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1.
The behavior of rare earth elements (REEs) during hot desert weathering of meteorites is investigated. Ordinary chondrites (OCs) from Atacama (Chile) and Lut (Iran) deserts show different variations in REE composition during this process. Inductively coupled plasma–mass spectrometry (ICP‐MS) data reveal that hot desert OCs tend to show elevated light REE concentrations, relative to OC falls. Chondrites from Atacama are by far the most enriched in REEs and this enrichment is not necessarily related to their degree of weathering. Positive Ce anomaly of fresh chondrites from Atacama and the successive formation of a negative Ce anomaly with the addition of trivalent REEs are similar to the process reported from Antarctic eucrites. In addition to REEs, Sr and Ba also show different concentrations when comparing OCs from different hot deserts. The stability of Atacama surfaces and the associated old terrestrial ages of meteorites from this region give the samples the necessary time to interact with the terrestrial environment and to be chemically modified. Higher REE contents and LREE‐enriched composition are evidence of contamination by terrestrial soil. Despite their low degrees of weathering, special care must be taken into account while working on the REE composition of Atacama meteorites for cosmochemistry applications. In contrast, chondrites from the Lut desert show lower degrees of REE modification, despite significant weathering signed by Sr content. This is explained by the relatively rapid weathering rate of the meteorites occurring in the Lut desert, which hampers the penetration of terrestrial material by forming voluminous Fe oxide/oxyhydroxides shortly after the meteorite fall.  相似文献   

2.
Abstract– We describe the geological, morphological, and climatic setting of the San Juan meteorite collection area in the Central Depression of the Atacama Desert (Chile). Our recovery activities yielded 48 meteorites corresponding to a minimum of 36 different falls within a 3.88 km2 area. The recovery density is in the range 9–12 falls km?2 depending on pairing, making it the densest among meteorite collection areas in hot deserts. This high meteorite concentration is linked to the long‐standing hyperaridity of the area, the stability of the surface pebbles (> Ma), and very low erosion rates of surface pebbles (approximately 30 cm Ma?1 maximum). The San Juan meteorite population is characterized by old terrestrial ages that range from zero to beyond 40 ka, and limited weathering compared with other dense collection areas in hot desert. Chemical weathering in San Juan is slow and mainly controlled by the initial porosity of meteorites. As in the Antarctic and other hot deserts, there is an overabundance of H chondrites and a shortage of LL chondrites compared with the modern falls population, suggesting a recent (< few ka) change in the composition of the meteorite flux to Earth.  相似文献   

3.
In the last 15 years, more than 2700 meteorites have been recovered and officially classified from the Atacama Desert. Although the number of meteorites collected in the Atacama has risen, the physical and climatic properties of the dense collection areas (DCAs) have not been fully characterized. In this article, we compiled the published data of all classified meteorites found in the Atacama Desert to (i) describe the distribution by meteorite groups, (ii) compare the weathering degree of chondrites among different Atacama DCAs and other hot and cold deserts, and (iii) determine the preservation conditions of chondrites in the main Atacama DCAs in relation with the local climatic conditions. The 35 DCAs so far identified in the Atacama Desert are located in three main morphotectonic units: The Coastal Range (CR), Central Depression (CD), and Pre-Andean Range/Basement. A comparison with reported weathering data from other cold and hot deserts indicates that the mean terrestrial weathering of Atacama chondrites (W1–2), displays less alteration than other hot deserts (W2–3) and resembles the weathering distribution of the Antarctic meteorites (W1–2). The highest abundance of Atacama chondrites with low weathering (≤W2) is localized in the CD (78.8%, N = 1435), which is protected from the coastal fog influence and seasonal rainfalls and displays the oldest surfaces in the Atacama Desert. The morphogenetic classification based on present-day temperatures and precipitations of the main Atacama DCAs reveals similar regional/subregional climatic conditions in the most productive areas and a truly productive surface for meteorite recovery between 5% and 58% of the quadrangles formally defined for each Atacama DCA. Our morphogenetic classification lacks consideration of some meteorological parameters such as the coastal fog, so it cannot fully explain the differences in weathering patterns among CR chondrites. Future studies of chondrite preservation in the Atacama DCAs should consider other meteorological variables such as relative humidity, specific humidity, or dew point, in combination with exposure ages of meteorites and its surfaces.  相似文献   

4.
We describe the geological, morphological, and climatic settings of two new meteorite collections from Atacama (Chile). The “El Médano collection” was recovered by systematic on‐foot search in El Médano and Caleta el Cobre dense collection areas and is composed of 213 meteorites before pairing, 142 after pairing. The “private collection” has been recovered by car by three private hunters and consists of 213 meteorites. Similar to other hot desert finds, and contrary to the falls and Antarctica finds, both collections show an overabundance of H chondrites. A recovery density can be calculated only for the El Médano collection and gives 251 and 168 meteorites larger than 10 g km?2, before and after pairing, respectively. It is by far the densest collection area described in hot deserts. The Atacama Desert is known to have been hyperarid for a long period of time and, based on cosmic‐ray exposure ages on the order of 1–10 Ma, to have been stable over a period of time of several million years. Such a high meteorite concentration might be explained invoking either a yet unclear concentration mechanism (possibly related to downslope creeping) or a previously underestimated meteorite flux in previous studies or an average terrestrial age over 2 Myr. This last hypothesis is supported by the high weathering grade of meteorites and by the common terrestrial fragmentation (with fragments scattered over a few meters) of recovered meteorites.  相似文献   

5.
Abstract– Although iron isotopes are increasingly used for meteorites studies, no attempt has been made to evaluate the effect of terrestrial weathering on this isotopic tracer. We have thus conducted a petrographic, chemical, and iron isotopic study of equilibrated ordinary chondrites (OC) recovered from hot Moroccan and Algerian Saharan deserts environment. As previously noticed, we observe that terrestrial desertic weathering is characterized by the oxidation of Fe‐Ni metal (Fe0), sulfide and Fe2+ occurring in olivine and pyroxene. It produces Fe‐oxides and oxyhydroxides that partially replace metal, sulfide grains and also fill fractures. The bulk chemical compositions of the ordinary chondrites studied show a strong Sr and Ba enrichment and a S depletion during weathering. Bulk meteoritic iron isotope compositions are well correlated with the degree of weathering and S, Sr, and Ba contents. Most weathered chondrites display the heaviest isotopic composition, by up to 0.1‰, which is of similar magnitude to the isotopic variations resulting from meteorite parent bodies’ formation and evolution. This is probably due to the release of isotopically light Fe2+ to waters on the Earth’s surface. Hence, when subtle Fe isotopic effects have to be studied in chondrites, meteorites with weathering grade above W2 should be avoided.  相似文献   

6.
Some terrestrial areas have climatic and geomorphologic features that favor the preservation, and therefore, accumulation of meteorites. The Atacama Desert in Chile is among the most important of such areas, known as DCA. This desert is the driest on Earth, one of the most arid, uninhabitable localities with semiarid, arid, and hyper‐arid conditions. The meteorites studied here were collected from within the DCA of San Juan and Pampa de Mejillones, located, respectively, in the Central Depression and the Coastal Range of the Atacama Desert. 57Fe Mössbauer spectroscopy was used for quantitative analysis of the degree of weathering of the meteorites, through the determination of the proportions of the various Fe‐bearing phases and in particular the amount of oxidized iron in terrestrial alteration products. The abundance of ferric ions in weathered chondrites can be related to specific precursor compositions and to the level of terrestrial weathering. The aim of the study was the identification, quantification, and differentiation of the weathering products in the ordinary chondrites found in the San Juan and the Pampa de Mejillones areas of the Atacama Desert. The 57Fe Mössbauer spectroscopy study was complemented by synchrotron radiation X‐ray diffraction and magnetic susceptibility measurements. The results allow a clear differentiation of the rate of weathering in meteorite samples collected from the San Juan versus the Pampa de Mejillones areas of the Atacama Desert.  相似文献   

7.
Abstract— Fifty‐four fragments of ordinary chondrites from 50 finds representing all searched areas in central Oman and all weathering stages were selected to compare the physical, chemical, and mineralogical effect of terrestrial weathering with 14C terrestrial ages. 14C ages range from 2.0 to >49 kyr with a median value of 17.9 kyr. The peak of the age range, which is between 10–20 kyr, falls in an arid climate period. A comparison of the chemical composition of Omani chondrites with literature data for unweathered H and L chondrites demonstrates a strong enrichment in Sr and Ba, and depletion in S during weathering. Water contents in H chondrites increase with terrestrial age, whereas L chondrites show a rapid initial increase followed by nearly constant water content. Correlating Sr, Ba, and H2O with age indicates two absorption trends: i) an initial alteration within the first 20 kyr dominated by H2O uptake, mainly reflecting Fe‐Ni metal alteration, and ii) a second Ba‐and Sr‐dominated stage correlated with slower and less systematic weathering of troilite that starts after H2O reaches ?2 wt%. Sulfur released from troilite partly combines with Ba and Sr to form sulfate minerals. Other parameters correlated with 14C age are degree of weathering, color of powdered meteorites, and the Ni/Fe ratio. Chemical analyses of 145 soils show a high degree of homogeneity over the entire interior Oman Desert, indicating large‐scale mixing by wind. Soil samples collected from beneath meteorite finds typically are enriched in Ni and Co, confirming mobilization from the meteorites. High Cr and Ni concentrations in reference soil samples, which decrease from NE to SW, are due to detrital material from ultramafic rocks of the Oman Mountains.  相似文献   

8.
Abstract— We have measured a surprisingly long terrestrial age of 410,000 ±45,0020,000 yr (410 ±2045ka) for basaltic eucrite Río Cuarto 001 using accelerator mass spectrometry of 26Al, 36Cl, and 41Ca. Though many meteorites are known to have survived for tens or hundreds of ka in Antarctica or hot deserts, the mean annual precipitation of 815 mm in Río Cuarto, Cordoba Province, Argentina, makes the long survival of this meteorite remarkable. We propose two explanations for the exceptional preservation of Río Cuarto 001. First, the meteorite contains only trace amounts of metal, so the weathering and oxidation of metallic Fe, which commonly destroys chondrites, is ineffective in this case. Second, the meteorite was found in a relatively young deflation basin, and may have been exhumed only recently from beneath a protective layer of soil. Insofar as the survival on Earth of Río Cuarto 001 is due to environmental factors, there may be other meteorites with comparably long terrestrial ages still to be discovered in the vicinity.  相似文献   

9.
Abstract— Mössbauer spectroscopy is a very useful tool for identifying ferric iron weathering products in meteorites because of the capability to quantify the relative amounts of ferric iron in them. Mössbauer measurements were made of 33 Antarctic H chondrites (predominately H5) and two paired Antarctic CR chondrites. The primary goals of this study are to determine if Mössbauer spectroscopy can be used to determine which phases are weathering in Antarctic meteorites and if the relative amounts of ferric iron correlate with terrestrial age. Determining which minerals are weathering in ordinary chondrites appears very difficult due to variations in composition for different ordinary chondrites of the same meteorite class and possible problems in preparing homogeneous samples. The analysis of the two paired CR chondrites appears to indicate that metallic iron is predominately weathering to produce ferric iron for this class of meteorite. No correlation is seen between the relative amounts of ferric iron and terrestrial age for ordinary chondrites. One Antarctic H5 chondrite (ALHA77294) with a short 14C age of 135 ± 200 years from the dating of interior carbonate weathering products does have a relatively low amount of ferric iron, which is consistent with this meteorite being exposed on the surface for a relatively short time.  相似文献   

10.
Abstract— A new meteorite find from the Nullarbor Plain in Australia was studied using optical, SEM, and electron microprobe techniques. The meteorite, Nullarbor 018, is an orthodox L6 chondrite that experienced minor-to-moderate alteration of metal during terrestrial weathering (grade A–B to B). During weathering, troilite was preferentially altered, and roughly 20% of the original complement of S in the meteorite was removed. Shock metamorphic effects corresponding to shock stage S4 (or shock facies d) are found, including the presence of some diaplectic feldspar (maskelynite). The meteorite is not obviously paired with other finds from the Nullarbor region, but the possibility that it is paired cannot be excluded.  相似文献   

11.
The common appearance of hygroscopic brine (“sweating”) on ordinary chondrites (OCs) from Oman during storage under room conditions initiated a study on the role of water‐soluble salts on the weathering of OCs. Analyses of leachates from OCs and soils, combined with petrography of alteration features and a 11‐month record of in situ meteorite and soil temperatures, are used to evaluate the role of salts in OC weathering. Main soluble ions in soils are Ca2+, SO42?, HCO3?, Na+, and Cl?, while OC leachates are dominated by Mg2+ (from meteoritic olivine), Ca2+ (from soil), Cl? (from soil), SO42? (from meteoritic troilite and soil), and iron (meteoritic). “Sweating meteorites” mainly contain Mg2+ and Cl?. The median Na/Cl mass ratio of leachates changes from 0.65 in soils to 0.07 in meteorites, indicating the precipitation of a Na‐rich phase or loss of an efflorescent Na‐salt. The total concentrations of water‐soluble ions in bulk OCs ranges from 600 to 9000 μg g?1 (median 2500 μg g?1) as compared to 187–14140 μg g?1 in soils (median 1148 μg g?1). Soil salts dissolved by rain water are soaked up by meteorites by capillary forces. Daily heating (up to 66.3 °C) and cooling of the meteorites cause a pumping effect, resulting in a strong concentration of soluble ions in meteorites over time. The concentrations of water‐soluble ions in meteorites, which are complex mixtures of ions from the soil and from oxidation and hydrolysis of meteoritic material, depend on the degree of weathering and are highest at W3. Input of soil contaminants generally dominates over the ions mobilized from meteorites. Silicate hydrolysis preferentially affects olivine and is enhanced by sulfide oxidation, producing local acidic conditions as evidenced by jarosite. Plagioclase weathering is negligible. After completion of troilite oxidation, the rate of chemical weathering slows down with continuing Ca‐sulfate contamination.  相似文献   

12.
Abstract– The single‐piece iron meteorite Javorje, with a mass of 4920 g, is the heaviest and largest meteorite found in the territory of Slovenia. The meteorite Javorje is a medium octahedrite with kamacite bandwidth of 0.85 ± 0.26 mm. The bulk composition of Ni (7.83 wt%), Co (0.48 wt%) and trace elements Ga (25 μg/g), Ge (47 μg/g), Ir (7.6 μg/g), As (5.8 μg/g), Au (0.47 μg/g), and Pt (13.4 μg/g) indicates that the meteorite Javorje belongs to the chemical group IIIAB. Mineral and bulk chemical compositions are consistent with other reported group IIIAB meteorites. The presence of numerous rhabdites, carlsbergite, sparse troilite, and chromite and abundance of daubréelites are in accordance with low‐Ni and low‐P IIIAB iron meteorites. The severely weathered surface and secondary weathering products in the interior of the meteorite suggest its high terrestrial age.  相似文献   

13.
Hot and cold deserts have been thoroughly searched for meteorites in the past decades, which has led to a large inventory of classified meteorites. H‐ and L‐chondrites are the most abundant meteorites in all collections, and many authors used the H/L ratio as a characteristic parameter in comparing meteorite populations. H/L ratios (after pairing) vary from 0.90 in observed falls up to 1.74 in El Médano (Atacama Desert). In this study, we investigate the H/L ratio of 965 unpaired H‐ and L‐chondrites collected in Oman and compare this population with observed falls and other hot desert collections. We find a mass dependence of the H/L ratio among hot desert finds and identify mechanisms such as fragmentation during weathering and fall that have an impact on the H/L ratio. We employ the Kolmogorov–Smirnov and Mann–Whitney U statistical tests to compare the mass distributions of H‐ and L‐chondrites and to test the relationship between the similarity of mass distributions and the H/L ratio. We conclude that the variations of the H/L ratios observed in various populations are a sampling artifact resulting from secondary effects and observational bias, expressed in differences of the H and L mass distributions which are not observed in falls, and not due to variations in H/L of the meteorite flux. The H/L ratio of 0.90 observed among recent falls is considered as most representative for the overall meteorite flux, at least since the Late Pleistocene.  相似文献   

14.
We describe the geological, geomorphological, and paleoclimatic setting of the Sahara of North Africa in particular, focused on the main meteorite dense collection areas (DCA; Morocco, Algeria, Tunisia, and Libya). We report on the outcome of several meteorite recovery field expeditions in Morocco and Tunisia since 2008, by car and by foot, that applied systematic search methods. The number of meteorites collected is 41 ordinary chondrites and one brachinite. The statistics of unpaired ordinary chondrites indicates that H chondrites are more abundant (21) than L chondrites (12), while LL chondrites are rare (2). Our meteorite density estimates for Tunisia and Morocco are in the order of magnitude of 1 met km?2. An estimate of the total maximum number of meteorites that could be recovered from the Sahara is 780,000 meteorites. We selected 23 meteorites from Aridal, Bou Kra, Bir Zar, and Tieret DCAs for 14C dating. The results show a wide range of terrestrial ages from 0.4 to more than 40 kyr with a majority of meteorites showing ages between 0.4 and 20 kyr. The weathering degree of these meteorites is ranges from minor (W1) to strong (W4). The highest weathering grades result from repeated oscillations between high and low humidity in the Sahara. However, there appears to be no correlation between weathering grade and terrestrial age of meteorites.  相似文献   

15.
The gamma‐ray activities of 33 meteorite samples (30 ordinary chondrites, 1 Mars meteorite, 1 iron, 1 howardite) collected during Omani‐Swiss meteorite search campaigns 2001–2008 were nondestructively measured using an ultralow background gamma‐ray detector. The results provide several types of information: Potassium and thorium concentrations were found to range within typical values for the meteorite types. Similar mean 26Al activities in groups of ordinary chondrites with (1) weathering degrees W0‐1 and low 14C terrestrial age and (2) weathering degree W3‐4 and high 14C terrestrial age are mostly consistent with activities observed in recent falls. The older group shows no significant depletion in 26Al. Among the least weathered samples, one meteorite (SaU 424) was found to contain detectable 22Na identifying it as a recent fall close to the year 2000. Based on an estimate of the surface area searched, the corresponding fall rate is ~120 events/106 km2*a, consistent with other estimations. Twelve samples from the large JaH 091 strewn field (total mass ~4.5 t) show significant variations of 26Al activities, including the highest values measured, consistent with a meteoroid radius of ~115 cm. Activities of 238U daughter elements demonstrate terrestrial contamination with 226Ra and possible loss of 222Rn. Recent contamination with small amounts of 137Cs is ubiquitous. We conclude that gamma‐ray spectroscopy of a selection of meteorites with low degrees of weathering is particularly useful to detect recent falls among meteorites collected in hot deserts.  相似文献   

16.
We combined high‐resolution and space‐resolved elemental distribution with investigations of magnetic minerals across Fe,Ni‐alloy and troilite interfaces for two nonmagmatic (Morasko and Mundrabilla) IAB group iron meteorites and an octahedrite found in 1993 in Coahuila/Mexico (Coahuila II) preliminarily classified on Ir and Au content as IIAB group. The aim of this study was to elucidate the crystallization and thermal history using gradients of the siderophile elements Ni, Co, Ge, and Ga and the chalcophile elements Cr, Cu, and Se with a focus on magnetic minerals. The Morasko and Coahuila II meteorite show a several mm‐thick carbon‐ and phosphorous‐rich transition zone between Fe,Ni‐alloy and troilite, which is characterized by magnetic cohenite and nonmagnetic or magnetic schreibersite. At Morasko, these phases have a characteristic trace element composition with Mo enriched in cohenite. In both Morasko and Coahuila II, Ni is enriched in schreibersite. The minerals have crystallized from immiscible melts, either by fractional crystallization and C‐ and P‐enrichment in the melt, or by partial melting at temperatures slightly above the eutectic point. During crystallization of Mundrabilla, the field of immiscibility was not reached. Independent of meteorite group and cooling history, the magnetic mineralogy (daubreelite, cohenite and/or schreibersite, magnetite) is very similar to the troilite (and transition zone) for all three investigated iron meteorites. If these minerals can be separated from the metal, they might provide important information about the early solar system magnetic field. Magnetite is interpreted as a partial melting or a terrestrial weathering product of the Fe,Ni‐alloy under oxidizing conditions.  相似文献   

17.
Among the many ungrouped meteorites, Acfer 370, NWA 7135, and El Médano 301—probably along with the chondritic inclusion in Cumberland Falls and ALHA 78113—represent a homogeneous grouplet of strongly reduced forsterite‐rich chondrites characterized by common textural, chemical, mineralogical, and isotopic features. All of these meteorites are much more reduced than OCs, with a low iron content in olivine and low‐Ca pyroxene. In particular, Acfer 370 is a type 4 chondrite that has olivine and low‐Ca pyroxene compositional ranges of Fa 5.2–5.8 and Fs 9.4–33.4, respectively. The dominant phase is low‐Ca pyroxene (36.3 vol%), followed by Fe‐Ni metal (16.3 vol%) and olivine (15.5 vol%); nevertheless, considering the Fe‐oxyhydroxide (due to terrestrial weathering), the original metal content was around 29.6 vol%. Finally, the mean oxygen isotopic composition Δ17O = +0.68‰ along with the occurrence of a silica phase, troilite, Ni‐rich phosphides, chromite, and oldhamite confirms that these ungrouped meteorites have been affected by strong reduction and are different from any other group recognized so far.  相似文献   

18.
The chemical effects of terrestrial alteration, with a particular focus on lithophile trace elements, were studied for a set of H chondrites displaying various degrees of weathering from fresh falls to altered finds collected from hot deserts. According to their trace element distributions, a considerable fraction of rare earth elements (REEs), Th, and U resides within cracks observed in weathered meteorite specimens. These cracks appear to accumulate unbound REEs locally accompanied by Th and U relative to the major element abundances, especially P and Si. The deposition of Ce is observed in cracks in the case of most of the weathered samples. Trace element maps visually confirm the accumulation of these elements in such cracks, as previously inferred based on chemical leaching experiments. Because the positive Ce anomalies and unbound REE depositions in cracks occur in all weathered samples studied here while none of such features are observed in less altered samples including falls (except for altered fall sample Nuevo Mercurio), these features are interpreted to have been caused by terrestrial weathering following chemical leaching. However, the overall effects on the bulk chemical composition remain limited as the data for all Antarctic meteorites studied in this work (except for heavily weathered sample A 09516, H6) are in good agreement with published data for unaltered meteorites.  相似文献   

19.
For the first time, this paper presents to the planetary scientists' community the catalog of the meteorite collection preserved at the Italian Museum of Planetary Sciences (Museo Italiano di Scienze Planetarie, henceforth MISP) in Prato (Italy). Founded in 2005, MISP is a type specimen official repository approved by the Nomenclature Committee of the Meteoritical Society. It represents one of the few museums worldwide entirely devoted to planetary sciences. The catalog of its meteorite collection encompasses 430 meteorites for a total of 1536 specimens, including 291 thin sections, 184 thick sections, and 278 specimens that MISP has classified. Furthermore, MISP is currently classifying 57 other meteorites. Some samples were found during meteorite recovery expeditions in hot deserts, promoted by MISP in collaboration with diverse Italian universities and national research institutions. MISP also keeps an impact rocks collection comprising 257 samples. In a country like Italy, where most of the collected meteorites are housed in museums whose catalogs are not available online, the publication of the MISP meteorite collection catalog, together with the catalog of the impact rocks collection, represents not only a significant scientific primary source but also a remarkable tool for disseminating meteoritics to nonresearch audiences in educational activities and citizen science projects.  相似文献   

20.
Abstract— The distribution of white evaporitic deposits differs among different meteorite compositional groups and weathering categories of Antarctic meteorites. Evaporites occur with unusual frequency on carbonaceous chondrites, and are especially common in carbonaceous chondrites of weathering categories A and B. Among achondrites, weathering categories A and A/B show the most examples of evaporite weathering. Unlike carbonaceous chondrites and achondrites, most evaporite-bearing ordinary (H and L) chondrites are from rustier meteorites of weathering categories B and, to a lesser degree, B/C and C. LL chondrites are conspicuous by their complete lack of any evaporitic weathering product. Almost two-thirds of all evaporite-bearing meteorites belong to weathering categories A, A/B, and B. Where chemical data are available, surficial evaporite deposits are associated with elemental anomalies in meteorite interiors. Meteorites of weathering classes B, A/B, and even A may have experienced significant element redistribution and/or contamination as a result of terrestrial exposure. Evaporite formation during terrestrial weathering cannot be neglected in geochemical, cosmochemical, and mineralogical studies of Antarctic meteorites. A lower-case “e” should be added to the weathering classification of evaporite-bearing Antarctic meteorites, to inform meteorite scientists of the presence of evaporite deposits and their associated compositional effects.  相似文献   

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