粤北白沙地区晚侏罗世高分异I型细粒花岗岩年代学、地球化学特征及其地质意义

受东西向佛冈-丰良断裂控制的佛冈复式岩体形成于多期次和不同来源的岩浆侵入作用。白沙地区细粒黑云母二长花岗岩体位于佛冈岩体北缘,是佛冈岩体的一部分,成因目前还不明确。文章以该岩体细粒黑云母二长花岗岩为研究对象,进行了岩石学、锆石U-Pb年代学、地球化学和Hf同位素组成研究。研究结果显示,白沙地区细粒黑云母二长花岗岩LA-ICP-MS锆石U-Pb加权平均年龄为155.6~157.1 Ma,表明其侵位于晚侏罗世。岩体具高硅（w（SiO₂）=70.74%~77.47%）、富碱（w（Na₂O+K₂O）=5.78%~8.62%）、低磷（w（P₂O₅）=0~0.10）等特征,富集Rb、Th、U、K、Pb、Nd、Zr和Hf等元素,亏损Ba、Nb、La、Ce、Sr、P、Eu和Ti等元素。岩石总体上明显富集轻稀土元素（（La/Yb）_N=0.94~54.69,1个为0.94）,具明显的负Eu异常（δEu=0.07~0.57,n=6）,个别正Eu异常（1.00~1.16,n=3）。岩体地球化学特征指示,细粒黑云母二长花岗岩为高分异I型花岗岩。岩体形成于古太平洋板块（库拉板块）与欧亚板块俯冲作用和菲律宾地块与南中国-印支地块的岩石圈消减作用下,岩石圈伸展-减薄,导致地幔物质上涌,在高温条件热流作用下幔源物质诱导下地壳中-元古代物质部分熔融形成。     

辽西早白垩世义县组砖城子层湖相碳酸盐岩地球化学特征及古湖泊学沉积意义

辽西义县盆地早白垩世义县组陆相湖盆沉积中常发育多个薄层碳酸盐岩沉积层,碳酸盐岩地球化学的研究对揭示湖盆沉积古环境具有重要理论意义。义县组砖城子层英窝山剖面湖相碳酸盐岩分析结果显示,岩石δ¹³C值为-3.44×10^-3~0.27×10^-3,均值为-1.21×10^-3;δ¹⁸O值为-15.73×10^-3~-9.93×10^-3,均值为-10.88×10^-3。盐度Z值变化范围114.78~122.39。碳酸盐岩主量元素分析表明,w（CaO+MgO+LOI）=53.38%~97.04%,均值71.15%;陆源组分w（Al₂O₃+SiO₂+Fe₂O₃）=2.19%~44.87%,均值为27.77%;x（Mg）/x（Ca）摩尔比介于0.92~1.01。碳酸盐岩微量元素地球化学提供了古湖泊学的古盐度、氧化还原和古气候证据。w（Sr）=110.4×10^-6~1360.2×10^-6,w（Ga）=0.152×10^-6~14.13×10^-6,w（Sr）/w（Ba）=0.34~131.49（多数>1）,指示沉积湖泊水体为咸水环境;氧化-还原指标w（V）/w（V+Ni）＝0.51~0.83,w（V）/w（Cr）＝1.59~8.28（多数>2.0）,w（U）/w（Th）=0.39~10.24,且变化范围较大,指示为半封闭—封闭的缺氧还原强分层水体沉积环境;w（Sr）/w（Cu）=54.94~1260.71,均值为213.79,反映炎热干旱气候类型。义县组砖城子层沉积期湖泊为干旱古气候背景下的半咸水—咸水、缺氧还原强分层的半封闭—封闭型。     

班公湖-怒江缝合带东段丁青地幔橄榄岩成因:来自钻孔ZK02地幔橄榄岩矿物学及地球化学特征约束

丁青蛇绿岩位于班公湖-怒江缝合带东段,是该缝合带出露面积最大的蛇绿岩。为查明岩体成因,在丁青东岩体中实施了一口165.19m的钻孔。除最顶部有约0.5m厚的第四系残坡积物外,其余均为地幔橄榄岩。结合显微镜鉴定将岩心划分出17个岩性单元层,岩性主要以方辉橄榄岩为主,夹少量纯橄岩和含铬铁矿纯橄岩。地幔橄榄岩中橄榄石的Fo变化于88.79~93.73,铬尖晶石的Cr^#变化于44.33~81.66,揭示丁青地幔橄榄岩可能经历过约20%~40%的中高度部分熔融作用;全岩地球化学分析表明其具有富镁（MgO=45.98%~49.45%）、贫铝（Al₂O₃=0.19%~1.37%）和贫钙（CaO=0.28%~0.70%）的特点,属于熔融程度较高的地幔残余物质。岩石具有明显不同于阿尔卑斯蛇绿岩的轻稀土元素富集特征,指示区内地幔橄榄岩先经历了较强程度的部分熔融,后经历了俯冲消减过程中的流体交代。利用地幔橄榄岩中的铬尖晶石成分计算母熔体Al₂O₃含量对应的FeO/MgO值,与不同构造环境原始岩浆成分相比较,发现丁青地幔橄榄岩母熔体大多处于玻安岩中。纯橄岩氧逸度估算FMQ=-3.05~-0.71,方辉橄榄岩氧逸度FMQ=-3.89~+1.47,显示丁青地幔橄榄岩有俯冲作用的参与。通过丁青钻孔岩心的研究,提出丁青东岩体可能形成于俯冲带之上的弧前环境这一观点。     

天宇铜镍矿床的岩相学、锆石U-Pb年代学、地球化学特征：对东疆镁铁-超镁铁质岩体源区和成因的制约

天宇镁铁-超镁铁质岩体位于新疆中天山地块与觉罗塔格构造带的分界断裂——沙泉子深大断裂的南侧约5km。岩体呈向北陡倾的岩墙状,地表出露面积约0.056km²。该杂岩体主要由辉长岩、辉石岩、辉橄岩和橄榄岩相组成,橄辉岩、辉橄岩和橄榄岩是主要的Cu、Ni赋矿岩相。镁铁-超镁铁岩的主量元素含量显示,天宇岩体属拉斑玄武岩成因系列,m/f为1.44~3.61,平均值为2.25,为铁质超基性岩（m/f=2~6.5）。稀土元素标准化配分模式为轻稀土富集型,Eu弱负异常或无异常,相似的稀土元素配分模式说明岩体的同源性。富集大离子亲石元素,亏损高场强元素Nb、Ta,说明源区可能有陆壳物质的混染。Nb/Hf、Ce/Pb、Nb/U、La/Sm、Th/Nb比值显示岩体可能经受上地壳物质的混染。锆石的LA-ICP-MS U-Pb年代学研究表明,岩体形成年龄为290.2±3.4Ma,与东天山地区镁铁-超镁铁质杂岩体的形成时间一致。锆石的Lu/Hf比值比较均一,且(¹⁷⁶Hf/¹⁷⁷Hf) _i变化很小,说明源区性质比较单一。锆石的(¹⁷⁶Hf/¹⁷⁷Hf) _i值为0.282625~0.282770,相应的ε_Hf(t)均为正值（1.10~6.06）,Lu-Hf的单阶段模式年龄（t_DM1）为674~884.7Ma,平均年龄为799Ma,比岩体的U-Pb年龄大,显示岩浆来源于亏损地幔或者源区有壳源物质的加入。上述岩石地球化学、年代学特征,为晚古生代古亚洲洋向南俯冲提供了佐证。     

川西松林口岩体锆石U-Pb定年及其地球化学特征

松林口岩体位于松潘—甘孜造山带中东部,为确定岩体的侵位时代和地球化学特征,通过镜下薄片观察、主微量元素分析以及锆石U-Pb测年,对松林口岩体进行了研究。结果表明,松林口岩体由二长花岗岩体和花岗闪长岩体组成,花岗闪长岩锆石²⁰⁶Pb/²³⁸U年龄加权平均值为（212.4±0.9） Ma （MSWD=0.66）,二长花岗岩锆石²⁰⁶Pb/²³⁸U年龄加权平均值为（222.4±1.1） Ma （MSWD=0.39）,形成于晚三叠世,由两期次岩浆作用形成;岩石的SiO₂含量56.56%~61.97%;铝饱和指数A/CNK=0.93~1.05,全碱含量3.78~5.38,K₂O/Na₂O=1.02~1.68,里特曼指数σ=1.194~1.612,样品属于准铝质中—高钾钙碱性岩系列。岩石轻重稀土比值LREE/HREE=5.22~7.13,La_N/Yb_N比值为6.93~8.96,轻、重稀土分异较明显,具较强的负Eu异常。岩石Mg^#值较高（50.97~61.27）,w（Rb）/w（Sr）为0.12~0.25,Rb-（Y+Nb）图解显示为后碰撞环境。因此,松林口二长花岗岩—花岗闪长岩属后碰撞准铝质中—高钾钙碱性I型花岗岩类。     

栖霞牙山花岗岩及其暗色包体地球化学特征及成因研究

栖霞牙山花岗岩体形成于中生代早白垩世（118 Ma）,其岩石类型以花岗岩和花岗闪长岩为主,岩体中发育大量的暗色闪长质微粒包体。通过对牙山花岗岩及其暗色包体地球化学特征研究表明,包体围岩w（SiO₂）=65.5%~68.82%,铝饱和度（A/CNK）为0.89~1.03<1.1,为准铝质钙碱性Ⅰ型花岗岩;暗色包体具有较低w（SiO₂）值（54.82%~60.89%）、高w（TFe₂O₃）值（6.11%~8.15%）、高w（MgO）值（3.57%~5.19%）的特征。稀土元素配分模式图显示二者皆为轻稀土富集的右倾型曲线,微量元素蛛网图中二者均表现为富集Ba、K等大离子亲石元素,亏损Ta、Nb、Ti等高场强元素,具有大陆地壳的特征。暗色包体与寄主岩石的Sr同位素初始比值（⁸⁷Sr/⁸⁶Sr）_i分别为0.709 29~0.709 58和0.709 21~0.709 71,应为同源岩浆的产物。两阶段Nd模式年龄（T_2DM）分为2 291 Ma-2 391 Ma和2 208 Ma-2 353 Ma,表明可能是古元古界陆壳物质部分熔融的产物。Pb同位素特征显示牙山岩体的原始岩浆以下地壳为主,w（Nb）/w（Ta）值介于下地壳与原始地幔之间,表明可能受到幔源物质的影响,包体中大量磷灰石呈针状结晶状态,进一步暗示存在岩浆混合作用。综上并结合区域构造背景认为,牙山岩体为早白垩世中晚期起源于火山弧环境的壳源特征花岗岩,形成过程中存在幔源物质的加入,它的形成与太平洋板块的俯冲作用密切相关。     

胶东海阳所超镁铁岩中强亲铁元素的地球化学特征及其构造环境探讨

强亲铁元素与亲石元素具有不同的地球化学行为，因此能够从不同的角度为造山带中超镁铁岩的成因及演化提供重要信息。位于苏鲁造山带东北端的胶东海阳所超镁铁岩主要由橄榄岩和辉石岩组成，它们常以团块状赋存于花岗质片麻岩中。虽然前人对这些超镁铁岩已经开展大量岩石学研究，但关于其成因及构造属性仍存在较大争议。本文开展了海阳所超镁铁岩的全岩主微量元素、强亲铁元素及Re-Os同位素的分析工作，结果显示蛇纹石化橄榄岩具有较高的MgO和Fe₂O₃^T含量，较低的Al₂O₃、TiO₂和CaO含量，明显富集流体迁移元素（U、Pb），亏损高场强元素（Zr、Hf），强亲铁元素没有发生明显分异，但Ru显示正异常，表明海阳所蛇纹石化橄榄岩是经历了低-中等程度部分熔融及熔/流体交代作用影响的残余地幔橄榄岩。海阳所辉石岩的主量元素表现出明显的结晶分异特征，稀土元素较原始地幔富集，铂族元素（PGEs）含量较低且发生了明显的分异，表明辉石岩的地幔源区经历过高程度的部分熔融和硫化物的分离。海阳所蛇纹石化橄榄岩的Os同位素地球化学特征表现出大洋亲和性，与辉石岩不具有熔体-残留体的关系。由于该地区发育较深层次的韧性剪切带，蛇纹石化橄榄岩中的橄榄石与辉石表现出韧性变形的特征，同时有辉石岩侵入到橄榄岩的现象，表明该地区的蛇纹石化地幔橄榄岩与辉石岩既不同时，也不同源，因此，暗示了该套岩石组合可能形成于大洋核杂岩（OCC）与洋脊型蛇绿岩（MOR）堆晶岩交互发育环境。     

辽北西丰地区晚侏罗世营厂岩体LA-ICP-MS锆石U-Pb年龄及岩石地球化学特征

营厂岩体分布于辽北西丰县和隆镇境内，研究结果表明，该岩体主要为似斑状二长花岗岩，锆石²⁰⁶Pb/²³⁸U年龄加权平均值为156.1 Ma±1.5 Ma，形成时代为晚侏罗世。营厂岩体w（Na₂O）/w（K₂O）平均值为1.07，属高钾钙碱性系列；里特曼指数σ平均值为2.15，属钙碱系列；铝饱和指数A/CNK平均值为1.16，A/CN平均值为1.99，属过铝型；Rb、Sr、Ba、Th、Hf含量偏高，Cr、Ni、Co、V、Rb、Zr、Nb等元素含量低，为"S"型花岗岩特征。稀土元素总量平均值为w（ΣREE）＝82.80×10^-6，w（LREE）/w（HREE）=15.76，w（La）_N/w（Yb）_N=24.32，表明其轻稀土相对富集，重稀土相对亏损，稀土配分曲线右倾。δEu=0.80，铕弱负异常，说明成因与板块运动有关，w（Sm）/w（Nd）=0.20，w（Ba）/w（Sr）=1.60，w（K）/w（Rb）=249.15，表明具有壳源性质。营厂岩体具有埃达克岩的特点，其属于受太平洋板块向欧亚板块俯冲作用的影响，在挤压环境下加厚下地壳部分熔融，从而形成活动陆缘型花岗岩。     

新疆图拉尔根镁铁-超镁铁质杂岩体镍铜钴成矿岩浆作用过程:流体化学与碳同位素组成制约

东天山造山带的图拉尔根镁铁-超镁铁杂岩体为一个早古生代长期活动的幔源岩浆通道,大型铜镍钴硫化物矿体赋存于Ⅰ号超镁铁质岩体的顶部,不同类型岩石中辉石矿物的流体挥发份化学组成以H₂O为主（平均91%,5400.4mm³/g）,其次为H₂（2.0%）、H₂S（2.3%）和CO₂（2.1%）;赋矿角闪橄榄岩中CO₂和H₂S含量最高,辉长岩中流体挥发份含量低于辉石橄榄岩和橄榄辉石岩等岩浆早期结晶的岩石。CO₂和CH₄的δ¹³C值位于地壳与甲烷氧化的范围内,甲烷同系物的碳同位素组成具有正序分布模式,部分样品（TLG512）释出的CH₄和C₂H₆具有较重的δ¹³C值和反序分布特征。表明I号岩体不同类型岩石可能是不同期次岩浆活动的产物,成矿岩浆具有富H₂O和H₂S的特征,可能起源于被流体交代的亏损地幔源区,混染壳源组分可能为俯冲板片来源蚀变沉积有机质组分。     

新疆天山地区榆树沟-铜花山蛇绿岩特征和构造背景

榆树沟-铜花山蛇绿岩出露于南天山北缘,属哈萨克斯坦-伊犁板块和塔里木板块之间的缝合带。蛇绿岩已被构造肢解,主要由超镁铁岩、堆晶岩、熔岩类组成。超镁铁岩以方辉橄榄岩为主,显示典型的亏损地幔岩特征,橄榄石为富镁型,Fo为90;斜方辉石为顽火辉石,En为90,单斜辉石含量少;副矿物铬尖晶石属低铬型,Cr^#值(＝Cr/(Cr+Al)×100)16~28,Mg^#值(=Mg/(Mg+Fe)×100)63~75,反映了深海橄榄岩特征。归一化后榆树沟超镁铁岩MgO含量38.84%~44.53%,Al₂O₃为1.51%~3.63%,CaO为0.42%~5.77%,成分近于大洋二辉橄榄岩;铜花山的超镁铁岩叠加碳酸岩化,LREE强烈富集,可能经历了俯冲洋壳流体改造。熔岩类在榆树沟和铜花山均有较大规模产出,其中榆树沟玄武岩为主,铜花山安山岩和英安岩较多。熔岩多已遭受绿片岩相海底热液蚀变。榆树沟玄武岩的REE含量总体比铜花山的低,稀土配分模式均为轻稀土富集型;玄武岩的微量元素特征表明其源区可能遭受过流体作用影响。铜花山三个高镁火山岩化学成份具有SiO₂(32%~36%)含量很低、MgO(20.12%~28.50%)含量高、K₂O+Na₂O(0.06%~0.46%)含量小于2%的特征,综合分析可归为苦橄岩类。堆晶岩通常以构造小岩块产在超镁铁岩块中或基性熔岩中,以辉长岩为主,有少量橄榄辉石岩等,岩石蚀变、构造变形强烈。堆晶岩的成分接近玄武岩,存在LREE富集和略亏损平坦两种类型。岩石地球化学特征表明榆树沟和铜花山的蛇绿岩形成于MOR构造环境,但具有受俯冲带流体改造特征,并伴生有岛弧火山岩。     

The terrestrial fauna of the Late Triassic Pant-y-ffynnon Quarry fissures,South Wales,UK and a new species of Clevosaurus (Lepidosauria: Rhynchocephalia)

Pant-y-ffynnon Quarry in South Wales yielded a rich cache of fossils in the early 1950s, including articulated specimens of new species (the small sauropodomorph dinosaur Pantydraco caducus and the crocodylomorph Terrestrisuchus gracilis), but no substantial study of the wider fauna of the Pant-y-ffynnon fissure systems has been published. Here, our overview of existing specimens, a few described but mostly undescribed, as well as freshly processed material, provides a comprehensive picture of the Pant-y-ffynnon palaeo-island of the Late Triassic. This was an island with a relatively impoverished fauna dominated by small clevosaurs (rhynchocephalians), including a new species, Clevosaurus cambrica, described here from a partially articulated specimen and isolated bones. The new species has a dental morphology that is intermediate between the Late Triassic Clevosaurus hudsoni, from Cromhall Quarry to the east, and the younger C. convallis from Pant Quarry to the west, suggesting adaptive radiation of clevosaurs in the palaeo-archipelago. The larger reptiles on the palaeo-island do not exceed 1.5?m in length, including a small carnivorous crocodylomorph, Terrestrisuchus, and a possible example of insular dwarfism in the basal dinosaur Pantydraco.     

Définition d'une limite multicritère ; stratigraphie du passage Campanien–Maastrichtien du site géologique de Tercis (Landes,SW France)Definition of a multi-criteria boundary; stratigraphy of the Campanian–Maastrichtian interval of the geological site at Tercis (Landes,SW France)

Lithostratigraphy, physicochemical stratigraphy, biostratigraphy, and geochronology of the 77–70 Ma old series bracketing the Campanian–Maastrichtian boundary have been investigated by 70 experts. For the first time, direct relationships between macro- and microfossils have been established, as well as direct and indirect relationships between chemo-physical and biostratigraphical tools. A combination of criteria for selecting the boundary level, duration estimates, uncertainties on durations and on the location of biohorizons have been considered; new chronostratigraphic units are proposed. The geological site at Tercis is accepted by the Commission on Stratigraphy as the international reference for the stratigraphy of the studied interval. To cite this article: G.S. Odin, C. R. Geoscience 334 (2002) 409–414.     

The effect of water on accessory phase solubility in subaluminous and peralkaline granitic melts

The solubilities of columbite, tantalite, wolframite, rutile, zircon and hafnon were determined as a function of the water contents in peralkaline and subaluminous granite melts. All experiments were conducted at 1035 °C and 2 kbar and the water contents of the melts ranged from nominally dry to approximately 6 wt.% H₂O. Accessory phase solubilities are not affected by the water content of the peralkaline melt. By contrast, solubilities are affected by the water content of the subaluminous melt, where the solubilities of all the accessory phases examined increase with the water content of the melt, up to 2 wt.% H₂O. At higher water contents, solubilities are nearly constant. It can be concluded that water is not an important control of accessory phase solubility, although the water content will affect diffusivities of components in the melt, thus whether or not accessory phases will be present as restite material. The solubility behaviour in the subaluminous and peralkaline melts supports previous spectroscopic studies, which have observed differences in the coordination of high field strength elements in dry vs. wet subaluminous granitic glasses, but not for peralkaline granitic glasses. Lastly, the fact that wolframite solubility increases with increasing water content in the subaluminous melt suggests that tungsten dissolved as a hexavalent species.     

Quaternary stresses revealed by calcite twinning inversion: insights from observations in the Savonnières underground quarry (eastern France)

Calcite samples were extracted both from the rock matrix and the superficial coating of a karstified fault plane of an underground quarry, located in the eastern border of the Paris basin. The karstification is dated as Quaternary. Analysis of mechanical calcite twinning reveals that only the calcite matrix has also undergone a compression trending WNW that can be attributed to the Mio-Pliocene alpine collision. Both coating and matrix have undergone a strike-slip regime with σ₁ roughly trending north–south, that could correspond to the regional present-day state of stress, a strike-slip compression rather trending NNW, modified by local phenomena. To cite this article: M. Rocher et al., C. R. Geoscience 335 (2003).     

HYDROGEOLOGY

正20141756 Chen Ruige(Mathematical College,China University of Geosciences,Beijing100083,China);Zhou Xun Numerical Simulation of Groundwater Level Fluctuation in a Coastal Confined Aquifer with Sloping Initial Groundwater Level Induced by the Tide(Geological Bulletin of China,ISSN1671-2552,CN11-4648/P,32(7),2013,p.1099-1104,6 illus.,16 refs.) Key words:confined water,groundwater level     

METAMORPHIC PETROLOGY

正20141408 Cai Jia(Institute of Geology,Chinese Academy of Geological Sciences,Beijing100037,China);Liu Fulai Petrogenesis and Metamorphic P-T Conditions of Garnet-Spinel-Biotitebearing Paragneiss in Danangou Area,Daqingshan-Wulashan Metamorphic Complex Belt(Acta Petrologica Sinica,ISSN1000-0569,CN11-1922/P,29(7),     

SERIALS

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GEOPHYSICAL EXPLORATION

正20142386An Guoying(China Aero Geophysical Survey and Remote Sensing Center for Land and Resources,Beijing 100083,China)Application of Satellite Remote Sensing in Regional Hydrogeological Investigation:Taking Cenozoic Strata in Wenquan Sheet(1∶250 000)of Karakoram Range as an Example(Geosci-     

QUATERNARY GEOLOGY & GEOMORPHOLOGY

正20141016An Chengbang(Key Laboratory of Western China’s Environmental Systems,Ministry of Education,Lanzhou University,Lanzhou 730000,China);Zhao Yongtao Lake Records during the Last Glacial Maximum from Xinjiang,NW China and Their Climatic Impli-     

PETROLEUM GEOLOGY

正20141538 Cao Qing(School of Earth Sciences and Engineering,Xi’an Petroleum University,Xi’an 710065,China);Zhao Jingzhou Characteristics and Significance of Fluid Inclusions from Majiagou Formation,Yichuan Huangling Area,Ordos Basin(Advances in Earth Science,ISSN1001-8166,CN62-1091/P,28(7),2013,p.819-828,7 illus.,3 tables,43 refs.)