、Ⅰ也有较高的垂直转移量;垂直转移形态的研究表明Ｎａ、Ｋ、Ｃａ、Ｍｇ、Ｓｒ主要以碳酸盐结合态向海底转移,其中Ｃａ、Ｍｇ、Ｓｒ占９９％以上,Ｆｅ、Ｉ、Ｂａ主要以铁锰氧化物结合态向海底输送,在垂直沉降颗粒物到达海底后,有相当部分的主要元素可再循环进入水体中,Ｂｒ、Ｉ、Ｋ、Ａｌ的绝大部分进入再循环,Ｍｇ、Ｎａ、Ｃｌ有一半左右进入再循环,Ｃａ、Ｓｒ、Ｂａ、Ｆｅ大部分被埋葬;Ｎａ等９种元素的垂直转移量随ＳＳＴ呈指数降低响应,对ＳＳＴ的敏感性Ｆｅ＞Ｂｒ＞Ｓｒ＞Ｃａ＞Ｎａ＞Ｃｌ＞Ｍｇ＞Ｉ＞Ａｌ,这再一次验证了ＣａＣＯ３随温度升高,其溶解度降低、化学沉积量增加这一自然界的普遍规律,表明在珊瑚礁海水的垂直沉降颗粒物中主要元素是作为珊瑚的重要成分与ＣａＣＯ３一同被沉积下来的,ＣａＣＯ３起到稀释剂的作用。     

海底承压含水层排泄电阻率法探测效果模拟与分析

海底承压含水层排泄是海底地下水排泄的一种主要形式。由于这一过程发生在海水层下部，探测难度较大。为探讨海洋多电极电阻率法对该过程的探测能力，根据典型海底承压含水层地质模型构建不同排泄阶段地电模型，模拟海面和海床面两种探测情形分别进行多电极电阻率法理论探测结果计算和物理模拟，并对所得电阻率剖面进行对比分析。研究结果表明，水面多电极电阻率探测剖面能够清晰刻画出排泄入海的淡水体在海水中迁移、混合过程，但剖面异常特征和分辨率受探测装置形式、电极极距、海水深度影响；海床面探测则对沉积层中咸淡水交换过程反映能力更强，沉积层中的锲形海水侵入体可得到良好反映。     

Pentachlorophenol and 3,4-dichloroaniline as models for photochemical reactions in seawater

Pentachlorophenol (PCP) and 3,4-dichloroaniline (DCA) were used as models to examine photochemical reactions in seawater.The photolysis of PCP in seawater differed in both rate and product distribution from that in distilled water; rates were slower in seawater due to the photonucleophilic interaction of PCP with chloride ions, demonstrated by the formation of ³⁶Cl-labeled PCP in irradiated PCP solutions containing Na³⁶Cl. DCA showed no rate change and gave identical products in both systems. Both PCP and DCA yielded greater amounts of photoreduction products in seawater than in distilled water, and tetrachloromuconic acid was isolated and identified as a new and unstable PCP photoproduct resulting from ringfission. This study demonstrates the operation of photooxidation, photonucleophilic substitution, and photoreduction reactions which differ in detail between seawater and distilled water and suggests that photochemical reactions can be a major factor in the breakdown of organic pollutants and other chemicals in the marine environment.     

Diffusion coefficients of major ions in seawater

Self-diffusion coefficients of five major ions have been determined by a radioactive tracer method (capillary tube method) in seawater of salinity 34.86 at 25°C. Data are presented for Na⁺, Ca²⁺, Cl⁻, SO₄², and HCO₃⁻, which constitute about 95% by weight of sea salt. The influence of temperature and salinity on these coefficients has been studied for Na⁺ and Cl⁻ which are the major components of sea salt: self-diffusion coefficients of these two ions have been measured in seawater, at different temperatures for a salinity of 34.86 and at different salinities for a temperature of 25°C. Diffusion coefficients of the same ions have been determined at 25°C by using another radioactive tracer method (quasi-steady cell method). In this experiment, seawater ions were allowed to diffuse from natural seawater into dilute seawater. Data have been obtained at 25°C for Na⁺, Ca ²⁺, Cl⁻, SO₄²⁻ and HCO₃⁻, corresponding to different salinity gradients.     

An ion-association model for estimating acidity constants (at 25°C and 1 ATM total pressure) in electrolyte mixtures related to seawater (ionic strength < 1 mol kg−1 H2O)

The ion-association model of Garrels and Thompson (1962) has been extended in order to incorporate the major acid—base systems present in seawater. The data for the activity coefficients of the various species considered have been presented as a function of ionic strength, thus making it possible to apply the model to solutions with ionic strengths in the range 0–1 mol kg^?1 H₂O. The model therefore allows the prediction of a variety of equilibrium thermodynamic data for natural waters.The model was used to estimate the stoichiometric acidity constants of the major weak acids present in seawater; the conditions simulated correspond to actual measurements made in seawater media at a variety of ionic strengths (salinities). The estimates obtained are generally in good agreement with the experimental results (all within 10% and usually within 5%), thus confirming the usefulness of this model.     

海水循环冷却系统腐蚀、污垢和菌藻控制技术研究

海水循环冷却技术,是海水资源利用领域一项新技术,属于海水直接利用技术的范畴。海水含盐量高,具有腐蚀和结垢性的离子浓度远高于一般淡水,且微生物和大生物的种类多、含量高,远不符合国家标准《工业循环冷却水处理设计规范》规定的循环冷却水的水质要求,但是,海水循环冷却技术实验室研究表明,通过添加海水缓蚀剂,阻垢分散剂,菌藻杀生剂等海水水处理药剂,在腐蚀控制,污垢控制,菌藻控制等方面,可以达到或接近国家有关标准规定的技术指标要求。     

北冰洋中心区表层淡化层的藻类色素组成

季节性海冰融化在北冰洋中心区表层形成淡水层,影响了浮游植物的类群。研究发现岩藻黄素（Fuco,指示硅藻）是冰芯底部检测到的主要光合色素,叶黄素（Lut）和叶绿素b （Chl b）（指示绿藻）是冰水界面浓度最高的类胡萝卜素。海冰底部硅藻占据了绝对的优势,但在冰水界面藻类类群转变了以绿藻为主的结构。冰下水中,浮游植物群落随着深度的增加,由绿藻为主快速转变为以硅藻为主,盐度可能是导致这种变化的原因。     

The effect of pressure on the chemical potentials of seawater components,on ionic species in seawater,and on calcite saturation levels

The activities of most of the major seawater components at 1,001 bars have been estimated, and values for the ions deduced. Equations giving the effect of pressure on the activities of ionic species in seawater ($\text{S = 35‰}$) have been developed. The species covered are: NaSO₄^?, MgSO₄⁰, CaSO₄⁰, H⁺, the free base (NH₃), the HCO₃^?/CO₃² activity ratio and the ion activity product of calcium carbonate. Comparison of the latter with the “ideal” solubility of calcite (pure solid in equilibrium with a mixed electrolyte solution) indicates a degree of saturation compatible with the trends indicated by in situ measurements.     

基于ArcEngine 的海水水质可变模糊评价系统设计、实现及应用

针对大多数传统的水质评价方法往往将评价标准或参照标准处理成点的形式存在一定的不足,将可变模糊评价方法引入海水水质评价,设计并建立基于 ArcEngine 的海水水质可变模糊评价系统,通过ArcSDE数据引擎和专用开发数据库访问类访问SQL Server中的海水水质评价数据库,在Visual C#2008开发环境下,将可变模糊数学模型与GIS空间分析手段集成,实现了海水水质等级评价结果的直观化、可视化表达。结果表明： GIS技术和可变模糊评价方法应用于海水水质综合评价中是完全可行的,为控制环境污染、进行环境规划提供了科学依据。