细粒子气溶胶光学厚度和谱分布偏振的反演

 细粒子气溶胶物理和光学参数定量卫星遥感反演一直是环境和气候领域研究人员关注的重要课题。气溶胶参数卫星业务遥感产品主要是反演气溶胶光学厚度,它体现大气中气溶胶总含量的信息,而获取气溶胶谱分布函数有助于进一步了解气溶胶物理特性,并提高气溶胶其他参数的遥感探测精度。目前,陆地气溶胶卫星反演面临两个关键问题:一是气溶胶模式;二是地表反射贡献的去除,偏振遥感在这两方面有其独有的优势。本文以多角度偏振方法,采用RT3辐射传输模型建立矢量查找表,利用法国PARASOL探测器一级数据反演了京津唐地区的细粒子气溶胶光学厚度和谱分布参数,并使用AERONET地基观测数据对反演结果进行验证,结果表明:偏振方法能较高精度地实现细粒子气溶胶光学厚度反演,而谱分布的反演还需进一步改进。     

大气气溶胶光学特性与遥感图像光谱相关性分析

大气气溶胶对气候变化有重要的影响,由于观测资料缺乏,遥感成为越来越重要的研究手段。通过对气溶胶粒子的散射和反射特性分析表明,气溶胶的光学特性因气溶胶的成分和入射光波长的不同而不同,利用这些光谱差异,可以通过遥感方法进行光学厚度的反演,进而研究气溶胶的运动及分布、气候效应等特征。气溶胶中不同的粒子尺度及组成使其散射光学特性有较大的差异,2.1μm(或2.2μm)波段处的光谱反射率受尘粒气溶胶的影响较大;气溶胶具有时空变异特征;气溶胶在大气层上界(TDA)的辐射强迫表现为正效应,在单粒子反射率(SSA)的某一区间,其净效应因云状大小、表面反射率以及垂直气溶胶和云的分布的变化而变化,它通过影响云的凝聚核和半向效应而具有间接辐射强迫效应,另外它与臭氧的含量具有密切关系;在气溶胶信息的获取中,太阳光度计观测是一种重要手段,遥感正成为研究气溶胶越来越重要的途径。     

现行POLDER陆地气溶胶偏振反演算法对粒子尺度的敏感性分析

目前,偏振遥感已被用于气溶胶卫星和地基遥感中,其仅对小粒子敏感。本研究以2007-2008年间的POLDER(Polarization and Directionality of the Earth’s Reflectances)和AERONET(Aerosol Robotic Network)合肥站的气溶胶数据为研究对象,探讨了偏振遥感对气溶胶粒子尺度的敏感性。利用AERONET合肥站的尺度分布数据和折射指数数据,计算了不同尺度范围内气溶胶粒子的光学厚度,并与对应的POLDER反演结果作拟合,通过寻找最佳拟合对应的尺度范围确定偏振遥感敏感的粒子尺度。结果表明,偏振遥感并非对所有尺度的小模式气溶胶粒子都敏感,在865 nm波段,其敏感的气溶胶粒子上限半径约为0.3 μm左右。这一结果对指导气溶胶偏振遥感,以及理解和应用偏振遥感气溶胶产品等具有重要意义。     

厦门市林地与建设用地对大气气溶胶空间分布的影响分析

分析大气气溶胶空间分布的影响因素有助于理解其变化机制与规律,从而为大气环境质量的调控提供科学依据。本文以厦门市为例,利用MODIS-Aqua卫星遥感影像,反演了大气气溶胶光学厚度。同时,选取Landsat8 OLI卫星数据,进行土地覆被分类。在此基础上,利用相关分析、一元线性回归模型和方差分解,对比研究了城市林地和建设用地对大气气溶胶空间分布的影响作用,得出以下结论：① 暗像元与插值法的结合适合厦门地区春季气溶胶光学厚度的反演;② 建设用地上空气溶胶光学厚度值明显高于林地;③ 林地对气溶胶空间分布的影响作用强于建设用地。本研究对缓解城市大气污染和改善城市生态环境具有重要参考价值和意义。     

区域优化Peterson模型的气溶胶光学厚度估算分析

气溶胶光学厚度作为描述气溶胶光学特性的重要参数之一, 被广泛应用于空气质量监测及辐射传输模型的大气订正等研究中。卫星遥感可快速反演获取大范围气溶胶信息, 但其产品通常因云覆盖或暗目标算法等原因而存在空间覆盖率较低的问题, 且产品时相受限于卫星过境时间。水平能见度作为描述气溶胶光学特性的另一重要参数, 由分布广泛的气象台站一日8 次固定时间多次发布。建立水平能见度与气溶胶光学厚度的转换关系, 可实现对卫星反演气溶胶光学厚度的有益补充。本文利用2001-2009 年的MODIS气溶胶光学厚度产品与中国华东地区71 个气象台站的水平能见度数据, 对描述两者转换关系的Peterson 模型进行区域优化。采用分区域高斯曲线拟合的方法, 对影响转换精度的主要参数气溶胶标高随时间变化规律开展研究和模拟。利用2010 年数据对优化模型进行精度及区域适用性验证。结果表明, 优化后模型的气溶胶光学厚度估算均方根误差为0.31, 低于原模型误差;精度基本上与单站点优化模型一致, 但在实用性方面优于单站点优化模型。     

城市气溶胶光学厚度空间格局特征多指标综合分析

本文以厦门市为例,基于MODIS影像反演的大气气溶胶光学厚度（AOD）,利用空间自相关和景观格局指数从数量、形态和结构方面综合分析了2014年各月份（5月和9月除外）AOD时空格局变化。结果表明,研究区AOD具有明显的时空分布差异,林地上空的AOD处于较低等级,建设用地上空AOD大部分处于中高等级;AOD在春夏季较大,在秋冬季较小。AOD分布存在显著正空间自相关性,而且主要存在高高（HH）、低低（LL）、高低（HL）3种聚集模式。低低聚集模式主要分布在厦门市的北部山区;高高（HH）和高低（HL）模式主要分布在本岛东北部新城和本岛外各新城的城区。在景观格局指数方面,从秋冬季节到春夏季节期间,研究区气溶胶光学厚度高等级斑块增加,景观结构趋于复杂,景观异质性增加。对AOD时空格局变化进行多指标综合分析可以更加深入、细致、全面地刻画气溶胶的变化规律,有助于精确评估气溶胶对环境、气候等的影响,为城市可持续发展提供决策支持。     

基于MODIS数据的气溶胶光学厚度反演

气溶胶在大气污染事件中扮演重要角色。光学厚度作为大气气溶胶的一个重要光学属性,常作为其他相关科学研究的重要参数。本文以ENVI5.0为平台,利用经典的暗像元算法,对2011年8月5日北京地区的MODIS卫星遥感影像数据进行了气溶胶光学厚度(AOD)反演,并对其空间分布进行了分析,为环境监测部门提供了大气污染治理依据。     

一种基于FY3D/MERSI2的AOD遥感反演方法

针对目前国产卫星对气溶胶遥感监测应用较少的情况,本研究综合暗象元和SARA算法优势,基于FY-3D MERSI2数据构建了一套气溶胶光学厚度(Aerial Optical Depth, AOD)快速遥感反演方法。首先,引入了传统暗象元算法中的地表反射率经验关系,然后利用AERONET长时间序列的地基观测数据,构建了红波段和蓝波段气溶胶光学厚度、不对称因子和单次散射率之间的关系,最后利用MOD04和AERONET的AOD产品对研究反演结果进行了验证和评估分析。结果发现：① 本研究反演的AOD不仅保持了与MODIS的气溶胶产品空间分布的一致性,而且合理地呈现了AOD的高值分布,改进了MOD04气溶胶产品在云和亮目标方面反演缺失问题;② 利用AERONET地基观测结果对本研究获取的MERSI2的AOD反演结果进行了对比分析,发现二者具有较高的线性相关性,蓝波段AOD线性相关系数超过0.85;③ 利用MERSI2数据完整地捕捉到了2018年3月9—14日京津冀及周边区域的一次重污染过程中气溶胶时空分布变化情况,这也说明了FY3D卫星具备良好的气溶胶遥感监测能力,为我国灰霾监测和预警提供参考依据。本研究对大力发展国产卫星在大气环境遥感的应用有重要参考意义。     

温度对平流层气溶胶光学常数及辐射特性的影响

本文阐述平流层气溶胶的光学常数在不同温度下取值时,用Mie散射理论对不同浓度的平流层气溶胶红外波段的辐射特性进行的计算和分析。分析结果表明:在卫星遥感中,由温度引起的平流层气溶胶光学常数的变化对某些红外波段的平流层气溶胶辐射特性的影响是不容忽视的。     

硫酸盐气溶胶对长江中下游夏季降水年代际转型的影响

为了研究人为硫酸盐气溶胶增长对1970年代末长江中下游夏季降水年代际转型的影响,使用全球气候模式（GFDL—AM2）,对硫酸盐直接气候效应进行了模拟。结果表明,硫酸盐气溶胶增长引起的降水年代际变化与观测到的降水转型有很好的时空一致性;观测中包括副热带高压西伸南移、中国东部近地面异常北风等夏季风年代际减弱信号以及对应的垂直温度、上升运动分布等均能很好地被模式再现。机制上,硫酸盐气溶胶通过引起负辐射强迫,造成中国中东部的大部分地区地面到对流层中层降温,海陆热力对比减小,使东亚夏季风减弱,雨带容易在长江中下游停留,从而导致该区域降水增多。于是,硫酸盐气溶胶增多对长江中下游降水年代际转型有重要贡献。     

基于MODIS数据的北京气溶胶类型特性与影响因素分析

应用北京城区2001-2007年间的MODIS气溶胶产品及辅助气象数据,分析了北京气溶胶类型特性及其变化趋势,以及风速、降水与气温等气候条件对其的影响。根据AOT550-FM关系模型,将北京气溶胶分成城市/工业型(UI),沙尘型(DD),干净海洋型(CM)和混合型(MT)4种类型,并在此基础上,结合辅助气象数据,分析了气候对总体气溶胶和各类型气溶胶的影响。研究表明,受风向、气温、降水等气候因素影响,北京气溶胶在5月取得最大值,北京气溶胶的主要类型为沙尘型气溶胶(DD)和混合型气溶胶(UI),而主要影响气溶胶为沙尘型气溶胶(DD)和城市/工业型气溶胶(UI)。在2001-2007年间,城市/工业型气溶胶(UI)有较明显的增长,沙尘型气溶胶(DD)则呈现为与地面统计数据相符的下降趋势,总体气溶胶和其他类型气溶胶都处于基本稳定状态,北京大气环境基本稳定。     

Concentrations and Distribution of Trace Metals of PM_(10) and TSP Particles Collected in the Qingdao Area

Aerosol samples of PM10 (particulate matter with aerodynamic diameters less than 10μm) and TSP (total suspended particles) were simultaneously collected from April 2001 to March 2002 at the top of Mount Baguan on the downtown campus of Ocean University of China, Qingdao, China. The concentrations of Al, Fe, Mn, Cu, Pb and Zn were determined by means of inductively coupled plasma atomic emission spectrometry (ICP-AES). The monthly variability of the mass concentrations of aerosol particles and the concentrations of trace metals are presented and discussed. The distribution pattern of these metals in PM10 and TSP is also discussed. During the observation period, the mass concentration of PM10 at this site ranged from 13.80 to 306.42μgm-3 , while that of TSP ranged from 31.02 to 568.82μgm-3. Both PM10 and TSP reached their highest concentrations in springtime, while the lowest values occurred in summertime. The concentrations of crustal metals followed the same variation pattern, while those of anthropo     

Concentrations and distribution of trace metals of PM<Subscript>10</Subscript> and TSP particles collected in the qingdao area

Aerosol samples of PM₁₀ (particulate matter with aerodynamic diameters less than 10μm) and TSP (total suspended particles) were simultaneously collected from April 2001 to March 2002 at the top of Mount Baguan on the downtown campus of Ocean University of China, Qingdao, China. The concentrations of Al, Fe, Mn, Cu, Pb and Zn were determined by means of inductively coupled plasma atomic emission spectrometry (ICP-AES). The monthly variability of the mass concentrations of aerosol particles and the concentrations of trace metals are presented and discussed. The distribution pattern of these metals in PM₁₀ and TSP is also discussed. During the observation period, the mass concentration of PM₁₀ at this site ranged from 13.80 to 306.42 μgm⁻³, while that of TSP ranged from 31.02 to 568.82μgm⁻³. Both PM₁₀ and TSP reached their highest concentrations in springtime, while the lowest values occurred in summertime. The concentrations of crustal metals followed the same variation pattern, while those of anthropogenic metals did not. A closer examination led to the conclusion that anthropogenic metals are mainly from local sources. The average concentration ratios of anthropogenic metals in PM₁₀ to TSP were higher than the average mass ratio of PM₁₀ to TSP, suggesting that there was a higher proportion of anthropogenic metals on smaller particles although there were a few exceptions. For crustal metals, however, the metal concentration ratios were close to the particle mass ratio, indicating that the distribution of crustal metals was much more homogeneous on aerosol particles with different sizes. The correlation analysis indicated that Al, Fe and Mn were originated from similar sources and were mainly controlled by the particle mass, while Cu, Pb and Zn were predominated by local anthropogenic sources, with Pb and Zn having similar origins.     

The Seasonal Variabilities in the Concentration of Atmospheric Aerosols over Qingdao, China

Mass concentrations of Total Suspended Particles （TSP） and size-segregated particles were obtained from July 2001 to June 2002 in Qingdao to characterize the seasonal variations of atmospheric aerosols and to show the impact of dust events on the air quality in Qingdao. Data on size-segregated aerosols show that 73.74% of the TSP mass concentration is contributed by particles with diameters less than 11 μm. Particles with diameters less than 1.1μm have a higher concentration during the winter. In spring, larger particles tend to have higher mass concentrations. Bimodal particle size distributions have been observed, with maxima around 4.7-7 μand 0.43-0.65 μm in the winter season, and 7-11 μm and 0.65-1.1 μm in the autumn season. Measurements made during the dust events in March 2002 show high concentrations of particles in the size range 2.1-7μm.     

Characterization of Dust and Non-dust Aerosols with SEM/EDX

Total suspended particulate （TSP） samples were collected at three sites along the coast of Qingdao, China, before and during a major dust storm in March, 2002. For comparison, PM10（particulate matter with aerodynamic diameters less than 10μm） samples were collected at one of the three sites. The morphological observation and compositional analysis of bulk and individual particles were performed by using scanning electron microscopy equipped with an energy dispersive X-ray system （SEM/EDX） for the TSP and PM10 samples. The results showed that the particles of different kinds of morphology had different elemental compositions, but the particles of similar morphology did not always have the same elemental composition for non-dust samples. The morphology and composition of non-dust particles were different at different sites. The fractal and spherical particles existed mainly in the coarse fraction for non-dust samples, while in the fine mode （〈 10μm） there were floccules formed by fine particles flocking together and containing crustal elements. Compared with the non-dust particles, the dust particles were more homogeneous in terms of morphology, particle size and composition. Particles with irregular shapes and well-distributed sizes dominated in the dust samples, containing crustal elements such as Mg, A1, Si, Ca, Fe, etc. The high sulfur content indicated that homogeneous and heterogeneous reactions took place on the surfaces of the dust particles in the specific environment of Qingdao.