Neoproterozoic magmatic events in the South Qinling Belt,China: Implications for amalgamation and breakup of the Rodinia supercontinent

Neoproterozoic magmatic rocks in the South Qinling Belt of China provide important clues for understanding the mechanism and timing of the amalgamation and breakup of the Rodinia supercontinent. Here we report new geochemical and high-precision LA-ICP-MS zircon U–Pb–Hf isotopic analyses on magmatic suites from the Liuba and Zhashui areas in the South Qinling Belt. Our data show that the crystallization ages of the granitic intrusions from Tiefodian and Tangjiagou in the Liuba area are 863 ± 22 Ma and 794 ± 11 Ma, respectively, whereas those of the dioritic and gabbroic intrusions at Chishuigou in the Zhashui area are 925 ± 28 Ma and 832.6 ± 4.0 Ma, respectively. The diorites at Chishuigou display arc-related geochemical affinity, characterized by strong depletion in Nb, Ta, P and Ti, and enrichment in large-ion lithophile elements (i.e., Rb, Ba, Th and U), indicating a subduction-related arc setting at ca. 925 Ma. The Tiefodian granitic rocks have high SiO₂ (68.46–70.98 wt.%), Na₂O (3.87–4.51 wt.%), and low K₂O (1.34–2.61 wt.%) contents with TTG affinity. However, their Cr, and Ni contents and Cr/Ni, Nb/Ta ratios are similar to those of continental crust, and together with high negative ε_Hf(t) values (− 4.87 to − 14.84), suggesting a continental margin arc at ca. 863 Ma. The gabbros at Chishuigou have high TiO₂ content (2.74–3.14 wt.%), Zr/Y (3.93–4.24), Ta/Yb (0.19–0.25) ratios and low Zr/Nb ratios (11.37–13.17), similar to the features of within-plate basalts, indicating an intra-continental rift setting at ca. 833 Ma. The granitoids at Tangjiagou exhibit enrichment of LREE, K and Pb, and depletion of Nb, Ta, P and Ti, suggesting an extensional tectonic environment at ca. 794 Ma.The results indicate that Neoproterozoic magmatic rocks in the South Qinling Belt formed before ca. 833 Ma and might represent the amalgamation of the Rodinia supercontinent in an arc-related subduction environment, whereas the magmatic events with the peak ages at ~ 740 Ma during ca. 833–680 Ma represent the breakup of Rodinia. Integrating our new data with those from previous works, we propose a new tectonic model for the evolutionary history of the South Qinling Belt in the Neoproterozoic, including four key stages: 1) an ocean that separated the South Qinling Belt and the Yangtze Block in the Early Neoproterozoic (ca.1000–956 Ma); 2) bidirectional subduction of the oceanic lithosphere during ca. 956–870 Ma; 3) subduction and collision between the South Qinling Belt and the Yangtze Block during ca. 870–833 Ma, thus suggesting that the South Qinling Belt was as a part of the Yangtze Block from this period; and 4) intra-continental rifting during ca. 833–680 Ma, although the blocks were not entirely rifted apart.     

The Mesoproterozoic Guaporé suture in the SW Amazonian Craton: Geotectonic implications based on field geology,zircon geochronology and Nd–Sr isotope geochemistry

A major Mesoproterozoic paleo-plate boundary in the southwestern Amazonian Craton, the Guaporé Suture Zone, is investigated by U–Pb zircon geochronology, Sr–Nd isotope geochemistry and aeromagnetic data. This suture zone is constituted dominantly by ophiolitic mafic–ultramafic rocks of the Trincheira Complex, and minor proportion of tonalites of the Rio Galera and São Felipe complexes, Colorado Complex, amphibolites of the Rio Alegre Terrane and syn- to late-kinematic mafic to felsic plutonic rocks. The ophiolitic Trincheira Complex formed during an accretionary phase from 1470 to 1430 Ma and was overprinted by upper amphibolite–granulite facies metamorphism during the collisional phase of the Ectasian followed by syntectonic emplacement of gabbro and granite plutons (1350–1340 Ma). The ophiolites were intruded by syntectonic tonalitic–plagiogranitic plutons ca. 1435 Ma. Mafic–ultramafic rocks of the Trincheira ophiolites show moderate to highly positive initial epsilon Nd (t = 1.46 Ga) values (+2.6 to +8.8) and very low initial ⁸⁷Sr/⁸⁶Sr ratio (0.7013–0.7033). It is suggested that these magmas originated from a depleted mantle source in an island-arc–back-arc setting. The identification of a fossil ophiolite in the Guaporé Suture Zone early as 1470–1435 Ma and later collisional phase, as late as 1350 Ma, marks the impingement of the proto-Amazonian Craton against the Paragua Block, before the formation of the Rodinia supercontinent. The results provide important insights into the geodynamic history of the SW Amazonian Craton, with evidence for both accretionary orogen and subduction of oceanic lithosphere in the Mesoproterozoic, and provide information that allows other workers to evaluate the configuration of supercontinents.     

U–Pb and Lu–Hf isotopes in detrital zircon from Neoproterozoic sedimentary rocks in the northern Yangtze Block: Implications for Precambrian crustal evolution

A combined study of Lu–Hf isotopes and U–Pb ages for detrital zircons from sedimentary rocks can provide information on the crustal evolution of sedimentary provenances, and comparisons with potential source regions can constrain interpretations of paleogeographic settings. Detailed isotopic data on detrital zircons from Neoproterozoic sedimentary rocks in the northern part of the Yangtze Block suggest that these rocks have the maximum depositional ages of ~ 750 Ma, and share a similar provenance. In their source area, units of late Archean (2.45 to 2.55 Ga) to Paleoproterozoic (1.9 to 2.0 Ga) U–Pb ages made up the basement, and were overlain or intruded by magmatic rocks of Neoproterozoic U–Pb ages (740 to 900 Ma). Hf isotopic signatures of the detrital zircons indicate that a little juvenile crust formed in the Neoarchean; reworking of old crust dominates the magmatic activity during the Archean to Paleoproterozoic, while the most significant juvenile addition to the crust occurred in the Neoproterozoic. Only the Neoproterozoic zircon U–Pb ages can be matched with known magmatism in the northern Yangtze Block, while other age peaks cannot be correlated with known provenance areas. Similar zircon U–Pb ages have been obtained previously from sediments along the southeastern and western margins of the Yangtze Block. Thus, it is suggested that an unexposed old basement is widespread beneath the Yangtze Block and was the major contributor to the Neoproterozoic sediments. This basement had a magmatic activity at ~ 2.5 Ga, similar to that in North China; but zircon Hf isotopes suggest significant differences in the overall evolutionary histories between the Yangtze and North China.     

Neoproterozoic sequences along the Dexing–Huangshan fault zone in the eastern Jiangnan orogen,South China: Geochronological and geochemical constrains

The Neoproterozoic Xikou Group is unconformably overlain by the Heshangzhen Group in the eastern Jiangnan orogen, South China. Samples from the Xikou and Heshangzhen Groups have generally intermediate to high SiO₂ (53.14–77.48 wt.%, average 65.33 wt.%) and Al₂O₃ (11.53–27.14 wt.%, average 18.96 wt.%) contents, typical of immature lithic varieties. Compared to the Xikou Group, the Heshangzhen Group has higher Al₂O₃ (average 21.19 wt.% for the Heshangzhen Group and 18.33 wt.% for the Xikou Group, respectively) and Fe₂O₃* + MgO (average 9.38 wt.% and 8.86 wt.%) contents, but lower SiO₂ (average 59.79 wt.% and 66.91 wt.%) content, suggesting that the Heshangzhen Group has more mafic components. The Chemical Index of Alteration (69–81) and the high Th/U ratios (> 3.8) indicate moderate weathering of the source area. Rare earth element patterns suggest that the source rocks came from an upper continental crust composed chiefly of felsic rocks. Discrimination diagrams reveal a mixed provenance of granitic and felsic volcanic components with minor old sedimentary component.Detrital zircon U–Pb ages and previous geochronological data of granitic plutons indicate that the Xikou and Heshangzhen Groups were deposited at 840–820 Ma and 810–780 Ma, respectively. The Xikou Group was deposited in a back–arc basin and its source rocks came mainly from the Yangtze Block. The Heshangzhen Group formed in a post-orogenic setting with a provenance of the Yangtze Block and the Shuangxiwu arc. The Jiangnan orogen was built at 820–810 Ma after the final suturing between the Yangtze and the Cathaysia Blocks. This orogen collapsed shortly following the collision (within 10–20 million years) and formed the Dexing–Huangshan normal fault zone.     

Neoproterozoic,Paleozoic, and Mesozoic granitoid magmatism in the Qinling Orogen,China: Constraints on orogenic process

The Qinling Orogen is one of the main orogenic belts in Asia and is characterized by multi-stage orogenic processes and the development of voluminous magmatic intrusions. The results of zircon U–Pb dating indicate that granitoid magmatism in the Qinling Orogen mainly occurred in four distinct periods: the Neoproterozoic (979–711 Ma), Paleozoic (507–400 Ma), and Early (252–185 Ma) and Late (158–100 Ma) Mesozoic. The Neoproterozoic granitic magmatism in the Qinling Orogen is represented by strongly deformed S-type granites emplaced at 979–911 Ma, weakly deformed I-type granites at 894–815 Ma, and A-type granites at 759–711 Ma. They can be interpreted as the products of respectively syn-collisional, post-collisional and extensional setting, in response to the assembly and breakup of the Rodinia supercontinent. The Paleozoic magmatism can be temporally classified into three stages of 507–470 Ma, 460–422 Ma and ∼415–400 Ma. They were genetically related to the subduction of the Shangdan Ocean and subsequent collision of the southern North China Block and the South Qinling Belt. The 507–470 Ma magmatism is spatially and temporally related to ultrahigh-pressure metamorphism in the studied area. The 460–422 Ma magmatism with an extensive development in the North Qinling Belt is characterized by I-type granitoids and originated from the lower crust with the involvement of mantle-derived magma in a collisional setting. The magmatism with the formation age of ∼415–400 Ma only occurred in the middle part of the North Qinling Belt and is dominated by I-type granitoid intrusions, and probably formed in the late-stage of a collisional setting. Early Mesozoic magmatism in the study area occurred between 252 and 185 Ma, with the cluster in 225–200 Ma. It took place predominantly in the western part of the South Qinling Belt. The 250–240 Ma I-type granitoids are of small volume and show high Sr/Y ratios, and may have been formed in a continental arc setting related to subduction of the Mianlue Ocean between the South Qinling Belt and the South China Block. Voluminous late-stage (225–185 Ma) magmatism evolved from early I-type to later I-A-type granitoids associated with contemporaneous lamprophyres, representative of a transition from syn- to post-collisional setting in response to the collision between the North China and the South China blocks. Late Mesozoic (158–100 Ma) granitoids, located in the southern margin of the North China Block and the eastern part of the North Qinling Belt, are characterized by I-type, I- to A-type, and A-type granitoids that were emplaced in a post-orogenic or intraplate setting. The first three of the four periods of magmatism were associated with three important orogenic processes and the last one with intracontinental process. These suggest that the tectonic evolution of the Qinling Orogen is very complicated.     

Geochemistry of Neoproterozoic mafic intrusions in the Panzhihua district (Sichuan Province,SW China): Implications for subduction-related metasomatism in the upper mantle

Metasomatism above subduction zones is an important process that produces heterogeneous mantle and thus a diversity of igneous rocks. In the Panzhihua district, on the western margin of the Yangtze Block (SW China), two Neoproterozoic mafic intrusions, one olivine gabbro and one hornblende gabbro, have identical ages of 746 ± 10 and 738 ± 23 Ma. Both of the gabbros are tholeiitic in composition and have arc-like geochemical compositions. The hornblende gabbros have K₂O concentrations ranging from 0.70 to 1.69 wt.% and show enrichment of Rb, Ba, U, Th and Pb and depletion of Nb,Ta and Ti. They have variable ⁸⁷Sr/⁸⁶Sr ratios (0.7045–0.7070) with constant ɛNd(t) values (−0.12 to −0.93). The olivine gabbros have relatively low K₂O (0.19–0.43 wt.%), are depleted in Rb and Th relative to Ba and U, and have obvious negative Nb–Ta and Zr–Hf anomalies on primitive mantle-normalized trace element diagrams. Their ɛNd(t) values range from −0.64 to −1.73 and initial ⁸⁷Sr/⁸⁶Sr ratios from 0.7070 to 0.7075. Both types of gabbro experienced fractional crystallization of clinopyroxene, plagioclase, amphibole and minor Fe–Ti oxide. The parental magmas of the olivine and hornblende gabbros were formed by about 20% partial melting of garnet–spinel lherzolite and spinel lherzolite, respectively. According to trace elemental ratios, the hornblende gabbros were probably derived from a source strongly modified by subducted slab fluids, whereas the olivine gabbros came from a mantle source modified by subducted slab melts. The close association of the olivine gabbros and hornblende gabbros suggests that a steep subduction zone existed along the western margin of the Yangtze Block during Neoproterozoic time. Thus, the giant Neoproterozoic magmatic event in South China was subduction-related.     

Multiple Mesozoic porphyry-skarn Cu (Mo–W) systems in Yidun Terrane,east Tethys: Constraints from zircon U–Pb and molybdenite Re–Os geochronology

Porphyry Cu ± Mo ± Au deposits typically formed in volcanoplutonic arcs above subduction zones. However, there is increasing evidence for the occurrence of porphyry deposits related to magmas generated after the underplating arc has ceased. Post-subduction lithospheric thickening, lithospheric extension, or mantle lithosphere delamination could trigger the remelting of subduction-modified arc lithosphere and lead to the formation of post-subduction porphyry deposits. The NNW-trending Yidun Terrane, located in the eastern Tethys, experienced subduction of Garze–Litang oceanic plate (a branch of the Paleotethys) in the Late Triassic and witnessed two mineralization events respectively associated with the ca. 215 Ma arc-related intermediate–felsic porphyries and the 88–79 Ma mildly-alkaline granitic porphyries. It is, therefore, an ideal place to investigate the genetic linkage between the subduction-related porphyry deposits and post-subduction porphyry deposits. Our new in situ zircon U–Pb dating of the two granitic intrusions (biotite granite, 213.4 ± 0.9 Ma; monzogranite porphyry, 86.0 ± 0.4 Ma) in the Xiuwacu district, the molybdenite Re–Os age (84.7 ± 0.6 Ma) of the mineralization, and previously published geochronological data, together show the spatially overlapping distribution of the multiple Mesozoic porphyry systems in the Late Triassic Yidun arc system. Furthermore, the arc-like elemental signatures and the mixed Sr–Nd–Hf isotopic signatures of the Late Cretaceous ore-related porphyries (i.e., originating from a mixed components between the ∼215 Ma juvenile arc crust and the Mesoproterozoic mafic lower crust) indicate a genetic linkage between the Late Triassic and Late Cretaceous porphyry systems. This suggests that the remelting of underplated arc-related mafic rocks formed during the subduction of the Garze–Litang Ocean could be responsible for the mixing between the mantle-derived components and the Mesoproterozoic lower crustal materials, when post-subduction transtension occurred in the Late Cretaceous. The formation of the Late Cretaceous porphyry–skarn Cu–Mo–W deposits could most likely be related to the remelting of Late Triassic residual sulfide-bearing Cu-rich cumulates in the subduction-modified lower crust that triggered by the Late Cretaceous transtension.     

Three successive Proterozoic island arcs in the Northern Arabian–Nubian Shield: Evidence from SIMS U–Pb dating of zircon

Four isolated metamorphic complexes located within post-collisional granitoids occupying up to 70% of the total area, were distinguished in Sinai (Egypt) and Elat area (southern Israel), the northernmost part of the Arabian–Nubian Shield. The metamorphic rocks include metasediments, felsic and mafic metavolcanic rocks intruded by granitic, dioritic, and gabbroic plutons, all subjected to penetrative deformation.We present new SIMS U–Pb dating of zircons from 13 rock units comprising metasediments, volcanic rocks, gneisses and plutons from three metamorphic complexes (Sa'al, Feiran–Solaf, and Kid). In addition we present a SIMS U–Pb titanite age of a granitic gneiss previously dated using zircon. On the basis of the new and published U–Pb data, three successive Meso- to Neoproterozoic island arcs formed during a period of ca. 500 My are recognized. The Sa'al arc (represented by the oldest arc rocks in the ANS) evolved from 1.03 to 0.93 Ga (100 My); the Feiran–Elat arc developed from ca. 870 to 740 Ma (130 My), and the Kid arc formed from ca. 640 to 620 Ma (20 My). Evidence for an older, ca. 1.1 Ga, pre-Sa'al island arc was established from the zircon xenocryst population, though no exposures of rocks of this age were found. In the Sa'al and Kid arcs both volcanic and sedimentary rocks are preserved, whereas in the Elat–Feiran arc volcanic rocks are missing. We suggest that at ~ 700 Ma the Elat−Feiran arc was subjected to rifting that resulted in separating of the Qenaia block and its movement to the SE.     

U–Pb SHRIMP ages and tectonic setting of the Munster Suite of the Margate Terrane of the Natal Metamorphic Belt

New U–Pb Zircon SHRIMP ages of 1091 ± 7.1 Ma and 1093.1 ± 5.8 Ma have been determined for two discrete phases of the Munster Suite. The Munster Suite is a calc-alkaline mafic to intermediate suite of intrusive igneous rocks that form part of the southern-most tectonic Terrane of the Mesoproterozoic-aged Natal Metamorphic Belt. Previously published geochemical data indicate that the discrete phases of the Suite are consanguineous and that these rocks originated within an oceanic island arc environment. The new age determinations now show that the different phases are also coeval. Moreover, the ages also indicate that the intrusions were, within statistical error, coeval with S-type granites within the Terrane. This is interpreted to indicate that magmatic underplating provided both the magma by way of a number of progressively more evolved pulses to produce the Munster Suite, as well as the heat necessary for crustal melting to produce the S-type granites within an island arc environment. Therefore, these new age determinations indicate a period of crustal growth at circa 1090 Ma. This moreover, is a maximum constraint on the age of the northward-verging structures within the Margate Terrane.     

Provenance of lateritic bauxite deposits in the Wuchuan–Zheng’an–Daozhen area,Northern Guizhou Province,China: LA-ICP-MS and SIMS U–Pb dating of detrital zircons

The provenance of the large and super-large scale bauxite deposits developed in the Wuchuan–Zheng’an–Daozhen (WZD) alumina metallogenic province in the Yangtze Block of South China is poorly understood. LA-ICP-MS and SIMS U–Pb dating of detrital zircons from bauxite ores and the underlying Hanjiadian Group in the WZD area provide new constrains on the provenance of the WZD bauxite and provide new insight on the bauxite ore-forming process. The ages of the detrital zircons in the bauxites and the zircons in the Hanjiadian Group are similar suggesting that the bauxites are genetically related to the Hanjiadian sediments. The detrital zircon populations of the four samples studied show four primary age peaks: 2600–2400 Ma, 1900–1700 Ma, 1300–700 Ma and 700–400 Ma. The age distribution of detrital zircons indicates that they are probably derived from various sources including Neoproterozoic, Mesoproterozoic, Paleoproterozoic, Archean and some minor Paleozoic sources. The most abundant age population contains a continuous range of ages from 1300 to 700 Ma, ages consistent with subduction-related magmatic activities (1000–740 Ma) along the western margin of the Yangtze Block and the worldwide Grenville orogenic events (1300–1000 Ma). Thus, it is suggested that the main provenances of the WZD bauxite and the Hanjiadian Group are the Neoproterozoic igneous rocks in the western Yangtze Block and the Grenville-age igneous rocks in the southern Cathaysia Block. In addition, this work verifies that the global Grenville orogenic events and subduction-related magmatic activities associated with the Yangtze Block had a significant influence on the formation of the WZD bauxite deposits.     

Zircon U–Pb age,Hf isotopic compositions and geochemistry of the Silurian Fengdingshan I-type granite Pluton and Taoyuan mafic–felsic Complex at the southeastern margin of the Yangtze Block

This work presents an integrated study of zircon U–Pb ages and Hf isotope along with whole-rock geochemistry on Silurian Fengdingshan I-type granites and Taoyuan mafic–felsic intrusive Complex located at the southeastern margin of the Yangtze Block, filling in a gap in understanding of Paleozoic I-type granites and mafic-intermediate igneous rocks in the eastern South China Craton (SCC). The Fengdingshan granite and Taoyuan hornblende gabbro are dated at 436 ± 5 Ma and 409 ± 2 Ma, respectively. The Fengdingshan granites display characteristics of calc-alkaline I-type granite with high initial ⁸⁷Sr/⁸⁶Sr ratios of 0.7093–0.7127, low εNd(t) values ranging from −5.6 to −5.4 and corresponding Nd model ages (T_2DM) of 1.6 Ga. Their zircon grains have εHf(t) values ranging from −2.7 to 2.6 and model ages of 951–1164 Ma. The Taoyuan mafic rocks exhibit typical arc-like geochemistry, with enrichment in Rb, Th, U and Pb and depletion in Nb, Ta. They have initial ⁸⁷Sr/⁸⁶Sr ratios of 0.7053–0.7058, εNd(t) values of 0.2–1.6 and corresponding T_2DM of 1.0–1.1 Ga. Their zircon grains have εHf(t) values ranging from 3.2 to 6.1 and model ages of 774–911 Ma. Diorite and granodiorite from the Taoyuan Complex have initial ⁸⁷Sr/⁸⁶Sr ratios of 0.7065–0.7117, εNd(t) values from −5.7 to −1.9 and Nd model ages of 1.3–1.6 Ga. The petrographic and geochemical characteristics indicate that the Fengdingshan granites probably formed by reworking of Neoproterozoic basalts with very little of juvenile mantle-derived magma. The Taoyuan Complex formed by magma mixing and mingling, in which the mafic member originated from a metasomatized lithospheric mantle. Both the Fengdingshan and Taoyuan Plutons formed in a post-orogenic collapse stage in an intracontinental tectonic regime. Besides the Paleozoic Fengdingshan granites and Taoyuan hornblende gabbro, other Neoproterozoic and Indosinian igneous rocks located along the southeastern and western margin of the Yangtze Block also exhibit decoupled Nd–Hf isotopic systemics, which may be a fingerprint of a previous late Mesoproterozoic to early Neoproterozoic oceanic subduction.     

Geochemistry,petrogenesis and tectonic setting of Neoproterozoic mafic–ultramafic rocks from the western Jiangnan orogen,South China

The Jiangnan orogenic belt (JOB) has been interpreted as a suture zone between the Yangtze craton and Cathaysian terranes in South China. The Neoproterozoic mafic–ultramafic rocks are extensively exposed in the western JOB, providing an ideal opportunity to study the Neoproterozoic assembly and tectonic evolution of South China. We present integrated field and geochemical studies including LA-ICP-MS zircon U–Pb dating, and whole-rock major and trace element and Sm–Nd isotope analyses of the Neoproterozoic mafic–ultramafic rocks exposed in the northern Guangxi Province, South China. Geochronological results show that the magmatic events took place in two distinct periods: the early Neoproterozoic (861–834 Ma) and the late Neoproterozoic (770–750 Ma). Early Neoproterozoic ultramafic rocks of the Sibao Group have positive ε_Nd(t) values (+ 2.7 to + 6.6) whereas mafic rocks exhibit negative ε_Nd(t) values (− 5.8 to − 0.9). The basaltic rocks show TiO₂ contents of 0.62–0.69 wt.% and Mg-number of 59–65, and also display an enrichment of light rare earth elements (LREEs) and pronounced negative Nb, Ta and Ti anomalies on chondrite- and primitive mantle-normalized diagrams, consistent with subduction-related geochemical signatures. Late Neoproterozoic rocks of the Danzhou Group show ε_Nd(t) values (− 1.23 to + 3.19) for both ultramafic and mafic rocks. The basaltic rocks have TiO₂ contents of 1.01–1.33 wt.% and Mg-number of 57–60, and have a mixture of MORB- and arc-like geochemical affinities, inferred to have formed in an extensional arc environment. Geochemical signatures suggest that all rock types in this study were derived from subarc mantle wedge sources and underwent various degrees of crustal contamination. Thus, we suggest that subduction may have continued to ca. 750 Ma in the western JOB, implying that the amalgamation event between the Yangtze craton and Cathaysian terranes was later than 750 Ma.     

Postcollisional magmatism: Geochemical constraints on the petrogenesis of Mesozoic granitoids in the Sulu orogen,China

A combined study of zircon U–Pb ages and Lu–Hf isotopes, mineral O isotopes, whole-rock elements and Sr–Nd isotopes was carried out for Mesozoic granitoids from the Shandong Peninsula in east-central China, which tectonically corresponds to the eastern part of the Sulu orogen that formed by the Triassic continental collision between the South and North China Blocks. Four plutons were investigated in this region, with the Linglong and Guojialing plutons from the northwestern part (Jiaobei) and the Kunyushan and Sanfoshan plutons from the southeastern part (Jiaodong). The results show that these granitoids mostly have high Sr, low Yb and Y contents, high (La/Yb)_N and Sr/Y ratios with negligible to positive Eu anomalies (Eu/Eu* = 0.69–1.58), which are similar to common adakites. On the other hand, they have relatively low MgO, Cr, Ni contents and thus low Mg#. Zircon U–Pb dating yields Late Jurassic ages of 141 ± 3 to 157 ± 2 Ma for the Linglong and Kunyushan plutons, but Early Cretaceous ages of 111 ± 2 to 133 ± 3 Ma for the Guojialing and Sanfoshan plutons. Some zircon cores from the Linglong and Kunyushan granitoids have Neoproterozoic U–Pb ages. All the granitoids have variably negative zircon ε_Hf(t) values of ?39.6 to ?5.4, with Mesoproterozoic to Paleoproterozoic Hf model ages of 1515 ± 66 to 2511 ± 97 Ma for the Sanfoshan pluton, but Paleoproterozoic to Paleoarchean Hf model ages of 2125 ± 124 to 3310 ± 96 Ma for the other three plutons. These indicate that the Mesozoic granitoids formed in the postcollisional stage and were derived mainly from partial melting of the subducted South China Block that is characterized by Paleoproterozoic juvenile crust and Neoproterozoic magmatic rocks along its northern edge. However, there are some differences between the Jiaobei and Jiaodong plutons. Compared to the Jiaodong granitoids, the Jiaobei granitoids have very old zircon Hf model ages of 3310 ± 96 Ma suggesting the possible involvement of a Paleoarchean crust that may be derived from the North China Block. Therefore, the continental collision between the two blocks would bring crustal materials from both sides into the subduction zone in the Triassic, yielding subduction-thickened crust as the magma source for the adakite-like granitoids. While lithospheric extension and orogenic collapse are considered a major cause for postcollisional magmatism, anatexis of the subducted mafic crust is proposed as a mechanism for chemical differentiation of the continental crust towards felsic composition.     

U–Pb ages and Hf isotopic record of zircons from the late Neoproterozoic and Silurian–Devonian sedimentary rocks of the western Yangtze Block: Implications for its tectonic evolution and continental affinity

The relationship of the Yangtze Block with other continental blocks of the Rodinia and Gondwana supercontinents is hotly debated. Here we report U–Pb and Lu–Hf isotopic data for zircons from the latest Neoproterozoic Yanjing Group and the overlying Silurian–Devonian rocks on the western margin of Yangtze Block, which provide critical constraints on the provenance of these sediments and further shed light on the crustal evolution and tectonic affinity of the western Yangtze Block in the context of Rodinia and the subsequent Gondwanaland. Mica schist from the middle part of the Yanjing Group contains dominant Neoproterozoic detrital zircons (0.72–0.80 Ga) with a pronounced age peak at 0.75 Ga. Based on the euhedral to subhedral shapes, high Th/U ratios and exclusively positive εHf(t) values (+ 6 to + 14) for the zircon crystals, and the lack of ancient zircons, we consider the sediments as products of proximal deposition near a Neoproterozoic subduction system in western Yangtze. Combined with the age of rhyolite from the lower part of the Yanjing Group, these strata were estimated to have been deposited in a period between 0.72 and 0.63 Ga. In contrast, the Silurian–Devonian sediments exhibit dominant Grenvillian ages (0.9–1.0 Ga), with middle Neoproterozoic (0.73–0.85 Ga), Pan-African (0.49–0.67 Ga) and Neoarchean (~ 2.5 Ga) age populations, suggesting a significant change of sedimentary provenance and thus a different tectonic setting. Although the shift occurred in the Silurian, the age spectra turn to be consistent along the western margin of the Yangtze Block until the Devonian, indicating persistence of the same sedimentary environment. However, the related provenance of these Paleozoic sediments cannot be found in South China. The presence of abundant Grenvillian, Pan-African and Neoarchean ages, along with their moderately to highly rounded shapes, indicates the possibility of exotic continental terrane(s) as a possible sedimentary provenance. Considering the potential source areas around the Yangtze Block when it was part of the Rodinia or Gondwana, we suggest that the source of these Paleozoic sediments had typical Gondwana affinities such as the Himalaya region, north India, which is also supported by their stratigraphic similarity, newly published paleomagnetic data and the tectono-thermal events of northwestern fragments of Gondwana. This implies that after a prolonged subduction in the Neoproterozoic, the western margin of the Yangtze Block began to incorporate into the assembly of the Gondwana supercontinent and was able to accept sediments from northwestern margin of Gondwanaland as a result of early Paleozoic orogeny.     

Geochronology and Hf isotope of detrital zircons from Precambrian sequences in the eastern Jiangnan Orogen: Constraining the assembly of Yangtze and Cathaysia Blocks in South China

The Jiangnan Orogen, the eastern part of which comprises the oceanic Huaiyu terrane to the northeast and the continental Jiuling terrane to the southwest, marks the collision zone of the Yangtze and the Cathaysia Blocks in South China. Here, zircon U–Pb geochronological and Lu–Hf isotopic results from typical basement and cover meta-sedimentary/sedimentary rock units in the eastern Jiangnan Orogen are presented. The basement sequences in southwestern Huaiyu terrane are mainly composed of marine volcaniclastic turbidite, ophiolite suite and tuffaceous phyllite, whereas those in the northeastern Huaiyu consist of littoral face pebbly feldspathic sandstones and greywacke interbedded with intermediate-basic volcanic rocks. Combined with previous studies, the present data show that the basement sequences exhibit arc affinities. Zircons from the basement phyllite in the southwestern margin of the Huaiyu terrane, representing a Neoproterozoic back-arc basin, yield a single age population of 800–900 Ma. The basement greywacke from northeastern Huaiyu terrane, representing fore-arc basin, is also characterized by zircons that preserve a single tectono-thermal event during 800–940 Ma. However, the late Neoproterozoic cover sequence preserves zircons from multiple sources with age populations of 750–890 Ma, 1670–2070 Ma and 2385–2550 Ma. Moreover, Hf isotopic data further reveal that most detrital zircons from the basement sequences yield positive εHf(t) values and late Mesoproterozoic model ages, while those of the cover sequence mostly show negative εHf(t) values. The Hf isotopic data therefore suggest that the basement sequences are soured from a Neoproterozoic arc produced by reworking of subducted late Mesoproterozoic materials. The geochronological and Hf isotopic data presented in this study suggest ca. 800 Ma for the assembly of the Huaiyu and Jiuling terranes, implying that the amalgamation of the Yangtze and Cathaysia Blocks in the eastern part occurred at ca. 800 Ma.     

A possible transition from island arc to continental arc magmatism in the eastern Jiangnan Orogen,South China: Insights from a Neoproterozoic (870–860 Ma) gabbroic–dioritic complex near the Fuchuan ophiolite

The Fuchuan ophiolite belt in the eastern Jiangnan Orogen of South China provides important constraints on the tectonic setting and evolution of the Neoproterozoic suture zone between the Yangtze and Cathaysia blocks. Combined UPbHf isotopic and REE analysis of zircon from gabbroic and dioritic samples of the Shexian complex, located 10 km southwest of the main Fuchuan ophiolite body, indicate that the complex crystallized at ca. 870–860 Ma with a large variation of zircon ε_Hf(t) values from − 4.80 to + 13.30. Whole-rock geochemistry reveals that the magma mainly experienced fractionation of olivine, clinopyroxene and plagioclase and was partly affected by crustal contamination, which resulted in elevated Th/Nb, Th/La and La/Sm ratios, as well as the scattered ε_Hf(t) values. The most mafic and least contaminated sample shows MORB affinity and was probably formed by partial melting of a depleted subduction-metasomatized mantle wedge. Other samples exhibit arc-like signatures and were probably modified by both melt- and fluid-related subduction metasomatism. The emplacement of the Shexian complex corresponds to the time that subduction switched from a ca. 1000–880 Ma intra-oceanic island arc to a 870–830 Ma continental arc along the southeastern Yangtze Block. The sequence of igneous rocks associated with this continental arc resemble those preserved in forearc Tethyan ophiolites, with magma evolving from ca. 870–860 Ma MORB to ca. 860–850 Ma arc tholeiite and ca. 830 Ma boninite. Arc magmatism concluded with the final assembly of the Yangtze and Cathaysia blocks at 830–800 Ma.     

Early Neoproterozoic tectonic evolution of the Erguna Terrane (NE China) and its paleogeographic location in Rodinia supercontinent: Insights from magmatic and sedimentary record

Owing to the lack of early Neoproterozoic geological and geochronological data, most Rodinia supercontinent reconstruction models do not include the Amuria Block in the Central Asian Orogenic Belt (CAOB), and the Amuria Block was varying attributed to the North China, Siberian or Tarim tectonic affinities. In this study, we identified one early Neoproterozoic granitic pluton (964–947 Ma) and one early Neoproterozoic sedimentary unit (<906 Ma) in the Erguna Terrane. The samples (964–947 Ma) are I-type granitoids, and show high zircon in-situ ε_Hf(t) (−2.1–10.0) and whole-rock ε_Hf(t) (1.4–4.8) and high ε_Nd(t) (−2.3 to −0.8). These granitoids are characterized by high Zr saturation temperature (T_Zr) (701–835 °C) and no inherited zircons, suggesting high-degree of partial melting of their source rocks. The granites were likely formed by biotite-/muscovite dehydration melting of subalkaline mafic lower crust in a continental arc setting. Detrital zircons of the sandstone sample define an age peak at 923–906 Ma. Early Neoproterozoic age data compilation from the four Amuria microcontinents (i.e., Erguna, Xing'an, Songnen and Jiamusi terranes) in NE China indicate the presence of two major magmatic flare-ups at 964–880 Ma and 850–740 Ma. Considering that early Neoproterozoic magmatic rocks are absent in the Siberian and North China cratons but widespread in the Tarim Craton, we suggested that the Erguna Terrane was part of the Tarim Craton in the Early Neoproterozoic. The Erguna Terrane may have undergone a two-staged Neoproterozoic tectonic evolutionary history: (1) early Neoproterozoic arc accretion in response to the Rodinia assembly, and (2) middle Neoproterozoic break-away from the SW Tarim Craton associated with the Rodinia breakup.     

The multi-stage tectonic evolution of the Xitieshan terrane,North Qaidam orogen,western China: From Grenville-age orogeny to early-Paleozoic ultrahigh-pressure metamorphism

The geodynamic evolution of the early Paleozoic ultrahigh-pressure metamorphic belt in North Qaidam, western China, is controversial due to ambiguous interpretations concerning the nature and ages of the eclogitic protoliths. Within this framework, we present new LA-ICP-MS U–Pb zircon ages from eclogites and their country rock gneisses from the Xitieshan terrane, located in the central part of the North Qaidam UHP metamorphic belt. Xitieshan terrane contains clearly different protolith characteristics of eclogites and as such provides a natural laboratory to investigate the geodynamic evolution of the North Qaidam UHP metamorphic terrane. LA-ICP-MS U–Pb zircon dating of three phengite-bearing eclogites and two country rock gneiss samples from the Xitieshan terrane yielded 424–427 Ma and 917–920 Ma ages, respectively. The age of 424–427 Ma from eclogite probably reflects continental lithosphere subduction post-dating oceanic lithosphere subduction at ~ 440–460 Ma. The 0.91–0.92 Ga metamorphic ages from gneiss and associated metamorphic mineral assemblages are interpreted as evidence for the occurrence of a Grenville-age orogeny in the North Qaidam UHPM belt. Using internal microstructure, geochemistry and U–Pb ages of zircon in this study, combined with the petrological and geochemical investigations on the eclogites of previous literature’s data, three types of eclogitic protoliths are identified in the Xitieshan terrane i.e. 1) Subducted early Paleozoic oceanic crust (440–460 Ma), 2) Neoproterozoic oceanic crust material emplaced onto micro-continental fragments ahead of the main, early Paleozoic, collision event (440–420 Ma) and 3) Neoproterozoic mafic dikes intruded in continental fragments (rifted away from the former supercontinent Rodinia). These results demonstrate that the basement rocks of the North Qaidam terrane formed part of the former supercontinent Rodinia, attached to the Yangtze Craton and/or the Qinling microcontinent, and recorded a complex tectono-metamorphic evolution that involved Neoproterozoic and Early Paleozoic orogenies.     

Neoproterozoic arc magmatism in the southern Madurai Block,India: Subduction,relamination, continental outbuilding,and the growth of Gondwana

The Madurai Block in southern India is a composite collage of at least three sub-blocks, with Neoarchean–Paleoproterozoic segments in the north and central domains, and a Neoproterozoic segment in the south. Here we investigate a suite of rocks with magmatic protoliths that constitute the basement in the southern margin of the Madurai Block including alkali granites, charnockites, enderbites and gabbros. The alkali granites are dominantly composed of perthitic K-feldspar, minor plagioclase and quartz, with hornblende as the main mafic mineral suggesting a calc-alkaline nature. The enderbites and charnockites have a broadly similar mineralogical constitution except for the variation in the modal content of plagioclase, K-feldspar and quartz, as well as the additional presence of clinopyroxene in some of the enderbites. The high modal content of hornblende in the gabbros suggests crystallization from hydrous basaltic melts. The geochemical features of this suite are identical to those of arc magmatic rocks, with distinct Nb, Ta, and Ti depletion suggesting magmatism in a subduction-related environment. We envisage that the underplating of basaltic magmas within a convergent margin setting provided the heat input for lower crustal melting generating the charnockitic suite of rocks. The intrusion of the underplated mafic melts as gabbroic dykes and sills into the crystallizing felsic magmas resulted in magma mixing and mingling generating the widespread enclaves of gabbroic rocks. The alkali granites were derived from the differentiation of lower crustal melts. Zircon U–Pb data from the alkali granites yield weighted mean ²⁰⁶Pb/²³⁸U ages of 786 ± 10 to 772 ± 11 Ma for the oldest and the most dominant group of magmatic grains, with a 662 ± 20 Ma subordinate group. The oldest group of magmatic zircons in the charnockite samples shows ages of 938 ± 27 Ma, 896 ± 12 Ma, and 786 ± 9 Ma, suggesting multiple magmatic pulses during early and mid-Neoproterozoic. A subordinate population of magmatic zircons with ages of 661 ± 9 Ma and 632 ± 7 Ma is also present. In the enderbites, the magmatic zircon population yields weighted mean ages of 926 ± 22 Ma, 923 ± 36 Ma, 889 ± 13 Ma, 803 ± 10 Ma, 787 ± 23 Ma, 786 ± 10 Ma, 748 ± 27 Ma, 742 ± 11 Ma, 717 ± 8 Ma and 692 ± 10 Ma suggesting continuous and multiple pulses of magmas emplaced throughout early to mid-Neoproterozoic. Magmatic zircons from the gabbros show weighted mean ²⁰⁶Pb/²³⁸U ages of 903 ± 13 Ma, 777 ± 10 Ma, 729 ± 10 Ma and 639 ± 27 Ma. Metamorphic zircons from all the rock types show latest Neoproterozoic-Cambrian ages in the range of 567 ± 19 Ma to 510 ± 8 Ma suggesting prolonged heating. Zircon Lu–Hf data show that the alkali granite-charnockite-enderbite suite has depleted mantle ages (T_DM) in the range of 1164–2172 Ma and crustal residence ages (T_DM^C) of 1227–3023 Ma. These spots show both negative εHf(t) and positive εHf(t) values (− 22.1 to 10.6), suggesting magma derivation from mixed juvenile mid- to late-Mesoproterozoic components and reworked Mesoarchean to mid-Mesoproterozoic components. Zircon grains from the gabbroic rocks show depleted mantle ages and (T_DM) in the range of 1112–2046 Ma, crustal residence ages (T_DM^C) of 1306–2816 Ma, and both negative and positive εHf(t) values (− 17.8 to 7.9), suggesting that the magmas were dominantly derived from juvenile mid-Mesoproterozoic to Neoproterozoic components as well as reworked Mesoarchean to mid-Mesoproterozoic sources.Our data clearly reveal multiple arc magmatism along the southern Madurai Block during distinct pulses throughout early to late Neoproterozoic, suggesting an active convergent margin along this zone at this time. Crustal thickening occurred through relamination by mafic magmas associated with slab melting. Continental outbuilding and southward growth of the Madurai Block were associated with the lateral accretion of the vast sedimentary belt of Trivandrum Block, culminating in collisional metamorphism during latest Neoproterozoic–Cambrian associated with Gondwana assembly.     

Origin and tectonic setting of the giant Duolong Cu–Au deposit,South Qiangtang Terrane,Tibet: Evidence from geochronology and geochemistry of Early Cretaceous intrusive rocks

We constrain the origin and tectonic setting of the giant Duolong porphyry–epithermal Cu–Au deposit in the South Qiangtang Terrane of northern Tibet, based on new zircon U–Pb ages and Hf isotopic data, as well as whole-rock major and trace element data from poorly studied ore-associated intrusions in the Duolong area. The LA–ICP–MS zircon U–Pb dating indicates that the ore-associated rocks formed between 121 and 126 Ma. These ore-associated rocks are geochemically similar to low-K tholeiitic M-type granitoids and to mid- to high-K, calc-alkaline I-type granitoids. They have variable and predominantly positive zircon ε_Hf(t) values (− 1.4 to + 15.6) and variable crustal model ages (T^C_DM(Hf); 176–1122 Ma). Taking into account previous data and the regional geology of the study area, we propose that the ore-associated rocks originated from fractional crystallization of mantle-derived mafic melts and magma mixing of mantle-derived mafic and hybrid lower crust-derived felsic melts, and the hybrid lower crust included a mix of juvenile and older continental material. The Duolong porphyry–epithermal Cu–Au deposit formed within an ‘ensialic forearc’ of an active continental margin as a result of the northwards subduction of the Bangong–Nujiang Ocean crust beneath the South Qiangtang Terrane.