东天山哈尔里克山区二叠纪高钾钙碱性花岗岩成因及地质意义

本文从岩石学、地球化学和同位素等方面讨论东天山克拉麦里-哈尔里克岛弧东段八大石和小铺东两个岩体的特征和成因。八大石岩体和小铺东岩体主要为二长花岗岩,SiO₂含量分别为61.92%~74.40%和69.17%~74.92%,K₂O+Na₂O的含量分别为6.50%~8.32%和7.74%~8.14%,绝大部分岩石具有高钾钙碱性花岗岩特征;∑REE分别为105×10^-6~210×10^-6和100×10^-6~172×10^-6,(La/Yb)_CN分别为4.1~8.9和9.1~15.3,配分模式右倾,δEu分别为0.40~0.93和0.59~0.80,为中-低负异常;两个岩体均富Rb、Ba等大离子亲石元素和Th、U、Hf、Zr等高场强元素,而贫Ta、Nb、Sr、Ti等。通过LA-ICP-MS分析得到八大石岩体中锆石²⁰⁶Pb/²³⁸U加权平均年龄为298±2Ma,表明岩体形成于早二叠纪,计算得到八大石和小铺东岩体的模式年龄t_DM分别为944Ma和648Ma;八大石和小铺东岩体的ε_Nd(t)u分别为+3.06和+4.47,(⁸⁷Sr/⁸⁶Sr) _i分别为0.70475和0.70384,表现出高ε_Nd(t)u 低(⁸⁷Sr/⁸⁶Sr) _i。综上所述,认为哈尔里克高钾钙碱性花岗岩可能为碰撞后挤压-伸展转折阶段的产物,主要由来自新生地壳的中钾钙碱性岩浆经过结晶分异作用而成。     

北祁连东段早古生代洋壳俯冲作用记录——来自晚奥陶世高镁埃达克岩的证据

具有特殊成因机制的埃达克质岩石是探究深部岩浆动力学过程与区域构造演化的重要岩石探针之一。本文对北祁连造山带东段宁夏南华山地区出露的石洼里花岗岩进行了系统的锆石U-Pb年龄、主量-微量元素及锆石原位Hf同位素分析,以探讨其岩石成因及地球动力学意义。LA-ICP-MS锆石U-Pb定年结果表明石洼里花岗岩侵位年龄为452±4 Ma, 为晚奥陶世岩浆活动的产物。岩石具有较高的SiO₂(68.60%~71.42%)、Al₂O₃(14.95%~15.75%)和Na₂O(5.06%~5.79%)含量,较低的K₂O(2.23%~3.10%)、MgO(0.91%~1.73%)含量和较高的Mg^# 值(55~59),属弱过铝质钙碱性系列岩石; 岩石具有高Ba(1 025×10^-6~1 250×10^-6)、Sr(324×10^-6~577×10^-6)和低Y(6.99×10^-6~7.69×10^-6)、Yb(0.65×10^-6~0.71×10^-6)含量,较高的Sr/Y(45~79)和(La/Yb)_N(17~31)值,且无明显Eu负异常。锆石εHf(t)值相对较高,变化范围为+0.5~+15.5。主量-微量元素及同位素分析结果表明石洼里花岗岩具有高镁埃达克岩的典型特征, 可能是在30~40 km深度的岛弧基性下地壳部分熔融的产物,其源区中可能存在早古生代的新生地壳。结合区内蛇绿岩、高压变质岩、弧岩浆岩的研究成果, 笔者认为受北祁连原特提斯洋北向俯冲影响,石洼里高镁埃达克岩形成于老虎山弧后盆地洋壳在晚奥陶世的南向俯冲过程中。     

大别山地区鸡公山岩体锆石U-Pb年龄、Sr-Nd-Hf同位素特征及其地质意义

鸡公山花岗岩是桐柏-大别山造山带的一处重要岩基。为探讨鸡公山花岗岩的岩石成因和动力学背景,指导区域找矿,对鸡公山岩体开展了锆石U-Pb定年、岩石地球化学和Sr-Nd-Hf同位素研究。岩石地球化学分析结果显示,岩体具准铝质-弱过铝质花岗岩特征,属于高钾钙碱性系列;副矿物有少量角闪石,为分异I型花岗岩。锆石U-Pb定年测得岩体年龄值为141.8±0.8 Ma(n=26, MSWD=1.15),表明鸡公山岩体形成于早白垩世。全岩Sr同位素(⁸⁷Sr/⁸⁶Sr)_i为0.707 75～0.708 18,εNd(t)值为-19.21～ -17.63,两阶段模式年龄为2.49~2.36 Ga。锆石¹⁷⁶Hf/¹⁷⁷Hf值为0.281 845～0.282 083,εHf(t)为-29.67～-21.31,两阶段模式年龄为3.07～2.54 Ga。Sr-Nd-Hf同位素特征暗示形成鸡公山岩体的岩浆可能是扬子板块中下地壳新太古代大别表壳岩物质重熔形成。岩体具较高的(La/Yb)_N、Sr/Y值,铕负异常不明显,与大别山埃达克型花岗岩特征类似,形成于构造伸展机制下,为尚未发生拆沉的加厚下地壳部分熔融产物。鸡公山岩体可能是岩体内伟晶岩脉的母体花岗岩。     

粤西高枨铅锌银矿区黑云母花岗岩的年代学及岩石成因

粤西高枨大型铅锌银矿赋存在黑云母花岗岩中,本文采用LA-ICP-MS锆石U-Pb测年获得黑云母花岗岩的结晶年龄为429±13Ma,为早志留世,属于加里东期岩浆活动的产物。详细的地球化学分析显示岩石的SiO₂含量为(64.33%~74.54%,平均为68.67%),Al₂O₃含量偏高(13.88%~16.61%),碱质含量高(K₂O+Na₂O=5.31%~7.89%),低P₂O₅(<0.25%)含量,强过铝质(A/CNK=1.07~1.32)。岩石富集LREE和Rb、K、U、Pb,贫Ba、Sr、Nb、P、Ti元素,铕呈负异常(Eu/Eu^*=0.38~0.90)。以上特征表明该岩体属于钙碱性强过铝质花岗岩。经年龄校正后的²⁰⁶Pb/²⁰⁴Pb,²⁰⁷Pb/²⁰⁴Pb 和²⁰⁸Pb/²⁰⁴Pb值分别为17.458~18.131、15.563~15.638和37.547~38.406。Sr初始值变化范围较大((⁸⁷Sr/⁸⁶Sr)_i=0.7091~0.7259),但ε_Nd(429Ma) 值相对较低 (-8.9~-6.1),暗示岩体来源于元古代(t_2DM=1.67~1.83Ga)的地壳组分,其源岩主要为含少量泥质的砂岩质组成。结合区域地质背景的综合分析,认为高枨黑云母花岗岩与华夏板块与扬子板块发生板内碰撞-拼合事件有关,由元古代地壳物质重熔形成的形成的S型花岗岩。     

内蒙古道郎呼都格地区A型花岗岩年代学、地球化学及地质意义

道郎呼都格钾长花岗岩体位于华北克拉通北缘白乃庙构造带。SHRIMP锆石U-Pb定年获得139.6±1.7Ma岩体侵位年龄。岩体富硅(SiO₂=75.79%~78.07%)、富碱(K₂O+Na₂O=7.39%~8.29%)、贫钙(CaO=0.22%~0.59%);稀土配分曲线呈现"海鸥式"分布特征,显示强烈的Eu负异常(δEu =0.03~0.12);微量元素特征显示具有较高Ga(21.2×10^-6~26.6×10^-6)、Zr(173×10^-6~417×10^-6)、Nb(32.3×10^-6~42.4×10^-6)和Y(24.6×10^-6~53.9×10^-6)含量,较低的Sr(14×10^-6~44×10^-6)、Ba(18×10^-6~211×10^-6)含量,在微量元素原始地幔标准化蛛网图上显示明显的Ba、Sr、P、Eu和Ti的负异常。以上特征表明道郎呼都格钾长花岗岩为A型花岗岩,为高温低压下长英质地壳的部分熔融及其后长石、榍石等的分离结晶作用的产物。结合区域构造演化,本文认为该区钾长花岗岩形成于板内伸展背景。在晚中生代期间,华北板块北缘的构造体制经历了重要的转变,由挤压体制转变为岩石圈减薄和地壳伸展,在伸展体制下,软流圈地幔上涌对上覆长英质地壳的直接加热作用促使其部分熔融形成该区A型花岗岩。     

西藏札佐晚白垩世中期埃达克岩年代学、地球化学及其构造意义

为解释南冈底斯晚白垩世埃达克质岩石成因及其地球动力学机制,本文对西藏扎囊县札佐地区二长花岗岩开展了锆石U-Pb年代学、Hf同位素和全岩地球化学分析。札佐二长花岗岩锆石U-Pb定年为80.43±0.62 Ma,其SiO₂为66.19%~66.84%,Al₂O₃为15.17%~15.48%,MgO为1.67%~1.91%,Mg#为47.4~51.5,K₂O为3.86%~4.09%,A/CNK=0.91~1.01,属准铝质高钾钙碱性岩石。岩石轻稀土富集明显,高Sr（492×10^-6~670.2×10^-6）,低Y（8.27×10^-6~14.99×10^-6）,Yb（1.07×10^-6~1.79×10^-6）,高Sr/Y（35.0~81.0）,高La/Yb（17.4~21.4）,弱负Eu异常,具埃达克岩地球化学特征。相对富集大离子亲石元素（LILE）,亏损高场强元素（HFSE）和重稀土。锆石ε_Hf（t）值为10.5~14.1,单阶段Hf模式年龄（t_DM1）为184.8~326.1 Ma,平均为203.4 Ma,二阶段Hf模式年龄（t_DM2）为247.2~476.0 Ma,平均为287.1 Ma,略大于侵位年龄,指示岩浆物质来源于俯冲洋壳,并可能卷入俯冲沉积物。岩石中地幔组分印记Mg#值和相容元素Ni、Cr含量较高,表明熔体在上升过程中与上覆地幔楔发生反应。研究分析表明,在新特提斯洋洋脊俯冲作用下,高温热流透过板片窗导致洋壳（及俯冲沉积物）部分熔融形成札佐埃达克质二长花岗岩。同时表明,在80 Ma左右,新特提斯洋仍处于洋脊俯冲阶段。     

大别造山带研子岗碱性岩体成因及其构造意义：锆石U-Pb年龄和地球化学制约

出露于大别造山带西南部的研子岗碱性杂岩体侵位于元古代和新太古代随县群中,本文采用锆石LA-ICPMS U-Pb定年方法,获得岩体的主体岩性角闪正长岩的岩浆锆石年龄为133± 1Ma,代表岩体的结晶年龄,这一年龄也是大别造山带中已知形成时代最早的早白垩世碱性岩体的结晶年龄（单颗粒锆石U-Pb法）。研子岗碱性杂岩体具有碱性岩典型的富碱（K₂O＋Na₂O＝8.38%~11.26%）、低硅（SiO₂＝63.41%~66.51%）的特点。主要矿物为微斜条纹长石,暗色矿物主要为镁角闪石。地球化学特征表明,全部岩石均具有高Ba-Sr花岗岩类高Ba（1230× 10^-6~4865× 10^-6）、高Sr（583× 10^-6~2088× 10^-6）和无负Eu异常（Eu/Eu^*＝0.97~1.12）等特征,并具有A型花岗岩的部分地球化学特征。岩石的Y/Nb比（0.46~1.09）较低,具洋岛玄武岩的部分地球化学特征,(⁸⁷Sr/⁸⁶Sr) _i初始比值（0.70513~0.70543）较低,表明岩体的物源主要来源于幔源。Nd二阶段模式年龄(t_2DM=1859~1942Ma)和锆石Hf二阶段模式年龄(t_DM2=2130~2330Ma）较老,ε_Nd(133)值(-12.5~-11.4）和ε_Hf(133)值(-18.2~-15.4）较低。综合分析表明,岩体主要为古老的富集岩石圈地幔物质低程度部分熔融和随后地壳物质轻度AFC（混染和分离结晶作用）过程的产物,源岩熔融的热量主要来源于软流圈物质的上涌底侵作用提供。研子岗岩体形成于碰撞后构造环境,岩体的形成预示着大别造山带早白垩世造山过程的即将结束,板内时期的即将来临。     

北山柳园地区中志留世埃达克质花岗岩类及其地质意义

北山柳园地区发育的埃达克质片麻状花岗闪长岩为钙碱性岩浆系列,具有较高SiO₂ (>56%),Al₂O₃ (>15%)和较低的MgO (<3%)含量,Na₂O>K₂O; 并且具有高的Sr含量(>400×10^-6)和Sr/Y比值; 样品轻重稀土强烈分异(La/Yb)_N ＝18~86,强烈亏损重稀土Yb与Y,具有不明显的Eu异常(δEu＝0.90~0.95); 富集LREE和大离子亲石元素(LILE),而亏损HREE、高场强元素(HFSE: Nb、Ta),与世界上典型的俯冲洋壳熔融形成的埃达克岩相似。然而样品具有相对高的(⁸⁷Sr/⁸⁶Sr)_I (0.70635~0.70636)和相对低的ε_Nd(t) (-0.8~-0.9),以及锆石具有相对较低的ε_Hf (t) (-0.8~+2.7)同位素特征,比典型的俯冲洋壳熔融形成埃达克岩具有更多的放射成因,推测可能是源区加入了地壳物质/沉积物/或特殊的洋壳(OIB/E-MORB)熔融,以及侵位过程中地壳物质的混染所造成的。埃达克质片麻状黑云母花岗岩锆石LA-ICPMS年龄为424±4Ma,代表了花岗岩埃达克花岗岩的结晶年龄。花牛山岛弧带在中晚志留世时期具有较高的地热梯度,发育了大面积高ε_Nd(t)钙碱性花岗岩和区域围岩发生了高温变质作用。因此,柳园埃达克岩是由于热的洋壳向花牛山岛弧地体俯冲过程中熔融形成的,俯冲洋壳熔融是本地区早古生代大规模地壳增生的重要方式之一。     

新疆准噶尔北东缘乌图布拉克岩体形成时代、地球化学特征及地质意义

乌图布拉克岩体位于准噶尔北东缘,额尔齐斯-玛因鄂博构造带南侧。岩体主要由花岗闪长岩和二长花岗岩组成,有少量石英闪长岩和钾长花岗岩。岩体的锆石SHRIMP U-Pb年龄为360.1±3.6Ma。岩石的K₂O+Na₂O=7.05%~9.48%,A/NKC=0.91~1.04,属准铝-过铝质“I”型花岗岩。岩石稀土总量低,∑REE为72×10^-6~184×10^-6,轻稀土富集,(La/Yb)_N=5~13。石英闪长岩、花岗闪长岩、二长花岗岩具弱的铕负异常或无明显异常（δEu=0.72~0.98）;钾长花岗岩铕负异常明显（δEu=0.15~0.21）。在微量元素配分模式中,具有Sr、Ba、P、Ti的亏损,而Nb、Ta亏损不明显。岩石有低的Sr初始值（0.70165~0.70462）和高的ε_Nd(t)u（+4.7~+6.9）。2个样品的Nd模式年龄分别为758Ma和551Ma。上述特征表明,岩浆可能具有较复杂的来源,推测该岩体岩浆可能来源于年轻的玄武质地壳,并有幔源物质的加入。综合本文资料及区域地质特征分析,阿尔泰造山带后碰撞时限可能为360~290Ma,即泥盆纪末-石炭纪末。     

河北赞皇地区许亭花岗岩的时代及成因:对华北克拉通中部带构造演化的制约

许亭花岗岩出露于赞皇杂岩中,位于河北省赞皇县西部山区,呈岩基状侵入新太古代TTG片麻岩和变质地层中,SHRIMP 锆石U-Pb年龄为2090±10Ma。岩体主要由钾长-二长花岗岩组成,无暗色包体,偶见围岩的捕掳体。岩体组成不均匀,局部含石英和少量钾长石斑晶,构成似斑状结构。主要的矿物组合为石英+钾长石+斜长石+黑云母+绿帘石±白云母±角闪石,含萤石副矿物。岩石具有高硅(SiO₂＞75%)、富碱(ALK=6.90%~8.75%)、低铝(Al₂O₃ =10.32%~11.64%)、钛(TiO₂=0.26%~0.36%)和贫钙(CaO=0.18%~0.48%)、镁(MgO=0.16%~0.40%)、铁(Fe₂O^T₃=2.58%~3.46%)的特征,为偏铝质到弱过铝质的高钾钙碱性系列。岩石的稀土总量较高(293.8×10^-6 ~702.8×10^-6),轻稀土相对富集,有明显的负Eu异常(Eu/Eu^*=0.1~0.35)。微量元素中,富Zr、Nb和Y,而贫Ba、Sr和P等元素,Rb/Sr比值较高,介于1.45~7.52之间,平均4.31。岩石还具有高的Ga/Al值(3.04×10^-6~4.08×10^-6),具有A型花岗岩特征。在同位素组成方面,具有较低的ε_Nd(t)值(-14.29~-0.29,平均为-5.58)。许亭花岗岩具有板内花岗岩特征,可能与2.1Ga时岩浆板底垫托,导致新太古代TTG岩石部分熔融,并可能有少量古老地壳物质加入。根据岩体性质及岩石组合等特征推测赞皇、阜平、五台等地区的2.1Ga岩浆活动形成于统一的拉张裂解环境。     

Wavelength-dispersive X-ray fluorescence spectrometric determination of Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites

Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours.     

高压微波消解法测定醋酸纤维过滤器采集的微尘粒子中的砷镉钴铬铜铁锰镍铅钒锌

最新的流行病学研究表明,空气中较高浓度的悬浮细颗粒可能对人类的健康有不利的影响。根据该项研究显示,由于心脏病、慢性呼吸问题和肺功能指标恶化而导致死亡率的升高与细尘粒子有关。这些研究结果已经促使欧盟于1999年4月出台了限制空气中二氧化硫、二氧化氮、氧化氮、铅和颗粒物含量的法案(1999/30/EC),对各项指标包括对可吸入PM10颗粒的浓度提出了新的限制性指标。PM10颗粒是指可以通过预分级器分离采集的气体动力学直径小于10μm的细颗粒。目前研究的兴趣重点逐步偏向PM2.5这些更细微颗粒物,PM2.5这种颗粒物对健康有明显的不利影响。在欧盟指令2008/50/EC中,对PM10和PM2.5都提     

硅酸盐类样品中硅、铁、铝、钛、锰、钙、镁、钾、钠和磷的x射线荧光光谱测定

本文拟定了一种以熔融法制备样片,用X射线荧光光谱测定硅酸盐类样品中Si、Fe、Al、Tj、Mn、Ca、Mg、K、Na、P等元素的分析方法。在对不同靶材X光管和分光晶体实验对比的基础上,选择了最佳的测量条件。该法具有快速、准确,测量范围广,检测限低,价格便宜等优点。经过近百个各种类型标样或管理样品的分析对比表明,本法不仅适用于硅酸盐类岩石样品的分析,还适用于铁矿、铝土矿、碳酸盐类岩矿样品以及水泥、耐火材料等样品的分析。     

Isotopic systematics of He,Ar, S,Cu, Ni,Re, Os,Pb, U,Sm, Nd,Rb, Sr,Lu, and Hf in the rocks and ores of the Norilsk deposits

This paper reports the first results of a study of 11 isotope systems (³He/⁴He, ⁴⁰Ar/³⁶Ar, ³⁴S/³²S, ⁶⁵Cu/⁶³Cu, ⁶²Ni/⁶⁰Ni, ⁸⁷Sr/⁸⁶Sr, ¹⁴³Nd/¹⁴⁴Nd, ^206–208Pb/²⁰⁴Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others.     

Viscous, cohesive, non-Newtonian, depositing, radial slurry flow

Mining induced subsidence can significantly affect mining costs where major surface facilities and natural environment need to be protected. Overburden grout injection is a technology used to control coal mine subsidence by injecting the mine waste material extracted from the coal back into the inter-burden rock during longwall mining. The flowing slurry is here categorised as a nonlinear viscous cohesive (Bingham plastic) fluid. During longwall mining the grout slurry is pumped into the separated beds of the rock mass through a central vertical borehole, which is drilled deep into the inter-burden rock strata above the coal seam. However, a blockage can occur in the injection system when the slurry velocity falls below a certain critical threshold velocity, indicating a material phase change from cohesive-viscous to cohesive-frictional. In situ field injection tests through boreholes have been simulated at a smaller scale at the CSIRO laboratory in Brisbane by pumping the slurry through a radial disk (gap = 4 mm) from its centre. Laboratory experiments indicate a general, nonlinear, cohesive, viscous, frictional model for shear behaviour of the slurry, in which the material shear parameters are functions of the disk radial distance. Complete dimensional and dimensionless analytical solutions have been developed based on an approach related to Bingham–Herschel–Bulkley fluid mechanics. The derived formulae include relations for minimum pump pressure, local pressure and pressure gradient, wall shear stress, volume rate, velocity and velocity gradient. The theoretical results match the experimental measurements. The experiments covered slurries with maximum particle sizes of 0.5 to 2 mm with about 50% being larger than 100 µm. The viscosities at the various solids concentrations were measured with a standard torsion viscometer. This study differs from the previous research in several distinct aspects, namely, consideration of the variable shear parameters rather than fixed values, inclusion of total nonlinear behaviour, and implementation of a friction function to mimic behaviour of the deposited and consolidating stiff slurry, which can cause a significant pressure rise as a result of the increased shear resistance.     

硅酸盐中铁、锰、钛、钙、钾、磷、硅、铝、镁、钠、锶、铷、钡的X-射线荧光光谱定量测定

本文介绍样品经四硼酸锂熔融制成玻璃小饼。采用Lachance模式和理论a系数来校正元素间的效应,由3080E型X-射线荧光谱仪和DF-350B数据处理系统完成硅酸盐中十三个项目的测定。     

岩石密度和超高压岩石折返速率

在常温常压条件下对中国大陆科学钻CCSD主孔100-3000米岩心样品进行了密度测量,建立了密度连续剖面,并界定了不同超高压岩石的密度值。通过对比高温高压物性实验资料,岩石密度随着退变程度增强而降低,榴辉岩密度变化序列为3.52g/cm3→3.49g/cm3→3.07g/cm3→2.93g/cm3。超高压长英质岩石密度变化序列为3.00g/cm→2.80g/cm3→2.65g/cm3。上述实验资料是讨论不同折返阶段岩石所受浮力的基础,为研究折返速率大小提供了基本参数。本文通过折返板块运动平衡时,上浮力与粘滞力平衡这一关系式,定量研究了大陆俯冲板块的折返速率,认为密度差产生上浮力从而引起折返,温度对板块折返速率的影响最为显著;密度差大小、折返角度、折返板块大小对折返速率也有直接的影响。定量模拟分析表明,在温度高于850℃时,板块的折返速率可以超过100mm/a;当温度降至700℃时,折返速率则低于1.5mm/a。作者认为在折返早期,温度较高,板块快速折返至60-70km榴辉岩相深度;随着传导散热,温度降低,板块以较慢的速率折返至中下地壳。折返速率的估算表明,浮力是板块折返第一阶段(从>100km深部折返至<40km的中下地壳)的主要驱动力。     

Bellechester,Minnesota, USA,lagoon collapses

Bellechester, Minnesota, is a small community of approximately 155 residents located on the county line between Goodhue and Wabasha counties in southeast Minnesota's karst region. Bellechester is served by a 21-year-old wastewater treatment facility (WWTF) consisting of three waste-stabilization ponds. On 28 April 1992 six sinkholes were discovered to have drained cell 2 of the WWTF resulting in the loss of approximately 8.7×10⁶ 1 of partially treated effluent and about 600 m³ of soil into previously undetected subsurface voids of unknown dimensions. In the week following the collapse, approximately 200 water wells located within a 5-km radius of the WWTF were sampled in an after-the-fact, emergency sampling program. Twelve samples with elevated fecal coliform levels, 18 samples with nitrate-nitrogen greater than the 10 mg/1 standard, and no samples with elevated chlorides were found. However, the elevated levels could not be unambiguously attributed to the WWTF collapse. This is the third WWTF to fail by sinkhole collapse in southeast Minnesota since 1974. All three collapsed lagoons have been located in similar geomorphic and stratigraphic settings. However, at least two lagoons have collapsed in the adjacent area in northeast Iowa, and these lagoons are located at different stratigraphic positions. Twenty-two WWTFs constructed in southeast Minnesota's karst region in the last 25 years have been identified as subject to potential sinkhole collapse. An unknown but significant number of manure storage lagoons, flood control structures, etc., have also been constructed in the karst region and are at risk. Public agencies are beginning to develop plans to deal with the risk associated with existing and future waste lagoons in this environment. The critical hydrogeologic parameters that can be used to prioritize the risk of collapse at existing facilities include: (1) the lithology of the first bedrock beneath each lagoon, (2) the thickness of surficial materials between the lagoon and the bedrock surface, (3) the presence and construction of liners (seepage rate), and (4) the proximity to existing sinkholes.     

Mercury,arsenic, antimony,and selenium contents of sediment from the Kuskokwim River,Bethel, Alaska,USA

The Kuskokwim River at Bethel, Alaska, drains a major mercury-antimony metallogenic province in its upper reaches and tributaries. Bethel (population 4000) is situated on the Kuskokwim floodplain and also draws its water supply from wells located in river-deposited sediment. A boring through overbank and floodplain sediment has provided material to establish a baseline datum for sediment-hosted heavy metals. Mercury (total), arsenic, antimony, and selenium contents were determined; aluminum was also determined and used as normalizing factor. The contents of the heavy metals were relatively constant with depth and do not reflect any potential enrichment from upstream contaminant sources.     

滇东南花岗岩与锡、银、铜、铅、锌多金属矿床的成因关系

滇东南锡、银、铅、锌多金属矿床主要分布在个旧、白牛厂、都龙3个矿区,而滇东南较大的3个花岗岩体又分别出露在3个矿区或附近.花岗岩体均形成于燕山晚期,岩石化学、矿物成分相似,富含锡、银、铅、锌、钨、铜等成矿元素.矿床主金属元素组合与岩体之间的距离由远而近出现由锡、钨、(铍、铌、钽)→锡、钨、(铁)、铜、铟→锡、铅、锌、银、铟、(锑)有规律的变化.花岗岩浆是成矿物质来源和成矿热源.岩浆侵入初期使上覆地层隆起产生背斜(凹陷部位成向斜);同时使地层产生一系列裂隙、压性断层或层间断裂;岩浆侵入晚期,这些断层再次活动,表现为张性,岩浆产生的含矿热液沿由其活动所造成的断裂迁移、充填、交代、沉淀而形成矿床.