http://www.sciencedirect.com/science/article/pii/S1674987114000644

正1.Introduction This special issue of Geoscience Frontiers is a tribute volume honoring the life and career of Jacques Touret.A set of research papers has been assembled,which broadly reflect his research interests over his 50 plus year career.These papers focus on the role that fluids play during the formation and evolution of the Earth's crust.Below I provide a brief summary of the life of Jacques Touret,along with a select bibliography of his more important papers.This is then followed by a brief introduction to the papers assembled for this special issue.     

http://www.sciencedirect.com/science/article/pii/S1674987114000395

The study of fluid inclusions in high-grade rocks is especially challenging as the host minerals have been normally subjected to deformation, recrystallization and fluid-rock interaction so that primary in- clusions, formed at the peak of metamorphism are rare. The larger part of the fluid inclusions found in metamorphic minerals is typically modified during uplift. These late processes may strongly disguise the characteristics of the ＂original＂ peak metamorphic fluid. A detailed microstructural analysis of the host minerals, notably quartz, is therefore indispensable for a proper interpretation of fluid inclusions. Cathodoluminescence （CL） techniques combined with trace element analysis of quartz （EPMA, LA- [CPMS） have shown to be very helpful in deciphering the rock-fluid evolution. Whereas high-grade metamorphic quartz may have relatively high contents of trace elements like Ti and A1, low- temperature re-equilibrated quartz typically shows reduced trace element concentrations. The result- ing microstructures in CL can be basically distinguished in diffusion patterns （along microfractures and grain boundaries）, and secondary quartz formed by dissolution-reprecipitation. Most of these textures are formed during retrograde fluid-controlled processes between ca. 220 and 500 ℃, i.e. the range of semi-brittle deformation （greenschist-facies） and can be correlated with the fluid inclusions. In this way modified and re-trapped fluids can be identified, even when there are no optical features observed under the microscope.     

Assimilation of carbonate country rock by the parent magma of the Panzhihua Fe-Ti-V deposit（SW China）：Evidence from stable isotopes

The Panzhihua intrusion in southwest China is part of the Emeishan Large Igneous Province and host of a large Fe-Ti-V ore deposit.During emplacement of the main intrusion,multiple generations of mafic dykes invaded carbonate wall rocks,producing a large contact aureole.We measured the oxygen-isotope composition of the intrusions,their constituent minerals,and samples of the country rock.Magnetite and plagioclase from Panzhihua intrusion haveδ¹⁸O values that are consistent with magmatic equilibrium, and formed from magmas withδ¹⁸O values that were 1-2‰higher than expected in a mantle-derived magma.The unmetamorphosed country rock has highδ¹⁸O values,ranging from 13.2‰（sandstone） to 24.6-28.6‰（dolomite）.The skarns and marbles from the aureole have lowerδ¹⁸O andδ¹³C values than their protolith suggesting interaction with fluids that were in exchange equilibrium with the adjacent mafic magmas and especially the numerous mafic dykes that intruded the aureole.This would explain the alteration ofδ¹⁸O of the dykes which have significantly higher values than expected for a mantle-derived magma.Depending on the exactδ¹⁸O values assumed for the magma and contaminant, the amount of assimilation required to produce the elevatedδ¹⁸O value of the Panzhihua intrusion was between 8 and 13.7 wt.%,assuming simple mixing.The exact mechanism of contamination is unclear but may involve a combination of assimilation of bulk country rock,mixing with a melt of the country rock and exchange with CO₂-rich fluid derived from decarbonation of the marls and dolomites.These mechanisms,particularly the latter,were probably involved in the formation of the Fe-Ti-V ores.     

http://www.sciencedirect.com/science/article/pii/S1674987112001223

The Paleogene succession of the Himalayan foreland basin is immensely important as it preserves evidence of India-Asia collision and related records of the Himalayan orogenesis. In this paper, the depositional regime of the Paleogene succession of the Himalayan foreland basin and variations in composition of the hinterland at different stages of the basin developments are presented. The Paleogene succession of the western Himalayan foreland basin developed in two stages, i.e. syn-collisional stage and post-collisional stage. At the onset, chert breccia containing fragments derived from the hanging walls of faults and reworked bauxite developed as a result of erosion of the forebulge. The overlying early Eocene succession possibly deposited in a coastal system, where carbonates represent barriers and shales represent lagoons. Up-section, the middle Eocene marl beds likely deposited on a tidal flat. The late Eocene/Oligocene basal Murree beds, containing tidal bundles, indicate that a mixed or semi-diurnal tidal system deposited the sediments and the sedimentation took place in a tide-dominated estuary. In the higher-up, the succession likely deposited in a river-dominated estuary or in meandering rivers. In the beginning of the basin evolution, the sediments were derived from the Precambrian basement or from the metasediments/volcanic rocks possessing terrains of the south. The early and middle Eocene (54.7–41.3 Ma) succession of the embryonic foreland possibly developed from the sediments derived from the Trans-Himalayan schists and phyllites and Indus ophiolite of the north during syn-collisional stage. The detrital minerals especially the lithic fragments and the heavy minerals suggest the provenance for the late Eocene/Oligocene sequences to be from the recycled orogenic belt of the Higher Himalaya, Tethyan Himalaya and the Indus-suture zone from the north during post-collisional stage. This is also supported by the paleocurrent measurements those suggest main flows directed towards southeast, south and east with minor variations. This implies that the river system stabilized later than 41 Ma and the Higher Himalaya attained sufficient height around this time. The chemical composition of the sandstones and mudstones occurring in the early foreland basin sequences are intermediate between the active and passive continental margins and/or same as the passive continental margins. The sedimentary succession of this basin has sustained a temperature of about 200 °C and undergone a burial depth of about 6 km.     

http://www.sciencedirect.com/science/article/pii/S1674987111000508

This paper presents the results of a set of numerical models focussing on structural controls on hydrothermal mineralization.We first give an overview of natural phenomena of structurally-controlled ore formation and the background theory and mechanisms for such controls. We then provide the results of a group of simple 2D numerical models validated through comparison with Cu-vein structure observed near the Shilu Copper deposit(Yangchun,Guangdong Province, China) and finally a case study of 3D numerical modelling applied to the Hodgkinson Province in North Queensland(Australia).Two modelling approaches,discrete deformation modelling and continuum coupled deformation and fluid flow modelling,are involved.The 2D model-derived patterns are remarkably consistent with the Cu-vein structure from the Shilu Copper deposit,and show that both modelling approaches can realistically simulate the mechanical behaviours of shear and dilatant fractures.The continuum coupled deformation and fluid flow model indicates that pattern of the Cuveins near the Shilu deposit is the result of shear strain localization,development of dilation and fluid focussing into the dilatant fracture segments.The 3D case-study models(with deformation and fluid flow coupling) on the Hodgkinson Province generated a number of potential gold mineralization targets.     

http://www.sciencedirect.com/science/article/pii/S1674987110000071

<正>The lithospheric structure of China and its adjacent area is very complex and is marked by several prominent characteristics.Firstly,China's continental crust is thick in the west but thins to the east,and thick in the south but thins to the north.Secondly,the continental crust of the Qinghai—Tibet Plateau has an average thickness of 60—65 km with a maximum thickness of 80 km,whereas in eastern China the average thickness is 30—35 km,with a minimum thickness of only 5 km in the center of the South China Sea.The average thickness of continental crust in China is 47.6 km,which greatly exceeds the global average thickness of 39.2 km.Thirdly,as with the crust,the lithosphere of China and its adjacent areas shows a general pattern of thicker in the west and south,and thinner in the east and north.The lithosphere of the Qinghai—Tibet Plateau and northwestern China has an average thickness of 165 km, with a maximum thickness of 180—200 km in the central and eastern parts of the Tarim Basin,Pamir, and Changdu areas.In contrast,the vast areas to the east of the Da Hinggan Ling—Taihang—Wuling Mountains,including the marginal seas,are characterized by lithospheric thicknesses of only 50—85 km.Fourthly,in western China the lithosphere and asthenosphere behave as a "layered structure", reflecting their dynamic background of plate collision and convergence.The lithosphere and asthenosphere in eastern China display a "block mosaic structure",where the lithosphere is thin and the asthenosphere is very thick,a pattern reflecting the consequences of crustal extension and an upsurge of asthenospheric materials.The latter is responsible for a huge low velocity anomaly at a depth of 85—250 km beneath East Asia and the western Pacific Ocean.Finally,in China there is an age structure of "older in the upper layers and younger in the lower layers" between both the upper and lower crusts and between the crust and the lithospheric mantle.     

http://www.sciencedirect.com/science/article/pii/S1674987114000437

The Pranhita-Godavari Basin in central eastern India is one of the Proterozoic "Purana" basins of cratonic India.New geochronology demonstrates that it has a vast depositional history of repeated basin reactivation from the Palaeoproterozoic to the Mesozoic.U-Pb laser ablation inductively coupled plasma mass spectrometry dating of detrital zircons from two samples of the Somanpalli Group—a member of the oldest sedimentary cycle in the valley-constrains its depositional age to ~1620 Ma and demonstrates a tripartite age provenance with peaks at ~3500 Ma,~2480 Ma and ~1620 Ma,with minor age peaks in the Eoarchaean(~3.8 Ga) and at ~2750 Ma.These ages are consistent with palaeocurrent data suggesting a southerly source from the Krishna Province and Enderby Land in East Antarctica.The similarity in the maximum depositional age with previously published authigenic glauconite ages suggest that the origin of the Pranhita-Godvari Graben originated as a rift that formed at a high angle to the coeval evolving late Meosproterozoic Krishna Province as Enderby Land collided with the Dharwar craton of India.In contrast,detrital zircons from the Cycle III Sullavai Group red sandstones yielded a maximum depositional age of 970±20 Ma and had age peaks of ~2550 Ma,~1600 Ma and then a number of Mesoproterozoic detrital zircons terminating in three analyses at ~970 Ma.The provenance of these is again consistent with a southerly source from the Eastern Ghats Orogen and Antarctica.Later cycles of deposition include the overlying Albaka/Usur Formations and finally the late Palaeozoic to Mesozoic Gondwana Supergroup.     

http://www.sciencedirect.com/science/article/pii/S1674987111001290

The Three Gorges Dam(TGD) of the Yangtze River.China,is one of the largest irrigation and hydroelectric engineering projects in the world.The effects of huge man-made projects like TGD on fauna and macrophyte are obvious,mainly through changes of water dynamics and flow pattern;however, it is less clear how microorganisms respond to such changes.This research was aimed to examine differences in microbial diversity at different seasons and locations(in front of and behind the TGD).In addition, differences between particle-attached and free-living communities were also examined.The community structures of total and potentially active microorganisms in the water columns behind and in front of the TGD were analyzed with the DNA- and RNA-based 16S rRNA gene phylogenetic approaches over three different seasons.Clone libraries of 16S rRNA genes were prepared after amplification from extracted DNA and.for some samples,after preparing cDNA from extracted rRNA.Differences were observed between sites at different seasons and between free-living and particle-attached communities.Both bacterial and archaeal communities were more diverse in summer than in winter, due to higher nutrient levels and warmer temperature in summer than in winter.Particle-attached microorganisms were more diverse than free-living communities,possibly because of higher nutrient levels and heterogeneous geochemical micro-environments in particles.Spatial variations in bacterial community structure were observed,i.e..the water reservoir behind the TGD(upstream) hosted more diverse bacterial populations than in front of the dam(downstream),because of diverse sources of sediments and waters from upstream to the reservoir.These results have important implications for our understanding of responses of microbial communities to environmental changes in river ecosystems affected by dam construction.     

http://www.sciencedirect.com/science/article/pii/S1674987112000072

The Abor volcanics outcroping in the core of the Siang window in the Eastern Himalaya comprise voluminous mafic volcanics (47％-56％ w(SiO2)),with subordinate felsic volcanics (67％-75％ w(SiO2)).The felsi...     

http://www.sciencedirect.com/science/article/pii/S1674987111000764

The Jinding Zn-Pb deposit has been generally considered to have formed from circulating basinal fluids in a relatively passive way,with fluid flow being controlled by structures and sedimentary facies,similar to many other sediments-hosted base metal deposits.However,several recent studies have revealed the presence of sand injection structures,intrusive breccias,and hydraulic fractures in the open pit of the Jinding deposit and suggested that the deposit was formed from explosive release of overpres-sured fluids.This study reports new observations of fluid overpressure-related structures from underground workings(Paomaping and Fengzishan).which show clearer crosscutting relationships than in the open pit.The observed structures include:I) sand(±rock fragment) dikes injecting into fractures in solidified rocks:2) sand(±rock fragment) bodies intruding into unconsolidated or semi-consolidated sediments;3) disintegrated semi-consolidated sand bodies;and 4) veins and breccias formed from hydraulic fracturing of solidified rocks followed by cementation of hydrothermal minerals.The development of ore minerals(sphalerite) in the cement of the various clastic injection and hydraulic fractures indicate that these structures were formed at the same time as mineralization.The development of hydraulic fractures and breccias with random orientation indicates small differential stress during mineralization,which is different from the stress field with strong horizontal shortening prior to mineralization. Fluid flow velocity may have been up to more than 11 m/s based on calculations from the size of the fragments in the clastic dikes.The clastic injection and hydraulic fracturing structures are interpreted to have formed from explosive release of overpressured fluids,which may have been related to either magmatic intrusions at depth or seismic activities that episodically tapped an overpressured fluid reservoir.Because the clastic injection and hydraulic structures are genetically linked with the mineralizing fluid source,they can be used as a guide for mineral exploration.     

http://www.sciencedirect.com/science/article/pii/S1674987112000679

Quasi-integrity of continental crust between Mid-Archaean and Ediacaran times is demonstrated by conformity of palaeomagnetic poles to near-static positions between～2.7-2.2 Ca,～1.5-1.2 Ga and～0.75-0.6 Ga.Intervening data accord to coherent APW loops turning at "hairpins" focused near a continental-centric location.Although peripheral adjustments occurred during Early Proterozoic （～2.2 Ga） and Grenville（～1.1 Ga） times,the crust retained a low order symmetrical crescent-shaped form constrained to a single global hemisphere until break-up in Ediacaran times.Conformity of palaeomagnetic data to specific Eulerian parameters enables definition of a master Precambrian APW path used to estimate the root mean square velocity(v_RMS) of continental crust between 2.8 and 0.6 Ga.A long interval of little polar movement between～2.7 and 2.2 Ga correlates with global magmatic shutdown between～2.45 and 2.2 Ga,whilst this interval and later slowdown at～0.75-0.6 Ga to velocities of <2 cm/year correlate with episodes of widespread glaciation implying that these prolonged climatic anomalies had an internal origin;the reduced input of volcanically-derived atmospheric greenhouse gases is inferred to have permitted freeze-over conditions with active ice sheets extending into equatorial latitudes as established by low magnetic inclinations in glaciogenic deposits.v_RMS variations through Precambrian times correspond to the distribution of U-Pb ages in orogenic granitoids and detrital zircons and demonstrate that mobility of continental crust has been closely related to crustal tectonism and incrementation.Both periods of near-stillstand were followed by rapid v_RMS recording massive heat release from beneath the continental lid at～2.2 and 0.6 Ga.The first coincided with the Lomagundi-Jatuli isotopic event and led to prolonged orogenesis accompanied by continental flooding and reconfiguration of the crust on the Earth’s surface;the second led to continental break-up and instigated the comprehensive Plate Tectonics that has characterised Phanerozoic times.The Mesoproterozoic interval characterised by anorogenic magmatism correlates with low v_RMS between～1.5 and 1.1 Ga.Insulation of the sub-continental mantle evidently permitted high temperature melting and weakening of the crustal lid to enable buoyant emplacement of large plutons at high crustal levels during this magmatic event unique to Mesoproterozoic and early Neoproterozoic times.     

A review of the ～1600 Ma sedimentation, volcanism, and tectono-thermal events in the Singhbhum craton, Eastern India

The Palaeoproterozoic–Mesoproterozoic transition (～1600 Ma) is a significant event in the Earth history as a global thermal perturbation affected the pre-1600 Ma landmasses. Like other cratonic blocks of the world, lithospheric thinning, sedimentation, magmatism, metamorphism and crustal melting/anatexis are associated with this significant geological event in the Singhbhum cratonic province of India. This paper is a review of sedimentological, magmatic and tectono-thermal events in the Singhbhum craton at ～1600 Ma. The Palaeo-Mesoproterozoic sedimentation and volcanism in the Singhbhum craton took place in a terrestrial intracontinental rift setting. The available geochronological data are indicative of late Palaeoproterozoic to Neoproterozoic tectono-thermal events in the Chhotanagpur Granite Gneissic Complex (CGGC), an east–west trending arcuate belt of granite gneisses, migmatites and metasedimentary rocks. A detailed multidisciplinary geo-scientific investigation of the Dalma volcanic belt and the area to its north (Chandil Formation) and further north in CGGC will enable us to constrain the extant surface processes and crust-mantle interactions, the collision events between the North and South Indian cratonic blocks, and the position of India in the Columbia supercontinent.     

http://www.sciencedirect.com/science/article/pii/S1674987111000545

By applying the ’theory of synchronization’ from the science of complexity to studying the regional regularity of ore formation within the Nanling region of southern China,a characteristic target-pattern regional ore zonality has been discovered.During the early and late Yanshanian epoch(corresponding respectively to the Jurassic and Cretaceous periods),two centers of ore formation emerged successively in the Nanling region;the former is mainly for rare metals(W,Sn,Mo,Bi,Nb) and one rare-earth element (La) and was generated in the Jurassic period;whereas the latter is mainly for base metals(Cu,Pb,Zn,Sb, Hg),noble metals(Au,Ag),and one radioactive element(U) and was generated in the Cretaceous period. Centers of ore formation were brought about by interface dynamics respectively at the Qitianling and Jiuyishan districts in southern Hunan Province.The characteristic giant nonlinear target-pattern regional ore zonality was generated by spatio-temporal synchronization process of the Nanling complex metallo-genic system.It induced the collective dynamics and cooperative behavior of the system and displayed the configuration of the regional ore zonality.Then dynamical clustering transformed the configuration into rudimentary ordered coherent structures.Phase dynamics eventually defined the spatio-temporal structures of the target-pattern regional ore zonality and determined their localization and distribution.A new methodology for revealing regional ore zonality is developed,which will encourage further investigation of the formation of deep-seated ore resources and the onset of large-scale mineralization.     

http://www.sciencedirect.com/science/article/pii/S1674987114000413

Braid-delta depositional systems are widely developed in most continental basins in China. Research indicates that, for different types of braid delta, the facies sequence and association, which are cr...     

http://www.sciencedirect.com/science/article/pii/S1674987114000401

In this paper, a new discrimination diagram using absolute measures of Th and Nb is applied to post-Archean ophiolites to best discriminate a large number of different ophiolitic basalts. This diagram ...     

Detrital and authigenic(?) baddeleyite (ZrO2) in ferromanganese nodules of Central Indian Ocean Basin

Occurrence of baddeleyite (ZrO2) which is a rare mineral has been recorded in ferromanganese nodules of Central Indian Ocean Basin (CIOB). The mineral occurs either as independent isolated sub-rounded to elliptical grains or in clusters forming fine subhedral crystals (<3 mm) within ferromanganese concretionary growth bands. The mode of occurrence, textural features and chemistry of the mineral suggest detrital and possibly an authigenic origin for baddeleyite. For authigenic origin it is proposed that zirconium might have got released either from the terrigenous sediments or the altered seafloor rocks forming halogen complexes and subsequently it has re-precipitated in the form of baddeleyite within manganese nodules under oxic to sub-oxic conditions.     

http://www.sciencedirect.com/science/article/pii/S1674987111001046

The role played by Paleoproterozoic cratons in southern South America from the Mesoproterozoic to the Early Cambrian is reconsidered here.This period involved protracted continental amalgamation that led to formation of the supercontinent Rodinia.followed by Neoproterozoic continental break-up,with the consequent opening of Clymene and Iapetus oceans,and finally continental re-assembly as Gondwana through complex oblique collisions in the Late Neoproterozoic to Early Cambrian.The evidence for this is based mainly on a combination of precise U-Pb SHRMP dating and radiogenic isotope data for igneous and metamorphic rocks from a large area extending from the Rio de la Plata craton in the east to the Argentine Precordillera in the west and as far north as Arequipa in Peru.Our interpretation of the paleogeographical and geodynamic evolution invokes a hypothetical Paleoproterozoic block(MARA) embracing basement ultimately older than 1.7 Ga in the Western Sierras Pampeanas(Argentina),the Arequipa block(Peru),the Rio Apa block(Brazil),and probably also the Paraguaia block(Bolivia).     

http://www.sciencedirect.com/science/article/pii/S1674987110000058

<正>The thermo-electric coefficients of twenty-six magnetite samples,formed either by magmatism or metamorphism,were tested by the thermo-electric instrument BHET—06.Results showed that the coefficient is of a constant value of about -0.05 mV/℃.It is emphasized that because every magnetite grain was tested randomly,the coefficient is independent of the crystallographic direction.This fact means the thermal voltage generated from a single magnetite crystal can be accumulated,and as a result a new thermo-electric field can arise when a gradient thermal field exists and is active within the earth's crust.Because magnetite is widespread in the earth's crust(generally appearing more in the middle-lower crust),there is more-than-random probability that the additional thermo-electric field can be generated when certain thermal conditions are fulfilled.We,therefore,used the thermo-electric effect of magnetite to study the mechanism responsible for the presence of abnormal geo-electric fields during earthquake formation and occurrence, because gradient thermal fields always exist before earthquakes.The possible presence of additional thermo-electric fields was calculated under theoretical seismological conditions,using the following calcu-lation formula:E= - 0.159(σ×△T×φ×ρ_2×[(h~2-2x~2)cosα+ 3hxsinα]/ρ_1(h~2 +x~2)~(5/2)).In the above formula,σis thermo-electric coefficient of magnetite,△T is the temperature difference acting on it,φis a sectional area on a block of magnetite vertically perpendicular to the direction of the thermal current.ρ_1 andρ_2 are the respective resistivities of magnetite and the crust,and h,α,and x,respectively,h is the depth of embedded magnetite block,αmeans the angle created by the horizontal line and ligature of the two poles of magnetite block,and x is the distance from observation point to projective center point of the magnetite block on earth surface.According to simulations calculated with this formula,additional thermo-electric field intensity may reach as high as n to n×10~2 mV/km.This field is strong enough to cause obvious anomalies in the background geo-electric field,and can be easy probed by earthquake monitoring equipment. Therefore,we hypothesize that geo-electric abnormalities which occur during earthquakes may be caused by the thermo-electric effect of magnetite.     

http://www.sciencedirect.com/science/article/pii/S1674987114000267

Habitable Trinity is a newly proposed concept of a habitable environment.This concept indicates that the coexistence of an atmosphere(consisting largely of C and N),an ocean(H and O).and a landmass(supplier of nutrients) accompanying continuous material circulation between these three components driven by the Sun is one of the minimum requirements for life to emerge and evolve.The life body consists of C,0,H,N and other various nutrients,and therefore,the presence of water,only,is not a sufficient condition.Habitable Trinity environment must be maintained to supply necessary components for life body.Our Habitable Trinity concept can also be applied to other planets and moons such as Mars,Europa,Titan,and even exoplanets as a useful index in the quest for life-containing planetary bodies.     

http://www.sciencedirect.com/science/article/pii/S1674987114000565

During granulite-facies metamorphism of metasedimentary rocks by the infiltration of carbonic fluids, the disappearance of hydrated minerals leads to the liberation of aqueous fluids. These fluids are strongly enriched in F and C1, and a series of Large-lon-Lithophile （LIL） elements and rare metals, resulting in their depletion in granulites. To sum up the fate of these elements, we focus on three domains representing different crustal levels and showing distinct behaviours with respect to these elements. The Lapland metasedimentary granulites illustrate the behaviour of the LILE and rare metals during lower crustal metamorphism. There is no change in Ba, moderate loss in Rb, and extreme depletion in Cs, Li, and Sn. F and CI contents are also very low compared to the protoliths or average upper continental crust. Biotite and amphibole breakdown leads to the incorporation of their partitioning into a fluid or a melt. The Tranomaro metasomatized marbles recrystallizing under granulite-facies conditions represent a demonstrative example of fluid transfer from granulite-facies supracrustals to traps represented by regional scale skarns. Such fluids may be at the origin of the incompatible element enrichment detected in leucosomes of migmatites from St Malo in Brittany （France） and Black Hills in South Dakota, The northern French Massif Central provides us with an example of a potential association between incompatible element enrichment of granitic melts and granulite-facies metamorphism. U- and F- enriched fine-grained granites are emplaced along a crustal scale shear zone active during the emplacement within the St Sylvestre peraluminous leucogranitic complex, We propose that during granulite-facies metamorphism dominated by carbonic waves in a deep segment of the continental crust, these shear zones control： （i） the percolation of F-, LILE-, rare metal-rich fluids liberated primarily by the breakdown of biotite; （ii） the enhancement of partial melting by F-rich fluids at intermediate crustal lev