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1.
贺兰山以北乌兰布和沙漠地下水水化学特征演化规律研究   总被引:5,自引:0,他引:5  
党慧慧  董军  岳宁  董阳  郭映  魏国孝 《冰川冻土》2015,37(3):793-802
乌兰布和沙漠对中国西北部干旱地区气候变化和水文循环过程研究具有指示意义, 以水文地球化学运移为导向, 通过分析33个地下水样, 探讨了该区地下水的补给与演化过程. 结果表明: 巴彦乌拉山浅层地下水水化学类型为Cl--HCO3--SO42--Na+; 从吉兰泰盐湖至乌兰布和沙漠, 主要水化学类型变化浅层地下水为Cl--HCO3--Na+到Cl--HCO3--SO42--Na+, 深层地下水为HCO3--Cl--Na+再到HCO3--Cl--Na+或HCO3--Cl--Ca2+. Gibbs图表明, 研究区地下水的水化学特征主要受蒸发浓缩作用影响和岩石风化作用控制, 大气降雨机制影响甚微. 主要离子相关关系图及饱和指数表明, 岩盐、芒硝、钠长石、方解石、白云石、石膏等矿物的风化溶解是该区地下水主要离子来源. 此外, 氯碱指数和Ca/Na的指示, 说明阳离子交换作用也是形成该地区地下水水化学组分的重要机制.  相似文献   

2.
Reported here are the first 187Os/188Os ratios and abundances of Os and Re for Taklimakan Desert sands and glacial moraines from the Kunlun Mountains. Osmium isotopic data are also reported for river sediments around the Taklimakan Desert, river sediments from the Kunlun and Tianshan Mountains, Tibetan soils and loesses from the Loess Plateau, as well as Sr and Nd isotopic data for these samples. The Taklimakan Desert sands from various regions show surprisingly homogeneous Os isotopic ratios (187Os/188Os = 1.29 ± 0.08) and abundances (Os = 11 ppt), with some variations in Re abundances (Re = 130 to 260 ppt) and 187Re/188Os ratios (60 to 140). The 187Os/188Os ratios for the Taklimakan Desert sands are close to the average for Kunlun moraines, river sediments around the Taklimakan Desert sands, and the Tibetan soils, supporting the idea that the Taklimakan Desert sands are derived from moraines and river sediments around the desert or from Tibetan soils and are homogenized by aeolian activity in the desert. Furthermore, the Os isotopic data for the sediments studied here are compared with those (187Os/188Os = 1.04, Os = 32 ppt, Re = 206 ppt, 187Re/188Os = 35) of loesses from the Loess Plateau reported elsewhere, and it is concluded that the Re-Os data for the loess can be used as proxy for the upper continental crust.  相似文献   

3.
《Quaternary Research》2014,81(3):476-487
The evolution of arid environments in northern China was a major environmental change during the Quaternary. Here we present the dating and environmental proxy results from a 35 m long core (A-WL10ZK-1) collected from the Ulan Buh Desert (UBD), along with supplemental data from four other cores. The UBD is one of the main desert dune fields in China and our results indicate the UBD has undergone complex evolution during the late Quaternary. Most of the present UBD was covered by a Jilantai-Hetao Mega-paleolake lasting until ~ 90 ka ago. A sandy desert environment prevailed throughout the UBD during the last glacial period and early Holocene. A wetland environment characterized by the formation of numerous interdunal ponds in the northern UBD occurred at ~ 8–7 ka, although a dune field persisted in the southern UBD. The modern UBD landscape formed after these wetlands dried up. During the last 2000 years, eolian sand from the Badain Jaran Desert has invaded the northern UBD, while farming and overgrazing resulted in the formation of the eastern UBD. We suggest that the formation of UBD landforms is related to the disintegration of the megalake Jilantai-Hetao and to summer monsoon changes during the last glaciation and Holocene.  相似文献   

4.
Geochemical and isotopic studies of aeolian sediments in China   总被引:5,自引:0,他引:5  
The Sr and Nd isotopic, rare earth element (REE) and major element compositions, together with mineral and grain‐size proportions, are reported for aeolian loess deposits and desert sands from several Chinese localities. The study was carried out in order to examine regional variations in the isotopic and geochemical features of these aeolian sediments, and to constrain the provenance of Chinese loess. Samples include loesses from the Tarim and Junggar basins and desert sands from the Taklimakan desert in north‐west China, loess from the Ordos area and desert sands from the Tengger and Mu‐us deserts in north‐central China, as well as loess and desert sands from the Naiman area, north‐east China. REE distributions show minimal variation among the Chinese loess deposits, whereas those for the desert sands show regional variations. New isotopic data document a latitudinal variation in Sr and Nd isotopic features for the loesses and desert sands. The Naiman and Junggar loesses have distinctly lower 87Sr/86Sr ratios and higher εNd(0) values than the loesses from the Tarim Basin, the Ordos area and the Loess Plateau. Among the desert sands, the Naiman samples have higher εNd(0) values than the Taklimakan, Tengger and Mu‐us samples. Isotopic data suggest that loesses of the Loess Plateau were supplied from the Tarim Basin loesses and Taklimakan Desert sand, and that the Naiman loesses were supplied from the Junggar Basin loesses. The latitudinal variation in the loesses and desert sands may be partly explained by isotopic variations reported previously for moraines from the Tianshan and west Kunlun Mountains, which are possible sources for the loesses and desert sands. These inferences on the provenance of the loesses and desert sands are consistent with the dust transport pattern over East Asia.  相似文献   

5.
Stabilization of desert sands using municipal solid waste incinerator ash   总被引:1,自引:0,他引:1  
This paper presents experimental results on the use of incinerator ash in stabilizing desert sands for possible use in geotechnical engineering applications. The incinerator ash was added in percentages of 2, 4, 8, 10 and 12%, by dry weight of sand. Laboratory tests such as compaction, unconfined compression, shear box and hydraulic conductivity were performed to measure the engineering characteristics of the stabilized material. The results showed substantial improvements in unconfined compressive strength and shear strength parameters (c and φ). Thus, incinerator ash can be used to improve the shear strength characteristics of desert sands. The permeability of the sand–incinerator ash mixture was relatively low.  相似文献   

6.
The geochemical study of groundwaters and core sediments from the Old Brahmaputra plain of Bangladesh was conducted to investigate the distribution of arsenic and related trace elements. Groundwaters from tube wells are characterized by pH of 6.4–7.4, dissolved oxygen (DO) of 0.8–1.8 mg/l, Ca contents of 5–50 mg/l, and Fe contents of 0.2–12.9 mg/l. Arsenic concentrations ranged from 8 to 251 μg/l, with an average value of 63 μg/l. A strong positive correlation exists between As and Fe (r 2 = 0.802; p = 0.001) concentrations in groundwater. The stratigraphic sequences in the cores consist of yellowish silty clays at top, passing downward into grayish to yellowish clays and sands. The uppermost 3 m and lower parts (from 13 to 31 m) of the core sediments are oxidized (average oxidation reduction potential (ORP) +170 and +220 mV, respectively), and the ORP values gradually become negative from 3 to 13 m depths (−35 to −180 mV), indicating that anoxic conditions prevail in the shallow aquifers of the Brahmaputra plain. Age determinations suggest that clay horizons at ~10 m depth were deposited at around 2,000 and 5,000 years BP (14C ages) during the transgressive phase of sea-level change. Elevated concentrations of As, Pb, Zn, Cu, Ni, Cr, and V are present in the silts and clays, probably due to adsorption onto clay particles. Significant concentrations of As occur in black peat and peaty sediments at depths between 9 and 13 m. A strong positive correlation between As and Fe was found in the sediments, indicating As may be adsorbed onto Fe oxides in aquifer sediments.  相似文献   

7.
本文以乌兰布和沙漠钻孔岩芯沉积物为例,测量了其中沙丘砂和沙丘底部湖相沉积物的粒度。通过对比和分析同一样品在粒度概率累积曲线和频率曲线上所反映的信息,发现概率累积曲线能更直观、准确、定量地显示沉积物粒度组成及各特征组分的分选性,包含有比频率曲线更丰富的沉积环境信息。  相似文献   

8.
The Namib Sand Sea is the largest active desert dunefield in southern Africa, and is comprised mainly of large north-south linear dunes. In the interdune areas of the northern Sand Sea eleven small areas of calcareous lacustrine sediment have been studied. These beds are typically less than a metre thick and are dominantly comprised of calcareous sandstones to mudstones and sandy limestones. The carbonates are mainly magnesian calcites (1–14% MgCO3) with some protodolomite and aragonite. Calcified reed casts and fresh to brackish water gastropods, diatoms, and ostracods are present in some beds. δ18O values indicate a hot and dry climate. A number of enriched δ13C values may reflect high salinity, low organic populations, or carbonate recrystallization.These carbonate-rich lacustrine deposits are indicative of increased periods of moisture availability in this normally hyperarid region during the Late Quaternary. The origin of the water responsible for depositing these sediments may be: (1) ponding at the end point of the Tsondab River, which at one time extended farther west into the Sand Sea; (2) flooding into interdune corridors when water levels rose in rivers such as the Kuiseb; (3) groundwater seepage into depressions either through dunes that border rivers or from the underlying Tsondab Sandstone; and (4) increased rainfall. We do not believe that there is evidence to support a major increase in precipitation over the region. However, even a small increase in precipitation in the headwaters of valleys that drain toward the Sand Sea might: (1) generate enough additional runoff to extend the terminal point of rivers such as the Tsondab farther into the dunes; (2) cause lateral flooding from major valleys into interdune corridors; and (3) recharge aquifers. The sedimentary records at Narabeb, Ancient Tracks, and West Pan, which lie along the old course of the Tsondab River, favor a ponded river origin for them, whereas groundwater seepage is favored at other sites. The chronology of deposition, based on radiocarbon dates, suggests that ponding and recharge occurred earlier in the lower, western part of the area, and later in the east. This is in harmony with the view that the end point of the Tsondab River progressively retreated eastward between about 30 and 14 ka BP, as dunes blocked its route.  相似文献   

9.
On the Qinghai-Tibet Plateau there are three super large lakes, the Qinghai Lake, Nam Co and Siling Co, and eleven large lakes, the Zhari Nam Co, Tangra Yumco, Ayakkum Lake, Banggong Co, Har Lake, Ngoring Lake, Yamzho Yumco, Gyaring Lake, Chibuzhang Co, Ulan Ul Lake and the Ngangla Ringco. The authors studied the changes of these major lakes in the past 25 years, based on interpretations of the MSS images obtained during the middle 1970s and ETM+ images obtained in the late 1990s or at the beginning of the 21st century. The study shows that: the areas of the Har Lake andNgoring Lake have remained relatively stable; the areas of the Qinghai Lake, Zhari Nam co, Tangra Yumco, Ayakkum Lake, Gyaring Lake, Ulan Ul Lake and Ngangla Ringco have been reduced to varying degrees, of which the areas of the Qinghai Lake and Ulan Ul Lake have decreased most sharply by 60.60 km2 and 59.80 km2 respectively; the areas of the Nam Co, Siling Co and Bangong Co have increased more or less, of which the area of the Siling Co has increased most sharply by 140.42 km2. The analysis on the changes in areas of major lakes has provided new materials for the study of the lake evolution, climatic change and environmental variation on the Qinghai-Tibet Plateau. __________ Translated from Geological Bulletin of China, 2007, 26(12): 1633–1645 [译自: 地质通报]  相似文献   

10.
 Ca-chloride waters are defined as those in which Q=rCa/r(SO4+HCO3)>1, rNa/rCl<0.80, rMg/rCa<0.5 and wCl/wBr<286 (r=meq l–1 and w=mg l–1). Throughout the last 50 years, different models for the formation of such waters have been suggested. These models include: (1) filtration through semipermeable membranes under conditions of highly compacted argillaceous sediments, (2) deaquation of seawater by evaporation and/or by freezing followed by dolomitization, (3) hydrolysis of plagioclase and biotites in igneous metamorphic rock masses, (4) radiolytic modification of residual metamorphic fluids, and (5) dissolution of chalks followed by ion exchange on smectites. The better understanding of processes and of natural environments leading to the evolution and natural occurrence of such brines, is imperative for the prospection and further sustained exploitation of such waters. Received: 11 October 1996 · Accepted: 24 February 1997  相似文献   

11.
The marine geology of Port Phillip is described in detail, based on data from seismic profiling, vibrocoring and grab sampling. Three major unconsolidated facies can be distinguished: sands and muddy sands peripheral to the present coastline, muds covering the major central region, and channel fills of muds and sands. The first two facies units result from an increase in wave sorting towards the coast, reworking of Tertiary and Quaternary sandstone outcrops around the coast, and a dominant mud supply from river sources into the central area. The distribution and thicknesses of the unconsolidated facies have been augmented by a shallow‐seismic program that reveals the thicknesses of the modern sediments overlying an older surface comprised of consolidated clays and sandy clays of Pleistocene or older age. In central Port Phillip, muds and sands up to 27 m‐thick have infilled Pleistocene channels cut into underlying consolidated units. Sediments immediately above the channel bases show characteristic seismic patterns of fluvial deposition. The presence of peat deposits together with gas phenomena in the water column suggest organic breakdown of channel‐fill deposits is releasing methane into the bay waters. Outside the channel areas, carbon‐14 dating indicates that the unconsolidated sediments largely post‐date the last glaciation sea‐level rise (<6500 a BP), with an early Holocene period of rapid deposition, similar to other Australian estuaries. Stratigraphic and depositional considerations suggest that the undated channel‐fill sequences correlate with the formation of cemented quartz‐carbonate aeolianite and barrier sands on the Nepean Peninsula at the southern end of Port Phillip. Previous thermoluminescence dating of the aeolianites suggests that channel‐fill sequences B, C and D may have been deposited as fluvial and estuarine infills over the period between 57 and 8 ka. The eroded surface on the underlying consolidated sediments is probably the same 118 ka age as a disconformity within the Nepean aeolianites. Further estuarine and aeolianite facies extend below the disconformity to 60 m below sea‐level, and may extend the Quaternary depositional record to ca 810 ka. Pliocene and older Tertiary units progressively subcrop below the Quaternary northwards up the bay.  相似文献   

12.
研究发现,河套地区在距今5~6万年前存在一个统一的"吉兰泰-河套"古大湖,覆盖吉兰泰和河套盆地的大部分地区。本研究试图依据钻孔资料和湖泊沉积物的测年结果,讨论新生代以来河套盆地的湖泊演化和古大湖的形成机制。结果表明,新生代以来,特别是早更新世以来吉兰泰盆地和河套平原的3个坳陷盆地就已经处于湖泊环境,但没有证据显示存在统一的湖泊。湖泊沉积及其OSL测年显示,"吉兰泰-河套"古大湖大约在距今10万年前后开始发育,至距今5~6万年之前湖面达到海拔1080m上下,随后湖泊衰退。我们认为,鄂尔多斯高原东北边缘距今12万年前后开始的快速构造隆升,可能导致了晋陕峡谷黄河外流受阻,最终在河套盆地积水形成统一湖泊,末次冰期中期(深海氧同位素3阶段)相对湿润的气候环境进一步促进了"吉兰泰-河套"古大湖的发育。  相似文献   

13.
A vibrocore from the sea floor of the southern North Sea provides a ~1,500-year record of early Holocene vegetation history and mire development in a landscape now 33 m below sea-level. Pollen, plant macrofossil and geochemical analyses of an AMS 14C dated sand–peat–marine mud sequence document the paludification on Pleistocene sands ~10,700 cal BP, the subsequent development of eutraphentic carr vegetation and the gradual inundation by the transgressing sea ~9,350 cal BP. PinusCorylus woodland prevailed on terrestrial grounds after hazel had immigrated ~10,700 cal BP. Salix dominated the carr vegetation throughout 1,300 years of peat formation, because Alnus did not spread in the Borkum Riffgrund area until 9,300 BP. Brackish reed vegetation with Phragmites established after inundation and siliciclastic marine sediments were being deposited. This article also examines the detection and suitability of key horizons indicative of marine influence. XRF-Scanning provides the most detailed results in the briefest possible time to pinpoint spectra best suitable for AMS 14C dating of classical key horizons such as start of peat formation and transgressive contact. The combined application of botanical and geochemical methods allows determining new key horizons indicative of marine influence, namely the earliest marine inundation and the onset of sea-level influence on coastal ground water level.  相似文献   

14.
Denitrification in continental shelf sediments has been estimated to be a significant sink of oceanic fixed nitrogen (N). The significance and mechanisms of denitrification in organic-poor sands, which comprise 70% of continental shelf sediments, are not well known. Core incubations and isotope tracer techniques were employed to determine processes and rates of denitrification in the coarse-grained, sandy sediments of the Georgia continental shelf. In these sediments, heterotrophic denitrification was the dominant process for fixed N removal. Processes such as coupled nitrification-denitrification, anammox (anaerobic ammonium oxidation), and oxygen-limited autotrophic nitrification-denitrification were not evident over the 24 and 48 h time scale of the incubation experiments. Heterotrophic denitrification processes produce 22.8–34.1 μmole N m-2 d-1 of N2 in these coarse-grained sediments. These denitrification rates are approximately two orders of magnitude lower than rates determined in fine-grained shelf sediments. These lower rates may help reconcile unbalanced marine N budgets which calculate global N losses exceeding N inputs.  相似文献   

15.
Metabasites with eclogite facies relics occur in northern Sardinia as massive to strongly foliated lenses or boudins embedded within low- to medium-grade rocks (Anglona) and migmatites (NE Sardinia). U–Pb zircon dating yielded 453 ± 14, 457 ± 2 and 460 ± 5 Ma as the protolith ages; 400 ± 10 and 403 ± 4 Ma have been interpreted as the ages of the HP event and 352 ± 3 and 327 ± 7 Ma as the ages of the main Variscan retrograde events. A pre-eclogite stage is documented by the occurrence of tschermakite, zoisite relics within garnet porphyroblasts (Punta de li Tulchi) and an edenite–andesine inclusion within a relict kyanite porphyroblast (Golfo Aranci). Four main metamorphic stages have been distinguished in the eclogite evolution: (1) eclogite stage, revealed by the occurrence of armoured omphacite relics within garnet porphyroblasts. The Golfo Aranci eclogites also include kyanite, Mg-rich garnet and pargasite; (2) granulite stage, producing orthopyroxene and clinopyroxene–plagioclase symplectites replacing omphacite. At Golfo Aranci, the symplectitic rims around relict kyanite consist of sapphirine, anorthite, corundum and spinel; (3) amphibolite stage, leading to the formation of amphibole–plagioclase kelyphites between garnet porphyroblasts and pyroxene–plagioclase symplectites and to the growth of cummingtonite on orthopyroxene. Tschermakite to Mg-hornblende, plagioclase, cummingtonite, ilmenite, titanite and biotite are coexisting phases; (4) greenschist to sub-greenschist stage, defined by the appearance of actinolite, chlorite, epidote ss, titanite, sericite and prehnite. The following PT ranges have been estimated for the different stages. Eclogite stage 550–700°C; 1.3–1.7 GPa; granulite stage 650–900°C; 0.8–1.2 GPa, clustering in the range 1.0–1.2 GPa; amphibolite stage 550–740°C; 0.3–0.7 GPa; greenschist stage 300–400°C; 0.2–0.3 GPa. Comparable ranges characterise the other Variscan massifs in Europe; eclogite stage: T = 530–800°C; P from 0.7–1.1 to 1.7 ± 0.3 GPa; granulite stage T = 760–870°C and P from 1.1–1.4 to 7.2–9.9 GPa, clustering around 1.0–1.2 GPa. Whole-rock chemistry: Sardinian eclogites are N- to T-MORB; European ones N- to E-MORB or calc-alkaline.  相似文献   

16.
During a lake‐full phase at the end of the Pleistocene Period, lacustrine silts and aeolian sands were deposited around the eastern margins of Kow Swamp. These sediments have yielded the remains of a large population of early Australian man, retaining certain archaic Homo erectus characteristics.

The lake‐lunette system in which the burials were made provides a geographically isolated situation for the examination of late Pleistocene and Holocene hydrological changes which have left their imprint on the sediments, soils and vegetation.  相似文献   

17.
Batch experiments were performed to investigate cephapirin (a widely used veterinary antibiotic) adsorption on various size sands of low total organic carbon content (0.08–0.36 wt%). In the aqueous concentration range investigated (11–112 μmol/L cephapirin), adsorption to nearly pure quartz filter sands (0.50–3.35 mm diameter) is low. Isotherms are S-shaped and most display a region of minimum adsorption, where decreased adsorption occurs with increasing solution concentration, followed by increased adsorption at higher concentrations. Cephapirin adsorption to quartz-rich, feldspar-bearing dune sands (0.06–0.35 mm diameter), and the smallest quartz filter sand investigated (0.43–0.50 mm), can be described by linear sorption isotherms over the range of concentrations investigated. Distribution coefficients (K d) range from 0.94 to 3.45 L/kg. No systematic relationship exists between grain size and amount of adsorption for any of the sands investigated. Cephapirin adsorption is positively correlated to the feldspar ratio (K-feldspar/(albite + Ca-plagioclase). Feldspar-ratio normalization of distribution coefficients was more effective than organic carbon normalization at reducing variability of K d values in the dune sands investigated.  相似文献   

18.
The Upper San Pedro River Basin in Mexico and the United States is an important riparian corridor that is coming under increasing pressure from growing populations and the associated increase in groundwater withdrawal. Several studies have produced three-dimensional maps of the basin fill sediments in the US portion of the basin but little work has been done in the Mexican portion of the basin. Here, the results of a ground-based transient electromagnetic (TEM) survey in the Upper San Pedro Basin, Mexico are presented. These basin fill sediments are characterized by a 10–40 m deep unsaturated surficial zone which is composed primarily of sands and gravels. In the central portion of the basin this unsaturated zone is usually underlain by a shallow clay layer 20–50 m thick. Beneath this may be more clay, as is usually the case near the San Pedro River, or interbedded sand, silt, and clay to a depth of 200–250 m. As you move away from the river, the upper clay layer disappears and the amount of sand in the sediments increases. At 1–2 km away from the river, sands can occupy up to 50% of the upper 200–250 m of the sediment fill. Below this, clays are always present except where bedrock highs are observed. This lower clay layer begins at a depth of about 200 m in the central portion of the basin (250 m or more at distances greater than 1–2 km from the river) and extends to the bottom of most profiles to depths of 400 m. While the depth of the top of this lower clay layer is probably accurate, its thickness observed in the models may be overestimated due to the relatively low magnetic moment of the TEM system used in this study. The inversion routine used for interpretation is based on a one-dimensional geologic model. This is a layer based model that is isotropic in both the x and y directions. Several survey soundings did not meet this requirement which invalidates the inversion process and the resulting interpretation at these locations. The results from these locations were rejected.  相似文献   

19.
沙漠微生物矿化覆膜及其稳定性的现场试验研究   总被引:2,自引:0,他引:2  
李驰  王硕  王燕星  高瑜  斯日古楞 《岩土力学》2019,40(4):1291-1298
将微生物诱导矿化技术应用于原位沙漠覆膜的形成,使得流动沙丘经结皮固定而成为半固定、固定沙丘,从根本上阻断沙尘暴的源头。在内蒙古乌兰布和沙漠腹地选择两个微生物矿化试验区域(TP1和TP3),分别用于两种不同矿化菌种诱导生成碳酸钙覆膜。研究沙漠微生物矿化覆膜的现场试验方法及工艺,对原位矿化覆膜的强度及其在沙漠环境中的长期稳定性进行跟踪检测。采用沙漠土中自行提取的葡萄球菌和传统的巴氏芽孢杆菌两种不同的微生物矿化菌种,通过现场贯入试验检测7、14、28、60、210 d后矿化覆膜沿深度发展的贯入阻力,并将覆膜厚度为2 cm处的平均贯入阻力换算成覆膜层强度,总结覆膜强度随时间的发展变化规律。现场观测结果显示,不同微生物菌种诱导生成的矿化覆膜均在试验的第4天开始形成,到第7天覆膜层具有稳定的强度和厚度,现场检测覆膜的平均厚度为2.0~2.5 cm,经自源葡萄球菌诱导生成的矿化覆膜(TP1)的强度是巴氏芽孢杆菌诱导生成的矿化覆膜(TP3)强度的1.05倍。当经历冬春交替后覆膜层强度都有不同程度的降低,明显地TP3较TP1区域表面剥落更为严重,第210天检测TP3的平均厚度为0.7~1.0 cm,覆膜强度较第7天时降低19%,覆膜内碳酸钙含量较第7天检测时降低15%~30%。而TP1在第210天时的强度较第7天时强度降低仅2%。因此,微生物诱导矿化技术可以应用于沙漠原位覆膜的形成,且沙漠自源葡萄球菌经诱导生成的矿化覆膜层具有更好的强度表现和稳定性。  相似文献   

20.
The organic matter of recent deltaic sediments cored in the Mahakam delta, East Kalimantan, has been studied before and after physical fractionation into sands >50 μm, silts 5–50 μm and clays <5 μm. Both the lipid and non-lipid components have been investigated.Weight, carbon and nitrogen fractionation budgets were used to define three types of samples, depending on coarse particle contributions to the total amount of organic matter: a = a first type with more than 50% of the O.M. in the coarse particles, high C/N ratios and O.M. content, b = an intermediary type with medium C/N ratios and O.M. content, each fraction having quite the same O.M. content, c = a third type with less than 5% of the whole O.M. in the sands and the lowest C/N ratios and O.M. content.Concerning the global organic characteristics of the fractions, a systematic increase of C/N ratios occurs when going from clays to sands; the finer the fraction is, the more nitrogenous the compounds are. This enrichment in nitrogen is related to a persistent high rate of hydrolysable material either for argillaceous organic matter-poor sediments or for the clay fractions of all types of samples. Conversely, the type (a) coarse sediments, in particular the sandy components were resistant to acid hydrolysis with burial.Concerning the geochemical markers signatures of granulometric fractions, the distribution patterns of n-alkanes and n-fatty acids are characterized by the predominance of high molecular weight compounds >C22. Carbon preference index (CPI) values are higher in the sands and silts, reflecting their enrichment in continentally-derived vegetation debris. For type (c), the fractionation revealed markers of microbial activity within the clay fractions. For all types of samples, we observed an increase with burial of the n-alkane and n-fatty acid concentrations, particularly in the clay fractions, suggesting possibly a better preservation and/or affinity of lipids with the finest fractions.  相似文献   

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