Clay mineral distribution in sediments of the Gulf of Thailand and the South China Sea

The 25 sediment samples collected from the Gulf of Thailand and the South China Sea were analyzed for clay mineral investigation. Results showed the presence of 35% montmorillonite, 13% chlorite, 30% illite, and 22% kaolinite in sediments of the Gulf and also 16% montmorillonite, 21% chlorite, 41% illite, and 22% kaolinite in sediments of the South China Sea. The relatively high concentration of montmorillonite in sediments of the Gulf as compared with that in sediments of the South China Sea may suggest that montmorillonite in these area has been largely derived from soil formation of the bordering land areas of the Gulf, particularly from the northern part of Malay Peninsula. On the contrary, the content of illite in sediments of the South China Sea is higher than that in the Gulf. This mineral appears to have been supplied from Borneo as well as the Mekong Delta. However, chlorite which shows a similar distribution to that of illite in sediments of the Gulf and the South China Sea has not indicated Borneo Isl. as a principal source area for chlorite. Greater resemblance in amount of kaolinite in both sediments of the Gulf and the South China Sea is due to the prevailing distribution of kaolinite as low latitude clay mineral on the bordering land areas. The distribution of clay minerals in sediments of the study area appears to be closely related to the soil formation and geology of the adjacent land areas.This work was carried out at Geological and Mineralogical Institute, Tokyo University of Education.     

云南星云湖断陷湖盆中粘土矿物组合特征与沉积环境关系的初步探讨

于１９８８年对云南星云湖盆地区进行调查，运用Ｘ射线衍射，差热分析，红外光谱分析和扫描电镜方法，对该盆地的第四系泥岩和现代沉积环境的泥质沉积物的４９个样品进行研究。发现，现代环境中粘土矿物分布规律明显，且与第四系沉积物有对比性，从而推断盆地沉积环境分布和演化与泥质沉积物的微量元素聚类分析结果相吻合。     

Mineral composition of sedimentary matter in the Caspian Sea

Data on the mineral composition of sedimentary matter and its fluxes in the sediment system of the Caspian Sea are presented. River runoff, aerosols, particulate matter from sediment traps, and the upper layer (0–1 cm) of bottom sediments are considered. The contents of detrital minerals (quartz, albite, and K-feldspar), clay minerals (illite, chlorite, and kaolinite), and carbonates (calcite, Mg-calcite, dolomite, aragonite, and rhodochrosite) are determined. Gypsum was found in bottom sediments but is absent in the other object of the sediment system.     

Clay mineralogy of bottom sediment in the Jinhae Bay,Korea

The bottom sediments of Jinhae Bay area contain, on average, 45 % illite, 23 % kaolinite, 17 % intergrade clay, 10 % chlorite, and 5 % smectite. The geographical distribution of the clay minerals shows, in general, an it crease in illite, a decrease in kaolinite, and a slight decrease in chlorite seawards. The distributional trends of smectite and intergrade clay are irregular. The clay fractions of the sediments of Jinhae Bay are supplied from stream-borne sediments and are mixed with sediments transported landwards from the East China Sea. Local erosion and redeposition of the clay fractions of the bottom sediments is caused by rapid tidal currents.     

The distribution characteristics of clay minerals in the northern South China Sea

The clay minearals are composed of illite, chlorite, kaolinite, montmorillonite and mixed-layer minerals in the submarine sediments of the northern South China Sea. Three types of clay mineral zone can be recognized on the basis of the distributive regularity of clay minerals, submarine relief, hydrodynamic conditions and depositional characteristics in this region. Apart from the northern mainland source, kaolinites carried from the Philippines volcanic arc in the east and Malaysia in the south are also assumed to be one of the sources of the clay minerals in the deep sea. The increase of chlorites to the abyssal direction in the west of 116° E might be associated with the residual chlorites carried from the ancient Zhujiang River during the glacial period and the conversion of kaolinite into chlorite submarine volcanoes appear to be one of the sources of the increment of montmorillonite and chlorite around the Huangyan Island. From the distribution pattern of clay minerals in the whole area, it is kn     

CIAY MINERALS IN THE SURFACE SEDIMENTS OF THE BOHAI SEA

Analyses of clay mineralogy about 30 surface sediments indicate widespread occurrence of illite, kaolinite, chlorite and montmorillonite throughout the Bohai Sea. Illite is the most abundant mineral, averaging 60%, kaolinite, next to illite, is the most abundant one,averaging 18%. Chlorite and montmorillonite come second, averaging 12% and 10% respectively. The distributive patterns of clay minerals in the surface sediments are closely related to the suspended materials carried into the Bohai Sea, especially to those did by the Huanghe River, and to water dynamics in the area. Based on the distribution, the assemblages and the others of clay minerals, the Bohai Sea can be divided into two clay mineral regions, the Liaodong Gulf region and the Bohai-Laizhou Bay region.     

帕里西维拉海盆西北部表层沉积物中粘土矿物的分布特征及物源分析

提要应用X射线衍射(XRD)方法对菲律宾海帕里西维拉海盆西北部的257个表层沉积物样品<2μm粘土组分进行了分析。结果表明,本研究区粘土矿物的组合特点是伊利石含量最高(平均含量47%),蒙皂石含量次之(平均含量35%),高岭石和绿泥石含量均很低(平均含量小于10%)。根据该区表层粘土矿物中伊利石、蒙皂石相对含量的分布,可以大体上分为两种含量组合类型,据此也可以划分出两个组合分区:Ⅰ.富伊利石分区,主要位于帕劳海脊和帕里西维拉海沟之间的大部分区域的地形平坦处;Ⅱ.富蒙皂石分区,主要位于研究区东部帕里西维拉海沟附近和南部零星区域。根据粘土矿物的平面分布特征,结合个别样品的扫描电子显微镜(SEM)和X射线能谱(EDS)分析,认为伊利石主要来源于研究区以西陆地及周边岛屿。伊利石的化学指数和结晶度指数表明,伊利石形成于物理风化较强的气候环境并可能与中国内陆黄土有关系,区内大部分蒙皂石具有富铁并含少量镁的特征,基性火山物质的蚀变是其主要成因,高岭石和绿泥石以陆源为主;风力的吹扬是研究区伊利石物质来源的主要输送方式,洋流作用对粘土矿物,尤其是蒙皂石矿物的分布具有一定影响。     

南海西北部表层沉积物黏土矿物分布特征及其来源

黏土矿物研究在示踪物源、源区风化历史乃至洋流变迁能力等方面具有重要的作用,尽管目前对南海表层沉积物黏土矿物宏观分布特征已获得了较系统的认识,但在受珠江和海南岛物源共同影响的南海西北部其高分辨率的黏土矿物学工作还未开展。本文对南海西北部表层沉积物中的黏土矿物组成、结晶学特征进行了分析,讨论了研究区黏土矿物的物质来源。结果表明,南海西北部表层沉积物的黏土矿物组成以伊利石为主（平均45%）,蒙脱石（平均27%）与高岭石（平均21%）次之,绿泥石含量最少（平均6%）。在区域空间分布上,蒙脱石含量呈现西南高东北低的特征,伊利石含量则与之相反;高岭石含量表现为近岸高离岸低,而绿泥石含量呈现离岸高近岸低的特征。总体上,研究区表层沉积物黏土矿物组成与现代珠江沉积物组成差异较大,而与珠江口2.5 ka前的沉积物黏土矿物组成比较接近,并且结合研究区岩心揭露的全新世以来极低的沉积速率（4 cm/ka）以及上部很薄（小于0.6 m）的泥质沉积,推测该区表层沉积物可能并非是现代沉积的结果,更可能主要来自全新世末期古珠江输送的沉积物。除古珠江作为研究区表层沉积物中蒙脱石的一个主要来源外,海南岛北部河流也贡献了少量蒙脱石到其邻近的东南海域。运用高岭石/伊利石比值和伊利石化学指数等进一步对比分析表明,珠江是研究区沉积物中伊利石、高岭石和绿泥石的主要物源,其次台湾和海南岛也可能分别提供了少量富含伊利石/绿泥石和高岭石的沉积物。本工作对于南海西北部沉积物源-汇过程和相应的古环境研究有重要的参考意义。     

南海粘土矿物组合特征及其环境意义

利用X射线衍射法(XRD)对南海12个海底表层沉积物和20个悬浮物样品中粘土矿物组成和分布特征进行了综合分析。结果表明:(1)研究区的表层沉积物粘土矿物以伊利石为主,其次为绿泥石、高岭石、伊/蒙间层矿物以及蒙皂石;悬浮物粘土矿物是以绿泥石为主,其次为高岭石、蒙皂石、伊利石以及伊/蒙间层矿物。(2)粘土矿物的组成和分布特征主要受气候条件、物质来源、水动力条件及相互间稀释作用的制约。伊利石的含量随离岸距离和水深的增加呈增大趋势;高岭石则在近岸区特别是河口区富集;绿泥石在西部沿岸海区的含量较低,在东部岛弧和北部台湾岛附近海区的含量较高;蒙皂石与火山作用密切相关,在东部火山岛弧附近海区含量较高。(3)粘土沉积物的来源以河流输入为主,海洋自生和风尘搬运对该区的沉积影响不大。(4)深海悬浮物粘土矿物的组成变化能够很好地指示短尺度气候环境的变迁,伊利石的结晶程度对气候和环境变化反映灵敏,其随所处环境的压力增大而变差。     

Ocean circulation patterns and dust supply into the South Atlantic during the last glacial cycle revealed by statistical analysis of kaolinite/chlorite ratios

Multivariate statistical analysis on the kaolinite/chlorite ratios from 20 South Atlantic sediment cores allowed for the extraction of two processes controlling the fluctuations of the kaolinite/chlorite ratio during the last 130,000 yrs, (1) the relative strength of North Atlantic Deep Water (NADW) inflow into the South Atlantic Ocean and (2) the influx of aeolian sediments from the south African continent. The NADW fluctuation can be traced in the entire deep South Atlantic while the dust signal is restricted to the vicinity of South Africa. Our data indicate that NADW formation underwent significant changes in response to glacial/interglacial climate changes with enhanced export to the Southern Hemisphere during interglacials. The most pronounced phases with Enhanced South African Dust Export (ESADE) occurred during cold Marine Isotope Stage (MIS) 5d and across the Late Glacial/Holocene transition from 16 ka to 4 ka (MIS 2 to 1). This particular pattern is attributed to the interaction of Antarctic Sea Ice extent, the position of the westerlies and the South African monsoon system.     

南海北部陆坡50 ka 以来黏土矿物来源与输运机制分析

在 AMS14C 定年的基础上,对南海北部 KNG5站和 KNG7站柱状沉积物中的粒度和黏土矿物进行了研究.KNG5孔黏土矿物组合的基本特点是以伊利石、绿泥石和高岭石为主,蒙脱石含量次之.而 KNG7孔黏土矿物组合的基本特点是以伊利石、绿泥石和蒙脱石为主,高岭石含量次之.物源分析进一步表明, KNG5和 KNG7孔高岭石主要来自于珠江,蒙脱石主要由吕宋岛提供,伊利石和绿泥石分别由珠江和台湾提供.相对于 KNG5孔而言, KNG7孔沉积物受珠江影响较小,而受台西南影响较大.由物源分析推测,珠江对南海北部的物源供应存在一个明显的界线,而这一界线可能位于 KNG5孔和KNG7孔之间,越过这一界线随着离岸距离的增加,南海北部陆坡陆源沉积物受珠江影响明显减弱,而主要由台湾贡献.     

Clay mineral distribution in surface sediments of the South Atlantic: sources, transport, and relation to oceanography

Surface samples, mostly from abyssal sediments of the South Atlantic, from parts of the equatorial Atlantic, and of the Antarctic Ocean, were investigated for clay content and clay mineral composition. Maps of relative clay mineral content were compiled, which improve previous maps by showing more details, especially at high latitudes. Large-scale relations regarding the origin and transport paths of detrital clay are revealed. High smectite concentrations are observed in abyssal regions, primarily derived from southernmost South America and from minor sources in Southwest Africa. Near submarine volcanoes of the Antarctic Ocean (South Sandwich, Bouvet Island) smectite contents exhibit distinct maxima, which is ascribed to the weathering of altered basalts and volcanic glasses. The illite distribution can be subdivided into five major zones including two maxima revealing both South African and Antarctic sources. A particularly high amount of Mg- and Fe-rich illites are observed close to East Antarctica. They are derived from biotite-bearing crystalline rocks and transported to the west by the East Antarctic Coastal Current. Chiorite and well-crystallized dioctaedral illite are typical minerals enriched within the Subantarctic and Polarfrontal-Zone but of minor importance off East Antarctica. Kaolinite dominates the clay mineral assemblage at low latitudes, where the continental source rocks (West Africa, Brazil) are mainly affected by intensive chemical weathering. Surprisingly, a slight increase of kaolinite is observed in the Enderby Basin and near the Filchner-Ronne Ice shelf.

The investigated area can be subdivided into ten, large-scale clay facies zones with characteristic possible source regions and transport paths. Clay mineral assemblages of the largest part of the South Atlantic, especially of the western basins are dominated by chlorite and illite derived from the Antarctic Peninsula and southernmost South America and supported by advection within the Circumantarctic Deep Water flow. In contrast, the East Antarctic provinces are relatively small. Assemblages of the eastern basins north of 30°S are strongly influenced by African sources, controlled by weathering regimes on land and by a complex interaction of wind, river and deep ocean transport. The strong gradient in clay mineral composition at the Brazilian slope indicate a relatively low contribution of tropically derived assemblages to the western basins.     

Eolian dust from the lower atmosphere of the eastern Atlantic and Indian Oceans,China Sea and Sea of Japan

Dust-loadings in the lower atmosphere of the Atlantic and Indian Oceans and the China Sea and Sea of Japan are given. Average dust-loadings decrease in the following order: North Atlantic (northeast trades, ～ 7.7 μg/m³ of air) > northern Indian Ocean (～ 1.2 μg/m³ of air) > South Atlantic (southeast trades, ～ 0.78 μg/m³ of air) = southern Indian Ocean (～ 0.68 μg/m³ of air) > China Sea (～ 0.21 μg/m³ of air).There are differences in the clay mineralogies of dusts transported in similar latitudes in the North Atlantic and northern Indian Oceans. Dusts in the Atlantic northeast trades are dominated by kaolinite from the soils of equatorial Africa; dusts in the northeast monsoons of the northern Indian Ocean have a source in the arid regions of the Rajasthan desert where illite is the principal clay mineral.In the regions investigated quartz occurs in larger amounts in the dusts of the Northern Hemisphere (～ 7% quartz) than those of the Southern Hemisphere (～ 3% quartz) over both the Atlantic and Indian Oceans.From the results given in the present paper and those reported in the literature a map is presented illustrating the order of magnitude of lower atmospheric dust-loadings in part of the world ocean.     

南海中南部表层沉积物黏土矿物分布及控制因素

利用南海中南部表层沉积物151个样品中黏土矿物的测试数据,计算了主要黏土矿物含量的平均值并编制分布图,据此分析黏土矿物的分布特征及其控制因素。南海中南部表层沉积物中的黏土矿物组合类型为伊利石-蒙脱石-高岭石-绿泥石,含量平均值依次为47%、19%、17%和16%。高岭石含量分布具有北部低、南部高的特点,与之对应的是蒙脱石矿物含量呈现北部高、南部低的趋势。伊利石和绿泥石含量分布规律不甚明显。前者呈现北部略高、南部稍低的分布趋势,含量变化起伏较大;后者的含量变化呈西北陆坡区稍偏低,其他部位含量分布均匀的趋势。伊利石/高岭石含量的比值变化与高岭石含量变化呈明显的负相关关系。从黏土矿物含量的分布规律来看,控制本区黏土矿物分布的主要因素有物源的搬运和输送、水动力条件变化、海底火山活动、地球化学环境影响等。     

闽江下游及河口区表层沉积物粘土矿物含量分布特征及其环境意义

为探究闽江下游及河口区粘土矿物的含量分布特征,于2009年在该区域采集表层沉积物样品25个,利用X射线衍射进行了粘土矿物的含量测定.结果表明粘土矿物的相对百分含量范围分别为：高岭石（33%-47%,平均值为42%）,伊利石（27%-43%,平均值为34%）,绿泥石（20%-29%,平均值为24%）,蒙脱石（0%-3%,平均值为1%）.在显著水平为0.01时,伊利石与高岭石、绿泥石的含量呈显著负相关关系,伊利石与高岭石的相关系数为-0.825,伊利石与绿泥石的相关系数为-0.611.通过对闽江下游及河口区粘土矿物含量分布的分析及与中国近海的粘土矿物含量分布对比,闽江下游及河口区粘土矿物的含量分布受物质来源、地形条件、介质环境、粘土矿物自身颗粒大小形态和人类活动的影响.相对于黄河和长江,闽江表层沉积物中具有较高的高岭石含量,较低的伊利石含量,与珠江的粘土矿物组合特征类似,这反映出气候效应的影响.     

Nature and composition of shore-zone sediments between Jeddah and Yanbu, eastern Red Sea

The shore-zone sediments between Jeddah and Yanbu, west coast of Saudi Arabia, are composed mostly of skeletal carbonate sands. The nearshore sediments containing benthic foraminifera, algal fragments and molluscs are multimodal, the mean grain size varying between 0.76 and 2.35 ø. The beach sediments, except samples dominated by cerithid gastropods in some localities, are relatively finer than the nearshore sediments. Although the beaches to a great extent comprise sand-sized material, fine lime muds and coarse clastic gravels occur in certain areas. The dune sediments comprising mostly algal grains and ooids are very fine with 50 percent of the material in the 0.25–0.18 mm size grade. Except a general northward decrease in mean grain size, regional trends in the textural parameters of the sediments between Jeddah and Yanbu are not quite apparent. Lateral variations in the textural characteristics suggest a landward migration of the sediments in the shore zone under the influence of northerly and northwesterly winds. The carbon and oxygen (δ ¹³C + 4.80 to 4.84‰ PDB) (δ ¹³O − 0.04 to + 0.53‰ PDB) isotopic ratios of the lime muds occurring in certain shallow margins in the shore-zone, which are much higher than those of the green algae, indicate that the fine carbonates are at least in part inorganic in origin.

Like the shallow-water carbonates in tropical seas, aragonite and high Mg-calcite are the dominant carbonate minerals in the shore-zone sediments. There is a landward increase in aragonite contents caused by the landward migration of fine material from the nearshore. The dominant clay mineral in the nearshore sediments is kaolinite with subordinate swelling chlorite and little illite. Kaolinite is contributed by the coastal regions under the sub-tropical humid climate. Swelling chlorite is considered to have been formed in the nearshore by mechanical mixture of chlorite and montmorillonite derived from the metamorphic and igneous terrains of the Tertiary mountains bordering the coastal plain.     

Mineralogical study of the core samples from the Indian Ocean,with special reference to the vertical distribution of clay minerals

The clay minerals in the 18 core samples collected from the northern, equatorial and southeastern Indian Ocean are illite, chlorite, montmorillonite and kaolinite. In the fraction finer than 2 in the surface layer (top to 5 cm deep) of each core, the relative abundance of clay minerals varies widely from area to area. Kaolinite possesses the maximum proportion of the clay mineral composition and chlorite has the minimum proportion.Kaolinite is particularly dominant in sediments near off the northwestern coast of Australia. In the factions finer and coarser than 2 of the surface layer, montmorillonite and kaolinite tend to be abundant in the fraction finer than 2, and chlorite and illite tend to be abundant in the fraction coarser than 2. In some cores, kaolinite-rich layers in sediments which are considered to have been transported by turbidity currents from the Bay of Bengal are found. Turbidity currents appear partly a role in transport of sediments to the equatorial Indian Ocean.As to the relation between the vertical change of clay mineral composition and geochronological data, montmorillonite and kaolinite tend to be more abundant in interglacial ages than in glacial ages, while illite and chlorite tend to exhibit opposite trend.Muscovite and biotite highly concentrated in the cores Ka-9 and Ka-15 collected from the equatorial Indian Ocean seem to originate from granite or gneiss of Ceylon and/or India.     

Effect of salinity on rheological and strength properties of cement-stabilized clay minerals

Abstract

This paper presents an experimental investigation into the effect of salinity on Atterberg limits, flowability, viscosity and strength properties of cement-stabilized clay minerals. Three groups of clay minerals (illite, kaolinite and montmorillonite) were obtained. Specimens with different porewater salinities were prepared by mixing the air-dried clays with sodium chloride (NaCl) at various salt concentrations (i.e., 0%, 2% 4%, 6% and 8%). Atterberg limits test results indicated that liquid limit and plasticity index decreased insignificantly with increasing salinity for Kaolinite and illite but significantly for montmorillonite. Flow test results indicated that of all specimens of three groups of clay minerals with or without adding cement consistently increase with increasing salinity. The flow value of montmorillonite increased more significantly than kaolinite and illite. Viscosity test results indicated that all the specimens tested behave as Bingham plastic. Flow value consistently decreased with increasing dynamic viscosity or yield stress, regardless of clay mineralogy, porewater salinity and cement amount. Strength test results indicated that all cement-stabilized specimens exhibit strain softening behavior. Unconfined compressive strength for three groups of clay minerals stabilized with cement consistently decreased with increasing salinity indicating that the presence of salt had an adverse effect on the development of strength.