Structure and stratigraphy of the Teplá–Barrandian Neoproterozoic,Bohemian Massif: A new plate-tectonic reinterpretation

The Teplá–Barrandian unit (TBU) of the Bohemian Massif exposes a section across the once extensive Avalonian–Cadomian belt, which bordered the northern active margin of Gondwana during late Neoproterozoic. This paper synthesizes the state-of-the-art knowledge on the Cadomian basement of the TBU to redefine its principal component units, to revise an outdated stratigraphic scheme, and to interpret this scheme in terms of a recent plate-tectonic model for the Cadomian orogeny in the Bohemian Massif. The main emphasis of this paper is on an area between two newly defined fronts of the Variscan pervasive deformation to the NW and SE of the Barrandian Lower Paleozoic overlap successions. This area has escaped the pervasive Variscan (late Devonian to early Carboniferous) ductile reworking and a section through the Cadomian orogen is here superbly preserved.The NW segment of the TBU consists of three juxtaposed allochthonous belts of unknown stratigraphic relation (the Kralovice–Rakovník, Radnice–Kralupy, and Zbiroh–?árka belts), differing in lithology, complex internal strain patterns, and containing sedimentary and tectonic mélanges with blocks of diverse ocean floor (meta-)basalts. We summarize these three belts under a new term the Blovice complex, which we believe represents a part of an accretionary wedge of the Cadomian orogen.The SE segment of the TBU exposes the narrow Pi?ín belt, which is probably a continuation of the Blovice complex from beneath the Barrandian Lower Paleozoic, and a volcanic arc sequence (the Davle Group). Their stratigraphic relation is unknown. Flysch units (the ?těchovice Group and Svrchnice Formation) overlay the arc volcanics, and both units contain material derived from volcanic arc. The former was also sourced from the NW segment, whereas the latter contains an increased amount of passive margin continental material. In contrast to the Blovice complex, the flysch experienced only weak Cadomian deformation.The new lithotectonic zonation fits the following tectonic scenario for the Cadomian evolution of the TBU well. The S- to SE-directed Cadomian subduction beneath the TBU led to the involvement of turbidites, chaotic deposits, and 605 ± 39 Ma ocean floor in the accretionary wedge represented by the Blovice complex. The accretionary wedge formation mostly overlapped temporally with the growth of the volcanic arc (the Davle Group) at ~ 620–560 Ma. Upon cessation of the arc igneous activity, the rear of the wedge and some elevated portions of the arc were eroded to supply the deep-water flysch sequences of the ?těchovice Group, whereas the comparable Svrchnice Formation (~ 560 to < 544 Ma) was deposited in a southeasterly remnant basin close to the continental margin. The Cadomian orogeny in the TBU was terminated at ~ 550–540 Ma by slab breakoff, by final attachment of the most outboard ~ 540 Ma oceanic crust, and by intrusion of ~ 544–524 Ma boninite dikes marking the transition from the destructive to transform margin during the early/middle Cambrian.     

The Pacific Gondwana margin in the late Neoproterozoic–early Paleozoic: Detrital zircon U–Pb ages from metasediments in northwest Argentina reveal their maximum age,provenance and tectonic setting

U–Pb detrital zircon ages are reported from Puncoviscana Formation (late Neoproterozoic–Early Cambrian) and Mesón Group (Late Cambrian) greywackes of northwest Argentina, to constrain provenance and depositional environment.The new data are combined with previously-published detrital zircon ages, to show that Puncoviscana Formation age patterns contain two broad groups: late Mesoproterozoic–early Neoproterozoic (1150–850 Ma) and late Neoproterozoic–Early Cambrian (650–520 Ma); with their relative proportions varying inversely with youngest component age. The 1150–850 Ma age components are dominant in greywackes with oldest late Neoproterozoic components > 600 Ma. The former diminish considerably when late Neoproteozoic components become dominant and younger, to 520 Ma. A northernmost greywacke sample from Purmamarca, Jujuy, is distinctive: whilst its zircon age pattern partly resembles other Puncoviscana Formation samples, it contains no Cambrian–late Neoproterozoic ages, the youngest ages being early Neoproterozoic. This may reflect an early, Neoproterozoic, passive-margin depocentre for the Formation, or an older (early Neoproterozoic) succession within it, which may predate the Brasiliano orogeny in Brazil. The youngest age components, c. 520 Ma, in a greywacke from Rancagua (Cachi, Salta province), dominate an almost unimodal pattern suggestive of contemporary volcanic sources at a late Early Cambrian depocentre. Detrital zircon age patterns of the Mesón Group (Lizoite Formation) have major Cambrian–latest Neoproterozoic components resembling those of the Puncoviscana Formation, but its Mesoproterozoic component is diminished, and there are no significant age components of this age. Small youngest components at c. 500 Ma suggest a maximum Late Cambrian stratigraphic age. The Puncoviscana Formation detrital zircon patterns suggest a provenance in a continental hinterland having a stabilised, extensive late Mesoproterozoic orogen (with minor Paleoproterozoic and Archean precursors), and a more variable late Neoproterozoic orogen containing an evolving sequence of less extensive subcomponents. A direct relationship with the Brazilian Shield is suggested; with sediment supplies originating within active-margin orogens of the interior and collisional orogens at the suture between African and South American cratons, but ultimate deposition in passive-margin environments of western Gondwanaland.     

Provenance of Neoproterozoic and early Paleozoic siliciclastic rocks of the Teplá-Barrandian unit (Bohemian Massif): Evidence from U–Pb detrital zircon ages

New LA-ICP-MS U–Pb detrital zircon ages from Ediacaran and Paleozoic siliciclastic rocks are used to constrain provenance and paleogeographic affinities of the Teplá-Barrandian unit (TBU) in the centre of the Bohemian Massif (Central Europe, Czech Republic). The samples taken span the period from ≤ 635 Ma to ～ 385 Ma and permit recognition of provenance changes that reflect changes in geotectonic regime. Detrital zircon age spectra of two Ediacaran, one Lower Cambrian and three Upper Ordovician samples resemble the ages known from the NW African proportion of Gondwana, particularly the Trans-Saharan belt, while three rocks from higher Lower Cambrian to Lowermost Ordovician strata contain detritus that may have been derived exclusively from local sources. The age spectrum of the Devonian rock is a combination of the NW Gondwanan and local features. These new findings in combination with a wide range of published data are in agreement with a Neoproterozoic subduction-related setting at the margin of Gondwana followed by a Cambrian/Early Ordovician rifting stage and an Ordovician passive margin setting. Furthermore the data are in favour of a position of the TBU at the Gondwanan margin throughout pre-Variscan times.     

Detrital zircon ages from the Ross Supergroup,north Victoria Land,Antarctica: Implications for the tectonostratigraphic evolution of the Pacific-Gondwana margin

We present new U–Pb isotopic age data for detrital zircons from 16 deformed sandstones of the Ross Supergroup in north Victoria Land, Antarctica. Zircon U/Th ratios primarily point to dominantly igneous parent rocks with subordinate contributions from metamorphic sources. Comparative analysis of detrital zircon age populations indicates that inboard stratigraphic successions (Wilson Terrane) and those located outboard of the East Antarctic craton (the Bowers and Robertson Bay terranes) have similar ~ 1200–950 Ma (Mesoproterozoic–Neoproterozoic) and ~ 700–490 Ma (late Neoproterozoic–Cambrian, Furongian) age populations. The affinity of the age populations of the sandstones to each other, as well as Gondwana sources and Pacific-Gondwana marginal stratigraphic belts, challenges the notion that the outboard successions form exotic terranes that docked with Gondwana during the Ross orogeny and instead places the terranes in proximity to each other and within the peri-Gondwana realm during the late Neoproterozoic to Cambrian. The cumulative zircon age suite from north Victoria Land yields a polymodal age spectra with a younger, primary 700–480 Ma age population that peaks at ~ 580 Ma. Cumulative analysis of zircons with elevated U/Th ratios (> 20) indicating metamorphic heritage yield ~ 657–532 Ma age probability peaks, which overlap with the younger dominantly igneous zircon population. The data are interpreted to give important new evidence that is consistent with ongoing convergent arc magmatism by ~ 626 Ma, which provided the dominant zircon-rich igneous rocks and subordinate metamorphic rocks. Maximum depositional ages as young as ~ 493–481 Ma yielded by deformed sequences in the outboard Bowers and Robertson Bay terrane samples provide new support for late Cambrian to Ordovician deformation in outboard sectors of the orogen, consistent with tectonic models that call for cyclic phases of contraction along the north Victoria Land sector of the Ross–Delamerian orogen.     

Peri-Gondwanan origin and early geodynamic history of NE Sicily: A zircon tale from the basement of the Peloritani Mountains

The ages of detrital zircon grains from one paragneiss and inherited zircon cores from two augen gneisses from the amphibolite facies basement of the Peloritani Mountains (southern Italy) measured by SHRIMP U–Pb constrain the previously unknown deposition age of the original sediments and help to elaborate a model for their provenance and subsequent evolution. The deposition age is latest Neoproterozoic to Cambrian (~ 545 Ma), bracketed by the combined ages of the youngest detrital/inherited zircon populations and of zircon from virtually coeval granitoids that intrude the metasediments. This is consistent with the subgreenschist facies Palaeozoic volcano–sedimentary sequences exposed in the southern Peloritani Mountains being the original cover rocks of the northern Peloritani late Neoproterozoic to early Cambrian basement. The age spectra of the detrital/inherited zircon grains show that the Neoproterozoic/Cambrian sediments were derived from the erosion of sources dominated by Neoproterozoic rocks with ages in the range of 0.85–0.54 Ga, with other main components aged 1.1–0.9 and ~ 2.7–2.4 Ga, and a minor one aged ~ 1.6 Ga, as typically found in peri-Gondwanan terranes. The presence of a large amount of Grenvillian-aged zircon contradicts previous models that propose a West African affinity for the Calabria–Peloritani Terrane, and the absence of 2.2–1.9 Ga Trans Amazonian/Tapajós–Parima/Eburnean zircon rules out an Amazonian provenance. The age spectra are more consistent with the basement sediments having an East African origin, similar to that of the early Palaeozoic sandstones in southern Israel and Jordan, part of a “provenance regionality” shared with other terranes currently located in the eastern Mediterranean area.     

How far did the Cadomian ʽterranesʼ travel from Gondwana during early Palaeozoic? A critical reappraisal based on detrital zircon geochronology

In this paper, laser ablation ICP-MS U–Pb detrital zircon ages are used to discuss provenance and early Palaeozoic palaeogeography of continental fragments that originated in the Cadomian–Avalonian active margin of Gondwana at the end of Precambrian, were subsequently extended during late Cambrian to Early Ordovician opening of the Rheic Ocean, and finally were incorporated into and reworked within the European Variscan belt. The U–Pb detrital zircon age spectra in the analysed samples, taken across a late Neproterozoic (Ediacaran) to Early/Middle Devonian metasedimentary succession of the southeastern Teplá–Barrandian unit, Bohemian Massif, are almost identical and exhibit a bimodal age distribution with significant peaks at about 2.1–1.9 Ga and 650–550 Ma. We interpret the source area as an active margin comprising a cratonic (Eburnean) hinterland rimmed by Cadomian volcanic arcs and we suggest that this source was available at all times during deposition. The new detrital zircon ages also corroborate the West African provenance of the Teplá–Barrandian and correlative Saxothuringian and Moldanubian units, questioned in some palaeogeographic reconstructions. Finally, at variance with the still popular concept of the Cadomian basement units as far-travelled terranes, we propose that early Palaeozoic basins, developed upon the Cadomian active margin, were always part of a wide Gondwana shelf and drifted northwards together before involvement in the Variscan collisional belt.     

Neoproterozoic–Early Cambrian tectono-magmatic evolution of the Central Iranian terrane,northern margin of Gondwana: Constraints from detrital zircon U–Pb and Hf–O isotope studies

U–Pb dating and oxygen and Lu–Hf isotope analyses are applied to ~ 400 detrital zircon grains from the Neoproterozoic–Cambrian Kahar, Bayandor and Zaigun sandstones. The results reveal the evolutionary history of the Central Iranian continental crust in the northern margin of Gondwana during the Neoproterozoic–Cambrian. The U–Pb dating produces major peaks of crystallization ages at 0.5–0.7 Ga and minor peaks around the Tonian, Paleoproterozoic and Neoarchean. The zircon population in the Zaigun sandstone is dominated by long-transported grains and exhibits slightly different zircon distribution patterns than those from the older Kahar and Bayandor units. The zircon population ages and Hf isotopes of the Zaigun sample are very similar to the Neoproterozoic–Early Palaeozoic siliciclastic units in the Arabian Nubian shield (ANS) and Turkey, which suggests the late to post–Pan-African unroofing of the Afro–Arabia realm as the main process for detritus accumulation in Central Iran during the early Palaeozoic. A significant proportion of the Tonian-aged zircons (~ 64%) in the Kahar and Bayandor samples show positive εHf_(t) values, whereas those with late Cryogenian–Ediacaran ages have high δ¹⁸O and variable εHf_(t) values (~− 30‰ to + 17‰), suggesting that the crustal evolution of provenance of the Tonian-aged zircons commenced in an island arc setting and continued in an active continental margin. All the samples contain pre-Neoproterozoic zircons that are ca 1.9–2.3 Ga or 2.5–3.2 Ga, which are much older than the known Neoproterozoic igneous rocks in Iran and are more consistent with pre-Neoproterozoic igneous-metamorphic rocks in the eastern ANS and northern Africa. These ages support the eastern sector of the Afro–Arabia margin as a provenance for the detrital zircons in the oldest sedimentary sequences of Iran during the late Neoproterozoic–Cambrian. The Hf model ages of zircons with mantle-like δ¹⁸O values suggest that a significant amount of continental crust in the provenance of the detrital zircons was generated at around 1.0–2.0 and 3.0–3.5 Ga, likely by mantle-derived mafic magmas, and subsequently reworked during crustal differentiation into younger, more felsic crust with varying crustal residence times.     

Recurrent rare earth element mineralization in the northwestern Okcheon Metamorphic Belt,Korea: SHRIMP U–Th–Pb geochronology,Nd isotope geochemistry,and tectonic implications

Rare earth element (REE) mineralization is hosted within Neoproterozoic alkaline metaigneous rocks in the northwestern part of the Okcheon Metamorphic Belt (OMB), a polymetamorphosed fold-and-thrust belt transecting the Paleoproterozoic Gyeonggi and Yeongnam Massifs in the southern Korean Peninsula. The principal carrier phase of REEs is allanite. Allanite grains can be subdivided into several types based on the texture and mineral assemblage including quartz, K-feldspar, biotite, britholite, apatite, fergusonite, andradite, magnetite, zircon, titanite and fluorite. Electron microprobe analysis of allanite clearly distinguishes sample-to-sample variations in total REEs, Ca, Al, Fe and Y but the textural varieties from each rock sample do not show marked differences in those elements. Sensitive high-resolution ion microprobe dating of allanite and zircon reveals a complex history of multistage mineralization. Allanite grains from REE ores yielded Late Ordovician (444.6 ± 8.0 Ma), Permian to Triassic (ca. 300–220 Ma) and Early Jurassic (199–183 Ma) ²⁰⁸Pb/²³²Th ages. These multiple age components often coexist in single grains showing slight differences in backscattered electron brightness. The Ordovician components have distinctly higher Th/U than the younger domains in the same rock sample. The cores and rims of zircon from a syenite hosting REE ore bodies yielded Neoproterozoic (858.2 ± 6.3 Ma) and Early Jurassic (ca. 190 Ma) ²⁰⁶Pb/²³⁸U ages, respectively. The Early Jurassic ages (194–187 Ma) also obtained from zircon grains from granites taken from dykes occurring close to the ores and a drill core indicate the correspondence between granitic magmatism and REE mineralization. The Neoproterozoic zircon inheritance (weighted mean = 853.9 ± 3.8 Ma) in these granites is in sharp contrast to the dominant Paleoproterozoic inherited zircon from the widespread earliest Middle Jurassic granites enclosing the mineralized zone. The geotectonic significance of the Late Ordovician event recorded in the allanite, as well as in detrital zircon from the OMB, is still unclear but its temporal coincidence with intraplate volcanism and arc-related igneous activity, respectively, reported from the southwestern edge of the adjacent Taebaeksan Basin and the southwestern Gyeonggi Massif is noteworthy. The following Permian–Triassic and Early Jurassic mineralization events are probably linked to the continental suturing between the North and South China blocks and subsequent post-orogenic magmatism, and arc magmatism resulting from the paleo-Pacific plate subduction, respectively. Sub-grain Sm–Nd isotopic analyses of allanite by laser ablation multiple collector ICPMS yielded initial ε_Nd values plotting along the Nd isotopic evolution path of the Neoproterozoic metaigneous rocks, indicating that REEs originating from the host rock have been recycled during multistage mineralization events. The profound differences in inherited zircon ages and Nd isotopic compositions between the Early and Middle Jurassic granites may reflect the presence of a major thrust-bounded crustal structure beneath the OMB.     

The Zhaheba ophiolite complex in Eastern Junggar (NW China): Long lived supra-subduction zone ocean crust formation and its implications for the tectonic evolution in southern Altaids

The composite Zhaheba ophiolite complex, exposed in Eastern Junggar in the Southern Altaids, records an unusually long record of oceanic crust and magmatic arc evolution. The Zhaheba ophiolite complex consists of ultramafic rocks, gabbro, diorite, basalt and chert intruded by diabase dikes and diorite porphyry. These rocks are overlain by a several-km-thick section of tuffaceous rocks, volcaniclastic sedimentary rocks, and intermediate volcanic rocks. The igneous rocks of the ophiolite complex show negative Nb and Ta anomalies and LREE enrichment relative to HREE, suggesting the influence of fluids derived from a subducting oceanic slab. The LA-ICPMS U–Pb age of zircons from gabbro is 495.1 ± 3.5 Ma. Zircon ages from diorite and basalt are 458.3 ± 7.2 Ma and 446.6 ± 6.0 Ma, respectively. The basalt is locally overlain by bedded chert. Diabase dikes and diorite porphyry yield the U–Pb ages of 421.5 ± 4.1 Ma and 423.7 ± 6.5 Ma, respectively. The age of stratigraphically lower part of the overlying volcanic–volcaniclastic section is constrained to be about 410 Ma, the maximum depositional age of the tuffaceous sandstone from U–Pb detrital zircon ages. Late rhyolite at the top of the stratigraphic section yielded a U–Pb zircon age of 280.3 ± 3.7 Ma. The age and stratigraphic relationships for the Zhaheba ophiolite complex and related rocks suggest that the period of ~ 70 Ma of initial supra-subduction magmatism was followed by construction of a mature island arc that spanned an additional 140 Ma. Many other ophiolites in the southern Altaids appear to record similar relationships, and are represented as substrates of oceanic island arcs covered by island arc volcanism in supra-subduction zone. The occurrence of the Zhaheba ophiolite complex with tuffaceous and intermediate to felsic volcanic rocks is different from the rock association of classic Tethyan SSZ ophiolites but similar to some ophiolites in North America. Although the Zhaheba ophiolite belt is flanked by the Dulate arc in the north and Yemaquan arc in the south, it cannot stand a suture between two arcs. It is suggested that Devonian–Carboniferous Dulate arc was built on the late Cambrian–middle Ordovician Zhaheba supra-subduction oceanic crust. The late Carboniferous rocks and early Permian rocks in Dulate arc are interpreted to form in the extensional process within Zhaheba–Dulate arc composite system.     

The missing Rheic Ocean magmatic arcs: Provenance analysis of Late Paleozoic sedimentary clastic rocks of SW Iberia

Early Carboniferous turbiditic sedimentary rocks in synorogenic basins located on both sides of the Rheic suture in SW Iberia were studied for provenance analysis. An enigmatic feature of this suture, which resulted from closure of the Rheic Ocean with the amalgamation of Pangea in the Late Carboniferous, is that there are no recognizable mid- to Late Devonian subduction-related magmatic rocks, which should have been generated during the process of subduction, on either side of it. U–Pb LA–ICP-MS geochronology of detrital zircons from Early Carboniferous turbidites in the vicinity of the Rheic suture in SW Iberia, where it separates the Ossa–Morena Zone (with Gondwana continental basement) to the north from the South Portuguese Zone (with unknown/Meguma? continental basement) to the south, reveals the abundance of mid- to Late Devonian (51–81%) and Early Carboniferous (13–25%) ages. The Cabrela and Mértola turbidites of the Ossa–Morena and South Portuguese zones, respectively, are largely devoid of older zircons, differing from the age spectra of detrital zircons in the oldest (Late Devonian) strata in the underlying South Portuguese Zone, which contain abundant Cambrian and Neoproterozoic ages. Mid- to Late Devonian zircons in the Cabrela Formation (age cluster at c. 391 Ma, Eifelian–Givetian transition) and Mértola Formation (age clusters at c. 369 Ma and at c. 387 Ma, Famennian and Givetian respectively) are attributable to a source terrane made up of magmatic rocks with a simple geological history lacking both multiple tectonic events and older continental basement. The terrane capable of sourcing sediments dispersed on both sides of the suture is interpreted to have been completely removed by erosion in SW Iberia. Given that closure of the Rheic Ocean required subduction of its oceanic lithosphere and the absence of significant arc magmatism on either side of the Rheic suture, we suggest: 1) the source of the zircons in the SW Iberia basins was a short-lived Rheic ocean magmatic arc, and 2) given the lack of older zircons in the SW Iberia basins, this short-lived arc was probably developed in an intra-oceanic environment.     

Formation and evolution of Precambrian continental lithosphere in South China

An overview is presented for the formation and evolution of Precambrian continental lithosphere in South China. This is primarily based on an integrated study of zircon U–Pb ages and Lu–Hf isotopes in crustal rocks, with additional constraints from Re–Os isotopes in mantle-derived rocks. Available Re–Os isotope data on xenolith peridotites suggest that the oldest subcontinental lithospheric mantle beneath South China is primarily of Paleoproterozoic age. The zircon U–Pb ages and Lu–Hf isotope studies reveal growth and reworking of the juvenile crust at different ages. Both the Yangtze and Cathaysia terranes contain crustal materials of Archean U–Pb ages. Nevertheless, zircon U–Pb ages exhibit two peaks at 2.9–3.0 Ga and ~ 2.5 Ga in Yangtze but only one peak at ~ 2.5 Ga in Cathaysia. Both massive rocks and crustal remnants (i.e., zircon) of Archean U–Pb ages occur in Yangtze, but only crustal remnants of Archean U–Pb ages occur in Cathaysia. Zircon U–Pb and Lu–Hf isotopes in the Kongling complex of Yangtze suggest the earliest episode of crustal growth in the Paleoarchean and two episodes of crustal reworking at 3.1–3.3 Ga and 2.8–3.0 Ga. Both negative and positive ε_Hf(t) values are associated with Archean U–Pb ages of zircon in South China, indicating both the growth of juvenile crust and the reworking of ancient crust in the Archean. Paleoproterozoic rocks in Yangtze exhibit four groups of U–Pb ages at 2.1 Ga, 1.9–2.0 Ga, ~ 1.85 Ga and ~ 1.7 Ga, respectively. They are associated not only with reworking of the ancient Archean crust in the interior of Yangtze, but also with the growth of the contemporaneous juvenile crust in the periphery of Yangtze. In contrast, Paleoproterozoic rocks in Cathaysia were primarily derived from reworking of Archean crust at 1.8–1.9 Ga. The exposure of Mesoproterozoic rocks are very limited in South China, but zircon Hf model ages suggest the growth of juvenile crust in this period due to island arc magmatism of the Grenvillian oceanic subduction. Magmatic rocks of middle Neoproterozoic U–Pb ages are widespread in South China, exhibiting two peaks at about 830–800 Ma and 780–740 Ma, respectively. Both negative and positive ε_Hf(t) values are associated with the middle Neoproterozoic U–Pb ages of zircon, suggesting not only growth and reworking of the juvenile Mesoproterozoic crust but also reworking of the ancient Archean and Paleoproterozoic crust in the middle Neoproterozoic. The tectonic setting for this period of magmatism would be transformed from arc–continent collision to continental rifting with reference to the plate tectonic regime in South China.     

Two types of ultrapotassic plutonic rocks in the Bohemian Massif — Coeval intrusions at different crustal levels

We present U–Pb zircon age determinations of two Variscan ultrapotassic plutonic rocks from the Moldanubian Zone (Bohemian Massif). Equant, multifaceted zircons without inherited cores from a two-pyroxene–biotite quartz monzonite of the Jihlava Pluton yielded a precise age of 335.12 ± 0.57 Ma, interpreted as dating magma crystallization. The majority of both tabular and prismatic grains from the amphibole–biotite melagranite (“durbachite”) from the T?ebí? Pluton plot along a discordia intersecting the concordia at 334.8 ± 3.2 Ma; prismatic zircon grains commonly contain inherited cores and yield an upper intercept age of 2.2 Ga, indicating early Proterozoic inheritance. We therefore suggest that both types of the ultrapotassic plutonic rocks from the Bohemian Massif crystallized at ca 335 Ma, and the previously published ages higher than ca 340 Ma for “durbachites” were biased by a small amount of unresolved inheritance. The ultrapotassic magma emplacement in the middle crust was related to rapid exhumation of a deep crustal segment, considered as isothermal decompression between high-pressure (～ 340 Ma) and medium-pressure (～ 333 Ma) stages recorded in granulites. Mineral assemblages as well as external and internal zircon morphology suggest that the Jihlava intrusion was deep and dry, whereas the T?ebí? intrusion was shallow and wet. Low ε_Hf values of zircons (? 4.4 to ? 7.5) in both rock types suggest a similar source with a predominant crustal component. However, inherited grains in the T?ebí? melagranite indicate its contamination with crustal material during emplacement, and thus possibly a slower rate of exhumation and/or of magma ascent through the crust.     

Ediacaran to Lower Ordovician age for rocks ascribed to the Schist–Graywacke Complex (Iberian Massif,Spain): Evidence from detrital zircon SHRIMP U–Pb geochronology

New SHRIMP U–Pb ages of detrital zircon obtained from eight samples of Neoproterozoic to Lower Paleozoic graywackes, schists, microconglomerates and shales provide the maximum depositional age and a new zircon age pattern for the Schist–Graywacke Complex (SGC) from the Iberian Massif (SW Europe). The ages of the youngest zircon grains found in four samples provide a maximum depositional age of latest Ediacaran–Lower Cambrian for the complex. Lower-Middle Cambrian fossiliferous formations on top of the lithologies correctly attributed to the SGC constrain its minimum depositional age. Unexpectedly, two samples attributed to the SGC yielded Cambro-Ordovician zircon populations. These must belong to younger Lower Ordovician sedimentary successions that, up to now, have not been differentiated from those of the SGC. The new age patterns are mainly composed of Neoproterozoic (73%) and Paleoproterozoic (15%) ages, with minor Neoarchean (7%), Mesoarchean (2%), Mesoproterozoic (3%) and Cambrian (1%) ages for the latest Ediacaran–Lower Cambrian successions, and Neoproterozoic (46%) and Cambro-Ordovician (46%) ages, with minor Neoarchean (1%), Mesoarchean (0.5%), Paleoproterozoic (6%), Mesoproterozoic (0.5%) and Carboniferous (1%) ages for the Lower Ordovician successions. The presence of Mesoproterozoic zircon points to the Saharan Metacraton as a contributing source for these sediments. Cadomian granitoids could have been a local Neoproterozoic source. The Cambro-Ordovician zircons may also indicate that Cambro-Ordovician magmatism contributed as a source. Cambro-Ordovician volcanism, the most probable source of the Cambro-Ordovician zircons, would have been coeval with the deposition of the Lower Ordovician successions.     

Geochronology and Hf isotope of detrital zircons from Precambrian sequences in the eastern Jiangnan Orogen: Constraining the assembly of Yangtze and Cathaysia Blocks in South China

The Jiangnan Orogen, the eastern part of which comprises the oceanic Huaiyu terrane to the northeast and the continental Jiuling terrane to the southwest, marks the collision zone of the Yangtze and the Cathaysia Blocks in South China. Here, zircon U–Pb geochronological and Lu–Hf isotopic results from typical basement and cover meta-sedimentary/sedimentary rock units in the eastern Jiangnan Orogen are presented. The basement sequences in southwestern Huaiyu terrane are mainly composed of marine volcaniclastic turbidite, ophiolite suite and tuffaceous phyllite, whereas those in the northeastern Huaiyu consist of littoral face pebbly feldspathic sandstones and greywacke interbedded with intermediate-basic volcanic rocks. Combined with previous studies, the present data show that the basement sequences exhibit arc affinities. Zircons from the basement phyllite in the southwestern margin of the Huaiyu terrane, representing a Neoproterozoic back-arc basin, yield a single age population of 800–900 Ma. The basement greywacke from northeastern Huaiyu terrane, representing fore-arc basin, is also characterized by zircons that preserve a single tectono-thermal event during 800–940 Ma. However, the late Neoproterozoic cover sequence preserves zircons from multiple sources with age populations of 750–890 Ma, 1670–2070 Ma and 2385–2550 Ma. Moreover, Hf isotopic data further reveal that most detrital zircons from the basement sequences yield positive εHf(t) values and late Mesoproterozoic model ages, while those of the cover sequence mostly show negative εHf(t) values. The Hf isotopic data therefore suggest that the basement sequences are soured from a Neoproterozoic arc produced by reworking of subducted late Mesoproterozoic materials. The geochronological and Hf isotopic data presented in this study suggest ca. 800 Ma for the assembly of the Huaiyu and Jiuling terranes, implying that the amalgamation of the Yangtze and Cathaysia Blocks in the eastern part occurred at ca. 800 Ma.     

Peri-Amazonian,Avalonian-type and Ganderian-type terranes in the South Carpathians,Romania: The Danubian domain basement

The Danubian domain basement of the South Carpathians, Romania, comprises two Neoproterozoic continental crustal fragments, the Dr?g?an and Lainici-P?iu? terranes, which were sutured by the closure of an intervening oceanic domain, the Ti?ovi?a terrane. Magmatic and detrital zircons extracted from an orthogneiss, four granitoid plutons, two metasedimentary units, and a Liassic sandstone were dated by zircon U/Pb LA-ICP-MS. The F?ge?el augen gneiss from the Dr?g?an terrane basement yielded an age of 803.2 ± 4.4 Ma, the oldest well-constrained crystallization age reported from the Romanian Carpathians basement. The Tismana, ?u?i?a, Novaci and Olte? granitoid plutons, which intrude the Lainici-P?iu? terrane basement, yielded ages of 600.5 ± 4.4, 591.0 ± 3.5, 592.7 ± 4.9, and 588 ± 2.9 Ma, respectively. The Tismana granitoid age of 600 Ma and the youngest detrital zircon ages of 637–622 Ma from a metaquartzite within the Lainici-Paiu? terrane, constrain the deposition of the metaquartzite protolith to ca. 620–600 Ma. The 803 Ma age represents an old Pan-African age, whereas the younger Neoproterozoic ages suggest Pan-African/Cadomian thermotectonic events. Detrital and inherited zircon ages within the Dr?g?an and Lainici-Paiu? terranes attest to a peri-Amazonian, Avalonian-type provenance for the Dr?g?an terrane and possibly a Ganderian-type provenance for the Lainici-P?iu? terrane. The Lainici-P?iu? terrane rifted off Gondwana before the Dr?g?an terrane. Both terranes were attached to Moesia during the Early Paleozoic.     

U–Pb and Lu–Hf isotopes in detrital zircon from Neoproterozoic sedimentary rocks in the northern Yangtze Block: Implications for Precambrian crustal evolution

A combined study of Lu–Hf isotopes and U–Pb ages for detrital zircons from sedimentary rocks can provide information on the crustal evolution of sedimentary provenances, and comparisons with potential source regions can constrain interpretations of paleogeographic settings. Detailed isotopic data on detrital zircons from Neoproterozoic sedimentary rocks in the northern part of the Yangtze Block suggest that these rocks have the maximum depositional ages of ~ 750 Ma, and share a similar provenance. In their source area, units of late Archean (2.45 to 2.55 Ga) to Paleoproterozoic (1.9 to 2.0 Ga) U–Pb ages made up the basement, and were overlain or intruded by magmatic rocks of Neoproterozoic U–Pb ages (740 to 900 Ma). Hf isotopic signatures of the detrital zircons indicate that a little juvenile crust formed in the Neoarchean; reworking of old crust dominates the magmatic activity during the Archean to Paleoproterozoic, while the most significant juvenile addition to the crust occurred in the Neoproterozoic. Only the Neoproterozoic zircon U–Pb ages can be matched with known magmatism in the northern Yangtze Block, while other age peaks cannot be correlated with known provenance areas. Similar zircon U–Pb ages have been obtained previously from sediments along the southeastern and western margins of the Yangtze Block. Thus, it is suggested that an unexposed old basement is widespread beneath the Yangtze Block and was the major contributor to the Neoproterozoic sediments. This basement had a magmatic activity at ~ 2.5 Ga, similar to that in North China; but zircon Hf isotopes suggest significant differences in the overall evolutionary histories between the Yangtze and North China.     

New data on the Neoproterozoic – Cambrian geotectonic setting of the Teplá-Barrandian volcano-sedimentary successions: geochemistry,U-Pb zircon ages,and provenance (Bohemian Massif,Czech Republic)

The Teplá-Barrandian unit (TBU) of the Bohemian Massif was a part of the Avalonian-Cadomian belt at the northern margin of Gondwana during Neoproterozoic and Early Cambrian times. New detrital zircon ages and geochemical compositions of Late Neoproterozoic siliciclastic sediments confirm a deposition of the volcano-sedimentary successions of the TBU in a back-arc basin. A change in the geotectonic regime from convergence to transtension was completed by the time of the Precambrian-Cambrian boundary. The accumulation of around 2,500 m Lower Cambrian continental siliciclastics in a Basin-and-Range-type setting was accompanied by magmatism, which shows within-plate features in a few cases, but is predominantly derived from anatectic melts displaying the inherited island arc signature of their Cadomian source rocks. The geochemistry of clastic sediments suggests a deposition in a rift or strike-slip-related basin, respectively. A marine transgression during Middle Cambrian times indicates markedly thinned crust after the Cadomian orogeny. Upper Cambrian magmatism is represented by 1,500 m of subaerial andesites and rhyolites demonstrating several geochemical characteristics of an intra-plate setting. Zircons from a rhyolite give a U-Pb-SHRIMP age of 499±4 Ma. The Cambrian sedimentary and magmatic succession of the TBU records the beginning of an important rifting event at the northern margin of Gondwana.

Identification and isotopic studies of early Cambrian magmatism (El Carancho Igneous Complex) at the boundary between Pampia terrane and the Río de la Plata craton,La Pampa province,Argentina

We have identified late Early Cambrian metaigneous rocks very poorly exposed at the Estancia El Carancho, in central La Pampa province, Argentina. They comprise calc–alkaline metadiorite and metagranite, and tholeiitic metapyroxenite and metagabbro. They are jointly referred to as the El Carancho Igneous Complex, and regarded to pertain to the Pampean magmatic arc and backarc, respectively. Titanite U–Pb SHRIMP dating of the metapyroxenite yielded 528 ± 5 Ma, and zircon U–Pb SHRIMP dating of the metadiorite yielded 520 ± 1.4 Ma. Hafnium isotope determinations on the dated zircons show ¹⁷⁶Hf/¹⁷⁷Hf ratios corresponding to positive εHf values from + 7.18 to + 9.37; Hf model ages of the Cambrian zircons yielded 884 Ma. It is interpreted that the metadiorites of the Complex crystallized from an Early Neoproterozoic (Tonian) juvenile source. We argue that the inferred occurrence of juvenile Tonian magmatic rocks in the (otherwise, mostly Paleo-Mesoproterozoic) substratum of the southern Pampia terrane could indicate a zone of thinned basement possibly associated with the early stage of Rodinia's breakup. In addition, the studied segment of the Pampean magmatic arc is contaminated by also juvenile, Late Mesoproterozoic crust, as evidenced by the presence of xenocrystic cores of 1140–1194 Ma – T_DM-Hf 1720 Ma and εHf values of + 3.24 to + 4.85 – in the Cambrian zircons, hence suggesting that the studied segment of the Pampean magmatic arc was intruded into juvenile Late Mesoproterozoic magmatic arc rocks. The El Carancho Igneous Complex would be located at the tectonic boundary between the Pampia terrane and the Río de la Plata craton. This boundary stands out in the aeromagnetic data as a change in the structural orientation about a roughly N-S line located approximately at 65° W and representing the suture zone between the Pampia terrane and the Río de la Plata craton. Our geotectonic model envisages westward dipping subduction of oceanic crust beneath the Pampia terrane; the El Carancho Igneous Complex would, therefore, have been originated on the Pampia side (upper plate) of the suture. Slivers of the arc- and backarc-type rocks would have been tectonically imbricated in the suture zone during the Pampean orogeny.     

Neoproterozoic to Early Cambrian history of an active plate margin in the Teplá–Barrandian unit—a correlation of U–Pb isotopic-dilution-TIMS ages (Bohemia, Czech Republic)

The Teplá–Barrandian unit (TBU) of the Bohemian Massif shared a common geological history throughout the Neoproterozoic and Cambrian with the Avalonian–Cadomian terranes. The Neoproterozoic evolution of an active plate margin in the Teplá–Barrandian is similar to Avalonian rocks in Newfoundland, whereas the Cambrian transtension and related calc-alkaline plutons are reminiscent of the Cadomian Ossa–Morena Zone and the Armorican Massif in western Europe. The Neoproterozoic evolution of the Teplá–Barrandian unit fits well with that of the Lausitz area (Saxothuringian unit), but is significantly distinct from the history of the Moravo–Silesian unit.The oldest volcanic activity in the Bohemian Massif is dated at 609+17/−19 Ma (U–Pb upper intercept). Subduction-related volcanic rocks have been dated from 585±7 to 568±3 Ma (lower intercept, rhyolite boulders), which pre-dates the age of sedimentation of the Cadomian flysch ( t chovice Group). Accretion, uplift and erosion of the volcanic arc is documented by the Neoproterozoic Dob í conglomerate of the upper part of the flysch. The intrusion age of 541+7/−8 Ma from the Zgorzelec granodiorite is interpreted as a minimum age of the Neoproterozoic sequence. The Neoproterozoic crust was tilted and subsequently early Cambrian intrusions dated at 522±2 Ma (T ovice granite), 524±3 Ma (V epadly granodiorite), 523±3 Ma (Smr ovice tonalite), 523±1 Ma (Smr ovice gabbro) and 524±0.8 Ma (Orlovice gabbro) were emplaced into transtensive shear zones.     

Evolution and provenance of Neoproterozoic basement and Lower Paleozoic siliciclastic cover of the Menderes Massif (western Taurides): Coupled U–Pb–Hf zircon isotope geochemistry

In the Menderes Massif (western Taurides) a Neoproterozoic basement comprising metasediments and intrusive granites is imbricated between Paleozoic platform sediments. U–Pb–Hf zircon analyses of Menderes rock units were performed by us using LA-ICP-MS. The U–Pb detrital zircon signal of the Neoproterozoic metasediments is largely consistent with a NE African (Gondwana) provenance. The oldest unit, a paragneiss, contains significant amounts (~ 30%) of Archean-aged zircons and εHf (t) values of about a half of its Neoproterozoic zircons are negative suggesting contribution from Pan-African terranes dominated by reworking of an old crust. In the overlying, mineralogically-immature Core schist (which is still Neoproterozoic), the majority of the detrital zircons are Neoproterozoic, portraying positive εHf (t) values indicating derivation from a proximal juvenile source, resembling the Arabian–Nubian Shield.The period of sedimentation of the analyzed metasediments, is constrained between 570 and 550 Ma (Late Ediacaran). The Core schist sediments, ~ 9 km thick, accumulated in less than 20 My implying a tectonic-controlled sedimentary basin evolved adjacent to the eroded juvenile terrane. Granites, now orthogneisses, intruded the basin fill at 550 Ma, they exhibit ± 0 εHf (t = 550 Ma) and T_DM ages of 1.4 Ga consistent with anatexis of various admixtures of juvenile Neoproterozoic and Late Archean detrital components. Granites in the northern Arabian–Nubian Shield are no younger than 580 Ma and their εHf (t) are usually more positive. This implies that the Menderes does not represent a straightforward continuation of the Arabian–Nubian Shield.The lower part of the pre-Carboniferous silisiclastic cover of the Menderes basement, comprises a yellowish quartzite whose U–Pb–Hf detrital zircon signal resembles that of far-traveled Ordovician sandstones in Jordan (including 0.9–1.1 Ga detrital zircons), supporting pre-Triassic paleorestorations placing the Tauride with Afro-Arabia. The detrital signal of the overlying carbonate-bearing quartzitic sequence indicates contribution from a different source: the majority of its detrital zircons yielded 550 Ma and ± 0 εHf (t = 550 Ma) values identical to that of the underlying granitic gneiss implying exposure of Menderes-like granites in the provenance.260–250 Ma lead-loss and partial resetting of the U–Pb system of certain zircons in both basement and cover units was detected. It is interpreted as a consequence of a Permian–Early Triassic thermal event preceding known Triassic granitoid intrusions.