西藏甲玛铜多金属矿床成因研究——来自流体包裹体的证据

甲玛铜多金属矿床位于西藏冈底斯斑岩铜矿带东段,是近年来勘探发现的超大型斑岩-矽卡岩型铜多金属矿床。通过冷热台显微观察与测温、扫描电镜、激光拉曼探针测试,对甲玛矿床各成矿阶段典型矿物的流体包裹体研究表明,成矿流体富含挥发分,临界相均一的流体来自岩浆超临界流体出溶,主成矿阶段具有沸腾包裹体组合特征,有机质包裹体荧光效应显著。显微测温结果显示,岩浆-热液阶段斑岩中石英斑晶的流体包裹体均一温度范围为250～540℃,含石盐子晶高盐度包裹体盐度范围为35～61(wt%)NaCl.eq,中等盐度的临界均一的气液包裹体盐度范围为3～29(wt%)NaCl.eq,岩浆期后热液阶段斑岩、角岩中石英脉的流体包裹体均一温度范围为210～410℃,盐度范围为33～41(wt%)NaCl.eq,与其不混溶共生的中低盐度气液两相流体包裹体盐度范围为5～25(wt%)NaCl.eq。矽卡岩阶段矿物均一温度范围为130～360℃,盐度范围为3～41(wt%)NaCl.eq,从岩浆热液过渡阶段到石英-硫化物阶段均一温度与盐度呈阶梯式降低趋势。斑岩体石英的流体包裹体中含有较多黄铜矿子矿物,岩浆结晶分异过程中已经具成矿元素的富集。激光拉曼探针测试结果显示,成矿早期至主成矿期矿物流体包裹体气相成分主要为CO2、CH4和N2,各阶段矿物流体包裹体气相成分具有继承性。成矿流体为高温度高盐度,富含CO2、CH4的流体。成矿流体主要源于岩浆,后期混有大气降水。当岩浆热液上升时因压力的突然释放造成高温含矿热流体发生减压沸腾,CO2和CH4等气体大量逃逸,导致成矿物质快速沉淀。矿床在成因上与岩浆-热液成矿作用密切相关。     

西藏甲玛铜多金属矿床成矿流体来源及演化

对斑岩、矽卡岩及角岩矿物中石英的熔融包裹体和流体包裹体进行测温,得到甲玛铜多金属矿床斑岩体形成温度为634～887℃,斑岩体中流体开始出溶的压力为59.1 MPa.从岩浆阶段、岩浆-热液阶段、矽卡岩阶段、矽卡岩退变质阶段到石英-硫化物阶段,温度范围为170～540℃,盐度集中在15%～50%范围内,密度为0.9233～...     

西藏墨竹工卡地区甲玛铜多金属矿床矽卡岩矿物学特征及其地质意义

为研究西藏甲玛铜多金属矿床中矽卡岩的矿物学特征,进一步确定矿床成因类型,利用电子探针测试和镜下鉴定手段对矽卡岩矿物中的石榴子石、辉石、硅灰石等矿物成分进行了分析。测试结果表明,矽卡岩中石榴子石以钙铁榴石-钙铝榴石为主,辉石以透辉石为主,甲玛矿床矽卡岩属于交代矽卡岩中典型的钙矽卡岩。结合前人对矿区矽卡岩、围岩和花岗岩类的岩石地球化学、矿床成矿年代学等的研究,进一步证实甲玛铜多金属矿床系矿区花岗岩类岩浆交代大理岩形成的典型矽卡岩型矿床。     

滇西北衙斑岩型金多金属矿床成矿流体特征及其演化

北衙超大型金多金属矿床位于扬子陆块西缘与三江特提斯造山带的结合部位。本文通过对北衙矿区内的斑岩体石英斑晶、斑岩型矿化、矽卡岩矿化中的矽卡岩及外围似层状热液型铅锌银矿化的岩(矿)石中发育的流体包裹体进行了系统研究,发现北衙矿区内主要发育CO2、富CO2、含CO2、含子矿物三相、富气相水溶液及气液两相水溶液包裹体六类流体包裹体;与斑岩型矿化有关的成矿流体为中-高温Na Cl-H2O-CO2体系热液,矽卡岩矿化相关成矿流体为一种高温的Na Cl-H2O及Na Cl-H2O-CO2体系热液,而外围似层状铅锌银矿化相关的成矿流体则为中温的Na Cl-H2O-CO2体系热液。对比分析表明,矽卡岩矿化中的矽卡岩矿物(以绿帘石类矿物为主)形成较早,其中发育富气相的流体包裹体,可以推断岩浆侵位后先分异出富水蒸气的流体,此后CO2才从成矿流体中大量分异。斑岩型矿化及外围地层中似层状铅锌银矿化脉体中发育的流体包裹体与斑岩体石英斑晶内发育的流体包裹体组合类型基本一致,表明成矿流体主要来自斑岩体结晶分异出的岩浆热液。流体包裹体研究表明,北衙金多金属矿区内的矽卡岩型(金铜铁)、斑岩型(铜金钼)及外围碳酸盐岩等地层中的似层状热液型(铅锌银)矿床系列为与富碱斑岩体侵位活动有关的,由岩浆分异热液并逐渐演化形成的斑岩型金-铁铜-铅锌(银)多金属成矿系统。     

湖南宝山铜铅锌多金属矿床矿物学特征及其地质意义

宝山铜铅锌多金属矿床位于我国南岭成矿带中段北缘,是南岭成矿带中的重要类型之一。宝山矿床具有明显的水平分带性,即以花岗闪长斑岩为中心的铜钼矿化,周边是铅锌银矿化。本文通过对宝山铜铅锌多金属矿床中的石榴子石、透辉石、黄铁矿、闪锌矿等矿物进行矿物学研究及电子探针测试分析,归纳总结出：宝山铜铅锌多金属矿床成矿期次为矽卡岩阶段、退变质与氧化物阶段、硫化物阶段;矿床石榴石端员组分总体以钙铁榴石（23.48%~90.39%）为主,其次为钙铝榴石（5.81%~71.27%）;辉石的成分端员以透辉石（Di_61-95）为主,石榴子石成分和透辉石组分与世界上典型矽卡岩型铜矿的石榴子石和透辉石组分十分相似,属于典型的矽卡岩型铜矿床。从宝山铜铅锌多金属矿床硫化物中黄铁矿、闪锌矿矿物成分组成可以看出,该矿床硫化物为岩浆热液成因,并呈现出北东向比南西向成矿温度高的特征。     

东昆仑拉陵灶火地区斑岩型钼矿成矿流体特征

拉陵灶火钼多金属矿床东昆仑成矿带新发现的一个矽卡岩-斑岩型钼多金属矿床,针对该矿床矿化石英脉中的流体包裹体进行温压条件及单个包裹体激光拉曼光谱研究。结果表明,流体包裹体类型主要有气液两相、含CO2三相及富CO2包裹体。测温结果显示石英辉钼矿化阶段包裹体均一温度集中于200℃~350℃,石英硫化物细脉阶段包裹体均一温度集中165℃~210℃。成矿流体的盐度w(NaCl eqv)介于2.73%~16.72%,总体属中低盐度CO2-H2O-NaCl体系。成矿过程中发生过沸腾作用,压力急剧降低,可能产生沸腾作用主要因素。本区斑岩型钼矿形成于洋壳俯冲结束到陆陆碰撞开始的转折期,下地壳的部分熔融是成岩成矿的主要物质源区,因此成矿流体具有富CO2的特征。     

安徽安庆铜铁矿床矽卡岩岩相学和矿物学特征及意义

安庆铜铁矿床系长江中下游铁铜成矿带中一典型矽卡岩型矿床.矿体产于月山岩体与下三叠统南陵湖组碳酸盐岩之间的接触带,外接触带矽卡岩中透辉石富集,以铁铜矿化为主;内接触带矽卡岩中石榴子石富集,以铜矿化为主.岩相学研究表明研究区含铜矽卡岩演化经历了矽卡岩期和热液蚀变期,其中,矽卡岩期包括早期矽卡岩阶段、磁铁矿阶段和晚期矽卡岩阶段;热液蚀变期包括早期热液交代阶段、石英-硫化物阶段和石英-碳酸盐阶段.大规模的黄铜矿化发生于石英-硫化物阶段.矿物学研究表明,石榴子石均为钙铁榴石,早期矽卡岩阶段的粒状石榴子石发育韵律环带,其FeO和Al2O3含量表现为振荡变化.与粒状石榴子石相比,晚期矽卡岩阶段脉状石榴子石的And组分更高.早期矽卡岩阶段的粒状辉石为透辉石,具有环带结构,由核部到边部MgO含量减少,FeO含量增加;晚期矽卡岩阶段的脉状辉石为钙铁辉石.空间上,从外接触带到内接触带,辉石的MgO含量与石榴子石的Al2O3含量分别减少,而FeO含量均分别增加.岩相学、矿物学,结合已有地球化学研究成果综合表明,安庆铜铁矿矽卡岩为岩浆热液接触交代成因,Mg来自碳酸盐岩,由外带向内带迁移;Fe来自岩浆热液,由内带向外带迁移,由于磁铁矿阶段的温压条件改变,Fe在外接触带以磁铁矿的形式沉淀富集.     

云南金厂河铁铜铅锌多金属矿床矽卡岩矿物学特征及蚀变分带

金厂河铁铜铅锌多金属矿床是位于"三江"地区保山地块北部的隐伏多金属矿床,矿体呈层状、似层状产于上寒武统核桃坪组大理岩化灰岩与矽卡岩内,受NW向F2断裂和NE向F10断裂控制明显。本文根据野外穿切关系及矿物共生组合,将矿床划分为4个成矿阶段,即矽卡岩阶段、退化蚀变阶段、石英-硫化物阶段、碳酸盐阶段。矿区脉石矿物包括石榴子石、辉石、角闪石、绿帘石、绿泥石、黑柱石、石英、方解石、萤石等,矿石矿物主要包括磁铁矿、黄铜矿、磁黄铁矿、黄铁矿、方铅矿和闪锌矿。本文以矽卡岩矿物为研究对象,利用电子探针技术对其矿物学特征进行研究,结果表明:该矿床矽卡岩矿物主要为钙矽卡岩,石榴子石以钙铁榴石为主,辉石为透辉石-钙铁辉石过渡系列,角闪石主要为阳起石、铁阳起石和铁闪石,黑柱石含铁较高,多与磁铁矿相伴生;本矿床含少量锰质矽卡岩,包括锰铝榴石、含锰钙铁辉石、含锰阳起石、含锰黑柱石。矿床从深至浅的垂向分带以及自东向西的水平分带具有相似性:含Fe钙质矽卡岩※含Cu钙质矽卡岩※含Pb-Zn锰质矽卡岩※大理岩化灰岩,表明由矿床中部至两侧,自东向西,均有明显高温氧化环境向低温还原环境演化趋势。通过与已有矽卡岩Pb-Zn矿床矿物分带模型对比,推测存在深部岩浆热液以断裂交汇部位侵入交代围岩成矿,该矿床应为远接触带的矽卡岩型隐伏铁铜铅锌多金属矿床。     

江西永平铜多金属矿床流体包裹体及硫同位素研究

永平铜多金属矿床位于华南地区十杭裂谷带南侧,是一个与晚侏罗世二长花岗斑岩侵入体有关的斑岩-矽卡岩矿床。矿区存在斑岩型钼矿和矽卡岩型铜矿两种矿化类型。其中,斑岩型钼矿含矿石英脉中主要发育I型气液两相包裹体、II型CO_2三相包裹体和III型含子矿物多相包裹体,早期石英-硫化物阶段流体包裹体的形成温度介于202~359℃之间,盐度介于4.62~36.68 wt%NaCl之间;晚期石英-碳酸盐-硫化物阶段均一温度介于211~318℃之间,盐度范围为2.07~11.47 wt%NaCl。矽卡岩铜矿主要发育I型气液两相包裹体,早期矽卡岩阶段均一温度达到406~486℃,盐度为9.21~9.89 wt%NaCl;石英-硫化物阶段均一温度介于137~335℃之间,盐度值范围为4.98~13.20 wt%NaCl;晚期碳酸盐阶段包裹体均一温度只有89~151℃,盐度范围介于2.07~19.13 wt%NaCl之间。激光拉曼结果显示两者流体包裹体中具有相似的气相成分,都以CO_2和H_2O为主,成矿流体总体上属于H_2O-CO_2-NaCl体系。含Mo成矿流体中存在CH_4,具有低氧逸度特征,在流体演化早期形成Mo矿化中心,石英-硫化物阶段含Mo流体相对于含Cu流体具有更高的温度和压力。矿石中金属硫化物的δ~(34)S值变化于–0.2‰~+1.9‰之间,这表明成矿物质硫源主要来自深源岩浆。结合地质特征,认为该矿床是与晚侏罗世花岗质岩浆密切相关的斑岩钼-矽卡岩铜矿床,铜和钼矿化存在分带现象,岩浆系统的中心部位具有斑岩型钼矿化,外围及和碳酸盐岩的接触带形成斑岩-矽卡岩型铜钨铅锌矿化。     

矽卡岩岩浆对中国北方某些矽卡岩型矿床形成的制约——来自包裹体激光拉曼分析证据

本文将报道中国北方主要矽卡岩型矿床矿物熔融包裹体和流体-熔融包裹体的激光拉曼分析结果。研究目的是确认这些矿化矽卡岩矿物是否含熔融包裹体和流体-熔融包裹体,获取有关它们相态特征和相组成以及它们的分布状况(是局部的、偶然性的,还是广泛的)的信息。文章对邯邢铁矿、蒙库铁矿和杨家杖子钼矿等9个矿床12块标本中石榴石、辉石和方解石或白云石中23个包裹体进行了共聚焦激光拉曼光谱仪分析。拉曼分析结果表明,所研究的矽卡岩矿物均含熔融包裹体和/或流体-熔融包裹体,它们是岩浆矽卡岩的直接证据。结合本文激光拉曼分析结果、地质背景和其他地区岩浆矽卡岩矿物包裹体测温学研究,对所研究矽卡岩的形成机制和岩浆矽卡岩对中国北方某些矽卡岩型矿床的制约进行了讨论。认为含有熔融包裹体和/或流体-熔融包裹体的矿化矽卡岩系岩浆成因,其分布范围广泛,规模不小。中国北方某些矽卡岩型矿床的时空分布和规模受控于该地区分布的岩浆矽卡岩。希望本文有助于拓宽矽卡岩型矿床成矿规律研究和深部找矿勘探的思路。     

南秦岭下地壳组成及岩石圈的拆离俯冲作用

根据新提供的Pb同位素组成及岩石地球化学研究成果，本文进一步证实了位于北秦岭北界的明港地区发育的早中生代安山玄武质火山角砾岩岩筒所携带的下地壳捕虏体属于南秦岭。所恢复的南秦岭下地壳剖面自下而上为：底侵成因的变辉长岩-基性麻粒岩(其中含有榴辉岩及辉石岩的透镜体)-酸性麻粒岩。秦岭造山带总体的岩石因模型为：南秦岭(扬子块体)向北拆离俯冲，北秦岭地壳向华北仰冲，华北岩石因呈楔状插入秦岭造山带，拆离面约在中、下地壳之间。南秦岭俯冲岩片延伸的范围在平面上有可能达到400km。     

青藏高原综合观测研究站的回顾与展望

中国科学院青藏高原综合观测研究站从１９８８年建站到１９９８年以来,在各个方面均取得了长足的发展,横向生产性项目的开展和完成不仅解决了部队和地方的实际问题,而且缓和了观测研究站在运行过程中所面临的经费严重不足的问题,同时也为我所冻土专业研究人员提供了在生产中实践的机会,在基础理论研究方面,承担了国家攀登计划项目,国家基金项目,中国科学院重点项目和中国科学院冰冻圈专项项目等的研究工作,在多年冻土变化,     

Principles of spatial organization and evolution of the biosphere and the noosphere

In his last lifetime essay, “A Few Words about the Noosphere”, Academician V.I. Vernadsky (1944) wrote that all living organisms on the planet, including man, are integral to the biosphere of the Earth, its material and energy structure and cannot be physically independent of it even for a minute. However, the substrate that generates all living beings and is no less tightly bound to the biosphere has always been characterized by a significant geochemical heterogeneity, traced both in the vertical and in the lateral structure of all geospheres.

The present work is devoted to three most important aspects of modern geochemistry and biogeochemistry:

• — evolution of the ecological and geochemical state of the environment under conditions of a virgin (anthropogenically untouched) biosphere;
• — structural features of the geochemical organization of the modern noosphere;
• — specificity of the interaction of living matter with the environment under increasing anthropogenic load.

On the basis of theoretical concepts of biogeochemistry and geochemical ecology, formulated in the works of V.I. Vernadsky, A.P. Vinogradov, A.E. Fersman, B.B. Polynov, A.I. Perel’man, M.A. Glazovskaya, V.V. Kovalsky, E. Odum, B. Commoner, E.I. Kolchinskii and others, the author puts forward a hypothesis that there exist two qualitatively different stages in the evolution of the biosphere.The first stage is recognized as the period of natural evolution of the biosphere during which it evolves successively into a more complex and more biogeochemically specialized object. In the course of the geological time, this constantly results, on the one hand, in an increase in species diversity and the perfection of individual species, and, on the other hand, to directed improvement and a greater differentiation of the geochemical conditions of the environment. At this stage, the evolution of all systems of the biosphere that were controlled by the mechanisms of self-organization and self-regulation resulted in the establishment of a dynamic equilibrium, which was responsible for the cycling of all essential chemical elements and therefore providing ecologically optimal geochemical conditions in all ecological niches and for all species and biocenoses inhabiting the biosphere at any given moment.The beginning of the second stage is related to the appearance of reason and qualitative changes in the biosphere caused by the goal-directed activity of the human mind, as an entirely new geological force that appeared to be able not only to disrupt the functioning of natural mechanisms of self-regulation and selforganization, but also to transform the environment in the intersts of a single biological species, Homo sapiens. A direct consequence of this change was the uncontrolled transformation of the natural environment, during which the primary structure (geochemical background) created in the course of billions of years was eventually superimposed by a qualitatively new layer of anthropogenically-derived chemical elements and compounds, thus building an interference pattern of a new geochemical field with which practically all modern living organisms are now forced to interact.An outstanding feature of the new evolutionary stage of the natural environment, called by Vernadsky the noosphere, is that biogeochemical changes at this stage proceed at a rate which exceeds that required for the living matter to adapt to these changes. The result is the disruption of the existing parameters of the biological cycle, leading to the emergence of a significant number of endemic diseases of geochemical nature.The proposed approach was used to prove the anthropogenic genesis of existing geochemical endemic diseases and explain the mechanisms of their appearance. In addition, this approach allowed us to develop a new methodology for mapping zones of ecological and geochemical risk and noticeably simplify the procedure of monitoring distribution and prevention of all diseases of geochemical nature.     

铀钍的地球化学及对地壳演化和生物进化的影响

本文论述了在含挥发份和贫挥发份条件下Ｕ、Ｔｈ的迁移行为及其对地球和行星演化的影响,并阐述了造成地球独特地质演化历史的原因。提出了Ｕ、Ｔｈ在地球中的迁移模式以及该模式对地壳形成、演化的控制作用和对生物发展演化的可能影响。     

Palaeoecology and the origin of the coconut

While botanists, archaeologists, historians and linguists have contributed to the debate on the origin of the coconut pollen analysts have been silent. This article attempts to integrate the results of recent palaeoecological research with findings from the other disciplines.     

共和盆地层状地貌系统与青藏高原隆升及黄河发育

利用卫星遥感影像,结合实地调查和测年结果,对共和盆地层状地貌系统进行了解译、分析。研究表明,共和盆地层状地貌系统由山麓剥蚀面、洪积扇面、盆地面以及黄河阶地面构成,其空间结构、物质组成对发生于早更新世早期的青藏运动C幕和中更新世末期的共和运动反映清晰。青藏运动C幕使青藏高原主夷平面在高原差异性隆升中彻底解体,垂直变形量高达1700m。共和运动使黄河在0.11Ma进入共和盆地,其后黄河平均以3.5mm/a的侵蚀速率下切盆地,同时在盆地边部的山前古冲洪积扇以大致相近的速率被抬升,最终导致高差在2000m左右的层状地貌系统的出现。     

Wavelets and the Generalization of the Variogram

The experimental variogram computed in the usual way by the method of moments and the Haar wavelet transform are similar in that they filter data and yield informative summaries that may be interpreted. The variogram filters out constant values; wavelets can filter variation at several spatial scales and thereby provide a richer repertoire for analysis and demand no assumptions other than that of finite variance. This paper compares the two functions, identifying that part of the Haar wavelet transform that gives it its advantages. It goes on to show that the generalized variogram of order k=1, 2, and 3 filters linear, quadratic, and cubic polynomials from the data, respectively, which correspond with more complex wavelets in Daubechies's family. The additional filter coefficients of the latter can reveal features of the data that are not evident in its usual form. Three examples in which data recorded at regular intervals on transects are analyzed illustrate the extended form of the variogram. The apparent periodicity of gilgais in Australia seems to be accentuated as filter coefficients are added, but otherwise the analysis provides no new insight. Analysis of hyerpsectral data with a strong linear trend showed that the wavelet-based variograms filtered it out. Adding filter coefficients in the analysis of the topsoil across the Jurassic scarplands of England changed the upper bound of the variogram; it then resembled the within-class variogram computed by the method of moments. To elucidate these results, we simulated several series of data to represent a random process with values fluctuating about a mean, data with long-range linear trend, data with local trend, and data with stepped transitions. The results suggest that the wavelet variogram can filter out the effects of long-range trend, but not local trend, and of transitions from one class to another, as across boundaries.