Ages and Hf isotopes of detrital zircons from Paleozoic strata in the Chagan Obo Temple area,Inner Mongolia: Implications for the evolution of the Central Asian Orogenic Belt

The Central Asian Orogenic Belt (CAOB), as one of the largest accretionary orogens in the world, was built up through protracted accretion and collision of a variety of terranes due to the subduction and closure of the Paleo-Asian Ocean in the Neoproterozoic to Early Mesozoic. Located in the Uliastai continental margin of the southeastern CAOB, the Chagan Obo Temple area is essential for understanding the tectonic evolution of the southeastern part of the CAOB and its relation with the “Hegenshan Ocean”. In this study, detrital zircon U-Pb geochronology coupled with Hf isotopic analysis was performed on Paleozoic sedimentary strata in this area. Most detrital zircons from the studied samples possess oscillatory zoning and have Th/U ratios of 0.4-1.73, indicative of an igneous origin. Detrital zircons from the Ordovician to Devonian sedimentary strata yield a predominant age group at 511-490 Ma and subordinate age groups at 982-891 Ma, 834-790 Ma and ~ 574 Ma, and have a large spread of ε_Hf(t) values (-20.77 to + 16.94). Carboniferous and Early Permian samples yield zircon U-Pb ages peaking at ~ 410 Ma and ~ 336 Ma, and have dominantly positive ε_Hf(t) values (+ 1.30 to + 14.86). Such age populations and Hf isotopic signatures match those of magmatic rocks in the Northern Accretionary Orogen and the Mongolian arcs. A marked shift of provenance terranes from multiple sources to a single source and Hf isotope compositions from mixed to positive values occurred at some time in the Carboniferous. Such a shift implies that the Northern Accretionary Orogen was no longer a contributor of detritus in the Carboniferous to Early Permian, due to the opening of the “Hegenshan Ocean” possibly induced by the slab rollback of the subducting Paleo-Asian Ocean.     

The Paleozoic evolution of Central Tianshan: Geochemical and geochronological evidence

A suite of Paleozoic granitoids in Central Tianshan was studied for both geochemistry and geochronology in an effort to constrain their origin and tectonic setting. We combined LA-ICP-MS dating of zircon, standard geochemical analyses and Hf-isotopic studies of zircon to develop our tectonic model. Based on our analysis, the granitoids formed in three distinctive stages: ~ 450–400 Ma, ~ 370–350 Ma and ca. 340 Ma. The first stage (450–400 Ma) granitoids exhibit metaluminous, magnesian, high-K to shoshonitic characteristics of I-type granitoids (arc-setting), that are enriched in LREE relative to HREE with high (La/Yb)_CN values, show negative Eu anomaly and are depleted in Nb, Ta and Ti. This phase of granitoid emplacement was most likely related to the southward subduction of the Paleo-Tianshan Ocean beneath the Tarim block and the subsequent Central Tianshan arc. In contrast, the second stage granitoids (370–350 Ma) are distinctly different and are classified as calc-alkaline or shoshonitic plutons with a weak positive Eu anomaly. Within the second stage granitoids, it appears that the earlier (~ 365 Ma) granitoids fit within the A-type field whereas the younger (~ 352 Ma) granitoids plot within the post-collisional potassic field. These granitoids formed during collisions between Central Tianshan and the Tuha terrane that occurred along the northern margin of Central Tianshan. Lastly, the ca. 340 Ma granitoids are typical of volcanic arc granitoids again that probably formed during the northward subduction of the South Tianshan Ocean beneath the Central Tianshan landmass or the subsequent southward subduction of the residual Paleo-Tianshan Ocean.The Hf isotopic data of zircons from all the studied granitoids were pooled and yielded three prominent Hf T_DM^C model age populations: ca. 2400 Ma, ca. 1400 Ma and ca. 1100 Ma. The Hf-data shows a significant input of juvenile crust in addition to crustal recycling. We interpret these three phases of juvenile crustal addition to phases of global growth of continental crust (~ 2400 Ma), the addition of juvenile crust during the breakup of the Columbia supercontinent (~ 1400 Ma) and the assembly of Rodinia (~ 1100 Ma).     

Tectonic regime switchover of Triassic Western Qinling Orogen: Constraints from LA-ICP-MS zircon U–Pb geochronology and Lu–Hf isotope of Dangchuan intrusive complex in Gansu,China

The Qinling Orogenic Belt, linking the Kunlun and Qilian Mountains to the west and continuing farther east to the Dabie Mountain, was assembled by the convergence and collision between the Greater South China and the North China blocks. The precise timing of the subduction and collision processes between these continental blocks and tectonic regime switchover is very equivocal. Zircon in-situ LA-ICP-MS U–Pb dating in this contribution indicates that the biotite monzogranite and monzogranite phases of the Dangchuan complex were crystallized at ca. 239.8 ± 2.3 Ma and 227.8 ± 1.2 Ma, respectively. The ca. 240 Ma biotite monzogranite displays ε_Hf(t) values ranging from −2.4 to +2.9, and corresponding T_DM2 of 1.72–1.94 Ga and T_DM1 of 0.77–0.88 Ga. The ca. 228 Ma monzogranite exhibits ε_Hf(t) values ranging from −4.3 to +1.9, and corresponding T_DM2 of 1.73–2.08 Ga and T_DM1 of 0.81–0.88 Ga. Lutetium–Hf isotopic composition indicates that the biotite monzogranite and monzogranite probably have the same parental magmas which were originated from hybrid sources of both reworking of Paleoproterozoic ancient crust and partial melting of the Neoproterozoic juvenile crust. The more negative ε_Hf(t) values of the monzogranite suggest more contribution of the ancient crust during the source contamination, or more possible crustal assimilation during their crystallization at ca. 228 Ma than precursor biotite monzogranite. Integrated with previous research and our detailed petrography, we propose that the Dangchuan complex underwent an episodic growth documenting the tectonic regime switchover from early Paleozoic to Triassic. The ca. 439 Ma inherited zircon recorded the persistent subduction of the oceanic crust, the ca. 240 Ma biotite monzogranite emplaced during the northward subduction of the Mianlue oceanic crust beneath the South Qinling block, and the ca. 228 Ma monzogranite emplaced during the syn-collisional process in a compressional setting.     

A geotraverse across two paleo-subduction zones in Tien Shan,Tajikistan

We present first LA-ICP-MS U–Pb zircon ages as well as geochemical and Sr–Nd–Pb isotope data for 14 magmatic rocks collected along ca. 400 km profile across the Chatkal-Kurama terrane in the Mogol-Tau and Kurama ranges and the Gissar Segment of the Tien Shan orogen in Tajikistan. These new data from supra-subduction and post-collisional magmatic rocks of two Late Paleozoic active margins constrain a tectonic model for terrane motions across two paleo-subduction zones: (1) The 425 Ma old Muzbulak granite of the Mogol-Tau range formed in a supra-subduction setting at the northern margin of the Turkestan Ocean. The north-dipping plate was subducted from the Early Silurian to the earliest Middle Devonian. Thereafter the northern side of the Turkestan Ocean remained a passive margin until the Early Carboniferous. (2) In the Early Carboniferous, subduction under the northern margin of the Turkestan Ocean resumed and the 315 to 305 Ma old Kara-Kiya, Muzbek, and Karamazar intrusions formed in a supra-subduction setting in the Mogol-Tau and Kurama ranges. (3) At the same time, in the Early Carboniferous, rifting of the southern passive margin of the Turkestan Ocean formed the short-lived Gissar Basin, separated from the Turkestan Ocean by the Gissar micro-continent. North-dipping subduction in the Gissar Basin is documented by the 315 Ma Kharangon plagiogranite and the voluminous ca. 321–312 Ma Andean-type supra-subduction Gissar batholith. The Kharangon and Khanaka gabbro-plagiogranite intrusions of the southern Gissar range have geochemical and Sr–Nd isotopic compositions (⁸⁷Sr/⁸⁶Sr(t) 0.7047–0.7056, εNd of + 1.5 to + 2.3) compatible with mantle-derived origin typical for plagiogranites associated with ophiolites. The supra-subduction rocks from the Gissar batholith and from the Mogol-Tau Kurama ranges have variably mixed Sr–Nd–Pb isotopic signatures (⁸⁷Sr/⁸⁶Sr(t) 0.7057–0.7064, εNd of − 2.1 to − 5.0) typical for continental arcs where mantle-derived magmas interact with continental crust. (4) In the latest Carboniferous, the Turkestan Ocean and the Gissar Basin were closed. The Early Permian Chinorsay (288 Ma) and Dara-i-pioz (267 Ma) post-collisional intrusions, emplaced in the northern part of the Gissar micro-continent after a long period of amagmatic evolution, have intraplate geochemical affinities and isotopic Sr–Nd–Pb isotopic compositions (⁸⁷Sr/⁸⁶Sr(t) 0.7074–0.7086, εNd of − 5.5 to − 7.4) indicating derivation from Precambrian continental crust which is supported by old Nd model ages (1.5 and 1.7 Ga), and by the presence of inherited zircon grains with ages 850–500 Ma in the Chinorsay granodiorite. The post-collisional intrusions in the southern Gissar and in the Mogol-Tau and Kurama ranges (297–286 Ma), emplaced directly after supra-subduction magmatic series, have geochemical and isotopic signatures of arc-related magmas. The distinct shoshonitic affinities of post-collisional intrusions in the Mogol-Tau and Kurama ranges are explained by the interaction of hot asthenospheric material with subduction-enriched wedge of lithospheric mantle due to slab break-off at post-collisional stage. Despite origination from different tectonic environments, all magmatic rocks have relatively old Nd model ages (1.7–1.0 Ga) indicating a significant proportion of Paleoproterozoic or older crustal material in their sources and their model ages are similar to those of post-collisional intrusions from the Alai and Kokshaal Segments of the South Tien Shan.     

Where was the Ailaoshan Ocean and when did it open: A perspective based on detrital zircon U–Pb age and Hf isotope evidence

The Indochina–Simao and Yangtze blocks were separated by a branch of the Paleo-Tethys Ocean, commonly referred as the Ailaoshan Ocean in the Paleozoic. Remnants of this Ailaoshan Ocean have been variably suggested to locate along (from east to west) the Ailaoshan fault, Jiujia–Anding fault and Amojiang–Lixianjiang fault. In order to test these models, we have carried out comprehensive detrital zircon U–Pb dating and Hf isotope analyses on the Cambrian to Devonian sedimentary units in the Ailaoshan Belt and its adjacent western margin of the Yangtze Block. Our results indicate marked detrital zircon provenance variation on different sides of the Ailaoshan–Tengtiaohe fault: detrital zircons from east of the fault display a diagnostic age peak at 730–900 Ma, which is characterized by both positive and negative εHf(t) values with a Hf model age (T_DM^C) peak at ~ 1.8 Ga, whereas detrital zircons from west of the fault display two major age populations of 400–500 and 900–1000 Ma, both characterized by mainly negative εHf(t) values with a Hf model age (T_DM^C) peak at ~ 2.1 Ga. Our new data indicate that detritus from east and west of the Ailaoshan–Tengtiaohe fault may have been mainly derived from, respectively, the Yangtze Block and Indochina–Simao blocks, thus suggesting the fault may represent the actual suture between the two blocks. Our study also reveals that the Ailaoshan Ocean may have started its early continental rift in the Early Silurian.     

Tectono-magmatic evolution of the Gaoligong belt,southeastern margin of the Tibetan plateau: Constraints from granitic gneisses and granitoid intrusions

The Gaoligong belt is located in the southeastern margin of the Tibetan plateau, and is bound by the Tengchong and Baoshan blocks. This paper presents new data from zircon geochronology, geochemistry, and whole-rock Sr–Nd–Pb–Hf isotopes to evaluate the tectonic evolution of the Gaoligong belt. The major rock types analysed in the present study are granitic gneiss, granodiorite, and granite. They are metaluminous to peraluminous and belong to high-K, calc-alkaline series. Laser ablation inductively coupled plasma mass spectrometry (LA–ICP–MS) analyses of zircons from nine granitic rocks yielded crystallization ages of 495–487 Ma, 121 Ma, 89 Ma, and 70–63 Ma. The granitoids can be subdivided into the following four groups. (1) Early Paleozoic granitic gneisses with high ε_Nd(t) and ε_Hf(t) values of − 1.06 to − 3.45 and − 1.16 to 2.09, and model ages of 1.16 Ga to 1.33 Ga and 1.47 Ga to 1.63 Ga, respectively. Their variable ⁸⁷Sr/⁸⁶Sr and Pb values resemble the characteristics of the Early Paleozoic Pinghe granite in the Baoshan block. Our data suggest that the rocks were derived from the break-off of the Proto-Tethyan oceanic slab between the outboard continent and the Baoshan block, which induced the partial melting of Mesoproterozoic pelitic sources mixed with depleted mantle materials. (2) Early Cretaceous granodiorites with low ε_Nd(t) and ε_Hf(t) values of − 8.92 and − 4.91 with Nd and Hf model ages of 1.41 Ga and 1.49 Ga, respectively. These rocks have high initial ⁸⁷Sr/⁸⁶Sr (0.711992) and lower crustal Pb values, suggesting that they were derived from Mesoproterozoic amphibolites with tholeiitic signature, leaving behind granulite residue at the lower crust. (3) Early Late Cretaceous granites with low ε_Nd(t) and ε_Hf(t) values of − 9.58 and − 4.61 with Nd and Hf model ages of 1.43 Ga and 1.57 Ga, respectively. These rocks have high initial ⁸⁷Sr/⁸⁶Sr (0.713045) and lower crustal Pb isotopic values. These rocks were generated from the partial melting of Mesoproterozoic metapelitic sources resulting from the delamination of thickened lithosphere, following the closure of the Bangong–Nujiang Ocean and collision of the Lhasa–Qiangtang blocks. (4) Late Cretaceous to Paleogene granitic gneisses with low ε_Nd(t) and ε_Hf(t) values of − 4.41 to − 10 and − 5.95 to − 8.71, Nd model ages ranging from 1.08 Ga to 1.43 Ga, and Hf model ages from 1.53 Ga to 1.67 Ga, respectively. These rocks show high initial ⁸⁷Sr/⁸⁶Sr (0.713201 and 714662) and lower crustal Pb values. The data suggest that these rocks are likely related to the eastward subduction of the Neo-Tethyan Oceanic slab, which induced partial melting of Mesoproterozoic lower crustal metagreywacke. The results presented in this study from the Gaoligong belt offer important insights on the evolution of the Proto-Tethyan, Bangong–Nujiang, and Neo-Tethyan oceans in the southeastern margin of the Tibetan Plateau.     

Coupled U–Pb–Hf of detrital zircons of Cambrian sandstones from Morocco and Sardinia: Implications for provenance and Precambrian crustal evolution of North Africa

U–Pb–Hf of detrital zircons from diverse Cambrian units in Morocco and Sardinia were investigated in order to clarify the sandstone provenance and how it evolved with time, to assess whether the detrital spectra mirror basement crustal composition and whether they are a reliable pointer on the ancestry of peri-Gondwanan terranes. Coupled with Hf isotopes, the detrital age spectra allow a unique perspective on crustal growth and recycling in North Africa, much of which is concealed below Phanerozoic sediments.In Morocco, the detrital signal of Lower Cambrian arkose records local crustal evolution dominated by Ediacaran (0.54–0.63 Ga) and Late-Paleoproterozoic (1.9–2.2 Ga; Eburnian) igneous activity. A preponderance of the Neoproterozoic detrital zircons possess positive ε_Hf(t) values and their respective Hf model ages (T_DM) concentrate at 1.15 Ga. In contrast, rather than by Ediacaran, the Neoproterozoic detrital signal from the Moroccan Middle Cambrian quartz-rich sandstone is dominated by Cryogenian-aged detrital zircons peaking at 0.65 Ga alongside a noteworthy early Tonian (0.95 Ga) peak; a few Stenian-age (1.0–1.1 Ga) detrital zircons are also distinguished. The majority of the Neoproterozoic zircons displays negative ε_Hf(t), indicating the provenance migrated onto distal Pan-African terranes dominated by crustal reworking. Terranes such as the Tuareg Shield were a likely provenance. The detrital signal of quartz–arenites from the Lower and Middle Cambrian of SW Sardinia resembles the Moroccan Middle Cambrian, but 1.0–1.1 Ga as well as ~ 2.5 Ga detrital zircons are more common. Therefore, Cambrian Sardinia may have been fed from different sources possibly located farther to the east along the north Gondwana margin. 1.0–1.1 Ga detrital zircons abundant in Sardinia generally display negative ε_Hf(t) values while 0.99–0.95 Ga detrital zircons (abundant in Morocco) possess positive ε_Hf(t), attesting for two petrologically-different Grenvillian sources. A paucity of detrital zircons younger than 0.6 Ga is a remarkable feature of the detrital spectra of the Moroccan and Sardinian quartz-rich sandstones. It indicates that late Cadomian orogens fringing the northern margin of North Africa were low-lying by the time the Cambrian platform was deposited. About a quarter of the Neoproterozoic-aged detrital zircons in the quartz-rich sandstones of Morocco (and a double proportion in Sardinia) display positive ε_Hf(t) values indicating considerable juvenile crust addition in North Africa, likely via island arc magmatism. A substantial fraction of the remaining Neoproterozoic zircons which possess negative ε_Hf(t) values bears evidence for mixing of old crust with juvenile magmas, implying crustal growth in an Andean-type setting was also significant in this region.     

Evolution and provenance of Neoproterozoic basement and Lower Paleozoic siliciclastic cover of the Menderes Massif (western Taurides): Coupled U–Pb–Hf zircon isotope geochemistry

In the Menderes Massif (western Taurides) a Neoproterozoic basement comprising metasediments and intrusive granites is imbricated between Paleozoic platform sediments. U–Pb–Hf zircon analyses of Menderes rock units were performed by us using LA-ICP-MS. The U–Pb detrital zircon signal of the Neoproterozoic metasediments is largely consistent with a NE African (Gondwana) provenance. The oldest unit, a paragneiss, contains significant amounts (~ 30%) of Archean-aged zircons and εHf (t) values of about a half of its Neoproterozoic zircons are negative suggesting contribution from Pan-African terranes dominated by reworking of an old crust. In the overlying, mineralogically-immature Core schist (which is still Neoproterozoic), the majority of the detrital zircons are Neoproterozoic, portraying positive εHf (t) values indicating derivation from a proximal juvenile source, resembling the Arabian–Nubian Shield.The period of sedimentation of the analyzed metasediments, is constrained between 570 and 550 Ma (Late Ediacaran). The Core schist sediments, ~ 9 km thick, accumulated in less than 20 My implying a tectonic-controlled sedimentary basin evolved adjacent to the eroded juvenile terrane. Granites, now orthogneisses, intruded the basin fill at 550 Ma, they exhibit ± 0 εHf (t = 550 Ma) and T_DM ages of 1.4 Ga consistent with anatexis of various admixtures of juvenile Neoproterozoic and Late Archean detrital components. Granites in the northern Arabian–Nubian Shield are no younger than 580 Ma and their εHf (t) are usually more positive. This implies that the Menderes does not represent a straightforward continuation of the Arabian–Nubian Shield.The lower part of the pre-Carboniferous silisiclastic cover of the Menderes basement, comprises a yellowish quartzite whose U–Pb–Hf detrital zircon signal resembles that of far-traveled Ordovician sandstones in Jordan (including 0.9–1.1 Ga detrital zircons), supporting pre-Triassic paleorestorations placing the Tauride with Afro-Arabia. The detrital signal of the overlying carbonate-bearing quartzitic sequence indicates contribution from a different source: the majority of its detrital zircons yielded 550 Ma and ± 0 εHf (t = 550 Ma) values identical to that of the underlying granitic gneiss implying exposure of Menderes-like granites in the provenance.260–250 Ma lead-loss and partial resetting of the U–Pb system of certain zircons in both basement and cover units was detected. It is interpreted as a consequence of a Permian–Early Triassic thermal event preceding known Triassic granitoid intrusions.     

Late Devonian OIB alkaline gabbro in the Yarlung Zangbo Suture Zone: Remnants of the Paleo-Tethys?

The Yarlung Zangbo Suture Zone (YZSZ) is believed to be composed of material largely derived from the destruction of the Neo-Tethys that occurred from early Mesozoic to early Cenozoic. We report here geochronological and petrological data obtained for newly discovered alkaline gabbro blocks embedded in a mélange zone of the western YZSZ. Single zircon U–Pb analyses from one representative gabbro sample by SIMS (Secondary Ion Mass Spectrometry) yielded a combined crystallization age of about 363.7 ± 1.7 Ma (1σ). In situ Hf isotopic analyses yielded ε_Hf(t) values of + 2.6 to + 5.5, suggesting an enriched mantle source. All of the gabbro samples show typical Ocean Island Basalt (OIB) affinity with little or no continental crust contamination. They also display strong geochemical similarities with the Hawaii basalts and the Xigaze seamount basalts suggestive of their intra-oceanic setting. These observations, in combination with the Early Carboniferous layered gabbros reported at Luobusa, indicate that these rocks could represent remnants of the Paleo-Tethys. We propose that a branch ocean separating the Western Qiangtang terrane and the Lhasa terrane from the Gondwana continent might have been present during the Late Devonian and the Early Carboniferous, providing new constrains on the configuration of Paleo-Tethys in Tibetan Plateau during early Late Paleozoic.     

Detrital zircons from Neoproterozoic sedimentary rocks in the Yili Block: Constraints on the affinity of microcontinents in the southern Central Asian Orogenic Belt

The Yili Block is one of the Precambrian microcontinents dispersed in the Central Asian Orogenic Belt (CAOB). Detrital zircon U–Pb ages and Hf isotopic data of Neoproterozoic meta-sedimentary rocks (the Wenquan Group) are presented to constrain the tectonic affinity and early history of the Yili Block. The dating of detrital zircons indicates that both the lower and upper Wenquan Groups have two major populations with ages at 950–880 Ma and 1600–1370 Ma. Moreover, the upper Wenquan Group has two minor populations at ~ 1100 Ma and 1850–1720 Ma. According to the youngest age peaks of meta-sedimentary rocks and the ages of related granitoids, the lower Wenquan Group is considered to have been deposited during the early Neoproterozoic (900–845 Ma), whereas the upper Wenquan Group was deposited at 880–857 Ma. The zircon ε_Hf (t) values suggest that the 1.85–1.72 Ga source rocks for the upper Wenquan Group were dominated by juvenile crustal material, whereas those for the lower Wenquan Group involved more ancient crustal material. For the 1.60–1.37 Ga source rocks, however, juvenile material was a significant input into both the upper and lower Wenquan Groups. Therefore, two synchronous crustal growth and reworking events were identified in the northern Yili Block at ca. 1.8–1.7 Ga and 1.6–1.3 Ga, respectively. After the last growth and reworking event, continuous crustal reworking took place in the northern Yili Block until the early Neoproterozoic. Comparing the age patterns and Hf isotopic compositions of detrital zircons from the Yili Block and the surrounding tectonic units indicates that the Yili Block has a close tectonic affinity to the Chinese Central Tianshan Block in the Precambrian. The Precambrian crustal evolution of the Yili Block is distinct from that of the Siberian, North China and Tarim Cratons. Such difference therefore suggests that the Yili Block and the Chinese Central Tianshan Block may have been united in an isolated Precambrian microcontinent within the CAOB rather than representing two different blocks rifted from old cratons on both sides of the Paleo-Asian Ocean.     

The building of an Archean microcontinent: Evidence from the North China Craton

Continents on the early earth are considered to have been built through the accretion of microterranes, oceanic arcs and plateaus. The North China Craton (NCC), envisaged in recent models as a collage of several microblocks which were amalgamated along multiple zones of ocean closure during the late Neoarchean, provide a typical case to investigate the origin and amalgamation of microcontinents through convergent margin processes. Here we report a suite of magmatic rocks developed at the periphery of one of these microblocks, the Jiaoliao Block, that forms part of the composite Eastern Block of the NCC. We integrate our new data with those from various parts of this microblock to elucidate the mechanism of continent building in the Archean. We present petrological, geochemical and zircon U–Pb geochronological and Lu-Hf isotopic data from the magmatic suite that belongs to the Yishui Complex. Geochemically, the felsic units of the suite straddle from monzonite through granodiorite to granite with dominantly metaluminous affinity, magnesian composition and arc-related features. The metagranites, TTG gneisses and charnockites are characterized by negative Nb-Ta anomalies and positive K and Pb anomalies. The diorites and gabbros display negative anomalies of Th-U, Nb-Ta and Zr-Hf and positive anomalies at Ba, Pb and Sm with negative Eu anomalies and minor positive Ce anomalies, attesting to arc-related features. In the tectonic discrimination diagrams, the rocks plot in the volcanic arc field, indicating arc-related origin in subduction setting.Zircon grains from all the rocks display core–rim texture with the cores showing magmatic crystallization and the narrow structureless rims corresponding to metamorphic overgrowth. The magmatic zircons from the metagranites show upper intercept ages or ²⁰⁷Pb/²⁰⁶Pb weighted mean ages of 2505 ± 29 Ma and 2569 ± 20 Ma to 2513 ± 27 Ma, those from the TTG gneisses show 2535 ± 17 Ma to 2546 ± 39 Ma, from charnockites display 2543 ± 20 Ma–2555 ± 15 Ma, and diorite and gabbro show 2587 ± 15 Ma and 2516 ± 13 Ma respectively. The zircon rim ages of 2472 ± 23 Ma, 2457 ± 35 Ma, 2545 ± 30 Ma and 2511 ± 35 Ma suggest the timing of metamorphism (ca. 2.55–2.45 Ga). Magmatic zircons with slightly older ages of ca. 2.73 Ga, 2.64 Ga also occur suggesting multiple magmatic pulses. The Lu-Hf isotopic data show positive εHf(t) values ranging from 0.2 to 5.7 for metagranites, with Hf model ages of 2602–2815 Ma (T_DM) and 2658–3002 Ma (T_DM^C), whereas for TTG gneisses, the positive εHf(t) values are up to 6.5 and display dominant Mesoarchean Hf model ages with limited early Neoarchean Hf model ages. Charnockite samples show positive εHf(t) values 2.3–5.7 and display the Hf model ages ranging from 2601 Ma to 2772 Ma (T_DM) and 2658 Ma to 2904 Ma (T_DM^C). Diorite and gabbro also show positive εHf(t) (2.3–6.9) and yield Hf model ages of 2625–2788 Ma (T_DM) and 2647 Ma to 2903 Ma (T_DM^C). The Hf isotopic data indicate that the magmas were derived from Neoarchean-Mesoarchean juvenile sources.Integrating our data with those from the entire Jiaoliao microblock reveals vestiges of Hadean crust involved in building the Eoarchean nucleus of this microblock. Vigorous convergent margin processes ranging from Mesoarchean to late Neoarchean with multiple pules of arc magmatism associated with subduction tectonics led to further growth of continental crust, culminating in paired high temperature and high pressure metamorphism during late Neoarchean – early Paleoproterozoic transition.     

Late Paleozoic provenance shift in the south-central North China Craton: Implications for tectonic evolution and crustal growth

U–Pb geochronologic and Hf isotopic results of seven sandstones collected from Late Carboniferous through Early Triassic strata of the south-central part of the North China Craton record a dramatic provenance shift near the end of the Late Carboniferous. Detrital zircons from the Late Carboniferous sandstones are dominated by the Early Paleozoic components with positive ε_Hf(t) values, implying the existence of a significant volume of juvenile crust at this age in the source regions. Moreover, there are also three minor peaks at ca. 2.5 Ga, 1.87 Ga and 1.1–0.9 Ga. Based on our new data, in conjunction with existing zircon ages and Hf isotopic data in the North China Craton (NCC), Central China Orogenic Belt (CCOB) and Central Asian Orogenic Belt (CAOB), it can be concluded that Early Paleozoic and Neoproterozoic detritus in the south-central NCC were derived from the CCOB. Zircons with ages of 1.9–1.7 Ga were derived from the NCC. However, the oldest components can't be distinguished, possibly from either the NCC or the CCOB, or both. In contrast, detrital zircons from the Permian and Triassic sandstones are characterized by three major groups of U–Pb ages (2.6–2.4 Ga, 1.9–1.7 Ga and Late Paleozoic ages). Specially, most of the Late Paleozoic zircons show negative ε_Hf(t) values, similar to the igneous zircons from intrusive rocks of the Inner Mongolia Paleo-Uplift (IMPU), indicating that the Late Paleozoic detritus were derived from the northern part of the NCC. This provenance shift could be approximately constrained at the end of the Late Carboniferous and probably hints that tectonic uplift firstly occurred between the CCOB and the NCC as a result of the collision between the South and North Qinling microcontinental terranes, and then switched to the domain between the CAOB and the NCC. Additionally, on the basis of Lu–Hf isotopic data, we reveal the pre-Triassic crustal growth history for the NCC. In comparison among the three crustal growth curves obtained from modern river sands, our samples, and the Proterozoic sedimentary rocks, we realize that old components are apparently underestimated by zircons from the younger sedimentary rocks and modern river sands. Hence, cautions should be taken when using this method to investigate growth history of continental crust.     

Age and composition of Antarctic sub-glacial bedrock reflected by detrital zircons,erratics, and recycled microfossils in the Ellsworth Land–Antarctic Peninsula–Weddell Sea–Dronning Maud Land sector (240°E–0°–015°E)

The age and composition of the 14 × 10⁶ km² of Antarctica's surface obscured by ice is unknown except for some dated detrital minerals and erratics. In remedy, we present four new analyses (U–Pb age, T_DM^C, εHf, and rock type) of detrital zircons from Neogene turbidites as proxies of Antarctic bedrock, and review published proxies: detrital hornblendes analysed for Ar–Ar age and bulk Sm–Nd isotopes; Pb isotope compositions of detrital K-feldspars; erratics and dropstones that reflect age and composition; and recycled microfossils that reflect age and facies. This work deals with the 240°E–0°–015°E sector, and complements Veevers and Saeed's (2011) analysis of the 70°E–240°E sector. Each sample is located in its ice-drainage basin for backtracking to the potential provenance. Gaps in age between sample and upslope exposure are specifically attributable to the provenance. The major provenance of detritus west of the Antarctic Peninsula (AP) is West Antarctica, and of detritus east of the AP East Antarctica. We confirm that the Central Antarctic provenance about a core of the Gamburtsev Subglacial Mountains (GSM) and the Vostok Subglacial Highlands (VSH) contains a basement that includes igneous (mafic granitoids) and metamorphic rocks with peak U–Pb ages of 0.65–0.50, 1.20–0.9, 2.1–1.9, 2.8–2.6, and 3.35–3.30 Ga, T_DM^C of 3.6–1.3 Ga, and mainly negative εHf. The potential provenance of zircons of 650–500 Ma age with T_DM^C ages of 1.55 Ga, and of zircons of 1200–900 Ma age with positive εHf lies beneath the ice in East Antarctica south and southeast of Dronning Maud Land within the Antarctic part of the East African–Antarctic Orogen. Zircons with the additional ages of 1.7–1.4 Ga, 2.1–1.9 Ga, and 3.35–3.00 Ga have a potential provenance in the GSM.     

Tectono-magmatic evolution of Late Jurassic to Early Cretaceous granitoids in the west central Lhasa subterrane,Tibet

There is ongoing debate as to the subduction direction of the Bangong–Nujiang Ocean during the Mesozoic (northward, southward or bidirectional subduction). Arc-related intermediate to felsic intrusions could mark the location of the subduction zone and, more importantly, elucidate the dominant geodynamic processes. We report whole rock geochemical and zircon U–Pb and Hf isotopic data for granitoids from the west central Lhasa subterrane (E80° to E86°). All rocks show metaluminous to peraluminous, calc-alkaline signatures, with strong depletion of Nb, Ta and Ti, enrichment of large ion lithophile elements (e.g., Cs, Rb, K), a negative correlation between SiO₂ and P₂O₅, and a positive correlation between Rb and Th. All these features are indicative of I-type arc magmatism. New zircon U–Pb results, together with data from the literature, indicate continuous magmatism from the Late Jurassic to the Early Cretaceous (160 to 130 Ma). Zircon U–Pb ages for samples from the northern part of the west central Lhasa subterrane (E80° to E82°30′) yielded formation ages of 165 to 150 Ma, whereas ages of 142 to 130 Ma were obtained on samples from the south. This suggests flat or low-angle subduction of the Bangong–Nujiang Ocean, consistent with a slight southward decrease in zircon εHf(t) values for Late Jurassic rocks. Considering the crustal shortening, the distance from the Bangong–Nujiang suture zone, and a typical subduction zone melting depth of ~ 100 km, the subduction angle was less than 14° for Late Jurassic magmatism in the central Lhasa interior, consistent with flat or low-angle subduction. Compared with Late Jurassic rocks (main εHf(t) values of − 16 to − 7), Early Cretaceous rocks (145 to 130 Ma) show markedly higher εHf(t) values (mainly − 8 to 0), possibly indicating slab roll-back, likely caused by slab foundering or break-off. Combined with previously published works on arc magmatism in the central Lhasa and west part of the southern Qiangtang subterranes, our results support the bidirectional subduction of the Bangong–Nujiang Ocean along the Bangong–Nujiang Suture Zone, and indicates flat or low-angle southward subduction (165 to 145 Ma) followed by slab roll-back (145 to 130 Ma).     

Zircon U–Pb age,Hf isotopic compositions and geochemistry of the Silurian Fengdingshan I-type granite Pluton and Taoyuan mafic–felsic Complex at the southeastern margin of the Yangtze Block

This work presents an integrated study of zircon U–Pb ages and Hf isotope along with whole-rock geochemistry on Silurian Fengdingshan I-type granites and Taoyuan mafic–felsic intrusive Complex located at the southeastern margin of the Yangtze Block, filling in a gap in understanding of Paleozoic I-type granites and mafic-intermediate igneous rocks in the eastern South China Craton (SCC). The Fengdingshan granite and Taoyuan hornblende gabbro are dated at 436 ± 5 Ma and 409 ± 2 Ma, respectively. The Fengdingshan granites display characteristics of calc-alkaline I-type granite with high initial ⁸⁷Sr/⁸⁶Sr ratios of 0.7093–0.7127, low εNd(t) values ranging from −5.6 to −5.4 and corresponding Nd model ages (T_2DM) of 1.6 Ga. Their zircon grains have εHf(t) values ranging from −2.7 to 2.6 and model ages of 951–1164 Ma. The Taoyuan mafic rocks exhibit typical arc-like geochemistry, with enrichment in Rb, Th, U and Pb and depletion in Nb, Ta. They have initial ⁸⁷Sr/⁸⁶Sr ratios of 0.7053–0.7058, εNd(t) values of 0.2–1.6 and corresponding T_2DM of 1.0–1.1 Ga. Their zircon grains have εHf(t) values ranging from 3.2 to 6.1 and model ages of 774–911 Ma. Diorite and granodiorite from the Taoyuan Complex have initial ⁸⁷Sr/⁸⁶Sr ratios of 0.7065–0.7117, εNd(t) values from −5.7 to −1.9 and Nd model ages of 1.3–1.6 Ga. The petrographic and geochemical characteristics indicate that the Fengdingshan granites probably formed by reworking of Neoproterozoic basalts with very little of juvenile mantle-derived magma. The Taoyuan Complex formed by magma mixing and mingling, in which the mafic member originated from a metasomatized lithospheric mantle. Both the Fengdingshan and Taoyuan Plutons formed in a post-orogenic collapse stage in an intracontinental tectonic regime. Besides the Paleozoic Fengdingshan granites and Taoyuan hornblende gabbro, other Neoproterozoic and Indosinian igneous rocks located along the southeastern and western margin of the Yangtze Block also exhibit decoupled Nd–Hf isotopic systemics, which may be a fingerprint of a previous late Mesoproterozoic to early Neoproterozoic oceanic subduction.     

Zircon U–Pb age and Hf isotopic compositions of Mesozoic granitoids in southern Qiangtang,Tibet: Implications for the subduction of the Bangong–Nujiang Tethyan Ocean

The southern Qiangtang magmatic belt was formed by the north-dipping subduction of the Bangong–Nujiang Tethyan Ocean during Mesozoic. To better understand the petrogenesis, time–space distribution along the length of this belt, 21 samples of several granitoid bodies, from west to east, in the Bangong Co, Gaize, Dongqiao and Amdo areas were selected for in-situ zircon U–Pb dating, Hf isotopic and whole-rock chemical analyses. The results suggest a prolonged period of magmatic activity (185–84 Ma) with two major stages during the Jurassic (185–150 Ma) and the Early Cretaceous (126–100 Ma). Both the Jurassic and Cretaceous granitoids are high-K calc-alkaline I-type rocks, except the Cretaceous two-mica granite from Amdo in the east, which belongs to S-type. The granitoids are generated from different source materials as indicated by zircon Hf isotopic compositions. The Bangong Co and Dongqiao granitoids show high zircon ε_Hf(t) values of − 1.3–13.6 with younger T_DM^C ages of 293–1263 Ma, suggesting a relatively juvenile source; whereas the Gaize and Amdo granitoids have low ε_Hf(t) values of − 16.1–2.9 with older T_DM^C ages of 999–2024 Ma, indicating an old crustal contribution. These source rocks melt at different P–T conditions as suggested by Sr/Y ratio and T_Zr. The Sr/Y ratio of both stage granitoids increases with decreasing age. However, the T_Zr of the Jurassic granitoids decreases, whereas the T_Zr of the Cretaceous granitoids increases with decreasing age. The contrasting geochemical signatures of these granitoids may be controlled by the varying contribution of slab-derived fluids involved in the generation of the Jurassic and Cretaceous granitic magmas; i.e. increasing amount of fluids in the Jurassic, whereas decreasing amount of fluids in the Cretaceous. Therefore, it is proposed that the Jurassic and Cretaceous magmatism may be related to subduction and closure of the Bangong–Nujiang Tethyan Ocean, respectively. The age pattern of the Jurassic and Cretaceous granitoids suggests an oblique subduction of the Bangong–Nujiang Tethyan Ocean and a diachronous collision between the Lhasa and Qiangtang blocks.     

Zircon ages and Hf isotopic constraints on sources of clastic metasediments of the Slyudyansky high-grade complex,southeastern Siberia: Implication for continental growth and evolution of the Central Asian Orogenic Belt

We present results of combined in situ U–Pb dating of detrital zircons and zircon Hf and whole-rock Nd isotopic compositions for high-grade clastic metasedimentary rocks of the Slyudyansky Complex in eastern Siberia. This complex is located southwest of Lake Baikal and is part of an early Paleozoic metamorphic terrane in the eastern part of the Central Asian Orogenic Belt (CAOB). Our new zircon ages and Hf isotopic data as well as whole-rock Nd isotopic compositions provide important constraints on the time of deposition and provenance of early Paleozoic high-grade metasedimentary rocks as well as models of crustal growth in Central Asia. Ages of 0.49–0.90 Ga for detrital zircons from early Paleozoic high-grade clastic sediments indicate that deposition occurred in the late Neoproterozoic and early Paleozoic, between ca. 0.62–0.69 and 0.49–0.54 Ga. Hf isotopic data of 0.82–0.69 Ga zircons suggest Archean and Paleoproterozoic (ca. 2.7–2.8 and 2.2–2.3 Ga; Hfc = 2.5–3.9 Ga) sources that were affected by juvenile 0.69–0.82 Ga Neoproterozoic magmatism. An additional protolith was also identified. Its zircons yielded ages of 2.6–2.7 Ga, and showed high positive ε_Hf(t) values of +4.1 to +8.0, and Hf model ages t_Hf(DM) = t_Hfc = 2.6–2.8 Ga, which is nearly identical to the crystallization ages. These isotopic characteristics suggest that the protolith was quite juvenile. The whole-rock Nd isotopic data indicate that at least part of the Slyudyansky Complex metasediments was derived from “non-Siberian” provenances. The crustal development in the eastern CAOB was characterized by reworking of the early Precambrian continental crust in the early Neoproterozoic and the late Neoproterozoic–early Paleozoic juvenile crust formation.     

Zircon Hf–isotopic mapping for understanding crustal architecture and metallogenesis in the Eastern Qinling Orogen

The Eastern Qinling Orogen (EQO) is a major composite collisional zone located between the North China and the Yangtze cratons. This contribution combines geological and Hf–isotopic data from magmatic rocks associated with mineralization to gain insights into links between the crust architecture and metallogeny, and to focus exploration in the orogen.The new zircon U–Pb dates reported in this study are 434 ± 2 Ma for diorite, 433 ± 2 and 436 ± 2 Ma for monzogranite, and 454 ± 2 Ma for granodiorite in the Nanzhao area; 225 ± 2 Ma for syenite and 160 ± 1 Ma for monzogranite at Songxian; and 108 ± 1 and 102 ± 1 Ma for syenogranite in eastern Fangcheng. Combining our data with those from the entire EQO reveals seven major magmatic events since the Cambrian. These magmatic events took place during the Cambrian–Silurian associated with subduction, Early Devonian magmatism related to a collisional event, Early Permian to Late Triassic magmatism related to subduction, Late Triassic collisional magmatism, Late Triassic to Early Jurassic post–collision magmatism, and Jurassic–Cretaceous magmatism during intra–continental subduction.Lu-Hf isotopic data collected from granitic rocks for this study give εHf(t) values of: − 1.4 to 10.9 for diorite and monzogranite at Nanzhao; − 27.1 to − 15.6 for syenite and − 27.5 to − 25.1 for monzogranite at Songxian; and − 12.9 to − 3.4 for syenogranite in the eastern Fangcheng. Combining Hf isotopic data for the EQO from previous studies, we have evaluated the spatio–temporal distribution of Hf isotopic compositions. The resultant Hf isotopic maps highlight the location of the Kuanping Suture as an important tectonic boundary between the North China and the Yangtze cratons, which separates the EQO into a north part with an old and reworked lower crust and a southern part representing a juvenile lower crust.The Hf isotopic mapping of the EQO also provides information on the distribution of mineral deposits. Porphyry and porphyry–skarn Mo(–W) deposits are associated with magmatic rocks were emplaced in zones with low–εHf and high T_DM^c values representing old and reworked crustal components. In contrast, porphyry and porphyry–skarn Cu(–Mo) deposits are associated with magmatic rocks emplaced in domains with variable εHf and T_DM^c values characterized by dominantly reworked old crustal components with minor juvenile material. The magmatic source for the intrusions is characterized by low–εHf and high T_DM^c values, which are granite–related Mo or Pb–Zn–Ag mineralization.     

Zircon geochemistry of two contrasting types of eclogite: Implications for the tectonic evolution of the North Qaidam UHPM belt,northern Tibet

Compared to the extensively documented ultrahigh-pressure metamorphism at North Qaidam, the pre-metamorphic history for both continental crust and oceanic crust is poorly constrained. Trace element compositions, U–Pb ages, O and Lu–Hf isotopes obtained for distinct zircon domains from eclogites metamorphosed from both continental and oceanic mafic rocks are linked to unravel the origin and multi-stage magmatic/metamorphic evolution of eclogites from the North Qaidam ultrahigh-pressure metamorphic (UHPM) belt, northern Tibet.For continental crust-derived eclogite, magmatic zircon cores from two samples with U–Pb ages of 875–856 Ma have both very high δ¹⁸O (10.6 ± 0.5‰) and mantle-like δ¹⁸O (averaging at 5.2 ± 0.7‰), high Th/U and ¹⁷⁶Lu/¹⁷⁷Hf ratios, and steep MREE-HREE distribution patterns (chondrite-normalized) with negative Eu anomalies. Combined with positive ε_Hf (t) of 3.9–14.3 and T_DM (1.2–0.8 Ga and 1.3–1.0 Ga, respectively), they are interpreted as being crystallized from either subduction-related mantle wedge or recycled material in the mantle. While the metamorphic rims from the eclogites have U–Pb ages of 436–431 Ma, varying (inherited, lower, and elevated) oxygen isotopes compared with cores, low Th/U and ¹⁷⁶Lu/¹⁷⁷Hf ratios, and flat HREE distribution patterns with no Eu anomalies. These reflect both solid-state recrystallization from the inherited zircon and precipitation from external fluids at metamorphic temperatures of 595–622 °C (T_Ti-in-zircon).For oceanic crust-derived eclogite, the magmatic cores (510 ± 19 Ma) and metamorphic rims (442.0 ± 3.7 Ma) also show distinction for Th/U and ¹⁷⁶Lu/¹⁷⁷Hf ratios, and the REE patterns and Eu anomalies. Combined with the mantle-like δ¹⁸O signature of 5.1 ± 0.3 ‰ and two groups of model age (younger T_DM close to the apparent ages and older > 700 Ma), two possible pools, juvenile and inherited, were involved in mixing of mantle-derived magma with crustal components. The relatively high δ¹⁸O of 6.6 ± 0.3‰ for metamorphic zircon rims suggests either the protolith underwent hydrothermal alteration prior to the ~ 440 Ma oceanic crust subduction, or external higher δ¹⁸O fluid activities during UHP metamorphism at ~ 440 Ma.Therefore, the North Qaidam UHPM belt witnesses multiple tectonic evolution from Late Mesoproterozoic–Neoproterozoic assembly/breakup of the Rodinia supercontinent with related magmatic emplacement, then Paleozoic oceanic subduction, and finally transition of continental subduction/collision related to UHP metamorphism.     

Mesoproterozoic (Grenville-age) terranes in the Kyrgyz North Tianshan: Zircon ages and Nd–Hf isotopic constraints on the origin and evolution of basement blocks in the southern Central Asian Orogen

The North Tianshan orogenic belt in Kyrgyzstan consists predominantly of Neoproterozoic to early Paleozoic assemblages and tectonically interlayered older Precambrian crystalline complexes and formed during early Paleozoic accretionary and collisional events. One of the oldest continental fragments of late Mesoproterozoic (Grenvillian) age occurs within the southern part of the Kyrgyz North Tianshan. Using SHRIMP zircon ages, we document two magmatic events at ~ 1.1 and ~ 1.3 Ga. The younger event is characterized by voluminous granitoid magmatism between 1150 and 1050 Ma and is associated with deformation and metamorphism. The older event is documented by ~ 1.3 Ga felsic volcanism of uncertain tectonic significance and may reflect a rifting episode. Geochemical signatures as well as Nd and Hf isotopes of the Mesoproterozoic granitoids indicate melting of still older continental crust with model ages of ca 1.2 to 2.4 Ga.The Mesoproterozoic assemblages are intruded by Paleozoic diorites and granitoids, and Nd and Hf isotopic systematics suggest that the diorites are derived from melts that are mixtures of the above Mesoproterozoic basement and mantle-derived material; their source is thus distinct from that of the Mesoproterozoic rocks. Emplacement of these plutons into the Precambrian rocks occurred between 461 and 441 Ma. This is much younger than previously assumed and indicates that small plutons and large batholiths in North Tianshan were emplaced virtually synchronously in the late Ordovician to early Silurian.The Mesoproterozoic rocks in the North Tianshan may be remnants of a once larger continental domain, whose fragments are preserved in adjacent blocks of the Central Asian Orogenic Belt. Comparison with broadly coeval terranes in the Kokchetav area of northern Kazakhstan, the Chinese Central Tianshan and the Tarim craton point to some similarities and suggests that these may represent fragments of a single Mesoproterozoic continent characterized by a major orogenic event at ~ 1.1 Ga, known as the Tarimian orogeny.