闽江下游湿地植物硅素空间分布特征及其影响因素

为研究闽江下游沿岸湿地植物硅素的分布特征及其影响因素,以闽江下游沿线湿地为研究对象,于2019年10月设置6个采样点,对植物生物硅含量及储量分配比、植物根冠比和硅素转移系数进行测定分析.结果表明:(1)闽江下游植物枯体生物硅含量普遍较高(6.88～70.60 mg·g-1),地下根系生物硅含量普遍较低(2.02～16....     

2011年夏季南大洋普里兹湾颗粒态生物硅的分布与变化特征

利用中国第27次南极科学考察期间获得的颗粒物样品,对南大洋普里兹湾海域水体中颗粒态生物硅的含量及分布特征进行了初步研究,分析了该海域颗粒态生物硅与营养盐、浮游植物以及颗粒有机碳之间的关系,同时结合历史数据对比了颗粒态生物硅的年际变化情况。研究结果显示：在2011年夏季普里兹湾表层水体中颗粒态生物硅含量在0.76-19.72μmol/ dm3之间变化,平均为6.06±4.55μmol/ dm3。在表层水体中的分布趋势是67°S以南的湾内区域颗粒态生物硅含量明显高于67°S以北的湾外区域,最大值出现在普里兹湾陆架区。在垂向分布上,P3断面水体中颗粒态生物硅含量随深度增加而减少。根据不同年份即24,25,26,27次南极科学考察期间获取的数据对比分析显示,颗粒态生物硅含量虽存在一定的年际差异,但是在普里兹湾的分布趋势基本一致。颗粒态生物硅含量的变化特征与硅酸盐相反与叶绿素a、颗粒有机碳相似。     

东寨港红树林中不同群落区表层土壤有机碳及其活性组分含量北大核心CSCD

2021年5月,在海南东寨港国家级自然保护区红树林中的9种群落区,采集表层(0~20 cm深度)的土壤样品,测定表层土壤样品中的有机碳及其活性组分的含量,分析其与土壤化学指标的关系。研究结果表明,东寨港国家级自然保护区红树林中9种群落区表层土壤中的总有机碳、微生物生物量碳、可溶性有机碳和易氧化有机碳质量比的平均值分别为34.45 g/kg、615.01 mg/kg、73.97 mg/kg和1.46 g/kg,其变异系数都大于60%;在9种群落区表层土壤的总有机碳含量中,易氧化有机碳含量所占比例(平均值为4.47%)最大,其次是微生物生物量碳含量所占比例(平均值为1.96%),可溶性有机碳含量所占比例(都小于1.00%)最小;表层土壤中的全氮含量、全钾含量和土壤pH是影响有机碳及其活性组分含量的主要因素。     

基于土壤粒度分析的草原风蚀特征探讨

对放牧、开垦和围封下内蒙古典型草原地表覆盖状况、土壤粒度与有机碳含量进行测定,分析人类活动对草原风蚀的影响。结果表明,与围封草地相比,过度放牧草地的群落盖度及高度分别降低了44.23%和80.71%,根系生物量下降了37.83%。由于植被覆盖及根系密度的降低,过度放牧草地土壤表现出明显的风蚀特征,表层土壤粗粒化明显,表层土壤平均粒径比围封草地增加了约1倍。而开垦造成的风蚀程度则更为严重,开垦使表层土壤颗粒平均粒径增加2.5倍。因此,过牧与开垦下的典型草原已形成为一个重要的沙尘源。土壤颗粒粗化直接引起土壤有机碳含量的下降,土壤中小于0.1 mm颗粒组分每被吹蚀1%,其有机碳含量将减少0.2546 g·kg-1。     

向海湿地不同植被群落下土壤氮素的分布特征

对比分析向海湿地8种植被群落下表层和亚表层土壤氮形态和全氮含量差异,研究不同植被群落下土壤氮素分布特征。结果表明,各植被群落下表层和亚表层土壤全氮主要以有机氮的形态存在;沼柳群落下表层土壤全氮含量最高,三棱群落最低;而香蒲群落下亚表层土壤全氮含量最高,碱蓬群落最低;根系分布较深的植物群落下表层和亚表层土壤氮素一般高于根系分布较浅的植物群落;除辣蓼群落下土壤无机氮以硝态氮为主外,其它各群落下土壤无机氮均以铵态氮为主。相关分析表明,土壤全氮和有机氮含量与土壤有机质含量显著正相关,与土壤pH值呈现显著负相关关系。     

浙闽沪滨海感潮沼泽主要草本植物生物硅含量特征

硅元素是植物生长发育必需的生源元素之一,在湿地生物地球化学循环中起着重要作用。在福建省、浙江省和上海市的18处滨海感潮沼泽中,采集主要的草本植物样品,测定其生物硅含量。研究结果表明,同一种植物的生物硅含量在不同纬度的河口或海湾差异显著,呈线性变化规律;在区域尺度,不同草本植物的生物硅含量差异明显,禾本科(Poaceae)植物芦苇(Phragmites australis)、互花米草(Spartina alterniflora)和莎草科(Cyperaceae)植物短叶茳芏(Cyperus malaccensis)、海三棱藨草(Scirpus mariqueter)、藨草(Scirpus triqueter)的生物硅含量显著高于藜科(Chenopodiaceae)植物南方碱蓬(Suaeda australis),其中芦苇的生物硅含量[(43.3±3.5) mg/g]最高,南方碱蓬的生物硅含量[(5.1±0.6) mg/g]最低;同种植物不同器官的生物硅含量也具有显著差异,互花米草叶片和叶鞘的生物硅含量显著高于茎和穗,芦苇叶鞘的生物硅含量显著高于叶片、茎和穗;互花米草、芦苇、短叶茳芏和南方碱...     

北极Barrow地区几种冻原植物的花粉形态

本文研究了北极巴罗 (Barrow)地区 1 2种冻原植物的花粉形态 ,它们的形状有球形、近球形、扁球形茧形和四合体型 ,其萌发孔有三孔沟、三沟、二合沟以及散孔等类型。花粉具辐射对称和两侧对称两种类型。这些花粉的植物体是北极冻原地区常见的植物 ,分属于 1 2个科 ,除 3种为小灌木外 ,大多数为多年生或一年生草本植物。这些冻原植物花粉形态的研究为恢复北极地区古植被和古气候的研究 ,提供了有价值的对比资料和依据。     

丰水期和枯水期大樟溪下游表层水体不同形态硅含量的差异及其影响因素

硅元素是硅藻和水生植物所必需的营养元素,河流的水文特性对其形态和含量具有重要影响。2019年7月(丰水期)和11月(枯水期),在闽江支流大樟溪下游采集表层水样,比较水体中不同形态硅、溶解性氮磷以及其它理化指标在丰水期和枯水期的差异。结果表明,大樟溪下游表层水体溶解态硅、成岩硅和活性硅含量在丰水期高于枯水期,而生物硅和颗粒态硅含量则反之,这与水体pH、悬浮颗粒物、电导率和溶解性氮磷浓度相关;从水体中各营养元素的化学计量比来看,大樟溪下游表层水体表现为明显的磷限制,营养盐浓度和硅氮比都表明大樟溪水体有利于硅藻类的生长;大樟溪水体长期输入闽江,对闽江下游及河口水体的营养盐平衡具有一定威胁,容易导致近海水域富营养化现象的发生。     

南极菲尔德斯半岛多环境介质中多环芳烃分布特征及环境行为研究

对南极菲尔德斯半岛地区采集的水体、土壤、苔藓、粪便和生物介质中16种多环芳烃(PAHs)进行了分析,考察了不同环境介质中PAHs的含量分布特征及其环境行为。结果表明,水体、土壤、苔藓、粪便和生物中∑PAHs浓度分别为34.9—346 ng·g-1(mean=184)、68.9—374 ng·g-1(mean=188)、122—894 ng·g-1(mean=251)、197—293 ng·g-1(mean=245)和137—443 ng·g-1(mean=265)。与其他地区相比,5种介质中2+3环PAHs的比例超过0.5,而5+6环PAHs的比例则0.2,说明大气传输是菲尔德斯半岛地区PAHs来源的主要途径。通过PAHs在土壤-苔藓(logQSM)、生物-海水(logQOW)和企鹅肌肉-企鹅粪土(logQPD)中的浓度比值与其理化参数的研究发现,logQSM与logpoL和logKOA成显著线性关系,logQOW和logQPD与logKOW成显著线性关系,表明不同环境介质间污染物浓度比值可以看作PAHs在极地偏远地区气-固分配行为以及在生物体内分配行为的镜像。     

楚科奇海表层海水颗粒物组成与来源

对研究区内第五次北极科学考察所取的表层海水颗粒物的浓度、显微组成、有机碳、氮含量及其同位素组成进行了分析。结果表明,楚科奇海域表层海水颗粒物浓度介于0.56—4.01 mg·L-1,具有冰区边缘高于开阔水域的特点。陆架区颗粒有机质相对含量高(TOC:9.78%—20.24%;TN:0.91%—2.31%),有机碳、氮同位素值相对重(δ13C:-23.29‰—-26.33‰PDB;δ15N:6.14‰—7.78‰),有机质主要来源于海洋生物,含有部分陆源有机质;陆坡及北冰洋核心区的颗粒有机质含量,除SR15站外,相对低(TOC:8.06%—8.96%;TN:0.46%—0.72%),有机碳、氮同位素值轻(δ13C:-26.93‰—-27.78‰PDB;δ15N:4.13‰—4.84‰),颗粒物有机质以陆源为主。陆坡区SR15站表层海水颗粒物中异常高的陆源有机质(TOC:27.94%,TN:1.16%;δ13C:-27.43;δ15N:3.81)可能来自源于东西伯利亚的穿极洋流。海冰携带的颗粒物(包括冰藻)是冰区边缘表层海水颗粒物的重要来源,在陆架区海冰融化,向水体中释放了大量生物体;而陆坡区和北冰洋核心区,海冰对颗粒物的贡献以碎屑矿物和黏土矿物为主。     

南大洋普里兹湾沉积物中生物硅的溶解度研究

本文利用中国南极科学考察航次获得的沉积物样品,采用分批（batch）实验方法,获取实验室生物硅溶解度,并结合间隙水中可溶性硅剖面,对普里兹湾沉积物中生物硅的溶出过程进行了初步研究。研究结果如下：在25℃,pH 8条件下,普里兹湾IV-10、 IS-4站表层沉积物中生物硅的实验室溶解度分别为1936、1539μmol/dm3,不同层次沉积物溶出结果显示随深度增加溶解度值降低。根据实验室溶解度数据与间隙水硅酸盐Cd的分析比较,表明研究站位沉积物生物硅的早期成岩过程中生物硅的溶出还伴随有其他化学过程。     

楚科奇海浮冰区夏季短期颗粒有机物通量及其主要组分

中国首次北极科学考察期间 ,于 8月 2 0- 2 3日在楚科奇海浮冰区联合冰站实施了为期 4天的短期颗粒有机物通量研究。结果显示真光层的颗粒有机碳通量为 1 .582mgCm- 2 day- 1 ,2 2 0m深层为 1 .339mgCm- 2 day- 1 ,而相应的沉降颗粒物总通量分别高达 8.788和 1 0 .30 3mgm- 2 day- 1 。显示北极浮冰区的夏季融冰季节后期 ,颗粒有机碳通量的水平较低。与颗粒有机碳通量水平相似 ,生源硅和活性磷的通量水平也较低。对硅藻通量组份的分析表明 ,真光层沉降硅藻的优势种为Nitzschiacf.seriata、Naviculaglacialis和Melosirasp .,而 2 2 0m层则Lepto cylindrussp .占绝对优势 ,其丰度数量百分比均超过 70 %。硅藻碳通量的绝对值较低 ,为0 .1 0 7- 0 .1 1 3mgCm- 2 day- 1 。然而 ,真光层大型桡足类的碳估算值高达 1 0 8.67mgCm- 2day- 1 ,占浮游动物总碳量的 95 .3 % ,大型浮游动物的表观碳通量高于浮游植物碳通量 2- 3个数量级 ,显示楚科奇海夏季融冰期高浮游动物碳量、低浮游植物碳量的特点。但浮游动物表观碳量高的主要原因与浮游动物的昼夜垂直运动有关 ,却并非是实际向深层海洋传输的碳量     

南极半岛邻近海域夏季POC分布特征及其影响因素

海水中的颗粒有机碳(POC)与生物的生命过程、初级生产力关系密切,是海洋食物链中重要的物质基础和能量来源,因此POC的分布特征可以有效反映其生物地球化学环境。利用中国第33次南极考察期间(2016年12月至2017年1月)在南极半岛邻近海域采集的海水颗粒物样品,研究POC的空间分布特征及其影响因素。结果表明,斯科舍海0—200 m的POC浓度范围为7.44—193.52μg·L~(-1),平均浓度为(48.84±35.09)μg·L~(-1);南斯科舍海岭0—200 m的POC浓度范围为9.13—62.17μg·L~(-1),平均浓度为(29.76±14.12)μg·L~(-1);鲍威尔海盆0—200 m的POC浓度范围为5.87—270.72μg·L~(-1),平均浓度为(48.57±38.92)μg·L~(-1)。表层POC高值出现在斯科舍海区和鲍威尔海盆区,而低值出现在海岭区,与叶绿素a(Chla)的变化趋势一致,与营养盐的变化趋势相反。垂向分布上,各个区域POC平均浓度随深度的增加而减少,鲍威尔海盆和斯科舍海POC最高值都出现在25 m层。分析结果表明光合浮游植物是研究海域POC的主要来源, POC的主要影响因素为温度、水团混合以及海冰环境。斯科舍海与鲍威尔海盆整体非生命POC占比高,可能是由于高磷虾生物量、海冰碎屑以及陆源输入的干扰;南斯科舍海岭整体非生命POC占比低。     

九寨沟箭竹海沉积物中BSi含量及其环境指示意义

通过对九寨沟箭竹海沉积物样品中生物硅( BSi)含量的分析,讨论箭竹海沉积物中BSi含量与总有机碳(TOC)及粒度的关系,进而探讨BSi含量反映自然和人类因素对湖泊水体和沉积物的影响.箭竹海沉积物中BSi含量介于5.5～ 15.8 mg/g之间,BSi含量与TOC呈显著正相关关系.BSi含量还较显著地受到粒度影响,较细颗粒沉积物对BSi有较强的吸附作用.箭竹海沉积物中BSi含量变化与气温波动关系不密切,主要反映了森林砍伐和旅游开发等人类活动对湖泊水体和沉积物的影响.     

An analysis of phytolith assemblages for the quantitativereconstruction of late Quaternary environments of the Lower Taieri Plain,Otago, South Island, New Zealand I. Modern assemblages and transferfunctions

An analysis of modern phytolith assemblages is presented.Phytolith assemblages were studied in modern surface soils and sediments of 28sites from east Otago, New Zealand, within a range of vegetation types andmicroclimates. No simple distinction could be made between vegetation types onthe basis of phytolith assemblage composition. A Principal Components Analysis(PCA) of the phytolith data set revealed that festucoid, chloridoid andspherical phytolith morphotypes formed strong associations with sites fromwetland, grassland, and forest vegetation types, respectively. Moreimportantly, a comparison of sample replicates from each field site using Squared ChordDistance (SCD) assemblage analysis showed that wetland and grassland sitestended to produce more internally consistent phytolith assemblages than forestsites. Environmental variables including pH, conductivity, altitude,precipitation and temperature were also gathered for each site. The ability ofeach environmental variable to reflect variance in the entire phytolithdata set was estimated by a series of Redundancy Analyses (RDA) with MonteCarlo permutation tests of statistical significance. After a forward selectionprocess, transfer functions were generated using Partial Least Squares (PLS)regression and calibration with jack-knife validation. The final transferfunctions have root mean squared errors of prediction for pH (0.47), logconductivity (0.38 S cm), average annual precipitation (63mm), and average annual (0.28 °C), spring (0.38 °C) andautumn temperature (0.41 °C); the smallest group of environmental variablesexplaining the most variance in the modern phytolith data set. The most usefultransfer functions for application to fossil phytolith data andpaleoenvironmental interpretation are pH, log conductivity and annualprecipitation. The relationship between changes in pH and annual precipitationand phytolith assemblage composition found in this study presents aprima facie relationship with the potential to providedirect proxies for soil weathering and indirectly for paleoenvironmentalreconstruction.     

Biogeochemistry of silica in Devils Lake: implications for diatom preservation

Diatom-salinity records from sediment cores have been used to construct climate records of saline-lake basins. In many cases, this has been done without thorough understanding of the preservation potential of the diatoms in the sediments through time. The purpose of this study was to determine the biogeochemistry of silica in Devils Lake and evaluate the potential effects of silica cycling on diatom preservation. During the period of record, 1867–1999, lake levels have fluctuated from 427 m above sea level in 1940 to 441.1 m above sea level in 1999. The biogeochemistry of silica in Devils Lake is dominated by internal cycling. During the early 1990s when lake levels were relatively high, about 94% of the biogenic silica (BSi) produced in Devils Lake was recycled in the water column before burial. About 42% of the BSi that was incorporated in bottom sediments was dissolved and diffused back into the lake, and the remaining 58% was buried. Therefore, the BSi accumulation rate was about 3% of the BSi assimilation rate. Generally, the results obtained from this study are similar to those obtained from studies of the biogeochemistry of silica in large oligotrophic lakes and the open ocean where most of the BSi produced is recycled in surface water. During the mid 1960s when lake levels were relatively low, BSi assimilation and water-column dissolution rates were much higher than when lake levels were high. The BSi assimilation rate was as much as three times higher during low lake levels. Even with the much higher BSi assimilation rate, the BSi accumulation rate was about three times lower because the BSi water-column dissolution rate was more than 99% of the BSi assimilation rate compared to 94% during high lake levels. Variations in the biogeochemistry of silica with lake level have important implications for paleolimnologic studies. Increased BSi water-column dissolution during decreasing lake levels may alter the diatom-salinity record by selectively removing the less resistant diatoms. Also, BSi accumulation may be proportional to the amount of silica input from tributary sources. Therefore, BSi accumulation chronologies from sediment cores may be effective records of tributary inflow.     

Sources and transport of organic carbon from the Dongjiang River to the Humen outlet ofthe Pearl River,southern China简

Transport of organic carbon via rivers to estuary is a significant geochemical proc- ess in the global carbon cycle. This paper presents bulk total organic carbon （TOC） from the Dongjiang catchment to the adjacent Humen outlet, and discusses the applicability of 613C and ratio of carbon to nitrogen （C/N） as indicators for sources of organic matter in the surface sediments. Survey results showed that organic carbon concentration in summer were higher than in the winter. An elevated trend of TOC occurred along the river to the Humen outlet in both surveys, and the highest mean values of dissolved and particular organic carbon （DOC-279 μmol L-1 and POC-163μmol L-1） were observed in the urban deltaic region in summer flood flow. Winter samples had a wide range of b＇13C and C/N （5-3C -24.6%o to -30.0%o, C/N 4-13）, and summer ones varied slightly （8-3C -24.2%o to -27.6%0, C/N 6-18）. As results suggest that POC in the three zones of upstream-delta-outlet dominantly came from riverbank soil, phytoplankton and agricultural C3 plants in winter, whereas main sources were from the riverbank and mangrove soil in summer. Moreover, anthropogenic sewage inputs had 11% and 7% contribution to POC in the deltaic and outlet. Transport accompanied with seasonal freshwater variation, phytoplankton production and degradation, and removal be- havior caused variation of organic carbon concentration. The results also discovered that TOC export bulk in Dongjiang was approximately one quarter of Humen flux in the dry flow, and anthropogenic activity significantly impacted the river export contribution.     

Independent measurement of biogenic silica in sediments by FTIR spectroscopy and PLS regression

We present an independent calibration model for the determination of biogenic silica (BSi) in sediments, developed from analysis of synthetic sediment mixtures and application of Fourier transform infrared spectroscopy (FTIRS) and partial least squares regression (PLSR) modeling. In contrast to current FTIRS applications for quantifying BSi, this new calibration is independent from conventional wet-chemical techniques and their associated measurement uncertainties. This approach also removes the need for developing internal calibrations between the two methods for individual sediments records. For the independent calibration, we produced six series of different synthetic sediment mixtures using two purified diatom extracts, with one extract mixed with quartz sand, calcite, 60/40 quartz/calcite and two different natural sediments, and a second extract mixed with one of the natural sediments. A total of 306 samples—51 samples per series—yielded BSi contents ranging from 0 to 100 %. The resulting PLSR calibration model between the FTIR spectral information and the defined BSi concentration of the synthetic sediment mixtures exhibits a strong cross-validated correlation ( \( {\text{R}}^{ 2}_{\text{cv}} \)  = 0.97) and a low root-mean square error of cross-validation (RMSECV = 4.7 %). Application of the independent calibration to natural lacustrine and marine sediments yields robust BSi reconstructions. At present, the synthetic mixtures do not include the variation in organic matter that occurs in natural samples, which may explain the somewhat lower prediction accuracy of the calibration model for organic-rich samples.     

高寒地区生态修复草地和林地土壤颗粒有机碳分解特征

为探讨高寒地区生态修复用地土壤颗粒有机碳（POC）分解特征,以祁连山南坡的修复草地和修复林地为研究对象,使用离心法将土壤分为砂粒（2 000—50 μm）、粉粒（2—50 μm）和黏粒（<2 μm）,对土壤颗粒有机碳含量、土壤颗粒有机碳分配及颗粒有机碳稳定同位素组成特征进行了研究。结果表明：（1）两种修复用地均能提高颗粒有机碳的含量,新增的颗粒有机碳在修复草地中以砂粒有机碳为主体,在修复林地以粉粒和黏粒有机碳为主体。（2）3种土壤颗粒δ¹³C值均随粒径变小而增大,δ¹³C值与颗粒有机碳含量对数的回归斜率随着粒径变小而降低,修复林地叶片与表土有机碳的δ¹³C值分馏幅度高于修复草地,根系与表土有机碳的δ¹³C值分馏幅度小于修复草地。（3）修复草地砂粒、粉粒、黏粒有机碳平均周转时间分为9、20、34 a,修复林地分别为20、29、94 a,且两种修复用地的3种颗粒有机碳周转时间均有随修复年限增加而变长趋势。两种生态修复用地土壤颗粒有机碳的分解程度和周转速率均随着粒径减小而增大,从叶片转换为黏粒有机碳的过程中,修复林地周转速率较大,从根系转换成黏粒有机碳的过程中,修复草地更快。     

南极普里兹湾真光层下水体中有机碳和无机碳的分解比例的估算

本文利用中国第25次南极科学考察数据,运用数学模型对南极普里兹湾有机碳与无机碳的分解比及上层水体POC的再矿化效率进行了估算。结果表明:普里兹湾及其邻近海域POC的浓度范围为24.38~446.40μg?dm-3,平均值为118.16μg?dm-3。在普里兹湾P2断面陆架区,上层水体中的有机碳和无机碳向下层水体输出埋藏过程中,两者分解速率比为1.27（摩尔比）,根据相关结果我们推测上层水体中的颗粒有机碳向底层输出埋藏的过程中有81%发生了转化重新参与海洋碳循环。