Estimating the criterion for determining water vapour sources of summer precipitation on the northern Tibetan Plateau

According to the precipitation and δ¹⁸O data obtained during the GEWEX Asian Monsoon Experiment–Tibet Intensive Observation Period, based on the knowledge that δ¹⁸O is lower in precipitation formed from ocean air mass vapour than that from local evaporation vapour, the water vapour sources can be identified from the δ¹⁸O values in precipitation. We attempt to give the identification criterion of δ¹⁸O values in precipitation. The threshold values chosen to distinguish between ocean and local sources are δ¹⁸O < ?20‰ and δ¹⁸O > ?13‰ respectively. According to this criterion, the proportion of local evaporation‐formed precipitation and ocean air‐mass‐formed precipitation in total precipitation was estimated. The average value of precipitation at three sites (NODA, Amdo and AQB) is 249·76 mm. Among this, precipitation formed directly by the ocean air mass vapour is 80·08 mm at most. Precipitation formed by water vapour evaporated from local places is 117·05 mm at least. That is to say that precipitation formed directly by the ocean air mass vapour accounts for 32·06% of the total precipitation at most. Precipitation formed by water vapour evaporated from local places accounts for 46·86% of the total precipitation at least. At least 21·8% of the total precipitation came from water vapour that was evaporated on the way and transported by the monsoon circulation. Copyright © 2005 John Wiley & Sons, Ltd.     

Seasonal variations of deuterium and oxygen‐18 isotopes and their response to moisture source for precipitation events in the subtropical monsoon region

Deuterium and oxygen‐18 are common environmental tracers in water used to investigate hydrological processes such as evaporation and groundwater recharge, and to trace moisture source. In this study, we collected event precipitation from 01 January 2010 to 28 February 2011 at a site in Changsha, Yangtze River Basin to estimate the influence of moisture source and atmospheric conditions on stable isotope compositions. The local meteoric water line, established as δD = (8.45 ± 0.13) δ¹⁸O + (17.7 ± 0.9) (r² = 0.97, n = 189), had a higher slope and intercept than global meteoric water line. Temperature–δ¹⁸O exhibited complex correlations, with positive correlations during Nov.–Apr. superior to during Jun.–Sep., which was attributed to distinctive moisture sources, but vague the overall period; amount effect examined throughout the year. Linear regressions between δ¹⁸O and δD value in different precipitation event size classes revealed progressively decreasing slope and intercept values with decreasing precipitation amount and increasing vapour pressure deficit, indicating that small rainfall events (0–5 mm) were subject to secondary evaporation effects during rainwater descent. In contrast, snowfall and heavy precipitation events exhibited high slope and intercepts for the regression equation between δ¹⁸O and δD. High concentrations of heavy isotopes were associated with precipitation events sourced from remote westerly air masses, degenerated tropical marine air masses from the Bay of Bengal (BoB), and inland moisture in the pre‐monsoon period, as determined from backward trajectories assessed in the HYSPLIT model. Meanwhile, low concentrations of heavy isotopes were found to correspond with remote maritime moisture from BoB, the South China Sea, and the west Pacific at three different air pressures in summer monsoon and post‐monsoon using HYSPLIT and records of typhoon paths. These findings suggest that stable isotope compositions in precipitation events are closely associated with the meteorological conditions and respond sensitively to moisture source in subtropical monsoon climates. Copyright © 2013 John Wiley & Sons, Ltd.     

Stable isotopes in the source waters of the Yamuna and its tributaries: seasonal and altitudinal variations and relation to major cations

Water samples from the Yamuna and its tributaries, one of the major river systems draining the Himalaya, have been analysed for their stable oxygen and hydrogen isotopes during three seasons (summer, monsoon and post‐monsoon). The data show clear seasonal and altitudinal variations; waters from higher altitudes and those collected during monsoon season are characterized by relatively depleted isotopic composition. Regression analysis of δD–δ¹⁸O data of samples collected during summer and monsoon seasons shows that the slope of the best‐fit lines are nearly identical to those of precipitation at New Delhi for the same period. The similarity in their slopes suggests that the isotopic composition of precipitation contributing water to these rivers are reasonably well preserved in both monsoon and non‐monsoon seasons, however, during the non‐monsoon period both rainfall and river waters carry signatures of evaporation. The ‘deuterium excess’ in river waters during the three seasons though overlap with each other, the values during October are higher. This can be understood in terms of recycled moisture contributions to precipitation. The ‘altitude effect’ for δ¹⁸O in these waters is determined to be 0·11‰ per 100 m, a factor of about two less than that reported for the Ganga source waters from similar altitudinal range. The variability in altitude effects in rivers draining the Himalaya seems to be controlled by the ‘amount effect’ associated with the monsoon. The significant spatial variability in altitude effect in these river basins, which are a few hundred kilometers apart, suggests that reconstruction of palaeoelevation in the Himalaya, based on δ¹⁸O‐altitude gradients, would depend critically on its proper assessment in the region. This study has established a relationship between total cation abundance and δ¹⁸O in waters of the Yamuna mainstream; total cations (corrected for cyclic components) double for a 1·4 km decrease in altitude as the Yamuna flows downstream. Copyright © 2002 John Wiley & Sons, Ltd.     

Isotopic temporal and spatial variations of tropical rivers in Thailand reflect monsoon precipitation signals

Stable isotopic compositions (δ¹⁸O and d-excess) from 25 rivers in Thailand were analysed monthly during 2013–2015. Results indicated that monsoon precipitation fundamentally influences the river isotopes. The overland flow supplied from monsoon precipitation and human-altered flow regimes produces considerable isotopic variability. Spatial and temporal variations were observed among four principal geographical regions. The seasonality of monsoon precipitation in mountainous Thailand produced large variations in isotopic compositions because most rainfall occurred during the southwest monsoon, and dry conditions prevailed during the northeast monsoon. The northern and northeastern regions are mountainous, highland areas. Low δ¹⁸O values were found in these regions, likely because of altitude effects on precipitation. Conversely, monsoonal precipitation continually supplies rivers in southern Thailand all year round, producing higher and more consistent δ¹⁸O values than in the other regions. The Chao Phraya plain in the central region experienced enrichment of δ¹⁸O river runoff related to evaporation in irrigation systems. Larger catchment areas and longer residence times resulted in more pronounced evaporation effects, producing lower values of d-excess and local river water line slopes compared with precipitation. The isotopic differences between river waters and precipitation were utilized to determine river recharge elevations and water transit time. The methods presented here can be used to explore hydrological interactions in other tropical river basins.     

Tracer-based estimation of temporal variation of water sources: an insight from supra- and subglacial environments

ABSTRACT

The temporal variations in electrical conductivity and the stable isotopes of water, δD and δ¹⁸O, were examined at Chhota Shigri Glacier, India, to understand water sources and flow paths to discharge. Discharge is highly influenced by supraglacially derived meltwater during peak ablation, and subglacial meltwaters are more prominent at the end of the melt season. The slope of the best fit linear regression line for δD versus δ¹⁸O, for both supraglacial and runoff water, is lower than that for precipitation (snow and rain) and surface ice, indicating strong isotopic fractionation associated with the melting processes. The slope of the local meteoric water line (LMWL) is close to that of the global meteoric water line (GMWL), reflecting that the moisture source is predominantly oceanic. The d-excess variation in rainwater confirms that the southwest monsoon is the main contributor during summer while the remainder including winter is mostly influenced by westerlies.     

Relation between stable isotope in monsoon precipitation in southern Tibetan Plateau and moisture transport history

The moisture transport history to the south of the Tibetan Plateau was modeled using the meteorological data provided by NCEP in this paper, and the modeled results were compared with the measured δ¹⁸O in the south of the Tibetan Plateau. The relation between δ¹⁸O in precipitation in the south of the Tibetan Plateau and moisture trajectories was discussed. The results show that the extremely low δ¹⁸O in precipitation in the south of the Tibetan Plateau is always related to the moisture from the low-level sea surface evaporation. The long-distance transport of moisture also contributes to low δ¹⁸O in precipitation probably due to the rainout process during moisture transport. It is also found that low δ¹⁸O in precipitation is also related with deep layer transport of moisture, and with intensive condensation in the upper layers of the atmosphere, resulting in low δ¹⁸O because of depletion of heavy isotopes in deep condensation. However, high δ¹⁸O in precipitation whether in monsoon period or not is always companied with moisture coming from the upper layers, and the moisture is from northern or western sides of the plateau. The interpretation of the modeled results is in agreement with the isotope fractionation processes.

     

Stable isotopic compositions and controlling factors of precipitation and atmospheric vapour in the headwaters of the Shule River

Stable isotopic compositions of precipitation (δ¹⁸O_p, δ²H_p and d-excess_p) and atmospheric vapour (δ¹⁸O_v, δ²H_v and d-excess_v) with high spatial–temporal resolution are crucial in revealing hydrologic cycle. Based on the variation characteristics of δ¹⁸O_p/δ¹⁸O_v, δ²H_p/δ²H_v and d-excess_p/d-excess_v in the headwaters of the Shule River (HSR) on hourly and daily scales from June to September 2018, this study analysed the relationships between δ¹⁸O_p/δ²H_p and δ¹⁸O_v/δ²H_v combined with the equilibrium fractionation model, as well as δ¹⁸O_p/δ¹⁸O_v and meteorological factors. The slopes of local meteoric water line (LMWL) and the δ²H_v-δ¹⁸O_v fitting equation were similar (7.96 and 7.94) with both intercepts exceeding 10, reflecting the great contribution of recycling moisture. The values of δ¹⁸O_v/δ²H_v were lower than δ¹⁸O_p/δ²H_p but with consistent variation patterns throughout the period. The equilibrium simulation results suggested that precipitation and atmospheric vapour almost approached isotopic equilibrium state, especially during monsoon intrusion period. Affected by monsoon intrusion, the slopes and intercepts of the LMWLs and the δ²H_v-δ¹⁸O_v fitting equations were smaller than those during non-monsoon period and d-excess and δ¹⁸O were negatively correlated. Relative humidity had significant negative correlations with δ¹⁸O_p and δ¹⁸O_v in the whole period, however, the positive correlations between δ¹⁸O_p/δ¹⁸O_v and temperature were observed during non-monsoon and monsoon intrusion period, respectively. Our results demonstrated that precipitation and atmospheric vapour isotopic compositions exhibited consistency under the influence of diverse moisture sources, while more complex relationships were found between δ¹⁸O_p/δ¹⁸O_v and meteorological factors. This research provided evidence for using the isotopic compositions of atmospheric vapour to indicate moisture sources, and can improve understanding of the water cycle and eco-hydrological process from the perspective of the interaction between water and gas phases of the inland river basin in northwest China.     

Water isotopes and hydrograph separation in different glacial catchments in the southeast margin of the Tibetan Plateau

Snow and glaciers are known to be important sources for freshwater; nevertheless, our understanding of the hydrological functioning of glacial catchments remains limited when compared with lower altitude catchments. In this study, a temperate glacial region located in the southeast margin of the Tibetan Plateau is selected to analyse the characteristics of δ¹⁸O and δD in different water sources and the contribution of glacier–snow meltwater to streamflow. The results indicate that the δ¹⁸O of river water ranges from ?16.2‰ to ?10.2‰ with a mean of ?14.1‰ and that the δD values range from ?117.0‰ to ?68.0‰ with a mean of ?103.1‰. These values are more negative than those of glacier–snow meltwater but less negative than those of precipitation. The d ‐excess values are found to decrease from meltwater to river to lake/reservoir water as a result of evaporation. On the basis of hydrograph separation, glacier–snow meltwater accounts for 51.5% of river water in the Baishui catchment in the melting season. In the Yanggong catchment, snow meltwater contributes 47.9% to river water in the premonsoon period, and glacier meltwater contributes only 6.8% in the monsoon period. The uncertainty in hydrograph separation is sensitive to the variation of tracer concentrations of streamflow components. The input of meltwater to a water system varies with local climate and glacier changes. The results confirm that hydrograph separation using water isotopes is valuable for evaluating the recharge sources of rivers, especially in ungauged glacial regions. This study provides insights into the hydrological processes of glacial catchments on the Tibetan Plateau, which is important for water resource management.     

“Amount effect” of water isotopes and quantitative analysis of post‐condensation processes

A numerical model is proposed that describes the interaction between raindrops and water vapour near the planetary boundary layer to explain the “amount effect”. This model relates the intensity to the isotopic composition of precipitation. The model resolves raindrop sizes, and explicitly includes: (1) the isotopic equilibration time of raindrops that is drop‐size dependent; (2) raindrop transit times through the atmosphere; and (3) the evolution of the isotopic composition of vapour at various rain rates. At high rain rate, the precipitation through a layer is less equilibrated with the vapour because the isotopic equilibration time is long compared to the fast transit time, and there is a preponderance of large drops, which take longer to equilibrate. The δ¹⁸O of vapour in the lower atmosphere becomes lower as a result of the interaction with these raindrops of low δ¹⁸O, and the degree of depletion of ¹⁸O is higher when precipitation rates are high. The model reproduces time‐series observations of isotopic composition of precipitation in Japan, and a vapour replenishment rate is inferred by either advection or evaporation of about 5% of the precipitation rate. The results could be the basis for a new parameterization of the isotopic equilibration for different precipitation types and rates in General Circulation Models (GCMs). When the model is applied to a GCM, this parameterization is important for places where precipitation occurs at cold temperatures (<15 °C). Copyright © 2007 John Wiley & Sons, Ltd.     

Mechanisms of isotopic control of precipitation in the Yellow River source region

The study of water vapour sources and water cycle patterns in the Yellow River source region is of great significance for ensuring water resource security in the arid and semi-arid regions of northern China. We established a precipitation stable isotope observation system in the Yellow River source region for three consecutive years (2020–2022), systematically analysed the spatial and temporal distribution characteristics of precipitation stable isotopes ²H and ¹⁸O in the Yellow River source region and their interrelationships with environmental factors and topography, and explored the regional water vapour transport pathways by using the HYSPLIT model and combining with the global reanalysis data. The results show that: (1) the δ¹⁸O and δ²H values of precipitation in the Yellow River source region follow the seasonal pattern, with the first half of the year being richer than the second half of the year; (2) the spatial variations of δ¹⁸O of precipitation in the Yellow River source region show a low in the southwest and a high in the northeast; (3) the water vapour source in the source area is basically stable, and the complex transport paths and the cross-effects of the local factors determine the stable isotope characteristics of the water, and the stable isotope characteristics of the water are determined by the cross-effects of the local factors, because the source of the water vapour and the local factors such as the height will not change significantly in the short term. Since the source of water vapour and local elevation factors will not change significantly in the short term, the precipitation pattern in the source area of the Yellow River can be considered to be basically stable.     

Using stable isotopes to understand seasonal and interannual dynamics in moisture sources and atmospheric circulation in precipitation

Stable isotopes in precipitation are useful tracers to strengthen understanding of climate change and hydrological processes. In this study, the moisture sources of 190 precipitation events in Beijing were analysed using the Hybrid Single‐particle Lagrangian Integrated Trajectory model, based on which we studied the relation between variations in precipitation δ¹⁸O and dynamics in moisture sources and atmospheric circulation in seasonal and interannual timescales. Categorization of 7 groups of moisture sources was performed, among which oceanic moisture sources presented lower δ¹⁸O in precipitation than continental moisture sources. The results show that seasonal variations of precipitation δ¹⁸O were caused by changes of moisture sources. In summer, moisture from proximal oceans dominated vapour transport to Beijing due to increasing monsoon strength and resulted in a relatively small variation of precipitation δ¹⁸O. At the interannual timescale, the variations of δ¹⁸O in summer precipitation were related to dynamics in oceanic moistures, showing depleted values when the contribution of oceanic moistures, especially the proportion of long‐distance oceanic moisture, was high. Further analysis indicated that changes of oceanic moisture sources were controlled by the strength of summer monsoons. These findings address the complexity of moisture sources in midlatitude monsoon areas and suggest that isotopic signals in precipitation have the potential to deduce changes in moisture sources and atmospheric circulation and can therefore serve for palaeoclimate reconstruction.     

Ocean air masses from the East Asian monsoon dominate the land-surface atmospheric water cycles in the coastal areas of Liaodong Bay,Northeast China

Long-term atmospheric water vapour hydrogen (δ²H), oxygen (δ¹⁸O) and deuterium excess (d-excess) can provide unique insights into the land-atmosphere coupling processes. The in-situ measurements of atmospheric water vapour δ²H, δ¹⁸O and d-excess were conducted above a reed wetland of Liaodong Bay (2019–2020). We found significant inter-annual variations in atmospheric water vapour isotopes between the two growing (May–September) seasons. The δ²H, δ¹⁸O and d-excess of atmospheric water vapour exhibited different seasonal and diurnal cycles concerning the vertical measurement heights, especially in 2019. The isotopic differences of atmospheric water vapour among vertical measurement heights were more evident in the daytime. Rainfall events directly impacted the diurnal patterns of water vapour isotopes, and the influences depended on rainfall intensities. However, only weak correlations existed between water vapour isotopes and local meteorological factors (R² = 0.01–0.16, p < 0.001), such as water vapour concentration (w), Relative Humidity (RH) and surface air temperature (T_a). Based on the back-air trajectory analyses, the spatial–temporal dynamics of atmospheric water vapour isotopes are highly synchronized with monsoon activities. Different water vapour sources influence the water vapour isotope in this region and the higher d-excess value is related to the intense convection brought by the monsoon. High-resolution measurements of atmospheric water vapour isotopes will improve our understanding of the hydrological cycles in coastal areas.     

Controls on stable isotopic characteristics of water vapour over Thailand

This study examined the weekly water vapour isotopic composition (δ¹⁸O_v) in Thailand. The water vapour was cryogenically collected from eight sites across the country. Two observational samples were collected over one 24-h period each week (a daytime and a night-time sample), from September 2013 to September 2014. The primary aim was to investigate the environmental factors influencing water vapour isotopes. The results revealed differences in water vapour isotopic values between day and night samples. Three periods of depleted δ¹⁸O_v were associated with large-scale convective systems in September, December, and May. The statistical relationship between the climate variables and water vapour isotopes indicated that the amount of precipitation and relative humidity were the primary controls on both diurnal and seasonal isotopic variability. The temperature did not affect the δ¹⁸O_v, mainly because the atmospheric processes are a function of vertical convection rather than temperature in tropical regions. The water vapour deuterium excess (d-excess) showed greater variability in 2013 than in 2014. The d-excess variation reflected the differences in convection occurring in the day and night. In addition, the vapour phase data were combined with the local meteoric water line to identify the local water vapour line and the interaction between the isotopic composition of water vapour and liquid water. The water vapour isotopic patterns paralleled the precipitation isotopes on rainy days because of equilibrium isotopic exchange. Water vapour and precipitation were isotopically similar under low humidity but showed greater differences from each other under wetter conditions. The study results provide insight into water vapour isotopic characteristics in tropical regions and constrain the role of large-scale atmospheric processes relative to isotopic variability of water vapour in Thailand and nearby countries.     

Isotopic variations in precipitation at Bangkok and their climatological significance

The stable isotopic composition of precipitation from low to mid latitudes contains information about changes of some climatic factors, such as temperature, precipitation and atmospheric circulation patterns. However, the isotopic variations in the area are very complicated because of the combined influences of these factors. Proper interpretation of the patterns of isotopic variations for palaeoclimate reconstructions in this area requires a detailed understanding of these complex stable isotope controls. The isotopic data (δ¹⁸O and δ²D) in precipitation at the International Atomic Energy Agency–World Meteorological Organization Bangkok station were collected and analysed because of the relatively long and unbroken isotopic records and the particular geographical location. The isotopic variations at Bangkok have strong seasonal patterns owing to distinct source regions in different seasons. In summer, the remote sources of water there can influence the δ¹⁸O values significantly, which is verified by the simple Rayleigh model. In winter, the mixing of isotopically distinct air masses with different origins, i.e. the continental and oceanic air masses, accounts for the isotopic variations. In the transition periods of the Asia–Australia monsoon, namely in May and October, the local vapour contribution may play a role in the isotopic ratios. On the interannual time‐scale, the influences of El Niño–southern oscillation (ENSO) and the Indian Ocean dipole (IOD) on isotopic composition are examined. The indications are that both the ENSO and IOD indices have a significant correlation with the δ¹⁸O ratios, and that the δ¹⁸O ratio in summer rains is significantly more enriched (depleted) during the warm (cold) phase of ENSO/IOD events. All the results suggest that it is useful for us in understanding the water cycling process and may be helpful in palaeoclimate reconstruction in this monsoon region. Copyright © 2006 John Wiley & Sons, Ltd.     

From precipitation to runoff: stable isotopic fractionation effect of glacier melting on a catchment scale

Stable isotope variability and fractionation associated with transformation of precipitation/accumulation to firn to glacial river water is critical in a variety of climatic, hydrological and paleoenvironmental studies. This paper documents the modification of stable isotopes in water from precipitation to glacier runoff in an alpine catchment located in the central Tibetan Plateau. Isotopic changes are observed by sampling firnpack profiles, glacier surface snow/ice, meltwater on the glacier surface and catchment river water at different times during a melt season. Results show the isotopic fractionation effects associated with glacier melt processes. The slope of the δD‐δ¹⁸O regression line and the deuterium excess values decreased from the initial precipitation to the melt‐impacted firnpack (slope from 9.3 to 8.5 and average d‐excess from 13.4‰ to 7.4‰). The slope of the δD‐δ¹⁸O line further decreased to 7.6 for the glacier runoff water. The glacier surface snow/ice from different locations, which produces the main runoff, had the same δD‐δ¹⁸O line slope but lower deuterium excess (by 3.9‰) compared to values observed in the firnpack profile during the melt season. The δD‐δ¹⁸O regression line for the river water exhibited a lower slope compared to the surface snow/ice samples, although they were closely located on the δD‐δ¹⁸O plot. Isotope values for the river and glacier surface meltwater showed little scatter around the δD‐δ¹⁸O regression line, although the samples were from different glaciers and were collected on different days. Results indicate a high consistency of isotopic fractionation in the δD‐δ¹⁸O relationships, as well as a general consistency and temporal covariation of meltwater isotope values at the catchment scale. Copyright © 2013 John Wiley & Sons, Ltd.     

Contemporary processes of environmental information in the atmosphere-glacier-runoff system in an area of typical monsoon temperate glacier

Sampling was carried out at Baishui No. 1, the largest glacier on Mt. Yulong, China, during the summers of 1999 and 2000, to investigate the spatial variations of oxygen isotopes in the atmosphere-glacier-river system. The results confirm that there is an inverse relation between the oxygen isotopic composition of precipitation and air temperature/precipitation amount. This suggests that a strong “precipitation amount effect” exists in this typical monsoon temperate-glacier region. There are marked differences of the δ¹⁸O values of winter-accumulated snow, glacial meltwater, summer precipitation and the glacier-fed river water. Spatial and temporal variations of isotopic composition are controlled by climatic conditions. Isotopic fractionation and differentiation occur during phase changes, snow-to-ice and ice-to-meltwater transformations, and runoff processes. Variations of stable isotopes in glacier runoff can indicate variations of sources of supply, as well as different discharge-related processes. Ionic changes occur as a result of meltwater contact with glacier bed materials.

     

Factors controlling diurnal variation in the isotopic composition of atmospheric water vapour observed in the taiga,eastern Siberia

Deciduous forest covers vast areas of permafrost under severe dry climate in eastern Siberia. Understanding the water cycle in this forest ecosystem is quite important for climate projection. In this study, diurnal variations in isotopic compositions of atmospheric water vapour were observed in eastern Siberia with isotope analyses of precipitation, sap water of larch trees, soil water, and water in surface organic layer during the late summer periods of 2006, 2007, and 2008. In these years, the soil moisture content was considerably high due to unusually large amounts of summer rainfall and winter snowfall. The observed sap water δ¹⁸O ranged from ?17.9‰ to ?13.3‰, which was close to that of summer precipitation and soil water in the shallow layer, and represents that of transpired water vapour. On sunny days, as the air temperature and mixing ratio rose from predawn to morning, the atmospheric water vapour δ¹⁸O increased by 1‰ to 5‰ and then decreased by about 2‰ from morning to afternoon with the mixing ratio. On cloudy days, by contrast, the afternoon decrease in δ¹⁸O and the mixing ratio was not observed. These results show that water vapour that transpired from plants, with higher δ¹⁸O than the atmospheric water vapour, contributes to the increase in δ¹⁸O in the morning, whereas water vapour in the free atmosphere, with lower δ¹⁸O, contributes to the decrease in the afternoon on sunny days. The observed results reveal the significance of transpired water vapour, with relatively high δ¹⁸O, in the water cycle on a short diurnal time scale and confirm the importance of the recycling of precipitation through transpiration in continental forest environments such as the eastern Siberian taiga. Copyright © 2012 John Wiley & Sons, Ltd.     

Groundwater Origin in Qanats,Chemo-Isotopic,and Hydrogeological Evidence

A systematic study of the chemo-isotopic characteristics and origin of the groundwater was carried out at six major qanats in the hyper-arid Gonabad area, eastern Iran. These qanats as a sustainable groundwater extraction technology have a long history, supporting human life for more than a thousand years in this region. The Gonabad qanats are characterized by outlet electrical conductivity (EC) values of 750 to 3900 µS/cm and HCO₃-Na-Mg and Cl-Na water types. The Gonabad meteoric water line (G_nMWL) was drawn at the local scale as δ²H = 6.32×δ¹⁸O + 8.35 (with R² = 0.90). It has a lower slope and intercept than the global meteoric water line due to different water vapor sources and isotope kinetic fractionation effects during precipitation in this arid region. The altitude effects on isotopic content of precipitation data were derived as δ¹⁸O = (−0.0031 × H_(m.a.s.l))−1.3). The δ²H and δ¹⁸O isotopes signatures demonstrate a meteoric origin of the groundwater of these qanats. The shift of the qanat's water samples from the local meteoric water line (LMWL) in a dry period with higher temperatures is most probably due to evaporation during the infiltration process and water movement in qanat gallery. Based on the isotopic results and mass balance calculations, the qanats are locally recharged from an area between 2000 to 2400 m.a.s.l of nearby carbonate formations and coarse alluvial sediments. The dissolution of evaporate interlayers in Neogene deposits deteriorates the groundwater quality, especially in Baidokht qanat.     

Orographic distillation and spatio‐temporal variations of stable isotopes in precipitation in the North Atlantic

Little is known about the spatial and temporal variability of the stable isotopic composition of precipitation in the North Atlantic and its relationship to the North Atlantic Oscillation (NAO) and anthropogenic climate change. The islands of the Azores archipelago are uniquely positioned in the middle of the North Atlantic Ocean to address this knowledge gap. A survey of spatial and temporal variability of the stable isotope composition of precipitation in Azores is discussed using newly presented analyses along with Global Network of Isotopes in Precipitation data. The collected precipitation samples yield a new local meteoric water line (δ²H = 7.1 * δ¹⁸O + 8.46) for the Azores region and the North Atlantic Ocean. The annual isotopic mean of precipitation shows a small range for the unweighted and precipitation mass‐weighted δ¹⁸O‐H₂O values. Results show an inverse relation between the monthly δ¹⁸O‐H₂O and the amount of precipitation, which increases in elevation and into the interior of the island. Higher amounts of precipitation (from convective storm systems) do not correspond to the most depleted values of stable isotopes in precipitation. Precipitation shows an orographic effect with depleted δ¹⁸O‐H₂O values related to the Rayleigh effect. Monthly δ¹⁸O‐H₂O values for individual precipitation sampling stations show little relationship to air temperature. Results show a local source of moisture during the summer with the characteristics of the first vapour condensate. The stable isotope composition of precipitation is strongly correlated to the NAO index, and δ¹⁸O‐H₂O values show a statistically significantly trend towards enrichment since 1962 coincident with the increased air temperature and relative humidity due to climate change. Results are in line with observations of increasing sea surface temperature and relative humidity.     

A Lagrangian approach to modelling stable isotopes in precipitation over mountainous terrain

A Lagrangian (Rayleigh) distillation model is used to track the evolution of stable isotopes in precipitation over mountainous terrain from the Pacific Coast of Canada to two alpine field sites in the Canadian Rocky Mountains. Precipitation δ¹⁸O at Vancouver constrains the model and air–mass back trajectories provide the water vapour pathway for 10 winter storm events. Isotopic values along storm pathways are modelled with a classical Rayleigh model that prescribes a linear decrease in temperature and pressure from initial to final conditions, and two models that account directly for orographic precipitation processes by: (i) applying an orographic rainfall model and (ii) using North American Regional Reanalysis data to calculate the change in vapour content along storm pathways. All models are significant predictors of snowpack δ¹⁸O, but the orographic model provides the best fit to precipitation‐weighted δ¹⁸O for each storm. The improvement in modelled δ¹⁸O by accounting for terrain along storm trajectories illustrates the need to account for orographically driven moisture loss when modelling vapour transport to ice core sites with mountainous upwind terrain. This finding is also applicable to isotopic studies of paleoaltimetry and source areas of groundwater recharge. Copyright © 2011 John Wiley & Sons, Ltd.