塔里木盆地西部白垩纪—古近纪海相地层框架及对重大地质事件的记录

塔里木盆地西部白垩纪—古近纪发生了大规模的海侵事件,形成一个喇叭状向西开口的海湾,该海湾属于东特提斯洋的一个分支。该地区白垩纪—古近纪海相地层记录了东特提斯洋演化和一系列重大地质事件,具有重要的研究价值,但对其地层的研究仍相对薄弱,对重大地质事件的研究还不够深入。本文拟通过详细的岩石地层、生物地层和其他地层方法,完善地层划分与对比框架,并在此基础上讨论Cenomanian/ Turonian界线大洋缺氧事件(OAE2)、白垩纪/古近纪界线(K/Pg)、古新世—始新世极热事件(PETM)、特提斯海进与海退等一系列重大地质事件。塔里木盆地白垩纪—古近纪海相或海陆过渡相地层自下而上为克孜勒苏群、库克拜组、乌依塔克组、依格孜牙组、吐依洛克组、阿尔塔什组、齐姆根组、盖吉塔格组、卡拉塔尔组、乌拉根组和巴什布拉克组,上述地层中含有丰富的有孔虫、介形虫、钙质超微、沟鞭藻、孢粉、双壳类、腹足类等化石,以及少量菊石、腕足类、海胆和鲨鱼牙齿等化石。综合的生物地层和年代地层研究表明,克孜勒苏群的时代为早白垩世Barremian-Albian期,库克拜组—依格孜牙组的时代为晚白垩世Cenomanian-Maastrichtian期(Cenomanian/Turonian界线可能位于库克拜组三段),吐依洛克组的时代为白垩纪—古近纪过渡期;阿尔塔什组的时代为古新世早中期,齐姆根组为古新世晚期—始新世最早期,盖吉塔格组—乌拉根组的时代为中始新世中晚期,巴什布拉克组的时代为晚始新世,但不排除最上部进入渐新世早期。塔里木盆地的海侵开始于克孜勒苏群中上部沉积期(Albian晚期—Aptian早期),但规模很有限,大规模的海侵始于晚白垩世Cenomanian早期;从晚白垩世—古新世,共经历了5次大规模的海侵—海退事件;大约41 Ma前后,海水退出盆地南部的昆仑山山前,34 Ma前后,海水退出盆地北部的天山山前。上述海侵—海退事件可能受构造和全球海平面变化的双重影响,但构造事件对海侵的启动和结束可能更具决定性的影响。阐述了塔里木盆地西部白垩纪—古近纪海相地层所记录的OAE2、K/Pg界线、PETM和特提斯海侵—海退等事件,其中笔者及团队第一次在塔里木盆地西部齐姆根组中所发现和报道的PETM事件,将有助于揭示全球近岸地区PETM的特征和生物-环境响应。在未来的研究中,需要进一步厘清塔里木盆地西部地层序列,建立更加精细的生物地层和年代地层框架,加强对PETM和特提斯海侵—海退等重大地质事件的研究。     

Integrated stratigraphy and palaeoenvironment of the P/E boundary interval, Rakhi Nala section, Indus Basin (Pakistan)

Marine sedimentary section across the Paleocene/Eocene (P/E) boundary interval is preserved in the Dungan Formation (Lower Indus Basin), Pakistan. Four dinoflagellate zones in the P/E interval of the Rakhi Nala section (Lower Indus Basin) are identified and correlated. The quantitative analysis of the dinoflagellate cyst assemblages together with geochemical data are used to reconstruct the palaeoenvironment across the P/E interval. The dinocyst assemblages allow the local correlation of the Dungan Formation (part) of the Sulaiman Range with the Patala Formation (part) of the Upper Indus Basin and global correlation of the Zone Pak-DV with the Apectodinium acme Zone of the Northern and Southern hemispheres. The onset of the carbon isotopic excursion (CIE) associated with Paleocene Eocene Thermal Maximum (PETM) is used globally to identify the P/E boundary. The CIE for the total organic carbon (fine fraction) δ¹³C_FF is of a magnitude of ?1.7‰ is recorded for the first time in the Indus Basin. The Apectodinium acme precedes and straddles the onset of the CIE in the Indus Basin. This Apectodinium acme is also accompanied by a planktonic and benthonic foraminifera “barren zone.” The CIE in the Indus Basin, coupled with the changes in the dinocyst distribution and the benthonic and planktonic foraminifera assemblages, provides evidence of the changes associated with the PETM in this little-known part of the world. The benthonic foraminiferal assemblage indicates bathyal environment of deposition at the time of P/E boundary interval; the presence of dominantly open marine dinoflagellates and high planktonic foraminiferal ratio suggest that the water column at this site was well connected with the rest of the Tethys.     

Carbon isotope and REE characteristics of the Paleocene–Eocene shallow marine Subathu formation from the NW Himalaya (India) and their paleo-environmental implications

Carbon isotope (δ¹³C) and rare earth element (REE) concentrations in representative samples of the shallow marine Subathu Formation, explored from the Neelkanth and Dogadda sections of Northwestern Himalaya (India) were determined to infer the palaeo-environmental condition during the late Paleocene and middle Eocene. δ¹³C values show variation of ～5.0‰ with maximum excursion (?27.34‰) in calcareous sandstone at the basal part and minimum (?22‰) in red shale towards the terminal end. Total REE concentration varies (due to lithology) from 27.23?ppm to 564.35?ppm with an average of 187.60?ppm. The chondrite and PAAS normalized patterns exhibit positive Ce anomaly (0.95–4.45), enriched LREE, and depleted HREE, medium Y/Ho ratio (～30–45) along with positive correlation between Y/Dy and Y/Ho ratio. In addition, calcite veins present in some shale samples indicate redox sensitive trace elements. The overall REE abundance and distribution suggests highly oxygenated environment under the shallow marine regressive phase of deposition. The depositional setting, biostratigraphical constrained age along with δ¹³C values and lower TOC suggested an intense warm period, that might be coeval with the Paleocene-Eocene Thermal Maxima event (PETM).     

Carbon and oxygen isotopic constraints on paleoclimate and paleoelevation of the southwestern Qaidam basin,northern Tibetan Plateau

We investigate the growth of the northern Tibetan Plateau and associated climate change by applying oxygen and carbon isotopic compositions in Cenozoic strata in the southwestern Qaidam basin. The X-ray diffraction and isotopic studies reveal that the carbonate minerals are mainly authigenic and they do not preserve any evidence for detrital carbonate and diagenesis. The isotope data show large fluctuations in the δ¹⁸O and δ¹³C values in the middle–late Eocene, indicating relatively warm and seasonal dry climate. The positive correlation of the δ¹⁸O and δ¹³C values in the Oligocene and the positive shift of the δ¹³C values from the Eocene to Oligocene suggest that the climate changed to arid in the Oligocene. However, the δ¹⁸O values show negative shift, which is closely related to the global cooling event. During the Miocene, the δ¹³C values vary between –2‰ and –4‰, whereas the δ¹⁸O values show continuous negative shift. The mean δ¹⁸O values decrease from –8.5‰ in the early Miocene to –10.0‰ in the late Miocene. The stable isotope-based paleoaltimetry results suggest that the elevation of the southwestern Qaidam basin was approximately 1500 m in the middle–late Eocene and Oligocene. Subsequently, during Miocene the crustal uplift process started and the elevation reached approximately 2000 m in the early Miocene and 2500 m in the late Miocene, which suggests large-scale growth of the northern Tibet Plateau during the Miocene.     

塔里木盆地古近系层序地层研究

运用露头、钻井岩心及测井层序地层学的有关理论方法,对塔里木盆地周边露头及盆地内钻井剖面的古近系进行了详细的沉积学和层序地层学研究,共识别出6个三级层序界面,把塔里木盆地古近系划分为5个三级层序。其中,古新世-始新世早期（库姆格列木群沉积期）发育3个层序,从下到上为S1,S2和S3。S1大致相当于库姆格列木群底部的砾岩段、膏泥岩段到白云岩段,在塔西南地区相当于土依洛克组。S2和S3大致相当于库车坳陷库姆格列木群上部两套膏盐岩段以及塔西南坳陷阿尔塔什组-齐姆根组及卡拉塔尔组-乌拉根组的两套膏盐岩段。始新世晚期-渐新世（苏维依组沉积期）发育1~2个三级层序,即S4和S5。S4相当于库车坳陷的苏维依组和塔西南坳陷巴什布拉克组的主体,S5仅在部分钻井中见到,以苏维依组顶部局部发育的扇三角洲相砂砾岩为代表。在这些层序中,低位体系域往往以发育扇三角洲分流河道及辫状河道相砂砾岩以及咸化潟湖或蒸发台地相厚层膏盐岩为特征,而水进体系域多以滨浅湖相泥岩和粉砂岩为主,高位体系域则主要为碳酸盐岩及富泥质的沉积序列。     

Post-Chicxulub depositional and diagenetic history of the northwestern Yucatan Peninsula,Mexico

The Chicxulub Sedimentary Basin of the northwestern Yucatan Peninsula, Mexico, which was formed because of the largest identified Phanerozoic bolide impact on Earth, became a site of deposition of dominantly marine carbonate sediments during most of the Cenozoic Era. This is a study of the filling and diagenetic history of this basin and surrounding areas. The study makes use of lithologic, biostratigraphic, petrographic, and geochemical data obtained on core samples from boreholes drilled throughout the northwestern Yucatan Peninsula.The core sample data indicate that: 1) The Chicxulub Sedimentary Basin concentrated the deposition of pelagic and outer-platform sediments during the Paleocene and Eocene, and, in places, during the Early Oligocene, as well, and filled during the Middle Miocene, 2) deeper-water limestone also is present within the Paleocene and Lower Eocene of the proposed Santa Elena Depression, which is located immediately south of the Basin, 3) shallow-water deposits are relatively more abundant outside the Basin and Depression than inside, 4) the autigenic and allogenic silicates from the Paleogene formations are the most abundant inside the Depression, 5) sediment deposition and diagenesis within the Basin also were controlled by impact crater topography, 6) the abundance of the possible features of subaerial exposure increases upward and outward from the center of the Basin, and 7) the formation of replacive low-magnesium calcite and dolomite, dedolomitization, dissolution, and precipitation of vug-filling calcite and dolomite cement have been more common outside the Basin than inside.δ¹⁸O in whole-rock (excluding vug-filling) calcite from core samples ranges from − 7.14‰ to + 0.85‰ PDB. δ¹³C varies from − 6.92‰ to + 3.30‰ PDB. Both stable isotopes correlate inversely with the abundance of subaerial exposure features indicating that freshwater diagenesis has been extensive especially outside and at the edge of the Chicxulub Sedimentary Basin.δ¹⁸O and δ¹³C in whole-rock (excluding vug-filling) dolomite ranges from − 5.54‰ to + 0.87‰ PDB and − 4.63‰ to + 3.38‰ PDB, respectively. Most dolomite samples have negative δ¹⁸O and positive δ¹³C suggesting that replacive dolomitization involved the presence of a fluid dominated by freshwater and/or an anomalously high geothermal gradient.Most dolomite XRD-determined mole percent CaCO₃ varies between 51 and 56. Replacive dolomite is larger, more euhedral, and less stoichiometric inside the Chicxulub Sedimentary Basin than outside.     

Stable carbon isotopes of alkane gases from the Xujiahe coal measures and implication for gas-source correlation in the Sichuan Basin,SW China

The Upper Triassic Xujiahe Formation in the Sichuan Basin, SW China consists of a series of coal measures. The first, third and fifth members of this formation are dominated by gas prone dark mudstones and coals. The mudstones contain Type II and III kerogens with average organic carbon contents around 1.96%. These source rocks are mature in the central Sichuan and highly mature in the western Sichuan Basin, characterized by gas generation with subordinate amounts of light oil or condensate oils. The source rocks are intercalated with the sandstone dominated second, fourth and sixth members of the Xujiahe Formation, thus leading to three separate self contained petroleum systems in the region. The proven gas reserves in the Xujiahe Formation are only less than that of the Triassic Feixianguan Formation and the Xujiahe Formation has the second largest gas field (Guang’an gas field) in the basin. Gases derived from the Xujiahe Formation coals generally show a normal stable carbon isotopic trend for C₁–C₄ n-alkanes, with the highest δ¹³C₂ values among the nine gas pay zones in the basin (?20.7‰ to ?28.3‰), and δ¹³C₁ values as low as ?43.0‰ in the central Sichuan. Gas accumulations with an oil leg have also been found in the eastern and southern Sichuan where the thickness of the Xujiahe Formation is significantly reduced. Gases in these accumulations tend to show low δ¹³C₂ values (?30.0‰ to ?36.3‰), characteristic of oil prone source rocks.     

Shallow marine ostracode turnover in response to environmental change during the Paleocene–Eocene thermal maximum in northwest Tunisia

Two outcrop sections spanning the Paleocene–early Eocene boundary in the Sidi Nasseur–Wadi Mezaz area in northwest Tunisia provided rich ostracode assemblages, yielding 26 species of which three are newly described: Reymenticosta bassiounii, Reymenticosta nasseurensis and Buntonia? tunisiensis. The recorded ostracode fauna and associated foraminifera reflect deposition in a coastal to inner neritic environment. Many of the recorded taxa have a wide geographic distribution throughout the Middle East and North Africa. A correspondence is also observed with West African faunas, especially in the early Eocene fauna. These taxa seem to have originated in West Africa during the Paleocene and migrated northwards during the late Paleocene to early Eocene. Sea-level change and decrease in oxygenation associated with the Paleocene–Eocene thermal maximum (PETM) caused the local disappearance of the South Tethyan Paleocene fauna represented by Paracosta kefensis (morphotype-A), Paracosta aff. paleomokattamensis, Paracypris sp. B Esker, Loxoconcha saharaensis, Buntonia sp. 3 Donze et al., Protobuntonia nakkadii, and probably Reymenticosta bassiounii and R. nasseurensis. Simultaneously, a new but poorly diverse Afro-Tethyan fauna, mainly represented by Alocopocythere attitogonensis and Buntonia? tunisiensis, settled in the studied part of the basin. After the PETM, diversity increased again as various taxa (e.g. Bairdia aegyptiaca, Reticulina lamellata and Aegyptiana duwiensis) (re)appeared. Although detailed records across the P/E boundary are still sparse, it appears that the PETM exerted significant influence on the paleobiogeography and composition of Tethyan ostracode faunas.     

Stable isotope(δ~(13)C_(ker),δ~(13)C_(carb),δ~(18)O_(carb)) distribution along a Cambrian outcrop section in the eastern Tarim Basin,NW China and its geochemical significance

This study investigated the geochemical features of the lower Paleozoic strata of Yaerdang Mountain outcrop along with the core samples from well TD2∈ in the eastern Tarim Basin,NW China.The total organic carbon abundance,hydrocarbon-generating precursor biospecies,and stable isotope ratios of organics and carbonate(δ~(13)C_(ker),δ~(13)C_(carb) and δ~(18)O_(carb)) were comprehensively studied for their possible correlative constraints during sedimentary evolution.The results revealed that the δ~(13)C_(ker)(VPDB) of Cambrian kerogens along the outcrop section varied from-34.6‰ to-28.4‰,indicating an increasing tendency from the lower Cambrian to the upper Cambrian.This was on the whole accompanied by the variation in the δ~(13)C_(carb) and δ~(18)O_(carb) along the profile,which might be associated with the changes in the sea level and also in the compositional variation of benthic and planktonic biomass.The large variation in the stable carbon isotope ratios up to 6‰ along the outcrop section reflected the heterogeneity of the Cambrian source rocks from the eastern Tarim Basin.Hence,the ~(13)C-enriched crude oils from well TD2∈might have been derived from a localized stratum of Cambrian source rocks.The results from this study showed the possibility of multiple source kitchens in the Cambrian-lower Ordovician portion of Tarim Basin.     

塔里木盆地新生代海相沉积问题

基于前人文献,对塔里木盆地新生代海相沉积问题进行梳理,进而探讨该盆地新生代海侵的次数和范围以及海退的时限、原因。研究表明,新生代,塔里木盆地至少经历古近纪的阿尔塔什晚期至齐姆根早期(古新世早期至古新世晚期)、卡拉塔尔期—乌拉根期(始新世中期)、巴什布拉克中期(始新世晚期至早渐新世)等三期海侵;塔里木盆地中新世仍有海相地层这一认识获得广泛认可仍需更多的地质证据来支持。塔里木盆地海侵范围在卡拉塔尔—乌拉根组沉积时期达到最大,向东可达玛扎塔格地区,在盆地北缘和南缘分别可以到达库尔勒以东地区和洛浦县阿其克以东地区。由于受到全球海平面变化和构造运动的共同影响,副特提斯海新生代从塔里木盆地退却的沉积记录包括齐姆根组顶部、乌拉根组顶部、巴什布拉克组第四段和第五段,时间上分别对应于古新世晚期、始新世中晚期和早渐新世。     

Calcareous Nannofossils and Molecular Fossils in Cobalt-rich Crusts and their Response to the P/E Global Event

A biostratigraphic study on calcareous nannofossils from the CM3D06 Co-rich ferromanganese crust from the Magellan seamounts in the northwestern Pacific enabled estimation of depositional age.The bio-imprinting of calcareous nannofossils and other fossil species suggests six age ranges for the nannofossils: late Cretaceous,late Paleocene,(early,middle,late) Eocene,middle Miocene,late Pliocene,and Pleistocene.Gas chromatography(GC) and gas chromatography-mass spectrometry(GC-MS) were used to test the Co-rich crusts,and a variety of molecular fossils were detected,such as chloroform bituminous "A",n-alkane,isoprenoid and sterol.Peak carbon and molecular indices(such as ΣC23 /ΣC24 +,CPI,Pr/Ph,Pr/nC17,Ph/nC18 and δ13C) indicate that the parent organic matter is dominated by marine phytoplankton and thallogen whereas there is little input of terrestrial organic matter.Researches on calcareous nannofossils,molecular fossils and molecular organic geochemistry data reveal that the Paleocene/Eocene(P/E) global event is recorded in the cobaltrich crusts from the northwestern Pacific Ocean.A succession of biomes can be observed near the 85 mm boundary(about 55 Ma),i.e.,the disappearance of the late Cretaceous Watznaueria barnesae and Zigodicus spiralis,and Broisonia parka microbiotas above the P/E boundary,and the bloom of Coccolithus formosus,Discoaster multiradiatus,Discoaster mohleri and Discoaster sp.below the boundary.Typical parameters of molecular fossils,such as saturated hydrocarbon components and carbon-number maxima,Pr/Ph,Pr/C17,Ph/C18,distribution types of sterols,Ts/Tm ratios and bacterial hopane,also exhibit dramatic changes near the P/E boundary.These integrated results illustrate that the biome succession of calcareous nannofossils,relative content of molecular fossils and molecular indices in the cobalt-rich crusts near the 85 mm boundary faithfully record the P/E global event.     

First carbon isotope chemostratigraphy of the Ouled Abdoun phosphate Basin,Morocco; implications for dating and evolution of earliest African placental mammals

The well-known Maastrichtian–Ypresian vertebrate-bearing phosphate series, in the Ouled Abdoun Basin, Morocco, is classically dated using regional selachian biostratigraphic zonation. These marine sediments yielded Paleocene and Eocene mammals comprising the earliest known placentals from Africa. This study provides the first insight into the organic carbon isotope chemostratigraphy (δ¹³C_org) of the Moroccan phosphate series and a refined dating of its vertebrate-bearing levels. Four Paleocene–Eocene sections in the NE Ouled Abdoun quarries show consistent δ¹³C_org long term evolutions, from the base to the top: 1) positive trend in phosphorite Bed IIa, beginning with the lower Bone Bed yielding mammals such as Eritherium, Ocepeia, Abdounodus, Lahimia, of early Thanetian and Selandian age; 2) transitional negative trend in the Intercalary phosphorite Beds II/I that includes the Otodus obliquus and Phosphatherium escuilliei Bone Bed of earliest Ypresian age; 3) negative trend to the lowermost δ¹³C_org values that are correlative to the early–middle Ypresian interval including ETM 2 and ETM 3 hyperthermal events in the global record; 4) positive trend in chert-enriched facies containing the middle Ypresian EECO global climatic event. Our chemostratigraphic study of the Ouled Abdoun phosphate series provides a new chronostratigraphic framework for calibrating the beginning of the evolution of placental mammals in Africa. The lower Bone Bed level from the Paleocene phosphorite Bed IIa yielding Eritherium is not younger than early Thanetian, and is most likely Selandian. The Phosphatherium Bone Bed in the Intercalary Beds II/I is earliest Ypresian. The phosphorite Bed 0, from which Daouitherium probably came, is early–middle Ypresian, just below the EECO. This suggests that the first large proboscideans evolved after the PETM, during mid-Ypresian warming events. The δ¹³C_org study does not support the presence of Lutetian in the NE Ouled Abdoun phosphate series and suggests that a noticeable part of the upper Thanetian is absent.     

塔里木北部库车前陆盆地晚白垩世和古新世的钙质超微化石组合

库车前陆盆地是中国大型油气基地之一,盆地中的白垩系及古近系为盆地油气的主要储层。对本区白垩系的时代划分和沉积环境的精确确定直接关系到对油气田的规模、储量和分布范围的正确评价。本研究在前人划分为陆相下白垩统巴什基奇克组的顶部首次发现了由10属15种组成的晚白垩世海相钙质超微化石组合Arkangelskiellacymbiformis—Quadrumgartneri。此外,在由前人定为古新统—始新统的塔拉克组下段也发现了晚白垩世Arkangel skiellacymbiformis—Quadrumgartneri组合,在该组上段发现了古新世化石Biantholithussparsus。该成果既为准确确定这两个岩组的地质时代提供了可靠的古生物证据,又为本区存在晚白垩世地层和海相沉积提供了佐证,表明巴什基奇克组顶部存在晚白垩世的海相沉积,塔拉克组下段属于上白垩统,上段属于古新统。     

Atmospheric palaeo-CO2 estimates based on the carbon isotope and stomatal data of Cheirolepidiaceae from the Lower Cretaceous of the Jiuquan Basin,Gansu Province

The stable carbon isotope compositions and the stomatal parameters (stomatal density and stomatal index) of four Cheirolepidiaceae species, Brachyphyllum ningxiaensis, Brachyphyllum obtusum, Pseudofrenelopsis dalatzensis and Pseudofrenelopsis gansuensis, were analyzed to recover the late Early Cretaceous atmospheric CO₂ levels. The fossil plants were collected from 5 consecutive sedimentary members of the uppermost Zhonggou Formation. Based on the stomatal data, the estimated palaeo-atmospheric CO₂ concentrations in the Jiuquan Basin during the late Early Cretaceous were 1060–882 ppmv based on the carboniferous standardization and were 641–531 ppmv based on the recent standardization; the pCO₂ values present at first a decreasing and then an increasing trend within the sedimentary time of the five members. The δ¹³Cp values based on the 21 Brachyphyllum specimens showed a large variation, which ranged from −20.98‰ to −25.69‰, with an average of −24.2‰. The values also identified a C3 photosynthetic pathway for the Brachyphyllum specimens. The predicted δ¹³Ca values varied from −2.1‰ to −6.38‰, with an average of −5.03‰. These two proxies were irregular within the different members; therefore, the correlation with the change in atmospheric CO₂ concentrations was not significant. Moreover, a water-stressed environment was proposed based on the δ¹³C values of the present fossil plants, a proposal that was also supported by the previous palaeobotanical, palynological and stratigraphical evidence. In the present study, an inconsistent relationship between the stable carbon isotope and the stomata values was apparent, which most likely indicated that the stomata numbers of the plant were more sensitive to the variation in the concentration of the atmospheric CO₂, whereas the δ¹³C values were sensitive to the moisture conditions.     

早古近纪陆相断陷型湖泊物质分异作用及其对“PETM”事件的响应:以济阳坳陷孔店组为例

古近纪早期,地球上发生了古新世-始新世极热气候(PETM)事件,严重影响全球碳循环过程和海陆生态环境系统.依据普通薄片、元素分析、碳同位素、TOC等实验结果.研究了渤海湾盆地济阳断陷湖盆古新世-始新世时期的湖泊环境时空波动变化及其对PETM事件的响应,发现济阳断陷湖盆早期经历了多旋回的演化过程,湖盆中碎屑物质和化学物质的分异作用同时发生,陆地风化作用和化学沉积物质分异指示了极热气候的变化过程;该时期湖水为逐渐咸化的盐湖环境,具有空间的分带性和时间的阶段演化性,湖水咸化是热气候事件发生的直接响应;湖泊的时空波动演化经历了古新世-始新世时期的极热气候(PETM)事件,该事件早期湖泊尚未完全咸化,浮游生物比较繁盛,早期浮游植物对12CO₂的吸收,会导致短暂的湖泊古生产力较高,但是随着湖盆逐渐咸化,生物的活动存活较难,主要以旱生植物为主,古生产力降到最低.由于过量的12C吸收沉淀,造成湖泊沉积记录中的δ13C明显负偏,最大可达5×10-3.由此证实全球PETM事件影响了古新世-始新世之交济阳断陷湖盆的时空演化和物质分异过程.      

Geochemical and isotopic approach to maturity/source/mixing estimations for natural gas and associated condensates in the Thrace Basin,NW Turkey

The Tertiary Thrace Basin located in NW Turkey comprises 9 km of clastic-sedimentary column ranging in age from Early Eocene to Recent in age. Fifteen natural gas and 10 associated condensate samples collected from the 11 different gas fields along the NW–SE extending zone of the northern portion of the basin were evaluated on the basis of their chemical and individual C isotopic compositions. For the purpose of the study, the genesis of CH₄, thermogenic C₂₊ gases, and associated condensates were evaluated separately.Methane appears to have 3 origins: Group-1 CH₄ is bacteriogenic (Calculated δ¹³C_C1–C = −61.48‰; Silivri Field) and found in Oligocene reservoirs and mixed with the thermogenic Group-2 CH₄. They probably formed in the Upper Oligocene coal and shales deposited in a marshy-swamp environment of fluvio-deltaic settings. Group-2 (δ¹³C_C1–C = −35.80‰; Hamitabat Field) and Group-3 (δ¹³C_1–C = −49.10‰; Değirmenköy Field) methanes are thermogenic and share the same origin with the Group-2 and Group-3 C₂₊ gases. The Group-2 C₂₊ gases include 63% of the gas fields. They are produced from both Eocene (overwhelmingly) and Oligocene reservoirs. These gases were almost certainly generated from isotopically heavy terrestrial kerogen (δ¹³C = −21‰) present in the Eocene deltaic Hamitabat shales. The Group-3 C₂₊ gases, produced from one field, were generated from isotopically light marine kerogen (δ¹³C = −29‰). Lower Oligoce ne Mezardere shales deposited in pro-deltaic settings are believed to be the source of these gases.The bulk and individual n-alkane isotopic relationships between the rock extracts, gases, condensates and oils from the basin differentiated two Groups of condensates, which can be genetically linked to the Group-2 and -3 thermogenic C₂₊ gases. However, it is crucial to note that condensates do not necessarily correlate to their associated gases.Maturity assessments on the Group-1 and -2 thermogenic gases based on their estimated initial kerogen isotope values (δ¹³C = −21‰; −29‰) and on the biomarkers present in the associated condensates reveal that all the hydrocarbons including gases, condensates and oils are the products of primary cracking at the early mature st age (R_eq = 0.55–0.81%). It is demonstrated that the open-system source conditions required for such an early-mature hydrocarbon expulsion exist and are supported by fault systems of the basin.     

Distinguishing Cambrian from Upper Ordovician source rocks: Evidence from sulfur isotopes and biomarkers in the Tarim Basin

The reported source rocks for the abundant petroleum in the Tarim Basin, China range from Cambrian to Lower Ordovician and/or Upper Ordovician in age. However, the difference between the two groups of source rocks is not well characterized. In this study, pyrite was removed from eleven mature to over mature kerogen samples from source rocks using the method of CrCl₂ reduction and grinding. The kerogen and coexisting pyrite samples were then analyzed for δ³⁴S values. Results show that the kerogen samples from the Cambrian have δ³⁴S values between +10.4‰ and +19.4‰. The values are significantly higher than those from the Lower Ordovician kerogen (δ³⁴S of between +6.7‰ and +8.7‰), which in turn are generally higher than from the Upper Ordovician kerogen samples (δ³⁴S of between ?15.3 and +6.8‰). The associated pyrite shows a similar trend but with much lower δ³⁴S values. This stratigraphically controlled sulfur isotope variation parallels the evolving contemporary marine sulfate and dated oil δ³⁴S values from other basins, suggesting that seawater sulfate and source rock age have an important influence on kerogen and pyrite δ³⁴S values. The relatively high δ³⁴S values in the Cambrian to Lower Ordovician source rocks are associated with abundant aryl isoprenoids, gammacerane and C₃₅ homohopanes in the extractable organic matter, indicating that these source rocks were deposited in a bottom water euxinic environment with water stratification. Compared with the Upper Ordovician, the Cambrian to Lower Ordovician source rocks show abundance in C₂₈ 20R sterane, C₂₃ tricyclic terpanes, 4,23,24-trimethyl triaromatic dinosteroids and depletion in C₂₄ tetracyclic terpane, C₂₉ hopane. Thus, δ³⁴S values and biomarkers of source rock organic matter can be used for distinguishing the Cambrian and Upper Ordovician source rocks in the Tarim Basin.     

Influencing factors and significance of organic and inorganic nitrogen isotopic compositions in lacustrine sedimentary rocks

Comprehensive nitrogen biogeochemical cycle has been reconstructed for representative lacustrine organic-rich sedimentary rock in China, namely the Triassic Yanchang Formation (YF, 199–230 Ma) in Ordos and the Cretaceous Qingshankou Formation (QF, 86–92 Ma) in Songliao basins, by evaluating the organic and inorganic nitrogen isotopic compositions rather than only organic or bulk nitrogen isotopic compositions. The results indicate that the nitrogen isotope values of bulk rock (δ¹⁵N_bulk) in the non-metamorphic stage are significantly different from that of kerogen, which challenge the conceptual framework of sedimentary nitrogen isotope interpretation. The δ¹⁵N_bulk from the YF and QF were lower than their respective the nitrogen isotope values of kerogen (δ¹⁵N_ker), with offsets up to ～5.1‰, which have the inverse relationship for the metamorphosed rock. Thermal evolution did not significantly modify the δ¹⁵N of bulk rock and kerogen. The δ¹⁵N of sediments from the YF (δ¹⁵N_bulk, 1.6‰–5.6‰) were lower than that of rock from the QF (δ¹⁵N_bulk, 10.2‰–15.3‰). The nitrogen isotope values of silicate incorporated nitrogen (δ¹⁵N_sil) were slightly lower than those of the δ¹⁵N_ker in the YF and obviously lower for the QF. The fact that different nitrogen cycles occur in the YF and QF due to the different depositional redox conditions leads to different isotopic results. The YF water environment dominated by oxic conditions is not conducive to the occurrence of denitrification and anammox, and no abundant N₂ loss leads to the relatively light δ¹⁵N_bulk. In the stratified water for the QF, redox transition zone promotes denitrification and anammox, resulting in the heavy δ¹⁵N_bulk of rock and promotes the DNRA, resulting in heavy δ¹⁵N_ker and low δ¹⁵N_sil.     

新疆吐鲁番盆地古近纪气候事件的研究

吐鲁番盆地是天山山脉中的一个山间盆地,古近系保存完好,是研究中国西北地区古近纪气候变迁的良好地区。通过对吐鲁番盆地连木沁剖面古近系多种气候代用指标（Fe₂O₃、FeO、CaCO₃、有机碳、有机碳同位素）的研究,探讨了吐鲁番盆地古近纪的气候变迁和重要气候事件。利用Fe3+/Fe2+值,恢复了吐鲁番盆地古近纪的气温：古新世的年均气温为22.35℃,始新世为21.82℃,渐新世为15.69℃,并且在渐新世的早期和晚期发生较大幅度的降温事件。对地层中CaCO3（碳酸钙）含量的研究表明,古新统和始新统碳酸钙平均含量分别为468％和666％,指示该沉积时期气候相对比较湿润,而渐新统达15.01％,指示渐新世气候明显干旱化,并且渐新世的早期和晚期气候更为干旱。有机碳同位素（δ¹³Corg）值分布于C3植物的范围内,表明其受C3植物的影响。对地层中的δ¹³Corg值研究显示,该值与地层中碳酸钙含量呈负相关,与气温呈正相关,即该值偏负时,地层中碳酸钙含量增加,气温降低。各种气候指标指示吐鲁番盆地古新世和始新世气候比较温暖湿润,而渐新世气候干旱温凉。     

Origin of spheroidal chert nodules, Drunka Formation (Lower Eocene), Egypt

Chert nodules of the Drunka Formation (Lower Eocene) are mostly spherical, have diameters from 40 to 120 cm, are quasi-uniformly spaced 2–3 m apart in the plane of bedding, have concentric internal structure and, except for rare small (<6 cm) solid chert nodules, are less than 85% chertified. Nodules formed after moderate alteration of limestone by meteoric water (δ¹⁸O_calcite = –4 to –8‰) at shallow (<100 m) burial depths; more extensive alteration of limestone (δ¹⁸O = –10 to –16‰) by meteoric water followed nodule growth. Chertification was by low-temperature meteoric water (δ¹⁸O_quartz = +18‰ in margins to +22‰ in nuclei) at shallow burial depths. Meteoric water may have invaded the Drunka Formation in association with shelf progradation during the Early Eocene, or during the development of a Middle Eocene unconformity. Replacement of carbonate mud by microcrystalline quartz was the dominant chertification process, but fossils were replaced in part by fine-grained equant megaquartz, quartzine and chalcedony; the last of these occurs in places as beekite. Opal A-secreting marine organisms are the inferred source of silica, but none are preserved. There is no compelling evidence of an opal-CT precursor, so quartz may have formed by direct precipitation. Self-organization processes of enigmatic character established the spacing pattern of the nodules and also the Liesegang-banded internal structure of the chert nodules. Nodules grew chiefly by diffusive supply of silica, although one locality has elongate nodules that grew when there was some porewater advection. Chertification patterns and δ¹⁸O values of both calcite and quartz indicate that nodule growth was complex and variable. Some nodules probably grew from the centre outwards. Many nodules, however, initially grew simultaneously across the entire nodule, but late-stage growth was predominantly at the outer margins or at selective internal sites.