塞浦路斯特罗多斯型洋壳最上部500米剖面(CY—1钻孔)中的不透明矿物、磁性及其蚀变作用的研究

引 言 近十年来为了鉴别大洋盆地中线性磁异常模式的起源,对洋壳磁化强度的研究显示了极大的兴趣。目前了解洋壳(尤其在深部)可以通过几种方法,如在推测为构造断崖的附近进行海底拖曳打捞、通过大洋基底钻探或通过考察蛇绿岩剖面等。 拖曳打捞和钻探均可从原地洋壳的各个层位获得样品,但是在钻探大洋基底时,大多数钻孔的穿透小于100米,一些深孔也小于600米,这个深度与推测的洋壳喷出岩1.5     

莫霍计划的回顾与展望

“莫霍计划”是20世纪50年代末提出来的堪与“登月计划”相媲美的最宏伟的科学计划之一。它开启了大洋钻探的新篇章，拉开了探索大洋岩石圈的序幕。历经半个多世纪的深海探索，研究学者逐渐揭开了洋壳结构的复杂性和多变性，其中代表下洋壳层3的辉长岩乃至地幔岩剥露的大洋核杂岩，为莫霍钻的实施提供了捷径和优选区。本文综述了“莫霍计划”以来在洋壳结构、洋壳增生机制和大洋核杂岩方面的研究进展，通过分析国际上莫霍计划的选址和策略，结合我国南海洋壳的特征，初步提出“南海莫霍计划”的两个站位及策略：① 南海残余洋中脊附近的U1431孔，该孔已钻到玄武岩层，可通过重复钻进钻穿莫霍面；② 南海东缘残余扩张脊的管事海山，可能有下洋壳辉长岩剥露，可在该区域采取多阶段钻探钻穿莫霍面。     

大洋岩石圈和大陆岩石圈的元素丰度

根据大洋地壳、大陆地壳、上地幔和球岩石圈的元素丰度资料,本文初次分别求出大洋岩石圈和大陆岩石圈的元素丰度.可用作研究化学元素在洋圈或陆圈内各地区分布特征的地球化学背景值.     

蛇绿岩记录的大洋地幔内熔体迁移过程

大洋岩石圈形成演化的关键过程是熔体如何从软流圈地幔中抽取、迁移汇集并最终形成洋壳.蛇绿岩可能为揭示上述过程提供关键对象.前人研究发现,熔体在地幔中主要通过网脉状纯橄岩通道发生迁移汇聚,这种地幔通道与壳幔过渡带和洋壳内的岩浆体系共同构成大洋扩张中心的巨型熔体抽取系统.地幔深部来源的熔体在通过纯橄岩通道时,会发生复杂的熔岩相互作用,使得熔体和地幔的组成均发生变化,形成大洋岩石圈壳-幔组成解耦现象.在不同的大洋扩张中心,地幔内熔体迁移方式和过程是多样的,导致大洋岩石圈的结构和组成复杂多变.我国西藏雅江带蛇绿岩形成于多种构造体制(洋中脊、俯冲带等),其地幔内发育较为新鲜的纯橄岩通道样品,如纯橄岩、铬铁矿岩、辉石岩等.这些样品能够为深入研究地幔纯橄岩通道的成因、熔体在通道内的反应迁移过程,以及不同构造体制下大洋岩石圈壳-幔组成解耦与否的原因,提供新的窗口,同时有助于进一步认知大洋扩张中心巨型岩浆-动力系统、壳幔圈层分异和地球物质循环过程.     

发育大洋斜长花岗岩的南海管事平顶海山：深部地壳和莫霍面钻探的优选区？

本文紧密围绕IODP“面向2050年大洋钻探科学框架”中的“地球深部探测”旗舰计划和“莫霍面”梦想，研究并总结全球现代洋壳发现的大洋斜长花岗岩的分布规律、岩石组合特征和成因模式，探讨发育大洋斜长花岗岩的南海管事平顶海山是否为深部地壳和莫霍面钻探潜在优选区。统计结果表明大洋斜长花岗岩在多种不同构造背景形成的洋壳上均有发现，包括西南印度洋超慢速扩张构造环境，大西洋、西北太平洋、西印度洋和中印度洋慢速扩张构造环境，东太平洋快速扩张构造环境，南海等边缘海构造环境，伊豆- 小笠原- 马里亚纳(IBM)岛弧、九州- 帕劳海脊、Amami海底高原等洋内俯冲构造环境。多数大洋斜长花岗岩呈脉状零散分布于辉长岩中，意味大洋斜长花岗岩可能形成于洋壳深部，在后期断裂等地质作用下被剥蚀而更容易被发现，成为了解洋壳深部岩浆过程和洋壳结构的一个窗口。管事平顶海山位于南海东部次海盆古扩张脊附近，拖网获得MORB型大洋斜长花岗岩，前人基于地球化学数据认为其可能为辉长岩部分熔融形成。本文推测管事平顶海山大洋斜长花岗岩很可能为洋壳深部物质剥露海底，是南海的一个重要构造窗口，有望成为南海深部地壳和莫霍面钻探的潜在优选区，但需要开展进一步调查研究以验证推测：① 海山大洋斜长花岗岩为拖网所得，位置误差较大，需开展可精确定位的电视抓斗、浅钻或有缆遥控水下机器人(ROV)调查；② 海山目前只发现大洋斜长花岗岩，需调查海山是否发育辉长岩等深部地壳岩石组合；③ 需开展重磁、深反射地震、海底地震仪(OBS)、大地电磁等调查研究，建立管事平顶海山洋壳和上地幔结构模型，查明断裂带分布，揭示莫霍面深度。     

石榴子石捕掳晶揭示洋中脊地幔的再富集过程

正大洋中脊的减压熔融是产生洋壳和大洋岩石圈地幔的场所。一般而言,洋脊处玄武岩熔体并不是被完全抽离的,残留在洋脊轴部的熔体会交代周边的大洋岩石圈地幔,使其具有较为富集的微量元素分配特征。然而,类似的富集过程在远离洋中脊轴部(offaxis)的区域是否会发生还不清楚。针对这个问题,最近瑞士洛桑大     

洋岛-海山研究进展及其对于重建洋板块的意义

在中国区域大地构造研究中,对洋岛-海山/洋底高原的识别尚未引起足够重视.为深入研究中国大陆洋板块构造,系统回顾了洋岛-海山/洋底高原的基本概念、基本特征和增生造山过程.洋岛-海山/洋底高原是在海底扩张、大洋壳演化过程中由于地幔热点/柱作用形成的有异常厚度洋壳的区域,是大洋岩石圈的重要组成部分.洋岛-海山/洋底高原在垂向上具有典型的二元结构,下部以镁铁质、超镁铁质岩石为主,上部以碳酸盐岩建造为主.现今大洋盆地中大面积分布着正在演化中和正在俯冲的洋岛-海山,根据比较大地构造学原理,古洋岛-海山的存在指示古大洋盆地的存在,是研究造山带的重要载体.认为地史时期大洋盆地中有相当数量的洋岛、海山,在俯冲增生碰撞造山过程中保留下来的古洋岛-海山残块以构造岩片（块）形式夹持在俯冲增生杂岩中,随大洋盆地关闭;其作为缝合带的重要组成部分,是识别对接带的重要判别依据之一.      

大陆增生:从大洋高原到异地陆块

在现代大洋里,某些异常高的海底地形区.可能是与大洋板块一起运动的近代异地陆块。由于碰撞和增生于相邻大陆之上,它们可能发生复杂的火山活动.切碎并捕获洋壳,并且可能引起造山运动变形。在大洋板块俯冲期间,海底高原的增生可以导致与大陆碰撞作用相似的造山运动。     

洋壳的基本问题与人类的莫霍钻梦想

一般认为,地球物理上的莫霍面是地幔和地壳的分界面。被海水覆盖的洋壳通常只有6~7km厚,相对于较厚的陆壳来说,洋壳不仅年轻得多,也活跃得多。然而,洋壳的地质结构以及莫霍面的地质意义到底是什么,至今仍是固体地球科学领域最大的悬疑之一。现有的结果表明,依据分布在大陆边缘的蛇绿岩套确定的Penrose模型基本不适用于慢速和超慢速扩张洋中脊的实际洋壳结构,对快速扩张洋中脊的适用性也有一定的疑问。解答洋壳结构及其莫霍面地质意义最有效的手段仍是大洋钻探。20世纪60年代初,试图挺进莫霍面的"莫霍钻"计划揭开了地球科学最伟大的大洋钻探计划的序幕。新世纪以来,随着各种研讨和计划的切实开展,人类真正实现莫霍钻梦想的日子似乎正在来临。     

西藏班公湖-怒江缝合带中段塔仁本洋岛型玄武岩的发现及地质意义

塔仁本洋岛型玄武岩是中特提斯洋古洋壳的重要组成部分,是班公湖怒江缝合带内构造混杂岩中局部有序部分的特殊洋壳残片。它以具有海底爆发相与远洋放射虫硅质岩相整合和大洋板内碱性玄武岩的构造环境为主要特征。它的发现丰富了班怒带的研究内容,证明当时中特提斯洋曾经有发育完好的古洋壳存在     

Mass transfer during sub-seafloor alteration of the upper Troodos crust (Cyprus)

Five major alteration zones in the Extrusive Series and the Sheeted Dike Complex of the Troodos Ophiolite are each characterized by (a) distinct elemental changes compared to the original composition and (b) secondary mineralogy. The upper ca. 300 m of the extrusive crust, the highly oxidatedcold seawater alteration zone (CSA), is strongly enriched in K₂O and depleted in Na₂O. It is followed downwards by alow temperature alteration zone (<170° C) which is most widespread in the Troodos extrusives and where Na₂O and K₂O are enriched, the latter less strongly than in the CSA zone. Three types ofhigh temperature alteration zones (<440° C; HTA I–III) are found in the Sheeted Dike Complex. All are marked by thorough leaching of K₂O, while the behavior of Na₂O (e.g. unchanged in type III) and CaO (depleted in type I, enriched in types II, III) is variable. Mass budgets of elemental changes are quantified by calibration of whole rock analyses via systematic stable element variations of fresh glasses found throughout the extrusive section. The Troodos extrusive crust and upper Sheeted Dike Complex are a major sink for MgO, K₂O, and Na₂O, and a source for CaO; the overall scale of fluxes drastically exceeds estimates based on fresh basalt compositions from present ocean crust.     

四川省理塘县日乃金矿床地质特征及控矿因素

四川省日乃金矿位于甘孜—理塘蛇绿混杂岩带的南段,区内中生代构造-岩浆活动强烈,发育上、下两套蛇绿岩,日乃金矿即赋存于上部的瓦能蛇绿岩组中,矿化带主要发育在区域性断裂次级的F6和F7之间的断裂破碎带中,矿化范围具有中-低温热液蚀变,形成3条金矿化带,矿体为脉状,长520~1120 m,宽5.18~6.97 m;矿体倾向NW,倾角40°~75°;矿石品位w（Au）=1.89×10^-6~3.77×10^-6;矿石的主要含金矿物为黄铁矿和毒砂。根据金矿地质特征和主要控矿因素提出矿床的成因类型为与燕山晚期构造-岩浆活动有关的热液交代充填型金矿床,同时归纳了日乃金矿床的控矿因素。     

宜昌地区砾石层的磁性特征与物源分析

分布于宜昌-宜都-鸦鹊岭-枝江一带的宜昌砾石层,是江汉平原边缘丘陵区厚度最大的第四纪沉积物,对地层划分、环境演化及长江形成等研究具有十分重要意义。通过对代表该砾石层完整沉积序列的善溪窑剖面（上段）、云池剖面（中段）与李家院剖面（下段）的磁学特征分析发现,从云池剖面距底部9m处向上,磁化率和磁化参数F_300mT等均明显高于其下部分,具体为：  1）下部磁化率平均值为28×10^-8 m³/kg,而上部磁化率平均达到17010^-8 m³/kg;   2）云池剖面距底部9m处以上主导砾石层剖面磁性特征的物质以低矫顽力的亚磁铁性矿物为主,而以下却含有更多的高矫顽力磁性矿物(如赤铁矿);   3）善溪窑和云池砾石层的亚磁性物质颗粒要粗于李家院样品。初步分析认为,上述磁性差异主要是物源变化引起的,距云池剖面底部9m以下的砾石层物源主要为鄂西山地,从云池剖面9m开始有四川以西的物质进入江汉平原,表明此时三峡已经贯通。根据已有的测年资料,推测长江贯通三峡的时间大约为1.0～1.1MaB.P.。     

O18 enriched ophiolitic metabasic rocks from E. Liguria (Italy), Pindos (Greece), and Troodos (Cyprus)

Low grade hydrothermally metamorphosed ophiolitic basic rocks from E. Liguria (Italy), Pindos (Greece) and Troodos (Cyprus) are enriched in O¹⁸ relative to the oxygen isotope ratio of fresh basalt (6.0±0.5‰). The maximum observed δO¹⁸ value of +13.22‰ corresponds to a positive isotope shift of 7‰ Enrichments in Sr⁸⁷ relative to Sr⁸⁶ correlate with hydrothermal alteration. The δC¹³ values of secondary calcite from E. Liguria are positive, and fall in the range from +0.2% to +3.6‰ Since ophiolitic rocks are considered to be fragments of the oceanic crust and upper mantle, and since the secondary metamorphic assemblages were produced before mechanical emplacement, it is considered that the hydrothermal metamorphism which affected these rocks occurred in the sub-sea-floor environment. The isotope data are directly consistent with the hypothesis that the alteration was produced by interaction of the basaltic material with introduced sea water. Water: rock ratios were sufficiently large to produce the observed isotope shifts. In the Troodos ophiolite sequence δO¹⁸ values decrease steadily downwards and change to progressively larger depletions in the Sheeted Intrusive Complex. The trend of δO¹⁸ decrease correlates with the original direction of increasing temperature. The O¹⁸ depletions, which have also been observed for oceanic “greenstones” (Muehlenbachs and Clayton, 1972b), resulted from water/rock interaction at temperatures greater than the particular temperature range above which whole rock-water fractionations became less than the isotopic difference between fresh basalt and sea water. Since this isotope geochemistry indicates that the water responsible for hydrothermal metamorphism was of sea water origin, the data support the more general hypothesis that convection of sea water within the upper 4–5 kms of the oceanic crust is a massive and active process at oceanic ridges. This process may be completely or partially responsible for (a.i.), the local scatter and low mean value of the conductive heat flux measured near ridges, (a.ii), the transfer of considerable quantities of heat from spreading oceanic ridges, (b) hydrothermal metamorphism, metasomatism and mineralization of oceanic crust, (c), the production of metal enriched, relatively reduced brines during sea water/basalt interaction, d), the high degree of scatter and low mean value of the compressional wave velocities of oceanic basement layer 2 and (e), the low natural remanent magnetization (NRM) intensity of the lower part of layer 2 and upper part of layer 3 of oceanic crust.     

Prograde Metamorphism of the Horokanai Ophiolite in the Kamuikotan Zone, Hokkaido, Japan

The Horokanai ophiolite is a segment of metamorphosed oceaniccrust and upper mantle, tectonically replaced into the KamuikotanZone of Hokkaido, Japan. Metamorphic grade, ranging from thezeolite faciles (Zone A) through the greenschist facile (ZoneB) and the greenschist-amphibolite transitional facile (ZoneC), to the amphibolitic and granulizes facile (Zone D) increasesprogressively downwards with zone boundaries subparallel tothe ophiolite pseudostraitigraphy. The granulite facile rocksinclude both metagabbros and their underlying ultranafic rocks.Coexisting minerals from several tens of samples covering allthe minerals zones were analysed by means of an electronprodemicroanalyser; the results are presented, along with brief considerationof their compositional variation with metamorphic grade. Thefaciles series of metamorphism of the Horokanai ophiolite correspondsto the low-pressure type with a temperature range of 100-750?C, which is broadly comparable to that inferred for ocean-floormetamorphism. The major difference is the presence of the granulitefacile rocks in the Horokanai ophiolite and its absence in ocean-floormetamorphism.     

Progressive metamorphism of the Taitao ophiolite; evidence for axial and off-axis hydrothermal alterations

We estimated metamorphic conditions for the  6 Ma Taitao ophiolite, associated with the Chile triple junction. The metamorphic grade of the ophiolite, estimated from secondary matrix minerals, changes stratigraphically downwards from the zeolite facies, through the prehnite–actinolite facies, greenschist facies and the greenschist–amphibolite transition, to the amphibolite facies. The metamorphic facies series corresponds to the low-pressure type. The metamorphic zone boundaries are subparallel to the internal lithological boundaries of the ophiolite, indicating that the metamorphism was due to axial hydrothermal alteration at a mid-ocean ridge.

Mineral assemblages and the compositions of veins systematically change from quartz-dominated, through epidote-dominated, to prehnite-dominated with increasing depth. Temperatures estimated from the vein assemblages range from  230 °C in the volcanic unit to  380 °C at the bottom of the gabbro unit, systematically  200 °C lower than estimates from the adjoining matrix minerals. The late development of veins and the systematically lower temperatures suggest that the vein-forming alteration was due to off-axis hydrothermal alteration.

Comparison between the Taitao ophiolite with its mid-ocean ridge (MOR) affinity, and other ophiolites and MOR crusts, suggests that the Taitao ophiolite has many hydrothermal alteration features similar to those of MOR crusts. This is consistent with the tectonic history that the Taitao ophiolite was formed at the South Chile ridge system near the South American continent (Anma, R., Armstrong, R., Danhara, T., Orihashi, Y. and Iwano, H., 2006. Zircon sensitive high mass-resolution ion microprobe U–Pb and fission-track ages for gabbros and sheeted dykes of the Taitao ophiolite, Southern Chile, and their tectonic implications. The Island Arc, 15(1): 130–142).     

Tectonics of the Akamas and Mamonia ophiolites, Western Cyprus: magnetic petrofabrics and paleomagnetism

The Akamas ophiolite is shown to be a distal, off-axis extension of the main outcrop of Cretaceous ophiolite in the Troodos complex of Cyprus. Mantle-sequence harzburgites of both ophiolites share similarly oriented mantle-flow fabrics and the same Tertiary magnetizations acquired during exhumation. However, compared with the Troodos mantle sequence rocks, the Akamas ferromagnetic mineralogy is more oxidized and remanences with lower blocking temperatures were acquired chemically. Paleopoles calculated from published vectors and our own new data define an apparent polar wander path (APWP) for the Troodos microplate. The APWP shows that between 88 and 50 Ma the Troodos microplate was equatorial and the vertical axis for its 60° anticlockwise rotation was located within the microplate. Subsequently, the microplate drifted northward to 34°N with minor anticlockwise rotation at a reduced rate. That requires microplate-rotation about a vertical axis located to the west of Cyprus in the last 50 Ma. The allochthonous Triassic Mamonia terrane docked with the Cretaceous Troodos terrane in SW Cyprus. Within it, disrupted tectonized ophiolite has been regarded as part of a Triassic ocean floor or as sheared fragments of Cretaceous Troodos ophiolite, incorporated into the Mamonia terrane when it docked with the Troodos terrane. Whatever their provenance, their paleomagnetic signals postdate their penetrative deformation and metamorphism and their paleopoles may still be used to track their post-strain motion. Our calculations of paleopoles from published vectors for the Mamonia terrane smear along an extension of the APWP for the Troodos microplate that is, moreover, concentric with the Troodos microplate. This suggests that the paleopole dispersion of the Triassic Mamonia rocks and their post-magnetization disruption occurred during their accretion onto the anticlockwise-spinning Troodos microplate.     

甘肃景泰县老虎山地区蛇绿岩及其上覆岩系中枕状熔岩的地球化学特征

甘肃景泰县老虎山地区蛇绿岩之上覆盖着一套镁铁质的喷出岩和沉积岩组合，位于蛇绿岩的枕状熔岩之上，不是蛇绿岩的成员，为蛇绿岩的上覆岩系。蛇绿岩的枕状熔岩具Ｎ－ＭＯＲＢ的特征，而其上覆岩系中的枕状熔岩类似Ｅ－ＭＯＲＢ。前者来自扩张脊的下部岩浆房；后者推测源于扩张脊之外的岩浆房，也是软流圈地幔中等至高程度部分熔融的产物，不过，可能有少量来自下地幔的物质的加入     

Clay minerals in sediments of the hydrothermally active southern trough in the Guaymas Basin (Gulf of California)

The results of the study of clay mineral alterations in Upper Pleistocene sediments of the southern trough in the Guaymas Basin (Gulf of California) due to the influence of hydrothermal solutions and heat produced by sill intrusions are discussed. Core samples from DSDP Holes 477 and 477A were taken for the analysis of clay minerals. Application of the method of modeling X-ray diffraction patterns of oriented specimens of the finely dispersed particles made it possible to establish the phase composition of clay minerals, determine their structural parameters, and obtain reliable quantitative estimates of their contents in natural mixtures. The modeling data allowed us to characterize reliably the transformation of clay minerals in sediments of the hydrothermally active southern trough in the Guaymas Basin. In Upper Pleistocene sandy–clayey sediments of the southern trough, changes in the composition of clay minerals occurred under the influence of a long-living hydrothermal system. Its lower part (interval 170.0–257.5 m) with maximum temperatures (~300°C) was marked by the formation of chlorite. Terrigenous clay minerals are not preserved here. Saponite appears at a depth of 248 m in the chlorite formation zone. Higher in the sedimentary section, the interval 146–170 m is also barren of terrigenous clay minerals. Sediments of this interval yielded two newly formed clay minerals (chlorite and illite), which were formed at lower temperatures (above 180°C and below 300°C, approximately up to ~250°C), while the relatively low-temperature upper part (110–146 m) of the hydrothermal system (from ~140°C to ~180°C) includes the mixture of terrigenous and newly formed clay minerals. Terrigenous illite is preserved here. Illitization of the mixed-layer illite–smectite was subjected to illitization. The terrigenous montmorillonite disappeared, and chlorite–smectite with 5–10% of smectite layers were formed. In the upper interval (down to approximately 110 mbsf), the composition of terrigenous clay minerals remains unchanged. They are composed of the predominant mixed-layer illite–smectite and montmorillonite, the subordinate illite, mixed-layer chlorite–smectite with 5% of smectite layers, mixed-layer kaolinite–smectite with 30% of smectite layers, and kaolinite. This composition of clay minerals changed under the influence of sill intrusions into the sedimentary cover at 58–105 m in the section of Hole 477. The most significant changes are noted in the 8-m-thick member above the sill at 50–58 m. The upper part of this interval is barren of the terrigenous mixed-layer illite–smectite, which is replaced by the newly formed trioctahedral smectite (saponite). At the same time, the terrigenous dioctahedral smectite (montmorillonite) is preserved. The composition of terrigenous clay minerals remains unchanged at the top of the unit underlying the sill base.     

西藏东坡蛇绿岩体深部结构的地球物理特征及其找矿意义

在西藏西部雅鲁藏布江南岸的东坡岩体进行了多种方法的地球物理探测,由地面磁测精确定位的航空磁测异常反演了东坡岩体深部磁性体范围;反射地震探测划分出了与地表出露蛇绿岩体反射波特征不同的岩体下部弱反射部位;同时,由大地电磁法确定了岩体下部的低阻体也都处于大致相同的部位。地面出露的蛇绿岩体向下延伸,整体呈锅底状,其中部具有较低电阻和弱反射波特征,同时,在1.5~3.0 km范围的磁性矿物相对较发育,可能正是含铬岩体矿化蚀变作用较强的地段,在罗布莎矿区有类似的特征,这对找矿是有利的部位。