Origin of some bedded welded tuffs

Well defined, laterally continuous welded tuff beds from <1 cm to 2 m thick are more common than has previously been recognized. Examples ranging in composition from rhyolitic to basaltic are described from Ordovician volcanic areas in Britain and Norway, and from the Miocene of the Canary Islands. Bedded welded tuffs are most common in areas of alkaline and peralkaline acidic pyroclastics. They generally occur within successions of massive, welded ash-flow tuff, or within non-welded air-fall tuff successions. Sequences consisting entirely of bedded welded tuff range from <1 m up to 75 m thick. Bedded welded tuffs are thought to originate in three ways. Poorly sorted, thick-bedded welded tuffs are interpreted as the deposits of pyroclastic flows, in which case the beds represent either individual flows units or the layers within flow units. Better sorted, thin-bedded welded tuffs are thought to be of air-fall origin. Thirdly, welding may be produced by the effects of an external heat source on non-welded bedded tuffs.     

Liparitic volcanism of some regional volcanic structures in Kazakhstan,Middle Asia and Caucasus

Liparitic volcanism is a typical feature of the orogenic phase giving rise to the Kazakhstan, Middle Asia and Caucasus folded systems. The main characteristics of the liparitic volcanism common to these three regions are the following:

1. Geo-structural zonation of the volcanic structures.
2. Dismembered Moho surface within the volcanic structures.
3. Synchronous, yet independent evolution of liparitic and andesitic volcanisms.
4. Ignimbritic character of the liparitic volcanism.
5. Lateral petrochemical zonation with some features common to the liparitic and andesitic rock series.

Geo-structural and petrochemical zonations are likely governed in the regions studied by a deep-seated plutonic body.     

Petrology of tholeiitic lavas from Tanna Island (New Hebrides): Importance of cumulative processes in Island arc magmatism

Tanna, one of the southernmost islands of the New Hebrides volcanic arc, is made of Late Pliocene to Recent island arc tholeiitic basalts and andesites, with SiO₂ contents ranging from 45 to 57%. These lavas are highly porphyritic (30–50% in volume): phenocrysts of plagioclase are the most abundant, together with olivine and clinopyroxene. The groundmass contain plagioclase, augite, olivine, magnetite and glass; pigeonite, tridymite, sanidine and, rarely, biotite may also occur. The olivines and clinopyroxenes show an iron enrichment from the cores of phenocrysts to their rims and the groundmass crystals, but their compositional variations are not correlated with the Mg/Fe ratio of bulk host rocks, the most Fe-rich compositions being found in Mg-rich lavas. Plagioclase compositions range from An₉₅ to An₆₀ in the basalts and An₆₀ to An₅₀ in the andesites, but, within each group, they are not correlated with SiO₂ or Na₂O contents of host lavas. Consequently, the bulk major element compositions of Tanna volcanic rocks cannot be considered as primarily controlled by crystal separation from successive liquids. The oxyde-SiO₂ variations diagrams, and the modal compositions and mineral chemistry show that crystal accumulation is the predominant mechanism accounting for bulk rock compositions. However, this does not exclude fractional crystallization: the variation of the calculated groundmass mineralogy strongly suggest the occurrence of crystal removal mainly clinopyroxene and magnetite.     

Calc-alkaline volcanic rocks from NW Sardinia: Evaluation of a fractional crystallization model

The volcanic centre of Monte Seda Oro, N. W. Sardinia, representative of a Cenozoic calc-alkaline andesitic suite of rocks is composed of a variety of rocks ranging from high alumina basalts to dacites. The minerals of basaltic, andesitic and dacitic rocks show only limited variation in chemical composition. The geochemical data suggest that the various rock-types are related by a crystal-liquid fractionation. Least-squate numerical calculations, using major element data, support the derivation of andesites with SiO₃ content ranging from 53.8 to 59.0% from basalts having about 48.7% of SiO₂ by low pressure crystal fractionation of the phenocryst phases present in these rocks. However, the origin of dacites cannot be readily explained by this mechanism.     

Eruption of Piip Crater (Kamchatka)

In autumn of 1966 on the northern slope of Kliuchevskoy volcano a chain of new adventive craters broke out at the height of about 2200 m. Eighty-four hours before the beginning of the eruption a swarm of preliminary volcanic earthquakes had appeared. The number of preliminary shocks was 457 with total energy of 4 × 10¹⁷ erg. With the beginning of the lava flow the earthquakes stopped and a continuous volcanic tremor appeared. The total energy of volcanic tremor amounts to 10¹⁶ erg. During the eruption numerous explosive earthquakes with the energy of 10¹⁵–10¹⁶ erg were recorded and besides the microbarograph of the Volcanostation recorded 393 explosions with an energy more than 10¹³ erg and their total energy was equal to 10¹⁷ erg. All together it has been formed 8 explosive craters and the lowest 9th crater was effusive. The slag cone was formed round this effusive crater, the lava effusion of basaltic-andesite composition (52,5% SiO₂) tooke place from the lava boccas at the cone base and from the crater. The lava flow covered a distance of 10 km along the valley of the Sopochnoy river and descended to a height of about 800 m. The lava flow velocity at the outflow reached 800 m/hr, the lava temperature was 1050°C. The effused lava volume amounts to 0.1 km³. The eruption stopped on December 25–26, 1966.     

Origin and diagenesis of the Roque Nublo breccia,Gran Canaria (Canary Islands) — Petrology of roque nublo volcanics,II

The Pliocene Roque Nublo Series, the second of three major magmatic series on Gran Canaria (Canary Islands), consists of a lower sequence (200 m) of alkalic lavas (basanite to phonolite) and a thicker upper section (600 m) of interlayered lava and widespread breccia sheets: encompassing pyroclastic flow deposits, lahars and reworked epiclastic rocks. Components in the poorly sorted block — and ash — flow deposits are (unwelded) pumice, rock fragments, crystals, glass shards and, locally, bread-crust bombs. Some flow units are graded with fine-grained basal zones and lithic-rich lower and pumice-rich upper parts. Some have strongly grooved the underlying rocks, directions of these striations being independent of preexisting topography and are constant in direction for more than 5 km. The flows are thought to have been emplaced below minimum welding temperatures by collapse of eruption columns. They are similar in many respects to coarse-grained pyroclastic flow deposits found in andesite volcanoes. Glass of tephritic to phonolitic composition of clasts of the breccias is generally altered to «palagonite» and is partly replaced by clay minerals and zeolites (mainly chabazite and phillipsite). Palagonitization was a low temperature diagenetic process, resulting in the hydration of glass accompanied and followed by precipitation of zeolites and clay minerals. Electron-microprobe data suggest the following decreasing order of mobility of selected elements during palagonitization: Na, K, Al, Si, Ca, Mg, and Fe; Ti was assumed to be inert.     

The linear relation between temperatures based on the silica content of groundwater and regional heat flow: A new heat flow map of the United States

Application of the silica geothermometer to over 70,000 non-thermal groundwaters from the United States has shown that there is a correlation between the average silica geotemperatures for a region (T SiO₂ in °C) and the known regional heat flow (q in mW m^?2) of the form: 1 $$TSiO_2 = mq + b$$ wherem andb are constants determined to be 0.67°C m² mW^?1 and 13.2°C respectively. The physical significance of ‘b’ is the mean annual air temperature. The slope ‘m’ is related to the minimum average depth to which the groundwaters may circulate. This minimum depth is estimated to be between 1.4 and 2.0 km depending on the rock type. A preliminary heat flow map based on equation (1) is presented using theT SiO₂ for new estimates of regional heat flow where conventional data are lacking. Anomalously high localT SiO₂ values indicate potential geothermal areas.     

Assessing the Current Evolution of the Greenland Ice Sheet by Means of Satellite and Ground-Based Observations

The present study utilises different satellite and ground-based geodetic observations in order to assess the current evolution of the Greenland Ice Sheet (GIS). Satellite gravimetry data acquired by the Gravity Recovery and Climate Experiment are used to derive ice-mass changes for the period from 2003 to 2012. The inferred time series are investigated regarding long-term, seasonal and interannual variations. Laser altimetry data acquired by the Ice, Cloud, and land Elevation Satellite (ICESat) are utilised to solve for linear and seasonal changes in the ice-surface height and to infer independent mass-change estimates for the entire GIS and its major drainage basins. We demonstrate that common signals can be identified in the results of both sensors. Moreover, the analysis of a Global Positioning System (GPS) campaign network in West Greenland for the period 1995–2007 allows us to derive crustal deformation caused by glacial isostatic adjustment (GIA) and by present-day ice-mass changes. ICESat-derived elastic crustal deformations are evaluated comparing them with GPS-observed uplift rates which were corrected for the GIA effect inferred by model predictions. Existing differences can be related to the limited resolution of ICESat. Such differences are mostly evident in dynamical regions such as the Disko Bay region including the rapidly changing Jakobshavn Isbræ, which is investigated in more detail. Glacier flow velocities are inferred from satellite imagery yielding an accelerated flow from 1999 to 2012. Since our GPS observations cover a period of more than a decade, changes in the vertical uplift rates can also be investigated. It turns out that the increased mass loss of the glacier is also reflected by an accelerated vertical uplift.     

A comparison of the recent eruptions of Mt. Pelée,Martinique and Soufrière,St. Vincent

The simultaneous eruption of Mt. Pelée, Martinique and Soufrière, St. Vincent are regarded as the first recognized examples of Pelean-type and St. Vincent-type pyroclastic eruptions. Both produced nuées ardentes, the former usually laterally directed because of the presence of a dome and the latter vertically directed from an open crater. Both volcanoes have subsequently erupted for a second time this century. The 1902–05 and 1929–32 eruptions of Mt. Pelée produced andesite lava of almost identical composition and mineralogy. Both contain two generations of plagioclase, orthopyroxene, Fe-Ti oxide, corroded brown amphibole and olivine rimmed by pyroxene. In contrast, the Soufrière material is more basic in composition varying from basaltic andesite to basalt in 1902–03 and basaltic andesite in 1971–72. The Soufrière material contains two generations of plagioclase (with those of 1971–72 having additional zones of labradorite), clinopyroxene, orthopyroxene, olivine and Fe-Ti oxide. The pyroclastic deposits are strikingly different, those from the Pelean-type eruption are termed «block and ash deposits» being characterised by poorly vesicular lava blocks up to 7 m in diameter, while the St. Vincent-type eruption produced «scoria and ash deposits» containing vesicular ropey blocks or bombs no larger than 1 m in diameter. The differences in styles of eruption are attributed to differences in viscosity and mechanism of eruption of the magmas. Stratigraphic studies of Mt. Pelée reveal that the volcano has produced basaltic andesite scoria and ash deposits from St. Vincent-type eruptions. It is concluded that the recent eruptions of Pelée tapped a deep level magma during both eruptions releasing magma of similar composition, while the 1971 Soufrière magma is thought to be a remnant of the 1903 basaltic magma which remained at a high level within the volcano where it underwent enrichment in plagioclase and loss of olivine and oxide.     

Fractional crystallization trends in the system Mg2SiO4-CaAl2Si2O8-FeO-Fe2O3-SiO2 over the range of oxygen partial pressures of 10−11 to 10−0.7 atm

A brief report is made of current laboratory investigations on phase relations among olivine, pyroxene, anorthite, magnetite, tridymite, liquid and gas in the system Mg₂SiO₄-CaAl₂Si₂O₈-FeO-Fe₂O₂-SiO₂ over a wide range of oxygen partial pressures. Courses of fractional crystallization under various conditions of oxygen partial pressure are depicted using an anorthite saturation diagram. Starting with a basalt-like composition in the system, fractional crystallization at a moderate oxygen partial pressure (10 atm.) results in an andesite-like residual liquid of composition 55 SiO₂, 14 iron oxide, 6 MgO, 9 CaO, 16 Al₂O₃ at a temperature of 1155°C. With fractional crystallization in a closed system, the end liquid approaches the composition of 45 SiO₂, 38 iron oxide, 6 CaO and 11 Al₂O₃, at a temperature of 1050°C and oxygen partial pressure of about 10^?12 atm. The andesitic final liquid in this system would be expected to further differentiate toward dacitic and rhyolitic compositions if alkalies and water were present in the system. On the basis of these studies, the derivation of liquids of andesitic, dacitic or rhyolitic composition from primary basalts by fractional crystallization seems entirely possible if the oxygen partial pressure is maintained at a moderate or high level.     

Gel- and ultramembrane filtration of aquatic humus: A comparison of the two methods

Fractionation is considered to be a necessary approach in order to obtain information about the complex composition of aquatic humus. Gel filtration has been used for this purpose for the last decade and recently ultramembrane filtration has been found useful. The two techniques are briefly described and results of a combined use of the two methods reported. The results show a poor correspondence, with regard to molecular size, between the two methods. Due to uncontrollable interaction between the gel used (Sephadex) and humus, the ultramembrane filtration technique is considered to be preferable for desalting and molecular size fractionation of aquatic humus.     

Seismicity of Vesuvius on its present state of activity

Reference is hereby made to the characteristics of seismic recordings of volcanic origin as obtained at the Vesuvian Observatory up to date. The new seismic equipment recently put into operation and consisting of four three-component seismographs set up on the slopes of the Vesuvius Great Cone is also described. The characteristics of the records obtained by the above said equipment are hereby explained and related to the activity of the volcano.     

Petrochemistry of quaternary pumiceous pyroclastic products in southern Guadeloupe (F.W.I.)

Pumiceous pyroclastic products are present as flows and falls at several stages of the evolution of the southern Guadeloupe volcanic island. An understanding of this volcanism had to rely on detailed petrochemical data of these products to complement similar data for effusive rocks so as to yield complete stratigraphical coverage. On the other hand most pumiceous rocks are more or less conspicuousily banded suggesting that mixing phenomena occurred to different degrees in their genesis. Three major classes of pumiceous products are found: (1) the Axial Chain deposits (2.0–0.5 My) are characterized by An90, 75-55 + En55 + Wo42En37 + Usp35-37 ± Fo68 ± Hble, SiO₂ 60%, SiO₂/Th 35.6, and La/Th 3.9. Banded samples have components that differ in evolution indices by about 50%; (2) the Bouillante Chaine pyroclastics (0.3–0.1 My) consist of scattered deposits with variable mineralogical and geochemical compositions that seem to have erupted from a number of small eruptive centers. Qz-dacitic pumice is common with An90, 70-45 + En66-56 + Usp32-38 + Ilm94 + Hble ± Wo40-42En40-42, SiO₂ 62%, SiO₂/Th 22.9, and La/Th >4. Mixed pumice samples have highly contrasted evolution indices differing by up to 120%; (3) the Pintade pumice flows and falls correspond to the major pyroclastic event (approx. 10 km³) in the southern Basse Terre area. They are characterized by An85-70 + En66-56 + Usp32-37 ± Wo42En42, SiO₂/Th 18.7-22?6, and La/Th 3.0-4.0. Banded pumice lumps are scarce and show slight compositional contrasts; differences in evolution indices do not exceed 38%. Axial and Bouillante chain pyroclastics and Grande Découverte volcano pumice respectively, form two different families in trace element plots. Minor elements in pyroxenes also are distinctive. These trends are similar to those obtained for effusive rocks and define comagmatic series. Major and trace element data for the separated components of inhomogeneous pumice in each formation always plot in the corresponding series. These chemical discriminants can be used to attribute samples of unknown provenance to a given volcanic ensemble. An inverse relationship between differences in evolution indices in inhomegeneous pumice and the volume of any single eruptive sequence is noted. This is an indication that pumiceous pyroclastic rocks were erupted from a zoned magma chamber. We favor an interpretation where zonation is produced by influx of less envolved magma in superficial differentiated chambers which is a direct cause for eruption.     

Geochemistry of mafic cainozoic volcanic rocks from Sardinia (western mediterranean)

The Cainozoic volcanism of Sardinia (Italy) can be divided into two main cycles with different magmatic and geodynamic significance. The early cycle — Oligo-Miocenic in age (29-13 My ago) — shows the calc-alkaline character typical of converging plate areas. The later activity, ranging from Lower Pliocene (about 5 My ago) to recent Pleistocene, produced mostly basic lavas extruded onto a continental plate («within plate basalts»). It was related to a period of tensional tectonics which had affected the western Mediterranean area prior to, and during, the volcanic activity. Intermediate and acid volcanic products were associated with the mafic rocks of the latest magmatic episodes. The main groups of rocks — the basic ones, already classified from their petrographic features and geological setting — can be characterized very well when a statistical elaboration of their chemical analyses is used. In fact, from chemical data it is possible to distinguish the Oligo-Miocene volcanic products from those of Plio-Pleistocene age. Moreover, within this latter group basanites, alkalic and subalkalic basaltic rocks can clearly be distinguished. Samples that had not clearly been defined on the basis of their petrographic characteristics (anonymous samples) have been attributed to one or the other of the main groups by means of discriminant functions. Chemical variations in the Plio-Pleistocenic rocks are due to fractionation episodes at shallow depths superimposed on primary magmatic variations. A model of partial fusion of the mantle accounts for many but not all the observed original chemical variations. Different physical melting conditions, the effects of minor mineral phases in the mantle and, probably, crustal contamination were also effective in creating the observed chemical variations.     

Origin and development of the Star Mountain rhyolite

The Star Mountain rhyolite covers 500 square miles in the Davis Mountains, 100 miles east of El Paso, Texas. It appears to be the largest known rhyolitic mass to have been emplaced as a liquid flow rather than as a « froth flow » or nuée ardente. That it was emplaced as a liquid is shown by the lineation of phenocrysts, the vesicular and autobrecciated zones, baking of underlying tuffs, and by the complete absence of shard structures and evidence for welding. Three flow units with an aggregate thickness of 800 feet can be distinguished on the basis of field, chemical, and petrographic criteria. With the exception of some vesicular zones the rock is either finely crystalline and massive, or glassy and brecciated. Minor structures indicate that the flow of each unit was highly irregular. Anorthoclase feldspar is the only significant phenocryst species in the unit. Phenocryst-groundmass compositional relationships cannot be explained on the basis of conventional granite system phase relationships, nor do recently proposed pantellerite relationships fit this case. An experimental investigation of this unusual case is under way. A high temperature of extrusion of the rhyolite is indicated by the lack of measurable triclinicity in the feldspar. A low water vapor pressure is demonstrated by the presence of apparently primary magnetite and the scarcity of vesicular zones. Despite the low water content, high temperature caused the low viscosity necessary for the melt to spread over the 500 square mile outcrop area, presumably with approximately the same fluidity as a typical basalt flow.     

Volcan ceboruco: A major composite volcano of the mexican volcanic belt

Ceboruco is a major composite volcano at the western end of the Mexican Volcanic Belt, near the junction between the North American and Pacific plates. The volcano is built from successive eruptions of andesite lavas and pyroclastic rocks, and major eruptions during its history have resulted in the formation of two concentric calderas. The youngest volcanic activity has included the extrusion of dacites within the inner caldera and a voluminous flank eruption of andesite during 1870–72. Fumarolic activity persists to the present day. Chemical analyses show that the lavas are of cale-alkaline type and rangs from andesite (SiO₂=58–61%) to acid dacite (SiO₂=68%) in composition. The rate of increase of K₂O relative to SiO is greater than that in volcanic rocks from the Mexican Volcanic Belt as a whole. This indicates that simple models based on the application of such relationships may not be adequate to explain the petrogenesis of calc-alkaline lavas.     

Silicate systems bearing on the crystallization courses in alkali basalts

Phase-equilibrium studies of the nepheline normative portion of the basalt tetrahedron nepheline-forsterite-silica-diopside ofYoder andTilley have shown that during the course of crystallization the composition of the liquid phase leaves this tetrahedron. When the tetrahedron is expanded to nepheline-forsterite-silica-Ca₂SiO₄ the courses of crystallization and composition of the liquid can be and have been followed by studying a series of joins within this expanded tetrahedron. These studies show that the ultimate goal of crystallization is the quaternary invariant point diopsidic pyroxene + nepheline solid solution + sodic plagioclase + wollastonite solid solution + liquid at 950 ± 5°"C. Attention is called to this low melting point in a dry system. With perfect equilibrium between the solid phases and liquid all melilite disappears by reaction with liquid below 1065 ± 5°C, the temperature of the quaternary reaction point with diopsidic pyroxene + melilite + nepheline solid solution + wollastonite solid solution + liquid. A flow sheet showing the reactions between all quaternary invariant points in the geologically interesting portion of the expanded tetrahedron is presented. This shows the interrelations (daughter-parent relations) between a large number of rock types found in intrusive and extrusive nepheline normative compositions as well as in the quartz normative tholeiitic basalts.     

Rayleigh wave phase velocity tomography and strong earthquake activity on the southeastern front of the Tibetan Plateau

To investigate the relationship between velocity structure and earthquake activity on the southeastern front of the Tibetan Plateau, we make use of continuous observations of seismic ambient noise data obtained at 55 broadband stations from the regional Yunnan Seismic Network. These data are used to compute Rayleigh wave Green's Functions by cross-correlating between two stations, extracting phase velocity dispersion curves, and finally inverting to image Rayleigh wave phase velocity with periods between 5 and 34 s by ambient noise tomography. The results show significant lateral variations in crustal and uppermost mantle structures in the studied region. Phase velocity anomalies at short periods(5–12 s) are closely related to regional tectonic features such as sediment thickness and the depth of the crystalline basement. The Sichuan-Yunnan rhombic block, enclosed by the Honghe, Xiaojiang and Jianchuan faults, emerges as a large range of low-velocity anomalies at periods of 16–26 s, that inverts to high-velocity anomalies at periods of 30–34 s. The phase velocity variation in the vicinity of the Sichuan-Yunnan rhombic block suggests that the low-velocity anomaly area in the middle-lower crust may correspond to lower crustal channelized flow of the Tibetan Plateau. The spatial distribution of strong earthquakes since 1970 reveals that the Yunnan region is inhomogeneous and shows prominent characteristics of block motion. However, earthquakes mostly occur in the upper crust, with the exception of the middle-Yunnan block where earthquakes occur at the interface zone between high and low velocity as well as in the low-velocity zones, with magnitudes being generally less than 7. There are few earthquakes of magnitude 5 at the depths of 15–30 km, where gather earthquakes of magnitude 7 or higher ones which mainly occur in the interface zone between high and low velocities with others extending to the high-velocity abnormal zone.     

Temperature observations of Crater Lake,Mt Ruapehu,New Zealand,using Temperature Telemetry Bouys

The temperature of the Crater Lake of the active volcano Ruapelm has been recorded by Temperature Telemetry Buoys, to determine if lake temperature is correlated with volcanic activity. These buoys had to be specially designed to cope with the unfavourable environment of Crater Lake. A buoy contains a thermistor to measure the lake temperature, and a radio transmitter to transmit a short signal every few minutes, the interval between signals being a function of temperature. The temperature records obtained from these buoys show that the temperature near the lake surface can vary considerably within a few hours. Some of these variations appear to be caused by disturbances in convective heat transfer occurring in the lake. The occurrence of these short term temperature variations means that there is no simple relation between Crater Lake temperatures and the volcanic activity of Ruapehu. Some rapid increases in temperature followed volcanic earthquakes, but one of the biggest increases in temperature occurred just before a group of earthquakes upder the lake.