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1.
Yiyang Zhao 《中国地球化学学报》1982,1(3):338-342
The following conclusions can be drawn from the work reported in this paper:
- Sixteen samples were determined for uranium by spectrophotometric method. The uranium content in the sea floor sediments of the Bohai Gulf ranges from 1.6 to 6.3 ppm, with an average of 4.3 ppm.
- Statistical data show close relationship between U concentration and grain size. Relatively larger amount of uranium was found accumulated in mud than in sand. The bulk of uranium is assumed to be derived from terrestrial detrital minerals.
- A positive correlation between U and Fe is recognized. Similar relation also can be seen between U and Al. The plot of U concentration vs. Fe is linear, and can be expressed by the linear regression equation:Y=?0.37+1.35X. The plot of U against Al gives an equation ofY=?2.48+1.01X.
- The average U/Corg. ratio for these sediments is 7×10?4, and the average ratios of U/P, U/Mn, and U/CaCO3 are 100×10?4, 50×10?4 and 2×10?4, respectively.
- Compared with the abundances of other shelf sediments, the average concentration of U in the area under consideration is close to that of sediments on the selves of Japan and the Gulf of Mexico, and the Black Sea. Uranium concentration in the Bohai Gulf sediments is comparable to that of the continental crust, but differs from that of deep-sea clay.
2.
Detailed sedimentological investigations were performed on sediments from DSDP-Site 594 (Chatham Rise, east of New Zealand) in order to reconstruct the evolution of paleoclimate and paleoceanographic conditions in the Southwest Pacific during the last 6 million years. The results can be summarized as follows:
- High accumulation rates of biogenic opal and carbonate and the dominance of smectites in the clay fraction suggest increased oceanic productivity and an equable dominantly humid climate during the late Miocene.
- During Pliocene times, decreasing contents of smectites and increasing feldspar/quartz ratios point to an aridification in the source area of the terrigenous sediments, culmunating near 2.5 Ma. At that time, accumulation rates of terrigenous components distinctly increased probably caused by increased sediment supply due to intensified atmospheric and oceanic circulation, lowered sea level, and decreased vegetation cover.
- A hiatus (1.45 to 0.73 Ma) suggests intensified intermediate-water circulation.
- Major glacial/interglacial cycles characterize the upper 0.73 Ma. During glacial times, oceanic productivity and terrigenous sediment supply was distinctly increased because of intensified atmospheric and oceanic circulations and lowered sea level, whereas during interglacials productivity and terrigenous sediment supply were reduced.
- An increased content of amphibols in the sediments of Site 594 indicates increased volcanic activities during the last 4.25 Ma.
3.
E. H. Brown 《Contributions to Mineralogy and Petrology》1977,64(2):123-136
Phase relations of pumpellyite, epidote, lawsonite, CaCO3, paragonite, actinolite, crossite and iron oxide are analysed on an Al-Ca-Fe3+ diagram in which all minerals are projected from quartz, albite or Jadeite, chlorite and fluid. Fe2+ and Mg are treated as a single component because variation in Fe2+/Mg has little effect on the stability of phases on the diagram. Comparison of assemblages in the Franciscan, Shuksan, Sanbagawa, New Caledonia, Southern Italian, and Otago metamorphic terranes reveals several reactions, useful for construction of a petrogenetic grid:
- lawsonite+crossite + paragonite = epidote+chlorite + albite + quartz + H2O
- lawsonite + crossite = pumpellyite + epidote + chlorite + albite+ quartz + H2O
- crossite + pumpellyite + quartz = epidote + actinolite + albite + chlorite + H2O
- crossite + epidote + quartz = actinolite + hematite + albite + chlorite + H2O
- calcite + epidote + chlorite + quartz = pumpellyite + actinolite + H2O + CO2
- pumpellyite + chlorite + quartz = epidote + actinolite + H2O
4.
Laihunite Research Group 《中国地球化学学报》1982,1(1):105-114
Laihuite reported in the present paper is a new iron silicate mineral found in China with the following characteristics:
- This mineral occurs in a metamorphic iron deposit, associated with fayalite, hypersthene, quartz, magnetitc, etc.
- The mineral is opaque, black in colour, thickly tabular in shape with luster metallic to sub-metallic, two perfect cleavages and specific gravity of 3.92.
- Its main chemical components are Fe and Si with Fe3+>Fe2+. The analysis gave the formula of Fe Fe 1.00 3+ ·Fe 0.58 2+ ·Mg 0.03 2+ ·Si0.96O4.
- Its DTA curve shows an exothermic peak at 713°C.
- The mineral has its own infrared spectrum distinctive from that of other minerals.
- This mineral is of orthorhombic system; space group:C 2h /5 ?P21/c; unit cell:α=5.813ű0.005,b=4.812ű0.005,c=10.211ű0.005,β=90.87°.
- The Mössbauer spectrum of this mineral is given, too.
5.
6.
Dr. W. -A. Flügel 《GeoJournal》1983,7(4):341-351
During the “Heidelberg-Ellesmere-Island-Expedition” to Oobloyah Valley, N-Ellesmere Island, NWT, Canada in 1978 the summerly water balance of this high arctic catchment area with continuous permafrost was investigated. The following results will be presented:
- Three hydrogeological areas with different physical parameters, thawing depths and drainage are distinguished and studied on slope I, II and slope III.
- The climatic situation of summer 1978 was mainly influenced by the change of radiating and cloudy periods. Due to air temperatures (2 m above ground), which never went below 0°C, these periods regulated the thawing of the glaciers and the respective run-off.
- Most of the winterly snow cover melted before July, thereafter soil thawing and its drainage began. In none of the sediments the latter reached field capacity.
- Considering the course of daily discharge and soil water balance the three studied streams were characterized by the “Dry-Weather-Discharge-Line”, DWL, of Peri-Creek the “Radiation-Weather-Discharge-Line”, RWL, and the “Cloudy-Weather-Discharge-Line”, CWL, of Nukapingwa River and Heidelberg River.
- The periglacial streams never had a measurable sediment load not even during snow melt, whereas the glacial and mixed glacial-periglacial streams as Nukapingwa River and Heidelberg River showed a sediment drift depending on their run-off. Only in Peri-Creek the ion concentrations were correlated to discharge.
- Precipitation (snow plus rain) add up to 51% of the summerly water balance. The glaciers contributed up to 48%, and the actual evapotranspiration is only 1%.
7.
Shijian Liu 《GeoJournal》1994,34(1):47-54
Debris flow is a natural phenomenon which occurs on steep slopes of mountain regions. Very often morainic material and nonmorainic sediments, such as debris flow material, fluvial and other sediments, are mixed in the marginal mountain systems of the Tibetan Plateau. The study of quartz-grain surface features of debris flow has an important significance for differentiating between different origins of Quaternary sediments. Features of quartz-grain in debris flow will be described as below:
- The predominant shapes of quartz grains are irregular.
- The degree of roundness of grains is in general are angular to subangular in shape.
- The textures of quartz-grains in debris flows are conchoidal fractures, parallel steps and mechanical V-marks. Parallel steps are especially abundant. Their presence is the most characteristic indicator of debris flow sand, aiding in the differentiation between debris flow and glacial sand.
- Fresh cleavage planes are extremely flat.
8.
The occurrence of talc and tremolite in a temperature gradient was investigated in siliceous calcite-dolomite sediments exposed along a strip in the southeastern part of the Damara Orogen. Five bivariant reactions may lead to the formation of talc and tremolite:
- 3 dolomite+4 quartz+1 H2O ? 1 talc+3 calcite+3 CO2
- 5 talc+6 calcite+4 quartz ? 1 tremolite+6 CO2+2 H2O
- 2 talc+3 calcite ? 1 tremolite+1 dolomite+1 CO2+1 H2O
- 5 dolomite+8 quartz+1 H2O ? 1 tremolite+3 calcite+7 CO2
- 2 dolomite+1 talc+4 quartz ? 1 tremolite+4 CO2.
9.
Gert Hoschek 《Contributions to Mineralogy and Petrology》1974,47(4):245-254
P, T, \(X_{{\text{CO}}_{\text{2}} }\) relations of gehlenite, anorthite, grossularite, wollastonite, corundum and calcite have been determined experimentally at P f =1 and 4 kb. Using synthetic starting minerals the following reactions have been demonstrated reversibly
- 2 anorthite+3 calcite=gehlenite+grossularite+3 CO2.
- anorthite+corundum+3 calcite=2 gehlenite+3 CO2.
- 3anorthite+3 calcite=2 grossularite+corundum+3CO2.
- grossularite+2 corundum+3 calcite=3 gehlenite+3 CO2.
- anorthite+2 calcite=gehlenite+wollastonite+2CO2.
- anorthite+wollastonite+calcite=grossularite+CO2.
- grossularite+calcite=gehlenite+2 wollastonite+CO2.
10.
A. Lacam 《Physics and Chemistry of Minerals》1985,12(1):23-28
Synthetic olivines, with composition Fa50, Fa75 and Fa100, have been transformed into spinel in a laser-heated diamond-cell at pressures from 70 to 200 kbar and at a luminance temperature of about 1,200° C. The electrical conductivity σ was measured, at room temperature and up to 200 kbar, on olivine (Lacam 1982; 1983) and spinel (present study). The data obtained permit the following conclusions:
- Sample nature effect: under the same conditions (composition, pressure), the σ of spinel is more than three orders of magnitude of the σ of olivine.
- Composition effect: there are more than three orders of magnitude between the values of σ for spinels derived from initial compositions of Fa50 and Fa100, respectively.
- Pressure effect: The P-effect on σ is greater for olivines than for spinels.
11.
Prof. Dr. Werner Schneider Dr. Dieter Schumann Dipl.-Miner. 《International Journal of Earth Sciences》1979,68(2):631-648
From 14 deeps and other regions of the Red Sea totally 226 samples from 28 cores recovered during the VALDIVIA cruises (1971, 1972) were investigated according to their clay mineral content (<2μm resp. < 6.3 μm) after carbonate dissolution. Three facies groups are to distinguish:
- normal sediments: dominance of chlorite, kaolinite, illite, small amounts of smectite and sepiolite. Two palygorskite types are present only in a few samples.
- normal sediments with hydrothermal influence: clay mineral paragenesis similar like that of normal sediments; but increase of smectite and presence of goethite in each sample; partly small contents of talc.
- heavy metal deposits: dominance of iron-bearing smectite, partly with amorphous components resp. pure ore mineral assemblages with authigenic silicates (talc, quartz, opal, chrysotile, sepiolite, palygorskite, chlorite).
12.
Dr. M. Pécsi 《GeoJournal》1987,15(2):151-162
The loess of type localities is subdivided into 3 subseries on the basis of the paleosols allowing even an Eurasian comparison for their lithostratigraphy.
- The upper young loess (8–10 m) is most widespread, characterized by 3 sandy loess and 2 intercalated humic loess horizons. The ages of the humic loess horizons H1, H2 are c. 16 ka and 20 ka BP, respectively.
- The lower young loess (15–20 m) contains 4 loess packets and 3 chernozem-like paleosols, usually doubled soil complexes (designated MF, BD, BA). The MF paleosol complex, first member of lower young loess is c. 27–28 ka BP (C14 and TL dating). The lower young loess is underlain by a brown forest soil and chernozem-like paleosol-assemblage (MB), probably formed during the last interglacial (c. 105–125 ka BP).
- The old loess (c. 20 m) is generally characterized by 6–7 loess, mainly brown forest soil and 2 interbedded fluvial sand layers. The lowermost old loess member and an ochre-red paleosol lie below the Brunhes-Matuyama boundary (0,73 Ma).
- The loess is underlain by a subaerial non-loessic sequence (20–40 m) with 5–10 red soils, red clays mostly directly superimposed on and locally interbedded by sand and silty sand. At the base of this sequence of red paleosols usually Uppermost Miocene inland sea deposits are found.
13.
Niranjan D. Chatterjee Ludger Terhart 《Contributions to Mineralogy and Petrology》1985,89(2-3):273-284
The system MgO-Al2O3-SiO2(MAS) comprises 88–90% of the bulk composition of an average peridotite. The MAS ternary is thus a suitable starting point for exploring peridotite phase relations in multicomponent natural systems. The basic MAS phase relations may be treated in terms of the reactions (see list of symbols etc).
- py (in Gt)=en (in Opx)+mats (in Opx),
- en (in Opx)+sp (in Sp)=mats (in Opx)+fo (in Ol), and
- py (in Gt)+fo (in Ol)=en (in Opx)+sp (in Sp).
- binary Sp (sp-pc) crystalline solution (Oka et al. 1984),
- ternary Opx (en-mats-mcts) crystalline solution (this study), and
- binary Gt (py-kn) crystalline solution (this study).
- With increasing incorporation of Cr+3 into Sp and Gt, the X mats isopleths of the reactions (1) and (2) are shifted to higher temperatures (Fig. 3a); simultaneously, the spinel-peridotite to garnet-peridotite phase transition is moved to higher pressures (Fig. 3b).
- At identical P and T, the X mats values of Opx coexisting in equilibrium with Ol and Sp is strongly dependent upon the X pc value in the latter phase (Figs. 4a and b). Accurate correction for the composition of Sp is, therefore, a necessary precondition for geothermometry of the spinelperidotites.
- The discrepant temperatures reported by Sachtleben und Seck (1981, Fig. 5) from the spinel-peridotites of the Eifel area (systematically too high temperatures as a function of X pc in Sp) are demonstrated to be the result of ignoring the nonideality in the chromian spinels.
14.
According to Sakai-Ohmoto's theory regarding the evolution of sulfur isotopes in hydrothermal systems, in conjunction of new data on chemical resaction equilibrium constants and equilibrium isotopic fractionation factors as well as on individual ion activity coefficients of aqueous sulfur species, the following lgfo2.-pH diagrams are constructed:
- mole fractions of aqueous sulfur species (X i ),
- stability fields of some minerals in the Fe-S-O system,
- diagram depicting the oxidation-reduction-state ratio for aqueous sulfur species (R′)
- isotopic compositions of sulfur compounds ( \(\delta S_1 ^{34} \) ).
15.
Basalts from DSDP Site 417 (109 Ma) exhibit the effects of several stages of alteration reflecting the evolution of seawater-derived solution compositions and control by the structure and permeability of the crust. Characteristic secondary mineral assemblages occur in often superimposed alteration zones within individual basalt fragments. By combining bulk rock and single phase chemical analyses with detailed mineralogic and petrographic studies, chemical changes have been determined for most of the alteration stages identified in the basalts.
- Minor amounts of saponite, chlorite, and pyrite formed locally in coarse grained portions of massive units, possibly at high temperatures during initial cooling of the basalts. No chemical changes could be determined for this stage.
- Possible mixing of cooled hydrothermal fluids with seawater resulted in the formation of celadonite-nontronite and Fe-hydroxide-rich black halos around cracks and pillow rims. Gains of K, Rb, H2O, increase of Fe3+/FeT, and possibly some losses of Ca and Mg occurred during this stage.
- Extensive circulation of oxygenated seawater resulted in the formation of various smectites, K-feldspar, and Fe-hydroxides in brown and light grey alteration zones around formerly exposed surfaces. K, Rb, H2O, and occasionally P were added to the rocks, Fe3+/FeT increased, and Ca, Mg, Si and occasionally Al and Na were lost.
- Anoxic alteration occurred during reaction of basalt with seawater at low water-rock ratios, or with seawater that had previously reacted with basalt. Saponite-rich dark grey alteration zones formed which exhibit very little chemical change: generally only slight increases in Fe3+/FeT and H2O occurred.
- Zeolites and calcite formed from seawater-derived fluids modified by previous reactions with basalt. Chemical changes involved increases of Ca, Na, H2O, and CO2 in the rocks.
- A late stage of anoxic conditions resulted in the formation of minor amounts of Mn-calcites and secondary sulfides in previously oxidized rocks. No chemical changes were determined for this stage.
16.
The groundwater reserves in Kharga Oases have been studied for the long-term socioeconomic development in the area. The Nubian Sandstone, which consists of a thick sequence of coarse clastic sediments of sandstone, sandy clay interbedded with shale, and clay beds, forms a complex aquifer system. The Nubian Aquifer has been providing water to artesian wells and springs in the Kharga Oases for several thousand years. Groundwater in the Kharga Oases is withdrawn from springs and shallow and deep artesian wells Nearly all the wells originally flowed, but with the exploitation of ground-water from deep wells for irrigation beginning about 1959. the natural flows declined as more and more closely spaced deep wells were drilled By 1975 many deep wells had ceased to flow The water demand in the area has been met by pumping both shallow and deep wells The total annual extraction from deep wells has fluctuated over the year, however, the annual withdrawal from deep wells has exceeded extraction from shallow wells About 17 billion m3 of water was withdrawn from the combination of shallow and deep wells during the period 1960–1980 The Nubian complex aquifer in the Kharga Oases has a very large groundwater potential that could be exploited and beneficially used for a long-term agricultural development in the area, provided proper well spacing and management are implemented Other major environmental considerations for which precise hydrogeologic data are needed include
- Determination of the long-term yield available from properly constructed and producing artesian wells that will support a planned migration of population from the overcrowded Nile delta and flood plain areas
- Development of an effective management program and adequate staff to maintain groundwater production over an extended period of years
- The impact on climate caused by extensive irrigation in the oases of the Western Desert of Egypt
- Protection against water logging of soils from irrigation practices
- Protection against salinization of soils from irrigation practices
- Development of effective surface and subsurface drainage practices
- The impact of farming and pest control practices on the shallow groundwater of the oases
- Determination of the long-term development of the artesian water on the quality of the water from the aquiter systems in the Western Desert
17.
Dr. Ulrich von Rad 《International Journal of Earth Sciences》1970,60(1):331-354
Paleocurrent directions can be reconstructed by determining optically the preferred orientation of longest grain axes of sediments; this can be estimated by measuring the anisotropy of magnetic susceptibility (Rees, 1965). In order to check the applicability of both methods, the orientation of large- and small-scale sedimentary structures (cross-bedding, sole markings, grain orientation) was compared with the “magnetic fabric” of some sand and silt layers of different ages and origins:
- Rosario Formation (Late Cretaceous), La Jolla: thin siltstone layers with small-scale current-ripple cross-lamination;
- Monterey and Topanga Formations (Miocene, Los Angeles Basin): graded and laminated sandstone beds (“turbidites”);
- Holocene submarine La Jolla Fan: graded and cross-laminated sand layers (Rees, v.Rad &Shepard, 1968).
18.
Alexander A. Godovikov George C. Kennedy 《Contributions to Mineralogy and Petrology》1968,19(2):169-176
Prior experimental work has shown that in the laboratory the mineralogy of eclogites is sensitive to the ratio of CaO ∶ MgO ∶ FeO and that the reaction pyroxene + kyanite?garnet + quartz proceeds to the right at high pressures in rocks rich in magnesium and to the left in rocks rich in calcium and iron. Typical basalts crystallized at high pressure never contain kyanite. The chemistry and mineralogy of a large number of naturally occurring eclogites show they belong to three classes.
- Kyanite-free magmatic eclogites, rich in magnesium, from:
- kimberlites
- dunites and serpentinites.
- Kyanite-bearing eclogites and grosspydites rich in CaO and low in FeO with intermediate MgO from:
- kimberlites
- gneisses.
- Kyanite-free eclogites of metamorphic origin rich in iron with low magnesium and intermediate amounts of calcium from:
- glaucophane schists
- gneisses.
19.
Joachim Lange 《Contributions to Mineralogy and Petrology》1970,28(4):288-305
The data obtained can be summed up in 6 points:
- The sediment consists of varying amounts of quartz (14–23 weight percent, mean value 18%), aragonite, dolomite, Mg-rich calcite, Mg-poor calcite, Na-rich plagioclase (7–10%, m.v. 8%), chlorite (18–32%, m.v. 22%), kaolinite (4–29%, m.v. 13%), illite and mixedlayered illite-montmorillonite (20–42%, m.v. 34%) and organic matter (0.7–2.5%, m.v. 1.1%).
- The composition of the carbonate fraction suggests a detrital origin for the carbonates deposited along the Persian Coast.
- The clay mineral distribution follows gradients perpendicular to the long half-axis of the Persian Gulf. This favours detrital origin. The kaolinite distribution suggests an additional detritus from Euphrates and Tigris,
- Enrichments of trace elements with regard to mean values in clays (Turekian and Wedepohl, 1961) are estimated for Fe, Co, Mo, Ni, V, Zr and Br; impoverishments are recorded for Cu, Mn, K. The contents of Rb, Ti and Zn comply with mean values of clays. The enrichments distribute as follows: chlorite concentrates Mn and Fe, kaolinite Ti and Zr, illite and mixedlayered illite-montmorillonite Rb, V, M, Zn, Mo and Co.
- The high Br-contents (up to 420 ppm) in the sediment give positive correlations with the concentrations of organic carbon. The X-ray analysis of isolated kerogen confirms an enrichment of Br in this fraction of the organic matter.
- The distribution of elements in the sediment to a large extent is controlled by a) detritus of Euphrates and Tigris, b) influence of organic matter.
20.
K. Viswanathan 《Contributions to Mineralogy and Petrology》1972,37(4):277-290
A series of K-plagioclases have been produced metastably by ion-exchanging the plagioclases in KCl-melt. Chemical analyses and re-exchange experiments (with NaCl-melt) have proved that the K-plagioclases are truly isomorphous with plagioclases. Because of their isomorphous nature it was possible to mix them in different proportions and homogenise them, thereby producing ternary feldspars of different compositions in the system Or-Ab-An. A comparative study of the lattice constants of plagioclases, their K-equivalents and the different ternary feldspars calculated using powder data leads to the following conclusions:
- It is possible to dertermine by X-ray methods the anorthite content of a plagioclase to an accuracy of ±1% An.
- The influence of the ionic size of the bigger cations Na, Ca, and K and that of order/disorder are different on different lattice constants and it is possible to distinguish these two effects.
- The b-parameter indicates a definite structural change in plagioclases at about 25–30% An.
- It is possible to predict the average Al/Si-distributions in the four different positions T1(o), T1(m), T2(o) and T(m) of all plagioclases of all stable structural states, using the c-parameter of their K-equivalents.