霍各乞铜多金属矿区热水沉积岩类初探

以绿片岩相为主的霍各乞矿区含矿地层内存在一些特殊的热水沉积岩。通过矿物学、岩石学、矿物共生组合以及地球化学特征判断，主要岩石类型包括硅质岩、含电气石岩、重晶石岩、透辉石、透闪石岩以及铁镁碳酸盐岩类等。这些岩石的存在和研究对于本矿床及狼山地区成矿作用和矿床成因的认识有重要启示意义。     

滇西大石坡超大型红柱石矿床成因:岩浆岩侵位的约束

滇西大石坡矿床是近年来新发现的超大型红柱石矿床。红柱石属于蓝晶石族矿物,是制造高级耐火材料的原料,在新兴产业、高新技术产业中也具有重要经济价值。红柱石矿物原料地质工作程度在云南省比较低,趋于空白。本文通过岩石地球化学和主要矿物相关性分析,深化认识大石坡红柱石矿床成矿特征与成因。大石坡红柱石矿体赋存在高黎贡山群红柱石石英云母片岩、含红柱石云母石英片岩、红柱石长石云母石英片岩中,矿体厚度大、品位中等,矿床规模达超大型。红柱石是受古近纪花岗岩侵位发生低压高温接触变质作用而形成,分布杂乱,无定向性,与区域片理产状斜交。研究显示,红柱石与矽线石相关系数为-0.369,说明二者之间成因不相关,红柱石与矽线石不是同一变质时期形成的。该矿床的形成明显受高黎贡山群片岩和古近纪钙碱性过铝质S型花岗岩制约。     

马达加斯加Antanisoa石墨矿床成因分析

马达加斯加是世界优质大鳞片石墨矿重要产地之一,随着大鳞片石墨在诸多新兴领域发挥着越来越大的作用,对马达加斯加石墨矿床的研究显得越来越重要。矿床成因研究对石墨矿床的找矿勘查具有指导作用,然而目前关于马达加斯加石墨矿床的研究程度较低,人们普遍认为马达加斯加的石墨矿床是沉积变质成因。文章将Antanisoa石墨矿床作为研究对象,通过对矿区内石墨片岩的岩相学研究以及矿物化学特征研究,发现沉积变质成因的说法并不妥当。野外地质调查和岩相学研究显示出较多与流体充填有关的现象,矿物化学特征表明石墨片岩中与石墨共生的云母为金云母,浅色电气石为镁电气石。结合前人对马达加斯加岛地质背景研究结果与认识,认为马达加斯加Antanisoa石墨矿床更有可能与幔源流体充填有关,有待进一步研究。     

硅酸盐体系的化学平衡:(1)物质平衡原理

通过具体应用实例,系统介绍了在硅酸盐体系的化学平衡研究中,依据物质平衡原理,求解“相混合方程”(PME)而进行物相定量分析的“相混合计算”(PMC)方法。应用实例包括矿物原料和结晶岩物相的定量分析,复杂固溶体矿物的端员组分计算,多组分硅酸盐陶瓷的配料比例计算,以及硅酸盐陶瓷制品物相的定量分析。物相定量分析结果是结晶岩和工业岩石原料分类命名的基础,可以为改进矿物原料预处理工艺提供依据,也是研究硅酸盐体系的化学平衡、对材料制备过程进行热力学分析的基础。实际计算中必须合理估计各种分析数据的累积误差。优化计算结果的理论依据主要有矿物晶体化学原理、矿物共生组合规律和次要组分分配的固溶体矿物相优先原则。     

《岩石矿物学杂志》征订征稿启事

《岩石矿物学杂志》是由中国地质学会岩石学专业委员会、矿物学专业委员会、中国地质科学院地质研究所联合主办的学术性期刊,属地质类全国中文核心期刊,主要报道内容包括:岩石学领域的专题性或区域性岩浆岩、变质岩、沉积岩的岩类学、岩理学、实验岩石学、宇宙岩石学、工艺岩石学等方面的基础理论和应用研究成果;矿物学领域的描述矿物学、理论矿物学、材料矿物学、应用矿物学、宝玉石矿物学、环境矿物学、矿物药学、矿相学、新矿物及矿物中包裹体等方面的研究成果;与岩石学、矿物学有关的边缘交叉学科中的构造岩石学、岩石大地构造学、岩石…     

孔兹岩系内棱柱状夕线石的成因

对我国鄂西及黑龙江省东部孔兹岩系的地质观察发现,含棱柱状夕线石的高铝夕线片岩类与含红柱石的云母片岩类岩石在区域上共生。系统的岩相学研究表明,这些夕线石系由叶蜡石直接转变所成。原岩恢复以及对变质作用过程中可能发生的变质反应的理论探讨和原始沉积物理想组分计算的结果都支持上述结论。认为孔兹岩系中的棱柱状夕线石和红柱石系低角闪岩相条件下在不同的原岩中经不同的变质反应形成。它们的形成主要受原岩的成分控制。这种由叶蜡石直接分解形成的夕线石,其初始形成温度较低,不能作为划分高角闪岩相的标志。     

岩石物理化学在矿物共生组合研究中的应用

<正>岩石物理化学是岩石学与物理化学之间的交叉学科,是现代岩石学又一重要的研究方向,其理论基础是相律和相平衡原理,以及热力学三大定律。是研究矿物、岩石、熔浆(体)、气体、溶液、流体之间在不同温度、压力条件下平衡共存关系的一种有效方法。矿物共生组合建立之后,是成矿作用和生成的物理—化学条件服务。就可以应用相平衡原理和相律,为探讨和解释矿相平衡图和相平衡曲线可帮助我们:(1)预测和识别物相;(2)认识矿石化学     

塔什库尔干新生代碱性杂岩造岩矿物化学成分及成因意义

新疆塔什库尔干碱性杂岩体主要由苦子干碱性正长岩体和卡日巴生碱性花岗岩体组成，是帕米尔地区最大的新生代碱性杂岩体。本文在岩相学和矿物化学的基础上，着重研究了苦子干岩体主要造岩矿物的种属、共生关系和结晶顺序。研究表明，苦子干岩体中的不同岩石类型系同源岩浆演化的产物；岩浆在整个演化过程中平衡结晶作用占主导，分离结晶作用的影响极小。据岩浆房中矿物结晶时的温度和压力条件、矿物的结晶特征及演化趋势，推测岩浆上升速度较快，侵位较浅。     

中国蓝片岩带的时空分布、地质特征和成因

本文主要介绍了中国蓝片岩的时空分布、一般地质特征和成因。内容主要包括以下6个方面:一是当前中国蓝片岩的研究概况和重要进展;二是蓝片岩、蓝闪片岩和蓝片岩相名词的讨论;三是对17个蓝片岩带的一般地质特征(主要包括原岩性质、岩石矿物共生组合,p-t条件,变质时代及赋存的大地构造背景等)进行描述;四是讨论蓝片岩带的成因,并提出深俯冲-陆陆碰撞型和深俯冲-洋壳碰撞两个模式;五是总结了几点蓝片岩带综合地质特征;六是提出了蓝片岩带研究中存在的6个地质科学问题,建议进一步加强考察与研究。     

塔里木盆地巴楚隆起岩盐中原生包裹体特征及意义——以巴探5井为例

塔里木盆地巴楚隆起发育一套中寒武统的膏岩盐层,是较好的区域性盖层。本文对巴楚隆起中段巴探5井蒸发岩层石盐中的包裹体进行了岩相学、显微测温学、热力学计算等研究。岩相学结果表明虽然经历了多期构造以及深埋作用的影响,在石盐中仍然发现了代表表生沉积环境的原生包裹体组合。包裹体的均一温度测温结果表明石盐沉积时的古水温约为29.9℃,与当时的古气候特征相一致。热力学计算表明,石盐中包裹体在埋深过程中所表现出的非等容-非等组成体系的热力学特征,可能是包裹体在后期地质改造过程中得以保存的重要因素之一。     

Wavelength-dispersive X-ray fluorescence spectrometric determination of Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites

Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours.     

高压微波消解法测定醋酸纤维过滤器采集的微尘粒子中的砷镉钴铬铜铁锰镍铅钒锌

最新的流行病学研究表明,空气中较高浓度的悬浮细颗粒可能对人类的健康有不利的影响。根据该项研究显示,由于心脏病、慢性呼吸问题和肺功能指标恶化而导致死亡率的升高与细尘粒子有关。这些研究结果已经促使欧盟于1999年4月出台了限制空气中二氧化硫、二氧化氮、氧化氮、铅和颗粒物含量的法案(1999/30/EC),对各项指标包括对可吸入PM10颗粒的浓度提出了新的限制性指标。PM10颗粒是指可以通过预分级器分离采集的气体动力学直径小于10μm的细颗粒。目前研究的兴趣重点逐步偏向PM2.5这些更细微颗粒物,PM2.5这种颗粒物对健康有明显的不利影响。在欧盟指令2008/50/EC中,对PM10和PM2.5都提     

硅酸盐类样品中硅、铁、铝、钛、锰、钙、镁、钾、钠和磷的x射线荧光光谱测定

本文拟定了一种以熔融法制备样片,用X射线荧光光谱测定硅酸盐类样品中Si、Fe、Al、Tj、Mn、Ca、Mg、K、Na、P等元素的分析方法。在对不同靶材X光管和分光晶体实验对比的基础上,选择了最佳的测量条件。该法具有快速、准确,测量范围广,检测限低,价格便宜等优点。经过近百个各种类型标样或管理样品的分析对比表明,本法不仅适用于硅酸盐类岩石样品的分析,还适用于铁矿、铝土矿、碳酸盐类岩矿样品以及水泥、耐火材料等样品的分析。     

Isotopic systematics of He,Ar, S,Cu, Ni,Re, Os,Pb, U,Sm, Nd,Rb, Sr,Lu, and Hf in the rocks and ores of the Norilsk deposits

This paper reports the first results of a study of 11 isotope systems (³He/⁴He, ⁴⁰Ar/³⁶Ar, ³⁴S/³²S, ⁶⁵Cu/⁶³Cu, ⁶²Ni/⁶⁰Ni, ⁸⁷Sr/⁸⁶Sr, ¹⁴³Nd/¹⁴⁴Nd, ^206–208Pb/²⁰⁴Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others.     

Viscous, cohesive, non-Newtonian, depositing, radial slurry flow

Mining induced subsidence can significantly affect mining costs where major surface facilities and natural environment need to be protected. Overburden grout injection is a technology used to control coal mine subsidence by injecting the mine waste material extracted from the coal back into the inter-burden rock during longwall mining. The flowing slurry is here categorised as a nonlinear viscous cohesive (Bingham plastic) fluid. During longwall mining the grout slurry is pumped into the separated beds of the rock mass through a central vertical borehole, which is drilled deep into the inter-burden rock strata above the coal seam. However, a blockage can occur in the injection system when the slurry velocity falls below a certain critical threshold velocity, indicating a material phase change from cohesive-viscous to cohesive-frictional. In situ field injection tests through boreholes have been simulated at a smaller scale at the CSIRO laboratory in Brisbane by pumping the slurry through a radial disk (gap = 4 mm) from its centre. Laboratory experiments indicate a general, nonlinear, cohesive, viscous, frictional model for shear behaviour of the slurry, in which the material shear parameters are functions of the disk radial distance. Complete dimensional and dimensionless analytical solutions have been developed based on an approach related to Bingham–Herschel–Bulkley fluid mechanics. The derived formulae include relations for minimum pump pressure, local pressure and pressure gradient, wall shear stress, volume rate, velocity and velocity gradient. The theoretical results match the experimental measurements. The experiments covered slurries with maximum particle sizes of 0.5 to 2 mm with about 50% being larger than 100 µm. The viscosities at the various solids concentrations were measured with a standard torsion viscometer. This study differs from the previous research in several distinct aspects, namely, consideration of the variable shear parameters rather than fixed values, inclusion of total nonlinear behaviour, and implementation of a friction function to mimic behaviour of the deposited and consolidating stiff slurry, which can cause a significant pressure rise as a result of the increased shear resistance.     

硅酸盐中铁、锰、钛、钙、钾、磷、硅、铝、镁、钠、锶、铷、钡的X-射线荧光光谱定量测定

本文介绍样品经四硼酸锂熔融制成玻璃小饼。采用Lachance模式和理论a系数来校正元素间的效应,由3080E型X-射线荧光谱仪和DF-350B数据处理系统完成硅酸盐中十三个项目的测定。     

岩石密度和超高压岩石折返速率

在常温常压条件下对中国大陆科学钻CCSD主孔100-3000米岩心样品进行了密度测量,建立了密度连续剖面,并界定了不同超高压岩石的密度值。通过对比高温高压物性实验资料,岩石密度随着退变程度增强而降低,榴辉岩密度变化序列为3.52g/cm3→3.49g/cm3→3.07g/cm3→2.93g/cm3。超高压长英质岩石密度变化序列为3.00g/cm→2.80g/cm3→2.65g/cm3。上述实验资料是讨论不同折返阶段岩石所受浮力的基础,为研究折返速率大小提供了基本参数。本文通过折返板块运动平衡时,上浮力与粘滞力平衡这一关系式,定量研究了大陆俯冲板块的折返速率,认为密度差产生上浮力从而引起折返,温度对板块折返速率的影响最为显著;密度差大小、折返角度、折返板块大小对折返速率也有直接的影响。定量模拟分析表明,在温度高于850℃时,板块的折返速率可以超过100mm/a;当温度降至700℃时,折返速率则低于1.5mm/a。作者认为在折返早期,温度较高,板块快速折返至60-70km榴辉岩相深度;随着传导散热,温度降低,板块以较慢的速率折返至中下地壳。折返速率的估算表明,浮力是板块折返第一阶段(从>100km深部折返至<40km的中下地壳)的主要驱动力。     

Bellechester,Minnesota, USA,lagoon collapses

Bellechester, Minnesota, is a small community of approximately 155 residents located on the county line between Goodhue and Wabasha counties in southeast Minnesota's karst region. Bellechester is served by a 21-year-old wastewater treatment facility (WWTF) consisting of three waste-stabilization ponds. On 28 April 1992 six sinkholes were discovered to have drained cell 2 of the WWTF resulting in the loss of approximately 8.7×10⁶ 1 of partially treated effluent and about 600 m³ of soil into previously undetected subsurface voids of unknown dimensions. In the week following the collapse, approximately 200 water wells located within a 5-km radius of the WWTF were sampled in an after-the-fact, emergency sampling program. Twelve samples with elevated fecal coliform levels, 18 samples with nitrate-nitrogen greater than the 10 mg/1 standard, and no samples with elevated chlorides were found. However, the elevated levels could not be unambiguously attributed to the WWTF collapse. This is the third WWTF to fail by sinkhole collapse in southeast Minnesota since 1974. All three collapsed lagoons have been located in similar geomorphic and stratigraphic settings. However, at least two lagoons have collapsed in the adjacent area in northeast Iowa, and these lagoons are located at different stratigraphic positions. Twenty-two WWTFs constructed in southeast Minnesota's karst region in the last 25 years have been identified as subject to potential sinkhole collapse. An unknown but significant number of manure storage lagoons, flood control structures, etc., have also been constructed in the karst region and are at risk. Public agencies are beginning to develop plans to deal with the risk associated with existing and future waste lagoons in this environment. The critical hydrogeologic parameters that can be used to prioritize the risk of collapse at existing facilities include: (1) the lithology of the first bedrock beneath each lagoon, (2) the thickness of surficial materials between the lagoon and the bedrock surface, (3) the presence and construction of liners (seepage rate), and (4) the proximity to existing sinkholes.     

Mercury,arsenic, antimony,and selenium contents of sediment from the Kuskokwim River,Bethel, Alaska,USA

The Kuskokwim River at Bethel, Alaska, drains a major mercury-antimony metallogenic province in its upper reaches and tributaries. Bethel (population 4000) is situated on the Kuskokwim floodplain and also draws its water supply from wells located in river-deposited sediment. A boring through overbank and floodplain sediment has provided material to establish a baseline datum for sediment-hosted heavy metals. Mercury (total), arsenic, antimony, and selenium contents were determined; aluminum was also determined and used as normalizing factor. The contents of the heavy metals were relatively constant with depth and do not reflect any potential enrichment from upstream contaminant sources.     

滇东南花岗岩与锡、银、铜、铅、锌多金属矿床的成因关系

滇东南锡、银、铅、锌多金属矿床主要分布在个旧、白牛厂、都龙3个矿区,而滇东南较大的3个花岗岩体又分别出露在3个矿区或附近.花岗岩体均形成于燕山晚期,岩石化学、矿物成分相似,富含锡、银、铅、锌、钨、铜等成矿元素.矿床主金属元素组合与岩体之间的距离由远而近出现由锡、钨、(铍、铌、钽)→锡、钨、(铁)、铜、铟→锡、铅、锌、银、铟、(锑)有规律的变化.花岗岩浆是成矿物质来源和成矿热源.岩浆侵入初期使上覆地层隆起产生背斜(凹陷部位成向斜);同时使地层产生一系列裂隙、压性断层或层间断裂;岩浆侵入晚期,这些断层再次活动,表现为张性,岩浆产生的含矿热液沿由其活动所造成的断裂迁移、充填、交代、沉淀而形成矿床.