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1.
国内首次发现的粤北下庄铀矿田竹筒尖矿床产出的束磷钙铀矿,在空间上与微晶石英和变钙铀云母紧密共生。该矿物多为纤维状、束状和放射状集合体;亮黄色,玻璃光泽,透明;条痕为浅黄色,摩氏硬度约为3;其具有一组平行于{010}的完全解理及平行于{100}和{001}的两组解理,贝壳状断口呈油脂光泽;单偏光下,该矿物为淡黄色;正交偏光下,具有鲜艳的高级干涉色。光性特征为对称消光,二轴晶负光性,正延性。电子探针分析显示,矿物主要由U、P、Ca这3种元素组成,其平均含量分别为UO3 68.64%、P2O5 11.70%、CaO 9.21%和杂质0.28%,另有H2O 9.25%,总量99.26%。按O=16计算的经验化学式可写为(Ca2.02,K0.05,Mg0.012.08(UO2,TiO2,PbO)2.97O1.97(PO42.03·6.32 H2O。X射线粉晶衍射分析表明,该矿物属于正交晶系,空间群为Pbca,晶胞参数:a=1.742 3(5) nm,b=1.603 2(4) nm,c=1.359 9(2) nm;α=β=γ=90°,V=3.798 64 nm3 ;强衍射线有7.994 Å和4.003 Å等。矿物的红外吸收光谱强峰主要为3 427.10、1 622.05、1 062.62、973.26和890.91 cm-1等。上述特征与已知的束磷钙铀矿极其类似。  相似文献   

2.
闪叶石族矿物是富含Sr、Na、Ca和Ba等的钛硅酸盐矿物的总称,迄今共有19个矿物种,其中的氟闪叶石矿物首次发现于巴西Serrote山碱性岩中。本文利用电子探针和X射线衍射仪等分析测试手段,从化学成分和晶体结构等方面对产出于中国辽宁赛马碱性岩体中的闪叶石族矿物进行了详细的矿物学特征研究,发现其中常呈柱状、针状和纤维状集合体产出的闪叶石的晶体化学式为(Sr1.00Na1.00)Σ2.00Ti2(Na1.98Sr0.33Mn0.26K0.12Mg0.10Ca0.09Ba0.05)Σ2.93(Ti0.69Fe3+0.33Al0.02)Σ1.04(Si3.80O14) O2(F1.16OH0.84)Σ2.00,属于单斜晶系,空间群为C2/m,晶胞参数a=19.271 9(8) Å,b=7.077 9(3) Å, c=5.388 2(2) Å, β=96.780(2)°, V=729.84(5) Å3, Z=2。上述矿物学特征均与巴西发现的新矿物氟闪叶石的矿物学特征一致,表明赛马碱性岩体产出的氟闪叶石堪称该矿物种在中国的首次发现。不仅如此,赛马碱性岩体也有闪叶石产出,而且,迄今已发现多个新矿物,寓示该岩体仍有良好的新矿物发现前景。  相似文献   

3.
采用常规宝石学测试、电子探针、单晶X射线衍射和拉曼光谱等方法,深入分析了尼日利亚锌尖晶石的常规宝石学特征、化学成分、晶体结构以及包裹体特征。尼日利亚锌尖晶石呈完好的八面体晶形,强玻璃光泽、半透明,相对密度为4.48~4.61,折射率为1.792~1.794,紫外荧光灯下呈惰性。通过电子探针测试,计算其化学式为Zn(0.87~0.92)Fe(0.06~0.07)Al(1.98~2.01)O4。单晶X射线衍射揭示其为立方晶系、空间群Fd3m,晶胞参数a=8.089(2)Å,四面体键长T—O=1.953(4)Å,八面体键长M—O=1.912 9(19)Å。锌尖晶石的特征拉曼吸收峰位于418 cm-1和659 cm-1,分别对应Eg模式、高频T2g(3)模式。包裹体研究显示锌尖晶石含有多种矿物包体,包括闪锌矿、钠长石、白云母、石英、绿柱石、锆石和硅铍石,结合前人研究认为尼日利亚锌尖晶石形成于富Li、Cs、Rb、Be和Ta等元素的花岗伟晶岩中。  相似文献   

4.
园珠顶铜钼矿床位于钦杭成矿带南段的大瑶山隆起北缘,为大型斑岩型铜钼矿床。通过LA-ICP-MS锆石U-Pb同位素测年,获得了花岗斑岩的高精度成岩年龄,为(154.3±1.7) Ma (n=12,MSWD=3.1),为晚侏罗世岩浆活动的产物,与辉钼矿的Re-Os同位素年龄155 Ma相吻合。岩石地球化学分析表明,园珠顶花岗斑岩高硅〔w(SiO2)为68.81%~70.21%〕、富碱〔w(Na2O)+w(K2O)为6.78%~8.01%〕、准铝质-弱过铝质(A/CNK为0.96~1.04);稀土元素总量中等(ΣREE 为142.15×10-6~170.83×10-6),富集轻稀土元素(ΣLREE 为135.05×10-6~162.34×10-6),轻重稀土元素分馏明显〔(La/Yb)N=30.97~32.10〕,弱的Eu负异常(δEu=0.86~0.89),稀土元素配分模式总体右倾;岩石相对富集Rb、K等大离子亲石元素(LILE)及高场强元素Th、U,亏损Nb、Ta、P、Ti等高场强元素(HFSE)及部分大离子亲石元素Ba、Sr。LA-MC-ICP-MS锆石Hf 的原位分析表明,176Hf/177Hf值变化于0.282 500~0.282 801之间,εHft)值介于-6.27~4.19。综合分析表明,园珠顶花岗斑岩为准铝质-弱过铝质的I型花岗岩,具有壳幔混合源成因,锆石εHft)值反映了园珠顶花岗斑岩的成岩源区较为复杂,总体具亏损岩浆源区的特征,以幔源物质为主,但在岩浆侵位过程中遭受了古老地壳物质的混染。结合区域构造背景和前人研究成果,认为园珠顶斑岩体及铜钼矿,与钦杭成矿带北段的永平铜矿具有一致的成岩成矿构造背景,形成于板块俯冲环境。  相似文献   

5.
西准噶尔巴音达拉地区发育一套酸性火山岩,被称为卡拉岗组,岩石组合以流纹岩、英安岩、流纹质熔结凝灰岩等酸性火山岩为主。本文对卡拉岗组火山岩进行高精度锆石LA-ICP-MS U-Pb测年,获得英安岩和流纹岩的加权平均206Pb/238U年龄分别为(294.4±1.3)Ma(n=9,MSWD=0.8)和(298.4±2.5)Ma(n=9,MSWD=3.4),其形成于早二叠世。岩石地球化学特征表明,卡拉岗组火山岩岩具有高硅(66.69%~75.21%),富碱(Na2O+K2O:6.98%~8.35%),低MgO(0.18%~1.32%),贫钙(0.24%~2.49%)的特征,均属过铝质(A/CNK:1.14~1.33)及高钾钙碱性系列。微量元素数据显示,稀土总量为∑REE为83.82×10-6~197.61×10-6,(La/Yb)N=3.15~12.50,轻、重稀土元素分馏比较明显,轻稀土元素(LREE)较为富集,重稀土元素分布相对平坦,球粒陨石标准化配分模式为右倾型。微量元素富集大离子亲石元素(LILE)Rb、Th、U、K,并亏损高场强元素(HFSE)Nb、Ta、P、Ti。综合最新区域资料及本文研究成果,文章认为研究区早二叠世卡拉岗组火山岩岩浆来源于壳源物质不同程度的部分熔融,残留相中有少量斜长石和角闪石,为后碰撞伸展阶段的产物。  相似文献   

6.
河南嵩县庙岭金矿区地处华北陆块南缘熊耳山-外方山地区,LA-ICP-MS锆石U-Pb定年结果表明,庙岭金矿区花岗斑岩的成岩年龄为157Ma左右。岩石地球化学数据显示岩石具有高硅,富钾、铝而贫钠,低铁、镁、钙的特征,SiO2含量为75.06%~77.66%,全碱含量(Na2O+K2O)为7.05%~7.39%;稀土元素总量较低,ΣREE=25.74×10-6~32.63×10-6,轻重稀土元素分馏明显,LREE/HREE=6.74~9.53,Eu具有中等的负异常;微量元素富集Rb、K、Pb等大离子亲石元素和Th、U,亏损Nb、Ta、Ti等高场强元素和Ba、Sr。Pb同位素分析结果显示庙岭金矿区花岗斑岩的Pb主要来自于下地壳;全岩的(87Sr/86Sr)i=0.706207~0.711774,εNd(t)值变化于-19.0~-17.8之间,tDM2=2.39~2.49Ga。岩石地球化学和Sr-Nd-Pb同位素组成特征显示庙岭金矿区花岗斑岩的源区物质主要来自于古老下地壳,可能为太古宙太华群。  相似文献   

7.
辽西义县盆地早白垩世义县组陆相湖盆沉积中常发育多个薄层碳酸盐岩沉积层,碳酸盐岩地球化学的研究对揭示湖盆沉积古环境具有重要理论意义。义县组砖城子层英窝山剖面湖相碳酸盐岩分析结果显示,岩石δ13C值为-3.44×10-3~0.27×10-3,均值为-1.21×10-3;δ18O值为-15.73×10-3~-9.93×10-3,均值为-10.88×10-3。盐度Z值变化范围114.78~122.39。碳酸盐岩主量元素分析表明,w(CaO+MgO+LOI)=53.38%~97.04%,均值71.15%;陆源组分w(Al2O3+SiO2+Fe2O3)=2.19%~44.87%,均值为27.77%;x(Mg)/x(Ca)摩尔比介于0.92~1.01。碳酸盐岩微量元素地球化学提供了古湖泊学的古盐度、氧化还原和古气候证据。w(Sr)=110.4×10-6~1360.2×10-6,w(Ga)=0.152×10-6~14.13×10-6,w(Sr)/w(Ba)=0.34~131.49(多数>1),指示沉积湖泊水体为咸水环境;氧化-还原指标w(V)/w(V+Ni)=0.51~0.83,w(V)/w(Cr)=1.59~8.28(多数>2.0),w(U)/w(Th)=0.39~10.24,且变化范围较大,指示为半封闭—封闭的缺氧还原强分层水体沉积环境;w(Sr)/w(Cu)=54.94~1260.71,均值为213.79,反映炎热干旱气候类型。义县组砖城子层沉积期湖泊为干旱古气候背景下的半咸水—咸水、缺氧还原强分层的半封闭—封闭型。  相似文献   

8.
新疆拜城县波孜果尔A型花岗岩类岩体位于塔里木地台北缘及邻区的近东西向碱性侵入岩带上,主要岩石类型为霓石钠闪石英碱长正长岩、霓石钠闪碱长花岗岩、黑云母碱长正长岩。全岩SiO2=68.97%~74.14%,Na2O+K2O=9.67%~11.19%,Al2O3=13.72%~15.26%,Fe2O3=0.18%~1.41%,FeO=0.91%~1.51%,CaO=0.35%~0.63%。稀土元素总量较高,ΣREE=298×10-6~1286×10-6,平均706×10-6,轻稀土富集,重稀土亏损,强烈的Eu负异常,呈“右倾海鸥型”的稀土元素配分模式。富Nb、Ta、Zr、Hf等高场强元素,亏损Ba、K、Sr等大离子亲石元素,Zr+Nb+Ce+Y=936×10-6~3684×10-6,平均1813×10-6。为A1型花岗岩。岩体形成于早二叠纪。锆石LA-ICP-MS U-Pb年龄为287.7~291.6Ma,平均289.8Ma,岩体形成后,在279.1~282Ma左右经历了后期热液流体的改造。锆石εHft)值为-6.3~9.0,两阶段模式年龄(tDM2)跨越古元古代晚期-新元古代中期,主要集中在中元古代。岩浆平均温度832~839℃,形成于非造山的板内构造环境,且具高温、无水、低氧逸度的成岩特点。该岩体具有壳幔混源的特点。  相似文献   

9.
曲林岩体位于冈底斯带中段的南缘,为渐新世-中新世复合岩体,主体为粗粒花岗斑岩,被后期煌斑质、花岗闪长质和花岗质岩脉切割,是多期岩浆作用的产物,出露面积约8km2。花岗斑岩两组样品(T0849-PG和T0849-G)的锆石U-Pb定年结果分别为29.7±0.1Ma和30.0±0.2Ma。花岗斑岩为高钾,准铝质,低MgO,高度富集轻稀土元素(LREE)和大离子亲石元素(LILE),亏损重稀土元素(HREE)和高场强元素(HFSE)。此外具有高Sr、Sr/Y、(La/Yb)N;低Y和Yb,弱Eu负异常等特征。岩体内发育一系列近南北向展布的花岗闪长玢岩脉,其中两组样品的锆石U-Pb定年结果分别为15.5±0.1Ma(T0848-PY)和14.4±0.1Ma(T0850)。两条花岗闪长玢岩脉具有与岩体主体相似的稀土和微量元素分布模式,同样富集轻稀土及大离子亲石元素,亏损重稀土及高场强元素。花岗斑岩的87Sr/86Sr(i)=0.706102~0.706202,εNdt)=-0.6~+0.6,锆石εHft)=+4.9~+7.9;花岗闪长玢岩脉的87Sr/86Sr(i)=0.705429~0.705474,εNdt)=-1.4~-0.2,锆石εHft)=+2.6~+7.6。本文数据和文献数据结果表明:曲林花岗斑岩与花岗闪长玢岩脉均来源于加厚南拉萨下地壳的部分熔融,很可能与增厚的深部岩石圈的拆沉或俯冲印度岩石圈的撕裂诱发软流圈上涌有关。  相似文献   

10.
北秦岭太白山晚中生代正长花岗岩成因及其地质意义   总被引:1,自引:1,他引:0  
张志华  赖绍聪  秦江锋 《岩石学报》2014,30(11):3242-3254
本文对北秦岭中段太白岩体北部正长花岗岩进行了系统研究.结果表明,岩石为高钾钙碱性I型花岗岩,SiO2=68.49%~72.84%,富Al2O3(14.13%~16.48%),相对富K2O,K2O/Na2O=0.45~1.57(多数样品大于1),A/CNK=0.97~1.05,属于准铝质-铝质系列.岩石富集大离子亲石元素(LILE),亏损高场强元素(HFSE),具弱负Eu 异常(δEu=0.58~0.89),高Sr、低Yb/Y.正长花岗岩锶同位素初始比值ISr=0.7053~0.7112,εNd(t)=-18.6~-0.1(平均为-9.2),二阶段模式年龄t2DM值为0.83~2.11Ga,变化较大,显示其源区主要为古老的壳源物质.铅同位素比值206Pb/204Pb=17.492~17.524,207Pb/204Pb=15.470~15.485,208Pb/204Pb=37.750~38.097,与南秦岭基底相近.锆石U-Pb年龄为153.17±0.89Ma和151.0±1.4Ma,形成于晚中生代.太白正长花岗岩源于古老地壳物质的部分熔融,并有年轻幔源组分的参与,形成于挤压向伸展转换的深部动力学背景.  相似文献   

11.
Pant-y-ffynnon Quarry in South Wales yielded a rich cache of fossils in the early 1950s, including articulated specimens of new species (the small sauropodomorph dinosaur Pantydraco caducus and the crocodylomorph Terrestrisuchus gracilis), but no substantial study of the wider fauna of the Pant-y-ffynnon fissure systems has been published. Here, our overview of existing specimens, a few described but mostly undescribed, as well as freshly processed material, provides a comprehensive picture of the Pant-y-ffynnon palaeo-island of the Late Triassic. This was an island with a relatively impoverished fauna dominated by small clevosaurs (rhynchocephalians), including a new species, Clevosaurus cambrica, described here from a partially articulated specimen and isolated bones. The new species has a dental morphology that is intermediate between the Late Triassic Clevosaurus hudsoni, from Cromhall Quarry to the east, and the younger C. convallis from Pant Quarry to the west, suggesting adaptive radiation of clevosaurs in the palaeo-archipelago. The larger reptiles on the palaeo-island do not exceed 1.5?m in length, including a small carnivorous crocodylomorph, Terrestrisuchus, and a possible example of insular dwarfism in the basal dinosaur Pantydraco.  相似文献   

12.
Lithostratigraphy, physicochemical stratigraphy, biostratigraphy, and geochronology of the 77–70 Ma old series bracketing the Campanian–Maastrichtian boundary have been investigated by 70 experts. For the first time, direct relationships between macro- and microfossils have been established, as well as direct and indirect relationships between chemo-physical and biostratigraphical tools. A combination of criteria for selecting the boundary level, duration estimates, uncertainties on durations and on the location of biohorizons have been considered; new chronostratigraphic units are proposed. The geological site at Tercis is accepted by the Commission on Stratigraphy as the international reference for the stratigraphy of the studied interval. To cite this article: G.S. Odin, C. R. Geoscience 334 (2002) 409–414.  相似文献   

13.
Robert L. Linnen   《Lithos》2005,80(1-4):267-280
The solubilities of columbite, tantalite, wolframite, rutile, zircon and hafnon were determined as a function of the water contents in peralkaline and subaluminous granite melts. All experiments were conducted at 1035 °C and 2 kbar and the water contents of the melts ranged from nominally dry to approximately 6 wt.% H2O. Accessory phase solubilities are not affected by the water content of the peralkaline melt. By contrast, solubilities are affected by the water content of the subaluminous melt, where the solubilities of all the accessory phases examined increase with the water content of the melt, up to 2 wt.% H2O. At higher water contents, solubilities are nearly constant. It can be concluded that water is not an important control of accessory phase solubility, although the water content will affect diffusivities of components in the melt, thus whether or not accessory phases will be present as restite material. The solubility behaviour in the subaluminous and peralkaline melts supports previous spectroscopic studies, which have observed differences in the coordination of high field strength elements in dry vs. wet subaluminous granitic glasses, but not for peralkaline granitic glasses. Lastly, the fact that wolframite solubility increases with increasing water content in the subaluminous melt suggests that tungsten dissolved as a hexavalent species.  相似文献   

14.
Some olistolites reworked in a Tertiary flysch of Mount Parnon (Peloponnesus, Greece) exhibit a Late Permian assemblage, dominated by Paradunbarula (Shindella) shindensis, Hemigordiopsis cf. luquensis and Colaniella aff. minima. This association corresponds to the Late Wuchiapingian (=Late Dzhulfian), a substage whose algae and foraminifera are generally little known. Contemporaneous limestones crop out in the middle part of the Episkopi Formation in Hydra, but they are rather commonly reworked in Mesozoic and Cainozoic sequences. The palaeobiogeographical affinities shared by the foraminiferal markers of Greece, southeastern Pamir, and southern China, are very strong (up to the specific level), and are congruent with the Pangea B reconstructions. To cite this article: E. Skourtsos et al., C. R. Geoscience 334 (2002) 925–931.  相似文献   

15.
PALEONTOLOGY     
正20141596 Liu Yunhuan(School of Earth Sciences and Resources,Chang’an University,Xi’an 710054,China);Shao Tiequan Early Cambrian Quadrapyrgites Fossils of Xixiang Boita in Southern Shaanxi Province(Journal of Earth Sciences and Environment,ISSN1672-6561,CN61-1423/P,35(3),2013,p.39-43,3 illus.,20 refs.)  相似文献   

16.
正20141719 Chen Zhijun(State Key Laboratory of Geological Processes and Mineral Resources,China University of Geosciences,Wuhan 430074,China);Chen Jianguo Automated Batch Mapping Solution for Serial Maps:A Case Study of Exploration Geochemistry Maps(Journal of Geology,ISSN1674-3636,CN32-1796/P,37(3),2013,p.456-464,2 illus.,2 tables,10 refs.)  相似文献   

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正20140962 Chen Fenning(Xi’an Institute of Geology and Mineral Resources,Xi’an710054,China);Chen Ruiming Late Miocene-Early Pleistocene Ostracoda Fauna of Gyirong Basin,Southern Tibet(Acta Geologica Sinica,ISSN0001-5717,CN11-1951/P,87(6),2013,p.872-886,6illus.,56refs.)  相似文献   

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PETROLOGY     
正1.IGNEOUS PETROLOGY20142008Cai Jinhui(Wuhan Center,China Geological Survey,Wuhan 430205,China);Liu Wei Zircon U-Pb Geochronology and Mineralization Significance of Granodiorites from Fuzichong Pb-Zn Deposit,Guangxi,South China(Geology and Mineral Resources of South China,ISSN1007-3701,CN42-1417/P,29(4),2013,p.271-281,7illus.,  相似文献   

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正20141205Cheng Weiming(State Key Laboratory of Resources and Environmental Information System,Institute of Geographic Sciences and Natural Resources Research,CAS,Beijing 100101,China);Xia Yao Regional Hazard Assessment of Disaster Environment for Debris Flows:Taking Jundu Mountain,Beijing as an  相似文献   

20.
正20141266Fan Chaoyan(Guangdong Provincial Key Laboratory of Mineral Resources and Geological Processes,Guangzhou 510275,China);Wang Zhenghai On Error Analysis and Correction Method of Measured Strata Section with Wire Projection Method(Journal of  相似文献   

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