Groundwater fluxes into a submerged sinkhole area,Central Italy,using radon and water chemistry

The groundwater contribution into Green Lake and Black Lake (Vescovo Lakes Group), two cover collapse sinkholes in Pontina Plain (Central Italy), was estimated using water chemistry and a ²²²Rn budget. These data can constrain the interactions between sinkholes and deep seated fluid circulation, with a special focus on the possibility of the bedrock karst aquifer feeding the lake. The Rn budget accounted for all quantifiable surface and subsurface input and output fluxes including the flux across the sediment–water interface. The total value of groundwater discharge into Green Lake and Black Lake (∼540 ± 160 L s⁻¹) obtained from the Rn budget is lower than, but comparable with historical data on the springs group discharge estimated in the same period of the year (800 ± 90 L s⁻¹). Besides being an indirect test for the reliability of the Rn-budget “tool”, it confirms that both Green and Black Lake are effectively springs and not simply “water filled” sinkholes. New data on the water chemistry and the groundwater fluxes into the sinkhole area of Vescovo Lakes allows the assessment of the mechanism responsible for sinkhole formation in Pontina Plain and suggests the necessity of monitoring the changes of physical and chemical parameters of groundwater below the plain in order to mitigate the associated risk.     

Nature and timing of large landslides in the Himalaya and Transhimalaya of northern India

Four large landslides, each with a debris volume >10⁶ m³, in the Himalaya and Transhimalaya of northern India were examined, mapped, and dated using ¹⁰Be terrestrial cosmogenic radionuclide surface exposure dating. The landslides date to 7.7±1.0 ka (Darcha), 7.9±0.8 ka (Patseo), 6.6±0.4 ka (Kelang Serai), and 8.5±0.5 ka (Chilam). Comparison of slip surface dips and physically reasonable angles of internal friction suggests that the landslides may have been triggered by increased pore water pressure, seismic shaking, or a combination of these two processes. However, the steepness of discontinuities in the Darcha rock-slope, suggests that it was more likely to have started as a consequence of gravitationally-induced buckling of planar slabs. Deglaciation of the region occurred more than 2000 years before the Darcha, Patseo, and Kelang Serai landslides; it is unlikely that glacial debuttressing was responsible for triggering the landslides. The four landslides, their causes, potential triggers and mechanisms, and their ages are compared to 12 previously dated large landslides in the region. Fourteen of the 16 dated landslides occurred during periods of intensified monsoons. Seismic shaking, however, cannot be ruled out as a mechanism for landslide initiation, because the Himalaya has experienced great earthquakes on centennial to millennial timescales. The average Holocene landscape lowering due to large landslides for the Lahul region, which contains the Darcha, Patseo, and Kelang Serai landslides, is ～0.12 mm/yr. Previously published large-landslide landscape-lowering rates for the Himalaya differ significantly. Furthermore, regional glacial and fluvial denudation rates for the Himalaya are more than an order of magnitude greater. This difference highlights the lack of large-landslide data, lack of chronology, problems associated with single catchment/large landslide-based calculations, and the need for regional landscape-lowering determinations over a standardized time period.     

Geologic hazards associated with seismogenic faulting in southern Siberia and Mongolia: forms and location patterns

The forms and location patterns of geologic hazards induced by earthquakes in southern Siberia, Mongolia, and northern Kazakhstan in1950 through 2008 have been investigated statistically, using a database of coseismic effects created as a GIS MapInfo application, with a handy input box for large data arrays. The database includes 689 cases of macroseismic effects from M_S = 4.1–8.1 events at 398 sites. Statistical analysis of the data has revealed regional relationships between the magnitude of an earthquake and the maximum distance of its environmental effects (soil liquefaction and subsidence, secondary surface rupturing, and slope instability) to the epicenter and to the causative fault. Thus estimated limit distances to the fault for the M_S = 8.1 largest event are 40 km for soil subsidence (sinkholes), 80 km for surface rupture, 100 km for slope instability (landslides etc.), and 130 km for soil liquefaction. These distances are 3.5–5.6 times as short as those to the epicenter, which are 150, 450, 350, and 450 km, respectively. Analysis of geohazard locations relative to nearest faults in southern East Siberia shows the distances to be within 2 km for sinkholes (60% within 1.5 km), 4.5 km for landslides (90% within 1.5 km), 8 km for liquefaction (69% within 1 km), and 35.5 km for surface rupture (86% within 2 km). The frequency of hazardous effects decreases exponentially away from both seismogenic and nearest faults. Cases of soil liquefaction and subsidence are analyzed in more detail in relation to rupture patterns. Equations have been suggested to relate the maximum sizes of secondary structures (sinkholes, dikes, etc.) with the earthquake magnitude and shaking intensity at the site. As a result, a predictive model has been created for locations of geohazard associated with reactivation of seismogenic faults, assuming an arbitrary fault pattern. The obtained results make basis for modeling the distribution of geohazards for the purposes of prediction and estimation of earthquake parameters from secondary deformation.     

Landslides triggered by the 22 July 2013 Minxian–Zhangxian,China, Mw 5.9 earthquake: Inventory compiling and spatial distribution analysis

On July 22, 2013, an earthquake of Ms. 6.6 occurred at the junction area of Minxian and Zhangxian counties, Gansu Province, China. This earthquake triggered many landslides of various types, dominated by small-scale soil falls, slides, and topples on loess scarps. There were also a few deep-seated landslides, large-scale soil avalanches, and fissure-developing slopes. In this paper, an inventory of landslides triggered by this event is prepared based on field investigations and visual interpretation of high-resolution satellite images. The spatial distribution of the landslides is then analyzed. The inventory indicates that at least 2330 landslides were triggered by the earthquake. A correlation statistics of the landslides with topographic, geologic, and earthquake factors is performed based on the GIS platform. The results show that the largest number of landslides and the highest landslide density are at 2400 m–2600 m of absolute elevation, and 200 m–300 m of relative elevation, respectively. The landslide density does not always increase with slope gradient as previously suggested. The slopes most prone to landslides are in S, SW, W, and NW directions. Concave slopes register higher landslide density and larger number of landslides than convex slopes. The largest number of landslides occurs on topographic position with middle slopes, whereas the highest landslide density corresponds to valleys and lower slopes. The underlying bedrocks consisting of conglomerate and sandstone of Lower Paleogene (E^b) register both the largest number and area of landslides and the highest landslide number and area density values. Correlations of landslide number and landslide density with perpendicular- and along-strike distance from the epicenter show an obvious spatial intensifying character of the co-seismic landslides. The spatial pattern of the co-seismic landslides is strongly controlled by a branch of the Lintan-Dangchang fault, which indicates the effect of seismogenic fault on co-seismic landslides. In addition, the area affected by landslides related to the earthquake is compared to the relationship of “area affected by landslides vs. earthquake magnitude” constructed based on earthquakes worldwide, and it is shown that the area affected by landslides triggered by the Minxian–Zhangxian earthquake is larger than that of almost all other events with similar magnitudes.     

Early Paleoproterozoic–Archean dykes and gneisses in Russian Karelia of the Fennoscandian Shield—New paleomagnetic,isotope age and geochemical investigations

We present here new palaeomagnetic, isotopic age and geochemical data from Archean and Early Palaeoproterozoic rocks in the eastern Fennoscandian Shield. We have studied NE–SW trending gabbronorite dyke sets and their host Archean basement rocks in the Vodlozero block near the 2449 Ma Burakovka layered intrusion in southern Russian Karelia. Both dyke sets are genetically related to the Burakovka intrusion. The other, ca. 25 km long Avdeev dyke, locating a few kilometers south from the Burakovka intrusion, yields a stable single component remanence direction that is in agreement with the direction previously obtained from the Burakovka intrusion. Another NE–SW trending dyke, 0.8 m wide Shalskiy diabase dyke, about 30 km south of the Burakovka intrusion yields a similar remanence direction as the Avdeev dyke. The overall mean remanence direction has a palaeopole at Plat = −12.3°N, Plong = 243.5°E (A95 = 15.4°, 4 sites, 28 samples). The thin Shalskiy diabase dyke transects a similarly NE–SW trending 500 m wide coarse grained gabbronorite dyke which has now been dated by Sm–Nd method as 2608 ± 56 Ma. Geochemically all the dykes are quite similar showing slight calc-alkaline affinity and low TiO₂ and high SiO₂ with moderate MgO and low Cr and Ni. Furthermore, the dykes are geochemically identical to the 2.45 Ga dyke swarm in the northern Karelian Province.The remanence direction of the thin Shalskiy diabase dyke differs significantly from the high temperature and high coercivity remanence component of the unbaked Archean gabbronorite dyke which yields a palaeopole at Plat = 22.7°N, Plong = 222.1°E (dp = 8.2°, dm = 16.2°, five samples). On the basis of different remanence directions of the diabase dyke and the unbaked Archean gabbronorite dyke, the baked contact test for the diabase dyke is positive. In addition to the high temperature and high coercivity component of the baked and unbaked Archean gabbronorite dyke, in low temperatures and coercivities we isolated a similar component as in the diabase dyke. A comparable remanence component was also obtained from the Archean basement at ca. 8 km from the dykes. We propose that in the studied area, the Archean basement and the Archaean dyke were partly remagnetized due to emplacement and subsequent uplift and cooling of the large Burakovka layered intrusion and related dykes at about 2.40 Ga ago.This interpretation lends support from a new ⁴⁰Ar/³⁹Ar dating of hornblende from another area, Lake Paajarvi area, in northern Karelia. There, a negative baked contact test was previously obtained for the remanence of the dated ca. 2.45 Ga dyke rocks related to the ca. 2.45 Ga Oulanka layered intrusion. The ⁴⁰Ar/³⁹Ar dating of the unbaked Archean basement which yields the same remanence component as the dykes, shows a plateau age of ca. 2.6 Ga, but in addition, it also shows resetting of the basement at ca. 2.4 Ga ago. The dating thus supports reactivation and partial remagnetization of the Archean basement at ca. 2.4 Ga ago.Our new palaeomagnetic results from the Burakovka dykes and the new ⁴⁰Ar/³⁹Ar dating from the Lake Paajarvi area give support to our previous interpretation that at Lake Paajarvi area the remanence component suggested to be 2.4 Ga, despite to negative baked contact test, is indeed of this age. Therefore, it is implied that the results can be used for continental reconstructions.     

40Ar/39Ar age pattern associated with differential uplift along the Eastern Highlands shear zone,Cape Breton Island,Canadian Appalachians

The Eastern Highlands shear zone in Cape Breton Island is a crustal scale thrust. It is characterized by an amphibolite-facies deformation zone ∼5 km wide formed deep in the crust that is overprinted by a greenschist-facies mylonite zone ∼1 km wide that formed at a more shallow level. Hornblende ⁴⁰Ar/³⁹Ar plateau ages on the hanging wall decrease towards the centre of the shear zone. In the older zone (over 7.8 km from the centre), the ages are between ∼565 and ∼545 Ma; in the younger zone (within 4.5 km of the centre), they are between ∼425 and ∼415 Ma; and in the transitional zone in between, they decrease abruptly from ∼545 to ∼425 Ma. Pressures of crystallization of plutons in the hanging wall, based on the Al-in-hornblende barometer and corresponding to depth of emplacement, increase towards the centre of the shear zone and indicate a differential uplift of up to ∼28 km associated with movement along the shear zone. The age pattern is interpreted to have resulted from the differential uplift. The pressure data show that rocks exposed in the younger zone were buried deep in the crust and did not cool through the hornblende Ar blocking temperature (∼500°C) until differential uplift occurred. The ⁴⁰Ar/³⁹Ar ages in the zone (∼425–415 Ma) thus date shear zone movement or the last stage of it. In contrast, rocks in the older zone were more shallowly buried before differential uplift and cooled through the blocking temperature soon after the emplacement of ∼565–555 Ma plutons in the area, long before shear zone movement. The transitional zone corresponds to the Ar partial retention zone before differential uplift. The ⁴⁰Ar/³⁹Ar age pattern thus reflects a Neoproterozoic to Silurian cooling profile that was exposed as a result of differential uplift related to movement along the shear zone. A similar K–Ar age pattern has been reported for the Alpine fault in New Zealand. It is suggested that such isotopic age patterns can be used to help constrain the ages, kinematics, displacements and depth of penetration of shear zones.     

Tectonics and thermal structure of western Satpura,India

Increased seismicity and occurrences of hot springs having surface temperature of 36–58 °C are observed in the central part of India (74–81° E, 20–25° N), where the NE trending Middle Proterozoic Aravalli Mobile Belt meets the ENE trending Satpura Mobile Belt. Earlier Deep Seismic Sounding (DSS) studies along Thuadara-Sendhwa-Sindad profile in the area has showed Mesozoic Sediments up to around 4 km depth covered by Deccan Trap and the Moho depth with a boundary velocity (P_n) of 8.2 km/s. In the present study, surface heat flow of 48 ± 4 mW m^?2 has been estimated based on P_n velocity, which agrees with the value of heat flow of 52 ± 4 mW m^?2 based on Curie point isotherms estimates. The calculated temperature-depth profile shows temperature of 80–120 °C at the basement, which is equivalent to oil window temperature in Mesozoic sediments and around 570–635 °C at Moho depth of 38–43 km and the thermal lithosphere is about 110 km thick, which is comparatively higher than those of adjoining regions. The present study reveals the brittle–ductile transition zone at 14–41 km depth (temperature around 250–600 °C) where earthquake nucleation takes place.     

Late Pleistocene–Holocene rise and collapse of Lake Suguta,northern Kenya Rift

The Late Pleistocene to Middle Holocene African Humid Period (AHP) was characterized by dramatic hydrologic fluctuations in the tropics. A better knowledge of the timing, spatial extent, and magnitude of these hydrological fluctuations is essential to decipher the climate-forcing mechanisms that controlled them. The Suguta Valley (2°N, northern Kenya Rift) has recorded extreme environmental changes during the AHP. Extensive outcrops of lacustrine sediments, ubiquitous wave-cut notches, shorelines, and broad terrace treads along the valley margins are the vestiges of Lake Suguta, which once filled an 80 km long and 20 km wide volcano–tectonic depression. Lake Suguta was deep between 16.5 and 8.5 cal ka BP. During its maximum highstand, it attained a water depth of ca 300 m, a surface area of ca 2150 km², and a volume of ca 390 km³. The spatial distribution of lake sediments, the elevation of palaeo-shorelines, and other geomorphic evidences suggest that palaeo-Lake Suguta had an overflow towards the Turkana basin to the north. After 8.5 cal ka BP, Lake Suguta abruptly disappeared. A comparison of the Lake Suguta water-level curve with other reconstructed water levels from the northern part of the East African Rift System shows that local insolation, which is dominated by precessional cycles, may have controlled the timing of lake highstands in this region. Our data show that changes of lake levels close to the Equator seem to be driven by fluctuations of spring insolation, while fluctuations north of the Equator are apparently related to variations in summer insolation. However, since these inferred timings of lake-level changes are mostly based on the radiocarbon dating of carbonate shells, which may have been affected by a local age reservoir, alternative dating methods are needed to support this regional synthesis. Between 12.7 and 11.8 cal ka BP, approximately during the Northern Hemisphere high-latitude Younger Dryas, the water level of Lake Suguta fell by ca 50 m, suggesting that remote influences also affected local hydrology.     

‘PALEOVAN’, International Continental Scientific Drilling Program (ICDP): site survey results and perspectives

Lake Van is the fourth largest terminal lake in the world (volume 607 km³, area 3570 km², maximum depth 460 m), extending for 130 km WSW–ENE on the Eastern Anatolian High Plateau, Turkey. The sedimentary record of Lake Van, partly laminated, has the potential to obtain a long and continuous continental sequence that covers several glacial–interglacial cycles (ca 500 kyr). Therefore, Lake Van is a key site within the International Continental Scientific Drilling Program (ICDP) for the investigation of the Quaternary climate evolution in the Near East (‘PALEOVAN’). As preparation for an ICDP drilling campaign, a site survey was carried out during the past years. We collected 50 seismic profiles with a total length of ～850 km to identify continuous undisturbed sedimentary sequences for potential ICDP locations. Based on the seismic results, we cored 10 different locations to water depths of up to 420 m. Multidisciplinary scientific work at positions of a proposed ICDP drill site included measurements of magnetic susceptibility, physical properties, stable isotopes, XRF scans, and pollen and spores. This core extends back to the Last Glacial Maximum (LGM), a more extended record than all the other Lake Van cores obtained to date. Both coring and seismic data do not show any indication that the deepest part of the lake (Tatvan Basin, Ahlat Ridge) was dry or almost dry during past times. These results show potential for obtaining a continuous undisturbed, long continental palaeoclimate record. In addition, this paper discusses the potential of ‘PALEOVAN’ to establish new results on the dynamics of lake level fluctuations, noble gas concentration in pore water of the lake sediment, history of volcanism and volcanic activities based on tephrostratigraphy, and paleoseismic and earthquake activities.     

Density structure of the cratonic mantle in Southern Africa: 2. Correlations with kimberlite distribution,seismic velocities,and Moho sharpness

We present a new regional model for the depth-averaged density structure of the cratonic lithospheric mantle in southern Africa constrained on a 30′ × 30′ grid and discuss it in relation to regional seismic models for the crust and upper mantle, geochemical data on kimberlite-hosted mantle xenoliths, and data on kimberlite ages and distribution. Our calculations of mantle density are based on free-board constraints, account for mantle contribution to surface topography of ca. 0.5–1.0 km, and have uncertainty ranging from ca. 0.01 g/cm³ for the Archean terrains to ca. 0.03 g/cm³ for the adjacent fold belts. We demonstrate that in southern Africa, the lithospheric mantle has a general trend in mantle density increase from Archean to younger lithospheric terranes. Density of the Kaapvaal mantle is typically cratonic, with a subtle difference between the eastern, more depleted, (3.31–3.33 g/cm³) and the western (3.32–3.34 g/cm³) blocks. The Witwatersrand basin and the Bushveld Intrusion Complex appear as distinct blocks with an increased mantle density (3.34–3.35 g/cm³) with values typical of Proterozoic rather than Archean mantle. We attribute a significantly increased mantle density in these tectonic units and beneath the Archean Limpopo belt (3.34–3.37 g/cm³) to melt-metasomatism with an addition of a basaltic component. The Proterozoic Kheis, Okwa, and Namaqua–Natal belts and the Western Cape Fold Belt with the late Proterozoic basement have an overall fertile mantle (ca. 3.37 g/cm³) with local (100–300 km across) low-density (down to 3.34 g/cm³) and high-density (up to 3.41 g/cm³) anomalies. High (3.40–3.42 g/cm³) mantle densities beneath the Eastern Cape Fold belt require the presence of a significant amount of eclogite in the mantle, such as associated with subducted oceanic slabs.We find a strong correlation between the calculated density of the lithospheric mantle, the crustal structure, the spatial pattern of kimberlites, and their emplacement ages. (1) Blocks with the lowest values of mantle density (ca. 3.30 g/cm³) are not sampled by kimberlites and may represent the “pristine” Archean mantle. (2) Young (< 90 Ma) Group I kimberlites sample mantle with higher density (3.35 ± 0.03 g/cm³) than the older Group II kimberlites (3.33 ± 0.01 g/cm³), but the results may be biased by incomplete information on kimberlite ages. (3) Diamondiferous kimberlites are characteristic of regions with a low-density cratonic mantle (3.32–3.35 g/cm³), while non-diamondiferous kimberlites sample mantle with a broad range of density values. (4) Kimberlite-rich regions have a strong seismic velocity contrast at the Moho, thin crust (35–40 km) and low-density (3.32–3.33 g/cm³) mantle, while kimberlite-poor regions have a transitional Moho, thick crust (40–50 km), and denser mantle (3.34–3.36 g/cm³). We explain this pattern by a lithosphere-scale (presumably, pre-kimberlite) magmatic event in kimberlite-poor regions, which affected the Moho sharpness and the crustal thickness through magmatic underplating and modified the composition and rheology of the lithospheric mantle to make it unfavorable for consequent kimberlite eruptions. (5) Density anomalies in the lithospheric mantle show inverse correlation with seismic Vp, Vs velocities at 100–150 km depth. However, this correlation is weaker than reported in experimental studies and indicates that density-velocity relationship in the cratonic mantle is strongly non-unique.     

On the origin of saline fluids in the KTB (Continental Deep Drilling Project of Germany)

Highly saline fluids were encountered during the German Continental Deep Drilling Project (KTB) from depths ranging between 2 and 3 km to about 9 km. The most reliable data were obtained from samples extracted during a long-term pumping test in the 4000-m deep KTB pilot hole. Some 460 m³ Ca–Na–Cl brines with about 68 g l⁻¹ total dissolved solids (TDS) and some 270 m³ associated gases, mainly N₂ and CH₄ were pumped to the surface from the main fracture system situated near the bottom of the pilot hole. Geochemical and isotopic data support the hydraulic tests which suggest the presence of an open and large fluid reservoir at depth. The pumped fluids from this main fracture system were released from a deep reservoir situated at more than 5500 m depth which is hydraulically connected with the 9101 m deep KTB main hole, drilled some 250 m to the northeast of the pilot hole.While Ca and Sr contents of the extracted brines may be the result of water–rock interaction, Cl is most likely of external origin. The Cl is hypothesized to derive from geotectonic processes rather than to descending infiltration of paleo-seawater (evaporitic brines). The sampled fluids have probably migrated from a deeper reservoir to their present position since the Cretaceous–Tertiary period due to tectonic activity. However, several isotopic studies have identified an admixture of descending paleowaters down to more than 4000 m depth. The high ³⁶Cl/Cl ratio of the fluids sampled during the long-term pumping test point to a host rock highly enriched in U–Th, unlike the sampled KTB country rocks. The fluid reservoir is believed to be in contact with the Falkenberg granite massif situated about 2 km to the E of the KTB holes, capable of supplying sufficient neutron flux for considerable subsurface production of ³⁶Cl. The Na–Cl–(K-, SO₄) precursor fluids of the Ca–Na–Cl brines were produced in the course of extensive tectonic processes since the Late Caledonian within the Bohemian Massif.     

Burning peat and reworking loess contribute to the formation and evolution of a large Carolina-bay basin

Carolina bays are nearly ubiquitous along ~ 1300 km of the North American Atlantic Coastal Plain, but relatively few bays have been examined in detail, making their formation and evolution a topic of controversy. The Lake Mattamuskeet basin, eastern North Carolina, USA, is a conglomeration of multiple Carolina bays that form a > 162 km² lake. The eastern shoreline of the lake is made up of a 2.9-km-wide plain of parabolic ridges that recorded rapid shoreface progradation. The lower shoreface deposit contains abundant charcoal beds and laminae dated 6465–6863 cal yr BP, corresponding with initiation of a lacustrine environment in the eastern part of the lake. A core from the western part of the lake sampled a 1541–1633 cal yr BP charcoal bed at the base of the lacustrine unit, indicating formation of this part of the basin postdates the eastern basin. Lake Mattamuskeet has no relationship to the Younger Dryas or a linked impact event because rim accretion significantly postdates 12,000 cal yr BP. The shoreline progradation, and association of charcoal beds with the oldest lake sediment in both main parts of the basin, suggest that fire and subsequent hydrodynamic processes were associated with initial formation of these Carolina bays.     

Identification of contamination in a lake sediment core using Hg and Pb isotopic compositions,Lake Ballinger,Washington, USA

Concentrations and isotopic compositions of Hg and Pb were measured in a sediment core collected from Lake Ballinger, near Seattle, Washington, USA. Lake Ballinger has been affected by input of metal contaminants emitted from the Tacoma smelter, which operated from 1887 to 1986 and was located about 53 km south of the lake. Concentrations and loadings of Hg and Pb in Lake Ballinger increased by as much as three orders of magnitude during the period of smelting as compared to the pre-smelting period. Concentrations and loadings of Hg and Pb then decreased by about 55% and 75%, respectively, after smelting ended. Isotopic compositions of Hg changed considerably during the period of smelting (δ²⁰²Hg = −2.29‰ to −0.38‰, mean −1.23‰, n = 9) compared to the pre-smelting period (δ²⁰²Hg = −2.91‰ to −2.50‰, mean −2.75‰, n = 4). Variations were also observed in ²⁰⁶Pb/²⁰⁷Pb and ²⁰⁸Pb/²⁰⁷Pb isotopic compositions during these periods. Data for Δ¹⁹⁹Hg and Δ²⁰¹Hg indicate mass independent fractionation (MIF) of Hg isotopes in Lake Ballinger sediment during the smelting and post-smelting period and suggest MIF in the ore smelted, during the smelting process, or chemical modification at some point in the past. Negative values for Δ¹⁹⁹Hg and Δ²⁰¹Hg for the pre-smelting period are similar to those previously reported for soil, peat, and lichen, likely suggesting some component of atmospheric Hg. Variations in the concentrations and isotopic compositions of Hg and Pb were useful in tracing contaminant sources and the understanding of the depositional history of sedimentation in Lake Ballinger.     

Inhomogeneous lithospheric thinning in the central North China Craton: Zircon U–Pb and S–He–Ar isotopic record from magmatism and metallogeny in the Taihang Mountains

The large scale Mesozoic magmatism and related metallogeny in the Taihang Mountains (TM) provide important clues for the lithospheric thinning of the North China Craton (NCC). Among the ore deposits, the vein gold mineralization of Shihu in the Fuping region and the skarn ore deposit of Xishimen in the Wu'an region represent typical Mesozoic metallogeny in the TM. In the Shihu gold mine, the Mapeng batholith is dominantly composed of monzogranite and granodiorite, whereas, the Wu'an pluton in the Xishimen iron mine mainly comprises monzonite and diorite. Here we present zircon LA–ICP-MS U–Pb data from 8 samples which reveal the timing of magmatism in the TM as ca. 130 Ma, which is contemporaneous with the large-scale metallogeny in the margins of the NCC. The δ³⁴S values recorded in the sulfide minerals from the Shihu gold deposit and the Xishimen skarn iron deposit show a range of 2.2‰–5.0‰, and 11.6‰–18.7‰, respectively. Helium isotopic compositions of fluid inclusions in pyrite from the Shihu gold deposit vary from 0.12 to 1.98 Ra (where Ra is the ³He/⁴He ratio of air = 1.39 × 10^? 6), with calculated mantle helium values of 1.4%–25%, whereas, those of the Xishimen skarn iron deposit range from 0.06 to 0.19 Ra, with calculated mantle helium of 0.7%–2.2%. The S–He–Ar isotopic data suggest a lower crustal origin for the ore-forming components, with variable inputs of mantle source. The large population of inherited zircons in our samples, with ²⁰⁷Pb/²⁰⁶Pb ages ranging between 2500 Ma and 1800 Ma, also supports crustal participation. Our data reveal that the Shihu gold deposit witnessed greater mantle input than the Xishimen skarn iron deposit, suggesting that the continental lithosphere is markedly thinner under the Fuping region than that under the Wu'an region. Our interpretation is also supported by published data from two ultra-broadband high-precision magnetotelluric sounding profiles across the TM region showing a variation in the lithosphere thickness from 155 km to 70 km while moving from the south (Wu'an region) to the north (Fuping region). Our study suggests that inhomogeneous lithospheric thinning in the central NCC occurred at least as early as ca. 130 Ma ago.     

Glacial–interglacial productivity and environmental changes in Lake Biwa,Japan: A sediment core study of organic carbon,chlorins and biomarkers

Temporal changes in paleoproductivity of Lake Biwa (Japan) over the past 32 kyr have been studied by analyzing bulk organic carbon and photosynthetic pigments (chlorins) in the BIW95-5 core. Primary productivity was estimated on the assumption of C/N_org values of 8 for autochthonous organic matter (OM) and 25 for allochthonous OM and using an equation developed for the marine environment. The estimate indicates that primary productivity ranges from 50 to 90 g C m^?2 yr^?1 in the Holocene, while it is ～60 g C m^?2 yr^?1 on average in the last glacial. Pheophytin a and pheophorbide a are the major chlorins. A downcore profile of chlorin concentration normalized to autochthonous organic carbon (OC) shows a decreasing trend. Chlorin productivity was corrected by removal of the effect of post-burial chlorin degradation. The temporal profile of chlorin productivity thereby obtained resembles that from autochthonous OC.The difference in primary productivity between the Holocene and the glacial for the lake is markedly smaller than that for Lake Baikal situated in the boreal zone. This difference between the two lakes is probably caused by the difference in their climatic conditions, such as temperature and precipitation. Precipitation at Lake Biwa is relatively large during the glacial and the Holocene because of the continuous influence of the East Asian monsoon. Lake Baikal precipitation is generally small as a result of control by the continental (Siberia) climate regime. In addition, a significant difference in productivity between the glacial and the Holocene for Lake Baikal may be essentially controlled by the hydrodynamic systems in the lake.Lake Biwa terrigenous OM input events occurred at least five times over the period 11–32 kyr BP, suggesting enhanced monsoon activity. Molecular examination of the layer with a large input of terrigenous OM during the Younger Dryas indicates that concentrations of terrigenous biomarkers such as n-C₂₇–C₃₁ alkanes, lignin phenols, cutin acids, ω-hydroxy acids and C₂₉ sterols are high, suggesting that soil OM with peat-like material entered the lake as a result of flooding. An enhanced sedimentation rate in the last 3000 years might have been partially caused by agricultural activity around the lake.     

High-altitude varve records of abrupt environmental changes and mining activity over the last 4000 years in the Western French Alps (Lake Bramant,Grandes Rousses Massif)

Two twin short gravity cores and a long piston core recovered from the deepest part of proglacial Lake Bramant (Grandes Rousses Massif, French Alps), under and overlying a large slump identified by high-resolution seismic profile, allow the investigation of Holocene natural hazards and interactions between human activity and climatic changes at high-altitude. Annual sedimentation throughout the cores (glacial varves) is identified on photographs, ITRAX (high-resolution continuous microfluorescence-X) and CAT-Scan (computerized axial tomography) analyses and is supported by (1) the number of dark and light laminations between dates obtained by radionuclide measurements (¹³⁷Cs, ²⁴¹Am), (2) the correlation of a slump triggered by the nearby AD 1881 Allemond earthquake (MSK intensity VII) and of a turbidite triggered by the AD 1822 Chautagne regional earthquake (MSK intensity VIII), (3) the number of laminations between two accelerator mass spectrometry (AMS) ¹⁴C dates, and (4) archaeological data. In Lake Bramant, dark layers are coarser, contain less detrital elements, but more neoformed elements and organic matter content. These darker laminations result from calm background sedimentation, whereas the lighter layers are finer and rich in detrital elements and reflect the summer snowmelt. Traces of mining activity during the Roman civilization apogee (AD 115–330) and during the Early Bronze Age (3770–3870 cal BP) are recorded by lead and copper content in the sediments and probably result from regional and local mining activity in the NW Alps. Warmer climate during the Bronze Age in this part of the Alps is suggested by (1) two organic deposits (4160–3600 cal BP and 3300–2850 cal BP) likely reflecting a lower lake level and smaller glaciers and (2) evidence of a different vegetation cover around 2500 m a.s.l. The onset of clastic proglacial sedimentation between 3600–3300 cal BP and since 2850 cal BP is synchronous with periods of glacier advances documented in the Alps and high-lake levels in west-central Europe. This major change in proglacial sedimentation highlights the development of a larger St. Sorlin glacier in the catchment area of Lake Bramant.     

Crustal shear-wave velocity structure beneath northeast India from teleseismic receiver function analysis

We investigated the seismic shear-wave velocity structure of the crust beneath nine broadband seismological stations of the Shillong–Mikir plateau and its adjoining region using teleseismic P-wave receiver function analysis. The inverted shear wave velocity models show ∼34–38 km thick crust beneath the Shillong Plateau which increases to ∼37–38 km beneath the Brahmaputra valley and ∼46–48 km beneath the Himalayan foredeep region. The gradual increase of crustal thickness from the Shillong Plateau to Himalayan foredeep region is consistent with the underthrusting of Indian Plate beyond the surface collision boundary. A strong azimuthal variation is observed beneath SHL station. The modeling of receiver functions of teleseismic earthquakes arriving the SHL station from NE backazimuth (BAZ) shows a high velocity zone within depth range 2–8 km along with a low velocity zone within ∼8–13 km. In contrast, inversion of receiver functions from SE BAZ shows high velocity zone in the upper crust within depth range ∼10–18 km and low velocity zone within ∼18–36 km. The critical examination of ray piercing points at the depth of Moho shows that the rays from SE BAZ pierce mostly the southeast part of the plateau near Dauki fault zone. This observation suggests the effect of underthrusting Bengal sediments and the underlying oceanic crust in the south of the plateau facilitated by the EW-NE striking Dauki fault dipping 30⁰ toward northwest.     

Crustal structure of the Gujarat region,India: New constraints from the analysis of teleseismic receiver functions

In this study, receiver function analysis is carried out at 32 broadband stations spread all over the Gujarat region, located in the western part of India to image the sedimentary structure and investigate the crustal composition for the entire region. The powerful Genetic Algorithm technique is applied to the receiver functions to derive S-velocity structure beneath each site. A detail image in terms of basement depths and Moho thickness for the entire Gujarat region is obtained for the first time. Gujarat comprises of three distinct regions: Kachchh, Saurashtra and Mainland. In Kachchh region, depth of the basement varies from around 1.5 km in the eastern part to 6 km in the western part and around 2–3 km in the northern part to 4–5 km in the southern part. In the Saurashtra region, there is not much variation in the depth of the basement and is between 3 km and 4 km. In Gujarat mainland part, the basement depth is 5–8 km in the Cambay basin and western edge of Narmada basin. In other parts of the mainland, it is 3–4 km. The depth of Moho beneath each site is obtained using stacking algorithm approach. The Moho is at shallower depth (26–30 km) in the western part of Kachchh region. In the eastern part and epicentral zone of the 2001 Bhuj earthquake, large variation in the Moho depths is noticed (36–46 km). In the Saurashtra region, the crust is more thick in the northern part. It varies from 36–38 km in the southern part to 42–44 km in the northern part. In the mainland region, the crust is more thick (40–44 km) in the northern and southern part and is shallow in Cambay and Narmada basins (32–36 km). The large variations of Poisson’s ratio across Gujarat region may be interpreted as heterogeneity in crustal composition. High values of σ (∼0.30) at many sites in Kachchh and few sites in Saurashtra and Mainland regions may be related to the existence of high-velocity lower crust with a mafic/ultramafic composition and, locally, to the presence of partial melt. The existing tectono-sedimentary models proposed by various researchers were also examined.     

Abrupt spatial and geochemical changes in lamprophyre magmatism related to Gondwana fragmentation prior,during and after opening of the Tasman Sea

High-precision ⁴⁰Ar/³⁹Ar dating of lamprophyre dike swarms in the Western Province of New Zealand reveals that these dikes were emplaced into continental crust prior to, during and after opening of the Tasman Sea between Australia and New Zealand. Dike ages form distinct clusters concentrated in different areas. The oldest magmatism, 102–100 Ma, is concentrated in the South Westland region that represents the furthest inboard portion of New Zealand in a Gondwana setting. A later pulse of magmatism from ~ 92 Ma to ~ 84 Ma, concentrated in North Westland, ended when the first oceanic crust formed at the inception of opening of the Tasman Sea. Magmatic quiescence followed until ~ 72–68 Ma, when another swarm of dikes was emplaced. The composition of the dikes reveals a dramatic change in primary melt sources while continental extension and lithospheric thinning were ongoing. The 102–100 Ma South Westland dikes represent the last mafic calc-alkaline magmatism associated with a long-lived history of the area as Gondwana's active margin. The 92–84 Ma North and 72–68 Ma Central Westland dike swarms on the other hand have strongly alkaline compositions interpreted as melts from an intraplate source. These dikes represent the oldest Western Province representatives of alkaline magmatism in the greater New Zealand region that peaked in activity during the Cenozoic and has remained active up to the present day. Cretaceous alkaline dikes were emplaced parallel to predicted normal faults associated with dextral shear along the Alpine Fault. Furthermore, they temporally correspond to polyphase Cretaceous metamorphism of the once distal Alpine Schist. Dike emplacement and distal metamorphism could have been linked by a precursor to the Alpine Fault. Dike emplacement in the Western Province coupled to metamorphism of the Alpine Schist at 72–68 Ma indicates a period of possible reactivation of this proto Alpine Fault before it served as a zone of weakness during the opening of the oceanic Emerald Basin (at ~ 45 Ma) and eventually the formation of the present-day plate boundary (~ 25 Ma–recent).     

Silver-base metal epithermal vein and listwanite hosted deposit Crnac,Rogozna Mts., Kosovo,part II: A link between magmatic rocks and epithermal mineralization

Crnac is an intermediate sulfidation Pb–Zn–Ag epithermal deposit located within the Vardar suture zone of the Central Balkan Peninsula. The epithermal Pb–Zn–Ag mineralization consists of (i) a series of steeply-dipping veins hosted within the Jurassic amphibolites, and (ii) overlying hydrothermal-explosive breccia with angular (level IV) or rounded fragments of listwanite (surface) cemented by epithermal mineralization. The mineralization is related to the Oligocene quartz latite dykes that crosscut the Crnac antiform. Quartz latite rocks predominantly display a shoshonitic character. The obtained ⁴⁰Ar/³⁹Ar age of fresh quartz latite is 28.9 ± 0.3 Ma. Fine-grained sericite from altered quartz latite is dated at 28.6 ± 0.5 Ma. Early, alteration related fluid inclusions within quartz latite show coexistence of high-density brine and a low-density vapor-saturated phase that homogenized at 280–405 °C. Phase separation occurs at a paleodepth of 0.6 to 0.9 km.Epithermal mineralization developed in three stages: (i) early pyrite–arsenopyrite–pyrrhotite–quartz–kaolinite; (ii) main sphalerite–galena–tetrahedrite–chalcopyrite and (iii) late carbonate–pyrite–arsenopyrite assemblage. The onset of mineral deposition within epithermal veins was initiated by boiling of Na–Cl ± K ± Ca ± Mg fluid at a paleodepth of 0.6 to 0.9 km. Coexisting vapor and liquid-rich inclusions display salinities and trapping temperatures of 4 wt.% NaCl equiv., 280–370 °C and 2–27 wt.% NaCl equiv., 230–375 °C, respectively. Boiling continued throughout the deposition of the sphalerite-galena-tetrahedrite-chalcopyrite assemblage. Late stage carbonate was deposited from diluted, non-boiling, low-temperature Na–Ca–Mg–Cl ± CO₂ fluid (0.2 to 4.8 wt.% NaCl equiv., 115–280 °C).About 100–150 m higher in the system, precipitation of listwanite breccia cement began as a result of boiling Na–Cl ± Ca ± Mg ± K fluid of medium salinities (2.6 to 12.1 wt.% NaCl equiv.) at temperatures of 245–370 °C. Boiling and dilution of fluids continue throughout the precipitation of the main sphalerite-galena-tetrahedrite and late, mainly carbonate assemblage. Surface listwanite breccia contain quartz phenocrysts deposited from a homogeneous fluid with a medium salinity (8–10 wt.% NaCl equiv.) and high temperatures (T_h = 295–315 °C), whereas the early and main stage of a surface listwanite breccia cement precipitated from a boiling fluid of decreasing salinity and temperature. Aqueous ± CO₂, high salinity (16 to 18 wt.% NaCl equiv.), low temperature (120 °C), homogeneously trapped fluid that precipitated late stage carbonates, is most likely a remnant of boiled off fluid. The epithermal assemblage of the surface listwanites precipitated at a paleodepth of 0.4 to 0.6 km.The δ¹³C values of the late stage ankerite range from − 4.2 to 4.1‰, whereas δ¹⁸O range from 9.6 to 17.5‰. The calculated δ¹⁸O of fluid that precipitated carbonates within epithermal veins, and listwanite breccia cement range from 6.3 to 11.3‰, indicating a contribution of magmatic water.Deposition of all mineralization types was initiated by neutralization of primary acidic magmatic fluid by water-rock reactions that caused widespread propylitization and sericitization. Extensive and long-lasting boiling combined with dilution by meteoric water increased the pH towards the final stage of hydrothermal activity.