延边小西南岔金铜矿区早白垩世英云闪长岩的岩石成因

锆石U-Pb测年结果表明小西南岔富金铜矿床矿区内的英云闪长岩形成于(112±1)Ma。该英云闪长岩富Na2O和Al2O3,高Sr、LREE(轻稀土元素),低Y、Yb和HREE(重稀土元素)(如Sr=369~774μg/g,(La/Yb)CN=7.5~17.5),具有类似于埃达克质岩石的元素地球化学特征。在同位素组成上具中等放射成因Sr((87Sr/86Sr)i=0.7044~0.7048)、Nd(εNd(t)=+0.5~+1.7)和Hf(εHf(t)=+5.4~+8.6,ΔεHf=2.3~4.2)同位素,高放射成因Pb((206Pb/204Pb)i=18.40~18.60;(207Pb/204Pb)i=15.56~18.60;(208Pb/204Pb)i=38.22~38.36)同位素的特点。结合区域构造背景以及古太平洋板块俯冲历史,笔者倾向认为该岩体可能是玄武质岩浆底侵下地壳部分熔融形成的,而非板片熔融形成的埃达克质岩浆,岩浆源区为石榴子石角闪岩相向角闪岩相过渡的岩石。该岩体侵位的晚古生代((257±3)Ma)镁铁质围岩的角闪石Ar-Ar坪年龄为(110.1±1.5)Ma,与英云闪长岩的侵位时间一致,暗示晚古生代镁铁质侵入岩经历的热液事件与英云闪长岩的侵位作用存在成因联系,区域金铜矿化可能为早白垩世岩浆热液作用下成矿物质富集而形成。     

西藏冈底斯东部门巴地区晚白垩世埃达克质岩的岩石成因

本文首次报道了西藏冈底斯东部门巴地区晚白垩世花岗闪长岩的岩石学、锆石U-Pb定年和Hf同位素、全岩元素与Sr-Nd同位素地球化学数据。门巴花岗闪长岩锆石U-Pb定年结果为88.3Ma。花岗闪长岩的SiO2含量为66.4%～68.5%,K2O含量为3.1%～4.1%,A/CNK为0.90～0.99,属于高钾钙碱性准铝质岩石。岩石强烈富集轻稀土元素,(La/Yb)N为25.3～46.6,具弱的负Eu异常(δEu=0.83～0.91),高Sr(725×10-6～766×10-6)、高Sr/Y比值(Sr/Y=52.2～65.2),具有埃达克岩的特征,本文称之为门巴埃达克质岩石。门巴埃达克质岩石εNd(t)值为-4.1～-4.3,(87Sr/86Sr)t值为0.70671～0.70672。εHf(t)范围为-3.4～-1.2,Hf同位素地壳模式年龄为tCDM=1.2～1.4Ga。结合门巴埃达克质岩的主、微量元素、同位素以及含有闪长质包体等特征,判断门巴埃达克质岩石主要来源于古老下地壳物质的部分熔融,可能是来源于下地壳物质的熔体与幔源岩浆(如底侵的玄武岩浆)发生混合作用的结果。通过与在南冈底斯发现的埃达克岩的成因及地球动力学背景的对比,本文认为新特提斯洋洋脊俯冲作用不仅为镁铁质下地壳的熔融提供了能量,而且在岩浆形成演化过程中也起到了重要作用。     

内蒙古牙克石地区晚古生代弧岩浆岩:年代学及地球化学证据

在内蒙古牙克石地区晚古生代岩浆岩中发现了岛弧火山岩和埃达克质花岗闪长岩。火山岩由玄武岩、安山岩、英安岩及凝灰岩组成,属于钙碱性系列,它们富集大离子亲石元素(LILE)、轻稀土元素(LREE),亏损高场强元素(HFSE)。玄武岩的SHPIMP锆石U-Pb年龄表明其形成于373.2±5.3Ma。锆石εHf(t)值为+14.67～+18.67,类似大洋中脊玄武岩(MORB)和现代俯冲带玄武岩的Hf同位素特征。上述特征说明,玄武岩很可能起源于受俯冲板片流体改造的亏损地幔楔,形成于活动大陆边缘。花岗闪长岩的结晶年龄为331.2±3.7Ma。岩石高SiO2、Sr,高Sr/Y比值,富集轻稀土元素,亏损重稀土元素和Y及高场强元素,铕异常基本不明显,具备埃达克岩的地球化学特征。锆石εHf(t)值较高(+12.78～+14.54),说明源区可能为亏损地幔或新生的玄武质下地壳。根据微量元素组成认为花岗闪长岩主要起源于晚古生代底侵的岛弧玄武-安山质下地壳。弧火山岩和埃达克质花岗闪长岩的发现表明,区内晚泥盆世-早石炭世发生过大洋板片的俯冲作用,可能与额尔古纳-兴安地块与松嫩地块的碰撞拼合密切相关。     

湘东北早中生代花岗闪长岩地球化学特征及其构造意义

湘东北早中生代花岗闪长岩 (约 16 5Ma)SiO2 =6 5 .4 %～ 6 9.6 5 % ,K2 O +Na2 O =6 .0 %～ 7.17% ,K2 O≈Na2 O ,A/NKC =0 .96～ 1.13,为弱过铝质钙碱性岩石。该花岗闪长岩 (La/Yb) CN=12 .75～ 37.5 0 ,(Gd/Yb) CN =1.2 8～ 2 .90 ,Eu/Eu =0 .6 2～ 0 .90 ,以富集LILE和亏损Nb Ta、Ti、P为特征。初始87Sr/ 86Sr =0 .7114 5 8～ 0 .7174 6 1,εNd=- 9.0～ - 12 .3,其同位素组成明显有别于被认为其成因与地幔派生岩浆有关的湘东南高钾花岗闪长质岩石。暗示湘东北早中生代花岗闪长岩可能是在华南早中生代伸展构造背景下中 /下地壳物质深熔作用的产物。湘东北早中生代代表性花岗闪长质岩石不能与湘东南同期花岗闪长质岩石一起构成一条连续的高εNd、低TDM钾质岩石带。     

徐淮地区早白垩世丰山和蔡山高镁埃达克质岩:拆沉下地壳熔融的熔体与地幔橄榄岩的反应

徐淮地区丰山花岗闪长斑岩和蔡山石英闪长玢岩的岩石地球化学、Sr-Nd-Hf同位素和石榴石的矿物化学研究对探讨华北克拉通东南缘早白垩世高镁埃达克质岩的岩石成因和构造演化具有重要意义。结果表明,丰山花岗闪长斑岩和蔡山石英闪长玢岩具高SiO_2(60.98%～67.88%)、富Al_2O_3(14.37%～15.04%)以及高的Na_2O/K_2O比值(1.58～2.24)和Mg~#值(57～66)的特征;富集LILE(Rb、Ba、Sr)和LREE,亏损HFSE(Nb、Ta、Ti)和HREE,具有Pb正异常和弱的Eu异常;结合高的Sr含量(579×10~(-6)～778×10~(-6))以及Sr/Y(33～69)和(La/Yb)_N比值(8.63～13.7),低的Y(10.5×10~(-6)～17.8×10~(-6))和Yb含量(0.74×10~(-6)～1.17×10~(-6)),暗示它们属于高镁埃达克质岩。丰山和蔡山埃达克质岩石的初始~(87)Sr/~(86)Sr比值介于0.7079～0.7086之间,ε_(Nd)(t)值变化于-10.77～-7.18之间,t_(DM2)=1504～1793Ma;岩浆锆石的ε_(Hf)(t)值为-14.2～-5.3,t_(DM2)=2101～2898Ma。徐淮地区早白垩世利国、班井、夹沟高镁埃达克质岩石中岩浆锆石的ε_(Hf)(t)值分别介于-13.4～-7.0、-13.4～-7.9和-15.9～-4.5之间,它们的t_(DM2)分别变化于2248～2825Ma、2331～2824Ma和2030～3048Ma之间。徐淮地区丰山和蔡山高镁埃达克质岩的Sr-Nd-Hf同位素组成和丰山花岗闪长斑岩中铁铝榴石残留晶的存在,结合它们高的Pb同位素组成和继承锆石U-Pb年代学暗示,丰山和蔡山高镁埃达克质岩浆主要起源于俯冲断离的扬子克拉通石榴辉石岩相下地壳物质熔融的熔体与地幔橄榄岩的反应,同时有拆沉的华北克拉通基底物质的参与,形成于华北克拉通东部岩石圈减薄的伸展构造背景。     

青藏高原班公湖地区晚白垩世埃达克岩年代学、地球化学及构造意义

青藏高原西部班公湖地区的日松岩体和甲维酸性岩脉位于班公湖蛇绿混杂岩带南侧,岩石类型为英云闪长岩,花岗闪长玢岩和花岗闪长岩,显示中钾钙碱性-高钾钙碱性过渡的特征.元素地球化学组成表明,岩石均具有埃达克岩特征,表现为高的SiO₂(63.05%~70.72%)、高Al₂O₃(≥15%)、低MgO(0.97%~2.33%)＜3%、高Sr含量(380.4×10-6~625.0×10-6)、Sr/Y(＞35)、低HREE、Y(5.64×10-6~13.80×10-6)和Yb(0.46×10-6~1.25×10-6),轻重稀土分异明显(17.09＜(La/Yb)_N＜48.51).日松花岗闪长岩体LA-ICP-MS锆石U-Pb年龄为82.0±1.1 Ma;甲维近东西走向的花岗闪长岩脉和近南北走向的花岗闪长玢岩脉LA-ICP-MS锆石U-Pb年龄分别为90.7±1.2 Ma和82.9±1.2 Ma.日松和甲维处埃达克岩均富钾贫钠,低Cr、Ni,高Th、Th/La、Th/U、Rb/Sr以及相对低的Sr/Y和高Mg#(43.09~54.35)等特征显示其为玄武质岩浆底侵加厚下地壳部分熔融形成.91~82 Ma的埃达克岩形成于后碰撞初期阶段,为中特提斯洋闭合后板内热隆伸展、壳幔相互作用的产物,可以作为班公湖地区由板块构造体制转向板内构造体制的标志.      

新疆西准噶尔发现早泥盆世埃达克岩:大地构造及成矿意义

新疆西准噶尔博什库尔-成吉斯(Boshchekul-Chingiz)岩浆弧南缘,额敏县东南约100km的阿克乔克含铜花岗闪长岩和花岗闪长斑岩,其锆石U-Pb年龄为410.5±2.9Ma,形成于泥盆世早期.岩石具有埃达克岩的地球化学特征,表现为高钾钙碱性-钙碱性,SiO2含量在61％～66％之间,具高Al(Al2O3=15.67％ ～ 16.87％)、Sr(475×10-6 ～ 879×10-6)及高Sr/Y比值(36 ～77),低Y(9.87×10-6～14.46×10-6)、Yb(0.96×10-6～ 1.49×10-6),富钠贫钾(Na2O =4.25％ ～5.58％,K2O=2.26％ ～3.27％,Na2O/K2O=1.40～ 2.47),MgO=1.51％ ～2.58％,Mg#=41～48,并显示富集强不相容元素(Ba、Rb、Sr、Th、U)和LREE,(La/Yb)N=6.0～10.2,强烈亏损高场强元素(Nb-Ta、Ti),Y/Yb=10,无Eu异常(Eu/Eu*≈1.0)和HREE呈平坦型的配分特点,以及与环太平洋新生代埃达克岩相当的Rb/Sr(0.04 ～0.07)和La/Ce(0.42 ～0.51)比值,但偏低的Nb/U比值可能与俯冲沉积物加入有关.阿克乔克花岗闪长岩及花岗闪长斑岩是早泥盆世早期库吉拜-和布克赛尔(Kujibai-Hebukesaier)及洪古勒楞蛇绿岩带所代表的古大洋向南俯冲的玄武质洋壳部分熔融的产物,源区残留相主要为角闪石+辉石+石榴石,源岩应为石榴角闪岩;阿克乔克早泥盆世埃达克岩及谢米斯台-赛尔山晚志留世-早泥盆世A-型花岗岩(422～405 Ma,Chen et al.,2010)构造岩浆岩带可东延至扎河坝-阿尔曼太蛇绿岩带之北的岛弧带,构成一条贯穿东、西准噶尔北部的巨型构造带;阿克乔克埃达克岩伴有斑岩型Cu成矿作用,因此,在东、西准噶尔博什库尔-成吉斯-达拉特-巴依塔格巨型岩浆弧带有可能存在与埃达克岩有关的Cu-Au矿带.     

中国东北新生代富锦岩体岩石成因及其构造意义

富锦岩体位于佳木斯地块东缘,紧邻环太平洋增生型完达山造山带,是中国东部最年轻的花岗岩体之一。野外出露点在黑龙江省富锦市东11 km、乌尔虎力山西北坡,GPS位置47°14'9.8"N 132°14'5.8"E。岩体由中粒花岗闪长岩组成,围岩是二叠纪砂岩地层,地层南北走向、近直立,砂岩发生接触热变质。花岗闪长岩具半自形粒状结构,含~50%斜长石、~25%石英、~15%黑云母及~10%碱性长石。锆石长轴~250 um,长宽比~3:1,阴极发光下见明显的振荡环带,为典型花岗岩锆石。15粒锆石SHRIMP U-Pb分析结果得出谐和年龄为(54±1)Ma。围岩砂岩的碎屑锆石颗粒直径50~100 um,SHRIMP锆石U-Pb年龄峰值260、500 Ma,少量属前寒武纪。花岗闪长岩Si O2(质量分数)为68.8%~70.3%,Na2O为3.8%~4.2%,K2O为1.9%~2.3%,富集轻稀土元素及大离子亲石元素,亏损高场强元素,强烈分异的稀土配分模式[(La/Yb)N22]、高Sr/Y比(Sr/Y60)、高Ba((699~764)×10-6)和Sr((707~735)×10-6)质量分数等特征表明其为埃达克质高钡锶花岗岩。其初始87Sr/86Sr比值为0.706 099~0.707 265,εNd(t)值为-0.15~-2.07,(208Pb/204Pb)t=38.244~38.279,(207Pb/204Pb)t=15.562~15.576,(206Pb/204Pb)t=18.353~18.376,锆石εHf(t)值为+3~+7,Sr-Nd-Pb-Hf同位素特征与佳木斯地块东缘及完达山造山带西缘的二叠纪岛弧岩浆岩[1]十分接近,反映了EM2同位素特征,而与中国东北新生代以双辽[2]、伊通—大屯[3]玄武岩为代表的DMM软流圈亏损地幔来源物质和以五大连池[4]、牡丹江黄花—海浪玄武岩[5]、永胜正长岩体[6]为代表的高钾质EM1岩石圈富集地幔来源物质有显著差异,亦未见岩浆混合的证据。因此,富锦花岗闪长岩更可能是来自由二叠纪岛弧岩石组成的玄武质下地壳的部分熔融,而不是来自新生代幔源岩浆的结晶分异或岩浆混合。结合研究区周缘广泛发育古近纪断陷盆地的区域地质背景,认为富锦岩体的形成与古近纪太平洋板块俯冲脱水、玄武质岩浆底侵以及陆壳伸展有关。本研究提供了一个新的埃达克质岩石形成于板内伸展环境下的案例[7]。     

湘东宏夏桥和板杉铺岩体LA-MC-ICPMS锆石U-Pb年龄及地质意义

运用阴极发光技术,对湖南东部宏夏桥和板杉铺岩体的锆石进行了内部结构分析,在此基础上利用LA-MC-ICPMS锆石U-Pb定年方法进行了同位素年代学测定。结果显示,宏夏桥2个黑云母花岗闪长岩样品分别给出了(421±2)Ma和(423±2)Ma的主体谐和年龄;板杉铺2个黑云母二长花岗岩样品给出了(422±2)Ma和(421±2)Ma的谐和年龄。这两岩体均为准铝质-过铝质花岗岩,具明显高Sr/Y和La/Yb比值和负εNd(t)值,与埃达克岩类似,推测它们为早古生代华南地壳缩短加厚和部分熔融作用的产物。综合区域岩浆和变形变质年龄,本文认为,华南早古生代陆内挤压造山作用发生于~460~420 Ma,以前泥盆纪地层广泛褶皱和大规模地壳重熔型岩浆活动、混合岩化作用、基底韧性剪切及高级变质作用为主;陆内造山后期的伸展松弛作用发生于~420~385 Ma,主要表现为后造山花岗岩形成、张扭性韧性剪切和退变质作用。     

西藏浦桑果铜多金属矿床中酸性岩石成因及动力学背景:年代学、地球化学及Sr-Nd-Pb-Hf同位素约束

浦桑果矿床位于拉萨地块冈底斯成矿带中段,为侵入岩体与钙质围岩接触带内形成的矽卡岩型高品位铜多金属矿床(Cu@1. 42%,Pb+Zn@2. 83%),是冈底斯成矿带目前唯一一个大型富铜铅锌(钴镍)矿床。本文以浦桑果矿床相关中酸性侵入岩体(黑云母花岗闪长岩和闪长玢岩)为主要研究对象,开展LA-ICP-MS锆石U-Pb年代学、全岩主微量元素、全岩SrNd-Pb及锆石Lu-Hf同位素研究,旨在厘定侵入岩体的形成时代、岩石成因及成岩成矿的动力学背景。LA-ICP-MS锆石U-Pb定年结果表明,黑云母花岗闪长岩和闪长玢岩侵位年龄分别为13. 6～14. 4Ma和13. 6～14. 6Ma,岩体形成时代均属中新世。岩石地球化学特征表明,闪长玢岩和黑云母花岗闪长岩均属高钾钙碱性I型花岗质岩石;岩石普遍具高Sr含量(599×10~(-6)～1616×10~(-6))、高Sr/Y(48. 2～132. 3)和高(La/Yb)N(19. 6～25. 4)比值特征,具低Y(10. 38×10~(-6)～12. 70×10~(-6))和Yb含量(0. 79×10~(-6)～1. 17×10~(-6))特征,表现出埃达克质岩的地球化学属性。全岩稀土元素表现为明显富集轻稀土元素(LREEs)和大离子亲石元素(LILEs),而相对亏损重稀土元素(HREEs)和高场强元素Nb、Ta、P、Ti等(HFSE)。全岩Sr-Nd-Pb及锆石Hf同位素分析结果表明,浦桑果矿床相关中酸性岩石与冈底斯成矿带中新世大多斑岩-矽卡岩矿床紧密相关的埃达克质侵入岩体具相似的同位素组成特征,指示岩石具同源岩浆特征且埃达克质岩浆主要起源于拉萨地块加厚新生下地壳。浦桑果矿床中酸性岩体主要形成于后碰撞伸展的构造背景,因碰撞挤压向后碰撞伸展背景的构造转换,引起印度大陆岩石圈发生拆沉(42～25Ma)及拉萨地块中富集岩石圈地幔发生部分熔融,从而形成富含Cu、Co等基性岩浆熔体底侵加厚新生下地壳(25～18Ma),导致拉萨地块加厚新生下地壳中部分石榴子石角闪岩相发生部分熔融,最终形成闪长质熔体于浦桑果矿区有利构造部位形成具埃达克质属性的中酸性侵入岩体(13～14Ma)和矽卡岩型铜多金属矿体。     

实验岩石学对埃达克岩成因的限定——兼论中国东部富钾高Sr/Y比值花岗岩类

大量变玄武岩脱水熔融实验表明,制约埃达克岩形成的主要因素是源岩、水和地壳热结构(p-T轨迹)。变玄武岩低到中等程度(10％～40％)的部分熔融过程中,含水矿物(主要是角闪石)脱水反应产生埃达克岩熔体,残余相组合为石榴石+单斜辉石±斜方辉石±角闪石(没有斜长石)。在俯冲带,当压力为1.6～2.2 GPa(约70～90 km)和温度为800～1150℃时,具有高的剪切热速率和非常年轻的(<25 Ma)、热的俯冲大洋岩石圈就会发生脱水熔融形成埃达克熔体。在增厚地壳内,具有高的热状态的底侵玄武质下地壳在压力≥0.8 GPa(>35 km)和温度介于800～1100℃之间发生部分熔融形成埃达克质熔体。然而,中国东部晚中生代富钾高Sr/Y比值花岗岩类,可能形成于加厚地壳开始减薄及地壳从挤压向拉张伸展转换的环境下,所对应的岩浆,与下地壳底侵的碱性玄武岩和/或拉斑玄武岩在压力1.0～1.5 GPa和温度850～1080℃之间发生部分熔融有关,熔融的残余相为辉石岩类,岩浆在上升侵位过程中还受到了地壳AFC的影响。中国东部中生代岩石圈从加厚转变为减薄的过程,就可能与玄武质岩浆的底侵作用及随后含石榴石辉石岩类残余体的拆沉作用有关。     

胶东范家庄地区晚侏罗世低镁埃达克质花岗岩成因及构造背景

胶东地区广泛发育一系列晚侏罗世岩浆作用产生的埃达克质岩,其成因机制及构造背景研究为揭示胶东地区中生代构造演化提供了重要证据.选取出露于胶东苏鲁地区的范家庄花岗岩进行锆石U-Pb年龄、全岩主微量元素和Sr-Nd-Pb同位素组成分析,探讨了岩石成因及成岩构造背景.锆石U-Pb年龄结果表明范家庄花岗岩侵位于晚侏罗世（161±2 Ma）.岩石主微量数据具有富硅（SiO₂=68.94%~71.00%）、高铝（Al₂O₃>15.17%）、低镁（MgO=0.32%~0.41%）;高Sr、低Y、Yb含量以及高（La/Yb）_N（>38.59）比值的特点,同位素测试结果显示相对高的（87Sr/86Sr）_i比值（0.709 28~0.711 41）、相对较低的ε_Nd（t）值（-20.5~-14.1）和高放射性Pb同位素组成（206Pb/204Pb）_t=16.853~17.207,（207Pb/204Pb）_t=15.436~15.495,（208Pb/204Pb）_t=37.340~37.629.综合分析认为,范家庄岩体属于低镁埃达克质岩,产于增厚下地壳部分熔融,源区以扬子板块下地壳组分为主,混合有华北板块下地壳成分.晚侏罗世伊泽奈奇板块俯冲形成的弧后拉张环境诱发重力不稳定或者岩石圈伸展造成加厚的造山带垮塌,软流圈上涌的导致加厚地壳部分熔融可能是形成胶东范家庄低镁埃达克岩的地球动力学背景.      

Origins and tectonic implications of Late Cretaceous adakite and primitive high-Mg andesite in the Songdo area,southern Lhasa subterrane,Tibet

Late Cretaceous igneous rocks in the southern Lhasa subterrane, Tibet, include primitive high-Mg andesites and adakites, which provide important constraints on the tectonic evolution of the Neo-Tethys Ocean. Here, we present detailed zircon UPb and Hf isotopic and whole-rock geochemical data for granodioritic and dioritic porphyry samples from the Songdo area in the southern Lhasa subterrane. Zircon UPb dating indicates that the granodiorite crystallized at 88 Ma, whereas the diorite yields ages of 68 and 66 Ma. The granodiorite has adakite-like geochemical characteristics, including high Sr (801–1005 ppm) and low Y (6.8–15.2 ppm) and Yb (0.6–1.3 ppm) concentrations, and high Sr/Y (62–145) and La/Yb (39–93) ratios. We infer that the adakitic granodiorites formed through partial melting of subducted oceanic crust. The dioritic porphyry has intermediate moderate SiO2 (53–58 wt%) and high MgO (5.6–8.2 wt%) contents, and high Mg# (66.4–69.5) values, and is therefore classified as a primitive high-Mg andesite that was derived from interaction between subducted sediment and mantle. The presence of coeval adakite and charnockite, as well as high-temperature granulite-facies metamorphism, indicates that mid-ocean ridge subduction occurred at 100–80 Ma, followed by a 10 Myr hiatus in magmatism and subsequent rollback of the Neo-Tethys slab at 68 Ma. These processes resulted in significant crustal growth within the Lhasa terrane.     

The genesis of felsic magmatism during the closure of the Northeastern Paleo-Tethys Ocean: Evidence from the Heri batholith in West Qinling,China

To better understand the origin of voluminous silicic rocks in a convergent continental margin, we conducted an integrated study in which we have obtained geochronological, mineralogical, and isotopic (including whole-rock Sr–Nd–Pb, in-situ zircon Hf) data of the Heri batholith in West Qinling on the NE Tibetan Plateau. The batholith is composed of metaluminous to weakly peraluminous granodiorites (235–233 Ma) and porphyritic granodiorites (230–223 Ma) with an I-type affinity. Both lithologies share similar major, trace elemental and SrNd isotopic compositions. Detailed elemental data demonstrate that these granodioritic rocks underwent fractional crystallization of hornblende and apatite, with plagioclase (i.e. sieve-textured plagioclase cores) accumulation to some extent. Except for porphyritic granodiorites, the Pb isotopes for other analyzed samples are characterized by high radiogenicity and uniformity ((²⁰⁶Pb/²⁰⁴Pb)_t: 17.263–18.472, (²⁰⁶Pb/²⁰⁴Pb)_t: 15.571–15.591, and (²⁰⁶Pb/²⁰⁴Pb)_t: 38.032–38.304), together with limited variations in initial Sr ((⁸⁷Sr/⁸⁶Sr)_t: 0.707251–0.708103) and Nd (ε_Nd(t) = −7.1 to −6.3) isotopes with two-stage model ages (T_DM2) of 1.58–1.52 Ga. These factors collectively point to a derivation from the Mesoproterozoic basement rocks at the lower crustal level, or a comprehensive mixing of different-age components that generated an average crustal residence age. The SrNd isotopic compositions of the porphyritic granodiorites are strikingly similar to those of granodiorites. Compared with the experimental melt compositions of amphibolites, the Heri granitoids are probably derived from an amphibolitic source under fluid-absent conditions due to the incongruent breakdown of amphibole and biotite. Based on the temporal–spatial distribution of granitic intrusions in West Qinling and the regional tectonic evolution, our interpretation is that the Heri batholith was formed during the initial collision between the North China Craton (NCC) and the South China Craton (SCC), which was accompanied by the closure of the Paleotethyan Ocean. Considering both previously published data and our new data, we propose that the Heri granitoids were mainly generated by the partial melting of lower crustal amphibolites, with minor mantle-derived melts.     

Origin of C type adakite magmas in the NE Xing’an block,NE China and tectonic implication

In this paper, we report new whole-rock geochemical and zircon U–Pb data for monzogranites in the NE Xing’an block. These data constrained the petrogenesis of C type (high Sr/Y) adakitic rocks and showed the spatial extent of the influence of the Mongol-Okhostsk ocean tectonic regime and the collision between the Jiamusi Massif and Songliao Terrane. New zircon laser-ablation inductivity coupled plasma mass spectrometry (LA-ICP-MS) U–Pb data indicated that the monzogranites in the studied area were emplaced in the Early Jurassic (~180 Ma). These rocks were characterized by unusally high SiO₂ (≥67.49), and Sr (461–759 ppm), but strikingly low Y (4.63–8.06 ppm) and HREE (∑HREE = 3.83–6.49 ppm, Yb = 0.5–0.77 ppm) contents, with therefore high Sr/Y (67.2–119) and (La/Yb)_N (29.7–41.5) ratios, showing the geochemical characteristics of C type adakitic granite. The data displayed negligible Eu anomalies (Eu/Eu* = 0.77–1.08), LREE-enriched and pronounced negative Nb and Ta anomalies. The C-type adakites in the studied area were most likely derived from the partial melting of a thickened lower continental curst. The magma source is most likely dominated by amphibolites and garnet amphibolites. In combination with previously-reported data from igneous rocks from the Mesozoic in NE China, we conclude that the Xing’an block was influenced by the Mongol-Okhotsk subduction tectonic system, and experiences compressive settings from the amalgamation of the Jiamusi block in the east of the CAOB.     

江西冷水火山—侵入杂岩体岩石化学及地球化学特征

冷水银铅锌矿的火山—侵入杂岩体出露于信江中生代火山盆地南缘。岩石化学、微量元素、稀土元素和铷锶同位素分析表明冷水火山岩及次火山岩是同源产物,是同熔岩浆分异的结果。岩浆中成矿物质Cu、Fe、Pb、Zn、S、H_2O的数量与下地壳、上地慢或洋壳物质的部分熔融程度有关。冷水火山—侵入杂岩是钙碱性岩浆于不同演化阶段形成的岩石组合并具有化学成分上的相似性和继承性。岩浆房中具有良好的分带现象,上部为富钾的流纹质岩浆,向下逐渐变为基性岩浆。岩浆由钙碱性向偏碱性演化,促使成矿元素大量富集,在一定条件下形成矿床。     

Geochemical characteristics of central Chile (33 °–34 °S) granitoids

Seventeen granitoid samples from batholiths in central Chile (33 °–34 ° S) have been analyzed for trace element content. The samples range in age from Paleozoic to Tertiary, and in rock type from quartz diorite to granite. In general, compared to andesites from central-south Chile these rocks are more siliceous with lower abundances of compatible trace elements and higher abundances of incompatible trace elements. However, Upper Tertiary granodiorites have important geochemical similarities, such as highly fractionated rare-earth element (REE) distributions relative to chondrites, to some modern andesites in this region; e.g., Marmolejo. Similar highly fractionated REE distributions are also common in the cores of zoned intrusive sequences in the Sierra Nevada of the western U.S. Based on limited sampling of central Chile Cretaceous and Tertiary plutonics, there may be a west to east increase in light REE/heavy REE ratio and in Sr content. Compared to the Upper Tertiary granodiorites, the Paleozoic granodiorites have similar REE abundances but lower Sr, Sc, Cr, Co, and Ni contents.     

挥发份对高硅岩浆演化趋势的制约:以东南沿海白垩纪晚期花岗岩类岩石为例SCIEI北大核心CSCD

东南沿海分布大面积的白垩纪晚期侵入岩。这些岩石可分为两期:其中115~100Ma以钙碱性系列岩石为主,岩石组合为辉长岩-闪长岩-花岗闪长岩-二长花岗岩-碱性长石花岗岩;而100~86Ma的岩石为碱性系列,岩石组合为石英二长斑岩-正长斑岩-碱性长石花岗岩。115~100Ma的辉长岩以角闪辉长岩为主,具有极高的CaO、MgO和Al_(2)O_(3)含量,具有极低的SiO_(2)(42.9%~53.8%)、全碱(K_(2)O+Na_(2)O:0.86%~5.28%)、Ba、Nb、Th、Rb和Zr含量,也具有极低的FeO^(T)/MgO、La/Yb和Zr/Hf比值,较高的Eu/Eu^(*)、Sr/Y比值和Sr含量,为基性-超基性堆晶岩。与辉长岩同期的闪长岩和细粒暗色包体具有较高的SiO_(2)(50.34%~63.68%),较低的CaO、P_(2)O_(5)、MgO、Al_(2)O_(3)含量,相对低的Eu/Eu^(*)和Sr/Y比值,变化较大的La/Yb和Zr/Hf比值,代表了从基性岩浆储库中抽取的富硅熔体。115~100Ma的花岗闪长岩和二长花岗岩类岩石为准铝质岩石,SiO_(2)含量变化较大(61.7%~75.3%),具有较低的FeO^(T)/MgO、Ga/Al比值和Nb、Zr及Nb+Zr+Ce+Y元素含量,显示出典型I型花岗岩的特征。这些花岗岩具有相对高的La/Yb、Eu/Eu^(*)和Zr/Hf比值和高的Sr、Ba和Zr含量。结合岩相学特征,这些花岗岩为堆晶花岗岩。而115~100Ma的碱性长石花岗岩具有极高的SiO_(2)含量(大于75%),低的Eu/Eu^(*)、La/Yb、Zr/Hf和Sr/Y比值,具有低的Ba、Sr和Zr含量和高的Rb、Nb、Y和Th含量和Rb/Sr比值,表明这些花岗岩是由富硅岩浆储库中抽离的高硅熔体侵入地壳形成。100~86Ma期间形成的二长斑岩和正长斑岩具有极高的全碱含量,可以达到8%~12%,其SiO_(2)主要集中在60%~70%,具有极高的Zr、Sr和Ba含量和Eu/Eu^(*)、La/Yb和Sr/Y比值,显示出堆晶花岗岩的特征。而100~86Ma期间形成的大部分碱性长石花岗岩具有极高的SiO_(2)含量(大于75%),并显示出A型花岗岩的特征,具有高的Rb/Sr比值和高的Rb、Y和Th和低的Ba、Sr含量和低的Zr/Hf、La/Yb、Eu/Eu^(*)和Sr/Y比值,表明它们是由富硅岩浆储库抽离的高硅熔体侵入浅部地壳形成。东南沿海高硅花岗岩的形成和穿地壳岩浆系统密切相关,高硅花岗岩是由浅部地壳内晶体-熔体分异产生的熔体侵入地壳所形成,而高硅花岗岩的地球化学特征与岩浆储库的水及挥发份含量密切相关。115~100Ma期间,从富水的岩浆储库抽离的熔体形成具有低高场强元素含量和低Rb/Sr比值的高硅花岗岩,这一过程与古太平洋板块俯冲有关;100~86Ma期间,从富挥发份的岩浆储库抽离的熔体形成碱性特征、富含高场强元素和具有高的Rb/Sr比值的高硅花岗岩,这一过程和古太平洋板块回撤软流圈上涌有关。     

New geological and geochemical data on the granitoids of the Uspensky massif in Southern Primorye

New geological, petrochemical, mineralogical, and geochemical data are presented on the Uspensky granitoid massif in Southern Primorye. The massif consists of the rocks of two associations: (1) the early association (103.3 ± 2.4 Ma) consisting of garnet-bearing biotite and two-mica granite-leucogranites and (2) the late association (99 ± 2 Ma) represented by biotite (±amphibole) granodiorites, melanogranites, and granites. The granitoids of both associations have moderate potassic alkalinity and elevated alumina contents but differ in the proportions of alumina, calcium, and alkalis. The garnet-bearing granite-leucogranites are characterized by the highest Rb, Th, and U contents and the lowest Sr, Ba, Hf, and Zr contents. The REE distribution patterns have a quasi-symmetric shape and deep Eu minimums. The melanogranites show higher Sr and Ba contents and, as granites, are characterized by asymmetric REE spectrums with an insignificant negative Eu anomaly. The porphyraceous granodiorites and granites are peculiar in their lowered Sr and Ba contents, while the granodiorites have lowered contents of K, REE, Zr, Hf, Th, and U; elevated Nb contents; and a distinctive Eu minimum.     

东昆仑加鲁河中三叠世含石榴石二云母花岗岩的成因及地质意义

东昆仑造山带广泛发育晚古生代-早中生代富含暗色微粒包体的花岗闪长岩类,被认为是研究壳幔岩浆混合作用的天然实验室,然而同时代的过铝质-强过铝质型花岗岩在该地区鲜有报道.在东昆仑东段加鲁河地区新识别出一套含石榴石二云母花岗岩,为了探究其成因归属及地质意义,我们对其开展了详细的矿物学、岩石学、锆石U-Pb年代学、岩石地球化学及锆石Lu-Hf同位素研究.该套岩石呈多条近平行脉状侵入花岗闪长岩中,主要组成矿物包括石英、斜长石、钾长石、黑云母和白云母,副矿物中可见少量石榴石.LA-ICP-MS锆石U-Pb定年获得含石榴石二云母花岗岩成岩年龄为242.0±1.4 Ma,属于中三叠世岩浆活动产物.化学成分上,该岩石具有高SiO₂（74.49%~75.24%）、高K₂O（4.21%~4.33%）、低P₂O₅（0.02%~0.03%）含量和过铝质-强过铝质（A/CNK值为1.08~1.12）特征,表现出较高的分异程度.其U、Th、Pb、Rb等元素相对富集,Nb、Ta、P、Ti等元素相对亏损,其中P、Ti强烈亏损,这可能与磷灰石及钛磁铁矿的早期结晶分异有关.稀土元素总量较低为（61.55×10-6~119.05×10-6）,有弱负Eu异常（δEu=0.51~0.65）.锆石ε_Hf（t）值变化范围为-8.19~-2.78（均值为-5.61）,二阶段模式年龄（T_DM2）为1.3~1.6 Ga,全岩Nb/Ta比值8.22~9.67（接近地壳比值10.91）,这与区域内近同期的黑云母二长花岗岩特征相似,均指示该岩石可能源于下地壳的重熔.岩石中广泛发育的富云包体暗示岩浆上升途中捕获围岩物质,岩浆存在明显同化混染作用.综上,本文认为东昆仑加鲁河地区的含石榴石二云母花岗岩脉为一套过铝质-强过铝质的高分异I型花岗岩,是下地壳部分熔融产生的长英质岩浆经历长期结晶分异作用并在上升途中受到围岩同化混染作用之后的产物.