藏南定日白垩纪火山岩岩石学与地球化学初步研究

本文描述了西藏定日白垩纪火山岩的地质、岩石学、岩石地球化学特征和构造造背景。该火山岩岩石类型有蚀变英安岩和蚀变安山岩,其岩石化学成分特征表明岩石为二氧化硅过饱、铝过饱和类型,属亚碱性拉斑玄武岩系列。岩石稀土元素配分曲线呈强烈右倾的轻稀土富集型;微量元素配分模式图呈锯齿状“多隆起”型,类似于岛弧火山岩的微量元素配分模式。综合判定该期火山岩形成于大陆边缘造山带岛弧构造环境。     

青海省中灶火地区鄂拉山组火山岩地球化学特征及构造环境

分析研究认为,中灶火地区分布的鄂拉山组火山岩为中酸性、亚碱性之钙碱性系列高钾低钛型的火山岩;火山岩的稀土元素总量变化较大（139.45×10^-6~219.55×10^-6）,轻稀土元素相对富集（LREE/HREE在7.695~13.46之间,平均为9.09）,稀土元素配分曲线均呈现右倾较缓的平滑线.δEu值在0.53~0.83之间,具有弱负Eu异常;岩石微量元素配分图中曲线型式基本一致,反映了该区火山岩的同源性.通过构造环境分析认为,区内鄂拉山组火山岩形成于挤压碰撞作用形成的岩浆弧.     

库鲁克塔格地区火山岩的岩浆过程与源区组成

在新疆库鲁克塔格地区的震旦纪和寒武纪沉积岩地层中,分布有四层火山岩。它们分别产出于早震旦世的贝义西组、晚震旦世的扎摩克提组和水泉组以及早寒武芤的西山布拉克组。其中,西山布拉克组和水泉组火山岩均属碱性玄武岩系列;扎摩克提组火山岩分属碱性玄武岩系列和拉斑玄武岩系列;贝义西组火山岩具有明显的双峰式组合特征,大部分属碱性火山岩。它们的多元素配分曲线均同板内玄武岩的大隆起特征。斜长石的分离结晶作用导致少部分     

湘南两江口火山岩的时代及其与西山岩体的成因联系

两江口酸性火山岩和西山花岗岩体的地球化学特征相似，物质来源与成因相同。从火山岩至西山岩体早、中、晚次单元花岗岩有明显的演化趋势，它们具有同时代、同源岩浆喷发→超浅成→浅成→中深侵入连续过程产物的特点。根据火山岩内沉积夹层所产古生物及孢粉组合和西山岩体已获对应性好的同位素年龄值推论，两江口酸性火山岩与西山花岗岩体的形成时代为中侏罗世中期至晚期初。     

云南龙脖河铜矿区变火山岩地球化学再研究

龙脖河铜矿床位于滇中地区红河成矿带南段,矿区火山岩发育、与铜矿化时空密切共生。区内火山岩遭受了不同程度的蚀变或区域变质作用,根据矿物组合可分为变安山岩、变次火山岩和变基性火山岩。三类变火山岩均相对富Na,在地球化学分类图解上样品主要位于碱性玄武岩区域。除个别微量元素外,三类岩石的微量元素含量相近,与各种构造环境玄武岩相比,本区变火山岩富集HFSE(Th、Nb等)、亏损LILE(Sr、Ba等),微量元素配分模式出现明显Th、Nb正异常和Sr、Ba负异常。三类岩石的REE含量范围相互重叠,除Eu异常外,其REE配分模式均为相似的LREE富集型。各种地球化学证据表明,本区三类变火山岩为同源岩浆不同演化阶段的产物,其原始岩浆为大陆板内拉张构造环境交代富集地幔部分熔融的产物,结晶分异作用在岩浆演化过程中具有重要地位。     

胶莱盆地西南缘青山群火山岩锆石U-Pb年龄、岩石地球化学特征及意义

胶莱盆地西南缘发育的青山群火山岩以中-中酸性为主,属同源岩浆喷发;岩石具有高硅、高钾、富铝、贫铁钛特征;微量元素Nb、Ta亏损,Zr、Hf较富集,岩浆来源于下地壳,与板块俯冲作用有关;稀土元素配分图具右倾特征,轻稀土富集,Eu异常不明显;岩浆演化特征以部分熔融为主,区内火山岩碱度指数A·R值小于4.0,判断研究区青山群...     

新疆笔架山早二叠世火山岩带岩石成因:来自岩石学、地球化学及同位素年代学的制约

选取塔里木东北部的笔架山二叠纪火山岩带为研究对象,通过年代学、岩石学和地球化学等研究,论证火山岩的亲缘关系以及火山岩与侵入岩的关系,探讨岩浆演化过程与源区性质。笔架山一带二叠纪火山岩分布于笔架山镁铁质-超镁铁质岩带北侧。火山岩的岩石类型主要有玄武岩、玄武质安山岩、安山岩、英安岩和流纹岩。流纹岩的LA-ICP-MS锆石U-Pb年龄为(285.0±2.9)Ma,属二叠纪乌拉尔世。该火山岩多属拉斑玄武岩系列。玄武岩、玄武质安山岩、安山岩的岩石学及地球化学特征表明,它们都是由拉斑玄武质岩浆通过分离结晶作用演化而成,玄武岩岩浆在上升过程中经历了一定程度的同化混染作用。玄武岩的w(TiO2)(2.35%~3.81%)、w(TFeO)(10.59%~13.87%)、w(P2O5)(0.35%~0.50%)高,属于高钛玄武岩系列,富集轻稀土元素和大离子亲石元素,Nd-Sr同位素组成具有OIB亲和性,地球化学特征显示出玄武岩的岩浆源区属尖晶石稳定域。笔架山二叠纪侵入岩和火山岩的时空关系、岩石地球化学特征和岩浆演化程度的研究表明:二者是同源岩浆分异的产物,岩浆进入现存岩浆房后,大量的堆晶相形成了镁铁-超镁铁质侵入岩,而演化的岩浆沿岩浆房顶部或旁侧的断层带溢出而形成基性-中性火山岩;酸性火山岩是由幔源岩浆的热量引起地壳重熔形成的。     

杭州河上地区新元古代火山岩与侵入岩的岩浆同源性

杭州河上地区是浙西北上元古界上墅组火山岩发育的典型地区,同时还发育新元古代辉绿岩和碱长花岗岩板状复合浅成侵入体。火山岩与侵入岩在空间上密切共生,形成时间相近,皆为晋宁晚期构造岩浆活动的产物。火山喷发并伴随的岩浆侵入经历了两个阶段,每个阶段的火山岩与侵入岩在岩石类型、岩石化学和地球化学方面具有相似性或一致性,稀土元素分布型式基本一致,说明每个阶段的火山岩与侵入岩来源于同一岩浆源,均是同源岩浆活动的产物。第一阶段上墅组基性火山岩与次坞辉绿岩体起源于亏损程度较低的地幔,或来源于亏损地幔的岩浆受到陆壳物质的混染;第二阶段上墅组酸性火山岩与道林山碱长花岗岩体可能起源于地壳中既含有基性地壳组分和又含有酸性地壳组分的源区的部分熔融。     

鲁西邹平盆地中生代火山岩的演化:对地幔源区的约束

邹平盆地中生代火山岩可分为三个亚组：中、下亚组具有相似的岩石组合,岩性主要为玄武岩-粗面玄武岩-玄武质粗面安山岩-粗面安山岩;上亚组岩性主要为粗面安山岩。火山岩由早期基性向晚期中偏碱性方向演化,与正常岩浆房酸度增高的岩浆分异趋势相同。具有Rb、Ba、Sr等大离子亲石元素（LILE）和轻稀土元素（LREE）富集,Nb、Ta、Ti等高场强元素（HFSE）相对亏损,类似于岛弧火山岩的地球化学特征。Nb／La、Hf／Sm比值随MgO的降低而升高或基本不变,说明高场强元素亏损是岩浆的原始特征。各亚组火山岩相似的稀土配分模式和微量元素蛛网图,表明它们具有共同的岩浆源区和密切的成因联系,分离结晶起了关键性作用。La／Nb、La／Ta、Ba／Nb比值较高,说明成岩物质可能主要来自岩石圈地幔。拆沉的大陆中、下地壳部分熔融形成的熔体与古生代岩石圈地幔（亏损的地幔橄榄岩）的相互作用是岩石圈地幔富集的重要方式,随之该富集地幔在陆内岩石圈伸展和区域热异常的双重作用下发生减压部分熔融而形成具有岛弧特征的邹平盆地火山岩。     

四川峨边群冷竹坪组和枷担桥组火山岩的地质地球化学特征及岩浆演化

本文在前人研究的基础上，重点讨论了峨边群下部冷竹坪组和枷担桥组火山岩的地质地球化学特征及演化规律，经研究认为，其岩石化学成分属拉斑玄武岩系列；微量元素组合不协调；主要岩元素和微量元素具有同源演化关系；分异作用是岩浆演化的主导因素，且分离结晶的矿物相为斜长石。     

吉林省南部早太古宙上壳岩地球化学特征

吉林省南部早太古宙上壳岩是太古宙高级区的组成部分,它包括变质火山岩和变质沉积岩,其中各类变质火山岩的地球化学特征与康迪统计的太古宙同类岩石大致可此。本区上壳岩随SiO_2含量增高,ΣREE逐渐增高。各类岩石普遍具Ce、Eu的负异常,表明它们具相同的成岩环境。     

碱性岩研究进展述评

碱性岩的概念曾有三种观点,现多数学者倾向于用化学方法来综合判别碱性岩:碱性岩就是根据化学成分判别其碱性程度属于碱性的岩浆岩。碱性岩物质来源较深,主要源自上地幔,形成于岩石圈拉张环境,是深部地球动力学过程在浅部地壳的直接表现和历史记录,因此对其研究是探索地球深部物质组成、物理化学环境、地壳上层构造和深部动力学过程的一个重要途径,碱性岩是除幔源岩石包体外另一类可提供地幔信息的岩石,是窥探地幔的窗口。20世纪后期以来,对这一类型岩石的研究越来越受到地球科学家们的重视,形成了新的研究热点。     

Correlation of hydraulic conductivity with stratigraphy in a fractured-dolomite aquifer, northeastern Wisconsin, USA

This study integrated surface and subsurface stratigraphic data with geophysical logs and hydrogeologic data in order to characterize the hydraulic properties of the Silurian dolomite in northeastern Wisconsin. Silurian stratigraphy consists of predictable alternations of characteristic facies associations. A vertical profile of hydraulic conductivity, obtained from short-interval packer tests in a core hole that penetrates a majority of the Silurian section, indicates that hydraulic conductivity ranges over five orders of magnitude (10^–1 to 10^–6 cm/s). Matrix conductivity is generally low and varies with texture; the finer-grained restricted-marine and transitional facies being less permeable than the coarser-grained open-marine facies. High-conductivity values are generally associated with bedding-plane fractures, and fracture frequency is greater in the restricted-marine facies. High-flow features in 16 wells were identified using fluid-temperature/resistivity and heat-pulse flowmeter logs. Natural-gamma logs were used to identify the stratigraphic position of flow features in each well and to correlate flow features to specific stratigraphic horizons. By combining stratigraphic, geophysical, and hydrogeologic data, 14 high-permeability zones within the Silurian aquifer have been identified and correlated in wells more than 16 km apart. These zones parallel bedding, appear most pronounced at contacts between contrasting lithologies, and are most abundant in restricted-marine lithologies. Electronic Publication     

Delineation of capture zones for municipal wells in fractured dolomite, Sturgeon Bay, Wisconsin, USA

A wellhead protection study for the city of Sturgeon Bay, Wisconsin, USA, demonstrates the necessity of combining detailed hydrostratigraphic analysis with groundwater modeling to delineate zones of contribution for municipal wells in a fractured dolomite aquifer. A numerical model (MODFLOW) was combined with a particle tracking code (MODPATH) to simulate the regional groundwater system and to delineate capture zones for municipal wells. The hydrostratigraphic model included vertical and horizontal fractures and high-permeability zones. Correlating stratigraphic interpretations with field data such as geophysical logs, packer tests, and fracture mapping resulted in the construction of a numerical model with five high-permeability zones related to bedding planes or facies changes. These zones serve as major conduits for horizontal groundwater flow. Dipping fracture zones were simulated as thin high-permeability layers. The locations of exposed bedrock and surficial karst features were used to identify areas of enhanced recharge. Model results show the vulnerability of the municipal wells to pollution. Capture zones for the wells extend several kilometers north and south from the city. Travel times from recharge areas to all wells were generally less than one year. The high seasonal variability of recharge in the study area made the use of a transient model necessary. Electronic Publication     

Study on petroleum geological conditions in Dazhuom area of Southern Qiangtang Basin of Tibet

Previous researchers in Dazhuoma area of Southern Qiangtang Basin have found some sporadic oil and gas on the surface and collected a small amount of source rocks for analysis, but the exploration degree was generally low and they have not carried out systematic analysis of the generation, storage and cap of oil and gas. Based on the previous data, the authors in this paper have studied the characteristics of the source rocks, reservoir rocks and cap rocks in Dazhuoma area of Southern Qiangtang Basin by means of field petroleum geological survey, sample collection, indoor analysis and comparative research. The results suggest that the mudstone and shale of Adula Formation in the study area are considered as good source rocks, and the mudstone and silty mudstone of Sewa Formation are poor-medium source rocks, while Buqu Formation, Shari Formation and Suowa Formation are poor source rocks. The main reservoir rocks are the sandstone of Adula Formation and the dolomite of Buqu Formation. The cap rocks are argillaceous rocks, limestone and gypsum, and are mainly Ⅰ and Ⅱ cap rocks. Furthermore, the discovery of oil exposure shows that this basin has underwent the process of oil and gas generation, migration, gathering and losing, which builds the material foundation of oil and gas generation and the petroleum geological conditions of hydrocarbon accumulation. It is suggested that more drilling should be arranged in Darzhuoma anticline with good oil and gas storage conditions, and further deep research should be carried out to achieve oil and gas breakthrough in this area.     

On the radiogenic heat production of metamorphic,igneous, and sedimentary rocks

Sedimentary rocks cover-73% of the Earth's surface and metamorphic rocks account for approximately91% of the crust by volume. Understanding the average behavior and variability of heat production for these rock types are vitally important for developing accurate models of lithospheric temperature. We analyze the heat production of ～204,000 whole rock geochemical data to quantify how heat production of these rocks varies with respect to chemistry and their evolution during metamorphism. The heat production of metaigneous and metasedimentary rocks are similar to their respective protoliths. Igneous and metaigneous samples increase in heat production with increasing SiO_2 and K_2 O, but decrease with increasing FeO, MgO and CaO. Sedimentary and metasedimentary rocks increase in heat production with increasing Al_2 O_3, FeO, TiO_2, and K_2 O but decrease with increasing CaO. For both igneous and sedimentary rocks, the heat production variations are largely correlated with processes that affect K_2 O concentration and covary with other major oxides as a consequence. Among sedimentary rocks,aluminous shales are the highest heat producing(2.9 μW~(-3)) whereas more common iron shales are lower heat producing(1.7 μW m~(-3)). Pure quartzites and carbonates are the lowest heat producing sedimentary rocks. Globally, there is little definitive evidence for a decrease in heat production with increasing metamorphic grade. However, there remains the need for high resolution studies of heat production variations within individual protoliths that vary in metamorphic grade. These results improve estimates of heat production and natural variability of rocks that will allow for more accurate temperature models of the lithosphere.     

包含变质岩分类三要素的主要变质岩分类表

变质岩分类的三要素是:变质岩的物质成分(化学成分、矿物成分)、变质岩的组构(结构、构造)和变质岩的成因(变质作用类型和形成变质岩的物理化学条件).由于变质岩的化学成分、矿物成分、组构特征和形成变质岩的地质环境十分复杂,致使至今尚无以变质岩分类三要素为基础的、内容比较完善的分类方案.本文中主要变质岩的分类是以其分类三要素为基础编制的,首次将不同成因的变质岩类并列于同一表中、将鉴定变质岩的主要标志性矿物成分和组构特征列入同一分类表中.该分类对鉴定变质岩石具有可操作性和实用性,分类表中涵盖了自然界主要的变质岩石.     

西藏南羌塘盆地达卓玛地区油气地质条件研究

前人在南羌塘达卓玛地区零星发现了一些地表油气显示并采集了少量的烃源岩进行分析,但勘查程度总体较低,未开展系统的生、储、盖研究。结合前人资料,通过野外石油地质调查、样品采集、室内分析、对比研究等手段,对南羌塘盆地达卓玛地区的烃源岩、储集岩、盖层等油气地质条件进行了分析,认为研究区阿堵拉组泥岩、页岩为好烃源岩,色哇组泥岩、粉砂质泥岩为差—中等烃源岩,布曲组、夏里组和索瓦组发育差烃源岩; 储集岩主要为阿堵拉组砂岩和布曲组白云岩; 盖层有泥质岩、灰岩和石膏,以Ⅰ、Ⅱ类盖层为主。野外调查中发现了大量地表油气显示,盆地经历了油气生成、运移、聚集和散失的过程,具有油气生成的物质基础和成藏的油气地质条件。建议在油气存储条件良好的达卓玛背斜布置钻井,进一步开展深部研究,力争实现该地区油气突破。     

塔里木盆地西南地区碎屑岩储集层特征与评价

目前巴楚隆起的下古生界、麦盖提斜坡区的石炭-二叠系、西南缘山前的中新生界3个主要勘探目的层,均发育有碎屑岩类储层.该区碎屑储集岩成岩环境可划分为酸性成岩环境和碱性成岩环境两种类型,储层重点层位为石炭系和古近系.将碎屑岩储层成岩作用归纳为建设性和破坏性成岩作用,建设性成岩作用主要为砂岩中可溶组份发生的各种溶蚀及成岩晚期构造应力作用,研究区碎屑岩次生孔隙发育带多发育在2 800~6 000 m深度,与该区古地温梯度较低有直接联系.     

CO2矿物捕获能力的研究进展

全球碳存储的研究表明, CO2最稳定的存储方式是 CO2的矿物捕获, 即将 CO2注入到地下,使其以方解石、菱铁矿、白云石及片钠铝石等碳酸盐矿物的形式存在.适合 CO2矿物捕获的岩石类型主要有火山岩、砂岩和火山碎屑岩.分析了3种岩石类型的金属元素含量、金属元素的释放能力、与 CO2反应生成的矿物类型及对 CO2的捕获量,并比较了3种岩石类型对 CO2矿物捕获能力的差异.其中玄武岩等火山岩的金属离子含量高,但其孔隙空间有限,制约了成岩反应,且 CO2注入后具有逸散的风险;砂岩分布广泛,有足够的孔隙利于流体注入,但是金属离子含量相对较低,对 CO2的矿物捕获所需时间相对较长;火山碎屑岩则结合了前2种岩石类型在矿物捕获方面的优势,是一种理想的 CO2矿物捕获的岩石类型.