Sustainable imaginaries and the green roof on Chicago’s City Hall

The concept of an imaginary has a long history of describing a society’s collective understanding of how the world works. This article introduces the concept of the sustainable imaginary as a society’s understanding and vision of how resources are being used and should be used to ensure socio-environmental reproduction. Incorporating John Allen’s modalities of power makes it possible to see exactly how those resources are being used within and outside of city government. This article employs the sustainable imaginary via the example of the green roof on Chicago’s City Hall. This structure exemplifies appropriate relationships within and with city government, the ways in which imaginaries are performed and reiterated, and how local environments interact with global discourses to produce specific discursive and material outcomes.     

Stratigraphy and facies development of the marine Late Devonian near the Boulongour Reservoir,northwest Xinjiang,China

Late Devonian to Early Carboniferous stratigraphic units within the ‘Zhulumute’ Formation, Hongguleleng Formation (stratotype), ‘Hebukehe’ Formation and the Heishantou Formation near the Boulongour Reservoir in northwestern Xinjiang are fossil-rich. The Hongguleleng and ‘Hebukehe’ formations are biostratigraphically well constrained by microfossils from the latest Frasnian linguiformis to mid-Famennian trachytera conodont biozones. The Hongguleleng Formation (96.8 m) is characterized by bioclastic argillaceous limestones and marls (the dominant facies) intercalated with green spiculitic calcareous shales. It yields abundant and highly diverse faunas of bryozoans, brachiopods and crinoids with subordinate solitary rugose corals, ostracods, trilobites, conodonts and other fish teeth. The succeeding ‘Hebukehe’ Formation (95.7 m) consists of siltstones, mudstones, arenites and intervals of bioclastic limestone (e.g. ‘Blastoid Hill’) and cherts with radiolarians. A diverse ichnofauna, phacopid trilobites, echinoderms (crinoids and blastoids) together with brachiopods, ostracods, bryozoans and rare cephalopods have been collected from this interval. Analysis of geochemical data, microfacies and especially the distribution of marine organisms, which are not described in detail here, but used for facies analysis, indicate a deepening of the depositional environment at the Boulongour Reservoir section. Results presented here concern mainly the sedimentological and stratigraphical context of the investigated section. Additionally, one Late Devonian palaeo-oceanic and biotic event, the Upper Kellwasser Event is recognized near the section base.     

Ore minerals down to the nanoscale: Cu-(Fe)-sulphides from the iron oxide copper gold deposit at Olympic Dam,South Australia

Cu-Fe-sulphide mineral assemblages from the Olympic Dam (OD) Fe-oxide Cu-U-Au-Ag deposit, South Australia, are studied down to the nanoscale to explore the potential these minerals have for understanding genetic processes such as primary deposit zonation. Cu-Fe-sulphide pairs: ‘brown’ bornite associated with chalcopyrite (bornite-chalcopyrite zone); and symplectites of ‘purple’ bornite with species from the chalcocite group, Cu_2 − xS (bornite-chalcocite zone), co-define an upwards and inwards deposit-scale zonation at OD. In the bornite-chalcocite zone, there is also an increase in the proportion of chalcocite relative to bornite within the symplectites towards upper levels. In this case, two-phase Cu_2 − xS assemblages are also present, as anisotropic, hexagonal chalcocite (CcH) with lamellar exsolutions of digenite, distinguishable at the μm-scale. Using compositional data (electron microprobe) combined with Transmission Electron Microscopy (TEM) study of foils prepared in–situ via Focused Ion Beam (FIB)-SEM, we show that Cu-Fe-sulphides from different ore zones feature nanoscale intergrowths, lattice defects, superstructure domains (na) and antiphase boundary domains (APBs) that can be interpreted as due to exsolution, coarsening and phase transformation during cooling from high-T solid solutions in the system Cu-Fe-S and sub-systems according to published phase diagrams. ‘Brown’ bornite [(Cu + Fe)/S > 5] contains pervasive lamellae of chalcopyrite which extend down to the nanoscale; such specimens appear homogeneous at the μm-scale. ‘Purple bornite’ [(Cu + Fe)/S < 5] in high-bornite symplectites is associated with chalcocite that shows APBs with 6a digenite and low-T chalcocite. Comparable APBs are also found in the ‘chalcocite’ zone with apparent homogeneity at the μm-scale. Both bornites contain exsolutions of djurleite. Systematic variation of Me/S and Cu/Fe in the two types of bornite points, however, to distinct origins from different bornite solid-solutions in the system Cu-Fe-S. Both show 2a and 4a intermediate superstructures. High-order superstructures (6a and incommensurate na) are restricted to the ‘purple’ bornite whereas the 2a4a low-T superstructure is found in both cases. Me/S ratios in the chalcocite group are variable; lower ratios (down to 1.8; digenite) are more common in chalcocite from symplectites with ‘purple’ bornite. Me/S can be as low as 1.4 where associated with ‘blue’ varieties (‘blaubleibender covellin’) of replacement origin. The two-phase Cu_2 − xS associations contain hexagonal chalcocite (Me/S = 1.95), lamellae of Cu-rich digenite (Me/S = 1.92), and anilite (Cu₇S₄) as nm-scale lamellae. Digenite shows 3a and 6a superstructures and CcH shows transition to pseudo-orthorhombic chalcocite. The presence of superstructures, high-T species and APBs is evidence for Cu-(Fe)-sulphide formation from high-T solid solutions at T > 300 °C (high-T phases, Cu-poor digenite), followed by cooling along distinct paths down to < 120 °C (APBs). The scenario of ‘exsolution from primary solid-solution’, corroborated by the consistency in phase relations within each zone across different scales of observation from deposit scale to nanoscale, backs up a model of primary hypogene ore precipitation rather than replacement, and accounts for the observed vertical zoning at OD. The FIB-TEM approach here is readily applicable to other deposits and shows that nanoscale observations are a valuable, although often overlooked, source of information to constrain ore genesis.     

From ‘criminals of the earth’ to ‘stewards of the environment’: The social and environmental justice of Fair Trade gold

The recent emergence of the Fairtrade certification of gold in Latin America and sub-Saharan Africa promises a radical new direction for the environmental governance of artisanal and small-scale mining (ASM). In doing so, it aims to tackle the longstanding environment and development challenges of the sector which mainstream policy has failed to alleviate. The move towards more responsible ASM practices is premised on the strategic deployment of a Fair Trade discourse that argues for its operators to be recognized not as criminals, but as valued and formalized parts of their broader economies. It is argued in this paper that this development intervention should be read within a social and environmental justice framework, one which directly answers the call from political geography for ‘compelling accounts’ of positive representations of the sector.Through a discourse analysis of 10 years of media reports, interviews and recorded life histories of key ASM and Fair Trade stakeholders in Tanzania, it shows how three strands of justice (conceptualized in terms of fairer distribution, procedure and recognition) are articulated by the Fair Trade gold movement and critically assesses the politics behind such a deliberate strategy. In particular, it argues that recognition is a key part of justice that has been underplayed by erstwhile analyses of Fair Trade. Through a case study of Tanzania, it is concluded that although significant progress has been made in terms of arguing for greater recognition for ASM operators, there remains a need to better link discourse with practice in establishing greater distributional justice.     

Minisauripus―the track of a diminutive dinosaur from the Cretaceous of China and South Korea: implications for stratigraphic correlation and theropod foot morphodynamics

The diminutive (2.5–3.0 cm long), Cretaceous dinosaur track ichnogenus Minisauripus, previously known only from the type ichnospecies, M. chuanzhuensis, from a single locality in Sichuan Province China, is here reported from two new localities in South Korea and one in China. Material from the new Chinese locality is assigned to the new ichnospecies M. zhenshuonani on the basis of its distinctive morphology. Most of the new material is well-preserved, revealing narrow asymmetric tracks with claw traces, long step and phalangeal formula (2-3-4 for digits II, III and IV, respectively), suggesting a theropod track maker rather than an ornithischian, as originally inferred for the Chinese type material.The South Korean samples (eight tracks), from two localities in the Haman Formation, are considered Early Cretaceous (Aptian-Albian) in age, whereas the Chinese type material (21 specimens) has been assigned both an Early and Late Cretaceous age. The former age is probably correct as suggested by a new Minisauripus locality (5 specimens) from the Early Cretaceous (Barremian-Albian) of Shandong Province, China.Other diminutive tracks from the Sichuan fauna include Aquatilavipes sinensis (2.5 cm long, a possible junior synonym of Koreanoris hamanensis), Grallator emeiensis (2 cm long) and Velociraptorichnus sichuanensis (10–11 cm), which occur, in various combinations, with Minisauripus at both the new Korean and Chinese localities.In Minisauripus, digit III is very short in comparison with other theropods and provides a striking contrast to G. emeinsis. This difference has significant implications for standard assumptions about theropod track allometry. Based on the classic Early Jurassic forms Grallator and Eubrontes, it has long been inferred that relative digit III length shrank with increasing size (up to foot lengths of 30–40 cm). The reiteration of reduction in relative length of digit III in specimens in the size range of 2–3 cm indicates that the allometric or morphodynamic ‘program’ that influenced development in large theropod clades reiterated fractally in theropod clades a full order of magnitude smaller. This shows that a given allometry can be size-dependent in one clade and size-independent in another. Thus, the developmental program appears ‘contracted’ or morphologically miniaturized by heterochrony to manifest paedomorphically in some clades and peramorphically in others. This strongly suggests that ‘formal’ developmental ‘programs operated’ along similar morphodynamic lines in quite different clades.     

High-pressure metamorphism in Antarctica from the Proterozoic to the Cenozoic: A review and geodynamic implications

The survey of high-P metamorphic rocks in Antarctica can help clarify the geodynamic evolution of the continent by pointing out palaeo-suture zones and constraining the age of subduction and collision events. There are eclogite-facies rocks along the eastern margin of the ‘Mawson block’ (e.g., in the Nimrod Glacier region and George V Land). Some of these have been long forgotten (George V Land; Eyre Peninsula in Australia). Stillwell (1918) described rocks from George V Land containing glaucophane, lawsonite, garnet coronas and symplectites possibly after omphacite. These high-P rocks were apparently involved in the Nimrod-Kimban orogenic cycle and therefore provide a record of convergence along the eastern margin of the Mawson block at ~ 1700 Ma; they could represent one of the oldest blueschist-facies imprint. Many terranes in East Antarctica underwent a tectonometamorphic evolution during the Grenvillian (1300–900 Ma) and/or the Pan-African (600–500 Ma) orogenies, corresponding to the amalgamation of Rodinia and Gondwana, respectively. High-P relicts have been described or are suspected to occur in these terranes. Garnet-bearing coronitic metagabbros, in some cases possibly containing omphacite, are common in Dronning Maud Land and the Rayner Complex. They formed under high-P granulite-facies or eclogite-facies conditions and recall similar metabasites from the Grenville mobile belt of Canada. Note that some reconstructions of the Rodinia supercontinent consider these two Antarctic regions as an extension of the Grenvillian belt of Canada. Other eclogite-facies metamorphic rocks and ophiolites (Shackleton Range and possibly Sverdrupfjella) belong to the Pan-African mobile belt extending from Tanzania to East Antarctica. Since the Cambrian, the terranes of West Antarctica have been accreted along the palaeo-Pacific margin of Gondwana/Antarctica during several subduction-accretion orogenies. The ultrahigh-P metamorphic rocks of Northern Victoria Land formed through the accretion of an arc-backarc system during the Cambrian-Ordovician Ross orogeny; eclogites of the same orogeny also exist in Tasmania and Australia. Lastly, on the western edge of the Antarctic Peninsula, the Mesozoic–Cenozoic Andean orogeny generated a subduction-accretionary complex containing blueschist-facies rocks.     

Global production networks in the passenger aviation industry

Although the number of directions which geographical research on transport is taking has recently increased, the extent to which transport geography capitalises on theoretical advancements made in other sub-disciplines of human geography is still fairly limited. This especially pertains to economic geography which, in contrast to the predominantly positivist and quantitative transport geography, has developed over the last few decades a more post-positivist and qualitative profile. By means of focusing on passenger air transport – one of the most neglected industries in economic geography – this paper aims to help bridge this gap. Three under-researched aspects of air transport are identified and a combination of two economic-geographical approaches – global production networks (GPN) and evolutionary economic geography (EEG) – is advocated as a useful conceptual basis for further, more qualitative and more critical research on this dynamic sector. The paper argues that GPN and EEG would help research on air transport to: (1) employ network thinking beyond the infrastructural understanding of networks of air connections and thus better explain the multi-actor nature of the aviation sector, (2) complement the research on supra-national and national regulatory frameworks with more attention to the array of sub-national environments that shape the aviation industry ‘from below’, and (3) explore how the relations between aviation and economic development are moulded by different place-specific institutional factors. To lay foundations under further research the paper conceptualises the aviation industry as a global production network and uses the example of Polish passenger air transport to highlight the paper’s key empirical implications.     

Structure et caractérisation des matériaux utilisés dans la construction d'une mosaı̈que romaine de la cité de Volubilis (Maroc)

In Volubilis, Roman mosaics are very beautiful and reveal, from the bottom to the surface, three layers: (i) ‘hedgehog’ layer, (ii) coarse grain mortar layer (rudus + nucleus) and (iii) tesselatum. Mineralogical analysis of coarse grain mortar sampled in Flavius Germanus mosaic shows that it consisted of quartz and calcite, with some feldspar and probably mica and dolomite. Fine-grained mortar in tesselatum is made from a mixture of calcite and quartz only. Limestone tesserae (white, pink and brown) show petrographic facies that change from micritic to oolithic limestone. Conversely, black and brick red tesserae are respectively made of marble, red sandstone and from fire clay. Other colours as yellow, blue, green and grey are obtained from artificial glass with different chemical compositions. To cite this article: A. Dekayir et al., C. R. Geoscience 336 (2004).     

New Precambrian palaeomagnetic constraints on the position of the North China Block in Rodinia

We report new palaeomagnetic results from a ca. 1300 to 800 Ma continental shelf succession on the southern margin of the North China Block. A total of 386 oriented core samples were subjected to stepwise demagnetisation. Two overprint components (‘A’ and ‘B’) were identified, with ‘A’ being a Recent geomagnetic field component and ‘B’ a likely Mesozoic remagnetisation related to collision of the North and South China Blocks. An interpreted primary remanence was isolated from six rock units. The most reliable results are as follow, in the order of stratigraphic ascendance. (1) Purple mudstone, muddy sandstone and andesite of the lower Yunmenshan Formation (Rb–Sr age ca. 1270 Ma) yields a high-temperature component that passes both reversal and fold tests and gives a palaeopole at (60.6°S, 87.0°E, A₉₅ = 3.7°). (2) Mudstone in the overlying Baicaoping Formation yields a high-temperature component with a palaeopole at (43.0°S, 143.8°E, A₉₅ = 11.1°). (3) Purple sandstone of the earliest Neoproterozoic Cuizhuang and Sanjiaotang Formations exhibits a high-temperature component that provides a palaeopole at (41.0°S, 44.8°E, A₉₅ = 11.3°). Based on both our new results and a critical selection of available palaeomagnetic data, we construct a preliminary apparent polar wander path (APWP) for the North China Block between 1300 and 510 Ma. Regardless of alternative polarity options applicable to these poles, North China was located within equatorial latitudes for much of this interval. Comparing the North China poles with coeval poles from Laurentia suggests that the two continents were situated on the same plate between 1200 and 700 Ma. North China was thus likely part of the supercontinent Rodinia. Separation of North China and Laurentia occurred between 650 and 615 Ma.     

Geological variation in S-wave velocity structures in Northern Taiwan and implications for seismic hazards based on ambient noise analysis

Ambient noise analysis in Northern Taiwan revealed obvious lateral variations related to major geological units. The empirical Green’s functions extracted from interstation ambient noise were regarded as Rayleigh waves, from which we analyzed the group velocities for period from 3 to 6 s. According to geological features, we divided Northern Taiwan into seven subregions, for which regionalized group velocities were derived by using the pure-path method. On average, the group velocities in mountain areas were higher than those in the plain areas. We subsequently inverted the S-wave velocity structure for each subregion down to 6 km in depth. Following the analysis, we proposed the first models of geology-dependent shallow S-wave structures in Northern Taiwan. Overall, the velocity increased substantially from west to east; specifically, the mountain areas, composed of metamorphic rocks, exhibited higher velocities than did the coastal plain and basin, which consist of soft sediment. At a shallow depth, the Western Coastal Plain, Taipei Basin, and Ilan Plain displayed a larger velocity gradient than did other regions. At the top 3 km of the model, the average velocity gradient was 0.39 km/s per km for the Western Coastal Plain and 0.15 km/s per km for the Central Range. These S-wave velocity models with large velocity gradients caused the seismic waves to become trapped easily in strata and, thus, the ground motion was amplified. The regionalized S-wave velocity models derived from ambient noises can provide useful information regarding seismic wave propagation and for assessing seismic hazards in Northern Taiwan.     

The Holocene climatic optimum and pollen records of sapropel 1 in the eastern Mediterranean, 9000–6000 BP

The most recent sapropel in the deep eastern Mediterranean Sea has been deposited between 9 and 6 ka bp. Climate conditions, as revealed by the pollen records of this sapropel in marine cores, were most favorable for temperate deciduous trees, which is in agreement with the inferences from records of peripheral land pollen sites. The abundance of deciduous oak pollen is much higher than that of Artemisia (sage-brush), indicating that annual precipitation in the mid-elevation borderlands was at least 550 mm without summer drought, but more probably in the range 800–1300 mm. The pollen of Pistacia, which formed a savanna at low elevations, is also at its highest abundance and signals the absence of frost in winter, while being capable of withstanding summer drought. The early Holocene therefore appears as the post-glacial climatic optimum with the highest moisture and mildest winters. In southwest Asia, this is also the time of the Neolithic population explosion with incipient domestication of cereals, possibly following natural selection of the ‘tough rachis’ mutation in wheat and barley by the extreme aridity of the preceding Younger Dryas.     

Kinetics of Au (III) extraction by DBC from hydrochloric solution using Lewis cell

The kinetics of forward extraction [AuCl₄]^? from aqua regia medium by diethylene glycol dibutyl ether (DBC) have been investigated by the Lewis cell (LC) technique. At first gold extraction has been carried out under different experimental conditions for achieving the stoichiometry coefficients and the value of the extraction equilibrium constant (K = 0.1). For kinetic data treatment, flux ‘F’ method has been applied. Reaction order with respect to DBC, pH and [AuCl₄]^? was determined and then the rate constant was calculated. The rate of gold extraction from 2 M chloride medium can be expressed as F = 10^0.88[AuCl₄^?]^1.25 [DBC]^0.4 [H⁺]^?0.22. Kinetics data were treated by EVIEWS software and coefficients were obtained. The comparison of manual and software results indicated that the results had good conformity. Influence of temperature was studied and then activation energy, E_a, (11.17 kJ/mol), activation enthalpy (11.66 kJ/mol) and entropy (?187 J/mol K) were calculated by using Arrhenius and activation complex theory respectively. E_a value (< 20.9 kJ/mol) indicates that, the extraction of gold (III) in the investigated system is controlled by diffusion process.     

Mineralogy of the lower mantle: A review of ‘super-deep’ mineral inclusions in diamond

Starting from the late 1980s, several groups of lower-mantle mineral inclusions in diamond have been found. Three associations were established among them: juvenile ultramafic, analogous to eclogitic, and carbonatitic. The juvenile ultramafic association strongly predominates, and it is composed of ferropericlase, MgSi-, CaSi- and CaTi-perovskites, stishovite, tetragonal almandine-pyrope phase (TAPP), and some others. The association analogous to the upper-mantle eclogitic association, formed from subducting lithosphere, comprises: majorite, CaSi-perovskite bearing compositional Eu anomalies, phase ‘Egg’ with a tetragonal structure, and stishovite. The carbonatitic association is represented by various carbonates, halides, and associated minerals. Some mineral associations (wüstite + periclase and native iron + iron carbides) are, possibly, related to the D″ layer at the core/mantle boundary. The mineralogical composition of the lower mantle is now understood to be more complex than had been suggested in theoretic and experimental works. The proportion of ferropericlase in the lower mantle is higher than it was suggested before, and its composition is more iron-rich (mg = 0.36–0.90) as compared to experimental and theoretical data. Free silica (stishovite) is always present in lower-mantle associations, and a separate aluminous phase (TAPP) has been identified in several areas. These discrepancies suggest that the composition of the lower mantle differs to that of the upper-mantle, and experiments based solely on ‘pyrolitic’ compositions are not, therefore, applicable to the lower mantle. These data indicate a probability of an alternative to the CI-chondrite model of the Earth's formation, for example, an enstatite-chondrite model.     

Size and shape characteristics of drumlins,derived from a large sample,and associated scaling laws

Ice sheets flowing across a sedimentary bed usually produce a landscape of blister-like landforms streamlined in the direction of the ice flow and with each bump of the order of 10² to 10³ m in length and 10¹ m in relief. Such landforms, known as drumlins, have mystified investigators for over a hundred years. A satisfactory explanation for their formation, and thus an appreciation of their glaciological significance, has remained elusive. A recent advance has been in numerical modelling of the land-forming process. In anticipation of future modelling endeavours, this paper is motivated by the requirement for robust data on drumlin size and shape for model testing.From a systematic programme of drumlin mapping from digital elevation models and satellite images of Britain and Ireland, we used a geographic information system to compile a range of statistics on length L, width W, and elongation ratio E (where E = L/W) for a large sample. Mean L, is found to be 629 m (n = 58,983), mean W is 209 m and mean E is 2.9 (n = 37,043). Most drumlins are between 250 and 1000 metres in length; between 120 and 300 metres in width; and between 1.7 and 4.1 times as long as they are wide. Analysis of such data and plots of drumlin width against length reveals some new insights. All frequency distributions are unimodal from which we infer that the geomorphological label of ‘drumlin’ is fair in that this is a true single population of landforms, rather than an amalgam of different landform types. Drumlin size shows a clear minimum bound of around 100 m (horizontal). Maybe drumlins are generated at many scales and this is the minimum, or this value may be an indication of the fundamental scale of bump generation (‘proto-drumlins’) prior to them growing and elongating. A relationship between drumlin width and length is found (with r² = 0.48) and that is approximately W = 7 L ^1/2 when measured in metres. A surprising and sharply-defined line bounds the data cloud plotted in E–W–L space, and records a scale-dependent maximum elongation limit (approximated by E_max = L^1/3, when L measured in metres). For a given length, for some reason as yet unknown, drumlins do not exceed the elongation ratio defined by this scaling law. We also report and compare our statistics to an amalgamated sample (25,907 drumlins) of measures derived from around 50 published investigations. Any theory must be able to explain the drumlin statistics and fundamental scaling properties reported herein and they thus provide powerful tests for drumlin modelling.     

Remarkably uniform oxygen isotope systematics for co-existing pairs of gem-spinel and calcite in marble,with special reference to Vietnamese deposits

Oxygen isotope systematics for co-existing pairs of gem-spinel and calcite in marble from Vietnam and other worldwide deposits have been determined in order to characterize the O-isotope fractionation between calcite and spinel. In Vietnam, the Δ¹⁸O_cc–sp (= 3.7 ± 0.1‰ for six samples from the An Phu and Cong Troi deposits) is remarkably constant. The combination of these data with those obtained on calcite–spinel pairs of Paigutan (Nepal, n = 2), Ipanko (Tanzania, n = 1), and Mogok (Myanmar, = 2) are also consistent with an overall Δ¹⁸O_cc–sp of 3.6 ± 0.3‰ for all the spinel samples (n = 11). The straight line correlation δ¹⁸O_cc = 0.96 δ¹⁸O_sp + 4.4 is excellent despite their worldwide geographic spread. The increment method of calculating oxygen isotope fractionation gave a geologically unreasonable temperature of formation for both minerals at 1374 °C when compared to temperatures obtained by mineral assemblage equilibrium of these marble type deposits, between 610 and 750 °C. The constant Δ¹⁸O_cc–sp reflects a constant temperature for this amphibolite facies assemblage, whose current best estimate is calculated at 620 ± 40 °C, but unquantified uncertainties remain.     

Le métamorphisme Tardi-Crétacé à Éocène des zones internes de la chaı̂ne Indo-Birmane (Myanmar occidental) : implications géodynamiquesLate Cretaceous to Eocene metamorphism of the internal zone of the Indo-Burma range (western Myanmar): geodynamic implications

Metamorphic study on Triassic schists in the internal zone of the Indo-Burma range, essentially based on chlorite–mica equilibrium in metapelites, allows a P–T path to be quantified. During the prograde metamorphism, the geothermic gradient evolves from that of a ‘normal’ crust (30 °C km^?1) to that of a thickened crust (18 °C km^?1). The peak conditions are around 8 kbar and 450 °C. This thickening (25–30 km) is probably made in a wedge set up between the Late Cretaceous and the Eocene, in front of the obduction. The obtained cold retrograde path requires a mechanism allowing thermal re-equilibration, implying slow exhumation. It occurred along a shear zone that put into contact the micaschists of the core with the Triassic schists of the roof. To cite this article: A. Socquet et al., C. R. Geoscience 334 (2002) 573–580.     

Occurrence and distribution of glycerol dialkanol diethers and glycerol dialkyl glycerol tetraethers in a peat core from SW Tanzania

Isoprenoid and branched glycerol dialkanol diethers (iso GDDs and br GDDs) have recently been detected in various environments, including sediment, soil and peat deposits. Their structures strongly resemble those of glycerol dialkyl glycerol tetraethers (GDGTs). Nevertheless, the origin of GDDs and their link to GDGTs remain unclear. Here we examined the concentration and distribution of iso GDDs and br GDDs, together with those of iso GDGTs and br GDGTs along a 4 m peat core from Tanzania. Whereas br GDDs have only been detected to date in their core lipid (CL) form, we report here, for the first time, br GDDs in both CL and intact polar lipid (IPL) forms, suggesting a biosynthetic origin for br GDDs. Concentrations of br GDGTs and br GDDs on one hand and of iso GDGTs and iso GDDs on the other hand, were observed to significantly co-vary (R² 0.49–0.58; p < 0.05), both for the CL and IPL fractions. Moreover, the fractional abundance of each GDD correlated significantly with that of its GDGT analogue (R² 0.33–0.97; p < 0.05). Taken together, the data show that GDDs and GDGTs are closely related and likely take part in common metabolic pathways, although the hypothesis of GDDs being degradation products of GDGTs cannot be excluded.     

Metasomatic alteration of chromite from parts of the late Archaean Sittampundi Layered Magmatic Complex (SLC), Tamil Nadu,India

Chromite deposits associated with layered anorthosite complexes in the Archaean high-grade terranes are rare in the world. The late Archaean Sittampundi Layered Magmatic Complex, Tamil Nadu, India is one of the few such deposits in the world where layers of Fe-Al rich chromites are associated with extremely calcic (An>95) anorthosite. ‘Frozen in’ magmatic mineralogy of the chromitite and the enclosing anorthosite suggest successive crystallization of chromite + clinopyroxene and chromite + clinopyroxene + anorthite from a hydrous Al-rich basaltic melt that was emplaced in a suprasubduction zone setting. Intense deformation and upper amphibolite facies metamorphism at ∼2.45 Ga converted the magmatic assemblages to hitherto unreported hornblende + gedrite + Mg-Al rich spinel ± chlorite bearing assemblages. During metamorphic reconstitution, chromite was pseudomorphically replaced by green spinel in the domains rich in secondary amphiboles. Mass-balance calculation and algebraic analyses of the observed mineralogy suggest that a number of chemical species including chromium became mobile during the formation of spinel pseudomorph in response to infiltration driven metamorphism. Aluminium became mobile in the length scale of chromite grain but remained immobile in the length scale of a thin section.     

The Niassa Gold Belt,northern Mozambique – A segment of a continental-scale Pan-African gold-bearing structure?

The Niassa Gold Belt, in northernmost Mozambique, is hosted in the Txitonga Group, a Neoproterozoic rift sequence overlying Paleoproterozoic crust of the Congo–Tanzania Craton and deformed during the Pan-African Orogeny. The Txitonga Group is made up of greenschist-facies greywacke and schist and is characterized by bimodal, mainly mafic, magmatism. A zircon U–Pb age for a felsic volcanite dates deposition of the sequence at 714 ± 17 Ma. Gold is mined artisanally from alluvial deposits and primary chalcopyrite-pyrite-bearing quartz veins containing up to 19 ppm Au have been analyzed. In the Cagurué and M’Papa gold fields, dominantly N–S trending quartz veins, hosted in metagabbro and schist, are regarded as tension gashes related to regional strike-slip NE–SW-trending Pan-African shear zones. These gold deposits have been classified as mesozonal and metamorphic in origin. Re–Os isotopic data on sulfides suggest two periods of gold deposition for the Cagurué Gold Field. A coarse-crystalline pyrite–chalcopyrite assemblage yields an imprecise Pan-African age of 483 ± 72 Ma, dating deposition of the quartz veins. Remobilization of early-formed sulfides, particularly chalcopyrite, took place at 112 ± 14 Ma, during Lower Cretaceous Gondwana dispersal. The ～483 Ma assemblage yields a chondritic initial ¹⁸⁷Os/¹⁸⁸Os ratio of 0.123 ± 0.058. This implies a juvenile source for the ore fluids, possibly involving the hosting Neoproterozoic metagabbro. The Niassa Gold Belt is situated at the eastern end of a SW–NE trending continental-scale lineament defined by the Mwembeshi Shear Zone and the southern end of a NW–SE trending lineament defined by the Rukwa Shear Zone. We offer a review of gold deposits in Zambia and Tanzania associated with these polyphase lineaments and speculate on their interrelation.     

Solubility of Fe2(OH)3Cl (pure-iron end-member of hibbingite) in NaCl and Na2SO4 brines

Pure-iron end-member hibbingite, Fe₂(OH)₃Cl(s), may be important to geological repositories in salt formations, as it may be a dominant corrosion product of steel waste canisters in an anoxic environment in Na–Cl- and Na–Mg–Cl-dominated brines. In this study, the solubility of Fe₂(OH)₃Cl(s), the pure-iron end-member of hibbingite (Fe^II, Mg)₂(OH)₃Cl(s), and Fe(OH)₂(s) in 0.04 m to 6 m NaCl brines has been determined. For the reactionFe₂(OH)₃Cl(s) + 3H⁺ ? 3 H₂O + 2 Fe²⁺ + Cl^?,the solubility constant of Fe₂(OH)₃Cl(s) at infinite dilution and 25 °C has been found to be log₁₀ K = 17.12 ± 0.15 (95% confidence interval using F statistics for 36 data points and 3 parameters). For the reactionFe(OH)₂(s) + 2H⁺ ? 2 H₂O + Fe²⁺,the solubility constant of Fe(OH)₂ at infinite dilution and 25 °C has been found to be log₁₀ K = 12.95 ± 0.13 (95 % confidence interval using F statistics for 36 data points and 3 parameters). For the combined set of solubility data for Fe₂(OH)₃Cl(s) and Fe(OH)₂(s), the Na⁺–Fe²⁺ pair Pitzer interaction parameter θ_{Na⁺/Fe²⁺} has been found to be 0.08 ± 0.03 (95% confidence interval using F statistics for 36 data points and 3 parameters). In nearly saturated NaCl brine we observed evidence for the conversion of Fe(OH)₂(s) to Fe₂(OH)₃Cl(s). Additionally, when Fe₂(OH)₃Cl(s) was added to sodium sulfate brines, the formation of green rust(II) sulfate was observed, along with the generation of hydrogen gas. The results presented here provide insight into understanding and modeling the geochemistry and performance assessment of nuclear waste repositories in salt formations.