西藏冈底斯带石炭纪—二叠纪岛弧造山作用：火山岩及地球化学证据

系统研究了西藏冈底斯带石炭纪—二叠纪火山岩的时空分布、岩相学、元素及Sr、Nd、Pb 同位素地球化学和构造环境、源区性质,并与喜马拉雅带二叠纪火山岩进行了对比研究。冈底斯带石炭纪—二叠纪火山岩近东西向集中分布在冈底斯构造带中北部地带,空间上从东至西火山活动的强度和规模渐次减小,时间上从早至晚火山活动的强度和规模总体由弱到强。冈底斯带石炭纪—二叠纪火山岩形成于活动大陆边缘的岛弧构造环境,从早到晚岛弧造山作用经历了初始岛弧→早期岛弧→成熟岛弧的发展演变过程,火山岩浆来源于富集型地幔部分熔融作用,原始岩浆在形成和演化的过程中有俯冲洋壳及随带的深海沉积物和再循环进人地慢的地壳物质组分的强烈混染,明显不同于受地壳物质组分强烈混染的喜马拉雅带二叠纪陆缘裂陷型火山岩。综合研究冈底斯带及其邻区近年来的最新调查与研究成果,从北向南拟建了石炭纪—二叠纪冈底斯岛弧→雅鲁藏布江弧后裂谷盆地→喜马拉雅陆缘裂陷盆地的弧盆系时空结构演化模式,探讨了冈瓦纳大陆北缘石炭纪—二叠纪活动大陆边缘的岛弧造山作用与青藏高原古特提斯演化的耦合关系及其动力学机制,讨论了冈底斯带松多乡榴辉岩的形成过程。     

北山石炭纪-二叠纪火山岩成因及构造背景

北山古生代火山岩尤其是石炭纪-二叠纪火山岩的形成环境及成因备受学者关注且长期以来存在争议。本文收集了近年来发表的关于北山石炭纪-二叠纪火山岩研究的地球化学数据,岩石地球化学特征显示北山石炭纪玄武岩主要为安山玄武岩,属拉斑系列,二叠纪火山岩主要为安山玄武岩和亚碱性玄武岩,落入拉斑系列及过渡区;石炭纪玄武岩和二叠纪玄武岩均具有LREE富集的球粒陨石标准化稀土元素配分模式,轻重稀土元素分馏程度均较低。在微量元素蛛网图上,石炭纪-二叠纪遭受地壳混染的玄武岩呈现出明显的Nb-Ta亏损和微弱的Ti亏损特征,而未遭受地壳混染作用的绝大多数石炭纪-二叠纪玄武岩主要呈现出与OIB相似的"隆起"状不相容元素标准化配分模式。岩石成因分析认为,石炭纪-二叠纪玄武质岩浆可能主要来源于地幔柱,部分石炭纪-二叠纪玄武岩在形成演化过程中遭受了明显的大陆地壳混染作用,导致其出现十分相似于岛弧或活动大陆边缘的地球化学特征。结合区域构造演化分析及构造环境判别,认为石炭纪-二叠纪玄武岩均形成于大陆板内环境。     

右江盆地晚古生代-三叠纪盆地转换及其构造意义

右江盆地是在南华加里东造山带夷平的基础上经再次裂陷形成的,它的形成与金沙江—红河—马江洋盆关系密切,是该洋盆与扬子板块之间的大陆边缘盆地。早泥盆世晚期—石炭纪随着金沙江—红河—马江洋盆的形成,扬子板块南部边缘开始裂陷,形成特殊的台地与台间海槽相间的大陆边缘裂谷盆地。二叠纪—早三叠世初期随着该洋盆的俯冲消减,形成越北岛弧,右江盆地进入弧后(裂陷)盆地阶段。早三叠世晚期以后,随着该洋盆的闭合和碰撞造山,在红河—马江造山带与扬子板块之间形成以复理石为特征的弧后前陆盆地。因此右江盆地经历了大陆边缘裂谷盆地(早泥盆世晚期—石炭纪)、弧后盆地(二叠纪—早三叠世早期)、弧后前陆盆地(早三叠世晚期—中三叠世)的构造演化阶段。     

西藏冈底斯带洛巴堆组火山岩地球化学及构造意义

冈底斯带中-新生代火山岩的成因和地质演化是青藏高原地质研究的热点领域,但是对晚古生代火山岩的性质及其形成的构造背景仍缺乏研究.冈底斯带二叠系显示缓慢的海退过程,并伴随基性和中酸性两期火山活动,具有活动大陆边缘特征.笔者对墨竹工卡县唐家乡和林周县勒青拉地区二叠纪洛巴堆组火山岩进行了常量、微量元素和St、Nd、Pb同位素地球化学测试.研究认为二叠纪是冈底斯岛弧的形成和演化时期.洛巴堆组玄武岩从下部(可能为早二叠世)到上部(中二叠世),MgO含量从7.43%降到3.99%,Al2O3含量从15.54%上升到17.57%,后者类似于岛弧高铝玄武岩;稀土总量∑REE从54.12(10-6)上升到108.82(10-6),LREE/HREE比值从3.00上升到5.40.洛巴堆组玄武岩均具有明显的Nb、Ta负异常,但中二叠世更显著.岩石地球化学示踪表明,冈底斯洛巴堆组玄武岩代表二叠纪初始岛弧环境.早期玄武岩形成于略亏损地幔和下地壳成分的混合源区,地壳相对较薄,源区或岩浆的壳源成分比例较低.到中二叠世地壳逐渐加厚.壳源成分在源区或岩浆中所占比例增大,代表向陆缘弧的演化过程.冈底斯带二叠纪岛弧是古特提斯洋向南的俯冲、消减的产物.     

西藏当雄纳龙晚古生代裂谷盆地的识别及其意义

西藏冈底斯构造带是冈瓦纳大陆北部边缘的重要组成部分，经历了特提斯演化的全过程，并在中生代发育的典型的多岛弧－盆地系统。笔者根据冈底斯构造带中部纳龙地区晚古生代发育的沉积相类型、火山岩组合以及古生物等方面的资料，首次提出当雄纳龙盆地在中二叠世栖霞期具有裂谷盆地性质，揭示出冈底斯地区在二叠纪已转化为活动大陆边缘，为研究西藏冈底斯地区弧－盆系统的形成过程及晚古生代的区域构造特征古地理格局提供了重要的资料。     

措勤盆地林子宗群火山岩地球化学特征

青藏高原措勤盆地新生代火山活动十分强烈,以古近纪林子宗群火山岩为代表,主要分布在盆地中央隆起带的冈底斯构造岩浆岩带中,在北部坳陷带中仅有零星分布。林子宗群火山岩主要由安山岩、流纹岩、中酸性熔岩和火山碎屑岩组成。岩石化学研究表明属钙碱－高钾钙碱系列;岩石地球化学研究表明,木子宗群火山岩具岛弧火山岩特点,为喜马拉雅板片与冈底斯－念青唐古拉板片碰撞作用的产物。     

青藏高原区域地质调查中几个重大科学问题的思考

在世纪之交，中国地质调查局部署的青藏高原近百幅1：25万区域地质调查填图，取得了一系列重要新发现、新进展、新成果，神秘的青藏高原地质构造、结构、组成、演化等问题得到了进一步的认识和理解。喜马拉雅奠基于5．5亿年左右的泛非造山事件基底上，历经奥陶纪至泥盆纪台地沉积，并于石炭纪末转化为印度板块北缘的弧后伸展裂陷带；雅鲁藏布江蛇绿混杂岩带曾是特提斯大洋南侧与冈底斯古岛弧带相对应的中生代弧后扩张盆地；冈底斯带曾经历了晚古生代岛弧造山作用；班公湖-怒江带两侧大量地质特征重大差异表明，班公湖-怒江带是冈瓦纳大陆北界，是印度(滇藏)地层区和华南(羌塘-三江)地层区的分界，是新元古代Rodinia超大陆解体后显生宙特提斯大洋俯冲、消减、碰撞，最后消亡的遗迹。     

三江特提斯复合造山与成矿作用

三江特提斯构造带作为全球特提斯构造在中国大陆最典型的发育地区,经历了复杂而完整的演化历史:从晚前寒武纪—早古生代泛大陆解体与原特提斯洋形成,经古特提斯多岛弧盆系发育与古生代—中生代增生造山/盆山转换,到新生代印度-亚洲大陆碰撞与叠加改造,完好地记录了超级大陆裂解→增生→碰撞的完整演化历史和大陆动力学过程,可谓是中国大陆构造演化的典型缩影。复合造山和叠加转换导致了三江特提斯域复杂的成矿演化,主要表现为:①在构造转换阶段,于元古代刚性基底基础上发育大量叠加改造型矿床,具有独特的金属组合(Sn-Cu,Sn-Pb-Zn,Fe-Cu等);②火山成因块状硫化物(VMS)矿床伴随特提斯岩石圈演化,连续发育于陆缘裂谷(Cu)→初始洋盆(Cu-Zn)→大洋岛弧(Cu-Zn-Pb)→弧间裂谷或弧后盆地(Pb-Zn-Ag)→弧-陆碰撞裂陷盆地(Cu-Pb-Zn)等阶段及诸环境;③特提斯阶段的岛弧型斑岩Cu矿被碰撞造山阶段的大陆型斑岩Cu矿所取代;④世界级规模的金属成矿带和巨型矿床,在新生代碰撞造山期爆发式产生。尽管已有的研究从整体上勾画出了三江特提斯域的基本构造特征和成矿面貌,但仍有许多重要问题尚未解决:①三江复合造山带构造叠加、...     

陆缘扩张型地洼盆地系及其形成机制探讨

本文提出“陆缘扩张型地洼盆地系”这一概念,以突出表述分布于东亚陆缘壳体之上,形成于地洼余动期的张性地洼盆地系列的壳体演化—动力环境。指出陆缘海中的裂陷盆地的成因难于与大洋板块俯冲导致弧后扩张的理论模式相联系,也不同于大西洋型盆地,而是大陆地壳演化到地洼余动期,并经历过华夏期地洼型造山运动之后拉伸裂陷的结果。论证了“岩石圈底层剥落、华夏期地洼造山带拉伸裂陷”是东亚陆缘扩张发生的一种重要机制,进而建立了由华夏期地洼型挤压造山带到盆岭型构造带和陆缘海盆地系的构造发展模式。     

云南哀牢山地区构造岩石地层单元及其构造演化

依据新获得的同位素年代学资料和构造岩石地层单元,重新认识了云南哀牢山造山带形成与演化历史。认为:在哀牢山地区元古界深变质岩系属基底构造层;前造山期岩石组合及构造演化为扬子地块西缘被动大陆边缘志留纪深水相碎屑岩→陆缘泥盆纪被动裂谷盆地中火山-沉积岩→石炭纪哀牢山有限洋盆及蛇绿岩石组合→晚二叠世-早三叠世哀牢山洋-陆碰撞成陆及弧火山岩-陆相碎屑岩组合。燕山期主造山期及岩石组合为晚三叠世-侏罗纪前陆盆地磨拉石建造-同造山期中酸性侵入岩-燕山期脆韧性剪切带及构造岩。喜马拉雅山期陆内造山成原的岩石组合为第三-第四纪陆内山间盆地中磨拉石建造-红河韧性剪切带及构造岩-富碱侵入岩和煌斑岩。     

Wavelength-dispersive X-ray fluorescence spectrometric determination of Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites

Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours.     

高压微波消解法测定醋酸纤维过滤器采集的微尘粒子中的砷镉钴铬铜铁锰镍铅钒锌

最新的流行病学研究表明,空气中较高浓度的悬浮细颗粒可能对人类的健康有不利的影响。根据该项研究显示,由于心脏病、慢性呼吸问题和肺功能指标恶化而导致死亡率的升高与细尘粒子有关。这些研究结果已经促使欧盟于1999年4月出台了限制空气中二氧化硫、二氧化氮、氧化氮、铅和颗粒物含量的法案(1999/30/EC),对各项指标包括对可吸入PM10颗粒的浓度提出了新的限制性指标。PM10颗粒是指可以通过预分级器分离采集的气体动力学直径小于10μm的细颗粒。目前研究的兴趣重点逐步偏向PM2.5这些更细微颗粒物,PM2.5这种颗粒物对健康有明显的不利影响。在欧盟指令2008/50/EC中,对PM10和PM2.5都提     

Isotopic systematics of He,Ar, S,Cu, Ni,Re, Os,Pb, U,Sm, Nd,Rb, Sr,Lu, and Hf in the rocks and ores of the Norilsk deposits

This paper reports the first results of a study of 11 isotope systems (³He/⁴He, ⁴⁰Ar/³⁶Ar, ³⁴S/³²S, ⁶⁵Cu/⁶³Cu, ⁶²Ni/⁶⁰Ni, ⁸⁷Sr/⁸⁶Sr, ¹⁴³Nd/¹⁴⁴Nd, ^206–208Pb/²⁰⁴Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others.     

硅酸盐中铁、锰、钛、钙、钾、磷、硅、铝、镁、钠、锶、铷、钡的X-射线荧光光谱定量测定

本文介绍样品经四硼酸锂熔融制成玻璃小饼。采用Lachance模式和理论a系数来校正元素间的效应,由3080E型X-射线荧光谱仪和DF-350B数据处理系统完成硅酸盐中十三个项目的测定。     

硅酸盐类样品中硅、铁、铝、钛、锰、钙、镁、钾、钠和磷的x射线荧光光谱测定

本文拟定了一种以熔融法制备样片,用X射线荧光光谱测定硅酸盐类样品中Si、Fe、Al、Tj、Mn、Ca、Mg、K、Na、P等元素的分析方法。在对不同靶材X光管和分光晶体实验对比的基础上,选择了最佳的测量条件。该法具有快速、准确,测量范围广,检测限低,价格便宜等优点。经过近百个各种类型标样或管理样品的分析对比表明,本法不仅适用于硅酸盐类岩石样品的分析,还适用于铁矿、铝土矿、碳酸盐类岩矿样品以及水泥、耐火材料等样品的分析。     

Viscous, cohesive, non-Newtonian, depositing, radial slurry flow

Mining induced subsidence can significantly affect mining costs where major surface facilities and natural environment need to be protected. Overburden grout injection is a technology used to control coal mine subsidence by injecting the mine waste material extracted from the coal back into the inter-burden rock during longwall mining. The flowing slurry is here categorised as a nonlinear viscous cohesive (Bingham plastic) fluid. During longwall mining the grout slurry is pumped into the separated beds of the rock mass through a central vertical borehole, which is drilled deep into the inter-burden rock strata above the coal seam. However, a blockage can occur in the injection system when the slurry velocity falls below a certain critical threshold velocity, indicating a material phase change from cohesive-viscous to cohesive-frictional. In situ field injection tests through boreholes have been simulated at a smaller scale at the CSIRO laboratory in Brisbane by pumping the slurry through a radial disk (gap = 4 mm) from its centre. Laboratory experiments indicate a general, nonlinear, cohesive, viscous, frictional model for shear behaviour of the slurry, in which the material shear parameters are functions of the disk radial distance. Complete dimensional and dimensionless analytical solutions have been developed based on an approach related to Bingham–Herschel–Bulkley fluid mechanics. The derived formulae include relations for minimum pump pressure, local pressure and pressure gradient, wall shear stress, volume rate, velocity and velocity gradient. The theoretical results match the experimental measurements. The experiments covered slurries with maximum particle sizes of 0.5 to 2 mm with about 50% being larger than 100 µm. The viscosities at the various solids concentrations were measured with a standard torsion viscometer. This study differs from the previous research in several distinct aspects, namely, consideration of the variable shear parameters rather than fixed values, inclusion of total nonlinear behaviour, and implementation of a friction function to mimic behaviour of the deposited and consolidating stiff slurry, which can cause a significant pressure rise as a result of the increased shear resistance.     

Mountains,nations, parks,and conservation

Between 1985 and 1991, two new mountain protected areas (MTNPA) covering more than 35,000 km² and based on participatory management models — the Makalu-Barun National Park and Conservation Area, Nepal, and Qomolangma Nature Preserve, Tibet Autonomous Region — were successfully established through the collaborative efforts of Woodlands Mountain Institute and conservationists in China and Nepal. Characteristics common to both projects include the importance of establishing (1) effective rationales, (2) local support constituencies, (3) a senior advisory group, (4) a task force, (5) linkages between conservation and development, and (6) fund raising mechanisms. The lessons derived from the experiences of Woodlands Mountain Institute are of significant value to others in preserving MTNPA. Increased collaboration and communication between all interested in conservation, however, will remain a critical component for expanding mountain protected area coverage to throughout the world.     

岩石密度和超高压岩石折返速率

在常温常压条件下对中国大陆科学钻CCSD主孔100-3000米岩心样品进行了密度测量,建立了密度连续剖面,并界定了不同超高压岩石的密度值。通过对比高温高压物性实验资料,岩石密度随着退变程度增强而降低,榴辉岩密度变化序列为3.52g/cm3→3.49g/cm3→3.07g/cm3→2.93g/cm3。超高压长英质岩石密度变化序列为3.00g/cm→2.80g/cm3→2.65g/cm3。上述实验资料是讨论不同折返阶段岩石所受浮力的基础,为研究折返速率大小提供了基本参数。本文通过折返板块运动平衡时,上浮力与粘滞力平衡这一关系式,定量研究了大陆俯冲板块的折返速率,认为密度差产生上浮力从而引起折返,温度对板块折返速率的影响最为显著;密度差大小、折返角度、折返板块大小对折返速率也有直接的影响。定量模拟分析表明,在温度高于850℃时,板块的折返速率可以超过100mm/a;当温度降至700℃时,折返速率则低于1.5mm/a。作者认为在折返早期,温度较高,板块快速折返至60-70km榴辉岩相深度;随着传导散热,温度降低,板块以较慢的速率折返至中下地壳。折返速率的估算表明,浮力是板块折返第一阶段(从>100km深部折返至<40km的中下地壳)的主要驱动力。     

Regional distribution of Al,B, Ba,Ca, K,La, Mg,Mn, Na,P, Rb,Si, Sr,Th, U and Y in terrestrial moss within a 188,000 km2 area of the central Barents region: influence of geology,seaspray and human activity

Five hundred and ninety-eight samples of terrestrial moss (Hylocomium splendens and Pleurozium schreberi) collected from a 188,000 km² area of the central Barents region (NE Norway, N Finland, NW Russia) were analysed by ICP-AES and ICP-MS. Analytical results for Al, B, Ba, Ca, K, La, Mg, Mn, Na, P, Rb, Si, Sr, Th, U and Y concentrations are reported here. Graphical methods of data analysis, such as geochemical maps, cumulative frequency diagrams, boxplots and scatterplots, are used to interpret the origin of the patterns for these elements. None of the elements reported here are emitted in significant amounts from the smelting industry on the Kola Peninsula. Despite the conventional view that moss chemistry reflects atmospheric element input, the nature of the underlying mineral substrate (regolith or bedrock) is found to have a considerable influence on moss composition for several elements. This influence of the chemistry of the mineral substrate can take place in a variety of ways. (1) It can be completely natural, reflecting the ability of higher plants to take up elements from deep soil horizons and shed them with litterfall onto the surface. (2) It can result from naturally increased soil dust input where vegetation is scarce due to harsh climatic conditions for instance. Alternatively, substrate influence can be enhanced by human activity, such as open-cast mining, creation of ‘technogenic deserts’, or handling, transport and storage of ore and ore products, all of which magnify the natural elemental flux from bedrock to ground vegetation. Seaspray is another natural process affecting moss composition in the area (Mg, Na), and this is most visible in the Norwegian part of the study area. Presence or absence of some plant species, e.g., lichens, seems to influence moss chemistry. This is shown by the low concentrations of B or K in moss on the Finnish and Norwegian side of the (fenced) border with Russia, contrasting with high concentrations on the other side (intensive reindeer husbandry west of the border has selectively depleted the lichen population).