Study of variation of aerosol optical properties over a high altitude station in Indian Western Himalayan region,palampur using raman lidar system

A Raman lidar system was operated along with the Microtops sunphotometer measurements to carry out the study of the variation of the optical properties of aerosols over Palampur (32.11° N and 76.53° E), India from 17th April to 11th May 2019. The lidar system is furnished with Raman (N₂) channel and depolarization channel allowing independent measurement of Lidar Ratio (LR) and linear depolarization ratio. The study reveals that the majority of the aerosols approximately were restricted within the planetary boundary layer (PBL) and very less loading was present in the free troposphere over the study location. The particle loading over the study period was found to be very less with aerosol backscatter coefficient (at 355 nm) ranging from ～0.13 Mm^?1sr^?1 to ～7.25 Mm^?1sr^?1 with mean value of 2.67?±?0.82 Mm^?1sr^?1 and it is well supplemented by the mean aerosol optical depth (AOD) of 0.37?±?0.13 obtained from Microtops Sunphotometer. The average lidar ratio values for 0-1 km altitude (L1) 72?±?13sr, for 1-2 km (L2) altitude 55?±?8sr, for 2-3 km (L3) 54?±?15sr were observed as suggesting dominance of the biomass burning aerosols and anthropogenic aerosols. The particle depolarization ratio (355 nm) values were found from approximately 4.8?±?2.7% to 11.5?±?1.9% with the mean value of 7?±?1.3% suggesting the presence of non-spherical particles. To trace the sources of the pollution, we derived the HYSPLIT trajectory which shows the majority of the movement was from local sources.

     

Improved estimation of average warming trend of China from 1951–2010 based on satellite observed land-use data

This paper provides new evidence of regional warming trends from local Chinese observations covering the period 1951–2010. We used satellite-derived land data and weighted urban and rural temperature records (a weighted method) and estimate the regional warming trend, which involves natural climate change and human impact. The annual warming rate over the whole of China is 0.21?±?0.02 °C/decade. The seasonal warming is 0.30?±?0.05 °C/decade (Winter), 0.24 °C?±?0.03 °C/decade (Spring); 0.16?±?0.02 °C/decade (Summer) and 0.21?±?0.03 °C/decade (Autumn). The mean warming trend is lower than previous estimates (e.g. NMIC, CRU-China) using un-weighted methods (arithmetic average of all records). The warming difference between the weighted and un-weighted accounts for 27 % (12 %) of the NMIC (CRU-China) un-weighted estimate on the total warming. This indicates that previous estimations overestimated a regional warming trend. The differences can be partly attributed to the weighting of the urban effect which is taken into consideration in this study, resulting in a much slower temperature increase. Spatially, the northern part of China shows a larger difference than the south especially for winter and spring. We argue that it is of importance to take into consideration the influence of urban land-use change to improve the physical understanding of surface warming in China over past decades.     

Assessment of global warming on the island of Tenerife, Canary Islands (Spain). Trends in minimum, maximum and mean temperatures since 1944

Temperature variation is studied at different altitudes and orientation on the island of Tenerife, according to the trends in the mean, maximum and minimum at 21 meteorological stations. Reference series are obtained by sectors, along with a representative overall series for Tenerife, in which temperature shows a statistically significant growth trend of 0.09?±?0.04°C/decade since 1944. Night-time temperatures have risen most (0.17°C?±?0.04°C/decade), while by day they have been more stable. Consequently, the diurnal temperature range between day and night has narrowed. By regions, warming has been much more intense in the high mountains than the other sectors below the inversion layer between 600 and 1,400?m altitude, and progressively milder towards the coast. The temperature rise on the windward (north-northeast) slopes is greater than on the leeward side and could be related to the increase in cloudiness on the northern side. The general warming of the island is less than in continental areas at between 24 and 44oN, being closer to the sea surface temperature in the same area. This is probably explained largely by the insular conditions. In fact warming is more evident in the high mountains (0.14?±?0.07°C/decade), where the tempering effect of the ocean and the impact of changes in the stratocumulus is weaker, being similar to the mean continental values in the northern hemisphere.     

Trends and variability of cloud fraction cover in the Arctic, 1982–2009

Climatology, trends and variability of cloud fraction cover (CFC) data over the Arctic (north of 70°N), were analysed over the 1982–2009 period. Data, available from the Climate Monitoring Satellite Application Facility (CM SAF), are derived from satellite measurements by AVHRR. Climatological means confirm permanent high CFC values over the Atlantic sector during all the year and during summer over the eastern Arctic Ocean. Lower values are found in the rest of the analysed area especially over Greenland and the Canadian Archipelago, nearly continuously during all the months. These results are confirmed by CFC trends and variability. Statistically significant trends were found during all the months over the Greenland Sea, particularly during the winter season (negative, less than ?5?%?dec ^?1) and over the Beaufort Sea in spring (positive, more than +5?%?dec ^?1). CFC variability, investigated by the Empirical Orthogonal Functions, shows a substantial “non-variability” in the Northern Atlantic Ocean. Statistically significant correlations between CFC principal components elements and both the Pacific Decadal Oscillation index and Pacific North America patterns are found.     

Measurements of stratospheric ozone at a mid-latitude observing station Valentia, Ireland (51.94° N, 10.25° W), using ground-based and ozonesonde observations from 1994 to 2009

Sixteen years (1994 – 2009) of ozone profiling by ozonesondes at Valentia Meteorological and Geophysical Observatory, Ireland (51.94^° N, 10.23^° W) along with a co-located MkIV Brewer spectrophotometer for the period 1993–2009 are analyzed. Simple and multiple linear regression methods are used to infer the recent trend, if any, in stratospheric column ozone over the station. The decadal trend from 1994 to 2010 is also calculated from the monthly mean data of Brewer and column ozone data derived from satellite observations. Both of these show a 1.5 % increase per decade during this period with an uncertainty of about ±0.25 %. Monthly mean data for March show a much stronger trend of?~?4.8 % increase per decade for both ozonesonde and Brewer data. The ozone profile is divided between three vertical slots of 0–15 km, 15–26 km, and 26 km to the top of the atmosphere and a 11-year running average is calculated. Ozone values for the month of March only are observed to increase at each level with a maximum change of +9.2?±?3.2 % per decade (between years 1994 and 2009) being observed in the vertical region from 15 to 26 km. In the tropospheric region from 0 to 15 km, the trend is positive but with a poor statistical significance. However, for the top level of above 26 km the trend is significantly positive at about 4 % per decade. The March integrated ozonesonde column ozone during this period is found to increase at a rate of ~6.6 % per decade compared with the Brewer and satellite positive trends of ~5 % per decade.     

The assessment of aerosol optical properties over Mohal in the northwestern Indian Himalayas using satellite and ground-based measurements and an influence of aerosol transport on aerosol radiative forcing

The present study deals with the aerosol optical properties which are assessed during the period 2007 to 2009 over Mohal (31.9oN, 77.12oE) in the northwestern Indian Himalaya, using ground-based measurements and multi-satellite data. The daily average value of aerosol optical depth (AOD) at 500?nm, ?ngstr?m exponent and turbidity coefficient are 0.24?±?0.08, 1.02?±?0.34 and 0.13?±?0.05, respectively. The comparative study of satellite and ground-based measurements reveals that the percentage retrieval for daily AOD at 550?nm over Mohal within the expected accuracy (???? _p?? ?=?±0.05?±?0.15?? _p?? ) is around 87%, with a significant correlation coefficient of 0.76. The present study suggests that the retrieval of AOD through satellite data is able to characterise the distribution of AOD over Mohal. However, further efforts are needed in order to eliminate systematic errors in the existing Moderate Resolution Imaging Spectroradiometer (MODIS) algorithm. The transport of desert dust and anthropogenic aerosol during high aerosol loading days caused a significant reduction in surface-reaching solar radiation by 149 and 117%, respectively. This large reduction in surface-reaching solar radiation increased the atmospheric heating rate by 0.93 and 0.72?K?day^?1, respectively. This study indicates significant climatic implications due to the transport of aerosols in the northwestern Indian Himalaya.     

Spectral radiance and sky luminance in Antarctica: a case study

Summary Sky luminance and spectral radiance has been characterised at Neumayer, Antarctica for selected situations during the austral summer 2003/04. Luminance has also been measured at Boulder, Colorado, USA in June 2003. The high reflectivity of the surface (albedo) in Antarctica, reaching values up to 100% in the ultraviolet (UV) and visible part of the solar spectrum due to snow cover, modifies the radiation field considerably when compared to mid-latitudes. A dependence of luminance and spectral radiance on solar zenith angle (SZA) and surface albedo has been identified. For snow and cloudless sky, the horizon luminance exceeds the zenith luminance by as much as a factor of 8.2 and 7.6 for a SZA of 86° and 48°, respectively. In contrast, over grass this factor amounts to 4.9 for a SZA of 86° and a factor of only 1.4 for a SZA of 48°. Thus, a snow surface with high albedo can enhance horizon brightening compared to grass by a factor of 1.7 for low sun at a SZA of 86° and by a factor of 5 for high sun at a SZA of 48°. For cloudy cases, zenith luminance and radiance exceed the cloudless value by a factor of 10 due to multiple scattering between the cloud base and high albedo surface. Measurements of spectral radiance show increased horizon brightening for increasing wavelengths and generally confirm the findings for luminance. Good agreement with model results is found for some cases; however there are also large deviations between measured and modelled values especially in the infrared. These deviations can only partly be explained by measurement uncertainties; to completely resolve the differences between model and measurement further studies need to be performed, which will require an improvement of modelling the spectral radiance. From the present study it can be concluded that a change in albedo conditions, which is predicted as a consequence of climate change, will significantly change the radiation conditions in polar regions as well.     

Study of Ozone and NO2 over Gadanki – a rural site in South India

We have studied long-term changes in tropospheric NO₂ over South India using ground-based observations, and GOME and OMI satellite data. We have found that unlike urban regions, the region between Eastern and Western Ghat mountain ranges experiences statistically significant decreasing trend. There are few ground-based observatories to verify satellite based trends for rural regions. However, using a past study and recent measurements we show a statistically significant decrease in NO_X and O₃ mixing ratio over a rural location (Gadanki; 13.48° N, 79.18° E) in South India. In the ground-based records of surface NO_X, the concentration during 2010–11 is found to be lower by 0.9 ppbv which is nearly 60 % of the values observed during 1994–95. Small but statistically significant decrease in noon-time peak ozone concentration is also observed. Noon-time peak ozone concentration has decreased from 34?±?13 ppbv during 1993–96 to 30?±?15 ppbv during 2010–11. NO_X mixing ratios are very low over Gadanki. In spite of low NO_X values (0.5 to 2 ppbv during 2010–11), ozone mixing ratios are not significantly low compared to many cities with high NO_X. The monthly mean ozone mixing ratio varies from 9 ppbv to 37 ppbv with high values during Spring and low values during late Summer. Using a box-model, we show that presence of VOCs is also very important in addition to NO_X in determining ozone levels in rural environment and to explain its seasonal cycle.     

Decadal Trends in Oxygen Concentration in Subsurface Waters of the Northeast Pacific Ocean

Previous studies have shown decreasing oxygen concentration (O₂) in subsurface waters of the continental slope from California to Canada since about 1980. With longer time series we show that from southern California to northern Canada increasing O₂ preceded these decreases from 1950 to about 1980. Because there has been no clear trend since 1950, we cannot yet conclude that anthropogenic climate change is the cause of these decreasing trends after 1980. These findings are based mainly on O₂ on the 26.7 potential density (σ_θ) surface in the region north of 30°N and east of 170°W, covering both the continental margin and deep-sea regions. On the continental slope, O₂ increased at most locations by 10 to 20?µmol?kg^?1 to about 1980, followed by declines of similar magnitude in recent years. Changes in O₂ were associated with changes in temperature of the opposite sign south of 37°N, but correlation of temperature and O₂ is irregular in more northerly locations. At all locations, temperature-related solubility change was a minor cause of these O₂ trends. In deep-sea waters, O₂ decreased with time with a more rapid decrease from about 1995 to about 2003. At Ocean Station P (OSP; 50°N, 145°W), which has the longest uninterrupted record of observations, significant linear trends of ?0.4 to ?0.5?µmol?kg^?1?y^?1 were found on the 26.5, 26.7, and 26.9 σ_θ surfaces. In addition, a significant sinusoidal oscillation of period 18.61 years and amplitude of 18?µmol?kg^?1 was found on the 26.9 σ_θ surface at OSP and a station 400?km to the east, which fits reasonably well with the lunar nodal cycle. The phase of this oscillation was identical at both locations. Clear evidence of similar variability did not emerge at other open-ocean locations or along the continental slope.     

Balloon-borne observations of mid-latitude stratospheric water vapour: comparisons with HALOE and MLS satellite data

We present here in situ measurements obtained between 1991 and 2011 in outer-vortex conditions by the ELHYSA balloon-borne frost-point hygrometer. The frost-point hygrometer profiles are used for comparisons with the satellite data from version 19 (v19) and version 3.3 (v3.3) of the HALogen Occultation Experiment (HALOE) and the Microwave Limb Sounder (MLS) respectively. Potential Vorticity mapping is applied to all data sets to remove contributions of transient tropical intrusions and polar vortex air masses and hence ensure consistent comparisons between the balloon and satellite observations. Our selected balloon in situ observations are too sparse to directly infer mid-latitude stratospheric time series for continuous comparisons with HALOE and MLS records or derive water vapour trends but can be used to validate the satellite data. A mean difference of ?0.83?±?1.58 % (?0.04?±?0.07 ppmv) is obtained between HALOE v19 data and the balloon frost-point observations (with respect to HALOE) over the 30–80 hPa altitude range. The hygrometer-HALOE differences appear time-dependent as already presented in the literature. The mean difference reaches 2.80?±?0.96 % (0.13?±?0.04 ppmv) for MLS v3.3, with MLS systematically wetter than the balloon data reflecting a systematic bias between both datasets. We use our balloon data as reference to provide some information about the HALOE-MLS difference. From post-2000 ELHYSA-HALOE and ELHYSA-MLS comparisons, we find a HALOE-MLS difference matching the expected bias, with MLS v3.3 6.60?±?2.80 % (0.27?±?0.11 ppmv) wetter than HALOE v19. From the results obtained from our balloon-satellite data comparisons, we finally discuss the issue about merging the HALOE and MLS data sets to provide stratospheric water vapour trends.     

The retention of ammonia and sulfur dioxide during riming of ice particles and dendritic snow flakes: laboratory experiments in the Mainz vertical wind tunnel

Laboratory experiments were carried out in the Mainz vertical wind tunnel to determine the retention of the trace gases ammonia and sulfur dioxide dissolved in supercooled cloud droplets during riming. The conditions during riming were similar to the ones in atmospheric mixed phase clouds: temperatures from ?18 °C to ?5 °C, liquid water contents between 1 and 1.5 g m^?3, liquid drop radii between 10 and 20 μm, liquid phase concentrations from 1 to 22 mg/l. As collectors, floating ice particles and snow flakes with diameters between 6 mm and 1.5 cm were used. After riming the retention coefficients, i.e. the fractions of the species which remained in the ice phase after freezing were determined. Retention coefficients lying between 0.1 and 1.0 were measured depending on the solubility and dissociation of the trace gas, liquid phase concentration, ambient air temperature, and shape of rimed collector. This can be explained from the chemists’ point of view by the effective Henry’s law constant of the species and physically with the rate of latent heat removal from the rimed collector during freezing. Parameterizations derived from the different experimental cases describe the retention coefficients as a function of temperature. In general, an average retention of ammonia of 92?±?21 % was determined independently of liquid phase concentration while mean values for sulfur dioxide were 53?±?10 % at low liquid phase concentrations and 29?±?7 % at high liquid phase concentrations.     

Variations in surface ozone and NOx at Kannur: a tropical, coastal site in India

Continuous measurements of surface ozone (O₃), NOx (NO + NO₂) and meteorological parameters have been made in Kannur (11.9?°N, 75.4?°E, 5?m asl), India from November 2009 to October 2010. It was observed that O₃ and NOx showed distinct diurnal and seasonal variabilities at this site. The annual average diurnal profile of O₃ showed a peak of (30.3?±?10.4) ppbv in the late afternoon and a minimum of (3.2?±?0.7) ppbv in the early morning. The maximum value of O₃ mixing ratio was observed in winter (44?±?3.1) ppbv and minimum during monsoon (18.46?±?3.5) ppbv. The rate of production of O₃ was found to be higher in December (10.1?ppbv/h) and lower in July (1.8?ppbv/h) during the time interval 0800?C1000?h. A correlation coefficient of 0.52 for the relationship between O₃ and [NO₂]/[NO] reveals the role of NO₂ photolysis that generates O₃ at this site. The correlation between O₃ and meteorological parameters indicate the influence of seasonal changes on O₃ production. Investigations were further extended to explore the week day weekend variations in O₃ mixing ratio at an urban site reveals the enhancement of O₃. The variations of O₃ mixing ratio with seasonal air mass flows were elucidated with the aid of backward air trajectories. This study also indicates how vapor phase organic species present in the ambient air at this location may influence the complex chemistry involving (VOCs) that enhances the production of O₃ at this location.     

Trends and variability in column-integrated atmospheric water vapor

An analysis and evaluation has been performed of global datasets on column-integrated water vapor (precipitable water). For years before 1996, the Ross and Elliott radiosonde dataset is used for validation of European Centre for Medium-range Weather Forecasts (ECMWF) reanalyses ERA-40. Only the special sensor microwave imager (SSM/I) dataset from remote sensing systems (RSS) has credible means, variability and trends for the oceans, but it is available only for the post-1988 period. Major problems are found in the means, variability and trends from 1988 to 2001 for both reanalyses from National Centers for Environmental Prediction (NCEP) and the ERA-40 reanalysis over the oceans, and for the NASA water vapor project (NVAP) dataset more generally. NCEP and ERA-40 values are reasonable over land where constrained by radiosondes. Accordingly, users of these data should take great care in accepting results as real. The problems highlight the need for reprocessing of data, as has been done by RSS, and reanalyses that adequately take account of the changing observing system. Precipitable water variability for 1988–2001 is dominated by the evolution of ENSO and especially the structures that occurred during and following the 1997–98 El Niño event. The evidence from SSM/I for the global ocean suggests that recent trends in precipitable water are generally positive and, for 1988 through 2003, average 0.40±0.09 mm per decade or 1.3±0.3% per decade for the ocean as a whole, where the error bars are 95% confidence intervals. Over the oceans, the precipitable water variability relates very strongly to changes in SSTs, both in terms of spatial structure of trends and temporal variability (with a regression coefficient for 30°N–30°S of 7.8% K^?1) and is consistent with the assumption of fairly constant relative humidity. In the tropics, the trends are also influenced by changes in rainfall which, in turn, are closely associated with the mean flow and convergence of moisture by the trade winds. The main region where positive trends are not very evident is over Europe, in spite of large and positive trends over the North Atlantic since 1988. A much longer time series is probably required to obtain stable patterns of trends over the oceans, although the main variability could probably be deduced from past SST and associated precipitation variations.     

Effect of data homogenization on estimate of temperature trend: a case of Huairou station in Beijing Municipality

Daily minimum temperature (Tmin) and maximum temperature (Tmax) data of Huairou station in Beijing from 1960 to 2008 are examined and adjusted for inhomogeneities by applying the data of two nearby reference stations. Urban effects on the linear trends of the original and adjusted temperature series are estimated and compared. Results show that relocations of station cause obvious discontinuities in the data series, and one of the discontinuities for Tmin are highly significant when the station was moved from downtown to suburb in 1996. The daily Tmin and Tmax data are adjusted for the inhomogeneities. The mean annual Tmin and Tmax at Huairou station drop by 1.377°C and 0.271°C respectively after homogenization. The adjustments for Tmin are larger than those for Tmax, especially in winter, and the seasonal differences of the adjustments are generally more obvious for Tmin than for Tmax. Urban effects on annual mean Tmin and Tmax trends are ?0.004°C/10 year and ?0.035°C/10 year respectively for the original data, but they increase to 0.388°C/10 year and 0.096°C/10 year respectively for the adjusted data. The increase is more significant for the annual mean Tmin series. Urban contributions to the overall trends of annual mean Tmin and Tmax reach 100% and 28.8% respectively for the adjusted data. Our analysis shows that data homogenization for the stations moved from downtowns to suburbs can lead to a significant overestimate of rising trends of surface air temperature, and this necessitates a careful evaluation and adjustment for urban biases before the data are applied in analyses of local and regional climate change.     

南极中山站太阳紫外辐射测值比较

比较分析了2017年南极中山站3种仪器测量地面太阳紫外B（UVB）波段和紫外A（UVA）波段的辐照度。以Brewer光谱仪测值为参考,国产宽波段FSUVB日射表在UVB（波段280~315 nm）的辐照度相对误差为（55±75）%,误差随大气臭氧总量的增加呈上升趋势,但在南极“臭氧洞”期间偏低。Yankee UVB宽波段日射表在UVB（波段280~320 nm）的辐照度相对误差为（-31±22）%;国产宽波段FSUVA日射表在UVA（波段315~400 nm）的辐照度相对误差为（23±5.9）%。太阳天顶角低于80°的晴天以Tropospheric Ultraviolet Visible（TUV）辐射模式计算结果为参考时,FSUVB,Yankee UVB和FSUVA辐照度的平均相对误差分别为（30±37）%,（-22±19）%和（27±6.4）%,而Brewer相对误差未超过3.5%。国产宽波段UV日射表测值偏高,反映出波长较长的杂散光对太阳辐照度测值影响明显。     

Trends, stability and stress in the Colombian Central Andes

Mountain ecosystems have been projected to experience faster rates of warming than surrounding lowlands. These changes in climatic conditions could have significant impacts on high-altitude Andean environments, affecting the quality and magnitude of their economic and environmental services. Even though long-term data in these regions are limited, it is important to identify any discernible long-term trends in local climatic conditions. Time series of several variables were analyzed to detect statistically significant long-term linear trends that occurred over recent years in a páramo ecosystem of the Colombian Central Andes. Records included cloud characteristics, sunshine, rainfall, minimum and maximum temperatures, diurnal temperature range, and relative humidity. Conditions of atmospheric stability were also explored. Total sunshine exhibited decreasing trends ranging from ?3.7 to ?8.5% per decade at altitudes around the pluviometric optimum. The strongest changes in sunshine occurred during the December-January-February season. Mean relative humidity observed at altitudes around and below this threshold showed increasing trends of +0.6 to +0.7% per decade. Annual rainfall and mean relative humidity above the optimum showed decreasing trends ranging from ?7 to ?11% per decade and from ?1.5 to ?3.6% per decade, respectively. Minimum temperatures on the coldest days and maximum temperatures on the warmest days exhibited increasing trends at all altitudes ranging from +0.1 to +0.6, and from +0.2 to +1.1°C per decade, respectively. Increases in minimum and maximum temperatures at higher altitudes were significantly greater than those observed in average at lower altitudes. The strongest changes in minimum temperatures, particularly, occurred during the December–January–February and June–July–August dry seasons. All these changes suggest that atmospheric conditions in the area are shifting from statically unstable conditions to conditionally unstable or statically stable conditions. Observed historical trends indicate that climate impacts and other human activities have stressed these unique and fragile environments.     

Analysing temporal trends in the Indian Summer Monsoon and its variability at a fine spatial resolution

Temporal trends between 1951 and 2007 in annual Indian Summer Monsoon (ISM) precipitation, frequency of severe drought years and onset date of ISM were analysed on a 0.25°?×?0.25° grid cell basis across India using APHRODITE daily gridded precipitation data. Locations which experienced temporal trends of increasing or decreasing inter-annual variation in annual ISM precipitation and onset date of ISM were detected using the non-parametric Mann-Kendall test. A new method of defining local onset of ISM from daily precipitation data was developed to enable countrywide temporal trend analysis of onset date. India was characterised by a heterogeneous spatial distribution in the magnitude of inter-annual variation and location of significant temporal trends in the examined facets of ISM precipitation. A greater extent of the country experienced significant trends (p?<?0.05) of increasing inter-annual variation rather than simple increasing or decreasing trends in annual ISM precipitation and onset date of ISM. Field significance tests showed grid cells reporting significant trends were significant (p?<?0.05) at the global or field level (except trends of increasing, i.e. later, ISM onset date). This research provides finer spatial detail regarding trends and variation in annual ISM precipitation, severe drought years and onset date of ISM complementing recent studies on trends in extreme precipitation events over India to produce a comprehensive overview of recent behaviour of ISM precipitation. These findings will benefit water managers charged with managing water resources sustainably at a fine spatial scale (the watershed or basin level).     

Spectral investigation of the diffuse-to-direct solar beam irradiances ratio (UV–VIS) in the urban Athens atmosphere

This study explores the influence of air gaseous pollutants–aerosols and solar zenith angle (SZA) on the spectral diffuse-to-direct beam E _dλ/E _bλ irradiances ratio. It does so using ground-based spectroradiometric measurements taken over the Athens atmosphere during May 1995. It was found that the spectral E _dλ/E _bλ ratio decreases rapidly with increasing wavelength and regression curves of the form E _dλ/E _bλ = aλ^?b fitted the experimental data. These curves are strongly modified by aerosols–air pollutants, aerosol optical properties, and SZA. The log–log plot of E _dλ/E _bλ versus λ reveals a significant departure from linearity, which is likely to be associated with aerosol physical properties and SZA effects. The effect of atmospheric turbidity, as expressed through the aerosol optical at 500 nm and SZA on the spectral E _dλ/E _bλ ratio, is investigated in detail for two discernible atmospheric conditions observed in the urban Athens atmosphere. The first case includes different atmospheric turbidity levels under the same SZA, while the second corresponds to different SZA values under the same turbidity levels. It was found that the correlation between E _dλ/E _bλ and spectral aerosol optical depth can be a useful tool in determining the aerosol optical properties and aerosol types composition.     

Ozone and Spectroradiometric UV Changes in the Past 20 Years over High Latitudes

Abstract

This study analyzes changes in solar ultraviolet (UV) irradiances at 305 and 325?nm at selected sites located at high latitudes of both hemispheres. Site selection was restricted to the availability of the most complete UV spectroradiometric datasets of the past twenty years (1990–2011). The results show that over northern high latitudes, between 55° and 70°N, UV irradiances at 305?nm decreased significantly by 3.9% per decade, whereas UV irradiance at 325?nm remained stable with no significant long-term change. Over southern high latitudes (55°–70°S), UV irradiances did not show any significant long-term changes at either 305 or 325?nm. Changes in solar UV irradiances are discussed in the context of long-term ozone and other atmospheric parameters affecting UV variability at ground level.     

Characterization of chemical properties of atmospheric aerosols over Anmyeon (South Korea), a super site under Global Atmosphere Watch

This paper reports aerosol chemical properties for the first time over a Korean Global Atmosphere Watch (GAW) supersite, Anmyeon (36°32′N; 126° 19′E), during 2003–2004 period. Total suspended Particulates (TSP) showed significant seasonal variation with consistent higher mass concentrations during spring season (average of up to 230?±?190 μg/m³). PM₁₀ also followed similar trend with higher concentrations during spring (average of up to 170?±?130 μg/m³) and showed reduced concentrations during summer. PM_2.5 showed a significant increase during summer (average of up to 60?±?25 μg/m³), which could be due to the influx of fine mode sea salt aerosols associated with the Changma front (summer monsoon). Chemical composition analysis showed enhanced presence of acidic fractions, majorly contributed by sulphates (SO ₄ ^2- ) and nitrates (NO ₃ ^- ) in TSP, PM₁₀ and PM_2.5 during different seasons. Enhanced presence of Calcium (Ca²⁺) was observed during sand storm days during spring. The high correlation obtained on matrix analysis between crustal ions and acidic ions suggests that the ionic compositions over the site are mainly contributed by terrestrial sources of similar origin. The neutralization factors has been estimated to find the extend of neutralization of acidicity by main basic components, and found to have higher value for Ammonium (up to 1.1) in different seasons, indicating significant neutralization of acidic components over the region by NH ₄ ⁺ . Back trajectory analysis has been performed during different seasons to constrain the possible sources of aerosol origin and the results are discussed in detail.