Geodynamic setting and geochemical signatures of Cambrian–Ordovician rift-related igneous rocks (Ossa-Morena Zone, SW Iberia)

An important rifting event, accompanied by massive igneous activity, is recorded in the Ossa-Morena Zone of the SW Iberian Massif (European Variscan Orogen). It likely culminated in the formation of a new oceanic basin (Rheic ocean?), remnants of which appear presently accreted at the southern margin of the Ossa-Morena Zone. Rifting propagated diachronously across the zone from the Early Cambrian to the Late Ordovician, but by Early Ordovician time, the existence of a significant tract of new ocean is evidenced by a breakup unconformity. Although early stages of rifting were not accompanied by mantle-derived igneous activity, a pronounced increase of the geothermal gradient is indicated by partial melting of metasedimentary protoliths in the upper and middle crust, and by coeval core-complex formation. Geochemistry of the main volume of igneous rocks, emplaced some million years later during more mature stages of rifting, suggests an origin in a variably enriched asthenospheric source, similar to that of many OIB, from which subsequent petrogenetic processes produced a wide range of compositions, from basalt to rhyolite. A tectonic model involving collision with, and subsequent overriding of, a MOR is proposed to account for the overall evolution, a present-day analogue for which lies in the overriding of the East Pacific Rise by North America and the rifting of Baja California.     

Thessaloniki–Gerakarou Fault Zone (TGFZ): the western extension of the 1978 Thessaloniki earthquake fault (Northern Greece) and seismic hazard assessment

Active faulting and seismic properties are re-investigated in the eastern precinct of the city of Thessaloniki (Northern Greece), which was seriously affected by two large earthquakes during the 20th century and severe damage was done by the 1759 event. It is suggested that the earthquake fault associated with the occurrence of the latest destructive 1978 Thessaloniki earthquake continues westwards to the 20-km-long Thessaloniki–Gerakarou Fault Zone (TGFZ), which extends from the Gerakarou village to the city of Thessaloniki. This fault zone exhibits a constant dip to the N and is characterised by a complicated geometry comprised of inherited 100°-trending faults that form multi-level branching (tree-like fault geometry) along with NNE- to NE-trending faults. The TGFZ is compatible with the contemporary regional N–S extensional stress field that tends to modify the pre-existing NW–SE tectonic fabric prevailing in the mountainous region of Thessaloniki. Both the 1978 earthquake fault and TGFZ belong to a ca. 65-km-long E–W-trending rupture fault system that runs through the southern part of the Mygdonia graben from the Strymonikos gulf to Thessaloniki. This fault system, here called Thessaloniki–Rentina Fault System (TRFS), consists of two 17–20-km-long left-stepping 100°-trending main fault strands that form underlapping steps bridged by 8–10-km-long ENE–WSW faults. The occurrence of large (M6.0) historical earthquakes (in 620, 677 and 700 A.D.) demonstrates repeated activation, and therefore the possible reactivation of the westernmost segment, the TGFZ, could be a major threat to the city of Thessaloniki. Changes in the Coulomb failure function (ΔCFF) due to the occurrence of the 1978 earthquake calculated out in this paper indicate that the TGFZ has been brought closer to failure, a convincing argument for future seismic hazard along the TGFZ.     

Active faults, seismicity and stresses in an internal boundary of a tectonic arc (Campo de Dalías and Níjar, southeastern Betic Cordilleras, Spain)

The Betic-Rif Cordilleras, formed by the interaction of NW–SE convergence between the Eurasian and African plates and the westward motion of their Internal Zones, provide a good example of an active tectonic arc. The Campo de Dalías and Campo de Níjar constitute outcropping sectors of Neogene and Quaternary rocks located in the southeastern border of the Betic Cordilleras and allow us to study the recent deformations developed in the internal border of this tectonic arc.The main active faults with related seismicity, representing a moderate seismic hazard, associated to the southeastern Betic Cordilleras boundary, include high-angle NW–SE-oriented normal faults that affect, at least, the upper part of the crust, a main detachment located at 10 km depth, and probably another detachment at 20 km as well. Seismite structures, recent fault scarps with associated colluvial wedges that deform the drainage network and the alignment of the coastline, indicate that the high-angle faults have been active at least since the Quaternary.Paleostresses determined from microfault analysis in Quaternary deposits generally show an ENE–WSW trend of extension. Present-day earthquake focal mechanisms include normal, strike-slip and reverse faulting. Normal and strike-slip focal mechanisms generally indicate ENE–WSW extension, and strike-slip and reverse focal mechanisms are related to NNW–SSE compression.The maximum horizontal compression has a consistently NNW–SSE trend. The deep activity of detachments and reverse faults determines the NNW–SSE crustal shortening related to the Eurasian–African plate convergence. At surface, however, the predominance of normal faults is probably produced by the increase in the relative weight of the vertical stress axis, which in turn may be related to relief uplift and subsequent horizontal spreading. The internal mountain front boundary of the Betic Cordilleras developed through the activity of a set of structures that is more complex than a typical external mountain front, probably as a consequence of a vertical variable stress field that acted on previously deformed rocks belonging to the Internal Zone of the cordilleras.     

Evidence of multi-stage faulting by clay mineral analysis: Example in a normal fault zone affecting arkosic sandstones (Annot sandstones)

Fault affecting silicoclastic sediments are commonly enriched in clay minerals. Clays are sensitive to fluid–rock interactions and deformation mechanisms; in this paper, they are used as proxy for fault activity and behavior. The present study focuses on clay mineral assemblages from the Point Vert normal fault zone located in the Annot sandstones, a Priabonian-Rupelian turbidite succession of the Alpine foredeep in SE France. In this area, the Annot sandstones were buried around 6–8 km below the front of Alpine nappes soon after their deposition and exhumed during the middle-late Miocene. The fault affects arkosic sandstone beds alternating with pelitic layers, and displays throw of about thirty meters. The fault core zone comprises intensely foliated sandstones bounding a corridor of gouge about 20 cm thick. The foliated sandstones display clay concentration along S–C structures characterized by dissolution of K-feldspar and their replacement by mica, associated with quartz pressure solution, intense microfracturation and quartz vein precipitation. The gouge is formed by a clayey matrix containing fragments of foliated sandstones and pelites. However, a detailed petrographical investigation suggests complex polyphase deformation processes. Optical and SEM observations show that the clay minerals fraction of all studied rocks (pelites and sandstones from the damage and core zones of the fault) is dominated by white micas and chlorite. These minerals have two different origins: detrital and newly-formed. Detrital micas are identified by their larger shape and their chemical composition with a lower Fe–Mg content than the newly-formed white micas. In the foliated sandstones, newly-formed white micas are concentrated along S–C structures or replace K-feldspar. Both types of newly formed micas display the same chemical composition confirmed microstructural observations suggesting that they formed in the same conditions. They have the following structural formulas: Na_0.05 K_0.86 (Al _1.77 Fe_0.08 Mg_0.15) (Si_3.22 Al_0.78) O₁₀ (OH)_2. They are enriched in Fe and Mg compared to the detrital micas. Newly-formed chlorites are associated with micas along the shear planes. According to microprobe analyses, they present the following structural formula: (Al_1,48 Fe_2,50 Mg_1,84) (Si_2,82 Al_1,18) O₁₀ (OH)₈. All these data suggest that these clay minerals are synkinematic and registered the fault activity. In the gouge samples, illite and chlorite are the major clay minerals; smectite is locally present in some samples.In the foliated sandstones, Kubler Index (KI) ((001) XRD peak width at half height) data and thermodynamic calculations from synkinematic chlorite chemistry suggest that the main fault deformation occurred under temperatures around 220 °C (diagenesis to anchizone boundary). KI measured on pelites and sandstones from the hanging and footwall, display similar values coherent with the maximal burial temperature of the Annot sandstones in this area. The gouge samples have a higher KI index, which could be explained by a reactivation of the fault at lower temperatures during the exhumation of the Annot sandstones formation.     

The Yenice–Gönen active fault (NW Turkey): Active tectonics and palaeoseismology

The Yenice–Gönen Fault (YGF) is one of the most important active tectonic structures in the Biga peninsula. On March 18, 1953, a destructive earthquake (M_w = 7.2) occurred on the YGF, which is considered to be a part of the southern branch of the North Anatolian Fault Zone (NAFZ). A 70 km-long dextral surface rupture formed during the Yenice–Gönen Earthquake (YGE).In this study, structural and palaeoseismological features of the YGF have been investigated. The YGF surface ruptures have been mapped and three trenches were excavated at Muratlar, Karaköy and Seyvan sites.According to the palaeoseismic interpretation and the results of ¹⁴C AMS dating, Seyvan trench shows that an earthquake of palaeoseismic age ca. 620 AD ruptured a different strand of the 1953 fault, producing rather significant surface rupture displacement, while there are indications that at least two older events occurred during the past millennia. Another set of trenches excavated near Gönen town (Muratlar village) revealed extensive liquefaction not only during the 1953 event, but also during a previous earthquake, dated at 1440 AD. The Karaköy trench shows no indications of recent reactivations.Based on the trenching results, we estimate a recurrence interval of 660 ± 160 years for large morphogenic earthquakes, creating linear surface ruptures. The maximum reported displacement during the 1953 earthquake was 4.2 m. Taking into account the palaeoseismologically determined earthquake recurrence interval and maximum displacement, slip-rate of the YGF has been calculated to be 6.3 mm/a, which is consistent with present-day velocities determined by GPS measurements. According to the geological investigations, cumulative displacement of the YGF is 2.3 km. This palaeoseismological study contributes to model the behaviour of large seismogenic faults in the Biga Peninsula.     

Normal faulting along the western side of the Matese Mountains: Implications for active tectonics in the Central Apennines (Italy)

We provide new field data from geologic mapping and bedrock structural geology along the western side of the Matese Mts in central Italy, a region of high seismicity, strain rates among the highest of the entire Apennines (4–5 mm/yr GPS-determined extension), and poorly constrained active faults. The existing knowledge on the Aquae Iuliae normal fault (AIF) was implemented with geometric and kinematic data that better constrain its total length (16.5 km), the minimum long-term throw rate (0.3–0.4 mm/yr, post-late glacial maximum, LGM), and the segmentation. For the first time, we provide evidence of post-350 ka and possibly late Quaternary activity of the Ailano – Piedimonte Matese normal fault (APMF). The APMF is 18 km long. It is composed of a main 11 km-long segment striking NW–SE and progressively bending to the E–W in its southern part, and a 7 km-long segment striking E–W to ENE-WSW with very poor evidence of recent activity. The available data suggest a possible post-LGM throw rate of the main segment of ≳0.15 mm/yr. There is no evidence of active linkage in the step-over zone between the AIF and APMF (Prata Sannita step-over).An original tectonic model is proposed by comparing structural and geodetic data. The AIF and APMF belong to two major, nearly parallel fault systems. One system runs at the core of the Matese Mts and is formed by the AIF and the faults of the Gallo-Letino-Matese Lake system. The other system runs along the western side of the Matese Mts and is formed by the APMF, linked to the SE with the Piedimonte Matese – Gioia Sannitica fault. The finite extension of the APMF might be transferred to the NW towards the San Pietro Infine fault. The nearly 2–3 mm/yr GPS-determined extension rate is probably partitioned between the two systems, with a ratio that is difficult to establish due to poor GPS coverage. The proposed model, though incomplete (several faults/transfer zones need further investigations), aids in the seismotectonic interpretation of poorly-known earthquakes (e.g., 346/355 AD earthquake on the Ailano – Piedimonte Matese – Gioia Sannitica fault system), and stimulates and further orients seismotectonic investigations aimed at constraining the segmentation pattern and seismogenic potential of the area.     

Evidence of diverse depletion and metasomatic events in harzburgite–lherzolite mantle xenoliths from the Iberian plate (Olot, NE Spain): Implications for lithosphere accretionary processes

Mantle xenoliths from the Olot volcanic district (NE Spain) comprise a bi-modal suite consisting of protogranular spinel lherzolites (cpx 12–14%) sometimes with pargasitic amphibole, and highly refractory spinel harzburgites (cpx ≤ 1%) with coarse-grained granular textures. The lherzolites range from slightly depleted to moderately LREE-enriched with flat HREE patterns between 1.5 and 2.7 × chondrite (Ch). In contrast, the harzburgites are extremely depleted in HREE (down to 0.2 × Ch) and strongly LREE-enriched (La_N/Yb_N = 12.3–17.2). LA-ICP-MS analyses of clinopyroxene and amphibole of the lherzolites highlight variable degrees of LREE depletion (HREE up to 13 × Ch, La_N/Yb_N down to 0.01), with the exception of a single sample in which both clinopyroxene and amphibole are LREE-enriched (La_N/Yb_N up to 19). In the harzburgites, clinopyroxenes display totally different REE distributions, characterized by extreme HREE depletion (down to 0.4 × Ch) and upward convex positively fractionated middle-light REE patterns (Nd_N/Yb_N up to 20.7 × Ch; La_N/Yb_N up to 12 × Ch). Sr–Nd–Hf isotopic data for both whole-rocks and cpx separates, coherently indicate depleted mantle (DM) compositions for the lherzolites (εSr = − 15 to − 26, εNd = + 9 to + 17, εHf = + 18 to + 68) and enriched mantle (EM) compositions for the harzburgites (εSr = − 10 to + 36, εNd = − 1 to − 6, εHf = + 3 to + 8). Modelling of the clinopyroxene REE data and isotopic systematics suggest that some lherzolites were affected by pre-Paleozoic (0.6–1 By) low-degree partial melting processes, while others probably reflect some extent of refertilization of the mantle protolith by metasomatizing melts similar to the Triassic rift-related tholeiites reported from several Pyrenean localities. The harzburgites represent extreme refractory residua, resulting from a complex depletion history due to multistage melt extraction as often observed in the cratonic mantle. The distinctive REE patterns and isotopic systematics of their clinopyroxenes suggest that the harzburgites were formed by the interaction of an ultra-depleted peridotite matrix with highly alkaline basic melts similar in composition to the Permo-Triassic alkaline lamprophyres which are widespread within the Iberian plate. Lherzolites possibly represent younger lithosphere (accreted asthenosphere?) up-lifted and juxtaposed to the older subcontinental lithospheric mantle (harzburgites) during the post-Variscan rifting of the Iberian margin. These two genetically different, but adjoining, mantle domains intimately mingled along the northern Iberian margin during the subsequent plate convergence processes, leading to the close association of harzburgites and lherzolites observed in the Olot mantle xenoliths and in some Pyrenean peridotite massifs.     

The Baza Fault: a major active extensional fault in the central Betic Cordillera (south Spain)

In the Guadix-Baza Basin (Betic Cordillera) lies the Baza Fault, a structure that will be described for the first time in this paper. Eight gravity profiles and a seismic reflection profile, coupled with surface studies, indicate the existence of a NE-dipping normal fault with a variable strike with N-S and NW-SE segments. This 37-km long fault divides the basin into two sectors: Guadix to the West and Baza to the East. Since the Late Miocene, the activity of this fault has created a half-graben in its hanging wall. The seismic reflection profile shows that the fill of this 2,000–3,000 m thick asymmetric basin is syntectonic. The fault has associated seismicity, the most important of which is the 1531 Baza earthquake. Since the Late Tortonian to the present, i.e. over approximately the last 8 million years, extension rates obtained vary between 0.12 and 0.33 mm/year for the Baza Fault, being one of the major active normal faults to accommodate the current ENE–WSW extension produced in the central Betic Cordillera. The existence of this fault and other normal faults in the central Betic Cordillera enhanced the extension in the upper crust from the Late Miocene to the present in this regional compressive setting.     

The presence, characteristics and earthquake implications of the St. Lawrence fault zone within and near Lake Ontario (Canada–USA)

Questions persist concerning the earthquake potential of the populous and industrial Lake Ontario (Canada–USA) area. Pertinent to those questions is whether the major fault zone that extends along the St. Lawrence River valley, herein named the St. Lawrence fault zone, continues upstream along the St. Lawrence River valley at least as far as Lake Ontario or terminates near Cornwall (Ontario, Canada)–Massena (NY, USA). New geological studies uncovered paleotectonic bedrock faults that are parallel to, and lie within, the projection of that northeast-oriented fault zone between Cornwall and northeastern Lake Ontario, suggesting that the fault zone continues into Lake Ontario. The aforementioned bedrock faults range from meters to tens of kilometers in length and display kinematically incompatible displacements, implying that the fault zone was periodically reactivated in the study area. Beneath Lake Ontario the Hamilton–Presqu'ile fault lines up with the St. Lawrence fault zone and projects to the southwest where it coincides with the Dundas Valley (Ontario, Canada). The Dundas Valley extends landward from beneath the western end of the lake and is marked by a vertical stratigraphic displacement across its width. The alignment of the Hamilton–Presqu'ile fault with the St. Lawrence fault zone strongly suggests that the latter crosses the entire length of Lake Ontario and continues along the Dundas Valley.The Rochester Basin, an east–northeast-trending linear trough in the southeastern corner of Lake Ontario, lies along the southern part of the St. Lawrence fault zone. Submarine dives in May 1997 revealed inclined layers of glaciolacustrine clay along two different scarps within the basin. The inclined layers strike parallel to the long dimension of the basin, and dip about 20° to the north–northwest suggesting that they are the result of rigid-body rotation consequent upon post-glacial faulting. Those post-glacial faults are growth faults as demonstrated by the consistently greater thickness, unit-by-unit, of unconsolidated sediments on the downthrown (northwest) side of the faults relative to their counterparts on the upthrown (southeast) side. Underneath the western part of Lake Ontario is a monoclinal warp that displaces the glacial and post-glacial sediments, and the underlying bedrock–sediment interface. Because of the post-glacial growth faults and the monoclinal warp the St. Lawrence fault zone is inferred to be tectonically active beneath Lake Ontario. Furthermore, within the lake it crosses at least five major faults and fault zones and coexists with other neotectonic structures. Those attributes, combined with the large earthquakes associated with the St. Lawrence fault zone well to the northeast of Lake Ontario, suggest that the seismic risk in the area surrounding and including Lake Ontario is likely much greater than previously believed.     

Deformation features within an active normal fault zone in carbonate rocks: The Gubbio fault (Central Apennines, Italy)

The Gubbio fault is an active normal fault defined by an important morphological scarp and normal fault focal mechanism solutions. This fault truncates the inherited Miocene Gubbio anticline and juxtaposes Mesozoic limestones in the footwall against Quaternary lacustrine deposits in the hanging wall. The offset is more than 2000 m of geological throw accumulated during a poly-phased history, as suggested by previous works, and has generated a complex zone of carbonate-rich fault-related structures. We report the results of a multidisciplinary study that integrates detailed outcrop and petrographic analysis of two well-exposed areas along the Gubbio fault zone, geochemical analysis (fluid inclusions, stable isotopes, and trace elements) of calcite-sealed fault-related structures and fault rocks, and biostratigraphic controls. Our aims are: (i) the characterization of the deformation features and their spatial–temporal relationships, and (ii) the determination of the P/T conditions and the fluid behaviour during deformation to achieve a better understanding of fluid–rock interaction in fault zones.We show that few of the observed structures can be attributed to an inherited shortening phase while the most abundant structures and fault rocks are related to extensional tectonics. The outcropping extensional patterns formed at depths less than 2.5–3 km, in a confined fluid system isolated from meteoric water, and the fault structures are the response to a small amount of cumulated displacement, 12–19% of the total geological throw.     

Active faulting in the western Pyrénées (France): Paleoseismic evidence for late Holocene ruptures

We have identified a 50-km-long active fault scarp, called herewith the Lourdes Fault, between the city of Lourdes and Arette village in the French Pyrénées. This region was affected by large and moderate earthquakes in 1660 (Io = VIII–IX, MSK 64,), in 1750 (Io = VIII, MSK 64) and in 1967 (M_d = 5.3, Io = VIII, MSK 64). Most earthquakes in this area are shallow and the few available focal mechanism solutions do not indicate a consistent pattern of active deformation. Field investigations in active tectonics indicate an East–West trending and up to 50-m-high fault scarp, in average, made of 3 contiguous linear fault sub-segments. To the north, the fault controls Quaternary basins and shows uplifted and tilted alluvial terraces. Deviated and abandoned stream channels of the southern block are likely due to the successive uplift of the northern block of the fault. Paleoseismic investigations coupled with geomorphic studies, georadar prospecting and trenching along the fault scarp illustrate the cumulative fault movements during the late Holocene. Trenches exhibit shear contacts with flexural slip faulting and thrust ruptures showing deformed alluvial units in buried channels. ¹⁴C dating of alluvial and colluvial units indicates a consistent age bracket from two different trenches and shows that the most recent fault movements occurred between 4221 BC and 2918 BC. Fault parameters and paleoseismic results imply that the Lourdes Fault and related sub-segments may produce a M_W 6.5 to 7.1 earthquake. Fault parameters imply that the Lourdes Fault segment corresponds to a major seismic source in the western Pyrénées that may generate earthquakes possibly larger than the 1660 historical event.     

Neotectonic structures in the area offshore of Alaçatı, Doğanbey and Kuşadası (western Turkey): evidence of strike-slip faulting in the Aegean extensional province

About 400 km of new seismic reflection data has been acquired in the study region offshore of Alaçatı, Doğanbey, and Kuşadası, which enables investigation of the active crustal deformation in this region. The deformation onshore in western Turkey is dominated by crustal extension, and clear evidence of this process is also now available from this offshore area. However, in the onshore area adjacent to this study region evidence of active right-lateral strike-slip faulting has also previously been observed. This strike-slip faulting has previously been thought only to accommodate variations in extension between adjacent normal faults. However, in the offshore area there is considerable evidence of zones of deformation, some of which may link to the strike-slip faulting onshore, suggesting that strike-slip faulting may be of greater importance in this region than previously thought.     

The Gibraltar Arc seismogenic zone (part 1): Constraints on a shallow east dipping fault plane source for the 1755 Lisbon earthquake provided by seismic data, gravity and thermal modeling

The Great Lisbon earthquake of 1755 with an estimated magnitude of 8.5–9.0 is the most destructive earthquake in European history, yet the source region remains enigmatic. Recent geophysical data provide compelling evidence for an active east dipping subduction zone beneath the nearby Gibraltar Arc. Marine seismic data in the Gulf of Cadiz image active thrust faults in an accretionary wedge, above an east dipping decollement and an eastward dipping basement. Tomographic and other data support subduction and rollback of a narrow slab of oceanic lithosphere beneath the westward advancing Gibraltar block.Although, no instrumentally recorded seismicity has been documented for the subduction interface, we propose the hypothesis that this shallow east dipping fault plane is locked and capable of generating great earthquakes (like the Nankai or Cascadia seismogenic zones). We further propose this east dipping fault plane to be a candidate source for the Great Lisbon earthquake of 1755. In this paper we use all available geophysical data on the deep structure of the Gulf of Cadiz–Gibraltar region for the purpose of constraining the 3-D geometry of this potentially seismogenic fault plane. To this end, we use new depth processed seismic data, have interpreted all available published and unpublished time sections, examine the distribution of hypocenters and perform 2-D gravity modeling. Finally, a finite-element model of the forearc thermal structure is constructed to determine the temperature distribution along the fault interface and thus the thermally predicted updip and downdip limits of the seismogenic zone.     

Ductile normal faulting along the West Bohemian Shear Zone (Moldanubian/Tepla-Barrandian boundary): Evidence for late Variscan extensional collapse in the Variscan Internides

Structural and kinematic investigations of the West Bohemian Shear Zone (WBS) clearly indicate late Variscan orogen-parallel (WSW-ENE) extension within the Variscan internides. Along the WBS the western part of the Tepla-Barrandian (TB) was downthrown to the east against the adjacent Moldanubian. According to seismic data, the steeply east-dipping WBS flattens with depth, forming a prominent detachment zone. The western part of the TB was tilted along this zone, producing the patterns of metamorphic isograds, the age of which is probably Cadomian. Cross-cutting relationships of WBS mylonites and Carboniferous granites, as well as the overall cooling ages of hornblende and mica, suggest that ductile normal faulting along the WBS was active from about 330 to 310 Ma.Geothermobarometric data, derived from WBS mylonites, prove that during the extensional movements relatively cold crust of the TB (medium pressure greenschist facies) was juxtaposed to relatively hot Moldanubian crust (low pressure amphibolite facies). Thus mylonites which originate from TB rocks show a first-stage prograde development reaching the lower amphibolite facies under medium pressure conditions. This stage was followed by further (uplift-related) retrograde shearing under low pressure greenschist facies conditions.Extensional movements and the emplacement of granitoids along the WBS, as well as the strong low pressure/high temperature metamorphism of the Moldanubian rocks are remarkably similar in age (Middle Carboniferous). Therefore, a close relationship and mutual dependence of all these features is suggested. Rapid advective thinning of the deeper part of the previously thickened lithosphere and associated rapid crustal uplift are the most probable processes to explain the high Middle Carboniferous heat flow as well as magmatism and extension.     

Trace element geochemistry of primary mantle minerals in spinel‐peridotites from polygenetic MOR–SSZ suites of SW Turkey: constraints from an LA‐ICP‐MS study and implications for mantle metasomatism

Ophiolites exposed across the western Tauride Belt in SW Turkey represent tectonically emplaced fragments of oceanic lithosphere incorporated into continental margin following the closure of the Neotethys Ocean during the Late Cretaceous. The mantle sections of the ophiolites contain peridotites with diverse suites of geochemical signatures indicative of residual origin by melt depletion in both mid‐ocean ridge (MOR) and supra‐subduction zone (SSZ) settings. This study uses a laser‐ablation inductively‐coupled plasma‐mass spectrometry (LA‐ICP‐MS) for in situ measurements of trace elements in primary mantle phases in order to identify the upper mantle petrogenetic processes effective during variable stage of melt extraction in these discrete tectonic settings and to discriminate between the effects of reaction with chemically distinct mantle melts migrating through the solid residues. Trace element signatures in pyroxenes suggest small‐length scales of compositional variations which may be interpreted to be a result of post‐melting petrogenetic processes. Relative distribution of rare earth elements and Li between coexisting orthopyroxene‐clinopyroxene pairs in the peridotites suggests compositional disequilibrium in sub‐solidus conditions, which possibly reflects differential effects of diffusive exchange during melting and melt transport or interaction with subduction melts/fluids. On the basis of Ga abundances and Ga–Ti–Fe⁺³# [Fe⁺³/(Fe⁺³ + Cr + Al)] relationships of chrome‐spinels it is documented that the peridotites have experienced the combined effects of partial melting and variable extent of melt‐solid interaction. The MOR peridotites have spinels with geochemical signatures indicative of melt‐depleted residual origin with subsequent incompatible element enrichment through melt impregnation, while the Ga–Ti–Fe⁺³# relationships of chrome‐spinels in SSZ peridotites indicate that these highly depleted peridotites are not simple melt residues, but have been subject to significant compositional modification by interaction with subduction related melts/fluids. The observed compositional variations, which are related to long‐term tectonic reorganisation of oceanic lithosphere, provide evidence for a time integrated evolution from a mid‐ocean ridge to a supra‐subduction zone setting and may be a possible analogue to explain the coexistence of geochemically diverse MOR–SSZ suites in other Tethyan ophiolites. Copyright © 2011 John Wiley & Sons, Ltd.     

Mineralization events in the Xiaokele porphyry Cu (–Mo) deposit,NE China: Evidence from zircon U–Pb and K‐feldspar Ar–Ar geochronology and petrochemistry

The Great Xing'an Range (GXR), Northeast (NE) China, is a major polymetallic metallogenic belt in the eastern segment of the Central Asian Orogenic Belt. The newly discovered Xiaokele porphyry Cu (–Mo) deposit lies in the northern GXR. Field geological and geochronological studies have revealed two mineralization events in this deposit: early porphyry‐type Cu (–Mo) mineralization, and later vein‐type Cu mineralization. Previous geochronological studies yielded an age of ca. 147 Ma for the early Cu (–Mo) mineralization. Our ⁴⁰Ar/³⁹Ar dating yielded ⁴⁰Ar/³⁹Ar plateau ages of 124.8 ± 0.4 to 124.3 ± 0.4 Ma on K‐feldspar in altered Cu‐mineralized diorite porphyrite dikes that represent the overprinting vein‐type Cu mineralization, consistent with zircon U–Pb ages of the diorite porphyrite (126.4 ± 0.5 to 125.0 ± 0.5 Ma). The Cr and Ni contents and Mg^# of the Xiaokele diorite porphyrites are high. The diorite porphyrites at Xiaokele are enriched in light rare‐earth elements (REEs), and large‐ion lithophile elements (e.g., Rb, Ba, and K), are depleted in heavy REEs and high‐field‐strength elements (e.g., Nb, Ta, and Ti), and have weak negative ε_Hf(t) values (+0.29 to +5.27) with two‐stage model ages (T_DM2) of 1,164–845 Ma. Given the regional tectonic setting in Early Cretaceous, the ore‐bearing diorite porphyrites were likely formed in an extensional environment related to lithospheric delamination and asthenospheric upwelling induced by subduction of the Paleo‐Pacific Plate. These tectonic events caused large‐scale magmatic activity, ore mineralization, and lithospheric thinning in NE China.     

The heat transfer in the region of the Mauna Kea (Hawaii)—constraints from borehole temperature measurements and coupled thermo-hydraulic modeling

The objectives of this paper are an understanding of the thermal and hydraulic field because of a negative temperature gradient and cold temperatures in the 1-km-deep borehole of the Hawaiian Scientific Drilling Project (HSDP), located near the coast line. The temperature pattern is attributed to a superposition of thermal and hydraulic processes. In the deeper borehole (HSDP-2, depth 3.1 km) detailed temperature monitoring was performed. Temperature measurements reveal two different thermal regimes. The upper part is characterised by cold temperatures and a negative temperature gradient similar to those observed in the shallow pilot borehole. Below 1100 m, increasing temperatures are observed. Different processes, such as topographically driven groundwater flow, ingress of salt water and conductive heat flow are investigated by numerical modeling. A pure conductive scenario fails to match the temperature measurements, implying that both borehole sections are overprinted by advective conditions. Coupled fluid and heat flow modeling with solute transport yield results that agree with observed temperatures. The results of these simulations suggest that meteoric water flow from the mountain range controls the thermal conditions in the upper part of the borehole. Below this level, the thermal regime is additionally affected by circulation of salt water from the nearby ocean. Each of these flow systems has been observed at other locations: topographically driven fresh water at locations with pronounced topography and ingress of salt water is typical for islands or coastal areas. At Hawaii, they coincide and influence each other, resulting in a salt water interface occurring at greater depth than expected.     

Geochronology and Genesis of the Tiegelongnan Porphyry Cu(Au) Deposit in Tibet: Evidence from U–Pb,Re–Os Dating and Hf,S, and H–O Isotopes

The Tiegelongnan Cu (Au) deposit is the largest copper deposit newly discovered in the Bangong–Nujiang metallogenic belt. The deposit has a clear alteration zoning consisting of, from core to margin, potassic to propylitic, superimposed by phyllic and advanced argillic alteration. The shallow part of the deposit consists of a high sulphidation‐state overprint, mainly comprising disseminated pyrite and Cu–S minerals such as bornite, covellite, digenite, and enargite. At depth porphyry‐type mineralization mainly comprises disseminated chalcopyrite, bornite, pyrite, and a minor vein molybdenite. Mineralization is disseminated and associated with veins contained within the porphyry intrusions and their surrounding rocks. The zircon U–Pb ages of the mineralized diorite porphyry and granodiorite porphyry are 123.1 ± 1.7 Ma (2σ) and 121.5 ± 1.5 Ma (2σ), respectively. The molybdenite Re–Os age is 121.2 ± 1.2 Ma, suggesting that mineralization was closely associated with magmatism. Andesite lava (zircon U–Pb age of 111.7 ± 1.6 Ma, 2σ) overlies the ore‐bodies and is the product of post‐mineralization volcanic activity that played a critical role in preserving the ore‐bodies. Values of ?4.6 ‰ to + 0.8 ‰ δ³⁴S for the metal sulfides (mean ? 1.55 ‰) suggest that S mainly has a deep magmatic source. The H and O isotopic composition is (δD = ?87 ‰ to ?64 ‰; δ¹⁸O_H2O = 5.5 ‰ to 9.0 ‰), indicating that the ore‐forming fluids are mostly magmatic‐hydrothermal, possibly mixed with a small amount of meteoric water. The zircon ε_Hf(t) of the diorite porphyry is 3.7 to 8.3, and the granodiorite porphyry is 1.8 to 7.5. Molybdenite has a high Re from 382.2 × 10^?6 to 1600 × 10^?6. Re and Hf isotope composition show that Tiegelongnan has some mantle source, maybe the juvenile lower crust from crust–mantle mixed source. Metallogenesis of the Tiegelongnan giant porphyry system was associated with intermediate to acidic magma in the Early Cretaceous (~120 Ma). The magma provenance of the Tiegelongnan deposit has some mantle‐derived composition, possibly mixed with the crust‐derived materials.     

High-grade metamorphism and hydrous melting of metapelites in the Pinos terrane (W Cuba): Evidence for crustal thickening and extension in the northern Caribbean collisional belt

The Pinos terrane (Isle of Pines, W Cuba) is a coherent metamorphic complex that probably represents a portion of the continental margin of the Yucatan Block during the Mesozoic. Within the framework of other metamorphic terranes in the Greater Antilles, the Pinos terrane is characterized by the occurrence of high‐grade kyanite‐, sillimanite‐ and andalusite‐bearing metapelites and migmatites. Assessment and modelling of phase relations in these high grade rocks indicate that they reached a peak temperature of c. 750 °C at 11–12 kbar, and then underwent strong decompression to c. 3 kbar at c. 600 °C. Decompression was contemporaneous with the main synmetamorphic deformation in the area (D2), and was accompanied by segregation of trondhjemitic partial melts formed by wet melting of metapelites. Metamorphism terminated in the Uppermost Cretaceous (68 ± 2 Ma; ⁴⁰Ar/³⁹Ar dates on biotite and muscovite). The P–T–t‐deformation relations of the high‐grade rocks suggest that crustal thickening (during collision of this portion of the Yucatan margin with the Great Volcanic Arc of the Caribbean?) was followed by decompression interpreted to reflect exhumation by extension, possibly related to the initial development of the Yucatan Basin in the uppermost Cretaceous.