考虑表皮效应的径向溶质迁移模型以及半解析解

径向示踪试验是一种非常有效的获取含水层弥散参数的试验方法,但传统径向示踪试验很少考虑抽水井附近的表皮效应(由于钻井施工工艺所导致抽水井附近一定区域水力性质发生变化).建立了考虑表皮效应的单井注入示踪试验模型,并利用Lapalce变换以及数值逆变换获得了该模型的半解析解.系统分析了表皮区域水力性质对示踪试验穿透曲线的影响规律.研究结果表明:表皮区域的弥散度越大,穿透曲线早期的浓度越高,且峰值越高;表皮孔隙度越大,穿透曲线早期浓度越低,后期浓度越高;此外,散度差异也会导致浓度分布曲线在表皮区域与含水层界面处发生突变.总之,表皮效应对径向溶质迁移产生了较大的影响,有必要将表皮效应考虑到径向示踪试验中去.     

The Effect of Flow on Pollution and Remediation in Groundwater

1IntroductionFlow is the key mechanism by which pollutants are transmitted from one point to another in hydro-geologic systems. Groundwater flow is not indepen-dent of the geological formation within which it occurs. Hydraulic conductivity which is a measure of groundwater flow is strongly related with the am-bient geologic properties such as texture,porosity and topography. These properties do not only con-trol the rate of groundwater flow but also limit the occurrence,hence the dispersion of…     

The Effect of Flow on Pollution and Remediation in Groundwater

Flow, solute transport and pollution remediation through attenuation in unconsolidated porous media were investigated in this study. The variables used in the investigation include soil texture, porosity, topography and hydraulic conductivity. The study revealed that hydraulic conductivity is highly dependent on soil texture, porosity and topography.Hydraulic conductivity was noted to have a controlling influence on groundwater flow and residence time, and the degree of natural attenuation in hydrogeologic systems. Contaminant transport simulated with the MODFLOW Model revealed dominance of advective transport of contaminants in unconsolidated porous media. However, attenuation through sorption (linear isotherm equilibrium controlled) and reaction (first-order irreversible decay) also retarded contaminant plume migration. Thus natural attenuation was found to be highly feasible in clay formations due to low hydraulic conductivity and long groundwater residence times. Though natural attenuation processes including dispersion, diffusion, dilution, mixing, volatilization and biodegradation were not investigated for in this paper, it is shown to be a sound remediation technique of contaminated ground water due to its capacity to destroy or transform contaminants or at least retard their flow.     

岩溶多重介质地下水模拟技术及应用进展

由于岩溶发育的极不均匀性和岩溶含水介质的多重介质性等特征, 使得岩溶水系统的地下水运动规律呈现出复杂多变的特点, 在孔隙或微小裂隙含水介质中岩溶水满足达西流, 而在岩溶管道中可能出现非达西运动, 这给岩溶区地下水模拟带来了极大挑战。系统地梳理了岩溶水流和溶质运移模拟的主要方法, 总结了复杂岩溶多重介质系统地下水模拟技术的现状, 并结合我国南方岩溶和北方岩溶各自的特点, 提出岩溶水模型在实际应用中需要关注的要点。主要包括: 需加强野外调查和观测, 提高模型中对岩溶含水介质结构非均质性表征的精度; 进一步深化对岩溶水运动机理的研究, 刻画岩溶多重介质的水流特征以及水交换机理; 针对北方岩溶水系统模拟, 可选择等效连续多孔介质模型, 重在耦合区域分布的岩溶溶孔－裂隙介质中慢速渗流与脉状分布的强径流带快速流; 对于南方岩溶区, 建议考虑建立分布式流域水文模型与能刻画集中管道流多流态变化的多重介质模型的岩溶地下水耦合模型。      

于家沟地下水反应溶质运移规律数值仿真

针对矸石淋滤液对于家沟地区地下水污染的实际情况,分析其在含水层中运移的规律,充分考虑了地下水变密度对浓度分布的影响,建立了多组分溶质在地下水中运移的耦合动力学数学模型,采用Galerkin有限元方法和Picard迭代法相结合对耦合模型进行了离散,通过室内土柱实验求得基本参数并对地下水污染的动态过程进行了仿真模拟,预测了污染浓度的时空分布特征。结果表明:污染面积随时间推移不断向两轴方向扩大,且纵向显著;不同组分由于各自特征的巨大差异,受到地下水密度影响的程度也有很大差别;渗滤液浓度拟合误差小于6%,从而验证了模型的可靠性和实用性。     

一种用于突发性场地污染模拟的解析模型

为了及时有效地应对各种突发性环境污染事故,有必要开发一种简单实用、适于各类型污染物的场地污染数学模型。通过污染事故发生后污染物在包气带、饱和带迁移转化的概化,建立了污染物运移的自由入渗模型以及降雨入渗模型并给出各自相应的解析解。无降雨时,考虑污染物在重力作用下随包气带向下渗透的作用,建立一维垂直入渗模型。有降雨时,考虑污染场地(包气带)中污染物迁移和转化的对流作用、扩散作用及挥发、生物降解、吸附、根系吸收等作用,建立包气带剖面二维溶质运移模型和饱和带平面二维溶质运移数学模型。建模过程中,假定降雨量的平均分布及土壤质地、水力参数以及有机物成分、种类均相同,同时假定污染物与多孔介质间的作用为线性吸附,植物根系对污染物的吸附遵循一级动力学。基于模型的解析解,实现案例的模拟计算。模拟结果表明:该模型具有适用范围广、模拟高效快捷等优点,能够较准确预测污染发生后污染物在土壤中的动向、到达饱和带的时间以及饱和带中污染物的迁移情况。     

本钢郑家屯潜水含水层弥散试验研究

在本钢郑家屯潜水含水层中进行了弥散试验，以Ｃｌ－为示踪剂，瞬时投放，根据流场条件，建立了二维水质运移模型。利用标准曲线法进行处理，得到了各监测井处的弥散度。对该试验结果进行分析，得到了在试验范围内，多孔介质中水动力弥散度的变化。     

Micromorphology of surface crusts in the Knersvlakte, South Africa

Soils in the Knersvlakte are particularly prone to crusting and have lower inherent infiltrability than other soils across western southern Africa. Micromorphological techniques were used to examine the structure and porosity of soil crusts in the Knersvlakte to ascertain why crusting is so intense in this region. Quantile regression using boundary lines was employed to examine the relationships between infiltrability and soil properties for all samples （n = 67）. This analysis showed that infiltrability is potentially maximal at low water- dispersible ＇clay plus silt＇ content and low silt content （r^2 = 0.72 and 0.64; respectively, n = 67） （Figure 2）. The strength of crusts, pH, EC, clay mineralogy, and water-dispersible clay, silt and ＇clay plus silt＇ content were compared, and a pore analysis using optical microscopy was undertaken on images of six soil thin sections （n = 6） （circular and parallel polarizers）. Pore analysis was further undertaken on five horizontal slices of equal dimensions taken through each soil thin section. The porosity samples with low infiltrability （〈 100 mm·hr^-1, n = 4） had greater crust strength, lower porosity （both total and in the least porous slice） and greater water-dispersible ＇day plus silt＇ and silt content than the porosity samples with high infiltrability （〉 100mm·hr^-1, n = 2）. The porosity samples with low infiltrability showed a trend of lower pH and greater water dispersible clay percentage. Porosity varied within the porosity samples due to the presence of dense clay/silt bands （〈 0.5 mm in width） with relatively few air vesicles. The porosity samples with horizontal slices of low porosity （but large numbers of air vesicles） had low infiltrability, while those without slices of low porosity （and relatively few air vesicles） had high infiltrability. We conclude that the intense crusting and resultant low infiltrability of soils in the Knersvlakte appears to be related to the formation of thin, dense clay/silt bands in the pedoderm.     

Porosity Distribution Characteristics and Geological Analysis of Brine Storage Medium in the Qaidam Basin,Western China

Underground brine is an unusual water resource that contains abundant mineral resources. It is distributed widely in the Qaidam Basin, western China, a hyperarid inland basin located in the northern Tibetan Plateau. Pores in the brine storage medium act as storage space and transmission channels of underground brine. Therefore, the porosity of brine storage medium determines its ability to store brine. In this study, Mahai Salt Lake was used as the research area as a modern saline lake located in the north area of the Qaidam Basin. A total of 100 porosity samples were collected from eight sampling points in two profiles of the research area at sampling depths of 1.30–314.78 m. The porosity distribution characteristics and influencing factors in brine storage medium were analysed according to the measured porosity data. Based on analysis of the pore structure characteristics, the brine storage medium contains intercrystalline pores, unlike conventional freshwater storage mediums. Moreover, the primary salt rock is susceptible to dissolution by lighter brine, facilitating the formation of secondary porosity. Due to the formation of secondary pores, a porosity greater than 20% remains even at buried depths greater than 100 m. Based on the geological statistical analysis, due to the geographic location, salt formation time, and depositional environment, the porosity values of Mahai Salt Lake do not exhibit a wider distribution, but also show more extreme values than a nearby salt lake. Based on the porosity characteristics by depth, due to the presence of secondary pores, flooding, stratigraphic static pressure, and other factors, porosity shows fluctuations with increasing depth.     

地下水含水介质的弥散度测定

以水动力弥散理论为基础,根据改进的水动力弥散装置,以氯化钠作为示踪剂,用电导仪间接地测定溶质的突破曲线,最后用解析法确定地下水多孔介质中溶质迁移的弥散度。     

江苏滨海平原弱透水层封存的古咸水及其运移过程

滨海平原弱透水层广布且多赋存古咸水，其盐度分布及运移过程深刻影响着含水层地下水的演变，却得到甚少关注。采集了江苏滨海区7个浅层钻孔弱透水层原状样品，压榨法收集孔隙水。利用孔隙水天然示踪剂ρ（Cl-），ρ（Br-）剖面和数值模拟分析了弱透水层孔隙水盐度特征和运移机制。得出浅层孔隙水ρ（Cl-）垂向剖面存在2个趋势:①峰值在表层，沿深度逐渐下降；②峰值在深度25m左右，向两端浓度降低。孔隙水ρ（Cl-）为486.2~38 036.7 mg/L，Cl/Br比值为72~360（均值241）。ρ（Cl-）与Cl/Br比值关系及剖面分布说明孔隙咸水为海相成因，来自于全新世海侵时期的古海水，并受到后期淡水的稀释。弱透水层孔隙水一维垂向运移数值模型表明海侵-海退事件控制了海岸带弱透水层孔隙水的盐度演变，全新世古海水仍封存在沉积物中，更新世时期的海水已被驱替。孔隙水运移以扩散为主，垂向运移速率为0.43~15.8 mm/Ma。在相对高渗透性的粉砂地层中，可能还受到侧向对流的影响。弱透水层中古海咸水的重新分布，尤其在地下水超采条件下，可能成为地下水的重要咸化来源。      

岩溶含水层饱和-非饱和流动与污染物运移数值模拟

岩溶含水层中的地下水是重要的可饮用水来源, 由于其复杂的水文地质特征, 采用数值模型分析和评价含水层中地下水环境极具挑战性。采用变饱和度流动方程描述含水层基质中的饱和-非饱和流动, 采用管道流方程描述岩溶管道中的层流及紊流流动, 基于流动解采用对流弥散方程分别描述基质与管道中的溶质迁移过程。根据相关实验数据以及MODFLOW-CFP程序的模拟结果对流动模拟的准确性进行验证, 并基于此开展了岩溶管道以及非饱和参数对地下水流动及污染物迁移影响的模拟。结果显示, 数值模型能很好地重现含水层中饱和区与非饱和区以及岩溶管道的地下水动态, 岩溶管道对含水层的渗流场产生了较大的影响。管道中快速流动的特性使得周围的水向其中汇集, 影响了局部流动场, 进而使得泄露的污染物质随水流进入管道, 快速向管道出口处(泉点)迁移, 突破曲线显示管道出口处的污染物浓度响应速度远快于基质中对应的位置, 非饱和参数对管道中污染物浓度的响应速率有着不同程度的影响。建立的模型完善了岩溶含水层中非饱和区地下水流动、污染物运移以及基质-管道流动与溶质运移耦合模拟等方面的工作, 加深了对岩溶含水层地下水动力学以及污染物迁移过程的认识, 对岩溶水文地质及地下水环境等方面具有重要意义。      

对弥散试验的几点新认识

弥散试验是揭示溶质在地下水中运移机理和获得弥散度等重要水质参数的可靠方法之一．本文在对弥散试验的研究现状、弥散理论的新发展进行了系统分析之后发现，目前弥散试验在条件选择方面存在着某些不足之处，进而对改进弥散试验提出了几点新认识。     

岩溶洼地内涝蓄水量与不同级次裂隙对溶质迁移影响的室内实验与模拟

岩溶洼地在西南地区分布广泛,岩溶地下水为当地居民生产和生活的主要水源,研究岩溶洼地内涝条件下裂隙系统中的溶质迁移及响应规律可为峰丛洼地区岩溶地下水的污染防控提供科学依据。基于相似原理构建了岩溶洼地-裂隙系统物理模型,采用对流-弥散模型和脉冲响应模型对溶质迁移过程进行了模拟分析,探讨了不同级次裂隙和内涝蓄水量大小对溶质迁移的影响。结果表明:大裂隙作为优先水流通道,对溶质迁移起主要的控制作用;小裂隙对溶质迁移起暂时储存和缓慢释放的调蓄作用,其溶质迁移的叠加过程使总出口溶质迁移的"拖尾"效应更加明显;随着内涝蓄水量的增加,稀释作用增强,导致溶质峰值质量浓度降低、溶质质量浓度回归至本底值的时间延长、延缓释放溶质的质量增加。该物理模型是对复杂岩溶洼地系统内污染物迁移研究的一种新探索,其模拟结果进一步深化了对洼地内涝条件下面源污染物在岩溶水系统中迁移规律的认识。      

Groundwater protection from cadmium contamination by permeable reactive barrier in Qian'an of Jilin,China

This research studies the reliability of an activated carbon permeable reactive barrier in removing cadmium from a contaminated shallow aquifer.Laboratory tests have been performed to characterize the equilibrium and kinetic adsorption properties of the activated carbon in cadmium-containing aqueous solutions.A 2D numerical model has been used to describe pollutant transport within a groundwater and the pollutant adsorption on the permeable reactive barrier(PRB).In particular,it has been considered the case...     

Experimental study on dispersive soil in western Jilin

In order to research engineering geological properties of the soil in Zhenlai of western Jilin,especially the dispersivity of soil,the authors carried out the basic physicochemical test and dispersivity identification test.The results show that the dispersivity of the soil increases with the increase of depth within 0-30 cm (surface soil);it decreases as the depth increases within in 30-100 cm.Furthermore,the statistical analysis of the dispersivity indexes and physicochemical propertity indexes show that t...     

Quantitative simulation on soil moisture contents of two typical vegetation communities in Sanjiang Plain,China

Different types of vegetation occupy different geomorphology and water gradient environments in the San-jiang Plain,indicating that the soil moisture dynamics and water balance patterns of the different vegetation communi-ties might differ from each other.In this paper,a lowland system,perpendicular to the Nongjiang River in the Honghe National Nature Reserve(HNNR),was selected as the study area.The area was occupied by the non-wetland plant forest and the typical wetland plant meadow.The Microsoft Windows-based finite element analysis software package for simulating water,heat,and solute transport in variably saturated porous media(HYDRUS),which can quantita-tively simulate water,heat,and/or solute movement in variably-saturated porous media,was used to simulate soil moisture dynamics in the root zone(20-40 cm) of those two plant communities during the growing season in 2005.The simulation results for soil moisture were in a good agreement with measured data,with the coefficient of determi-nation(R2) of 0.44-0.69 and root mean square error(RMSE) ranging between 0.0291 cm3/cm3 and 0.0457 cm3/cm3,and index of agreement(d) being from 0.612 to 0.968.During the study period,the volumetric soil moisture content of meadow increased with the depth and its coefficient of variation decreased with the depth(from 20 cm to 40 cm),while under the forest the soil moisture content at different depths varied irregularly.The calculated result of water budget showed that the water budget deficit of the meadow was higher than that of the forest,suggesting that the meadow is more likely to suffer from water stress than the forest.The quantitative simulation by HYDRUS in this study did not take surface runoff and plant growth processes into account.Improved root water uptake and surface runoff models will be needed for higher accuracy in further researches.     

滇中高原岩溶关键带典型含水系统水化学特征及成因分析

岩溶关键带水文地球化学过程的研究对于科学认识其内部的演化环境与结构特征具有重要意义。岩溶水是水-岩作用后主要的信息载体, 定量分析其水化学特征及成因是揭示岩溶关键带含水系统介质环境与水动力条件的有效手段。以滇中高原岩溶关键带3个典型岩溶含水系统为研究对象, 通过对不同含水系统出露的岩溶泉进行野外采样与室内测试, 综合采用数理统计分析、水化学图解、离子比例系数与水文地球化学模拟等方法, 深入剖析了各含水系统岩溶水水化学组分特征、成因作用和含水层介质特性, 并对关键带中水循环与水化学的内在联系及规律进行了探讨。结果表明: ①HCO₃-、Ca2+是各含水系统岩溶水中含量最高且来源稳定的离子组分, Mg2+是控制各含水系统水化学类型异化的关键因素; ②碳酸盐岩类的岩石风化、矿物溶解是各含水系统内岩溶水化学组分特征的主要成因作用, 岩溶水对华宁水系统含水层的溶蚀作用仍在发生, 阳离子吸附交替与硅酸盐岩类的风化溶解是区域岩溶水中Na+、K+的重要来源; ③区域岩溶的发育强度、岩溶含水层的出露条件及含水介质岩性与连通性共同塑造了滇中高原岩溶关键带不同含水系统地下水化学特性。研究成果丰富了对滇中高原岩溶关键带水文地球化学过程的认识, 为区域岩溶水资源的开发、利用与保护提供基于水化学的证据支撑。      

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Chemical mechanism of flocculation and deposition of clay colloids in coastal aquifers

Seawater intrusion has become one of serious environmental problems in coastal areas. During the replacement of saline water by fresh water in the aquifers, in-situ clay could be released, transport and deposit in the porous media due to the change of hydrodynamic and geochemical conditions, which resulted in the increasing of particle size, plugging of pores and reduction of the permeability. Batch experiments and sand column experiments were explored to study the relationships between the flocculation of in-situ clay and geochemical conditions, by changing ionic strength and ionic type of clay suspension. Column outflow was analyzed for suspended particles and electrical conductivity. The total percentage of colloid straining and interception distribution in porous media was calculated. The results indicate that porous media had an effect on the interception of clay colloid particles with about 10 percent clay colloids captured due to the rough surfaces and spatial structure of porous media. Ionic strength played a key role on the permeability reductions. The higher ionic strength is, the greater the amount of colloidal particles trapped. Ionic type also had a significant effect on the interception of clay colloid particles. Ripening was the main mechanism for the interception within porous media when the bulk solution was potassium chloride while blocking happened when the bulk solution was sodium chloride. The distribution of clay colloids in porous media was heterogeneous. The closer to the sand column inlet was the less interception of clay colloids was. The results can provide the scientific basis for preventing the water sensitivity during the process of salty aquifer restoration.