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1.
羌塘比隆错新近纪火山岩主要岩石类型为安粗岩-粗面岩,为一套中基性-中性的碱性系列岩石组合,SiO2含量介于52%~62%之间,Al2O3>15%,Na2O/K2O>1,MgO<3.30%.岩石轻稀土元素较强富集,LREE/HREE=10~13,(La/Yb)N=15~19,弱负Eu异常,δEu=0.71~0.89.Mg#与SiO2的相关关系和La/Sm-La、Cr-Tb等亲岩浆元素与超亲岩浆元素协变关系表明,该套岩石为共源岩浆分离结晶的产物.岩石组合类型和低的Sm/Yb值(3.23~3.97)表明,它们应来源于岩石圈地幔尖晶石二辉橄榄岩的局部熔融;弱的负Eu异常和Nb、Ta、Ti的相对亏损,又反映了陆源岩浆的特征,可见,比隆错新近纪碱性火山岩应为青藏高原特殊的壳幔过渡带局部熔融的产物.  相似文献   

2.
羌塘比隆错新近纪火山岩主要岩石类型为安粗岩—粗面岩,为一套中基性—中性的碱性系列岩石组合,SiO2含量介于52%~62%之间,Al2O3>15%,Na2O/K2O>1,MgO<3.30%。岩石轻稀土元素较强富集,LREE/HREE=10~13,(La/Yb)N=15~19,弱负Eu异常,δEu=0.71~0.89。Mg#与SiO2的相关关系和La/Sm-La、Cr-Tb等亲岩浆元素与超亲岩浆元素协变关系表明,该套岩石为共源岩浆分离结晶的产物。岩石组合类型和低的Sm/Yb值(3.23~3.97)表明,它们应来源于岩石圈地幔尖晶石二辉橄榄岩的局部熔融;弱的负Eu异常和Nb、Ta、Ti的相对亏损,又反映了陆源岩浆的特征,可见,比隆错新近纪碱性火山岩应为青藏高原特殊的壳幔过渡带局部熔融的产物。  相似文献   

3.
藏北羌塘火车头山新生代火山岩可区分为钙碱性及碱性两个不同的系列。钙碱性火山岩主要岩石组合为玄武岩-安山岩-英安岩,其SiO_2介于49%~70%之间,Al_2O_3>10%,Na_2O/K_2O>1;其中玄武岩具平坦型稀土配分型式,LREE/HREE为1.3~1.8,(La/Yb)_N为2.87~4.45,无明显铕异常,δEu为0.96~1.09;该套岩石的Mg~#与SiO_2相关关系以及La/sm-La等亲岩浆元素与超亲岩浆元素协变关系表明,它们应为幔源岩浆经分离结晶演化的产物,其岩石组合类型以及低的Sm/Yb值(Sm/Yb=1.53~5.35)表明它们的原始岩浆应来源于岩石圈地幔尖晶石二辉橄榄岩的局部熔融。本区碱性火山岩为一套典型的钾质岩石系列,主要岩石组合类型为碱玄岩-碱玄质响岩-响岩,其SiO_2介于44%~59%之间,Al_2O_3>14%,Na_2O/K_2O介于0.47~1.51之间;岩石轻稀土强烈富集,LREE/HREE为13.20~15.76,(La/Yb)_N=50.44~91.99;其岩石组合类型以及Mg~#与SiO_2相关关系以及La/Sm-La协变关系同样表明它们为共源岩浆分离结晶演化的产物;然而,其较高的Sm/Yb值(Sm/ Yb=2.63~13.98)表明它们并非地幔橄榄岩直接局部熔融的产物,岩石弱的负Eu异常(δEu=0.77~0.85)以及Th、U的强烈富集和Nb、Ta的相对亏损,又反映了原始岩浆中有显著的地壳物质的贡献;该套钾质碱性系列岩石在La/Co-Th/Co同分母协变图上呈直线型分布,而在La/Co-Sc/Th异分母协变图上呈显著的双曲线分布,从而表明其源区为二源混合型,是青藏高原特殊的壳幔混合层局部熔融的产物,这些特征是新生代青藏高原壳幔层圈物质交换的重要岩石学证据。  相似文献   

4.
金灿海 《地质与勘探》2010,46(6):1061-1070
沙窝滩、洪玉泉地区火山岩产于北羌塘若拉岗日冲断带及其南侧,呈熔岩被产出。火山活动发生在新近纪,K-Ar及40Ar/39Ar年龄为2.5~8.76Ma,为晚中新世~晚上新世。岩石组合主要为粗面岩、粗安岩,少量安山质凝灰熔岩。岩石SiO2含量为58.34~68.05%,里特曼组合指数(σ)为2.85~3.72,赖特碱度率(AR)为2.21~2.97,Na2O+K2O含量为7.36~8.45%,K2O/Na2O值为1.1~1.51,为高钾碱性、钙碱性火山岩。大离子亲石元素K、Rb、Sr、Ba强富集,高场强元素Ta、Nb负异常明显,Th、La、Zr主要呈正异常,轻重稀土比值为17.54~34.16,属轻稀土富集型,无负Eu异常,或负Eu异常不明显,过渡族金属元素Cr、Ni含量低。上述特征表明,北羌塘沙窝滩、洪玉泉地区新近纪火山岩产于陆内造山后构造环境,火山岩岩浆主要来源于下地壳部分熔融。  相似文献   

5.
大兴安岭北段龙江盆地中生代火山岩主要为一套中酸性岩石,岩石化学成分显示其主要为英安岩与流纹岩,少量安山岩.各类岩石的LA-ICP-MS锆石U-Pb定年结果显示,其形成于122.2~126.5Ma之间的早白垩世.火山岩为高钾钙碱性系列岩石,稀土元素总量较高(∑REE=103.22×10-6~249.29×10-6),轻重稀土元素分馏明显((La/Yb)N=6.29~25.89),负Eu异常(Eu/Eu* =0.48~0.84).富集大离子亲石元素Rb、Ba、Th、U、K和LREE,亏损高场强元素Nb、Ta、P、Ti;火山岩稀土元素与微量元素标准化配分曲线与地壳配分曲线近乎一致,为一套壳源岩浆系列火山岩;大部分岩石300<Sr<700;Yb平均为2.24,Y平均为18.36,符合埃这克岩型岩石标准;岩石Y/Yb平均为9.15,(Ho/Yb)N=0.98,而弱负Eu异常(平均值δEu=0.71).地球化学特征说明,岩浆主要是增厚(高压)基性麻粒岩下地壳部分熔融的结果.结合区域上同期火山岩的资料,龙江盆地中生代火山岩可能是蒙古-鄂霍茨克洋闭合碰撞造山构造背景下加厚下地壳部分熔融的产物.  相似文献   

6.
北京西山东狼沟组钾质火山岩成因及其动力学机制   总被引:7,自引:1,他引:6  
北京西山东狼沟组火山岩为钾质系列岩石(K2O=3.40%~4.70%,K20/Na20>1),由玄武质粗安岩和粗安岩组成.它们表现出LREE富集[(La/Yb)N=31.4~44.6]和HREE弱分馏[(Dy/Yb)N=1.64~2.01]的REE分布模式,Eu表现出弱的负异常(Eu/Eu*=0.81~0.86),富集Ba、K、LREE和相对亏损Nb-Ta、Th-U.较高的Sr[(87Sr/86Sr)i=0.705 7~0.705 9]和低Nd[δNd(t)=-14.7~-12.4],类似于辽西义县组和华北陆内同时代的EM I型基性火成岩.其Th-U相对Ba、La的强烈亏损,暗示早期可能有华北古老的下地壳再循环进入源区.结合区域构造研究,东狼沟组火山岩可能为陆内伸展拉张环境下早期交代富集的岩石圈地幔部分熔融作用的产物,并在岩浆演化过程中经历了橄榄石 辉石 斜长石的分离结晶作用.  相似文献   

7.
八达岭花岗杂岩的组成、地球化学特征及其意义   总被引:23,自引:21,他引:23  
王焰  张旗 《岩石学报》2001,17(4):533-540
北京地区八达岭花岗杂岩是燕山期岩浆侵入活动的典型代表,按照地球化学特征及成因,本文将其分为3类第1类由辉长-闪长岩组成,富Fe、Ti和P,Th/Ta比值近似等于1(0.7~1.2),ISr和εNd(t)值低(分别为0.705和-8~-11),产于板内环境,推测是大陆岩石圈地幔部分熔融形成的,可能代表了燕山期时底侵到加厚陆壳底部的玄武质岩浆.第2类为八达岭花岗杂岩的主体,由石英闪长岩-花岗闪长岩-二长花岗岩组成,其地球化学特征为SiO2>57%,K2O>2.7%,Na2O/K2O=0.9~1.7,Al2O3在16%~14%之间,LREE富集,(La/Yb)N=25~41,HREE亏损(Yb<1.32μg/g),无或有弱的负铕异常(Eu/Eu*=1.0~0.9),富Sr(354~1191μg/g),贫Y(<16μg/g),Sr/Y比值高(45~156).上述地球化学特征除了K2O含量偏高和Al2O s含量偏低外,大体类似于埃达克质岩石的性质,表明岩浆的源区很深,与石榴石处于平衡,暗示其来源于燕山期华北加厚的陆壳底部,可能是下地壳中基性麻粒岩部分熔融形成的.第3类由碱长花岗岩和石英二长岩组成,Na2O+K2O>9%,贫Sr、Ba,富Rb,LREE富集,有明显的负铕异常(Eu/Eu*=0.4~0.5),属于A型花岗岩,是由于第2类埃达克质岩石形成之后,引起了岩石圈拆沉,造成地幔上涌至减薄陆壳的底部,引起壳幔过渡带物质部分熔融的结果.该区燕山期岩浆活动与古太平洋板块的消减作用无关,是板内伸展事件的产物.  相似文献   

8.
康明  岳长成  刘孝峰  陈宇  高超  原烨 《岩石学报》2017,33(6):1686-1704
内蒙古渣尔泰地区处于华北地台西北部,其分布的中生代火山岩划分为两大类,形成于两个喷发旋回。早白垩世早期喷发旋回以中基性火山岩为主,沿近东西向的深大断裂呈北东东向裂隙式喷发;晚期喷发旋回以酸性火山岩为主,沿近南北向断裂带呈裂隙-中心式喷发。中基性火山岩主要为橄榄玄武粗安岩和安粗岩,其SiO_2介于49.65%~56.64%;酸性火山岩包括次火山岩、火山碎屑岩、火山熔岩,其Si O2介于73.18%~83.82%;两者组成典型的宽双峰火山岩。中基性火山岩富碱(Na_2O+K_2O=6.70%~7.47%)、高Ti(TiO_2=2.29%~3.55%)、Fe,相对贫Ca、Mg,富含大离子亲石元素(LILE)(Rb、Ba),轻稀土相对富集,轻、重稀土元素分馏明显,LREE/HREE=4.50~6.47,(La/Yb)N=4.17~8.85,具微弱的负Eu异常(δEu=0.67~0.96),具有与洋岛玄武岩(OIB)相似的地球化学特征,其岩浆来源于交代富集的软流圈地幔,岩浆上升过程中地壳组分混染较少。酸性火山岩富Si、高K,贫Ca、Mg、Fe、Ti,富含大离子亲石元素(LILE)(Rb、Th、U)和高场强元素(HFSE)(Nb、Ta、Zr、Hf),富集轻稀土,LREE/HREE=2.91~14.3,轻、重稀土分馏明显,(La/Yb)N=2.53~28.4,(La/Sm)N=1.16~4.57,(Gd/Yb)N=1.22~5.04,负Eu异常明显(δEu=0.02~0.25),具有A型流纹岩的特征,为幔源岩浆底侵,使上覆的先存地壳岩石发生部分熔融的产物。结合区域地质背景,认为研究区双峰式火山岩形成于西伯利亚板块与华北板块碰撞造山期后陆内拉张的构造环境。  相似文献   

9.
通过对出露于西藏南部岗巴—定日地区花岗岩体的地球化学研究表明,岩石中SiO2,Al2O3,Na2O和FeO,MgO等的含量均高,贫CaO和Fe2O3;w(SiO2)介于71.40%~73.06%,A/CNK在1.17~1.34之间,为铝和硅过饱和类型的强过铝质花岗岩。岩石的稀土元素总量(ΣREE)为56.80×10-6~89.12×10-6,(La/Yb)N=6.30~18.26,(La/Sm)N=2.62~3.40,ΣLREE/ΣHREE=2.41~4.66;稀土元素配分曲线呈右倾型,具有弱的负铕异常。Nb,Ti等高场强元素具有明显的亏损,而Rb,U,La,Nd,Hf,Eu,Y等大离子亲石元素具有明显的正异常。岩石的87Sr/86Sr初始比值较高,87Sr/86Sr为(0.738 71~0.751 12)。综合研究认为,本区花岗岩的成因为陆壳部分熔融作用形成的,属陆壳改造型强过铝质花岗岩。本区花岗岩岩浆源区岩石成分主要为砂屑岩,其次为泥质岩,是上地壳部分熔融作用的结果。岩石的微量元素标准化曲线图、岩石地R1-R2图解、Rb-(Yb+Ta)和Rb-(Nb+Yb)图解均显示本区岩体形成于同碰撞构造环境的花岗岩,具有同碰撞岩浆活动的特征,是喜马拉雅早期印度板块与冈底斯板块的俯冲碰撞导致的地壳增厚,上地壳部分熔融的产物;为形成于同碰撞构造环境的花岗岩。  相似文献   

10.
对位于北羌塘盆地结扎乡一带二叠系尕笛考组火山岩进行岩石学、岩石化学、微量元素的分析及研究,为恢复二叠纪北羌塘盆地性质与古构造环境提供岩石地球化学约束.主要岩石类型为玄武岩、安山岩、英安岩及少量流纹岩、火山角砾岩等,SiO2=48.49%~74,52.,平均60.87%,Al2O3多数在14.5~18.86之间.K20含量平均为1.99.显示钙碱性系列特征.LREE/HREE=4.31~14.60,平均8.74,(La/Yb)n=3.72~16.16.平均9.59,具有LREE富集的特征.δEu=0.61~1.11,平均0.80,多数样品δEu<1.0,表明铕呈弱负异常或不显异常.火山岩La×Nb/Zr×Zr>0.005,平均0.025,Th×Ta/Hf×Hf>0.098.平均为0.210,与典型的岛弧火山岩具相似性.由上述特征表明,北羌塘地块在早中二叠世处于岛弧环境的构造背景.  相似文献   

11.
Police, politics, and the right to the city   总被引:1,自引:0,他引:1  
Mustafa Dikeç 《GeoJournal》2002,58(2-3):91-98
Space and spatiality have recently been at the core of debates concerning the political possibilities of the city. The arguments advanced in this paper might be seen as an attempt to contribute to these debates through a reflection on the spatiality of (in) justice, politics, and the right to the city. The case of French urban policy, with its focus on distressed urban areas, and the `suburban problem' in France are used as examples to make arguments more concrete.  相似文献   

12.
This paper reports the first results of a study of 11 isotope systems (3He/4He, 40Ar/36Ar, 34S/32S, 65Cu/63Cu, 62Ni/60Ni, 87Sr/86Sr, 143Nd/144Nd, 206–208Pb/204Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others.  相似文献   

13.
Transport and transformation of nitrate was evaluated along a 1-km groundwater transect from an almond orchard to the Merced River, California, USA, within an irrigated agricultural setting. As indicated by measurements of pore-water nitrate and modeling using the root zone water quality model, about 63% of the applied nitrogen was transported through a 6.5-m unsaturated zone. Transport times from recharge locations to the edge of a riparian zone ranged from approximately 6 months to greater than 100 years. This allowed for partial denitrification in horizons having mildly reducing conditions, and essentially no denitrification in horizons with oxidizing conditions. Transport times across a 50–100-m-wide riparian zone of less than a year to over 6 years and more strongly reducing conditions resulted in greater rates of denitrification. Isotopic measurements and concentrations of excess N2 in water were indicative of denitrification with the highest rates below the Merced River. Discharge of water and nitrate into the river was dependent on gradients driven by irrigation or river stage. The results suggest that the assimilative capacity for nitrate of the groundwater system, and particularly the riverbed, is limiting the nitrate load to the Merced River in the study area.  相似文献   

14.
马元铅锌矿床是近年扬子陆块北缘铅锌找矿的新突破。矿体呈层状、似层状产于碑坝隆起翼部震旦系灯影组角砾状白云岩层间构造带中,围岩蚀变很弱。矿石中硫化物以闪锌矿、方铅矿为主,中粗粒晶质结构,充填于白云岩角砾间。闪锌矿富集Cd、Ge、Ag,贫In、Tl、Se,Ga/In为6~132,Ge/In多1000,成矿温度以中-低温为主。金属硫化物ε~(34)S值相对集中,为12.9‰~19.4‰,平均为17.4‰,来自于海相硫酸盐的还原。铅同位素组成稳定,~(206)Pb/~(204)Pb为17.858~17.918:~(207)Pb/~(204)Pb为15.603~15.694;~(208)Pb/~(204)Pb为37.756~38.046,具有造山带和上地壳铅的特征,震旦系可能提供了金属成矿物质。闪锌矿中流体包裹体的~3He/~4He为0.03Ra~1.05Ra,~(40)Ar/~(36)Ar为326.1~765.1,~(38)Ar/~(36)Ar为0.183~0.204,表明成矿流体主要为地壳流体和饱和大气水(大气降水或海水)的混合。闪锌矿内流体包裹体挥发分δ~(13)C_(CH_4)值为-36.01‰~-28.80‰,δ~(13)C_(C_2H_6)值为-27.72‰~-22.44‰,δ~(13)C_(CO_2)值为-23.24‰~-9.68‰,表明有机流体参与了成矿作用。石英、方解石的H-O同位素结果表明具有海水和有机水混合的特征。可见,成矿流体具有两种流体混合的特征,一为蒸发海水与围岩反应所形成的盆地卤水,二为有机流体。推测矿区可能存在一个古油气藏,由于TSR生成一高硫气藏,为区内还原性有机流体的主要来源。当富含Pb、Zn等成矿物质的成矿流体运移至富含CH_4和H_2S的还原性流体的矿区角砾岩带时,两种流体混合,Pb、Zn等遇到H_2S发生反应而沉淀成矿,并伴生热液白云石等,形成了马元铅锌矿床。综上所述,我们认为马元矿床属MVT型铅锌矿床。  相似文献   

15.
16.
Clay subfractions (SFs) of <0.1, 0.1–0.2, 0.2–0.3, 0.3–0.6, 0.6–2 and 2–5 μm separated from Middle Riphean shales of the Debengda Formation are studied using the TEM, XRD, K-Ar and Rb-Sr isotopic methods. The oxygen and hydrogen isotope compositions in the SFs are studied as well. The low-temperature illite-smectite is dominant mineral in all the SFs except for the coarsest ones. The XRD, chemical and isotopic data imply that two generations of authigenic illite-smectite different in age are mixed in the SFs. The illite crystallinity index decreases in parallel with size diminishing of clay particles. As compared to coarser SFs, illite of fine-grained subfractions is enriched in Al relative to Fe and Mg, contains more K, and reveals higher K/Rb and Rb/Sr ratios. The Rb-Sr age calculated by means of the leachochron (“inner isochron”) method declines gradually from 1254-1272 Ma in the coarsest SFs to 1038-1044 Ma in finest ones, while the K-Ar age decreases simultaneously from 1225–1240 to 1080 Ma. The established positive correlation of δ18O and δD values with dimensions of clay particles in the SFs seems to be also consistent with the mixing systematics. The isotopic systematics along with data on mineral composition and morphology lead to the conclusion that mixedlayer illite-smectite was formed in the Debengda shales during two periods 1211–1272 and 1038–1080 Ma ago. The first period is likely close to the deposition time of sediments and corresponds to events of burial catagenesis, whereas the second one is correlative with the regional uplift and changes in hydrological regime during the pre-Khaipakh break in sedimentation.  相似文献   

17.
岑巩县羊桥乡罗家塘杷榔组仅出露中-上部地层,岩性单一,均为青灰、灰绿色粉砂质泥、页岩.在其上部层位发现了俞氏贵州始海百合(Guizhoueocrinus yui Zhao,Parsley et Peng,2007),计有棘皮动物始海百合、腕足动物、软体动物-软舌螺、节肢动物-三叶虫等8属9种,包括了2个未定名的新种和1...  相似文献   

18.
Over the past decade researchers working on the rocks of the Beaufort Group in the main Karoo Basin of South Africa have vastly increased our understanding of this important Permo-Triassic sequence. Many new fossil forms have been discovered, allowing for breakthroughs into the biodiversity, biogeography and biostratigraphy of the group. Taxonomic and phylogenetic advances are many and varied, and cover most of the vertebrate taxa, but with emphasis placed on the temnospondyl amphibians, archosauriforms and non-mammalian synapsids, in particular the anomodontia. Biostratigraphic breakthroughs have centered on the Middle Permian Eodicynodon and Tapinocephalus assemblage zones, the Late Permian Dicynodon Assemblage Zone, and the Triassic Lystrosaurus and Cynognathus assemblage zones. Correlation of these biozones with better dated sequences in Europe, Russia and China has allowed for many chronostratigraphic refinements, which are in turn vital for sequence stratigraphical analysis of the basin fill. Based on fossil data, both the lower (Ecca–Beaufort) and upper (Beaufort–Molteno) contacts of the group have been proved to be highly diachronous. The refined chronostratigraphic framework has also allowed for a better analysis of the basin evolution through time, particularly in terms of the correlation of external stimuli that affect basin sedimentation patterns.  相似文献   

19.
The Trinity River (Texas, USA) contains in its watershed 23 different reservoir lakes, the largest one being Lake Livingston situated in the lower Trinity River watershed and two potentially polluting metroplexes, Dallas and Houston. In order to determine fluxes of nutrients and trace metals to Galveston Bay, a survey that included 24 discreet samples collected over a year and at various stages of discharge was carried out during 2000–2001. Geochemical (i.e., sorption by Fe oxyhydroxides), biological (i.e., seasonal uptake by sinking algae in Lake Livingston), and hydrological (i.e., dilution effects by increasing flow rates) controls were found to be mainly responsible for variations in dissolved trace metal concentrations rather than pollution sources. The Trinity River loads of suspended sediments and pollutant trace metals entering Galveston Bay at Anahuac were <20% of those reaching Lake Livingston, and only a few percent of the total upstream trace metal load is entering the Gulf of Mexico. Thus, during the transit through the 23 man-made lakes and an estuary, >96% of the pollutant trace metal load is lost to sediments.  相似文献   

20.
填海工程使滨海地区的地下水物理化学条件改变,导致该区域地下水中重金属浓度升高。本文以深港西部通道填海区为例,采用实验室模拟填海条件的办法,初步探讨了影响填海区地下水重金属迁移的关键因素。模拟实验结果表明,填海区地下水中钨元素含量升高与地下水淡化、淤泥氧化过程以及填料风化有关;铜元素含量升高则与淤泥氧化过程以及填料风化有关;钒元素含量升高与地下水淡化和淤泥氧化过程有关,而其他元素含量升高则主要与填料风化释放有关。  相似文献   

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