广州麓湖大气多环芳烃的干湿沉降

以广州麓湖为小型城市湖泊的代表,对大气中多环芳烃的颗粒态沉降进行了连续一年的采样与分析. 结果表明,年均颗粒态多环芳烃的沉降通量为0.47mg/( m2·a). 全年直接由大气输入到麓湖的颗粒态多环芳烃总量约为0.1kg. 不同季节相比,夏季多环芳烃的沉降通量略高于秋季,而冬春季最高. 对比大气总悬浮颗粒物中多环芳烃的组成发现,当降雨量增大时,沉降颗粒物中多环芳烃的组成逐渐趋近于大气总悬浮物中多环芳烃的组成. 广州地区雨热同期、干冷咸至的季风气候特点,以及由此导致的大气颗粒物粒径变化和PAHs的气-粒分配变化,与大气PAHs污染程度一起,共同控制着沉降颗粒物中PAHs相对组成的季节变化.     

Modelling mixing and circulation in subglacial Lake Vostok,Antarctica

Lake Vostok, isolated from direct exchange with the atmosphere by about 4 km of ice for millions of years, provides a unique environment. This inaccessibility raises the importance of numerical models to investigate the physical conditions within the lake. Using a three-dimensional numerical model and the best available geometry, we test different parameter settings to define a standard model configuration suitable for studying flow in this subglacial lake. From our model runs we find a baroclinic circulation within the lake that splits into three different parts: Along a topographic ridge in the northern part of Lake Vostok, bottom water masses are transported eastward, diverging away from the ridge. In the lake’s surface layer, the flow in these two vertical overturning cells has opposite directions. In the southern part of the lake, where freezing occurs across about 3,500 km², two opposing gyres split the water column vertically. The general flow is stronger in the southern basin with horizontal velocities in the order of 1 mm/s. The strongest upwelling, found in the eastern part of this basin, is about 25 μm/s. We estimate the lower limit of the overturning timescale to be about 2.5 years vertically and 8.6 years horizontally. The basal mass loss of ice from the ice sheet floating on the lake is 5.6 mm/year (equivalent to a fresh water flux of 2.78 m³/s, or a basal ice loss of 0.09 km³/year). This imbalance indicates either a constant growth of the lake or its continuous (or periodical) discharge into a subglacial drainage system.     

Low carbon dioxide partial pressure in a productive subtropical lake

The purposes of this study were to assess if Lake Apopka (FL, USA) was autotrophic or heterotrophic based on the partial pressure of dissolved carbon dioxide (pCO₂) in the surface water and to evaluate factors that influence the long-term changes in pCO₂. Monthly average pH, alkalinity and other limnological variables collected between 1987 and 2006 were used to estimate dissolved inorganic carbon (DIC), pCO₂ and CO₂ flux between surface water and atmosphere. Results indicated that average pCO₂ in the surface water was 196 μatm, well below the atmospheric pCO₂. Direct measurements of DIC concentration on three sampling dates in 2009 also supported pCO₂ undersaturation in Lake Apopka. Supersaturation in CO₂ occurred in this lake in only 13% of the samples from the 20-year record. The surface-water pCO₂ was inversely related to Chl a concentrations. Average annual CO₂ flux was 28.2 g C m⁻² year⁻¹ from the atmosphere to the lake water and correlated significantly with Chl a concentration, indicating that biological carbon sequestration led to the low dissolved CO₂ concentration. Low pCO₂ and high invasion rates of atmospheric CO₂ in Lake Apopka indicated persistent autotrophy. High rates of nutrient loading and primary production, a high buffering capacity, a lack of allochthonous loading of organic matter, and the dominance of a planktivorous–benthivorous fish food web have supported long-term net autotrophy in this shallow subtropical eutrophic lake. Our results also showed that lake restoration by the means of nutrient reduction resulted in significantly lower total phosphorus (TP) and Chl a concentrations, and higher pCO₂.     

多环芳烃在城市湖泊气-水界面上的交换

利用大流量采样器和半渗透膜装置对广州麓湖大气中气态多环芳烃和水体中溶解态多环芳烃进行了连续一年的观测,在此数据基础上,依据国内外通用的双膜理论计算了多环芳烃在广州麓湖水面上的交换通量.结果显示萘、苊、二氢苊的交换通量方向是由湖水挥发进入大气,其它主要化合物都是从大气进入水体;在单个化合物的交换通量中,以菲的通量值为最大,平均达13137.1ng/(m2·d),最高达到21211.22ng/(m2·d),其次为萘、荧蒽、蒽、芘、芴、二氢苊和苊等.各化合物交换通量的季节变化特点大部分都是在夏季达到最大值,在冬季交换通量降到最小值,但唯一例外的是芴,其交换通量却是在夏季降到最低值.     

Nutrient Budgets,Dynamics and Storm Effects in a Eutrophic,Stratified Baltic Lake

Between 1989 and 1998 the small eutrophic stratified Lake Belau was investigated intensively and multidisciplinarily. This article is a short, comprehensive summary and re‐evaluation of the hydrochemistry of the lake, with focus on nitrogen and phosphorus. In several aspects the lake can be regarded as a typical example of the glacial north German lakes. The 1960's and 1970's are characterised by heavy nutrient inputs and fast eutrophication. During the last two decades the external nutrient load, especially the phosphorus load into Lake Belau was significantly reduced. But phosphorus‐rich sediments and large areas with summerly anoxic sediment surface conditions cause intensive release of phosphorus from older deeper sediment layers. Annual budgets reveal that despite an average sediment accumulation of 3 mm a^?1 the lake has lost its function as net phosphorus sink and it is very likely that internal eutrophication by the sediments will keep the lake in its eutrophic state during the next decades. Despite that, monthly budgets of five vertical layers show that the main phosphorus supplier for the phosphorus depleted epilimnion during summer is the creek Alte Schwentine. The annual nitrogen budget indicates groundwater and interflow water as well as atmospheric input as additional important nitrogen sources. 36% (98 μmol m ^?2 h^?1 N) of all nitrogen input is lost to atmosphere mainly due to denitrification. The example of a heavy storm shows that about 10% of the annual nitrogen loss to the atmosphere can take place during a single day and in form of ammonia. The storm further made obvious that these unpredictable events can have strong impact on nutrient cycling and ecology in Lake Belau and the lake can become an unexpected nutrient source for downstream systems.     

The Oxygen Cycle in Lake Baikal

The oxygen cycle and the balance of free oxygen and oxygen bound in CO₂in Lake Baikal are discussed based on new data on the gas exchange between the lake and atmosphere, O₂consumption in bottom sediments, and the rate of aerobic decomposition in the abyssal zone of the lake.     

滇池沉水植物的分布格局及其水环境影响因子识别

研究滇池沉水植物的分布及其与水环境因子的关系,对于滇池沉水植物的恢复具有重要的指导意义.2016年4-11月对滇池24个典型点位沉水植物群落特征进行调查,共发现16个调查区存在9种沉水植物,以篦齿眼子菜(Potamogeton pectinatus)、微齿眼子菜(P.maackianus)、穗花狐尾藻(Myriophyllum spicatum)、轮叶黑藻(Hydrilla verticillata)、马来眼子菜(P.wrightii)等为主,沉水植物主要分布在近岸3 m以内水域,盖度在10%左右.主成分分析结果表明,总氮、总磷、悬浮物、化学需氧量和叶绿素a浓度是影响沉水植物种类和生物量的主要因素,透明度是影响沉水植物盖度的主要因素;典范对应分析结果显示,滇池沉水植物的分布主要受水体中营养盐含量和化学需氧量的影响,穗花狐尾藻和轮叶黑藻对有机物和藻类的耐受能力较强,马来眼子菜和篦齿眼子菜适于生长在高营养盐的环境.滇池沉水植物恢复初级阶段的关键是降低水体中化学需氧量、抑制藻类的生长,其次是控制水体营养盐浓度.按照"一区一策"的原则,草海东风坝内和外海南部适于进行沉水植物恢复,外海北部实行控藻治理,外海东部需改善水体有机物浓度和营养盐条件,外海西部以沉水植物自然保育为主.     

Water Quality and Phosphorus Budget of Mogan Lake,Turkey

Mogan Lake is the largest recreational area near Ankara, which is the capital city of Turkey. Increased macrophyte growth in the water body and the present levels of urban development within the catchment are reflected in declining water quality and aesthetic deterioation. A study of the water quality of the lake was undertaken to quantify the variation of phosphorus, nitrogen, and chlorophyll-a concentrations during ice-free seasons from 1992 to 1994. Its total phosphorus and chlorophyll-a concentrations indicate a meso-eutrophic status. The total phosphorus budget of Mogan Lake was measured for a period of 22 months. The estimation of nutrient loading using Dillon-Rigler nutrient budget shows that an artificial load caused too high phosphorus inputs. The management implications of phosphorus loading and budget are discussed.     

洞庭湖冲淤变化分析(1956-1995年)

根据１９５６－１９９５年洞庭湖水文泥沙原型观测和地形测绘等翔实资料,运用输沙量法和地形法对洞庭湖冲瘀变化进行了认真的统计分析,分析结果表明,洞庭湖来水量以四水为主,占５７．８％,来沙量以四口为主,多年平均沉积率为７４．０％,出湖仅占２６．０％;淤积量及湖水沙量随着四分流分沙比的减少而减少。     

Snow pollution in Lake Baikal water area in nearby land areas

The extent of the effect of technogenic sources in the Baikal Natural Territory on Lake Baikal water area and coastal zone is assessed. Regional pollution from sources remote from the lake migrates over tens of kilometers in accordance with wind rose and transforms into local in the water protection zone of Lake Baikal. Snow pollution in lake water area has been recorded near the coastal populated localities Listvyanka, Kultuk, Baikal’sk, Slyudyanka, Ust’-Barguzin, Severobaikal’sk, Nizhneangarsk, and at Selenga R. mouth and found to have a local character. The southern depression ranks first in terms of the input of NO₂, NO₃, NH₄, PO₄, F, Al, Na, Ba, Mo, Mn, Pb, Cu, Zn, Sr, Hg, and oil products onto lake water area through the atmosphere. However, larger amounts of SO₄, H₂CO₃, Cl, Ca, Mg, and K falls onto the northern depression, and more Be, V, Cr, and Co falls onto the middle part, because of the operation of coastal enterprises, boiler-houses, TPPs, stove heating, motor-car emissions, and natural transport of dust in low-snow areas. Data on the past 15 years show the pollution to drop by half in the late 1990s and early 2000s because of industrial decline. However, a small increase in regional pollution by individual components could be seen in the recent 5 years.     

The macrobenthos of Lake Ontario during 1964 to 1966, and subsequent changes in the deepwater community

From January 1964 through January 1966, Dr. F.P. Ide and colleagues at the University of Toronto Great Lakes Institute (GLI) collected benthic macroinvertebrates from up to 63 stations during each of 16 cruises on Lake Ontario. This intensive survey was conducted at a time of rapidly increasing anthropogenic impact. Total invertebrate abundance decreased with increasing depth; this distribution was bimodal on the northern side of the lake, with peaks at ca. 35 and 80 m. Oligochaeta were more abundant along the southern than on the northern side of the lake, except in Humber Bay. The amphipodDiporeia was rarely collected at most stations near the mouth of the Niagara River. Chironomidae were most abundant in the Kingston Basin but were common throughout the lake at depths less than 50 m. Sphaeriidae were confined to water <100 m deep and were most abundant along the southern shore. When compared with the results of subsequent surveys of the deepwater zone, the GLI data provide evidence of two major shifts in the abundance of benthic animals. Numbers of Oligochaeta decreased by about 40% during 1965 and remained at the lower levels through 1990. The abundance ofDiporeia changed little from 1964 through 1977, but increased sharply between 1977 and 1981. These shifts do not appear to reflect implementation of controls on the discharge of phosphorus, or direct predation by fish. Changes in fish and zooplankton communities and inputs of toxic contaminants seem equally likely to be responsible for the shifts in the deepwater benthic community. We have proposed several predictions which could test the relative importance of biotic interactions or chemical stressors.     

Revisiting lake sediment budgets: How the calculation of lake lifetime is strongly data and method dependent

Lake sedimentation has a fundamental impact on lake lifetime. In this paper, we show how sensitive calculation of the latter is to the quality of data available and assumptions made during analysis. Based on the collection of a large new dataset, we quantify the sediment masses (1) mobilized on the hillslopes draining towards Lake Tana (Ethiopia), (2) stored in the floodplains, (3) transported into the lake, (4) deposited in the lake and (5) delivered out from the lake so as to establish a sediment budget. In 2012–2013, suspended sediment concentration (SSC) and discharge measurements were made at 13 monitoring stations, including two lake outlets. Altogether, 4635 SSC samples were collected and sediment rating curves that account for land cover conditions and rainfall seasonality were established for the 11 river stations, and mean monthly SSC was calculated for the outlets. Effects of the floodplain on rivers' sediment yield (SY) were investigated using measurements at both sides of the floodplains. SY from ungauged rivers was assessed using a model that includes catchment area and rainfall, whereas bedload and direct sediment input from lake shores were estimated. As a result, the gross annual SY was c. 39.55 (± 0.15) Mt, dominantly from Gilgel Abay and Gumara Rivers. The 2.57 (± 0.17) Mt sediment deposited in floodplains indicate that the floodplains serve as an important sediment sink. Moreover, annually c. 1.09 Mt of sediment leaves the lake through the two outlets. Annual sediment deposition in the lake was c. 36.97 (± 0.22) Mt and organic matter accumulation was 2.15 Mt, with a mean sediment trapping efficiency of 97%. Furthermore, SSC and SY are generally higher at the beginning of the rainy season because soils in cultivated fields are bare and loose due to frequent ploughing and seedbed preparation. Later in the season, increased crop and vegetation cover lead to a decrease in sediment production. Based on the established sediment budget with average rainfall, the lifetime of Lake Tana was estimated as 764 to 1032 years, which is shorter than what was anticipated in earlier studies. The sedimentation rate of Lake Tana (11.7 ± 0.1 kg m^?2 yr^?1) is in line with the sedimentation rates of larger lakes in the world, like Lake Dongting and Lake Kivu. Copyright © 2017 John Wiley & Sons, Ltd.     

广州麓湖水-气界面多环芳烃的通量分析

利用干湿沉降采样器、大流量采样器和半渗透膜装置对广州麓湖大气干湿沉降、大气中气态和颗粒态多环芳烃以及水体中溶解态多环芳烃进行了连续一年的采样监测,并在此数据基础上依据多环芳烃在大气和水体间的作用规律,计算了广州麓湖水-气界面上多环芳烃的交换通量．结果显示,每年大气将向麓湖中输送约1300g的多环芳烃,主要以菲为主,占总量的60%以上．而湖水向大气挥发约220g的多环芳烃,主要以萘为主,占总挥发的95%．不同化合物在气水交换中的主要作用方式是不同的,2-3环的化合物主要以气水界面交换为主,5-6环的化合物以颗粒物沉降为主．而4环的化合物则以三种方式并存．不同季节,除了4环的化合物的各种作用方式所占地比重有所变化外,其它化合物变化不大．     

环太湖江苏段入湖河道污染物通量与湖区水质的响应关系

基于2008-2018年环太湖江苏段入湖河道污染物通量及湖区水质数据,从时空变化及相关关系两个方面探讨了入湖污染物通量与湖区水质的响应关系,并分析了污染物进入湖体影响水质的主要因子.结果表明:太湖污染减排已见成效,氨氮、总氮、高锰酸盐指数和化学需氧量入湖污染物通量整体呈下降趋势,年均下降率分别为8.0%、2.0%、1.6%和2.2%,湖体氨氮和总氮时间格局响应较好,年均下降率分别为2.1%和2.3%.湖体氨氮、总氮、总磷、高锰酸盐指数和化学需氧量与入湖污染物通量整体由西北部、西部湖区向东南部、东部湖区递减,空间格局上响应基本一致.全湖区年尺度总氮、氨氮浓度与入湖河道污染物通量分别呈显著正相关、极显著正相关关系;影响湖区总氮、氨氮的主要因子为入湖河道的总氮、氨氮浓度,其次为入湖河道浓度与原湖区水质差值,因此亟需加强入湖河道水质浓度的控制.     

三峡工程运行前后洞庭湖水质变化分析

为了解三峡工程运行前后洞庭湖水质变化,基于1996 2013年洞庭湖水质监测数据,采用内梅罗污染指数(IP)法对三峡工程运行前后洞庭湖水质进行评价,并对洞庭湖水质与主要污染物的时空变化特征进行分析.结果表明,1996 2013年洞庭湖IP值在1.10~2.20之间,平均值为1.63,水质属轻污染~污染,总体变化平稳,但从2010年起,洞庭湖IP值连续低于其多年平均值,总体水质趋好;主要污染物为总磷和总氮,总磷浓度变化平稳,总氮浓度则呈显著上升趋势.与三峡工程运行前相比,三峡工程运行后洞庭湖全年和汛期总氮浓度以及南洞庭湖IP值和总氮浓度显著升高,南洞庭湖水质显著恶化.洞庭湖IP值和总磷浓度的水期分布格局均由三峡工程运行前的汛期非汛期变化为三峡工程运行后的非汛期汛期,其空间分布格局均由三峡工程运行前的西洞庭湖东洞庭湖南洞庭湖变化为三峡工程运行后的西洞庭湖南洞庭湖东洞庭湖;从2010年起,洞庭湖IP值的空间分布格局发生新的变化,其大小顺序变化为东洞庭湖南洞庭湖西洞庭湖.三峡工程运行前后洞庭湖IP值与总磷浓度的时空变化与其水沙条件变化有关,总氮浓度的空间分布受三峡工程运行影响较小,主要受湘江、资水等"四水"流域氮污染的影响.     

Diurnal Variations in the Rate of Gas Exchange between Lake Baikal and the Atmosphere

The diurnal course of gas exchange between Lake Baikal and the atmosphere during the summer warming up is calculated using the data of continuous 102-hour observations in August 2000 and the published materials of individual diurnal measurements of the dissolved gases concentrations made in different years. The diurnal course of the rate of gas exchange in both the coastal and open parts of the lake is found to be due to the fact that slow gas-exchange processes fail to compensate fast changes in the partial pressures of gases dissolved in the upper water layer. The changes are associated with the diurnal dynamics of the hydrometeorological conditions and the intensity of the production–destruction processes. It is found that under light winds, the contribution of biological factors to the formation of short-period variations in the CO₂ and O₂ fluxes through the lake water surface makes about 80% and that of abiotic factors, 20%. Considerable aperiodic changes in the diurnal course of hydrometeorological conditions are found to essentially distort the normal diurnal course of the gas-exchange processes.     

The spatial distribution of sedimentary compounds and their environmental implications in surface sediments of Lake Khar Nuur (Mongolian Altai)

Lake sediments are valuable natural archives to reconstruct paleoclimate and paleoenvironmental changes which consist of inorganic and organic sediment compounds of allochthonous origin from the catchment and of autochthonous production in the lake. However, for robust paleo-reconstructions it is important to develop a better understanding about sedimentation processes, the origin of inorganic and organic sediment compounds and their distribution within the lake. In this context, modern process studies provide important insights, although environmental and anthropological changes can affect the spatial distribution of sediment compounds through time. Therefore, in this study the spatial distribution of grain size and geochemical proxies in 52 surface sediment samples from Lake Khar Nuur, a small high-altitude lake in the Mongolian Altai with a small and anthropogenically used hydrological catchment, is investigated. The results show a distinct sediment focussing in the two deep basins of the lake, which therefore act as accumulation zones. In those accumulation zones, total organic carbon (TOC), total nitrogen (N) and their isotopic composition (δ¹³C_TOC, δ¹⁵N) as well as n-alkanes indicate that organic sediment compounds are a mixture of both allochthonous and autochthonous origin. While the recent catchment vegetation consists of grasses/herbs and the shrub Betula nana (L.) with distinct differences in their n-alkane homologue patterns, those differences are not reflected in the sediment surface samples which rather indicates that grass-derived n-alkanes become preferentially incorporated in the lake. Extensive anthropogenic activity such as grazing and housing in the southern part of the catchment causes soil erosion which is well reflected by high TOC, N and sulphur (S) contents and ¹⁵N depleted δ¹⁵N values at the central southern shore, i.e. increased allochthonous sediment input by anthropogenically-induced soil erosion. Overall, the surface sediments of Lake Khar Nuur origin from allochthonous and autochthonous sources and are focussed in the accumulation zones of the lake, while their distribution is both environmentally and anthropogenically driven.     

Modeling spring-summer phytoplankton bloom in Lake Michigan with and without riverine nutrient loading

There were two phytoplankton blooms captured by remote sensing in Lake Michigan in 1998, one from March to May, and one during June. In this paper, those phytoplankton blooms were simulated by a coupled physical–biological model, driven by observed meteorological forcing in 1998. The model reasonably reproduced the lake currents. The biological model results, with and without riverine nutrient loading, were compared with the remote sensing data. A 3-month-long donut-like phytoplankton bloom that appeared in southern Lake Michigan was reasonably well simulated only when riverine input was included, indicating the importance of riverine nutrient input for supporting the growth of phytoplankton in Lake Michigan. The model with riverine input also captured a second event-driven phytoplankton bloom during June with weaker magnitude that occurred in mid-south Lake Michigan, which lasted for about 20 days. The major reason for the weaker bloom in June was that vertical mixing in the hydrodynamic model was too weak (leading to a mixed-layer depth of 20 m) to bring the bottom nutrient-rich water up to the epilimnion. High chlorophyll concentration that persisted in Green Bay for almost a year was simulated with less intensity.     

Michigan basin regional ground water flow discharge to three Great Lakes

Ground water discharge to the Great Lakes around the Lower Peninsula of Michigan is primarily from recharge in riparian basins and proximal upland areas that are especially important to the northern half of the Lake Michigan shoreline. A steady-state finite-difference model was developed to simulate ground water flow in four regional aquifers in Michigan's Lower Peninsula: the Glaciofluvial, Saginaw, Parma-Bayport, and Marshall aquifers interlayered with the Till/"red beds," Saginaw, and Michigan confining units, respectively. The model domain was laterally bound by a continuous specified-head boundary, formed from lakes Michigan, Huron, St. Clair, and Erie, with the St. Clair and Detroit River connecting channels. The model was developed to quantify regional ground water flow in the aquifer systems using independently determined recharge estimates. According to the flow model, local stream stages and discharges account for 95% of the overall model water budget; only 50% enters the lakes directly from the ground water system. Direct ground water discharge to the Great Lakes' shorelines was calculated at 36 m3/sec, accounting for 5% of the overall model water budget. Lowland areas contribute far less ground water discharge to the Great Lakes than upland areas. The model indicates that Saginaw Bay receives only approximately 1.13 m3/sec ground water; the southern half of the Lake Michigan shoreline receives only approximately 2.83 m3/sec. In contrast, the northern half of the Lake Michigan shoreline receives more than 17 m3/sec from upland areas.     

The effect of drawdown on suspended solids and phosphorus export from Columbia Lake,Waterloo, Canada

This study examines the effect of drawdown on the timing and magnitude of suspended solids and associated phosphorus export from a 12 ha reservoir located in an urbanized watershed in southern Ontario, Canada. Water level in Columbia Lake was lowered by 1·15 m over a 2‐week period in November 2001. The total phosphorus (TP) concentrations ranged from 63 to 486 µg L^?1 in Columbia Lake and 71 to 373 µg L^?1 at its outflow. All samples exceeded the Provincial Water Quality Objective of 30 µg TP L^?1. Outflow concentrations of suspended solids and TP increased significantly with decreasing lake level and were attributed to the resuspension of cohesive bottom sediments that occurred at a critical threshold lake level (0·65 m below summer level). Suspended solids at the outflow consisted of flocculated cohesive materials with a median diameter (D₅₀) of c. 5 µm. Particulate organic carbon accounted for 8·5% of the suspended solids export by mass. A total mass of 18·5 t of suspended solids and 62·6 kg TP was exported from Columbia Lake, which represents a significant pulse of sediment‐associated P to downstream environments each autumn during drawdown. The downstream impacts of this release can be minimized if the water level in Columbia Lake is lowered no more than 0·5 m below summer levels. Copyright © 2004 John Wiley & Sons, Ltd.