The petrology of a complex sodic and sodic–calcic amphibole association and its implications for the metasomatic processes in the jadeitite area in northwestern Myanmar,formerly Burma

In the Myanmar jadeitite area of Pharkan, amphibole felses occur between jadeitites and serpentinized dunites. These so-called amphibole fels boundary zones were studied optically and by electron microprobe, and found to include the six amphibole species magnesiokatophorite (Mg-kat), nyböite (Nyb), eckermannite (Eck), glaucophane (Gln), richterite (Rich) and winchite (Win). In most samples, the two main amphibole species Mg-kat and Eck coexist with amphiboles containing variable amounts of components of the remaining four species, as well as with the clinopyroxenes jadeite (Jd), omphacite (Omp) and kosmochlor (Ko). However, Mg-kat, Nyb and Eck are also present as separate phases as well as in zoned porphyroblasts with Mg-kat in the core, Nyb in the inner rims, and Eck in the outer rims. The analytical data on such zoned amphiboles reveal that the chemistry changes from core to inner rim by virtue of the substitution NaAlCa _-1Mg _-1 (glaucophane vector), and from the inner to the outer rim along MgSiAl _-1Al _-1 (tschermak vector). The overall substitution from core to outer rim is, therefore, along NaSiCa _-1Al _-1 (plagioclase vector). Based on the Si content, three groups can be distinguished within Eck: Eck coexisting with Nyb has low Si contents of <7.6 a.p.f.u., Eck rimming Nyb has higher Si contents of 7.6–8.0 a.p.f.u., and fine-grained Eck in the matrix has Si contents of 7.9–8.0 a.p.f.u. Plotting the amphibole analyses in a compositional volume with the axes (Na+K) in A, Na in M(4), and tetrahedral Si shows that three groups of amphibole compositions can be distinguished, one being subdivided into three subsets. Group A contains Rich and Mg-kat, B comprises of Win and Gln, whereas the subsets C can be defined as follows: C1: high-Na amphiboles with low tetrahedral Si; these are mainly amphiboles from the Eck field but overlap with the two fields of Gln and Win; C2: high-Na and low-Si Ecks overlapping to high-Si Nybs; this group is midway between Eck and Nyb end members; C3: high-Na Mg-kats. Textural observations indicate three stages of sodic and sodic–calcic amphibole growth: stage 1 are amphiboles of group A (Mg-kat+Rich), stage 2 are amphiboles of group C2 (Nyb+Eck with Si<7.6 a.p.f.u.), and stage 3 are amphiboles of groups C1 and B (Eck with Si>7.6 a.p.f.u., +Gln+Win). Based on the subdivision into the compositional groups A–C, the only hint to a miscibility gap is provided by the large gap in the (Na+K) content on the A site which may point to a possible solvus in the system Eck–Win. Overall, the amphiboles investigated here show discontinuities in their growth compositions, rather than miscibility gaps. Textural observations suggest amphibole formation during fluid infiltration in the contact zone between the jadeitite bodies and the surrounding peridotite under high-pressure conditions (>1.0 GPa) and rather low temperatures of about 250–370 °C. Based on compositional trends within the amphiboles as well as phase-equilibrium constraints between amphibole and coexisting pyroxene solid solutions, the chemical composition of zoned amphibole porphyroblasts indicates two growth episodes—increasing pressures from stage 1 to stage 2 lead to the formation of Nyb from Mg-kat, and subsequently decreasing pressures lead to the formation of stage 3 Eck from Rich.     

Spherules with pure iron cores from Myanmar jadeitite: Type-I deep-sea spherules?

Here we report spherules in Myanmar jadeitite, a rock forming from jadeitic fluids within mantle-derived serpentinized rocks in subduction zones under high-pressure conditions (>1.0 GPa) and rather low temperatures of about 250-370 °C. The spherules have off-centre iron nuclei and dendritic wüstite cortexes, with tiny wüstite crystals perpendicular to the surface of iron core. Within the spherules are vesicles occupied by calcite, jadeite, albite? or mixtures of these phases, and the cortexes contain about 10 wt.% SiO₂ + Al₂O₃ + Na₂O filling materials within wüstite. The spherules are in direct contact with jadeite crystals. Contrasting patterns of some individual spherules are obvious between a front area with a crowd of hill-like prominences and a rear zone with one or more rings on the surface. Such surface features and internal textures suggest that they experienced movement at high temperature and then rapid cooling. Chemical compositions of the nuclei are homogenous and consist of nearly pure iron with minor Cr (<0.05 wt.%), Mn (<0.80 wt.%), and Ni (0.142-0.23 wt.%), and a trend of Ni decreasing and Cr increasing from core to cortex. Mn in the cortex (up to about 2.00 wt.%) is far more enriched than the nucleus. The bulk ratios (average) of δ⁵⁶Fe and δ⁵⁷Fe in the core and cortex are 0.51and 0.78, respectively. Such features suggest that there is a very low possibility of origin associated with volcanic explosive eruption, impact ejecta, chemical reduction or oxidation of iron on seafloor. Since biological reduction processes are not significant under high P/T condition in subduction zones, this origin is excluded. Considering their low Ni contents, it is more likely that they belong to the minor type-I deep-sea cosmic spherules/dusts of low isotope fractionation. This discovery shows that such spherules could remain stable under low-temperature and high-pressure conditions during recycling processes, and therefore could be found in rocks related to slab-derived sediments within subduction zones. This also suggests that subducted oceanic slab sediments contribute to the formation of jadeitite, coupled with dehydration of sediments and altered oceanic crust.     

Internal waves in the near-bottom thermocline and microdeformations in the Earth’s crust in the continent-ocean transition zone

The results of synchronous measurements of temperature variations in a near-bottom thermocline, as well as microdeformations of the Earth’s crust and atmospheric pressure pulsing, recorded on-shore with the help of a laser strainmeter and laser nanobarograph, are presented. A string containing 20 thermosensors spaced at 0.5 m was used; it was placed by an anchored buoy in a place with 21-m depth and 500 m away from the shore. A good correlation between microdeformations and atmospheric pressure variations was observed for periods longer than 6 h. Quantitative estimates and spectral analysis via the Gilbert-Huang method for investigation of nonstationary and nonlinear processes lead to the conclusion that, on temporal scales from tidal to several minutes, the predominant way of formation of microdeformations in the Earth’s crust can be breaking of internal waves in a thermocline that leads to shallow water (i.e., in the zone of “internal breakers”).     

Changes in the Abundance and Species Composition of Phytoplankton in the Last 150 Years in the Southern Black Sea

Changes in total abundance and in species composition of phytoplankton in the last 150 years in the southern Black Sea were investigated through a paleoecological study of two sediment cores. The results show changes in the species composition and a marked increase in total abundance of siliceous protists after around 1960. In core 22 (42°13.534′ N/36°29.555′ E), the dominating species before 1960 were Cyclotella choctawhatcheeana and Thalassiosira oestrupii. In core 25 (42°6.212′ N/36°37.460′ E), the dominating species before 1960 were T. oestrupii, Cyclotella meneghiniana, C. choctawhatcheeana, and Pseudosolenia cf. calcar-avis. Core 22 was located in closer proximity to the rim current than core 25, and the differences in total abundance between the cores could be related to differences in local nutrient loading prior to 1960. After around 1960, both cores changed to a community dominated by C. choctawhatcheeana. The changes in total abundance and species composition after around 1960 could be related to the increased nutrient loading from the Danube River into the rim current after the late 1960s. The results also showed changes in both total abundance and in species composition of dinoflagellate cysts. The dominating dinoflagellate cysts recorded were Lingulodinium polyedrum, Polykrikos schwartzii, and Spiniferites spp.     

Mercury pollution in the atmosphere-soil-biology ecosystem along the trunk road in Guilin

Based on the mercury distribution in soil, atmosphere and plant in seven sections beside the trunk road, some advances are obtained： （1） Mercury content of fuel oil of petrol station in Guilin is 3.66-9.74 ng/g, higher than that reported by other countries （0.7-3.2 ng/g）. The higher the number of petrol, the lower the content. Number 90 petrol widely used is the highest （9.74 ng/g）. （2） Mercury content in soil is commonly 0.30-0.80 μg/g near the road, （0.30-2.60 μg/g） besides the street, both are higher than the average of Guilin background value （0.204 μg/g）. Mercury content in vegetable near the road is generally 0.025-0.055 μg/g, higher than that far away from the road （0.022-0.038 μg/g）. The content in cinnamon leaves on both sides of the street is 0.06-0.16 μg/g, also higher than that far away from the street （0.051-0.067 μg/g）. Guilin Highway atmospheric mercury content is usually 7-12 ng/m^3, higher than the mean background value （4.4-6.6 ng/m^3）. Atmospheric mercury content near rural roads is below the level on urban roads. The atmospheric mercury content increases apparently in traffic-intensive stations and intersections. （3） The average concentration of mercury in vegetables is mostly 0.025-0.055 μg/g. Mercury content in various tissues of vegetable follows the order of leaves （mostly 0.044）.09 μg/g）〉roots （mostly 0.02-0.05 lag/g）〉stems （mostly 0.01-0.04 μg/g）. （4） The distribution of mercury in soil, plants and atmosphere near the road is of certain similarity, with a single peak, nearly symmetrical. As far away from road, the content reduces gradually, which shows the release of exhaust gas mercury is the main source of atmospheric mercury pollution.     

Change in the Geodynamic Settings in the Pacific‒Eurasia Transition Zone at the End of the Early Cretaceous

Doklady Earth Sciences - An attempt to provide a new explanation for the change in the geodynamic regime in the Early Cretaceous is presented below. It accounts for data on a number of global...     

The Orogeny in the Altaides

Studies of the deformation styles, formation types and isotopic age data indicate that the Altaides has successively experienced 5 stages of orogeny: (1) the Kanas orogeny forming the angular unconformity between the Baihaba Formation (O_3) and the Habahe Group (Z-O_2); (2) the Daqiao orogeny (S_3-D_(1-2) giving rise to the early Hercynian quasi-aulacogen extensional continental crust of the area; (3) the Altay orogeny (middle-late Hercynian) leading to the oblique intracontinentai collision and the formation of large shear arc-shaped thrust system and representing a strong orogeny stage; (4) the pan-Altay orogeny (latest Hercynian-Indosinian) resulting in the uplifting and erosion of the mountains as a whole; (5) the Himalayan movement causing the rejuvenation of fault systems and block uplift of the Aitaides since the Cenozoic.     

Fluctuations in the angular momentum of the atmosphere and intraday irregularities in the Earth’s rotation

Numerical celestial-mechanical models are used to compare (andg interpolate and forecast) near-diurnal tidal variations in the Earth’s axial rotation and oscillations in the global angular momentum of the atmosphere using the IERS data and NCEP/NCAR meteorological data. In order to improve the accuracy of interpolations and forecasts made for short and intraday time intervals, it is expedient to include the effect of small perturbations in short-term zonal tides, which influence fluctuations in Universal Time UT1 directly related to the Earth’s rotation. Due to the quasi-static formulation of the problem, it is assumed that the dynamics of the thin surface atmosphere are completely determined by the gradient of the tide-generating geopotential, which supports forced oscillations of the entire subsystem (i.e., of the mantle and atmospheric envelope). A comparison of the numerical simulations with the NCEP/NCAR data shows that the model is effective for applications in forecasting atmospheric tides.     

Sedimentary Characteristics of the Cretaceous in the Songliao Basin

The rupture of the lithosphere in Late Jurassic brought about the eruption of basaltic magma in the Songliao Basin. The evolution of the basin in Cretaceous progressed through six stages: pre-rift doming, extensional fracturing, fault subsidence, fault downwarping, downwarping and shringkage, resulting in the deposition of terrstrial facies nearly 10,000 m thick. There are different depositional sequences in these stages: the depositional period of the Early Cretaceous Shahezi and Yincheng Formations is the development stage of the down-faulted basin, forming a volcanic rock-alluvial fan-fan delta-lacustrine (intercalated with episodic turbidites)-swamp facies sequences; the period of the Early Cretaceous Dengluku Formation is the transformation stage of fault subsidence into fault downwarping of the basin, forming a sequence mainly of alluvial plain-lacustrine facies; the depositional period of the Early Cretaceous Quantou Formation-Late Cretaceous Nenjiang Formation is the downwarping stage of the basin, forming an alluvial plain-delta-lacustrine facies sequence; the period of the Late Cretaceous Sifangtai Formation-Mingshui Formation is the shringkage stage of the basin, forming again a sequence mainly of alluvial plain-alluvial fan and small relict lacustrine facies. These vertical depositional sequences fully display the sedimentary characteristics of a failed continental rift basin. Many facts indicate that the two large-scale lake invasions, synchronous with the global rise of sea level, which took place in the downwarping stage of the basin development, led to the connection between the lake and sea.     

Magnetostratieraphy of the Red Beds in the Hengyang Basin

This paper discusses the Cretaceous-Tertiary magnetic polarity sequence of the the Hengyang Basin on the basis of magnetostratigraphic study. The age of each stratigraphic unit has been determined with the magnetic polarity time scale combined with 39Ar/40Ar dating, thus providing evidence for determining the geological ages of different formations. The authors assign the age of the Dongjing Formation of the Hengyang Basin to Early Cretaceous, the Shenhuangshan Formation to Early-Late Cretaceous, the Daijiaping Formation to Late Cretaceous, and the Dongtang and Xialiushi formations to Palaeocene.     

Analysis on the sources of mercury in soils in the Chengdu Basin, China

Mercury is a pollutant of concern due to its toxic and bioaccumulative properties. Studies on the distribution and hazard of mercury in the environment are mainly focused on its forms, toxicity and the environment standard, and progresses and results have been achieved. But these studies in the past were concentrated on the scales of laboratory or smaller districts merely, such as a small unit of mineral area, vegetable base, paddy field, lake, etc. Multi-target regional geochemical survey carried out by China Geological Survey from the 1990s to now is a fundamental and commonweal geological survey, large-scale and systematical inquisition and research were conducted in 19 provinces （or municipalities directly under the Central Government） in the eastern overlay region of China, and the purpose is to provide the basic geochemical data for national economic construction, adjustment of industrial and agricultural structures and sustainable social development. Geochemical studies aim at investigating soils in these regions and 52 elements have been tested, producing a great amount of data at the same time. Methods： based on the data from 3061 samples of surface soil and 832 samples of deep soil from the project of multi-purpose geochemical survey in the Chengdu Basin, Sichuan, China, this paper describes the correlation relationship between Hg and other 48 elements and their spatial distribution in surface and deep soils of these areas by applying the method of linear regression and factor analysis.     

Gas–oil fluids in the formation of travertines in the Baikal rift zone

Active participation of gas–oil fluids in the processes of mineral formation and petrogenesis in travertines of the Arshan and Garga hot springs is substantiated. The parageneses of the products of pyrolytic decomposition and oxidation of the gas–oil components of hydrothermal fluids (amorphous bitumen, graphite-like CM, and graphite) with different genetic groups of minerals crystallized in a wide range of P–T conditions were established. Travertines of the Baikal rift zone were formed from multicomponent hydrous–gas–oil fluids by the following basic mechanisms of mineral formation: chemogenic, biogenic, cavitation, fluid pyrometamorphism, and pyrolysis.     

Activity of the Seyfert galaxy NGC 4151 in the near-IR in 1994–2011

We present the results of our infrared J H K L photometry of the Seyfert galaxy NGC 4151 during its active period in 1995–2011. The variable IR source was still in its active state in 2011, though its observed luminosity had almost halved compared to the maximum of 1995–1996. If the “cool” component of the galaxy’s variable source is a dust shell heated with the central “hot” source, its optical depth at 1.25 µm varied from 0.3 to almost 1.0, its temperature from 700 to 950 K, its size from 20 to 40 pc, and its mass from 2 to 40M _⊙ during our observations. A component with a period of 317 ± 5 days can be revealed in the flux variations observed in 1994–2011.     

Mathematical Model of the Geothermal Water Resources in the South Hot Spring System in Chongqing

INTRODUCTION Southhotspring,smallhotspringandQiaokou barepresent,betweenthem,thegeothermalwaters ofthesouthhotspringsysteminthesouthhotspring anticlineinChongqing.Thesouthhotspringanti clineisageothermalwaterstoragesystem.Itex tendsfromnorthtosouthinthecentralpartof Chongqing.Itis45kmlongfromsouthtonorthand2kmwide.Thesouthhotspringandsmallhot spring,inthemiddleoftheanticline,arewell known touristattractionsfortheirgeothermalwaters.Ex cessiveexploitationledtoagradualdeclineinthewa terlev…     

Changes in Phytoplankton Biomass in the Western Scheldt Estuary During the Period 1978–2006

We investigated whether climate change results in long-term changes in phytoplankton biomass and phenology in a turbid eutrophic coastal plain estuary. Changes in annual mean chlorophyll a (chla) concentrations were studied for the period 1978–2006 in the eutrophic and turbid macro-tidal Western Scheldt estuary. Three stations were investigated: WS1, at the mouth of the estuary; station WS6, halfway up the estuary; and station WS11, near the Dutch–Belgian border near the upstream end of the estuary. No significant long-term changes in yearly averaged chla concentrations were observed in WS1 and WS6, but in WS11 the phytoplankton biomass decreased considerably. This is most likely due to an increase in grazing pressure as a result of an improvement in the dissolved oxygen concentrations. Spectral analyses revealed a possible periodicity of 7 years in the mean chla which was related to periodicity in river discharge. We also observed strong phenological responses in the timing of the spring/summer bloom which were related to a well-documented increase in the temperature in the estuary. The fulcrum, the center of gravity or the day at which 50% of the cumulative chla was reached during the year, advanced by 1–2 days/year. A similar trend was observed for the month in which the maximum bloom was observed, with the exception of station WS1. All stations showed an earlier initiation of the bloom, whereas the day at which the phytoplankton bloom was terminated also moved forward in time excepted for WS11. As a result, the bloom length decreased at station WS1, remained the same at station WS6, and increased at WS11. This complicated pattern in bloom phenology demonstrates the complex nature of ecosystem functioning in estuaries.     

What Happened in the Trans-North China Orogen in the Period 2560-1850 Ma？

The Trans-North China Orogen （TNCO） was a Paleoproterozic continent-continent collisional belt along which the Eastern and Western Blocks amalgamated to form a coherent North China Craton （NCC）. Recent geological, structural, geochemical and isotopic data show that the orogen was a continental margin or Japan-type arc along the western margin of the Eastern Block, which was separated from the Western Block by an old ocean, with eastward-directed subduction of the oceanic lithosphere beneath the western margin of the Eastern Block. At 2550-2520 Ma, the deep subduction caused partial melting of the medium-lower crust, producing copious granitoid magma that was intruded into the upper levels of the crust to form granitoid plutons in the low- to medium-grade granite-greeustone terranes. At 2530-2520 Ma, subduction of the oceanic lithosphere caused partial melting of the mantle wedge, which led to underplating of mafic magma in the lower crust and widespread mafic and minor felsic volcanism in the arc, forming part of the greenstone assemblages. Extension driven by widespread mafic to felsic volcanism led to the development of back-arc and/or intra-arc basins in the orogen. At 2520-2475 Ma, the subduction caused further partial melting of the lower crust to form large amounts of tonalitic-trondhjemitic-granodioritic （TTG） magmatism. At this time following further extension of back-arc basins, episodic granitoid magmatism occurred, resulting in the emplacement of 2360 Ma, -2250 Ma 2110-21760 Ma and -2050 Ma granites in the orogen. Contemporary volcano-sedimentary rocks developed in the back-arc or intra-are basins. At 2150-1920 Ma, the orogen underwent several extensional events, possibly due to subduction of an oceanic ridge, leading to emplacement of mafic dykes that were subsequently metamorphosed to amphibolites and medium- to high-pressure mafic granulites. At 1880-1820 Ma, the ocean between the Eastern and Western Blocks was completely consumed by subduction, and the dosing of the ocean led to the continent-arc-continent collision, which caused large-scale thrusting and isoclinal folds and transported some of the rocks into the lower crustal levels or upper mantle to form granulites or eclogites. Peak metamorphism was followed by exhumation/uplift, resulting in widespread development of asymmetric folds and symplectic textures in the rocks.     

Is geographical proximity necessary in the innovation networks in the era of global economy?

In the analysis of geographical spillovers, a commonly accepted hypothesis is that the different actors of innovation need to be physically closed to one another because the transfer of tacit knowledge implies frequent face-to-face relations. This hypothesis is put under closer examination in this paper. The first section analyses the need for economic agents to be closely located to develop research and innovative activities, starting with the analysis of their need for co-ordination and using some case studies. Based on the example of three French regions, the second section examines the importance given by the local development policies to geographical proximity in order to support the rapid development of local networks favouring innovation. In both sections, nonlocal relations appear as a key factor to develop innovation. As a conclusion, nonlocal relations should be encouraged by local development policies in the same way as local relations.     

Unconformity-like Reflection Pattern under the Moho in the Sulu Area

1.IntroductionSincethediscoveryofcoesiteandndcrodiamond,theDabie-Suluultra-highPressure(UHP)meta-morphicbelthasbeenattractingworldwideattentionsofgeoscientists.Studyingthisoutstandinggeologicalregionmaygreatlyenhanceourunderstandingofmetamorphism,deepeffectsofcontinentalcollisionandgeodynandcsinconvergentplateboundaries.Thestudymayalsobeveryhelpfultoprovideevidencetorevealinteractionbetweenthecrustandthemantle,andtheformationofnewtypesofdiamonddeposits.EncouragedbytheinternationalContinenta…     

Noble Gases in the Lunar Regolith

The most fundamental character of lunar soil is its high concentrations of solar-wind-implanted elements, and the concentrations and behavior of the noble gases He, Ne, Ar, and Xe, which provide unique and extensive information about a broad range of fundamental problems. In this paper, the authors studied the forming mechanism of lunar regolith, and proposed that most of the noble gases in lunar regolith come from the solar wind. Meteoroid bombardment controls the maturity of lunar soil, with the degree of maturation decreasing with grain size; the concentrations of the noble gases would be of slight variation with the depth of lunar soil but tend to decrease with grain size. In addition, the concentrations of noble gases in lunar soil also show a close relationship with its mineral and chemical compositions. The utilization prospects of the noble gas ^3He in lunar regolith will be further discussed.