钼矿石物相的快速分析方法

钼矿石的主要矿物有辉钼矿,其次是钼钨钙矿、铁钼华矿、钼华矿和钼酸铅矿。样品经碱熔融分解,硫氰酸盐比色法测定总钼;利用电感耦合等离子体质谱法测定氢氧化铵溶解钼华中的钼;酒石酸溶解钼钨钙矿中的钼;碳酸钠溶解钼酸铅矿中的钼;盐酸溶解铁钼华矿中的钼。方法对不同钼矿石样品进行了5种钼矿石物相分析,结果与实际地质成矿组分符合。     

我国首次发现的多水钼铀矿

多水钼铀矿属铀酰钼酸盐类矿物。我国首次发现的多水钼铀矿产于北方某火山岩型铀钼矿床的氧化带，为非晶质矿物，在显微镜下呈均质性，电子探针分析既含铀又含钼等是其主要特征。     

460铀钼矿床综合回收初步研究

460铀钼矿床综合回收是采用铀钼矿样和钼矿样分别浸出→固液分离→两种浸出液混合→萃取和反萃取铀钼→分别精制铀钼产品的水冶工艺流程。铀钼矿的铀钼浸出率分别达到90%和75%以上,钼矿样钼的浸出率达70%以上,取得了稳定的工艺参数;铀钼分离取得了较好的结果,制出了合格的铀、钼产品。     

极谱法测定钼矿石中的总钼氧化钼硫化钼

钼的物相分析要求测定硫化矿物相和氧化矿物相,常用比色法和电感耦合等离子体发射光谱法等对辉钼矿、钼华矿、钼钨钙矿、钼酸铅矿等钼矿石进行物相分析,但分离物相的品种较多,方法繁琐耗时.本文用王水-硫酸消解钼矿石样品,碱溶液复溶浸提得到钼总量,使其他大多数元素形成沉淀而分离,用碳酸钠-氢氧化铵混合溶液浸取钼的氧化矿物,将残渣进一步溶解得到硫化矿物含量,在硫酸-氯酸钾-二苯羟乙酸体系中用极谱法简单快速测定钼总量、氧化钼和硫化钼含量.方法的线性范围为0.04～0.4 mg/L,检出限为0.028 mg/L.对三种钼矿样品进行物相分析,氧化矿物与硫化矿物含量的加和与钼总量相当;总钼、氧化钼、硫化钼测定结果的相对标准偏差在1.69％ ～3.56％之间,与比色法测定结果相符.方法实用快速,易于推广,适于实际批量样品的测试.     

中国钼矿床的时空分布及成矿背景分析

我国钼资源十分丰富,目前已发现钼矿床四百余个,它们具有成带分布的特点。本文在钼矿床地质特征基础上,系统总结了钼矿床和含钼矿床的成矿年代(依据辉钼矿Re-Os年龄),结果显示我国钼矿床空间上可分为东秦岭-大别、兴-蒙、长江中下游、华南、青藏和天山-北山六大钼成矿带;成矿时代上,钼成矿作用分为古元古代(1882~1804Ma)、早古生代(480~420Ma)、晚古生代(412~260Ma)、中生代印支期(251~209Ma)、中生代燕山期(194~77Ma)和新生代(65~13Ma)等六个阶段,主要集中于中生代和新生代。元古宙形成的钼矿床分布于东秦岭-大别钼成矿带,古生代钼矿床主要分布于天山-北山钼成矿带,中生代钼矿床在中国东部广泛分布,新生代钼矿床全都分布于青藏钼成矿带。我国古元古代钼矿床(1882~1804Ma)形成于古陆块之间俯冲碰撞背景下的岛弧环境(东秦岭-大别);早古生代钼矿床(480~420Ma)形成于不同构造单元由挤压向伸展转换的岛弧或陆缘弧环境(东秦岭-大别、兴-蒙和华南);晚古生代钼矿床(412~260Ma)形成于古亚洲洋壳俯冲的岛弧环境(兴-蒙);中生代印支期钼矿床(251~209Ma)形成于板块碰撞及后碰撞背景(东秦岭-大别、兴-蒙和天山-北山)或洋壳俯冲的背景(青藏);燕山期钼矿床形成于古太平洋板块俯冲转向及其后伸展体制下岩石圈减薄拆沉环境(东秦岭-大别、兴-蒙、长江中下游和华南),燕山晚期钼矿床(85~77Ma)形成于碰撞后的伸展背景(青藏);新生代(65~13Ma)钼矿床形成于印度板块与欧亚板块陆陆碰撞及其后的伸展背景(青藏)。我国钼成矿作用受到了环太平洋构造带(东秦岭-大别、兴-蒙、长江中下游和华南)、中亚造山带(天山-北山、兴-蒙)和特提斯构造带(青藏)三大构造体制的影响。     

镇江谏壁钼矿床钼的迁移成矿机理初探

通过对有关钼配合物的形成条件、物理化学性质的考察、碳酸盐、CO2与CO、碳氢化物的相关性以及有关矿床的矿物流体包裹体液相、气相化学成分等的研究，结合镇江谏壁钼矿床成矿的地质背景、矿床特征、钼矿物的共生、伴生矿物组合等的实际情况，认识到镇江谏壁钼矿中钼是呈易挥发的羰基配合物从地球深部迁移至地壳浅部，在有利部位被氧化、硫化沉淀富集成矿。     

闽东地区钼矿床控矿因素与成矿模式探讨

通过对闽东地区地质背景、地球化学特征、主要钼矿床地质特征的阐述,重点剖析了钼矿床的控矿因素,探讨其成因,尝试性总结区内钼成矿模式,为今后在该地区寻找同类型的钼矿床提供找矿思路和借鉴。     

河南省钼矿床的分布规律及其控矿地质因素探讨

通过对河南省钼矿床的分布规律和控矿地质因素的分析,总结出如下认识:(1)河南省钼矿床属东秦岭—大别山钼成矿带的一部分;(2)在地槽活动带的边缘区的构造-岩浆岩带是钼矿床产出的有利场所;(3)成矿母岩是主要控矿因素,同时也是最重要的找矿标志;(4)区域上巨大的燕山期花岗岩基是成钼小岩体的母岩,而成钼小岩体又是钼矿床的成矿母岩,三者在空间分布上具有高度的一致性。     

斑岩型钼矿床的形成机制与地球化学过程

斑岩型钼矿床是世界钼矿床中最重要的种类,其中90%以上的钼矿床都和斑岩有关。斑岩型钼矿床主要分布于环太平洋成矿带和特提斯成矿带上,主要与板块俯冲过程有关,可以分为斑岩铜钼矿床、高氟型斑岩钼矿床和低氟型斑岩钼矿床。我们通过对全球斑岩型钼矿床的时空分布与钼元素地球化学性质分析,认为斑岩型钼矿床的物质来源是钼元素通过表生地球化学作用进行初始富集后形成的富钼沉积物。新元古代晚期(750～542Ma)大气氧再次升高之后,富钼的黑色页岩等才大量出现,因此斑岩型钼矿床主要形成于500Ma之后。富钼黑色页岩等沉积物在板块俯冲过程中脱水,形成富含Mo和Re的变质流体,同时两者发生分异。这种变质流体交代上覆地幔楔使Mo和Re留存在其中。随着俯冲洋壳的部分熔融,形成富Cu(Au)的岩浆,穿过富含Re(Mo)的上覆地幔楔,形成斑岩型铜钼矿床,因此这类矿床的辉钼矿Re含量更高。而随后出现的板块后撤,使软流圈上涌,板片上大量多硅白云母分解,形成了富含F的岩浆,穿过富含Mo的上覆地幔楔,进而形成高氟型斑岩矿床。低氟型钼矿床很可能与俯冲关系较小,富钼沉积物通过造山过程被深埋,在适当的条件下形成低氟型斑岩钼矿床。     

黑龙江翠宏山铁钼多金属矿田两期钼成矿事件厘定

黑龙江省翠宏山铁钼多金属矿田属于小兴安岭-张广才岭铁多金属成矿带,发育铁、铅、锌、钼、钨等多金属大规模成矿作用.尤以钼矿化最具特色,出现矽卡岩-斑岩型钼钨矿化、斑岩型钼矿化和隐爆角砾岩型钼矿化等多种类型的钼矿化在单一矿田中并存的现象.但三种钼矿化类型的矿化特征和时空关系等缺乏系统梳理,钼成矿事件尚未清晰厘定.选取该矿田...     

Définition d'une limite multicritère ; stratigraphie du passage Campanien–Maastrichtien du site géologique de Tercis (Landes,SW France)Definition of a multi-criteria boundary; stratigraphy of the Campanian–Maastrichtian interval of the geological site at Tercis (Landes,SW France)

Lithostratigraphy, physicochemical stratigraphy, biostratigraphy, and geochronology of the 77–70 Ma old series bracketing the Campanian–Maastrichtian boundary have been investigated by 70 experts. For the first time, direct relationships between macro- and microfossils have been established, as well as direct and indirect relationships between chemo-physical and biostratigraphical tools. A combination of criteria for selecting the boundary level, duration estimates, uncertainties on durations and on the location of biohorizons have been considered; new chronostratigraphic units are proposed. The geological site at Tercis is accepted by the Commission on Stratigraphy as the international reference for the stratigraphy of the studied interval. To cite this article: G.S. Odin, C. R. Geoscience 334 (2002) 409–414.     

Quaternary stresses revealed by calcite twinning inversion: insights from observations in the Savonnières underground quarry (eastern France)

Calcite samples were extracted both from the rock matrix and the superficial coating of a karstified fault plane of an underground quarry, located in the eastern border of the Paris basin. The karstification is dated as Quaternary. Analysis of mechanical calcite twinning reveals that only the calcite matrix has also undergone a compression trending WNW that can be attributed to the Mio-Pliocene alpine collision. Both coating and matrix have undergone a strike-slip regime with σ₁ roughly trending north–south, that could correspond to the regional present-day state of stress, a strike-slip compression rather trending NNW, modified by local phenomena. To cite this article: M. Rocher et al., C. R. Geoscience 335 (2003).     

HYDROGEOLOGY

正20141756 Chen Ruige(Mathematical College,China University of Geosciences,Beijing100083,China);Zhou Xun Numerical Simulation of Groundwater Level Fluctuation in a Coastal Confined Aquifer with Sloping Initial Groundwater Level Induced by the Tide(Geological Bulletin of China,ISSN1671-2552,CN11-4648/P,32(7),2013,p.1099-1104,6 illus.,16 refs.) Key words:confined water,groundwater level     

METAMORPHIC PETROLOGY

正20141408 Cai Jia(Institute of Geology,Chinese Academy of Geological Sciences,Beijing100037,China);Liu Fulai Petrogenesis and Metamorphic P-T Conditions of Garnet-Spinel-Biotitebearing Paragneiss in Danangou Area,Daqingshan-Wulashan Metamorphic Complex Belt(Acta Petrologica Sinica,ISSN1000-0569,CN11-1922/P,29(7),     

SERIALS

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GEOPHYSICAL EXPLORATION

正20142386An Guoying(China Aero Geophysical Survey and Remote Sensing Center for Land and Resources,Beijing 100083,China)Application of Satellite Remote Sensing in Regional Hydrogeological Investigation:Taking Cenozoic Strata in Wenquan Sheet(1∶250 000)of Karakoram Range as an Example(Geosci-     

QUATERNARY GEOLOGY & GEOMORPHOLOGY

正20141016An Chengbang(Key Laboratory of Western China’s Environmental Systems,Ministry of Education,Lanzhou University,Lanzhou 730000,China);Zhao Yongtao Lake Records during the Last Glacial Maximum from Xinjiang,NW China and Their Climatic Impli-     

PETROLEUM GEOLOGY

正20141538 Cao Qing(School of Earth Sciences and Engineering,Xi’an Petroleum University,Xi’an 710065,China);Zhao Jingzhou Characteristics and Significance of Fluid Inclusions from Majiagou Formation,Yichuan Huangling Area,Ordos Basin(Advances in Earth Science,ISSN1001-8166,CN62-1091/P,28(7),2013,p.819-828,7 illus.,3 tables,43 refs.)     

GEOCHEMISTRY

正20142002 Wei Hualing(Institute of Geophysical and Geochemical Exploration,Chinese Academy of Geological Sciences,Langfang065000,China);Zhou Guohua Element Content and Mineral Compositions in Different Sizes of Soil in Tongling Area,Anhui Province(Geological Bulletin of China,ISSN1671-2552,CN11-4648/P,32(11),2013,p.1861     

ENGINEERING GEOLOGY

正20141768 An Shaopeng(Institute of Rock and Soil Mechannics,Chinese Academy of Sciences,Wuhan 430071,China);Wei Lide Experimental Study on Mechanical Behavior of Xigeda Formation Siltstone and Structure Interface(Journal of Engineering Geology,ISSN1004-9665,CN11-3249/P,21(5),2013,p.702-708,9illus.,1 table,16 refs.)