Stratigraphy and correlation of Mesoproterozoic rocks associated with Mohar cauldron,Shivpuri district,Madhya Pradesh

A circular structure, termed as cauldron of volcanic origin, was located near Mohar village in Shivpuri district (M.P.) in the year 2000. Subsequently, the same structure was called as Dhala structure of impact origin. There may be debate over the origin and evolution of this circular structure, but it is characterized by a unique lithological set-up within the Bundelkhand craton. The circular structure is defined by annular disposition of igneous and sedimentary rocks. This includes a set of felsic volcanic rocks and associated breccias named as Mohar Formation, exposed in the outer rim of the circular structure. The inner part of the circular structure has sedimentary sequence, termed as Dhala Formation.The field relations indicate that the Mohar and Dhala foarmations are younger than Bundelkhand granitoid complex but older than Kaimur Group. This period in Indian stratigraphy corresponds to Semri Group which consists of Porcellanite Formation, the rocks of which have formed due to deposition of volcanic ash.The geochronological data and field relations between different litho-units indicate that the Mohar volcanism which generated large volume of volcanic ash was a possible source for the formation of Porcellanite Formation. The deposition of sedimentary sequence in main Vindhyan basin was continued, whereas the volcanic activity in Mohar area continued till H ≈ 1.0 Ga. Since, acid volcanic activity has been reported in different parts of the world at H ≈ 1.0 Ga., it is possible that the Mohar acid volcanic activity is not an isolated event; instead it may be a part of global volcanic activities around H ≈ 1.0 Ga.     

Uranium mineralisation associated with felsic volcanism at Mohar,Shivpuri district,Madhya Pradesh

Several small lensoidal bodies of felsic volcanics are exposed in a curvilinear pattern within the brecciated granitoids of Bundelkhand Gneissic Complex (BGC) at Mohar. Sub-surface data reveals extensive presence of these felsic volcanics below the sediment of Vindhyan Supergroup. It occurs like a sheet with thickness varying from 12 m to 134 m. Its lateral extent has been traced upto 4.8 km. Multiple flows of felsic magma are identified based on colour, granularity, cross cutting relations and cyclic distribution of multiple vesicular bands along the entire thickness of felsic magma. The felsic rock contains upto 13.21% K₂O. Chemical composition of these felsic volcanics varies across the column. Petrographically and chemically all these felsic volcanics are identified as rhyolite or rhyolite tuff.     

Peperite occurrence and its implications on origin and temporal development of the Proterozoic Dhala basin,Mohar area,Shivpuri district,Madhya Pradesh

In the western part of Bundelkhand massif, a caldera with intra-caldera sediments, known as Dhala Formation, occurs as an outlier in and around Mohar village of Shivpuri district, Madhya Pradesh. For the first time, occurrence of peperite is being reported from the basal part of the Dhala sediment. Two types of peperites have been recognized: blocky and fluidal or globular with variable morphology. In peperitic zones, features like soft sediment deformations, presence of sediment into the rhyolite along cracks, vesiculation of the sediments and other evidences suggestive of sediment fluidization are some definite characteristics of interaction of hot magma with wet sediments forming peperite. The occurrence of peperites reflects the contemporaniety of deposition of the Dhala sediments and volcanism, which is well in accordance to the volcanic origin of Dhala structure. Further, the nature of unconformity between the Dhala and overlying Kaimur which is characterized by merely a few centimeter thick pebbly/conglomeratic bed does not appear to represent a large hiatus as expected between the Semri and Kaimur of Vindhyan Supergroup. So, the contemporaniety of the Dhala Formation (at least the lower part) as reflected by occurrence of peperites, coupled with the available age of the rhyolite and the nature of the unconformity between the Dhala and overlying Kaimur provide convincing evidence to correlate the Dhala Formation with the Lower part of the Kaimur and unlikely with the Semri Group or Bijawar as proposed earlier.     

Geology, petrography and geochemistry of rhyolite-hosted uranium mineralization at Mohar, Shivpuri district, Madhya Pradesh

In the westernmost part of the Bundelkhand Granitoid Complex (BGC), a mesa structure represents a unique outlier, surrounded by brecciated granite and filled with Vindhyan sedimentary rocks locally known as the Dhala Formation near Mohar village of Shivpuri district, Madhya Pradesh. Uranium mineralisation located in the area is mostly associated with rhyolite of peralkaline to peraluminous in nature, that has a high average uranium concentration (30 ppm). The mineralization is in or adjacent to caldera and is hydrothermal vein-type. Radioactivity is mainly due to coffinite with limited radioactivity due to U-Ti complex, uranium adsorbed in clay and labile uranium along fracture. Coffinite occurs in association with pyrite and chalcopyrite or chlorite with presence of fluorite. Features such as chloritisation, clay formation and sulfide mineralisation manifest hydrothermal alteration. Chemical analysis indicates the aluminous nature of the rock and their high K₂O/Na₂O (3.81–12.84) ratios are suggestive of predominance of potash feldspar over sodic. The alteration index varies from 49.88–92.40, which, reflects high intensity of hydrothermal alteration. Chlorite-carbonatepyrite index (CCPI), a measure of the intensity of replacement of sodic feldspars and glass by sericite, chlorite, carbonate, and pyrite associated with hydrothermal alteration proximal to the ore bodies varies from 3.84–49.66. On the basis of core study, geochemistry and mineralogy, it is envisaged that epigenetic hydrothermal solutions were responsible for concentration of uranium as coffinite, radioactive carbonaceous matter and adsorbed uranium phases in rhyolite with sulfide confined to weak planes.     

Petrological evidences of impact-induced shock metamorphism in the basement granitoids and rhyolitic melt breccia of Mohar area,Shivpuri district,Madhya Pradesh

The circular structure at Mohar (Dhala structure) in the western part of Bundelkhand Gneissic Complex, is marked by a prominent outlier of Kaimur sediments surrounded by low lying concentric sequence of sediments of Dhala Formation and basement granite breccia. This has been interpreted as a volcanic eruption related cauldron structure and meteoritic impact crater structure by various authors, on the basis of absence or presence of shock indicators in the clasts of a rhyolite-like rock that crops out scantily in the north western part of the structure. During the course of extensive sub-surface uranium exploration in this structure, the geoscientists of Atomic Minerals Directorate for Exploration and Research observed unequivocal and rampant evidences of shock metamorphic features for the first time in drill core samples of basement granitoids which constitute the bed rock for the rhyolite-like melt breccia, which overlies it. Published data of shock metamorphic features from this area are largely confined to the surface samples of the rhyolite-like melt rock, exposed in sparse outcrops. The shock metamorphic features recorded in the sub-surface granitoid bed rock samples during the present study, comprise planar deformation features (PDF) in quartz, feldspar, apatite and zircon, toasted, diaplectic, ladder-textured feldspars, selectively shock-melted feldspars and melt-veined quartz. The shock metamorphic features recorded in surface and sub-surface samples of the melt rock include ballen quartz, PDF in quartz clasts, toasted and diaplectic feldspar clasts shocked basic rock fragments with isotropised feldspars. Both the shocked bedrock granitoid and the melt rock bear uncharacteristic geochemical signatures with elevated K₂O, MgO and depleted CaO. The study also observes that the melt breccia overlying the granitoid bedrock also occurs as pocket-like patches at various depths within the granitoids. Thus, the present findings have helped in understanding the attributes of the basement granitoid and associated melt breccia, thereby linking the genesis of the latter by selective melting of the former, due to the process of impact. It reinforces the already propounded theory of impact as the likely cause for the development of the structure in the basement Bundelkhand granitoid that was later filled by sediments standing out presently as a mesa.     

Mineralogy and genesis of the metamorphosed manganese silicate rocks (gondite) of Gowari Wadhona,Madhya Pradesh,India

Manganese silicate rocks, interbanded with manganese oxide orebodies, constitute an important stratigraphic horizon in the Mansar formation of the Sausar Group of Precambrian age in India. The manganese silicate rocks of Gowari Wadhona occupy the westernmost flank of the manganese belt of the Sausar Group. These rocks are constituted of spessartite, calcium-rich rhodonite, quartz, manganoan diopside, blanfordite (manganese bearing member of diopside-acmite series), brown manganese pyroxene (manganese bearing aegirine-augite), winchite (manganese bearing richterite-tremolite), juddite (manganese bearing amphibole with richterite, tremolite, magnesioriebeckite and glaucophane molecules), tirodite (manganese bearing amphibole with richterite, cummingtonite and glaucophane molecules), manganophyllite, alurgite, piedmontite, braunite, hollandite (and other lower oxides of manganese) with minor apatite, plagioclase, calcite, dolomite and microcline. A complete mineralogical account of the manganese-bearing phases has been given in the text. It has been shown that the juxtaposition of manganese silicate rocks with dolomitic marble, regional metamorphism to almandine-amphibolite facies and assimilation of pegmatite veins cutting across the manganese formation, were responsible for the development of these manganese silicate rocks and the unusual chemical composition of some of the constituent minerals. It has been concluded that the manganese silicate rocks of Gowari Wadhona were originally laid down as sediments comprising manganese oxides admixed with clay, silica etc. and were later regionally metamorphosed to almandine-amphibolite facies. All evidences indicate that rhodochrosite was not present in the original sediment and the bulk composition of the sediments was rich in manganese. These rocks agree entirely to the detailed nomenclature of the gondites enunciated by Fermor (1909) and amplified by Roy and Mitra (1964) and Roy (1966).     

Braunite mineralogy and paragenesis from the Kajlidongri mine,Madhya Pradesh,India

The Kajlidongri manganese deposit, Madhya Pradesh, India contains braunite belonging to at least two different parageneses, i.e. a fine-grained, metamorphic type and a younger, coarser-grained, hydrothermal type. Microanalyses of braunite from these paragenetic types indicate considerable variations in iron content from zero to 32.7% Fe₃O₃, which the writers consider is due to varying proportions of braunite I and bixbyite modules in polysomatic braunite.     

Petrology of calc-silicate rocks from Koduru,Andhra Pradesh,India

Mineral assemblages, rock and mineral chemistry, and mineral reactions, in calc-silicate rocks from Koduru area, Andhra Pradesh, India are discussed. Mineralogical and bulk chemical differences indicate 3 calc-silicate rock types — type I with K feldspar+calcite+wollastonite+quartz+scapolite+diopside_ss +andradite_ss+sphene, has relatively high rock oxidation ratios. Type II is a highly calcic variety with high rock MgFe ratios, and has K feldspar+calcite+wollastonite+quartz+scapolite + diopside_ss±grossularite_ss+sphene+zoisite. Type III has K feldspar +calcite+wollastonite+quartz+scapolite+diopside_ss +sphene+hornblende+magnetite, and has relatively low oxidation ratio and low MgFe ratio. The 3 calc-silicate rock types have originated as mixtures of limestone/dolomite/marl.Diopside was produced by a reaction involving Ca-amphibole +calcite+quartz, and reversed during retrogression. Andradite_ss in type I rocks was produced at the expense of hedenbergitic component of pyroxene in a continuous reaction as a consequence of increase in the oxygen content of the original sediment relative to type III. Calcite+quartz reacted to give wollastonite. During cooling an influx of water caused scapolite to alter to zoisite.     

Melt inclusions in olivine and pyroxene phenocrysts from lamprophyres of Chhaktalao Area,Madhya Pradesh,India

Melt inclusions in olivine and pyroxene phenocrysts in kersantite and camptonite at Chhaktalao in Madhya Pradesh, India are mainly of the evolved type forming daughter minerals of olivine, pyroxene, plagioclase, spinel, mica, titanomagnetite and sulphides. Heating studies exhibit a temperature range from 1215° to 1245°C for the melt inclusions in olivine in camptonite and 1220–1245°C for olivine in kersantite. The temperature for melt inclusions in pyroxene ranged from 1000° to 1150°C in camptonite and 850–1100°C for pyroxene in kersantite. The bubble inside these melt inclusions is mainly CO₂. The T_h°C of CO₂ into liquid phase occurred between 26° and 31°C in olivine and 25–30°C in pyroxene from kersantite and camptonite. The maximum density estimated is 0.72 g/cm³ and the minimum is 0.45 g/cm³. The depth of entrapment of the melt inclusion is estimated between 10–15 km. The pressure of entrapment of melt inclusion in olvine is 4.6 kbar where as that in pyroxene is 3.7 kbar. The lamprophyres in the Chhaktalao area are considered to be derived from low depth and low pressure region, possibly within spinel lherzolite zone.     

Structural and luminescent characterisation of uraniferous fluorapatite and haematite associated with phosphatic rocks of the Bijawar group in Sagar District,Madhya Pradesh (India)

The structural and spectroscopic characteristics of phosphatic ferruginous shale samples from the Bijawar Group rocks from Sagar District of Madhya Pradesh (India) have been probed for identification of uranium species. Fluorapatite (\(\hbox {Ca}_{5}\hbox {(PO}_{4})_{3}\hbox {F}\), FAP) and haematite (\(\upalpha \)-\(\hbox {Fe}_{2}\hbox {O}_{3}\)) were identified as the main phases in the separated mineral concentrates. The photoluminescence (PL) and X-ray absorption near edge spectroscopy (XANES) studies pointed to a strong experimental evidence of both U(IV) and U(VI) oxidation states in the mineral concentrate portion obtained from the same parent host rock. The PL spectrum has confirmed the charge transfer (f–d) transition bands in UV and near-UV regions with emission peaks at ca. 290, 313, 336, 399 and 416 nm, which has been attributed to the substitution of \(\hbox {Ca}^{2+}\) ions by U(IV) in FAP and broad structureless emission due to stabilisation of U(VI) as \(\hbox {UO}_{6}^{6-}\) in haematite. Time-resolved spectroscopy studies have revealed biexponential decay components lasting 2–5 ns for U(IV) species and \(10\,\upmu \hbox {s}\) for U(VI) species. These characterisations revealed the fundamental information about the oxidation state and form of uranium in this region. Remediation measures for the Bijawar region are also suggested.     

Petrology of metamorphic rocks of almandine-amphibolite facies in Saidapuram-Podalakuru area,Nellore district,Andhra Pradesh,India

Summary Precambrian amphibolites and quartz-mica schists in the Saidapuram-Podalakuru area fall within the almandine-amphibolite facies of regional metamorphism. The analysed rocks represent metamorphosed basic igneous rocks. It is suggested that the quartz-muscovite-staurolite schists underwent metamorphism between 550° and 700° C at an average pressure of 7.2 kb; the quartz-muscovite (±biotite), hornblende-biotite (±garnet), and hornblende-garnet schists between 600°–700° C/7.5 kb; and the quartz-biotitekyanite schists between 650°–700° C/8 kb.

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Petrologie der metamorphen Gesteine in Almandin-Amphibolit-Fazies im Gebiet von Saidapuram-Podalakuru, Distrikt Nellore, Andhra Pradesh, Indien

Zusammenfassung Präkambrische Amphibolite und Quarz-Glimmer-Schiefer im Gebiet von Saidapuram-Podalakuru gehören der Almandin-Amphibolit-Fazies an. Die analysierten Gesteine stellen metamorphe basische Erstarrungsgesteine dar. Die Quarz-Muskovit-Staurolith-Schiefer wurden bei 550°–700°C und einem durchschnittlichen Druck von 7,2 kb metamorph, die Quarz-Muskovit-(±Biotit-), die Hornblende-Biotit- (±Granat-) und die Hornblende-Granat-Schiefer bei 600°–700° C/7,5 kb, die Quarz-Cyanit-Schiefer bei 650°–700° C/8 kb.

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With 6 Figures     

Geothermal investigations in the Upper Vindhyan sedimentary rocks of Shivpuri area,central India

Heat flow has been determined by combining temperature measurements in 7 boreholes with thermal conductivity measurements in the Upper Vindhyan sedimentary rocks of Shivpuri area, central India. The boreholes are distributed at 5 sites within an area of 15 × 10 km²; their depths range from 174 to 268 m. Geothermal gradients estimated from borehole temperature profiles vary from 8.0–12.7 mK m⁻¹ in the sandstone-rich formations to 25.5–27.5 mK m⁻¹ in the shale-rich formations, consistent with the contrast in thermal conductivities of the two rock types. Heat flow in the area ranges between 45 and 61 mW m⁻², with a mean of 52±6 mW m⁻². The heat flow values are similar to the >50 mW m⁻² heat flow observed in other parts of the northern Indian shield. The heat flow determinations represent the steady-state heat flow because, the thermal transients associated with the initial rifting, convergence and sedimentation in the basin as well as the more recent Deccan volcanism that affected the region to the south of the basin would have decayed, and therefore, the heat flow is in equilibrium with the radiogenic heat production of the crust and the heat flow from the mantle. The present study reports the heat flow measurements from the western part of the Vindhyan basin and provides heat flow information for the Bundhelkhand craton for the first time. Radioelement (Th, U and K) abundances have been measured both in the sedimentary rocks exposed in the area as well as in the underlying basement granite-gneiss of Bundelkhand massif exposed in the adjacent area. Radioactive heat production, estimated from those abundances, indicate mean values of 0.3 μW m⁻³ for sandstone with inter-bands of shale and siltstone, 0.25 μW m⁻³ for sandstone with inter-bands siltstone, 0.6 μW m⁻³ for quartzose sandstone, and 2.7 μW m⁻³ for the basement granitoids. With a total sedimentary thickness not exceeding a few hundred metres in the area, the heat production of the sedimentary cover would be insignificant. The radioactive heat contribution from the basement granitoids in the upper crust is expected to be large, and together with the heat flow component from the mantle, would control the crustal thermal structure in the region.     

Sediment Yield Index mapping and prioritization of Madia subwatershed,Sagar District of Madhya Pradesh (India)

Assessment of soil loss through Sediment Yield Index (SYI) is important for watershed planning, prioritization, and development. In the absence of measured sediment data, SYI expressing the relative sediment yield from different basins work as a basis for grading another basin to adopt erosion control measures. An attempt was made to evaluate SYI in wider scale by using cost-effective tools like remote sensing and geographical information system (GIS). SYI was calculated for Madia subwatershed, which consists of 29 microwatersheds and located in Sagar District, Madhya Pradesh (M.P.) The IRS LISS III data and Shuttle Radar Topography Mission (SRTM) digital elevation models (DEM) of 90-m resolution were used to identify land use characteristics and geomorphometric analysis. Major land use was observed as agricultural land (24.7 %), water bodies (16.7 %), forest area (10.2 %), and settlement (21.3 %). In categorization, similar overall accuracy was observed for dense forest, barren land, settlement, and water bodies. The highest SYI with a value more than 20 was observed in microwatershed Mw6, Mw7, and Mw24, which comprises 33 % of the total watershed area. It gives the information about the watershed area that requires very high priority.     

Analysis of groundwater levels for detection of trend in Sagar district,Madhya Pradesh

Groundwater being an important component of the hydrological cycle as it sustains the streamflow during precipitation free periods and is a major source of water supply. The dependence on the groundwater has increased drastically over the years leading to over exploitation of the aquifers. Therefore, it is imperative to assess the extent of exploitation and analyse the groundwater level scenarios in the area of interest. The existence of a trend in a hydrological time series can be detected by statistical tests. The present study investigates the application of various methods for identification of trends in groundwater levels in few blocks of Sagar district, which faces severe water scarcity owing to the declining groundwater levels. The non-parametric Kendal rank correlation test as well as the parametric linear regression test has been used for trend detection based on the analysis of the seasonal groundwater levels. Kendal’s rank correlation test, has been applied to identify the trend persisting in the data and the linear regression test is used to identify the significance of the slope. The analysis indicates that the time series of groundwater levels are cyclical with characteristics of seasonal variation in all the blocks coupled with a declining trend at Sagar, Khurai and Bina.     

Geochemical Modelling of Fluoride Concentration in Hard Rock Terrain of Madhya Pradesh, India

The aim of the present study is to locate and decipher the groundwater quality,types,and hydrogeochemical reactions,which are responsible for elevated concentration of fluoride in the Chhindwara district in Madhya Pradesh,India.Groundwater samples,quality data and other ancillary information were collected for 26 villages in the Chhindwara District,M.P.India during May 2006.The saturation index was computed for the selected samples in the region,which suggest that generally most of the minerals are saturated with respect to water.The concentration of fluoride in the region varies from 0.6 to 4.74 mg/l,which is much higher as per the national and international water quality standards.The study also reveals that the fluoride bearing rock formations are the main source of the higher concentration of fluoride in groundwater along with the conjuncture of land use change.Moreover,the area is a hard rock terrain and consists of fractured granites and amygdaloidal and highly jointed compact basalt acting as good aquifer,which is probably enriching the high content of fluoride in groundwater.High concentration of fluoride is found in deeper level of groundwater and it is possible due to rock-water interaction,which requires further detailed investigation.The highly alkaline conditions indicate fluorite dissolution,which works as a major process for higher concentration of fluoride in the study area.The results of this study will ultimately help in the identification of risk areas and taking measures to mitigate negative impacts related to fluoride pollution and toxicity.     

Mixed marine,brackish water and non-marine microfaunal association in the Inter-trappean beds (Early Palaeocene) of Jhilmili,Chhindwara district,Madhya Pradesh

Except for the east coast of Andhra Pradesh, the Deccan Inter-trappean sedimentary beds of Peninsular India have been long known to yield non-marine microfauna, mainly ostracods. These have been extensively described from different localities of Madhya Pradesh, Maharashtra, Karnataka, Andhra Pradesh, Gujarat and Rajasthan states. Occurrence of mixed microfaunal association of marine, brackish water and non-marine foraminifers and ostracods is being recorded from these beds from Jhilmili, Chhindwara district, Madhya Pradesh. It comprises at least two or more planktonic foraminifer species, and one brackish water and 17 non-marine ostracod species. The brackish water ostracod, Neocyprideis raoi (Jain, 1978) has been previously recorded in great profusion from the Inter-trappean beds of Duddukuru, West Godavari District, Andhra Pradesh, which have been assigned Early Palaeocene age (Khosla and Nagori, 2002). Presence of molt stages of the bulk of non-marine and brackish water ostracods in the Inter-trappean beds of Jhilmili is suggestive that they were inhabitants of low mesohaline inland pool/lake. The planktonic foraminifers were carried to this pool/lake by a marine transgression probably from the east coast of India through the Trans Deccan Straits.     

Appraisal of highly fluoride zones in groundwater of Kurmapalli watershed,Nalgonda district,Andhra Pradesh (India)

Fluoride (F) contamination study had been carried out to see its allocation in Kurmapalli watershed, Nalgonda district, Andhra Pradesh, India. The study area is located about 60 km SE of Hyderabad city. The groundwater is the main source of water for their living. The groundwater in villages and its surrounding are affected by fluoride contamination and consequently the majority of the people living in these villages has health hazards and is facing fluorosis. The purpose of this study is to identify the wells with high F, raise awareness in people, study the water chemistry, and also find out the source of F in groundwater. A total of 32 groundwater samples were collected from different wells in both shallow aquifers and deeper fractures zones during October 2004. The chemical analysis of groundwater has been done. Fluoride values vary from 0.7 to 19.0 mg/l. It is noted that the maximum value (19.0 mg/l) is one of the highest values found in groundwater in India and 78% of the total samples show F concentrations that exceeds the permissible limit value (1.5 mg/l). The highest value of F is found at Madanapur bore well which is located at central part of the watershed. The F value of this bore well was monitored from October 2004 to October 2006. During this period the F concentration varies from 17.8 to 21.0 mg/l with mean 19.3 mg/l. There is no correlation of F with chemical parameters except calcium. The Ca has shown inverse proportional with F. Water–rock interaction studies were also carried out to understand the behavior of F in groundwater at prominent F affected areas. Rock samples were collected and analyzed, and found their enrichment of F. The anthropogenic possibility of F is almost negligible. The rocks of this area are enriched in F from 460 to 1,706 mg/kg. It is indicated that the rock–water interaction is the main source of F in groundwater. The highest values of F are found in middle part of the region and are related to the occurrence of fluoride rich rocks and their chemical kinetic behavior with groundwater.     

Petrographic,chemical and trace-elemental composition of the coal of Sohagpur coalfield,Madhya Pradesh,India

The Sohagpur coalfield is a remnant of the Son valley basin of Gondwana deposition and can be subdivided into three major subbasins from west to east: Rungta-Amlai, Kotma and Bijuri. Thick coal seams occur in the Barakar Formation (Lower Permian) and are being worked extensively.Petrographic, reflectance, chemical and trace-elemental studies on samples of coal representative of the coal seams of the different subbasins have been carried out, and the results are presented here. Petrographically, the coals of one subbasin are different from those of another subbasin and are mainly composed of vitrinertite I, and vitrinertite V, that alternates with fusite. Vitrite increases in proportion in the coal seams towards the eastern part of the coalfield, and sclerotinite occurs in increased proportion in coal seams towards the western part. The reflectance in oil (Ro_max) varies from 0.50 to 0.58% in the coals of Rungta-Amlai, 0.46–0.56% in Kotma, and 0.53–1.05% in Bijuri subbasins. Chemically, the coals belong to type High Volatile Symbol B 4 of Class Bituminous. The significant trace elements are V (20–400 ppm); Cu, Ni, Co (up to 300 ppm); Mn, Ba, Sr, Zr (up to 800 ppm); and La (up to 1200 ppm). The trace elements show a tendency to increase in proportion towards the eastern part of the coalfield.To the immediate east of the coalfield lies the Chirimiri coalfield, of which the compositional characteristics are also presented. These data clearly suggest that the coals of the Son valley are different from those of the other Gondwana basins, i.e., Mahanadi, Godavari, and Damodar valley basins.     

Geochemistry of groundwater in parts of Guntur district, Andhra Pradesh, India

Hydrogeochemical investigations, which are significant for the assessment of water quality, have been carried out to study the sources of dissolved ions in groundwaters of some rural areas of Guntur district, Andhra Pradesh, India. Groundwaters in the area are mostly brackish. High contents of SiO₂, and Na⁺ and Cl^- ions in groundwater, in comparison with those of seawater, suggests a meteoric origin of groundwater. The high concentration of SiO₂ and various geochemical signatures reflect the weathering of minerals. However, the Na⁺+K⁺ vs Cl^- ratio suggests weathering, has occurred only to some extent. The chemistry of groundwater favours the formation of clay minerals (montmorillonite, illite and chlorite), because of evapotranspiration. The positive saturation index of CaCO₃ and the high signatures of Ma²⁺:Ca²⁺ and Na⁺:Ca²⁺ reveals the occurrence of evaporation. The evaporation enhances the concentration of ions (which occurred originally in the water) in the soils during summer. The very high % MathType!MTEF!2!1!+- % feaaeaart1ev0aaatCvAUfKttLearuavTnhis1MBaeXatLxBI9gBae % bbnrfifHhDYfgasaacH8srps0lbbf9q8WrFfeuY-Hhbbf9v8qqaqFr % 0xc9pk0xbba9q8WqFfea0-yr0RYxir-Jbba9q8aq0-yq-He9q8qqQ8 % frFve9Fve9Ff0dmeaabaqaciGacaGaaeqabaqabeaadaaakeaacqqG % tbWucqqGpbWtdaqhaaWcbaGaeeinaqdabaGaeeOmaiJaeeyla0caaa % aa!2EC5! SO₄^{2 -} {\rm SO}_{\rm 4}^{{\rm 2 - }} and Cl^- contents in some groundwaters and the occurrence of kankar (CaCO₃) in the area suggest a long history of evaporation. Greater ionic concentration in the groundwaters of post-monsoon compared with pre-monsoon indicates the increasing addition of leachates into the groundwater from the soils in the monsoon and anthropogenic activities, which leads to a deteriorating quality of groundwater. According to the Gibbs' diagrams, rock weathering, to some extent, and evaporation are the dominant phenomena responsible for the higher ionic concentrations found in groundwater. Measures that benefit sustainable management of groundwater quality are suggested in this study.     

Morphometric analysis of Morar River Basin, Madhya Pradesh, India, using remote sensing and GIS techniques

Hydrogeological mapping and drainage analysis can form an important tool for groundwater development. Assessment of drainage and their relative parameters have been quantitatively carried out for the Morar River Basin, which has made positive scientific contribution for the local people of area for the sustainable water resource development and management. Geographical Information System has been used for the calculation and delineation of the morphometric characteristics of the basin. The dendritic type drainage network of the basin exhibits the homogeneity in texture and lack of structural control. The stream order ranges from first to sixth order. The drainage density in the area has been found to be low which indicates that the area possesses highly permeable soils and low relief. The bifurcation ratio varies from 2.00 to 5.50 and the elongation ratio (0.327) reveals that the basin belongs to the elongated shaped basin category. The results of this analysis would be useful in determining the effect of catchment characteristics such as size, shape, slope of the catchment and distribution of stream net work within the catchment.