南岭早侏罗世稀有金属成矿作用研究——以闽西南大坪花岗斑岩为例

华南地区是我国重要的稀有金属矿产区,绝大部分具经济规模的稀有金属矿床均与高演化的富Li-F花岗岩有成因联系。大坪花岗斑岩位于南岭构造带最东缘福建省永定地区,与区内Nb-Ta矿床形成有关。该岩体SIMS和LA-ICP-MS锆石U-Pb定年结果分别为186.7±1.2Ma和190.7±1.1Ma,是华南少见的早侏罗世(200~180Ma)侵入的花岗岩侵入体,也是华南最早报道的早侏罗世稀有金属成矿事件。大坪花岗斑岩具高钾低镁、准铝质到弱过铝质的特征,属于高钾钙碱性花岗岩,并显示A型花岗岩的地球化学特征,如富硅(72.81%~76.44%)、高10000×Ga/Al比值、高FeO^T/MgO和高的Zr+Nb+Ce+Y含量、亏损高场强元素和Eu负异常明显等。全岩体系低的Zr/Hf、Nb/Ta比值,指示岩浆具有较高的分异演化程度,Nb 2 O 5和Ta 2 O 5均含量达到了花岗岩型稀有金属矿床的工业品位。花岗斑岩中锆石Hf-O同位素分析结果显示,其具有比较亏损的Hf同位素与比较均一的O同为素组成(εHf(t)=-2.4~3.4,δ^18 O=6.0‰~6.6‰)。结合微量元素地球化学特征,大坪花岗斑岩源区主要来源于软流圈地幔,并有约20%~30%壳源岩浆的加入,在成岩过程中发生了显著的分离结晶。晚期富氟的流体出熔并向上迁移可能对于Nb和Ta的再次富集与分异具有重要作用。大坪花岗斑岩与闽西南地区同时期的火山岩,如藩坑组双峰式火山岩,在空间上可与前人提出的“南岭山脉早侏罗世发育的东西向裂谷岩浆岩带(OIB型玄武岩、辉长岩和A型花岗岩组合)”相对应,是该裂谷带向东的延伸。     

班—怒成矿带西段躬穷左波Fe-Cu矿区侵入岩年代学及地球化学特征

本文对躬穷左波Fe-Cu矿区出露的三套酸性侵入岩进行了系统的LA-ICP-MS锆石U-Pb年代学和岩石地球化学研究。年代学测试结果显示花岗斑岩、二长花岗斑岩和钾长花岗岩~(206)Pb/238U加权平均年龄分别为147.0 Ma、143.6 Ma和142.8 Ma,矿区存在晚侏罗世—早白垩世存在3期岩浆事件。岩石地球化学组成特征显示,花岗斑岩属准铝质-弱过铝质I型花岗岩;二长花岗斑岩为高钾钙碱性系列,属弱过铝质I型花岗岩;钾长花岗岩经历了强烈的结晶分异作用,属高分异I型花岗岩。岩石微量元素富集Rb、Th、U、Pb而亏损Nb、Ta、Ti、P元素,Nb/Ta比值接近大陆地壳组成及锆石负的εHf(t)值特征,指示成岩物质以壳源物质为主。躬穷左波晚侏罗世矽卡岩型Fe-Cu矿化事件的发现对于完善班—怒带西段成矿规律和指导区域找矿工作具有重要意义。     

南岭龙源坝复式岩体的地球化学特征研究

龙源坝复式岩体是南岭花岗岩带的重要组成部分,曾被作为其东侧燕山期陂头岩体的组成部分。最新研究表明,岩体的主体形成于印支期,在时代和成因上明显不同于陂头岩体。该印支期花岗岩与燕山期花岗岩和燕山期正长岩在主要氧化物成分上存在显著差别,暗示它们可能不存在结晶分异的演化关系。在微量元素特征上,印支期花岗岩稀土元素总量较高,富集轻稀土元素;燕山期花岗岩的稀土元素含量低,亏损中稀土,Th/U、Nb/Ta和Zr/Hf比值小,分馏明显,暗示岩浆作用过程中流体作用比较强烈;燕山期正长岩以富集高场强元素和稀土元素为特征,类似于A型花岗岩。锶、钕同位素地球化学特征表明,龙源坝复式岩体属于壳源S型花岗岩,起源于早元古代壳-幔分异产生的地壳。     

再论南岭侏罗纪“铝质”A型花岗岩的成因及其对古地温线的制约

对南岭地区侏罗纪4个典型"铝质"A型花岗岩岩基——柯树北、寨背、西山和南昆山的成因分析表明:柯树北、寨背岩基中的低分异花岗岩SiO2≈70%,A/CNK<1.1,CaO≥1%,高Zr、Ba含量,是下地壳部分熔融产物;而SiO2含量较高者由低分异花岗岩岩浆通过分离结晶演化而来。西山花岗质火山-侵入杂岩也是下地壳部分熔融产物。南昆山花岗岩为高硅花岗岩,贫Zr、低Ba、Sr和Eu/Eu*值,但具有高的Nb、Ga、REE含量和Ga/Al比值,在Whalen等(1987)图解中地球化学参数落在A型花岗岩区域内。碱性玄武岩浆分离结晶的成岩模式无法解释南昆山岩基较大的体积、均一的成分和低的Nb/Ta比值。详细的成岩分析表明,南昆山花岗岩可能是先期侵入的(幔源)碱性正长岩在富水和相对低温低压条件下发生部分熔融的产物。由这些"铝质"A型花岗岩的熔融温压条件估算得出热流值达到80~95mWm-2的南岭地区侏罗纪古地温线。由古地温线推算出的岩石圈厚度45~75km。南岭侏罗纪高热流背景及其对应的花岗质岩浆活动可能与后碰撞造山阶段岩石圈地幔拆沉或被"热侵蚀"有关,但并不一定意味着岩石圈伸展的大地构造环境。     

湖南仁里稀有金属矿田206号锂辉石伟晶岩脉地球化学特征及成矿时代

湖南仁里稀有金属矿田是中国近年来新发现的一处重要的花岗伟晶岩型铌、钽、锂等稀有金属矿产地,文章针对矿田含锂伟晶岩地球化学特征、成矿时代及其与花岗岩的关系,选取传梓源锂铌钽矿床内规模最大的206号锂辉石伟晶岩脉开展地球化学和白云母Ar-Ar定年工作,并与区内其他伟晶岩、花岗岩的地球化学特征、成岩时代对比分析.传梓源206号锂辉石伟晶岩属高分异稀有金属伟晶岩,形成时代为(135.4±1.4)Ma,岩石地球化学表现为高硅、高铝、低钙、相对富碱、钙碱性及过铝质特征;稀土元素总量很低,以轻稀土元素为主;微量元素富集Cs、Rb、U、Ta、Nb、Zr、Hf,相对亏损Ba、Ti,Zr/Hf、Nb/Ta比值低且集中.幕阜山地区稀有金属成矿可分为2期:第1期稀有金属成矿时代约145 Ma,与燕山早期岩浆活动有关;第2期稀有金属成矿时代135～125 Ma,为主成矿期,该期稀有金属伟晶岩与燕山晚期的二云母二长花岗岩存在成因联系,两者为同源岩浆连续结晶分异过程中不同阶段的产物.稀有金属富集成矿经历了岩浆-热液两阶段作用,Be、Nb、Ta、Li、Rb、Cs等稀有元素的富集多发生于岩浆结晶分异晚期,热液作用使Ta、Li、Rb、Cs再次富集.     

南岭侏罗纪花岗岩成因类型的厘定及其成矿意义

对中国东南部南岭地区出露的侏罗纪(燕山早期)花岗岩成因类型至今仍有不同认识.李献华等(2007)将南岭侏罗纪花岗岩的成因类型划分为:①铝质A型花岗岩;②型花岗岩;③分异Ⅰ型花岗岩.认为南岭广泛出露的含角闪石花岗闪长岩、黑云母花岗岩和二(白)云母花岗岩组成准铝质-弱过铝质的Ⅰ型/分异Ⅰ型花岗岩成因演化系列.     

粤北佛冈岩体中粒斑状花岗岩地球化学、年代学及地质意义

佛冈岩体是南岭地区最大的复式岩基,主体岩性为中粒斑状黑云母二长花岗岩,近期在佛冈岩体北缘新发现了大型离子吸附型稀土矿床。对佛冈花岗岩岩石样品进行了LA-ICP-MS锆石U-Pb定年,得出结晶年龄分别为160.5±2.9Ma、161.9±2.6Ma和164.5±2.4Ma,表明岩体形成于中晚侏罗世。岩体具有高硅、富碱富铝的特征(K2O/Na2O=1.48~2.17,A/CNK=1.05~1.27),属钙碱性过铝质钾玄质花岗岩;富集Rb、Th、U、K、Pb、Nd、Zr和Hf等元素,亏损Ba、Nb、Ta、La、Ce、Sr、P和Ti等元素,具明显的负Eu异常(δEu=0.17~0.41)。初步研究结果表明,佛冈岩体主体由上地壳砂-泥质岩在高温条件下部分熔融而成,是陆壳改造型(即S型)花岗岩,形成于古太平洋板块向欧亚板块俯冲的构造背景。     

福建河田高分异花岗岩的矿物和全岩地球化学找矿标志研究

我国的华南地区是一个钨、锡、钼、铋、铀、铌钽、铅锌、稀有、稀土多金属成矿区。近年来,高精度年代学数据表明上述矿产集中爆发形成于晚侏罗世的165~150Ma。野外和实验证据表明,花岗岩可以划分为高分异花岗岩、低分异花岗岩和未分异花岗岩。从目前的研究结果来看,钨、锡、铌钽、锂、铍等成矿作用都与高分异花岗岩密切相关。建立与这些矿产有关高分异花岗岩的普适性的矿物学、矿物地球化学和全岩地球化学的指标,有助于判断植被覆盖严重和风化严重地区、数据积累较少的岩体的成矿潜力。位于福建省长汀县境内的河田花岗岩体新鲜露头少,大部分岩体都掩盖在厚厚的风化层下,且植被覆盖严重,但是该岩体中已发现多处锡、钨、铅锌矿(化)点。本研究发现,该岩体的锆石U-Pb年龄、石榴子石和全岩地球化学特征与江西西华山第二期成矿花岗岩具有高度相似性,因此推断河田岩体可能具有成钨锡多金属(超)大型矿的成矿潜力。此外,当花岗岩向高分异阶段不断演化的过程中,某些元素比值(例如Rb/Sr、Zr/Hf和Nb/Ta)可以作为衡量岩浆的结晶分异程度的参数;西华山和河田花岗岩在达到熔体-流体相互作用阶段时,全岩Zr含量和Zr/Hf比值大概在Zr=50×10-6和Zr/Hf=15处发生转折。同时,与不成矿花岗岩中的石榴子石相比,成矿花岗岩中石榴子石的Sn、Y和Yb元素含量明显升高,可达2~10倍,因此,高分异花岗岩的石榴子石的微量元素特征可能是重要的找矿标志之一。     

小兴安岭二龙山林场堆晶辉长岩地球化学特征及构造环境

小兴安岭北部二龙山林场辉长岩的主量、微量和稀土元素的测试分析结果显示: 二龙山辉长岩为钙碱性系列、偏铝质岩石; δEu 正异常,Sr 元素含量富集明显,具有堆晶辉长岩特征; Rb /Sr、Nb / Ta、LILE/HFSE、Th /Ta、Nb /U 和Nb /La 比值特征均显示,辉长岩岩浆来自受到俯冲流体交代的地幔源区。Nb /Zr、Th /Nb、Th /Ta 和Ta /Hf 比值特征及对Th /Hf --Ta /Hf 构造环境判别图解投点表明,二龙山辉长岩形成于陆内拉张环境。     

滇西北休瓦促Mo-W矿区印支晚期和燕山晚期岩浆活动与成矿作用:来自锆石U-Pb年代学和地球化学的证据

本文首次在格咱岛弧休瓦促Mo-W矿区识别出印支晚期似斑状黑云母花岗岩,并确定其结晶年龄为200.93±0.65Ma,同时获得燕山晚期二长花岗岩结晶年龄83.57±0.32Ma;即首次在休瓦促Mo-W矿区内厘定出印支晚期和燕山晚期两期花岗岩浆叠加活动,而Mo-W成矿作用与燕山晚期二长花岗岩具有成因关系。岩石地球化学显示燕山晚期二长花岗岩具有较高的SiO_2和全碱含量及较低的Fe、Mg、Ca和P含量,呈准铝质-弱过铝质;富集Rb、Th、U、Nb、Zr和轻稀土元素,亏损Ba、Sr、P、Eu,具有高分异I型花岗岩特征;其形成于与拉萨-羌塘板块碰撞相关的陆内伸展环境,主要来自中-基性下地壳物质的部分熔融,为Mo-W成矿作用提供了重要的物质基础。相对于二长花岗岩,印支晚期似斑状黑云母花岗岩具有较低的SiO_2、Na_2O+K_2O含量和A/CNK比值,较高的Mg、Ca和P含量;富集Th、U、Rb和轻稀土元素,强烈亏损Nb、Ta、Zr、Hf等高场强元素,为准铝质高钾钙碱性具有岛弧岩浆性质的花岗岩,可能形成于甘孜-理塘洋壳俯冲作用结束后,松潘-甘孜地块和义敦岛弧碰撞后伸展环境,为俯冲期改造后形成的下地壳部分熔融的产物。     

Neoproterozoic A-type granitoids of the central and southern Appalachians: intraplate magmatism associated with episodic rifting of the Rodinian supercontinent

Emplacement of compositionally distinctive granitic plutons accompanied two pulses (765–680 and 620–550 Ma) of crustal extension that affected the Rodinian craton at the present location of the central Appalachians during the Neoproterozoic. The dominantly metaluminous plutons display mineralogical and geochemical characteristics of A-type granites including high FeO_t/MgO ratios, high abundances of Nb, Zr, Y, Ta, and REE (except Eu), and low concentrations of Sc, Ba, Sr, and Eu. These dike-like, sheet complexes occur throughout the Blue Ridge province of Virginia and North Carolina, and were emplaced at shallow levels in continental crust during active extension, forming locally multiple-intrusive plutons elongated perpendicular to the axis of extension. New U–Pb zircon ages obtained from the Polly Wright Cove (706±4 Ma) and Suck Mountain (680±4 Ma) plutons indicate that metaluminous magmas continued to be replenished near the end of the first pulse of rifting. The Suck Mountain body is presently the youngest known igneous body associated with earlier rifting. U–Pb zircon ages for the Pound Ridge Granite Gneiss (562±5 Ma) and Yonkers Gneiss (563±2 Ma) in the Manhattan prong of southeastern New York constitute the first evidence of plutonic felsic activity associated with the later period of rifting in the U.S. Appalachians, and suggest that similar melt-generation processes were operative during both intervals of crustal extension. Fractionation processes involving primary minerals were responsible for much of the compositional variation within individual plutons. Compositions of mapped lithologic units in a subset of plutons studied in detail define overlapping data arrays, indicating that, throughout the province, similar petrologic processes operated locally on magmas that became successively more chemically evolved. Limited variation in source-sensitive Y/Nb and Yb/Ta ratios is consistent with results of melting experiments and indicates that metaluminous granitoids of the supersuite likely were derived through melting of lower crustal sources. Mildly peralkaline rocks of the Robertson River batholith and Irish Creek pluton may be derived from more chemically primitive sources similar in composition to ocean–island basalts. Blue Ridge granitoids define a plutonic episode that occurred during an unsuccessful pulse of crustal extension which predated opening of Iapetus by more than 100 million years. Granitoid gneisses in New York were emplaced during an extension-related, dominantly mafic magmatic episode that ultimately led to development of Iapetus.     

The earliest Jurassic A-type granite in the Nanling Range of southeastern South China: petrogenesis and geological implications

The tectonic transition from the palaeo-Tethyan to palaeo-Pacific dynamic domains in the South China Block (SCB) is still a matter of debate. The A-type granites collected from the southeastern SCB offered an opportunity to illustrate this tectonic transition. This article records a set of petrographic, geochronological, and geochemical data for the Wengong granitic pluton from the eastern Nanling Range. LA-ICP-MS zircon U–Pb dating shows a crystallization age of 196.9 ± 4.4 Ma with ε_Hf(t) values ranging from +2.1 to +7.7. The samples have high SiO₂, Zr+Nb+Ce+Y, FeOt/MgO, Ga/Al, and Y/Nb and are depleted in Nb–Ta, Zr–Hf, Ba, Sr, Ti, and Eu, similar to those of the A₂-type granite. Their initial ⁸⁷Sr/⁸⁶Sr ratios range from 0.70885 to 0.70983 and the ε_Nd(t) values range from ?2.9 to ?1.1, close to those of the Early Palaeozoic mafic rocks in the southeastern SCB. The Wengong A₂-type granite was derived from partial melting of the mafic rocks underplated into the lower crust during the Early Palaeozoic.

The Mesozoic A-type granites in the southeastern SCB can be subdivided into 229–215 Ma (Late Triassic), 197–152 Ma (Jurassic), and 135–92 Ma (Cretaceous). They differ in geochemical and spatial distribution characteristics. The Late Triassic A-type granites were formed in the post-collision extensional setting associated with the palaeo-Tethyan dynamic domain, whereas the Cretaceous A-type granites were under the control of the palaeo-Pacific dynamic domain. The A-type granites were hardly exposed during the Late Triassic–Early Jurassic and Late Jurassic–Early Cretaceous. The Jurassic A-type granites were formed in the intra-plate extensional setting, a response to the tectonic transition from the palaeo-Tethyan to palaeo-Pacific dynamic domains. Thus, the occurrence of the Wengong A₂-type granite indicates that this tectonic transition possibly initiated at the earliest Early Jurassic.     

Shrimp U–Pb zircon geochronology,geochemistry, and Nd–Sr isotopic study of contrasting granites in the Emeishan large igneous province,SW China

The Cida A-type granitic stock (∼ 4 km²) and Ailanghe I-type granite batholith (∼ 100 km²) in the Pan-Xi (Panzhihua-Xichang) area, SW China, are two important examples of granites formed during an episode of magmatism associated with the Permian Emeishan mantle plume activity. This is a classic setting of plume-related, anorogenic magmatism exhibiting the typical association of mantle-derived mafic and alkaline rocks along with silicic units. SHRIMP zircon U–Pb data reveal that the Cida granitic pluton (261 ± 4 Ma) was emplaced shortly before the Ailanghe granites (251 ± 6 Ma). The Cida granitoids display mineralogical and geochemical characteristics of A-type granites including high FeO^⁎/MgO ratios, elevated high-field-strength elements (HFSE) contents and high Ga/Al ratios, which are much higher than those of the Ailanghe granites. All the granitic rocks show significant negative Eu anomalies and demonstrate the characteristic negative anomalies in Ba, Sr, and Ti in the spidergrams. It can be concluded that the Cida granitic rocks are highly fractionated A-type granitoids whereas the Ailanghe granitic rocks belong to highly evolved I-type granites.The Cida granitoids and enclaves have Nd and Sr isotopic initial ratios (ε_Nd(t) = − 0.25 to + 1.35 and (⁸⁷Sr/⁸⁶Sr)_i = 0.7023 to 0.7053) close to those of the associated mafic intrusions and Emeishan basalts, indicating the involvement of a major mantle plume component. The Ailanghe granites exhibit prominent negative Nb and Ta anomalies and weakly positive Pb anomalies in the spidergram and have nonradiogenic ε_Nd(t) ratios (− 6.34 to − 6.26) and high (⁸⁷Sr/⁸⁶Sr)_i values (0.7102 to 0.7111), which indicate a significant contribution from crustal material. These observations combined with geochemical modeling suggest that the Cida A-type granitoids were produced by extensive fractional crystallization from basaltic parental magmas. In contrast, the Ailanghe I-type granites most probably originated by partial melting of the mid-upper crustal, metasedimentary–metavolcanic rocks from the Paleo-Mesoproterozoic Huili group and newly underplated basaltic rocks.In the present study, it is proposed that petrogenetic distinctions between A-type and I-type granites may not be as clear-cut as previously supposed, and that many compositional and genetically different granites of the A- and I-types can be produced in the plume-related setting. Their ultimate nature depends more importantly on the type and proportion of mantle and crustal material involved and melting conditions. Significant melt production and possible underplating and/or intrusion into the lower crust, may play an important role in generating the juvenile mafic lower crust (average 20 km) in the central part of the Emeishan mantle plume.     

Late Jurassic granitoids in the Xilamulun Mo belt,Northeastern China: geochronology,geochemistry, and tectonic implications

ABSTRACT

The Xilamulun Mo belt of Northeastern China, located in the southeastern segment of the Central Asia Orogenic Belt (CAOB), is composed of large deposits of porphyry Mo and quartz-vein-type Mo, which are related to Mesozoic granitoids. Previous studies led to the conclusion that all granitoids in the region formed during the Cretaceous and Triassic, but our new laser ablation inductively coupled plasma mass spectrometry U–Pb zircon dating of magmatic zircons from five samples of four mineralized plutons (Nailingou, Longtoushan, and Hashitu granites and Erbadi and Hashitu granite porphyries) reveals that these range in age from 143.8 ± 1.2 to 149.5 ± 1.0 Ma. These granites show post-collisional (A-type) geochemical characteristics (e.g. enrichment in total alkali, LILE, and LREE and depletion in Eu, Ba, P, and Nb). The Erbadi, Longtoushan, Hashitu, and Longtoushan granitoids exhibit moderately positive Hf isotopic compositions (ε_Hf(t) = ?0.3 to 10.2), indicating that granitic magmas may reflect mixtures of mantle melts and continental crust. These mineralized granites were all emplaced along a major fault over a time span of ~6 million years during the Late Jurassic. We conclude that igneous activity and mineralization resulted from the rollback of the subducted Palaeo-Pacific plate beneath Eurasia. Confirming that the Late Jurassic granitic intrusives are related to the Mo mineralization is useful for understanding the Mesozoic tectonic evolution of the Xilamulun Mo belt and also has significant implications for the regional exploration of ores.     

藏南冈底斯岩基日多地区花岗岩体形成时代和地球化学特征

冈底斯岩基广泛发育三叠纪-中新世的岩浆岩,是研究与新特提斯洋北向俯冲和印度-欧亚大陆碰撞相关的构造岩浆作用特征的天然实验室。日多地区花岗岩体位于藏南墨竹工卡县东侧日多乡附近,其主体为花岗岩,被花岗闪长玢岩脉侵入。锆石U-Pb地质年代学表明:主体花岗岩形成于62.7±0.5Ma,侵入其中的花岗闪长玢岩脉形成于59.5±1.5Ma,并捕获了大量的侏罗纪岩浆岩锆石(155.4±1.8Ma)。日多地区花岗岩体的全岩地球化学特征为:(1)高Si O_2、Na_2O、Al_2O_3,低Fe O~T、MgO、Ti O_2;(2)富集轻稀土(LREE),亏损重稀土(HREE)及高场强元素Nb、Ta、Ti、P元素;(3)具有Eu负异常,总体显示高钾钙碱性、过铝质花岗岩和岛弧型岩浆岩特征。锆石Hf同位素特征暗示其岩浆源区为基性下地壳物质。花岗闪长玢岩脉裹挟大量侏罗纪岩浆型锆石,表明冈底斯岩基拉萨以东地区可能经历了较广泛的晚侏罗世岩浆作用。     

Tetrad effect in rare earth element distribution patterns: Evidence from the Paleozoic granitoids of the Oka zone,Eastern Sayan

The tetrad effect is a systematic change in REE properties, which is expressed as a split of a normalized REE pattern into four rounded segments (tetrads) and caused by the formation of complex compounds. It was identified in the granitoids of the Oka zone of the Eastern Sayan by ICP determination of REE contents. The granitoids have a high F content, a prominent negative Eu anomaly, and a low K/Rb ratio. An increase in the tetrad effect in the granitoids correlates with increasing Nb/Zr, Y/Ho, and Rb/Sr ratios and SiO₂ contents and decreasing Zr/Hf, Ce/Pb, La/Sm, and La/Ta ratios and the contents of Fe₂O₃ and Na₂O. In terms of correlation of the tetrad effect with the Y/Ho, Zr/Hf, and K/Rb ratios, the Li-F and alkali rare metal granitoids of the Oka zone are correlated with, respectively, the granitoids of the northern and northwestern part of the Bohemian Massif, eastern Germany, and the Baerzhe Massif, northeastern China.     

The Geochemical and Zircon Trace Elements Characteristics of A-type Granitoids in Boziguoer,Baicheng County,Xinjiang

The Boziguoer A-type granitoids in Baicheng County,Xinjiang,belong to the northern margin of the Tarim platform as well as the neighboring EW-oriented alkaline intrusive rocks.The rocks comprise an aegirine or arfvedsonite quartz alkali feldspar syenite,an aegirine or arfvedsonite alkali feldspar granite,and a biotite alkali feldspar syenite.The major rock-forming minerals are albite,K-feldspar,quartz,arfvedsonite,aegirine,and siderophyllite.The accessory minerals are mainly zircon,pyrochlore,thorite,fluorite,monazite,bastnaesite,xenotime,and astrophyllite.The chemical composition of the alkaline granitoids show that SiO2 varies from 64.55％ to 72.29％ with a mean value of 67.32％,Na2O＋K2O is high （9.85％-11.87％） with a mean of 11.14％,K2O is 2.39％-5.47％ （mean =4.73％）,the K2O/Na2O ratios are 0.31-0.96,Al2O3 ranges from 12.58％ to 15.44％,and total FeOT is between 2.35％ and 5.65％.CaO,MgO,MnO,and TiO2 are low.The REE content is high and the total SREE is （263-1219） ppm （mean =776 ppm）,showing LREE enrichment and HREE depletion with strong negative Eu anomalies.In addition,the chondrite-normalized REE patterns of the alkaline granitoids belong to the ＂seagull＂ pattern of the right-type.The Zr content is （113-1246） ppm （mean =594 ppm）,Zr＋Nb＋Ce＋Y is between （478-2203） ppm with a mean of 1362 ppm.Furthermore,the alkaline granitoids have high HFSE （Ga,Nb,Ta,Zr,and Hf） content and low LILE （Ba,K,and Sr） content.The Nb/Ta ratio varies from 7.23 to 32.59 （mean =16.59） and the Zr/Hf ratio is 16.69-58.04 （mean =36.80）.The zircons are depleted in LREE and enriched in HREE.The chondrite-normalized REE patterns of the zircons are of the ＂seagull＂ pattern of the left-inclined type with strong negative Eu anomaly and without a Ce anomaly.The Boziguoer A-type granitoids share similar features with A1-type granites.The average temperature of the granitic magma was estimated at 832-839℃.The Boziguoer A-type granitoids show crust-mantle mixing and may have formed in an anorogenic intraplate tectonic setting under high-temperature,anhydrous,and low oxygen fugacity conditions.     

南秦岭勉略带北光头山花岗岩体群的成因及其构造意义

南秦岭勉略带北部花岗岩体从闪长岩到花岗闪长岩和花岗岩变化,反映了钙碱性岩岩石组合特征,矿物组成以长石、石英、黑云母和少量角闪石为主,副矿物有锆石、磷灰石、磁铁矿和榍石,岩石化学上它们相对高K、Sr,Zr／Y比值较高,富集LEE和LILE,贫化HFSE,与后碰撞富钾钙碱性I型花岗岩特征一致。此外,它们明显亏损Nb、Ta,低Y、Yb和有较高的 LaN／YbN和Sr／Y比值,多数岩体发育淬冷岩浆结构的暗色闪长质微粒包体,包体与寄主花岗岩的稀土及微量元素存在明显差异,证明它们是地壳增厚背景下,可能由下部地壳拆沉作用导致的分别来自幔源和下部地壳熔融的二元岩浆混合演化的产物。个别高分异岩体的Fetot／Mg比值高、明显亏损Sr、Ba、Ti、P,呈现了向强分异A型花岗岩过渡的后碰撞富钾过铝偏碱性花岗岩特征。因此,结合西部岩体形成年代早于东部岩体分析,西部形成时代较早偏中基性的含有大量闪长质微粒包体的岩体代表了早期下部地壳拆沉作用的发生,东部形成较晚分异程度高的高钾钙碱性Ⅰ型花岗岩体的出现指示了南、北两大陆块碰撞汇聚后向伸展的转折,而更晚期高度分异的姜家坪富钾花岗岩体的出现则表明秦岭造山带已进入主碰撞结束期的伸展拉张演化阶段,并预示了新的板内演化期的到来。     

北山柳园地区双峰山早泥盆世A型花岗岩的确定及其构造演化意义

北山柳园地区分布有大量的早中古生代花岗岩类岩石.柳园双峰山岩体具有高硅、高碱(AR=3.99～5.05,NK/A>0.85)、高FeOT/MgO比值和10 000×Ga/Al值、低Al2O3、贫CaO和MgO的特征,显示出准铝质、碱质花岗岩的特点;∑REE较高,LREE略富集,轻重稀土元素分馏不十分明显,Eu负异常明显;相对富集Rb、K、Pb等大离子亲石元素(LILE),强烈亏损Ba、Sr、P、Eu、Ti,弱亏损Ta、Nb等元素;同时具有较高的Rb/Nb和Y/Nb比值,显示了A2型铝质花岗岩的特征.采用LA-ICP-MS锆石U-Pb定年方法,获得双峰山岩体的206Pb/238U年龄为415±3 Ma(MSWD=1.5),代表该岩体的形成年龄,即双峰山岩体形成于早泥盆世.地球化学及Nd同位素特征综合分析显示,该岩体可能由幔源岩浆底侵导致上覆地壳物质(可能由洋壳和岛弧建造组成)部分熔融形成的花岗闪长质岩浆经进一步结晶分异作用形成,为该区较早的钙碱性花岗岩演化到后期的产物.岩体特征、年代学、地球化学和地质背景综合分析结果表明,该岩体形成于后造山或造山作用演化晚期阶段.双峰山早泥盆世A型花岗岩为目前北山地区发现的最老的A型花岗岩,这对探讨古生代花岗岩成因类型及岩浆演化具有重要的意义.