Magnetic zones of Mars: Deformation‐controlled origin of magnetic anomalies

Abstract— Intense magnetic anomalies over Martian surface suggest preservation of large volumes of very old crust (>3 Gyr) that formed in the presence of a global magnetic field. The global distribution of the magnetic intensities observed above the Martian crust suggests a division into three zones. Zone 1 is where the magnetic signature is negligible or of relatively low intensity at Mars Global Surveyor (MGS) satellite mapping altitude (400 km). Zone 2 is the region of intermediate crustal magnetic amplitudes and zone 3 is where the highest magnetic intensities are measured. Crater demagnetization near zone 3 reveals the presence of rocks with both high magnetic intensity and coercivity. Magnetic analyses of terrestrial rocks show that compositional banding in orogenic zones significantly enhances both magnetic coercivity and thermal remanent magnetization (TRM) efficiency. Such enhancement offers a novel explanation for the anomalously large intensities inferred of magnetic sources on Mars. We propose that both large magnetic coercivity and intensity near the South Pole is indicative of the presence of a large degree of deformation. Associated compositional zoning creates conditions for large scale magnetic anisotropy allowing magnetic minerals to acquire magnetization more efficiently, thereby causing the distinct magnetic signatures in zone 3, expressed by intense magnetic anomalies. We use a simple model to verify the magnetic enhancement. We hypothesize that magnetically enhanced zone would reside over the down welling plume at the time of magnetization acquisition.     

Impact demagnetization of the martian crust

The lack of magnetic anomalies within the giant martian impact basins, Hellas, Argyre, and Isidis suggests that the impacts demagnetized the crust. Our analysis of the magnetic anomaly intensity shows that the interior parts of the basins are completely demagnetized, while the outer parts and surroundings are partially demagnetized. We investigate the shock pressure and impact heating resulting from the impacts. The crust has been completely demagnetized within ∼0.8 basin radius by a combination of thermal and shock effects, and the surroundings have been partially demagnetized by shock to a distance of at least 1.4 radii. We also investigate magnetic signatures of intermediate-size craters. From the pressures generated by both the large and intermediate-sized impacts, we conclude that the remanent magnetization is carried at least in part by high coercivity rocks. Since the crust beneath the basins does not appear to have been remagnetized as it cooled following the impacts, we conclude that the martian core dynamo was inactive or very weak for at least 100 Myr following the Hellas impact.     

Magnetic fields of lunar multi‐ring impact basins

Abstract— We survey the magnetic fields of lunar multi‐ring impact basins using data from the electron reflectometer instrument on the Lunar Prospector spacecraft. As for smaller lunar craters, the primary signature is a magnetic low that extends to ?1.5–2 basin radii, suggesting shock demagnetization of relatively soft crustal magnetization. A secondary signature, as for large terrestrial basins, is the presence of central magnetic anomalies, which may be due to thermal remanence in impact melt rocks and/or shock remanence in the central uplift. The radial extent of the anomalies may argue for the former possibility, but the latter or a combination of the two are also possible. Central anomaly fields are absent for the oldest pre‐Nectarian basins, increase to a peak in early Nectarian basins, and decrease to a low level for Imbrian basins. If basin‐associated anomalies provide a good indication of ambient magnetic fields when the basins formed, this suggests the existence of a “magnetic era” (possibly due to a lunar core dynamo) similar to that implied by paleointensity results from returned lunar samples. However, the central basin anomalies suggest that the fields peaked in early Nectarian times and were low in Imbrian times, while samples provide evidence for high fields in Nectarian and early Imbrian times.     

Low-magnetic crust underlying South Province of Mars

The lack of distinct magnetic signatures observed by Mars Global Surveyor (MGS) over the impact craters and impact-related Quasi-Circular-Depressions (QCDs) with diameters greater than 200 km located on South Province, south of 30S and from almost the west of Hellas to Argyre basins, implies a weakly magnetized crust. Using MOLA topography and the recent JPL gravity model of Mars we determine the structure of the crust beneath the craters and impact-related QCDs, and show that the impacts that have created these features were capable of strongly disturbing the crust directly beneath. On the basis of theoretical magnetic anomaly modeling and shock demagnetization models, we demonstrate that the impacts are capable of demagnetizing the entire crust beneath and creating distinct magnetic anomalies at the satellite altitude of 400 km in case the crust was appreciably magnetized prior to the impacts. We derive the magnetic anomalies of these features using the radial component of the high-altitude nighttime MGS data. An upper limit of <2 × 10⁴ A for the bulk magnetization of the crust beneath South Province is estimated, which is about 30 times less than that underlying Terra Cimmeria and Terra Sirenum. Similar weak bulk magnetization is obtained for part of the crust surrounding Hellas, Isidis, and Argyre basins.     

On the properties of O and O2 ions in a hybrid model and in Mars Express IMA/ASPERA-3 data: A case study

We have performed a numerical simulation to analyze the energy spectra of escaping planetary O⁺ and O₂⁺ ions at Mars. The simulated time-energy spectrograms were generated along orbit no. 555 (June 27, 2004) of Mars Express when its Ion Mass Analyzer (IMA)/ASPERA-3 ion instrument detected escaping planetary ions. The simulated time-energy spectrograms are in general agreement with the hypothesis that planetary O⁺ and O₂⁺ ions far from Mars are accelerated by the convective electric field. The HYB-Mars hybrid model simulation also shows that O⁺ ions originating from the ionized hot oxygen corona result in a high-energy (E>1 keV) O⁺ ion population that exists very close to Mars. In addition, the simulation also results in a low-energy (E<0.1 keV) planetary ion population near the pericenter. In the analyzed orbit, IMA did not observe a clear high-energy planetary ion or a clear low-energy planetary ion population near Mars. One possible source for this discrepancy may be the Martian magnetic crustal anomalies because MEX passed over a strong crustal field region near the pericenter, but the hybrid model does not include the magnetic crustal anomalies.     

Antipodal effects of lunar basin-forming impacts: Initial 3D simulations and comparisons with observations

3D simulations of basin-scale lunar impacts are carried out to investigate: (a) the origins of strong crustal magnetic fields and unusual terrain observed to occur in regions antipodal to young large basins; and (b) the origin of enhanced magnetic and geochemical anomalies along the northwest periphery of the South Pole-Aitken (SPA) basin. The simulations demonstrate that a basin-forming impact produces a massive, hot, partially ionized cloud of vapor and melt that expands thermally around the Moon, converging near the basin antipode approximately 1 h after the impact for typical impact parameters. In agreement with previous work, analytic calculations of the interaction of this vapor-melt cloud with an initial ambient magnetic field predict a substantial temporary increase in field intensity in the antipodal region. The time of maximum field amplification coincides with a period when impacting ejecta also converge near the antipode. The latter produce antipodal shock stresses within the range of 5-25 GPa where stable shock remanent magnetization (SRM) of lunar soils has been found experimentally to occur. Calculated antipodal ejecta thicknesses are only marginally sufficient to explain the amplitudes of observed magnetic anomalies if mean magnetization intensities are comparable to those produced experimentally. This suggests that pre-existing ejecta materials, which would also contain abundant metallic iron remanence carriers, may be important anomaly sources, a possibility that is consistent with enhanced magnetic anomalies observed peripheral to SPA. The latter anomalies may be produced by amplified secondary ejecta impact shock waves in the thick SPA ejecta mantle occurring near the antipodes of the Imbrium and Serenitatis impacts. Together with converging seismic compressional waves, these antipodal impact shocks may have produced especially deep fracture zones along the northwest edge of SPA near the Imbrium antipode, allowing the ascent of magma with enhanced KREEP concentrations.     

Global mapping of lunar crustal magnetic fields by Lunar Prospector

The Lunar Prospector Electron Reflectometer has obtained the first global map of lunar crustal magnetic fields, revealing that the effects of basin-forming impacts dominate the large-scale distribution of remanent magnetic fields on the Moon. The weakest surface magnetic fields (<0.2 nT) are found within two of the largest and most recent impact basins, Orientale and Imbrium. Conversely, the largest concentrations of strong surface fields (>40 nT) are diametrically opposite to these same basins. This pattern is present though less pronounced for several other post-Nectarian impact basins larger than 500 km in diameter. The reduced strength and clarity of the pattern for older basins may be attributed to: (1) demagnetization from many smaller impacts, which erases antipodal magnetic signatures over time, (2) superposition effects from other large impacts, and (3) variation in the strength of the ambient magnetizing field. The absence of fringing fields stronger than 1 nT around the perimeter of the Imbrium basin or associated with craters within the basin implies that any uniform magnetization of the impact melt must be weaker than ∼¹⁰⁻⁶ G cm³ g⁻¹. This limits the strength of any steady ambient magnetic field to no more than ∼0.1 Oe at the lunar surface while the basin cooled for tens of millions of years following the Imbrium impact 3.8 billion years ago.     

Influence of redox conditions on the intensity of Mars crustal magnetic anomalies

We evaluate the relationship between the intensity of remanent magnetization and fO₂ in natural and synthetic Mars meteorites. The olivine‐phyric shergottite meteorite Yamato 980459 (Y‐980459) and a sulfur‐free synthetic analog (Y‐98*) of identical major element composition were analyzed to explore the rock magnetic and remanence properties of a basalt crystallized from a primitive melt, and to explore the role of magmatic and alteration environment fO₂ on Mars crustal anomalies. The reducing conditions under which Y‐980459 is estimated to have formed (QFM‐2.5; Shearer et al. 2006) were replicated during the synthesis of Y‐98*. Y‐980459 contains pyrrhotite and chromite. Chromite is the only magnetic phase in Y‐98*. The remanence‐carrying capacity of Y‐980459 is comparable to other shergottites that formed in the fO₂ range of QFM‐3 to QFM‐1. The remanence‐carrying capacity of these low fO₂ basalts is 1–2 orders of magnitude too weak to account for the intense crustal anomalies observed in Mars's southern cratered highlands. Moderately oxidizing conditions of >QFM‐1, which are more commonly observed in nakhlites and Noachian breccias, are key to generating either a primary igneous assemblage or secondary alteration assemblage capable of acquiring an intense remanent magnetization, regardless of the basalt character or thermal history. This suggests that if igneous rocks are responsible for the intensely magnetized crust, these oxidizing conditions must have existed in the magmatic plumbing systems of early Mars or must have existed in the crust during secondary processes that led to acquisition of a chemical remanent magnetization.     

Crustal properties of Mercury by morphometric analysis of multi‐ring basins on the Moon and Mars

Abstract— We use satellite altitude free‐air and terrain gravity correlations to differentiate regional variations in crustal viscosity and transient cavity diameters of impact basins on the Moon and Mars that we combine with surface roughness for a rheological assessment of the crust of Mercury. For the Moon and Mars, we separate the free‐air anomalies into terrain‐correlated and terrain‐decorrelated components using the spectral properties of the free‐air and computed terrain gravity effects. Adjusting the terrain effects for the terrain‐correlated anomalies yields compensated terrain effects that we evaluate for crustal thickness variations of the impact basins. We interpret the terrain‐correlated anomalies for uncompensated elements of the crustal thickness variations that we find are strongly correlated with the distribution of basin rings from photogeologic analyses. Hence, we estimate the transient cavity diameter from the innermost diameter of the gravity‐inferred rings. Comparing these diameters with the related crustal thickness estimates clearly differentiates regional variations in the crustal rheologies. For the Moon, the analysis points to a farside crust that was significantly more rigid than the nearside crust during bombardment time. For Mars, the growth in transient cavity diameters with apparent crustal age also reflects increased viscosity due to crustal cooling. These results are also consistent with local estimates of surface roughness developed from the root‐mean‐squared topography over 64 times 64° patches centered on the basins. Hence for Mercury where gravity observations are lacking, rheological inferences on its crust may result from comparing photometric estimates of transient cavity diameter and local surface roughness with the lunar and martian estimates. These results for the Beethoven Basin, a typical multi‐ring impact feature of Mercury, suggest that the viscosity of the mercurian crust was relatively great during bombardment time. This enhanced rigidity, despite crustal temperatures that were probably much hotter than those of the Moon and Mars, may reflect an extremely dry crust for Mercury in its early development.     

Oxygen fugacity in the Martian mantle controlled by carbon: New constraints from the nakhlite MIL 03346

Abstract— Pyroxene structural data, along with analyses of titanomagnetite, fayalite and mesostasis of the new nakhlite Miller Range (MIL) 03346, define equilibration near 1 bar, 1100 °C, and oxygen fugacity near the FMQ buffer. There is a clear progression of oxygen fugacity (fO₂) in Martian meteorites from reduced Allan Hills (ALH) 84001 to intermediate shergottites to oxidized nakhlites. This trend can be explained by polybaric graphite‐CO‐CO₂ equilibria in the Martian mantle. Shergottites would have formed at pressures between 1.2 and 3.0 GPa, and nakhlite parent liquids formed at pressures >3.0 GPa, consistent with geochemical and petrologic data for the shergottites and nahklites. Carbon buffering in the Martian mantle could be responsible for variation in fO₂ in Martian meteorites (rather than assimilation or crustal interaction), as well as C‐H‐O fluids that could be the source of ˜30 ppb CH₄ detected by recent spacecraft missions. The conundrum of an oxidized current mantle and basalts, but reduced early mantle during core‐mantle equilibrium exists for both the Earth and Mars. A polybaric buffering role for graphite can explain this discrepancy for Mars, and thus it may not be necessary to have an oxidation mechanism like the dissociation of MgFe‐perovskite to account for the oxidized terrestrial mantle.     

Impact‐related thermal effects on the redox state of Ca‐pyroxene

Oxidation is observed in Ca‐pyroxene subjected to a range of shock pressures (21–59 GPa). Changes in the pyroxene redox ratio as measured by the changes in %Fe³⁺ ranged from 2–6 times the starting composition. Mössbauer and reflectance spectroscopy record the changing Fe³⁺ concentration as a preferential oxidation of Fe²⁺ in the M2 crystallographic site. The oxidation is also accompanied by mechanical changes in the pyroxene crystals including fracturing, linear defects, and twinning. As oxygen fugacity is often calculated using mineral redox ratios and thought to represent the prevailing fO₂ during crystallization, it is imperative to recognize that the fO₂ values measured in impact‐derived materials may represent that of the impact and not the magma source region.     

Oxidation state of the atmosphere and crust of Venus from pioneer Venus results

Recent spacecraft observations of Venus permit a detailed model of sulfur chemistry in the atmosphere-lithosphere system. Pioneer Venus experiments confirm that, as predicted, COS and H₂S are dominant over SO₂ in the lower atmosphere, and that the equilibrium concentrations of S₂ and S₃ are significant. Many criteria serve to bracket the oxidation state of the crust: it is nearly certain that the S₂^2?/SO₄^2? buffer regulates the oxygen fucagity, and that FeO is at least as abundant as Fe₂O₃ in crustal silicates. A highly oxidized crust (as, for example, would result from O₂ absorption complementary to escape of vast amounts of H₂) is incompatible with the gas-phase sulfur chemistry. If the Pioneer Venus mass spectrometer estimates of the abundance of sulfur gases are correct, Earth-like models for the bulk composition of Venus are seriously in error, and a far lower FeO content is required for Venus.     

Observations of magnetic anomaly signatures in Mars Express ASPERA-3 ELS data

Mars Express (MEX) Analyser of Space Plasmas and Energetic Atoms (ASPERA-3) data is providing insights into atmospheric loss on Mars via the solar wind interaction. This process is influenced by both the interplanetary magnetic field (IMF) in the solar wind and by the magnetic ‘anomaly’ regions of the martian crust. We analyse observations from the ASPERA-3 Electron Spectrometer near to such crustal anomalies. We find that the electrons near remanent magnetic fields either increase in flux to form intensified signatures or significantly reduce in flux to form plasma voids. We suggest that cusps intervening neighbouring magnetic anomalies may provide a location for enhanced escape of planetary plasma. Initial statistical analysis shows that intensified signatures are mainly a dayside phenomenon whereas voids are a feature of the night hemisphere.     

Origin of the Earth's ocean basins

The Earth's original ocean basins are proposed to be mare-type basins produced 4 billion y.a. by the flux of asteroid-sized objects responsible for the lunar mare basins. Scaling upward from the observed number of lunar basins for the greater capture cross-section and impact velocity of the Earth indicates that at least 50% of an original global crust would have been converted to basin topography. These basins were flooded by basaltic liquids in times short compared to the isostatic adjustment time for the basin. The modern crustal dichotomy (60% oceanic, 40% continental crust) was established early in the history of the Earth, making possible the later onset of plate tectonic processes. These later processes have subsequently reworked, in several cycles, principally the oceanic parts of the Earth's crust, changing the configuration of the continents in the process. Ocean basins (and oceans themselves) may be rare occurences on planets in other star systems.     

Lithospheric drift on early Mars: Evidence in the magnetic field

The crustal magnetic anomalies on Mars may represent hot spot tracks resulting from lithospheric drift on ancient Mars. As evidence, an analysis of lineation patterns derived from the ΔBr magnetic map is presented. The ΔBr map, largely free of external magnetic field effects, allows excellent detail of the magnetic anomaly pattern, particularly in areas of Mars where the field is relatively weak. Using cluster analysis, we show that the elongated anomalies in the martian magnetic field form concentric small circles (parallels of latitude) about two distinct north pole locations. If these pole locations represent ancient spin axes, then tidal force on the early lithosphere by former satellites in retrograde orbits may have pulled the lithosphere in an east-west direction over hot mantle plumes. With an active martian core dynamo, this may have resulted in the observed magnetic anomaly pattern of concentric small circles. As further evidence, we observe that, of the 15 martian giant impact basins that were possibly formed while the core dynamo was active, seven lie along the equators of our two proposed paleopoles. We also find that four other re-magnetized giant impact basins lie along a great circle about the mean magnetic paleopole of Mars. These 11 impact basins, likely the result of fallen retrograde satellite fragments, indicate that Mars once had moons large enough to cause tidal drag on the early martian lithosphere. The results of this study suggest that the magnetic signatures of this tidal interaction have been preserved to the present day.     

Estimating shock pressures based on high‐pressure minerals in shock‐induced melt veins of L chondrites

Abstract— Here we report the transmission electron microscopy (TEM) observations of the mineral assemblages and textures in shock‐induced melt veins from seven L chondrites of shock stages ranging from S3 to S6. The mineral assemblages combined with phase equilibrium data are used to constrain the crystallization pressures, which can be used to constrain shock pressure in some cases. Thick melt veins in the Tenham L6 chondrite contain majorite and magnesiowüstite in the center, and ringwoodite, akimotoite, vitrified silicate‐perovskite, and majorite in the edge of the vein, indicating crystallization pressure of ?25 GPa. However, very thin melt veins (5–30 μm wide) in Tenham contain glass, olivine, clinopyroxene, and ringwoodite, suggesting crystallization during transient low‐pressure excursions as the shock pressure equilibrated to a continuum level. Melt veins of Umbarger include ringwoodite, akimotoite, and clinopyroxene in the vein matrix, and Fe₂SiO₄‐spinel and stishovite in SiO₂‐FeO‐rich melt, indicating a crystallization pressure of ?18 GPa. The silicate melt veins in Roy contain majorite plus ringwoodite, indicating pressure of ?20 GPa. Melt veins of Ramsdorf and Nakhon Pathon contain olivine and clinoenstatite, indicating pressure of less than 15 GPa. Melt veins of Kunashak and La Lande include albite and olivine, indicating crystallization at less than 2.5 GPa. Based upon the assemblages observed, crystallization of shock veins can occur before, during, or after pressure release. When the assemblage consists of high‐pressure minerals and that assemblage is constant across a larger melt vein or pocket, the crystallization pressure represents the equilibrium shock pressure.     

Estimate of the magnetic field of Mars based on the magnetic characteristics of the Yamato 000593 nakhlite

Abstract— Yamato 000593, a nakhlite, was analyzed in terms of its magnetic record and magnetomineralogy. The natural remanent magnetization (NRM: 3.55–6.07 times 10^?5 Am²/kg) was thermally demagnetized at ～320 °C, and it was unstable against alternating field demagnetization. Based on analyses of thermomagnetic curves, the temperature dependence of hysteresis parameters, and microscopic observations, the magnetic minerals mainly consist of magnetite (0.68 wt% of the sample, including ～5% Fe₂TiO₄) of less than 100 μm in size, associated with minor amounts of monoclinic pyrrhotite (<0.069 wt% of the sample) and goethite. Thermal demagnetization of NRM at ～330 °C is explained due to an offset of magnetization of antipodal NRM components of magnetite, whereas it is not due to a pyrrhotite Curie point. Large magnetite grains show exsolution texture with ilmenite laths, and are cut by silicate (including goethite) veins that formed along cracks. Numerous single‐domain (SD) and pseudo‐single‐domain (PSD) magnetite grains are scattered in the mesostasis and adjacent olivine grains. Moderate coercive forces of H_C = 6.8 mT and H_RC = 31.1 mT suggest that Yamato 000593 is fundamentally able to carry a stable NRM; however, NRM was found to be unstable. Accordingly, the meteorite was possibly crystallized at 1.3 Ga under an extremely weak or absent magnetic field, or was demagnetized by impact shock at 12 Ma (ejection age) on Mars. This finding differs from the results of previous paleomagnetic studies of SNC (shergottites, nakhlites, chassignites, and orthopyroxenite) Martian meteorites. The significant dipole magnetic field resulting from the molten metallic core was probably absent during the Amazonian Epoch (after 1.8 Ga) on Mars.     

Maohokite,a post‐spinel polymorph of MgFe2O4 in shocked gneiss from the Xiuyan crater in China

Maohokite, a post‐spinel polymorph of MgFe₂O₄, was found in shocked gneiss from the Xiuyan crater in China. Maohokite in shocked gneiss coexists with diamond, reidite, TiO₂‐II, as well as diaplectic glasses of quartz and feldspar. Maohokite occurs as nano‐sized crystallites. The empirical formula is (Mg_0.62Fe_0.35Mn_0.03)²⁺Fe³⁺₂O₄. In situ synchrotron X‐ray microdiffraction established maohokite to be orthorhombic with the CaFe₂O₄‐type structure. The cell parameters are a = 8.907 (1) Å, b = 9.937(8) Å, c = 2.981(1) Å; V = 263.8 (3) ų; space group Pnma. The calculated density of maohokite is 5.33 g cm^?3. Maohokite was formed from subsolidus decomposition of ankerite Ca(Fe²⁺,Mg)(CO₃)₂ via a self‐oxidation‐reduction reaction at impact pressure and temperature of 25–45 GPa and 800–900 °C. The formation of maohokite provides a unique example for decomposition of Fe‐Mg carbonate under shock‐induced high pressure and high temperature. The mineral and its name have been approved by the Commission on New Minerals, Nomenclature and Classification of the International Mineralogical Association (IMA 2017‐047). The mineral was named maohokite after Hokwang Mao, a staff scientist at the Geophysical Laboratory, Carnegie Institution of Washington, for his great contribution to high pressure research.     

Shock metamorphic history of >4 Ga Apollo 14 and 15 zircons

During impact events, zircons develop a wide range of shock metamorphic features that depend on the pressure and temperature conditions experienced by the zircon. These conditions vary with original distance from impact center and whether the zircon grains are incorporated into ejecta or remain within the target crust. We have employed the range of shock metamorphic features preserved in >4 Ga lunar zircons separated from Apollo 14 and 15 breccias and soils in order to gain insights into the impact shock histories of these areas of the Moon. We report microstructural characteristics of 31 zircons analyzed using electron beam methods including electron backscatter pattern (EBSP) and diffraction (EBSD). The major results of this survey are as follows. (1) The abundance of curviplanar features hosting secondary impact melt inclusions suggests that most of the zircons have experienced shock pressures between 3 and 20 GPa; (2) the scarcity of recrystallization or decomposition textures and the absence of the high‐pressure polymorph, reidite, suggests that few grains have been shocked to over 40 GPa or heated above 1000 °C in ejecta settings; (3) one grain exhibits narrow, arc‐shaped bands of twinned zircon, which map out as spherical shells, and represent a novel shock microstructure. Overall, most of the Apollo 14 and 15 zircons exhibit shock features similar to those of terrestrial zircon grains originating from continental crust below large (~200 km) impact craters (e.g., Vredefort impact basin), suggesting derivation from central uplifts or uplifted rims of large basins or craters on the Moon and not high‐temperature and ‐pressure ejecta deposits.     

High‐pressure phases in shock‐induced melt veins of the Umbarger L6 chondrite: Constraints of shock pressure

Abstract— We report a previously undocumented set of high‐pressure minerals in shock‐induced melt veins of the Umbarger L6 chondrite. High‐pressure minerals were identified with transmission electron microscopy (TEM) using selected area electron diffraction and energy‐dispersive X‐ray spectroscopy. Ringwoodite (Fa₃₀), akimotoite (En₁₁Fs₈₉), and augite (En₄₂Wo₃₃Fs₂₅) were found in the silicate matrix of the melt vein, representing the crystallization from a silicate melt during the shock pulse. Ringwoodite (Fa₂₇) and hollandite‐structured plagioclase were also found as polycrystalline aggregates in the melt vein, representing solid state transformation or melting with subsequent crystallization of entrained host rock fragments in the vein. In addition, Fe₂SiO₄‐spinel (Fa₆₆‐Fa₉₉) and stishovite crystallized from a FeO‐SiO₂‐rich zone in the melt vein, which formed by shock melting of FeO‐SiO₂‐rich material that had been altered and metasomatized before shock. Based on the pressure stabilities of the high‐pressure minerals, ringwoodite, akimotoite, and Ca‐clinopyroxene, the melt vein crystallized at approximately 18 GPa. The Fe₂SiO₄‐spinel + stishovite assemblage in the FeO‐SiO₂‐rich melts is consistent with crystallization of the melt vein matrix at the pressure up to 18 GPa. The crystallization pressure of ?18 GPa is much lower than the 45–90 GPa pressure one would conclude from the S6 shock effects in melt veins (Stöffler et al. 1991) and somewhat less than the 25–30 GPa inferred from S5 shock effects (Schmitt 2000) found in the bulk rock.